US3159581A - Detergency composition - Google Patents

Detergency composition Download PDF

Info

Publication number
US3159581A
US3159581A US187327A US18732762A US3159581A US 3159581 A US3159581 A US 3159581A US 187327 A US187327 A US 187327A US 18732762 A US18732762 A US 18732762A US 3159581 A US3159581 A US 3159581A
Authority
US
United States
Prior art keywords
builder
detergent
sodium
water
ehdp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US187327A
Other languages
English (en)
Inventor
Francis L Diehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL132418D priority Critical patent/NL132418C/xx
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to US187327A priority patent/US3159581A/en
Priority to DK156563AA priority patent/DK111829B/da
Priority to FI0728/63A priority patent/FI41762B/fi
Priority to GB14689/63A priority patent/GB1035913A/en
Priority to DE19631467648 priority patent/DE1467648A1/de
Priority to FR931532A priority patent/FR1439824A/fr
Priority to AU51843/64A priority patent/AU294552B2/en
Priority to NL6413483A priority patent/NL6413483A/xx
Priority to BE655988A priority patent/BE655988A/xx
Application granted granted Critical
Publication of US3159581A publication Critical patent/US3159581A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites

Definitions

  • This invention relates to detergent compositions, and more particularly detergent compositions containing socalled builder materials that serve to enhance the cleaning capacity of detergent compounds.
  • water-soluble inorganic alkaline builder salts which are used alone or in combination.
  • alkali metal carbonates borates, phosphates, polyphosphates, bicarbonates and silicates.
  • organic builder compounds known heretofore and which also can be used alone and in. combination are alkali metal, ammonium or substituted ammonium aminopolycarboxylates, e.g., sodium'and potassium ethylenediaminetetraacetate, sodium and potassium N-(2- hydroxyethyl)-ethylenediaminetriacetate, sodium and potassium nitrilotriacetate and sodium, potassium and tri- United States Patent v sess builder properties to an exceptional degree.
  • alkali metal, ammonium or substituted ammonium aminopolycarboxylates e.g., sodium'and potassium ethylenediaminetetraacetate, sodium and potassium N-(2- hydroxyethyl)-ethylenediaminetriacetate, sodium and potassium nitrilotriacetate and sodium, potassium and tri- United States Patent v sess builder properties to an exceptional degree.
  • watersoluble salts of ethane-bhydroxy-l,l-diphosphonate pos- can be used to build detergent compositions containing a broad range of known detergent active materials. For instance, these compounds can build detergent compositions containing as active ingredients anionic, nonionic, ampholytic and zwitterionic detergent compounds.
  • FIGURE 1 is a graph showing washing grades obtained as a function of the molar concentration of two builder materials as hereinafter more fully described.
  • the water-soluble builder salts of this invention are derivatives of ethane -l-hydroxy-l,l-diphosphonic acid which has the following molecular formula CHSU a 2h hydrogens are replaced by sodium.
  • the salt comethanolammonium N (2 hydroxyethyl)-nitrilodiacetate.
  • Alkali metal salts of phytic acid, e.g.,' sodium phytate are also suitable asorganic builders.
  • the tetrasodium salt, the trisodium salt and mixtures thereof are the preferred forms.
  • Mixtures of the tetrasodium and trisodium salts give a pH in water solution from about 9.5 to 11.5.
  • Each of the lesser neutralized forms such as monosodium and disodium derivatives or the free acid have comparable builder capacity to the trisodium and tetrasodium salt forms'provided that additional alkali is added to adjust the pH of the washing solution to about 9 to about 12.
  • the standard alkaline materials can be used for this purpose, such as alkali metal silicates, phosphates, borates and carbonates.
  • Free alkali materials such as sodium and potassium hydroxides can also be used.
  • EHDP novel builder compound
  • compositions consisting essentially of a synthetic non-soap detergent surfactant compound and as a builder, a watersoluble salt of ethane-l-hydroxy-l,l-diphosphonate, such as the sodium or potassium salts, the ratio by weight of the builder to the detergent surfactant compound being in the range of about 1:2 to about 10:1, said composition providing in solution a pH of about 9 to 12.
  • the preferred ratio of diphosphonate builder to said detergent surfactant compound is in the range of about 1:1 to about 5:1 and the optimum pH range is 9.5 to 11.5.
  • EHDP-built compositions forms a highly soluble compound in water whereas the ST? complex forms a sodium salt which is substantially less soluble and tends to precipitate out on the articles being washed.
  • the insoluble complex which precipitates out on the articles firmly adheres to such articles.
  • the precipate is ex posed to an excess of hardness imparting ingredients which proceed to react with the precipitated complex salt and transform it to an even more insoluble adherent form.
  • the washing process can be complicated by the complex forming properties of an STP built detergent composition where the active STP builder is consumed and bound up in an insoluble complex.
  • EHDP when used as a detergency builder is bound up in a solubiliz ed form which allows it to participate in and carry on the many other builder functns.
  • Anionic synthetic detergents This class of synthetic detergents can be broadly described as the watersoluble salts, particularly the alkali metal salts of organic sulfuric reaction products having in their molecular structure an alkyl radical containing from about 8 to about 22 carbon atoms and a radical selected from the group consisting of sulfonic acid and sulfuric acid ester radicals.
  • alkyl is the alkyl portion of higher acyl radicals.
  • the synthetic detergents which form a part of the preferred compositions of the present invention are the sodium alkyl sulfates, especially those obtained by sulfating the higher alcohols (C C carbon atoms) produced by reducing the glycerides of tallow or coconut oil; sodium or potassium alkylbenzenesulfonates, in which the alkyl group contains from about 9 to about 15 carbon atoms, especially those of the types described in United States Letters Patent Numbers 2,220,099, and 2,477,383; sodium alkylglycerylethersulfonates, especially those ethers of the higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulfates and sulfonates; sodium or potassium salts of sulfuric acid esters of the reaction product of one mole of a higher fatty alcohol (e.g., tallow or
  • Nonionic synthetic detergents This class of synthetic detergents may be broadly defined as compounds aliphatic or alkyl aromatic in nature which do not ionize in water solution.
  • Pluronic a well known class of nonionic synthetic detergents is made available on the market under the trade name of Pluronic. These compounds are formed by condensing ethylene oxide with an hydrophobic base formed by the condensation of propylene oxide with propylene glycol.
  • the hydrophobic portion of the molecule which, of course, exhibits water insolubility has a molecular weight of from about 1200 to 2500.
  • the addition of polyoxyethylene radicals to this hydrophobic portion tends to increase the water solubility of the molecule as a whole and the liquid character of the product is retained up to the point where polyoxyethylene content is about 50% of the total weight of the condensation product.
  • nonionic synthetic detergents include:
  • the polyethylene oxide condensates of alkylphenols, e.g., the condensation products of alkylphenols or dialkylphenols wherein the alkyl group contains from about 6 to 12 carbon atoms in either a straight chain or branched chain configuration, with ethylene oxide, the said ethylene oxide being present in amounts equal to 10 to 25 moles of ethylene oxide per mole of alkylphenol.
  • alkyl substituent in such compounds may be derived from polymerized propylene, diisobutylene, n-octene, or
  • Those derived from the condensation of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylenediamine For example, compounds containing from about 40% to about polyoxyethylene by weight and having a molecular weight of from about 5000 to about 11,000 resulting from the (3)
  • R R R N O Long chain tertiary amine oxides corresponding to the following general formula, R R R N O, wherein R is an alkyl radical of from about 8 to 18 carbon atoms, and R and R are each methyl or ethyl radicals.
  • the arrow in the formula is a conventionalrepresentation of a semi-polar bond.
  • amine oxides suitable for use in this invention include dimethyldodecylarnine oxide, dimethyloctylamine oxide, dimethyldecylamine oxide, dimethyltetradecylamine oxide, dimethylhexadecylamine oxide.
