US3220869A - Process for improving textile fabrics - Google Patents
Process for improving textile fabrics Download PDFInfo
- Publication number
- US3220869A US3220869A US6954060A US3220869A US 3220869 A US3220869 A US 3220869A US 6954060 A US6954060 A US 6954060A US 3220869 A US3220869 A US 3220869A
- Authority
- US
- United States
- Prior art keywords
- parts
- fabric
- aqueous
- copolymer
- impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title claims description 112
- 238000000034 method Methods 0.000 title claims description 30
- 239000004753 textile Substances 0.000 title claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 53
- 150000001875 compounds Chemical class 0.000 claims description 25
- -1 METHYLOL GROUPS Chemical group 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 47
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 34
- 239000006185 dispersion Substances 0.000 description 33
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 27
- 238000005299 abrasion Methods 0.000 description 25
- 239000000203 mixture Substances 0.000 description 24
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical class CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 24
- 239000007864 aqueous solution Substances 0.000 description 22
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 21
- 239000003795 chemical substances by application Substances 0.000 description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 description 16
- XKALZGSIEJZJCZ-UHFFFAOYSA-N 1,3-bis(methoxymethyl)urea Chemical compound COCNC(=O)NCOC XKALZGSIEJZJCZ-UHFFFAOYSA-N 0.000 description 13
- 229920000742 Cotton Polymers 0.000 description 13
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 13
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
- 229950005308 oxymethurea Drugs 0.000 description 12
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 11
- 239000005696 Diammonium phosphate Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 11
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 11
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 11
- 235000019838 diammonium phosphate Nutrition 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 11
- 238000011084 recovery Methods 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 10
- 238000005470 impregnation Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 9
- 235000021355 Stearic acid Nutrition 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 9
- 239000008117 stearic acid Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 239000007859 condensation product Substances 0.000 description 8
- 230000003292 diminished effect Effects 0.000 description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 8
- MSISRBNSEDYCOX-UHFFFAOYSA-N 1,3-bis(hydroxymethyl)-1,3-dimethylurea Chemical compound OCN(C)C(=O)N(C)CO MSISRBNSEDYCOX-UHFFFAOYSA-N 0.000 description 7
- 229920000297 Rayon Polymers 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 238000004855 creaseproofing Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000002964 rayon Substances 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 6
- NCMAUXCEBVDHDA-UHFFFAOYSA-N NC(=O)OCC.NC(=O)OCC.C(O)C(C(O)(O)CO)CC Chemical compound NC(=O)OCC.NC(=O)OCC.C(O)C(C(O)(O)CO)CC NCMAUXCEBVDHDA-UHFFFAOYSA-N 0.000 description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 description 6
- 125000004433 nitrogen atom Chemical group N* 0.000 description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 5
- 229920003043 Cellulose fiber Polymers 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- DFGLHEOSIBIARJ-UHFFFAOYSA-N 5-[3-hydroxy-2-(hydroxymethyl)propyl]-1H-triazin-6-one Chemical compound C(O)C(CC=1C(NN=NC=1)=O)CO DFGLHEOSIBIARJ-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 4
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 235000019837 monoammonium phosphate Nutrition 0.000 description 4
- 239000006012 monoammonium phosphate Substances 0.000 description 4
- NNTWKXKLHMTGBU-UHFFFAOYSA-N 4,5-dihydroxyimidazolidin-2-one Chemical compound OC1NC(=O)NC1O NNTWKXKLHMTGBU-UHFFFAOYSA-N 0.000 description 3
- RXCWKMRKGFIQDO-UHFFFAOYSA-N 5,6-bis(hydroxymethyl)-1-(2-methylpropyl)triazin-4-one Chemical compound C(O)C1=C(C(N=NN1CC(C)C)=O)CO RXCWKMRKGFIQDO-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- XUCKRMMSUKCKBN-UHFFFAOYSA-N C(O)C(C(C)C)(C=1C(NN=NC1)=O)CO Chemical compound C(O)C(C(C)C)(C=1C(NN=NC1)=O)CO XUCKRMMSUKCKBN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 description 3
