US2909404A - Protection of polyamide fibers during treatment with peroxide containing bleaching or washing agents - Google Patents
Protection of polyamide fibers during treatment with peroxide containing bleaching or washing agents Download PDFInfo
- Publication number
- US2909404A US2909404A US419911A US41991154A US2909404A US 2909404 A US2909404 A US 2909404A US 419911 A US419911 A US 419911A US 41991154 A US41991154 A US 41991154A US 2909404 A US2909404 A US 2909404A
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- US
- United States
- Prior art keywords
- per liter
- bleaching
- washing
- peroxide
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000004952 Polyamide Substances 0.000 title claims description 26
- 229920002647 polyamide Polymers 0.000 title claims description 26
- 150000002978 peroxides Chemical class 0.000 title claims description 20
- 238000005406 washing Methods 0.000 title description 33
- 238000004061 bleaching Methods 0.000 title description 30
- 239000000835 fiber Substances 0.000 title description 22
- 239000003795 chemical substances by application Substances 0.000 title description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
- 239000001301 oxygen Substances 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 150000002894 organic compounds Chemical class 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- -1 AMINO GROUP Chemical class 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000003223 protective agent Substances 0.000 description 13
- 239000004744 fabric Substances 0.000 description 12
- 229920002955 Art silk Polymers 0.000 description 11
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- 235000019353 potassium silicate Nutrition 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 6
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 6
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 5
- 235000019341 magnesium sulphate Nutrition 0.000 description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical class 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229960001922 sodium perborate Drugs 0.000 description 4
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 4
- 125000001302 tertiary amino group Chemical group 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
- 229940048086 sodium pyrophosphate Drugs 0.000 description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- LDZYRENCLPUXAX-UHFFFAOYSA-N 2-methyl-1h-benzimidazole Chemical compound C1=CC=C2NC(C)=NC2=C1 LDZYRENCLPUXAX-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229960002366 magnesium silicate Drugs 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229960001124 trientine Drugs 0.000 description 2
- PVRZMTHMPKVOBP-UHFFFAOYSA-N 1-n,4-n-dimethylbenzene-1,4-diamine Chemical compound CNC1=CC=C(NC)C=C1 PVRZMTHMPKVOBP-UHFFFAOYSA-N 0.000 description 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BZORFPDSXLZWJF-UHFFFAOYSA-N N,N-dimethyl-1,4-phenylenediamine Chemical compound CN(C)C1=CC=C(N)C=C1 BZORFPDSXLZWJF-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OCIDXARMXNJACB-UHFFFAOYSA-N n'-phenylethane-1,2-diamine Chemical compound NCCNC1=CC=CC=C1 OCIDXARMXNJACB-UHFFFAOYSA-N 0.000 description 1
- RLRHPCKWSXWKBG-UHFFFAOYSA-N n-(2-azaniumylethyl)carbamate Chemical compound NCCNC(O)=O RLRHPCKWSXWKBG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000004987 o-phenylenediamines Chemical class 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/42—Per-compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/376—Oximes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/02—Washing ; Displacing cooking or pulp-treating liquors contained in the pulp by fluids, e.g. wash water or other pulp-treating agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/06—Resin bleach
Definitions
- the present invention relates to an improved process for treating polyamide fibers, such as, nylon or Perlon fibers with peroxide containing bleaching or washing agents wherein attack on such fibers is minimized.
- polyamide fibers are strongly attacked during treatment in bleaching or washing baths containing peroxide with the result of a considerable loss of strength of s h fibers.
- the loss in tensile strength polyamide fibers sold under the trade name Perlon can amount to 40% to 80% of their original tensile strength, when such fibers are subjected to the action of peroxide containing bleaching or washing baths at high temperatures for any substantial length of time as may occur in order to obtain satisfactory bleaching effects in polyamide fiber containing mixed fabrics or when polyamide fiber containing products are washed from time to time after having become soiled.
- the washing or bleaching baths have been stabilized with magnesium silicate, phosphates or other materials which retard the spontaneous evolution of oxygen, the same damage to polyamide fibers occurs during their use.
- the protective agents employed according to the invention are organic nitrogen compounds or their salts which contain at least two nitrogen atoms of which at least one is in the form of a primary or secondary amino group and the second of which can be of the same nature, or also be a tertiary amino group or a sulfonamide group.