  • Long chain tertiary phosphine oxides correspond ing to the following general formula RRR"P O wherein R is an alkyl, alkenyl or monohydroxyalkyl radical ranging from 10 to 18 carbon atoms in chain length and R and R are each alkyl or monohydroxyalkyl groups containing from 1 to 3' carbon atoms.
  • RRR"P O wherein R is an alkyl, alkenyl or monohydroxyalkyl radical ranging from 10 to 18 carbon atoms in chain length and R and R are each alkyl or monohydroxyalkyl groups containing from 1 to 3' carbon atoms.
  • the arrow in the formula is a conventional representation of a semi-polar bond.
  • suitable phosphine oxides are:
  • anionic, nonionic, ampholytic and zwitterionic detergent surfactants mentioned above can be used singly or in combination in the practice of the present invention.
  • the above examples are merely specific illustrations of the numerous detergents which can find application within the scope of thisinvention.
  • Granular detergent compositions according to one embodiment of this invention can contain the EHDP builder and the detergent active in the ratio of about'lzZ to about 10: 1.
  • the preferred ratio of builder to active is about 1:1 to aboutSzl.
  • Another embodiment of this invention is a liquid detergent composition also containing the EHDPbuilder and the detergent active in the ratio of about 1:2 to about about 1:2 to about 3:1.
  • a'sample'built detergent composition' of this invention can consist essentially of EHDP and a detergent surfactant in: the ratios above described and the balance beinga vehiclemediurn, for example, water, a, g V "water-alcohol mixture, nonionic. surfactant compounds, 7'0 a
  • F minor amounts to inhibit soil redeposition.
  • a tarnish inhibitor such as benzotriazole or ethylenethiourea may also be added in amounts up to about 2%.
  • Fluorescers, perfume and color while not essential in the compositions of the invention may be added in amounts up to about 1%.
  • An alkaline material or alkali such as sodium hydroxide or potassium hydroxide can be added in minor amounts as supplementary pH adjusters. There might also be mentioned as suitable additives moisture, brightening agents, sodium sulfate, and sodium carbonate.
  • Corrosion inhibitors generally are also added.
  • Soluble silicates are highly effective inhibitors and can be added to certain formulas of this invention at levels of from about 3% to about 8%.
  • Alkali metal, preferably potassium or sodium, silicates having a weight ratio of SiO M O of from 1.0:1 to 28:1 will be used. M in this ratio refers to sodium and potassium.
  • a sodium silicate having a ratio of SiO :Na O of about 1.6:1 to 2.45:1 is especially pre ferred for economy and effectiveness.
  • a hydrotropic agent may at times be found desirable.
  • Suitable hydrotropes are water-soluble alkali metal salts of toluenesulfonate, benzenesulfomate, and xylenesulfonate.
  • the preferred hydrotropes are the potassium or sodium toluenesulfonatcs.
  • the hydrotrope salt may be added, if desired, at levels of to about 12%. While a hydrotrope will not ordinarily be found necessary, it can be added if so desired for any reason such as to produce a product which retains its homogeneity at a low temperature.
  • compositions will serve to illustrate this facet of the invention.
  • gent formulation according to this invention has the following composition, in which the percentages are by weight.
  • sodium dodecylbenzenesulfonate (dodecyl group derived from tetrapropylene) 2.0% potassium toluenesulfonate 47.0% trisodium ethane-l-hydroxy-l,l-diphosphonate 6.0% sodium silicate (ratio siO zNa O of 2:1)
  • a granular detergent composition was prepared having Condensation products of ethylene oxide with a hydrophobic oase formed by the condensation of propylene oxide avitlz propylene glycol and having molecular weights of approximately 3000 and 8000 respectively.
  • Washing performance characteristics of this composition are exceptionally good from the point of view of general cleaning and whiteness maintenance performance.
  • sodium dodecylbenzenesulfonate (dodecyl group derived from tetrapropylene) 2.0% potassium toluenesulfonate .5 trichlorocarbanilide (as a bacteriostat) 30.0% trisodium ethane-1-hydr0x -1,1-diphosphonate 6.0% sodium silicate (ratio SiO :Na O of 2:1)
  • An effective cool water built granular composition according to this invention has the following composition:
  • the test employed was conducted in the following manner. White dress shirts, cotton T-shirts and other fabrics were distributed among various individuals. Each dress shirt and T-shirt was worn for one normal working day under uniform conditions and the other articles were used for their generally intended purposes. The soiled clothes and fabrics were then washed in an automatic agitating type washer, for a period of ten minutes, with detergent solutions at F. temperature. The wash water was at a pH of 10 and had a hardness of 7 grains per gallon.
  • the detergent composition employed during the tests consisted of 20% sodium tallow alkyl sulfate asthe detergent active, (the alkyl chain length distribution of tallow alkyl sulfate was approximately 66% C 30% C and 4% others), 50% sodium tripolyphosphate or a molar equivalent of EHDP, 6% sodium silicate and 24% sodium sulfate. On a total basis of 100%, a molar equivalent of 50% sodium tripolyphosphate is 37.0% EI-IDP (as trisodium salt). In this instancewhen EHDP was employed,
  • FIGURE 1 The concentrations of FIGURE 1" are millimoles of EHDP or STP per liter of wash water. concentration of the builder detergent in solution was varied from about 033% to .050% of STPiand..024% to 037% of EHDP (as trisodiumsalt) to provide the molar concentration of builder in the wash water set of'the builder materials.
  • An improved cleansing and laundering composition consisting essentially of a water-soluble trisodium salt of ethane-l-hydroxy-l,l-diphosphonate as a builder and. an organic water-soluble non-soap synthetic detergent surfactant having pronounced detergent power selected from the group consisting of anionic, nonionic, zwitterionic, ampholyrtic detergent surfactants, and mixtures thereof, the ratio, by weight, of said disph'osphonate builder to said detergent surfactant being in the range of about 1:2 to about 10:1, said composition providing in aqueous solution a pH between about 9 and about 12.
  • the ratio of said diphosphonate builder to said detergent active being in the range of about 1:2 to about ;10:1, said composition providing in aqueous solution a pH between about 9.and about 12.
  • An improved cleansing and laundering composition consisting essentially of awater-soluble trisodium salt of ethane-l-hydroxy-1,1-diphosphonateas a builder and as a detergent active.
  • an anionic Water-solublealkali metal salt Yof an organic sulfuric reaction product having in its jmolccular structure an alkyl radical having 8 to '22 carbon atoms and'a radical selecte d from the group consisting of Itwill benoted from FIGURE 1 that this snperiority i of *the .EHDP formulation was l, consistently maintained sulfonicacid and sulfuric acid/ester radicals, the ratio of said diphosphonate builder to said detergentfactive being inthe range of 5 about.-1. 2 to about 10:1,. said.
  • composition providing in aqueous solution a pH between References Cited in the file of this patent abOutg UNITED STATES PATENTS 6.
  • anionic detergent active is selected from 2,491,920 Emsberger 1949 the group consisting of alkali metal alkyl sulfates in 5 which the alkyl substituent contains from about 8 to 18 FOREIGN PATENTS carbon atoms, alkali metal alkylbenzenesulfonates in 1,010,965 Germany May 8, 1956 which the alkyl group contains from about 9 to about 15 1,072,346 Germany Dec.
  • alkali metal alkylglycerylethersulfo- 1,082,235 Germany May 25, 1960 mates in which the alkyl is derived from the higher alcohols 10 1 107,207 Germany May 25, 19 1 obtained from tallow and coconut oil.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
US187327A 1962-04-13 1962-04-13 Detergency composition Expired - Lifetime US3159581A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
NL132418D NL132418C (hu) 1962-04-13
US187327A US3159581A (en) 1962-04-13 1962-04-13 Detergency composition
DK156563AA DK111829B (da) 1962-04-13 1963-04-04 Rense- og vaskemiddel.
GB14689/63A GB1035913A (en) 1962-04-13 1963-04-11 Detergent composition
FI0728/63A FI41762B (hu) 1962-04-13 1963-04-11
DE19631467648 DE1467648A1 (de) 1962-04-13 1963-04-11 Wasch- und Reinigungsmittel
FR931532A FR1439824A (fr) 1962-04-13 1963-04-12 Compositions détergentes à supports particulièrement efficaces
AU51843/64A AU294552B2 (en) 1962-04-13 1964-11-18 Detergent composition
NL6413483A NL6413483A (hu) 1962-04-13 1964-11-19
BE655988A BE655988A (hu) 1962-04-13 1964-11-19

