US2941949A - Acid baths for cleaning and pickling metal - Google Patents

Acid baths for cleaning and pickling metal Download PDF

Info

Publication number
US2941949A
US2941949A US658961A US65896157A US2941949A US 2941949 A US2941949 A US 2941949A US 658961 A US658961 A US 658961A US 65896157 A US65896157 A US 65896157A US 2941949 A US2941949 A US 2941949A
Authority
US
United States
Prior art keywords
cleaning
bath
acid
pickling
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US658961A
Other languages
English (en)
Inventor
Albert J Saukaltis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Amchem Products Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1194245D priority Critical patent/FR1194245A/fr
Priority to NL227726D priority patent/NL227726A/xx
Priority to NL97745D priority patent/NL97745C/xx
Priority to BE566739D priority patent/BE566739A/xx
Application filed by Amchem Products Inc filed Critical Amchem Products Inc
Priority to US658961A priority patent/US2941949A/en
Priority to GB5901/58A priority patent/GB817790A/en
Priority to DEA29059A priority patent/DE1095623B/de
Application granted granted Critical
Publication of US2941949A publication Critical patent/US2941949A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/065—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/80—Forming a predetermined ratio of the substances to be mixed
    • B01F35/83—Forming a predetermined ratio of the substances to be mixed by controlling the ratio of two or more flows, e.g. using flow sensing or flow controlling devices
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C19/00—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving
    • E01C19/02—Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving for preparing the materials
    • E01C19/10—Apparatus or plants for premixing or precoating aggregate or fillers with non-hydraulic binders, e.g. with bitumen, with resins, i.e. producing mixtures or coating aggregates otherwise than by penetrating or surface dressing; Apparatus for premixing non-hydraulic mixtures prior to placing or for reconditioning salvaged non-hydraulic compositions
    • E01C19/1059—Controlling the operations; Devices solely for supplying or proportioning the ingredients
    • E01C19/1068—Supplying or proportioning the ingredients

Definitions

  • the cleaning and pickling acids with which my invention is especially useful are those non-oxidizing mineral acids from the class which consists of sulphuric, phosphoric, hydrochloric, r ilfamic, hydroll ub'fic and fluosll sisa
  • My invention resides in the discovery that the addition of a small amount of triphenyl sulfonium chloride to an slsanias 9 1PiFEQPQQhlE QEPfgl iglfi describsd substantialj prevents or retards the attack of the acid on the Basis metalwithoutinterfefing with theremovahof scale or x15513651 the surface? carrying out my invention the baths are normally used at conventional concentrations of acid and at customary temperatures. These factors, therefore, are familiar to the art and can be varied as desired within the practices which are customary in this field.
  • triphenyl sulfonium chloride which I incorporate in such baths can vary but should, of course, be suflicieut to substantially reduce the rate of acid attack on the basis metal while still accomplishing the "desired 'cleaning and pickling.
  • triphenyl sulfonium chloride is required and my experience indicates that this need be np greater than approximately 1% by weight of the bath, although this limit may be exceeded to a reasonable extent without, apparently, in any way impairing the desired results.
  • a useful amount for any particular acid or type of work can easily be determined by simple test within the knowledge of those skilled in this art.
  • Still another example involved steel panels certain of which were immersed in a 75% phosphoric acid pickling solution containing 1% triphenyl sulfonium chloride. The bath was employed at 45 C., and the panels lost only 1.17 grams per square foot after 24 hours immersion, whereas, similar panels pickled in a similar but uninhibited phosphoric acid solution lost 209 grams per square foot after only 17.5 hours of immersion.
  • cleaning and pickling of metals according to my invention can be carried out with any of the procedures familiar in this art as by continuously passing the metal to be pickled (such as wire or sheets) through a nhmber of baths in a regulated manner or by immersing the articles in the bath for a suitable period of time.
  • the temperature may be varied as indicated above, but ordinarily the baths of my invention are used at temperatures of from to F.
  • a mineral acid bath for cleaning and pickling metal surfaces said bath containing, as an inhibiting addition agent, an amount of triphenyl sulfonium chloride which is sufficient to reduce the rate of acid attack on metal.
  • An acid bath for cleaning and pickling metal surfaces comprising acid from the class consisting of sulphuric, phosphoric, hydrochloric, sulfamic, hydrofluoric and fluosilicic acids and including triphenyl sulfonium chloride in an amount sufiicient to reduce the rate of attack of the acid on the metal.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
US658961A 1957-05-14 1957-05-14 Acid baths for cleaning and pickling metal Expired - Lifetime US2941949A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1194245D FR1194245A (en, 2012) 1957-05-14
NL227726D NL227726A (en, 2012) 1957-05-14
NL97745D NL97745C (en, 2012) 1957-05-14
BE566739D BE566739A (en, 2012) 1957-05-14
US658961A US2941949A (en) 1957-05-14 1957-05-14 Acid baths for cleaning and pickling metal
GB5901/58A GB817790A (en) 1957-05-14 1958-02-24 Improvements in or relating to acid baths for cleaning and pickling metal
DEA29059A DE1095623B (de) 1957-05-14 1958-03-15 Einen Inhibitor enthaltendes Saeurebad zum Reinigen und Beizen von Metalloberflaechen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US658961A US2941949A (en) 1957-05-14 1957-05-14 Acid baths for cleaning and pickling metal