- VQBYRDFXBAXTHC-UHFFFAOYSA-N [[4-(hydroxymethylamino)-6-[hydroxymethyl(methyl)amino]-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCN(C)C1=NC(NCO)=NC(NCO)=N1 VQBYRDFXBAXTHC-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 238000004900 laundering Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical class NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000004627 regenerated cellulose Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000009988 textile finishing Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- 235000005074 zinc chloride Nutrition 0.000 description 3
- UUGLSEIATNSHRI-UHFFFAOYSA-N 1,3,4,6-tetrakis(hydroxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound OCN1C(=O)N(CO)C2C1N(CO)C(=O)N2CO UUGLSEIATNSHRI-UHFFFAOYSA-N 0.000 description 2
- AMTOHUZYCNNVHB-UHFFFAOYSA-N 1,5-dihydroxy-2,2-bis(hydroxymethyl)pentan-3-one Chemical compound OCCC(=O)C(CO)(CO)CO AMTOHUZYCNNVHB-UHFFFAOYSA-N 0.000 description 2
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 206010003549 asthenia Diseases 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000005108 dry cleaning Methods 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- XMKLTEGSALONPH-UHFFFAOYSA-N 1,2,4,5-tetrazinane-3,6-dione Chemical compound O=C1NNC(=O)NN1 XMKLTEGSALONPH-UHFFFAOYSA-N 0.000 description 1
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 1
- XPJZBBZXCSKUDN-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)hexanediamide Chemical compound C(O)C(C(=O)N)(CCCC(=O)N)CO XPJZBBZXCSKUDN-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- CTRPRMNBTVRDFH-UHFFFAOYSA-N 2-n-methyl-1,3,5-triazine-2,4,6-triamine Chemical compound CNC1=NC(N)=NC(N)=N1 CTRPRMNBTVRDFH-UHFFFAOYSA-N 0.000 description 1
- JIHOVGXINXMLLR-UHFFFAOYSA-N 2-n-phenyl-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2C=CC=CC=2)=N1 JIHOVGXINXMLLR-UHFFFAOYSA-N 0.000 description 1
- IBZGBXXTIGCACK-UHFFFAOYSA-N 6,7,9,11-tetrahydroxy-9-(2-hydroxyacetyl)-4-methoxy-8,10-dihydro-7h-tetracene-5,12-dione Chemical compound C1C(O)(C(=O)CO)CC(O)C2=C1C(O)=C1C(=O)C(C=CC=C3OC)=C3C(=O)C1=C2O IBZGBXXTIGCACK-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920008712 Copo Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004890 Hydrophobing Agent Substances 0.000 description 1
- 239000004233 Indanthrene blue RS Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical class CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- XGEGHDBEHXKFPX-UHFFFAOYSA-N N-methylthiourea Natural products CNC(N)=O XGEGHDBEHXKFPX-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- SUPOBRXPULIDDX-UHFFFAOYSA-N [[4-amino-6-(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound NC1=NC(NCO)=NC(NCO)=N1 SUPOBRXPULIDDX-UHFFFAOYSA-N 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- SIIVGPQREKVCOP-UHFFFAOYSA-N but-1-en-1-ol Chemical compound CCC=CO SIIVGPQREKVCOP-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- HRKWOOHVRHBXHJ-UHFFFAOYSA-N hexan-2-yl prop-2-enoate Chemical compound CCCCC(C)OC(=O)C=C HRKWOOHVRHBXHJ-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000010002 mechanical finishing Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XGEGHDBEHXKFPX-NJFSPNSNSA-N methylurea Chemical compound [14CH3]NC(N)=O XGEGHDBEHXKFPX-NJFSPNSNSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- UWBHMRBRLOJJAA-UHFFFAOYSA-N oxaluric acid Chemical compound NC(=O)NC(=O)C(O)=O UWBHMRBRLOJJAA-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229930189118 repenin Natural products 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229940055764 triaz Drugs 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
- D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/08—Decorating textiles by fixation of mechanical effects, e.g. calendering, embossing or Chintz effects, using chemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
- Y10T442/2393—Coating or impregnation provides crease-resistance or wash and wear characteristics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/273—Coating or impregnation provides wear or abrasion resistance
Definitions
- R; and R are, for example, H, alkyl (for example, with 1 to 18 and especially 1 to 4 carbon atoms), C H or CN, or R and R together may be a divalent radical such as in which R may be H or an alkyl radical of the abovementioned kind, and X is in general :0, 8 or :NH, are especially suitable.
- R; and R are, for example, H, alkyl (for example, with 1 to 18 and especially 1 to 4 carbon atoms), C H or CN, or R and R together may be a divalent radical such as in which R may be H or an alkyl radical of the abovementioned kind, and X is in general :0, 8 or :NH, are especially suitable.