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US187327A US3159581A (en) 1962-04-13 1962-04-13 Detergency composition

Publications (1)

Publication Number Publication Date
US3159581A true US3159581A (en) 1964-12-01

Family

ID=22688518

Family Applications (1)

Application Number Title Priority Date Filing Date
US187327A Expired - Lifetime US3159581A (en) 1962-04-13 1962-04-13 Detergency composition

Country Status (9)

Country Link
US (1) US3159581A (hu)
AU (1) AU294552B2 (hu)
BE (1) BE655988A (hu)
DE (1) DE1467648A1 (hu)
DK (1) DK111829B (hu)
FI (1) FI41762B (hu)
FR (1) FR1439824A (hu)
GB (1) GB1035913A (hu)
NL (2) NL6413483A (hu)

Cited By (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3297578A (en) * 1963-07-26 1967-01-10 Monsanto Co Bleaching, sterilizing, disinfecting, and deterging compositions
US3303896A (en) * 1965-08-17 1967-02-14 Procter & Gamble Process for drilling boreholes in the earth utilizing amine oxide surfactant foaming agent
US3312626A (en) * 1965-09-03 1967-04-04 Procter & Gamble Toilet bar
US3312627A (en) * 1965-09-03 1967-04-04 Procter & Gamble Toilet bar
US3313735A (en) * 1963-09-25 1967-04-11 Procter & Gamble Shampoo composition
US3318817A (en) * 1965-07-16 1967-05-09 Procter & Gamble Process for preparing detergent tablets
US3346504A (en) * 1962-08-10 1967-10-10 Procter & Gamble Detergent compositions
US3346873A (en) * 1962-08-10 1967-10-10 Procter & Gamble Liquid detergent composition containing solubilizing electrolytes
US3351558A (en) * 1966-09-06 1967-11-07 Procter & Gamble Detergent composition containing organic phosphonate corrosion inhibitors
US3351559A (en) * 1963-11-13 1967-11-07 Henkel & Cie Gmbh Pourable and free-flowing detergent, wetting, and emulsifying compositions
US3368978A (en) * 1964-12-28 1968-02-13 Monsanto Co Builder compositions and detergent compositions using same
US3392121A (en) * 1962-11-05 1968-07-09 Procter & Gamble Built detergent compositions
US3394083A (en) * 1963-08-15 1968-07-23 Monsanto Co Effervescent builder compositions and detergent compositions containing the same
US3400176A (en) * 1965-11-15 1968-09-03 Procter & Gamble Propanepolyphosphonate compounds
US3400148A (en) * 1965-09-23 1968-09-03 Procter & Gamble Phosphonate compounds
US3404178A (en) * 1963-03-18 1968-10-01 Procter & Gamble Substituted methylene diphosphonic acids and their salts
US3422137A (en) * 1965-12-28 1969-01-14 Procter & Gamble Methanehydroxydiphosphonic acids and salts useful in detergent compositions
US3424689A (en) * 1964-08-28 1969-01-28 Kao Corp Heavy-duty liquid detergent composition
US3453144A (en) * 1965-02-12 1969-07-01 Procter & Gamble Liquid cleaner composition
US3454500A (en) * 1966-02-08 1969-07-08 Procter & Gamble Soap compositions having improved curd-dispersing properties
US3471406A (en) * 1965-09-07 1969-10-07 Plains Chem Dev Co Detergent compositions containing methane tri and tetra phosphonic acid compounds
US3484480A (en) * 1968-02-23 1969-12-16 Procter & Gamble Process for separating ethane - 1 - hydroxy-1,1-diphosphonic acid from a solution of it in an organic solvent which also contains oxyacids of phosphorus
US3488419A (en) * 1965-12-08 1970-01-06 Procter & Gamble Oral compositions for calculus retardation
US3536628A (en) * 1965-12-22 1970-10-27 Frank Lancashire Soap compositions
US3539521A (en) * 1965-05-03 1970-11-10 Procter & Gamble Detergent composition
US3678154A (en) * 1968-07-01 1972-07-18 Procter & Gamble Oral compositions for calculus retardation
US3962100A (en) * 1975-08-18 1976-06-08 The Procter & Gamble Company Fabric softening agents
USRE29182E (en) * 1965-12-08 1977-04-12 The Procter & Gamble Company Oral composition for calculus retardation
US4020091A (en) * 1965-10-28 1977-04-26 Plains Chemical Development Co. Chelation
US4025444A (en) * 1975-08-18 1977-05-24 The Procter & Gamble Company Fabric softening agents
US4329244A (en) * 1979-06-21 1982-05-11 Interox (Societe Anonyme) Particles of stabilized peroxygenated compounds, process for their manufacture, and composition containing such particles
US4421669A (en) * 1979-12-12 1983-12-20 Interox (Societe Anonyme) Process for the stabilization of particles containing peroxygen compounds and bleaching compositions containing particles stabilized according to this process
EP0150532A1 (en) 1983-12-22 1985-08-07 The Procter & Gamble Company Peroxygen bleach activators and bleaching compositions
EP0679714A2 (en) 1994-04-28 1995-11-02 The Procter & Gamble Company Detergent compositions containing cellulase enzyme and selected perfumes for improved odor and stability
EP0693549A1 (en) 1994-07-19 1996-01-24 The Procter & Gamble Company Solid bleach activator compositions
WO1996025478A1 (en) 1995-02-15 1996-08-22 The Procter & Gamble Company Detergent composition comprising an amylase enzyme and a nonionic polysaccharide ether
EP0753557A1 (en) 1995-07-13 1997-01-15 The Procter & Gamble Company Packaged foaming composition
EP0753559A1 (en) 1995-07-13 1997-01-15 The Procter & Gamble Company Method of cleaning textile fabrics
EP0763594A1 (en) 1995-09-18 1997-03-19 The Procter & Gamble Company Process for making granular detergents
EP0771785A1 (en) 1995-11-02 1997-05-07 The Procter & Gamble Company Beta-amino ester compounds of perfume alcohols and their use in cleaning or laundry compositions
WO1997042282A1 (en) 1996-05-03 1997-11-13 The Procter & Gamble Company Detergent compositions comprising polyamine polymers with improved soil dispersancy
WO1998031778A1 (en) * 1997-01-21 1998-07-23 Henkel Corporation Process for chelating divalent metal ions in alkaline detergent formulations