Publications (1)

Publication Number Publication Date
US2941949A true US2941949A (en) 1960-06-21

Family

ID=24643464

Family Applications (1)

Application Number Title Priority Date Filing Date
US658961A Expired - Lifetime US2941949A (en) 1957-05-14 1957-05-14 Acid baths for cleaning and pickling metal

Country Status (6)

Country Link
US (1) US2941949A (en, 2012)
BE (1) BE566739A (en, 2012)
DE (1) DE1095623B (en, 2012)
FR (1) FR1194245A (en, 2012)
GB (1) GB817790A (en, 2012)
NL (2) NL97745C (en, 2012)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3083180A (en) * 1960-06-10 1963-03-26 Monsanto Chemicals Oxygen-containing heterocyclemethyl dihydroquinolinyl ethers
US3274114A (en) * 1965-11-04 1966-09-20 Grof Tibor Thomas Process for detarnishing and inhibiting copper and copper alloys
US3668137A (en) * 1969-04-01 1972-06-06 Amchem Prod Composition and method for inhibiting acid attack of metals
US3718594A (en) * 1970-11-30 1973-02-27 Eastman Kodak Co Method of preparing magnetically responsive carrier particles
US3764543A (en) * 1971-02-23 1973-10-09 Dow Chemical Co Sulfonium compound as a corrosion inhibitor in aqueous acid
US3819527A (en) * 1972-11-06 1974-06-25 Amchem Prod Composition and method for inhibiting acid attack of metals
US4053329A (en) * 1976-04-02 1977-10-11 Ppg Industries, Inc. Method of improving corrosion resistance of metal substrates by passivating with an onium salt-containing material
US4180469A (en) * 1977-12-30 1979-12-25 Amchem Products, Inc. Dithiocarbamate sulfonium salt inhibitor composition
DE3742367A1 (de) * 1987-12-14 1989-06-22 Pelox Chemietechnik Gmbh Co Kg Beiz- und reinigungsmittel fuer metalloberflaechen
US5492629A (en) * 1993-10-12 1996-02-20 H.E.R.C. Products Incorporated Method of cleaning scale and stains in water systems and related equipment
US5873944A (en) * 1997-05-13 1999-02-23 H.E.R.C. Products Incorporated Vacuum waste pipe cleaning
US5895763A (en) * 1997-04-16 1999-04-20 H.E.R.C. Products Incorporated Controlled carbonate removal from water conduit systems
US20050095871A1 (en) * 2003-10-31 2005-05-05 Chang Cathleen H. Process of maintaining hybrid etch
US20050194025A1 (en) * 2001-12-26 2005-09-08 H.E.R.C. Products Incorporated Countermeasure washdown system cleaning
US10301553B2 (en) 2017-02-28 2019-05-28 Ecolab Usa Inc. Use of sulfonium salts as hydrogen sulfide inhibitors
US10900128B2 (en) 2018-08-29 2021-01-26 Championx Usa Inc. Use of sulfonium salts as corrosion inhibitors