- R and R are, for example, H, alkyl (for example, with 1 to 18 and especially 1 to 4 carbon atoms), C H or CN, or R and R together may be a divalent radical such as in which R may be H or an alkyl radical of
- mixtures of the above mentioned kind in which the copolymer has been prepared from 1 to 25% of an N-methylolamide of an acrylic acid and 99 to 75% of one or more copolymerizable compounds are eminently suitable for imparting to a fabric the properties required for the production of mechanical effects, the mechanical effects being produced by subjecting a fabric impregnated with said aqueous mixture, preferably after drying, to a mechanical treatment at an elevated temperature and heating the fabric thus treated again to a high temperature.
- the values measured for fabric 13 are obtained by the use of 20 parts of tetramethylolacetone, 20 parts of dimethylolisobutyltriazinone, 40 parts of dimethylolethyleneurea and 15 parts of zinc nitrate in 1000 parts of water.
- the aqueous bath contained, in 1000 parts, 150 parts of a 70% aqueous crystal pulp of equal parts of monomethylolurea and dimethylolurea and 3 parts of monoammonium phosphate.
- Each formulanon w1ll 70 contain one agent I, one agent II, one dispersing agent product of iso-octylphenol with ethylene oxide and 5 parts of ammonium nitrate.
- the fabric thus impregnated is dried at 100 C. until it has a residual moisture content of about 12%. It is then embossed at 180 C. by applying a pressure of about 15 metric tons, and finally heated for 5 minutes at C.
- Agent Ila.60 parts of a 40% aqueous dispersion of a copolymer derived from:
- Dispersion agent IlI.-2 to 5 parts of a reaction product of iso-octylphenol or a fatty acid monoethanol amide with ethylene oxide.
- a process for improving a textile fabric which contains at least 25% by weight of cellulose fibers comprising treating said textile fabric with an aqueous liquor which contains:
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB52466A DE1110606B (de) | 1959-03-13 | 1959-03-13 | Verfahren zum Veredeln von Textilgeweben |
| DEB55580A DE1128397B (de) | 1959-03-13 | 1959-11-18 | Verfahren zum Veredeln von Textilgeweben |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3220869A true US3220869A (en) | 1965-11-30 |
Family
ID=25965350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US6954060 Expired - Lifetime US3220869A (en) | 1959-03-13 | 1960-11-16 | Process for improving textile fabrics |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3220869A (en(2012)) |
| BE (1) | BE588503A (en(2012)) |
| CH (2) | CH388244A (en(2012)) |
| DE (2) | DE1110606B (en(2012)) |
| GB (2) | GB882743A (en(2012)) |
| NL (3) | NL249327A (en(2012)) |
| SE (1) | SE310481B (en(2012)) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3322569A (en) * | 1962-11-10 | 1967-05-30 | Basf Ag | Treatment of cellulosic textiles with a crease resisting finish and a copolymer of a n-methylolamide of an acrylic acid for the purpose of reducing wet soiling |
| US3420702A (en) * | 1965-05-11 | 1969-01-07 | Dan River Mills Inc | Double bath treatment of cellulosic fabrics to impart crease resistance and high abrasion resistance thereto |
| US3448462A (en) * | 1964-09-14 | 1969-06-10 | Deering Milliken Res Corp | Collar and cuff-like garment member and method of making it |
| US3516781A (en) * | 1967-02-13 | 1970-06-23 | Stevens & Co Inc J P | Novel modifying process |
| US3519459A (en) * | 1964-09-23 | 1970-07-07 | Ciba Ltd | Process for producing finely porous coatings |
| US3632419A (en) * | 1967-11-15 | 1972-01-04 | Fukui Seiren Kako Co Ltd | Method for imparting durable soil-resistant finish to polyamide and polyester fabrics and the treated fabrics |
| US3731411A (en) * | 1971-06-11 | 1973-05-08 | Burlington Industries Inc | Process for producing durable press textiles |
| US3807952A (en) * | 1971-10-08 | 1974-04-30 | Raduner & Co Ag | Method of crosslinking cellulosic fibres |