US6617300B2 (en) 2000-08-30 2003-09-09 Procter & Gamble Company Granular bleach activators having improved solubility profiles
US20030203035A1 (en) * 2000-09-29 2003-10-30 The Procter & Gamble Company Allergen neutralization compositions
US20030206965A1 (en) * 2000-09-29 2003-11-06 The Procter & Gamble Company Allergen neutralization compositions
US20030216485A1 (en) * 2000-09-13 2003-11-20 The Procter & Gamble Co. Process for making a water-soluble foam component
US6660711B1 (en) 1999-07-16 2003-12-09 The Procter & Gamble Company Laundry detergent compositions comprising zwitterionic polyamines and mid-chain branched surfactants
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
US6858570B2 (en) 2001-03-03 2005-02-22 Clariant Gmbh Laundry detergents and laundry treatment compositions comprising one or more dye-transfer-inhibiting dye fixatives
US7091167B2 (en) 2001-03-03 2006-08-15 Clariant Gmbh Laundry detergents and laundry treatment compositions comprising dye-transfer-inhibiting dye fixatives
US20070191246A1 (en) * 2006-01-23 2007-08-16 Sivik Mark R Laundry care compositions with thiazolium dye
US20070277327A1 (en) * 2004-04-08 2007-12-06 Clariant Produkte (Deutschland) Gmbh Detergent And Cleaning Agents Containing Dye Fixatives And Soil Release Polymers
US20080139442A1 (en) * 2004-06-17 2008-06-12 Frank-Peter Lang Highly Concentrated, Aqueous Oligoester And Polyester Formulations
WO2008109384A2 (en) 2007-03-05 2008-09-12 Celanese Acetate Llc Method of making a bale of cellulose acetate tow
DE102007013217A1 (de) 2007-03-15 2008-09-18 Clariant International Ltd. Anionische Soil Release Polymere
DE102007028310A1 (de) 2007-06-20 2008-12-24 Clariant International Ltd. Tensidmischungen mit synergistischen Eigenschaften
US20090036641A1 (en) * 2005-12-21 2009-02-05 Frank-Peter Lang Anionic Soil Release Polymers
US20090053354A1 (en) * 2006-03-03 2009-02-26 Jaroslav Hajduch Venting valve to be used in venting bores of vulcanization molds
DE102008023803A1 (de) 2008-05-15 2009-11-26 Clariant International Ltd. Additive für Wasch- und Reinigungsmittel
US7638475B2 (en) 2006-03-24 2009-12-29 Georgia-Pacific Consumer Products Lp Space saving toilet cleaning system
US20100022434A1 (en) * 2001-02-28 2010-01-28 Chandrika Kasturi Liquid detergent composition exhibiting enhanced alpha-amylase enzyme stability
US20100105597A1 (en) * 2008-10-27 2010-04-29 Roy Jerome Harrington Methods for making a nil-phosphate liquid automatic dishwashing composition
US20100197545A1 (en) * 2009-01-30 2010-08-05 Ecolab USA High alkaline detergent composition with enhanced scale control
WO2011100411A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising polyglycerol esters
WO2011100500A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising polyglycerol esters
WO2011100420A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising crosslinked polyglycerol esters
WO2011100405A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising crosslinked polyglycerol esters
WO2012040130A1 (en) 2010-09-20 2012-03-29 The Procter & Gamble Company Non-fluoropolymer surface protection composition
WO2012040171A1 (en) 2010-09-20 2012-03-29 The Procter & Gamble Company Non-fluoropolymer surface protection composition
WO2012040131A2 (en) 2010-09-20 2012-03-29 The Procter & Gamble Company Fabric care formulations and methods
WO2013007367A1 (de) 2011-07-12 2013-01-17 Clariant International Ltd. Verwendung von sekundären paraffinsulfonaten zur erhöhung des reinigungsvermögens von enzymen
WO2013007366A1 (de) 2011-07-12 2013-01-17 Clariant International Ltd Verwendung einer kombination von sekundärem paraffinsulfonat und amylase zur erhöhung des reinigungsvermögens von flüssigen waschmitteln
DE102012015826A1 (de) 2012-08-09 2014-02-13 Clariant International Ltd. Flüssige tensidhaltige Alkanolamin-freie Zusammensetzungen
DE102013004428A1 (de) 2013-03-15 2014-09-18 Clariant International Ltd. Verfahren zum Waschen und Reinigen von Textilien
US8871703B2 (en) 2009-11-27 2014-10-28 Clariant Finance (Bvi) Limited Polyester concentrates having high stability in solution and having a greying-inhibiting effect
US8871702B2 (en) 2009-11-27 2014-10-28 Clariant Finance (Bvi) Limited Soil-release polymers having a grey-inhibiting effect and having high stability in solution
EP2857486A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857485A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising alkanolamine-free cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857487A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
US9796952B2 (en) 2012-09-25 2017-10-24 The Procter & Gamble Company Laundry care compositions with thiazolium dye
DE102016223585A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymere und deren verwendung in waschmittel-zusammensetzungen
DE102016223584A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymer enthaltende waschmittelzusammensetzungen
WO2020074944A1 (en) 2018-10-11 2020-04-16 Sanifit Therapeutics S.A. Inositol phosphates for the treatment of ectopic calcification
EP4015494A1 (en) 2020-12-15 2022-06-22 Sanifit Therapeutics S.A. Processes for the preparation of soluble salts of inositol phosphates
US11530373B2 (en) 2016-11-28 2022-12-20 Clariant International Ltd Cleaning agent compositions containing copolymer
CN116018394A (zh) * 2020-08-26 2023-04-25 联合利华知识产权控股有限公司 包含羟乙基磺酸盐表面活性剂的洗涤剂组合物
US11649310B2 (en) 2016-11-28 2023-05-16 Clariant International Ltd Copolymers and the use of same in cleaning agent compositions
US11692052B2 (en) 2016-11-28 2023-07-04 Clariant International Ltd Copolymers and use thereof in cleaning-agent compositions