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3277008A (en) * 1962-04-20 1966-10-04 Pfaudler Permutit Inc Surface cleaning method and composition
GB1444171A (en) * 1973-04-11 1976-07-28 Dow Chemical Co Sulphonium salt corrosion inhibitors for aqueous acidic metal cleaning solutions rev
FR2467547A1 (fr) * 1979-10-22 1981-04-30 Elf Aquitaine Pesticide perfectionne, inhibiteurs de corrosion a base de sulfonium
NL9002321A (nl) * 1990-10-24 1992-05-18 Grint & Zandexpl Mij Vh Smals Werkwijze en inrichting voor het doseren, mengen en aanbrengen van een bijzondere specie.
US5522459A (en) * 1993-06-03 1996-06-04 Halliburton Company Continuous multi-component slurrying process at oil or gas well
US5452954A (en) * 1993-06-04 1995-09-26 Halliburton Company Control method for a multi-component slurrying process

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1852194A (en) * 1929-04-19 1932-04-05 Goodrich Co B F Method of cleaning and pickling metals
US1877504A (en) * 1932-06-30 1932-09-13 Dow Chemical Co Treatment of deep wells
US2006216A (en) * 1932-02-26 1935-06-25 Ici Ltd Inhibitor
US2148006A (en) * 1938-10-21 1939-02-21 Standard Oil Co Acidizing wells
US2149894A (en) * 1934-12-11 1939-03-07 Standard Oil Dev Co Carbon remover
US2178353A (en) * 1937-07-21 1939-10-31 Du Pont High molecular weight tetravalent sulphur compounds and process for their production
US2220451A (en) * 1938-02-09 1940-11-05 Du Pont Composition
US2531812A (en) * 1948-01-16 1950-11-28 Ernst A Hauser Application of drilling fluids
US2531440A (en) * 1947-03-29 1950-11-28 Nat Lead Co Lubricants
US2681314A (en) * 1951-12-21 1954-06-15 Shell Dev Process for an inorganic colloid thickened grease
US2698781A (en) * 1953-04-27 1955-01-04 Enthone Accelerating action of acids on metals
US2702279A (en) * 1955-02-15 Detergent compositions having
US2713033A (en) * 1952-09-15 1955-07-12 Dow Chemical Co Acidizing oil-bearing formations
US2759975A (en) * 1952-05-28 1956-08-21 Gen Aniline & Film Corp Mixed alkyl-benzyl-alkylol quaternary ammonium salts
US2800747A (en) * 1955-06-15 1957-07-30 Stauffer Chemical Co Soil conditioning
US2814593A (en) * 1953-12-18 1957-11-26 Gen Aniline & Film Corp Corrosion inhibition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE699060C (de) * 1939-06-24 1940-11-21 Henkel & Cie Gmbh Verfahren zur Entfernung von Milchstein

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2702279A (en) * 1955-02-15 Detergent compositions having
US1852194A (en) * 1929-04-19 1932-04-05 Goodrich Co B F Method of cleaning and pickling metals
US2006216A (en) * 1932-02-26 1935-06-25 Ici Ltd Inhibitor
US1877504A (en) * 1932-06-30 1932-09-13 Dow Chemical Co Treatment of deep wells
US2149894A (en) * 1934-12-11 1939-03-07 Standard Oil Dev Co Carbon remover
US2178353A (en) * 1937-07-21 1939-10-31 Du Pont High molecular weight tetravalent sulphur compounds and process for their production
US2220451A (en) * 1938-02-09 1940-11-05 Du Pont Composition
US2148006A (en) * 1938-10-21 1939-02-21 Standard Oil Co Acidizing wells
US2531440A (en) * 1947-03-29 1950-11-28 Nat Lead Co Lubricants
US2531812A (en) * 1948-01-16 1950-11-28 Ernst A Hauser Application of drilling fluids
US2681314A (en) * 1951-12-21 1954-06-15 Shell Dev Process for an inorganic colloid thickened grease
US2759975A (en) * 1952-05-28 1956-08-21 Gen Aniline & Film Corp Mixed alkyl-benzyl-alkylol quaternary ammonium salts
US2713033A (en) * 1952-09-15 1955-07-12 Dow Chemical Co Acidizing oil-bearing formations
US2698781A (en) * 1953-04-27 1955-01-04 Enthone Accelerating action of acids on metals
US2814593A (en) * 1953-12-18 1957-11-26 Gen Aniline & Film Corp Corrosion inhibition
US2800747A (en) * 1955-06-15 1957-07-30 Stauffer Chemical Co Soil conditioning