| US3949108A (en) * | 1973-06-01 | 1976-04-06 | The United States Of America As Represented By The Secretary Of Agriculture | Process for producing fire resistant organic textile materials |
| JPS6053551A (ja) * | 1983-08-06 | 1985-03-27 | ヘキスト・アクチエンゲゼルシヤフト | 架橋性重合体を基礎とするホルムアルデヒド不含の合成樹脂水性分散物、その製造方法およびその用途 |
| EP0206588A1 (en) * | 1985-06-04 | 1986-12-30 | Sumitomo Chemical Company, Limited | Copolymer binder composition and fabrics and papers treated therewith |
| CN106049101A (zh) * | 2016-06-12 | 2016-10-26 | 青岛大学 | 一种海藻无纺布常温快速浸染及增强防紫外线性能的方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1351590A (fr) * | 1962-12-28 | 1964-02-07 | Nobel Bozel | Produits de condensation de l'acrylamide avec l'acétylène-mono-uréine |
| GB1054682A (en(2012)) * | 1963-04-13 | 1900-01-01 | ||
| CH1357464D (en(2012)) * | 1964-09-21 | 1900-01-01 | ||
| DE1594914B1 (de) * | 1966-10-06 | 1970-06-04 | Basf Ag | Verfahren zum Veredeln von Cellulose enthaltendem oder daraus bestehendem Fasergut |
| DE3443327C1 (de) * | 1984-11-28 | 1985-09-05 | Rosorius, Gerhard, 2085 Quickborn | Verfahren zur Verbesserung der Eigenschaften von Textilien,die aus nativen pflanzlichen oder tierischen Fasern bestehen oder diese enthalten |
| US4927698A (en) * | 1989-03-15 | 1990-05-22 | Springs Industries, Inc. | Pucker and shrink resistant flame retardant fabric formed of corespun yarns |
| DE4233497A1 (de) * | 1992-10-06 | 1994-04-07 | Basf Ag | Verwendung von wäßrigen Polymerisatdispersionen als Textilhilfsmittel zur pflegeleichten Veredlung von Textilien |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2536050A (en) * | 1947-11-10 | 1951-01-02 | American Cyanamid Co | Treatment of cellulosic textile materials and products thereof |
| US2819179A (en) * | 1954-01-18 | 1958-01-07 | American Cyanamid Co | Textile finishing process |
| US2864093A (en) * | 1954-10-20 | 1958-12-16 | Chicopec Mfg Corp | Washable garment part |
| US2876062A (en) * | 1953-09-03 | 1959-03-03 | Phrix Werke Ag | Process of crease-proofing cellulose fibers and fabrics by applying ureaformaldehyde-glyoxal reaction products |
| US2950553A (en) * | 1957-01-16 | 1960-08-30 | Rohm & Haas | Method of producing wrinkle resistant garments and other manufactured articles of cotton-containing fabrics |
| US2974432A (en) * | 1956-02-20 | 1961-03-14 | Koret Of California | Press-free crease retained garments and method of manufacture thereof |
| US2976167A (en) * | 1955-08-17 | 1961-03-21 | Ciba Ltd | Process for improving fibrous material and composition therefor |
| US3037963A (en) * | 1955-02-24 | 1962-06-05 | Pittsburgh Plate Glass Co | Resinous materials |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE906568C (de) * | 1951-10-20 | 1954-03-15 | Basf Ag | Verfahren zur Herstellung nassfester UEberzuege, Impraegnierungen, Drucke u. dgl. auf faserigem Material |
| DE1014957B (de) * | 1955-07-08 | 1957-09-05 | Basf Ag | Textilhilfsmittel auf Basis von wasserloeslichen Mischpolymerisaten |
-
0
- NL NL257973D patent/NL257973A/xx unknown
- BE BE588503D patent/BE588503A/xx unknown
- NL NL128429D patent/NL128429C/xx active
- NL NL249327D patent/NL249327A/xx unknown
-
1959
- 1959-03-13 DE DEB52466A patent/DE1110606B/de active Pending
- 1959-11-18 DE DEB55580A patent/DE1128397B/de active Pending
-
1960
- 1960-03-01 CH CH231360A patent/CH388244A/de unknown
- 1960-03-11 GB GB861860A patent/GB882743A/en not_active Expired
- 1960-10-21 CH CH1180060A patent/CH407939A/de unknown
- 1960-11-03 SE SE1059060A patent/SE310481B/xx unknown
- 1960-11-16 US US6954060 patent/US3220869A/en not_active Expired - Lifetime
- 1960-11-17 GB GB3946960A patent/GB916698A/en not_active Expired
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2536050A (en) * | 1947-11-10 | 1951-01-02 | American Cyanamid Co | Treatment of cellulosic textile materials and products thereof |