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1424356A (en) * 1972-03-17 1976-02-11 Unilever Ltd Detergent composition
GB2283494A (en) * 1993-11-03 1995-05-10 Procter & Gamble Machine dishwashing

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2491920A (en) * 1946-05-16 1949-12-20 Du Pont Diesters of 1-ketophosphonic acids
DE1010965B (de) * 1956-05-08 1957-06-27 Henkel & Cie Gmbh Verfahren zur Herstellung von sauren Estern der Acylphosphonsaeuren bzw. ihrer Salze
DE1072346B (de) * 1959-02-06 1959-12-31 Henkel a Cie G m b H, Dusseldorf Verfahren zum Stabilisieren oberflächenaktiver Stoffe
DE1082235B (de) * 1958-09-06 1960-05-25 Henkel & Cie Gmbh Verwendung von organischen Acylierungsprodukten der phosphorigen Saeure oder ihrer Derivate als Komplexbildner fuer Metallionen
DE1107207B (de) * 1959-06-03 1961-05-25 Henkel & Cie Gmbh Stabilisierungsmittel fuer Peroxyverbindungen und deren Loesungen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2491920A (en) * 1946-05-16 1949-12-20 Du Pont Diesters of 1-ketophosphonic acids
DE1010965B (de) * 1956-05-08 1957-06-27 Henkel & Cie Gmbh Verfahren zur Herstellung von sauren Estern der Acylphosphonsaeuren bzw. ihrer Salze
DE1082235B (de) * 1958-09-06 1960-05-25 Henkel & Cie Gmbh Verwendung von organischen Acylierungsprodukten der phosphorigen Saeure oder ihrer Derivate als Komplexbildner fuer Metallionen
DE1072346B (de) * 1959-02-06 1959-12-31 Henkel a Cie G m b H, Dusseldorf Verfahren zum Stabilisieren oberflächenaktiver Stoffe
DE1107207B (de) * 1959-06-03 1961-05-25 Henkel & Cie Gmbh Stabilisierungsmittel fuer Peroxyverbindungen und deren Loesungen