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3083180A (en) * 1960-06-10 1963-03-26 Monsanto Chemicals Oxygen-containing heterocyclemethyl dihydroquinolinyl ethers
US3274114A (en) * 1965-11-04 1966-09-20 Grof Tibor Thomas Process for detarnishing and inhibiting copper and copper alloys
US3668137A (en) * 1969-04-01 1972-06-06 Amchem Prod Composition and method for inhibiting acid attack of metals
US3718594A (en) * 1970-11-30 1973-02-27 Eastman Kodak Co Method of preparing magnetically responsive carrier particles
US3764543A (en) * 1971-02-23 1973-10-09 Dow Chemical Co Sulfonium compound as a corrosion inhibitor in aqueous acid
US3819527A (en) * 1972-11-06 1974-06-25 Amchem Prod Composition and method for inhibiting acid attack of metals
US4053329A (en) * 1976-04-02 1977-10-11 Ppg Industries, Inc. Method of improving corrosion resistance of metal substrates by passivating with an onium salt-containing material
US4180469A (en) * 1977-12-30 1979-12-25 Amchem Products, Inc. Dithiocarbamate sulfonium salt inhibitor composition
DE3742367A1 (de) * 1987-12-14 1989-06-22 Pelox Chemietechnik Gmbh Co Kg Beiz- und reinigungsmittel fuer metalloberflaechen
US5492629A (en) * 1993-10-12 1996-02-20 H.E.R.C. Products Incorporated Method of cleaning scale and stains in water systems and related equipment
US5895763A (en) * 1997-04-16 1999-04-20 H.E.R.C. Products Incorporated Controlled carbonate removal from water conduit systems
US5873944A (en) * 1997-05-13 1999-02-23 H.E.R.C. Products Incorporated Vacuum waste pipe cleaning
US20050194025A1 (en) * 2001-12-26 2005-09-08 H.E.R.C. Products Incorporated Countermeasure washdown system cleaning
US20050095871A1 (en) * 2003-10-31 2005-05-05 Chang Cathleen H. Process of maintaining hybrid etch
US7138342B2 (en) * 2003-10-31 2006-11-21 The Boeing Company Process of maintaining hybrid etch
US10301553B2 (en) 2017-02-28 2019-05-28 Ecolab Usa Inc. Use of sulfonium salts as hydrogen sulfide inhibitors
US10900128B2 (en) 2018-08-29 2021-01-26 Championx Usa Inc. Use of sulfonium salts as corrosion inhibitors

Also Published As

Publication number Publication date
BE566739A (en, 2012)
GB817790A (en) 1959-08-06
NL97745C (en, 2012)
NL227726A (en, 2012)
DE1095623B (de) 1960-12-22
FR1194245A (en, 2012) 1959-11-06

Similar Documents

Publication Publication Date Title
US2941949A (en) Acid baths for cleaning and pickling metal
US2485529A (en) Composition for removing scale from ferrous metal surfaces
US2564549A (en) Pickling treatment
US2380284A (en) Method of cleaning ferrous metal articles
US2965577A (en) Corrosion inhibitor composition and method of using same
US1719168A (en) Pickling of metals, etc.
US2450861A (en) Composition for descaling ferrous metal
US3335090A (en) Corrosion inhibition with propargyl benzylamine
US3655582A (en) Synergistic combination of silicates and barium salts for inhibiting the attack of alkaline solutions on aluminum containing materials
US3672821A (en) Inhibitor for aluminum in alkaline solutions
US2511988A (en) Pickling process
US4229409A (en) Method of inhibiting corrosion of aluminum with 2-phosphono-butane-1,2,4-tricarboxylic acid
US2499283A (en) Inhibited hydrochloric acid
US3819527A (en) Composition and method for inhibiting acid attack of metals
US2481977A (en) Metal protective coating method
US3282850A (en) Corrosion inhibition with dipropargyl butylamine
US2617771A (en) Corrosion retarder
US3428566A (en) Process of corrosion inhibition with 1-hexyn-3-ol
US3094489A (en) Method and composition for brightening aluminum
US3337470A (en) Corrosion inhibition with propargyl cyclohexylamine
US3197340A (en) Composition and method for cleaning aluminum castings
US3619125A (en) Method of inhibiting acidic corrosion with cyclohexylthioureas
US3249548A (en) Corrosion inhibiting composition comprising 4-ethyl-1-octyn-3-ol
US2593057A (en) Inhibitors against hydrogen sulfide and brine corrosion
US2485528A (en) Composition for descaling ferrous metal surfaces