| US2876062A (en) * | 1953-09-03 | 1959-03-03 | Phrix Werke Ag | Process of crease-proofing cellulose fibers and fabrics by applying ureaformaldehyde-glyoxal reaction products |
| US2819179A (en) * | 1954-01-18 | 1958-01-07 | American Cyanamid Co | Textile finishing process |
| US2864093A (en) * | 1954-10-20 | 1958-12-16 | Chicopec Mfg Corp | Washable garment part |
| US3037963A (en) * | 1955-02-24 | 1962-06-05 | Pittsburgh Plate Glass Co | Resinous materials |
| US3037963B1 (en) * | 1955-02-24 | 1962-06-05 | Reexamination certificate | |
| US2976167A (en) * | 1955-08-17 | 1961-03-21 | Ciba Ltd | Process for improving fibrous material and composition therefor |
| US2974432A (en) * | 1956-02-20 | 1961-03-14 | Koret Of California | Press-free crease retained garments and method of manufacture thereof |
| US2950553A (en) * | 1957-01-16 | 1960-08-30 | Rohm & Haas | Method of producing wrinkle resistant garments and other manufactured articles of cotton-containing fabrics |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3322569A (en) * | 1962-11-10 | 1967-05-30 | Basf Ag | Treatment of cellulosic textiles with a crease resisting finish and a copolymer of a n-methylolamide of an acrylic acid for the purpose of reducing wet soiling |
| US3448462A (en) * | 1964-09-14 | 1969-06-10 | Deering Milliken Res Corp | Collar and cuff-like garment member and method of making it |
| US3519459A (en) * | 1964-09-23 | 1970-07-07 | Ciba Ltd | Process for producing finely porous coatings |
| US3420702A (en) * | 1965-05-11 | 1969-01-07 | Dan River Mills Inc | Double bath treatment of cellulosic fabrics to impart crease resistance and high abrasion resistance thereto |
| US3516781A (en) * | 1967-02-13 | 1970-06-23 | Stevens & Co Inc J P | Novel modifying process |
| US3632419A (en) * | 1967-11-15 | 1972-01-04 | Fukui Seiren Kako Co Ltd | Method for imparting durable soil-resistant finish to polyamide and polyester fabrics and the treated fabrics |
| US3731411A (en) * | 1971-06-11 | 1973-05-08 | Burlington Industries Inc | Process for producing durable press textiles |
| US3807952A (en) * | 1971-10-08 | 1974-04-30 | Raduner & Co Ag | Method of crosslinking cellulosic fibres |
| US3949108A (en) * | 1973-06-01 | 1976-04-06 | The United States Of America As Represented By The Secretary Of Agriculture | Process for producing fire resistant organic textile materials |
| JPS6053551A (ja) * | 1983-08-06 | 1985-03-27 | ヘキスト・アクチエンゲゼルシヤフト | 架橋性重合体を基礎とするホルムアルデヒド不含の合成樹脂水性分散物、その製造方法およびその用途 |
| EP0143175A1 (de) * | 1983-08-06 | 1985-06-05 | Hoechst Aktiengesellschaft | Formaldehydfreie wässrige Kunststoffdispersionen auf Basis eines vernetzbaren Polymerisats, Verfahren zu ihrer Herstellung und ihre Verwendung |
| AU568391B2 (en) * | 1983-08-06 | 1987-12-24 | Hoechst A.G. | Formaldehyde-free aqueous polymer dispersion |
| JPH0791434B2 (ja) | 1983-08-06 | 1995-10-04 | ヘキスト・アクチェンゲゼルシャフト | 架橋性重合体を基礎とするホルムアルデヒド不含の合成樹脂水性分散物およびその製造方法 |
| EP0206588A1 (en) * | 1985-06-04 | 1986-12-30 | Sumitomo Chemical Company, Limited | Copolymer binder composition and fabrics and papers treated therewith |
| US4847143A (en) * | 1985-06-04 | 1989-07-11 | Sumitomo Chemical Company, Limited | Binder composition and nonwoven fabrics and impregnated papers using the same |
| CN106049101A (zh) * | 2016-06-12 | 2016-10-26 | 青岛大学 | 一种海藻无纺布常温快速浸染及增强防紫外线性能的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE588503A (en(2012)) | 1900-01-01 |
| CH407939A (de) | 1966-09-15 |
| DE1128397B (de) | 1962-04-26 |
| GB916698A (en) | 1963-01-23 |
| NL249327A (en(2012)) | 1900-01-01 |
| SE310481B (en(2012)) | 1969-05-05 |
| NL257973A (en(2012)) | 1900-01-01 |
| GB882743A (en) | 1961-11-22 |
| CH388244A (de) | 1965-06-15 |
| CH1180060A4 (en(2012)) | 1965-10-15 |
| DE1110606B (de) | 1961-07-13 |
| CH231360A4 (en(2012)) | 1964-08-31 |
| NL128429C (en(2012)) | 1900-01-01 |
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