Cited By (112)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3346504A (en) * 1962-08-10 1967-10-10 Procter & Gamble Detergent compositions
US3346873A (en) * 1962-08-10 1967-10-10 Procter & Gamble Liquid detergent composition containing solubilizing electrolytes
US3392121A (en) * 1962-11-05 1968-07-09 Procter & Gamble Built detergent compositions
US3404178A (en) * 1963-03-18 1968-10-01 Procter & Gamble Substituted methylene diphosphonic acids and their salts
US3297578A (en) * 1963-07-26 1967-01-10 Monsanto Co Bleaching, sterilizing, disinfecting, and deterging compositions
US3394083A (en) * 1963-08-15 1968-07-23 Monsanto Co Effervescent builder compositions and detergent compositions containing the same
US3313735A (en) * 1963-09-25 1967-04-11 Procter & Gamble Shampoo composition
US3351559A (en) * 1963-11-13 1967-11-07 Henkel & Cie Gmbh Pourable and free-flowing detergent, wetting, and emulsifying compositions
US3424689A (en) * 1964-08-28 1969-01-28 Kao Corp Heavy-duty liquid detergent composition
US3368978A (en) * 1964-12-28 1968-02-13 Monsanto Co Builder compositions and detergent compositions using same
US3453144A (en) * 1965-02-12 1969-07-01 Procter & Gamble Liquid cleaner composition
US3539521A (en) * 1965-05-03 1970-11-10 Procter & Gamble Detergent composition
US3318817A (en) * 1965-07-16 1967-05-09 Procter & Gamble Process for preparing detergent tablets
US3303896A (en) * 1965-08-17 1967-02-14 Procter & Gamble Process for drilling boreholes in the earth utilizing amine oxide surfactant foaming agent
US3312627A (en) * 1965-09-03 1967-04-04 Procter & Gamble Toilet bar
US3312626A (en) * 1965-09-03 1967-04-04 Procter & Gamble Toilet bar
US3471406A (en) * 1965-09-07 1969-10-07 Plains Chem Dev Co Detergent compositions containing methane tri and tetra phosphonic acid compounds
US3892676A (en) * 1965-09-07 1975-07-01 Plains Chemical Dev Co Detergent compositions containing methane diphosphonic acid compounds
US3451937A (en) * 1965-09-23 1969-06-24 Procter & Gamble Phosphonate compounds
US3400148A (en) * 1965-09-23 1968-09-03 Procter & Gamble Phosphonate compounds
US4020091A (en) * 1965-10-28 1977-04-26 Plains Chemical Development Co. Chelation
US3502585A (en) * 1965-11-15 1970-03-24 Procter & Gamble Detergent compositions containing propanepolyphosphonate compounds
US3400176A (en) * 1965-11-15 1968-09-03 Procter & Gamble Propanepolyphosphonate compounds
US3488419A (en) * 1965-12-08 1970-01-06 Procter & Gamble Oral compositions for calculus retardation
USRE29182E (en) * 1965-12-08 1977-04-12 The Procter & Gamble Company Oral composition for calculus retardation
US3536628A (en) * 1965-12-22 1970-10-27 Frank Lancashire Soap compositions
US3422137A (en) * 1965-12-28 1969-01-14 Procter & Gamble Methanehydroxydiphosphonic acids and salts useful in detergent compositions
US3454500A (en) * 1966-02-08 1969-07-08 Procter & Gamble Soap compositions having improved curd-dispersing properties
US3351558A (en) * 1966-09-06 1967-11-07 Procter & Gamble Detergent composition containing organic phosphonate corrosion inhibitors
US3484480A (en) * 1968-02-23 1969-12-16 Procter & Gamble Process for separating ethane - 1 - hydroxy-1,1-diphosphonic acid from a solution of it in an organic solvent which also contains oxyacids of phosphorus
US3678154A (en) * 1968-07-01 1972-07-18 Procter & Gamble Oral compositions for calculus retardation
US3962100A (en) * 1975-08-18 1976-06-08 The Procter & Gamble Company Fabric softening agents
US4025444A (en) * 1975-08-18 1977-05-24 The Procter & Gamble Company Fabric softening agents
US4329244A (en) * 1979-06-21 1982-05-11 Interox (Societe Anonyme) Particles of stabilized peroxygenated compounds, process for their manufacture, and composition containing such particles
US4421669A (en) * 1979-12-12 1983-12-20 Interox (Societe Anonyme) Process for the stabilization of particles containing peroxygen compounds and bleaching compositions containing particles stabilized according to this process
EP0150532A1 (en) 1983-12-22 1985-08-07 The Procter & Gamble Company Peroxygen bleach activators and bleaching compositions
EP0679714A2 (en) 1994-04-28 1995-11-02 The Procter & Gamble Company Detergent compositions containing cellulase enzyme and selected perfumes for improved odor and stability
EP0693549A1 (en) 1994-07-19 1996-01-24 The Procter & Gamble Company Solid bleach activator compositions
WO1996025478A1 (en) 1995-02-15 1996-08-22 The Procter & Gamble Company Detergent composition comprising an amylase enzyme and a nonionic polysaccharide ether
EP0753557A1 (en) 1995-07-13 1997-01-15 The Procter & Gamble Company Packaged foaming composition
EP0753559A1 (en) 1995-07-13 1997-01-15 The Procter & Gamble Company Method of cleaning textile fabrics
EP0763594A1 (en) 1995-09-18 1997-03-19 The Procter & Gamble Company Process for making granular detergents
EP0771785A1 (en) 1995-11-02 1997-05-07 The Procter & Gamble Company Beta-amino ester compounds of perfume alcohols and their use in cleaning or laundry compositions
WO1997042282A1 (en) 1996-05-03 1997-11-13 The Procter & Gamble Company Detergent compositions comprising polyamine polymers with improved soil dispersancy
US5929020A (en) * 1997-01-21 1999-07-27 Henkel Corporation Process for chelating divalent metal ions in alkaline detergent formulations
WO1998031778A1 (en) * 1997-01-21 1998-07-23 Henkel Corporation Process for chelating divalent metal ions in alkaline detergent formulations
US6660711B1 (en) 1999-07-16 2003-12-09 The Procter & Gamble Company Laundry detergent compositions comprising zwitterionic polyamines and mid-chain branched surfactants
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
US6617300B2 (en) 2000-08-30 2003-09-09 Procter & Gamble Company Granular bleach activators having improved solubility profiles
US6953587B2 (en) 2000-09-13 2005-10-11 Proacter & Gamble Company Process for making a water-soluble foam component
US20030216485A1 (en) * 2000-09-13 2003-11-20 The Procter & Gamble Co. Process for making a water-soluble foam component
US20030206965A1 (en) * 2000-09-29 2003-11-06 The Procter & Gamble Company Allergen neutralization compositions
US20030203035A1 (en) * 2000-09-29 2003-10-30 The Procter & Gamble Company Allergen neutralization compositions
US20110053824A1 (en) * 2001-02-28 2011-03-03 Chandrika Kasturi Liquid detergent composition exhibiting enhanced alpha-amylase enzyme stability
US20100022434A1 (en) * 2001-02-28 2010-01-28 Chandrika Kasturi Liquid detergent composition exhibiting enhanced alpha-amylase enzyme stability
US6858570B2 (en) 2001-03-03 2005-02-22 Clariant Gmbh Laundry detergents and laundry treatment compositions comprising one or more dye-transfer-inhibiting dye fixatives
US7091167B2 (en) 2001-03-03 2006-08-15 Clariant Gmbh Laundry detergents and laundry treatment compositions comprising dye-transfer-inhibiting dye fixatives
US20070277327A1 (en) * 2004-04-08 2007-12-06 Clariant Produkte (Deutschland) Gmbh Detergent And Cleaning Agents Containing Dye Fixatives And Soil Release Polymers
US20080139442A1 (en) * 2004-06-17 2008-06-12 Frank-Peter Lang Highly Concentrated, Aqueous Oligoester And Polyester Formulations
US7790665B2 (en) 2004-06-17 2010-09-07 Clariant Produkte (Deutschland) Gmbh Highly concentrated, aqueous oligoester and polyester formulations
US20090036641A1 (en) * 2005-12-21 2009-02-05 Frank-Peter Lang Anionic Soil Release Polymers
US8299010B2 (en) 2006-01-23 2012-10-30 The Procter & Gamble Company Laundry care compositions with thiazolium dye
US20070191246A1 (en) * 2006-01-23 2007-08-16 Sivik Mark R Laundry care compositions with thiazolium dye
US20100325814A1 (en) * 2006-01-23 2010-12-30 Mark Robert Sivik Laundry care compositions with thiazolium dye
US20090053354A1 (en) * 2006-03-03 2009-02-26 Jaroslav Hajduch Venting valve to be used in venting bores of vulcanization molds
US7638475B2 (en) 2006-03-24 2009-12-29 Georgia-Pacific Consumer Products Lp Space saving toilet cleaning system
WO2008109384A2 (en) 2007-03-05 2008-09-12 Celanese Acetate Llc Method of making a bale of cellulose acetate tow
DE102007013217A1 (de) 2007-03-15 2008-09-18 Clariant International Ltd. Anionische Soil Release Polymere
DE102007028310A1 (de) 2007-06-20 2008-12-24 Clariant International Ltd. Tensidmischungen mit synergistischen Eigenschaften
DE102008023803A1 (de) 2008-05-15 2009-11-26 Clariant International Ltd. Additive für Wasch- und Reinigungsmittel
US7790664B2 (en) 2008-10-27 2010-09-07 The Procter & Gamble Company Methods for making a nil-phosphate liquid automatic dishwashing composition
US20100105597A1 (en) * 2008-10-27 2010-04-29 Roy Jerome Harrington Methods for making a nil-phosphate liquid automatic dishwashing composition
US20100197545A1 (en) * 2009-01-30 2010-08-05 Ecolab USA High alkaline detergent composition with enhanced scale control
US20110071065A1 (en) * 2009-01-30 2011-03-24 Ecolab USA High alkaline detergent composition with enhanced scale control
US8481473B2 (en) 2009-01-30 2013-07-09 Ecolab Usa Inc. High alkaline detergent composition with enhanced scale control
US8809249B2 (en) 2009-01-30 2014-08-19 Ecolab Usa Inc. High alkaline detergent composition with enhanced scale control
US8871703B2 (en) 2009-11-27 2014-10-28 Clariant Finance (Bvi) Limited Polyester concentrates having high stability in solution and having a greying-inhibiting effect
US8871702B2 (en) 2009-11-27 2014-10-28 Clariant Finance (Bvi) Limited Soil-release polymers having a grey-inhibiting effect and having high stability in solution
WO2011100405A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising crosslinked polyglycerol esters
WO2011100420A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising crosslinked polyglycerol esters
WO2011100500A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising polyglycerol esters
WO2011100411A1 (en) 2010-02-12 2011-08-18 The Procter & Gamble Company Benefit compositions comprising polyglycerol esters
US8637442B2 (en) 2010-09-20 2014-01-28 The Procter & Gamble Company Non-fluoropolymer surface protection composition comprising a polyorganosiloxane-silicone resin mixture
US8633146B2 (en) 2010-09-20 2014-01-21 The Procter & Gamble Company Non-fluoropolymer surface protection composition comprising a polyorganosiloxane-silicone resin mixture
WO2012040131A2 (en) 2010-09-20 2012-03-29 The Procter & Gamble Company Fabric care formulations and methods
WO2012040171A1 (en) 2010-09-20 2012-03-29 The Procter & Gamble Company Non-fluoropolymer surface protection composition
WO2012040130A1 (en) 2010-09-20 2012-03-29 The Procter & Gamble Company Non-fluoropolymer surface protection composition
WO2013007367A1 (de) 2011-07-12 2013-01-17 Clariant International Ltd. Verwendung von sekundären paraffinsulfonaten zur erhöhung des reinigungsvermögens von enzymen
WO2013007366A1 (de) 2011-07-12 2013-01-17 Clariant International Ltd Verwendung einer kombination von sekundärem paraffinsulfonat und amylase zur erhöhung des reinigungsvermögens von flüssigen waschmitteln
US9777249B2 (en) 2012-08-09 2017-10-03 Weylchem Switzerland Ag Liquid surfactant-containing alkanolamine-free compositions
DE102012015826A1 (de) 2012-08-09 2014-02-13 Clariant International Ltd. Flüssige tensidhaltige Alkanolamin-freie Zusammensetzungen
WO2014023427A1 (de) 2012-08-09 2014-02-13 Clariant International Ltd Flüssige tensidhaltige alkanolamin-freie zusammensetzungen
US9796952B2 (en) 2012-09-25 2017-10-24 The Procter & Gamble Company Laundry care compositions with thiazolium dye
DE102013004428A1 (de) 2013-03-15 2014-09-18 Clariant International Ltd. Verfahren zum Waschen und Reinigen von Textilien
EP2857485A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising alkanolamine-free cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857487A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
WO2015051901A1 (en) 2013-10-07 2015-04-16 Weylchem Wiesbaden Gmbh Multi-compartment pouch comprising alkanolamine-free cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
EP2857486A1 (en) 2013-10-07 2015-04-08 WeylChem Switzerland AG Multi-compartment pouch comprising cleaning compositions, washing process and use for washing and cleaning of textiles and dishes
WO2018095916A1 (de) 2016-11-28 2018-05-31 Clariant International Ltd Copolymere und deren verwendung in waschmittel-zusammensetzungen
US11530373B2 (en) 2016-11-28 2022-12-20 Clariant International Ltd Cleaning agent compositions containing copolymer
WO2018095923A1 (de) 2016-11-28 2018-05-31 Clariant International Ltd Copolymer enthaltende waschmittelzusammensetzungen
DE102016223585A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymere und deren verwendung in waschmittel-zusammensetzungen
DE102016223584A1 (de) 2016-11-28 2018-05-30 Clariant International Ltd Copolymer enthaltende waschmittelzusammensetzungen
US11692052B2 (en) 2016-11-28 2023-07-04 Clariant International Ltd Copolymers and use thereof in cleaning-agent compositions
US11649310B2 (en) 2016-11-28 2023-05-16 Clariant International Ltd Copolymers and the use of same in cleaning agent compositions
WO2020074944A1 (en) 2018-10-11 2020-04-16 Sanifit Therapeutics S.A. Inositol phosphates for the treatment of ectopic calcification
US10973838B2 (en) 2018-10-11 2021-04-13 Sanifit Therapeutics S.A. IP and IP analogs dosage regimens for the treatment of ectopic calcifications
US12070469B2 (en) 2018-10-11 2024-08-27 Sanifit Therapeutics S.A. IP and IP analogs dosage regimens for the treatment of ectopic calcifications
CN116018394A (zh) * 2020-08-26 2023-04-25 联合利华知识产权控股有限公司 包含羟乙基磺酸盐表面活性剂的洗涤剂组合物
WO2022129148A1 (en) 2020-12-15 2022-06-23 Sanifit Therapeutics, S.A. Processes for the preparation of soluble salts of inositol phosphates
EP4015494A1 (en) 2020-12-15 2022-06-22 Sanifit Therapeutics S.A. Processes for the preparation of soluble salts of inositol phosphates
US12049476B2 (en) 2020-12-15 2024-07-30 Sanifit Therapeutics, S.A. Processes for the preparation of soluble salts of inositol phosphates

Also Published As

Publication number Publication date
DK156563A (hu)
BE655988A (hu) 1965-05-19
NL6413483A (hu) 1966-05-20
DK111829B (da) 1968-10-14
AU5184364A (en) 1966-05-19
FI41762B (hu) 1969-10-31
AU294552B2 (en) 1969-09-29
NL132418C (hu)
FR1439824A (fr) 1966-05-27
GB1035913A (en) 1966-07-13
DE1467648A1 (de) 1969-10-16

Similar Documents

Publication Publication Date Title
US3159581A (en) Detergency composition
US3213030A (en) Cleansing and laundering compositions
US3553139A (en) Enzyme containing detergent composition and a process for conglutination of enzymes and detergent composition
US3843563A (en) Detergent compositions
US3694364A (en) Laundering aid
US3523088A (en) Novel antiredeposition agent and built detergent compositions containing said antiredeposition agent
US3726797A (en) Detergent compositions and processes incorporating n-(2-hydroxy hydrocarbyl)iminodicarboxylates
US3812041A (en) Non-gelling heavy duty liquid laundry detergent
US3762859A (en) Enhancing the apparent whiteness of fabrics by applying an effective amount of an alkali and heat stable water soluble disazo blue dyestuff fabric softening and detergent composition therefor
US3953380A (en) Liquid detergent
US4304680A (en) Laundry soap
US3619115A (en) Cool water laundering process
US3539521A (en) Detergent composition
US3341459A (en) Detergent compositions
US3697453A (en) Iminodisuccinic acid salts as detergent builders
US3957661A (en) Fabric softening laundry detergent containing organic esters of phosphoric acid
US3876563A (en) Liquid detergent compositions
US4013577A (en) Heavy duty dry biodegradable detergent composition
US3336233A (en) Built detergent compositions containing 3-hydroxyalkyl alkyl sulfoxides
US3959165A (en) Biodegradable, non-polluting, heavy duty synthetic organic detergent composition
US3776851A (en) Detergents containing tetrahydroxysuccinic acid and salts thereof
US3536628A (en) Soap compositions
US3819538A (en) Environmentally compatible laundry detergent
US3686124A (en) Carboxymethylated derivatives of diand tri-saccharide compounds and detergent compositions containing them
US3609090A (en) Built detergent compositions containing hydroxy ether sulfonates