- the nitrogen containing groups should be connected through a preponderantly saturated hydrocarbon chain which contains no more than 6 carbon atoms, such hydro carbon chain can also be interrupted by hetero-atoms or they can be connected through a chain forming part of a ring structure, which is of saturated or aromatic nature.
- Suitable protective substances according to the invention are for example as follows:
- the protective agents according to the invention have been found considerably more active than protective agents previously suggested and, consequently, are effective at considerably lower concentrations both in bleaching baths as well as washing.
- the protective agents according to the invention give good protection action at concentrations between 0.01 mol and 0.05 mol per liter even strongly aggressive alkaline bleaching baths.
- the quantity of protective agent employed, according to the invention, to provide good protective action can be reduced to about 0.001 to 0.005 mol per liter.
- the protective agents according to the invention are added to peroxide bleaching baths containing the normal ingredients, such as soluble silicates, magnesium sili cate or other peroxide stabilizers, alkalies, normal or anhydrous phosphates, soaps or washing agents, surface active agents, wetting agents and the like, a very good protective action upon the polyamide fibers treated in such baths, as when such protective agents are added, the normally expected 40 to loss in strength by the polyamide fibers is reduced to only about 2 to 8%
- a further advantage of the protective agents employed in accordance with the invention is that in most instances they support the bleaching power of peroxide bleaching or washing baths and undesired discolorations of the fibers are avoided.
- Example 1 A yarn of 60 denier Perlon L filaments was treated with movement for two hours at 60 C. in a bath of the following composition:
- the tearing strength of the Perlon L polyamide yarn was originally 40.2 kilometers (that is, it would sup- .port a weight equivalent to a length of such yarn 40.2 kilometers long before rupture). After the five hours treatment in the bleaching bath, its strength had only decreased to 37 kilometers or in other words, had only suffered a loss in strength of 8% of the original strength.
- Example 2 A polyamide artificial silk fabric produced from 60 denier filaments was bleached in a reel vat at 60 C. for three hours in an aqueous bleaching bath of the following composition:
- the three hours bleaching treatment only lowered the tearing strength of the polyamide artificial silk from 43.1 kilometers to 42 kilometers and consequently caused only a 2.5% loss in strength.
- Example 3 Piece goods whose warp and weft were woven from polyamide artificial silk were treated on star reel at 60 C. for 2 hours in a bleaching bath of the following composition:
- the two hours bleaching treatment only lowered the tearing strength of the warp from 43.5 kilometers to 40 kilometers and consequently only caused a 7.8% loss in strength.
- Example 4 A mixed fabric woven with a warp of 60 denier polyamide artificial silk and a weft of 100 denier viscose artificial silk was treated in loose form with movement at 60 C. for two hours in a bleaching bath of the following composition:
- the two hours treatment produced a good bleaching effect and only lowered the tearing strength of the warp from 44.2 kilometers to 42.2 kilometers and consequently only caused a 4.5% less in strength.
- Example 5 A woven fabric produced from 60 denier polyamide artificial silk yarn was treated at 60 C. for two and one half hours in a bath of the following composition:
- Example 7 Wash goods woven of polyamide artificial silk were washed at 60 C. (with light movement of the wash goods) in a washing liquid of the following composition:
- the ratio of goods to washing liquid was 1:50.
- Example 8 Wash goods woven of pclyamide artificial silk (Perlon- L-artificial silk) were washed at a temperature of 80 C. for one hour in an aqueous washing liquid containing g. per liter of a washing powder of the following composition:
- Example 9 A polyamide artificial silk fabric woven of 60 denier Perlon-L-silk was washed for two hours at 90 C. in an aqueous washing liquid of the following composition:
- peroxide as used herein, not only denotes peroxides, such as sodium peroxide and hydrogen peroxide, but also such compounds as sodium perborate, sodium percarbonate, sodium perpyrophosphate which form hydrogen peroxide in aqueous solution.
- the step which comprises incorporating in such aqueous solution 0.001 to 0.05 mole per liter an organic compound containing at least two nitrogen atoms of which at least one is in the form of an amino group selected from the group consisting of primary and secondary amino groups and any other is in the form of a group selected from the group consisting of pn'mary amino, secondary amino and tertiary amino groups, said nitrogen atoms being linked together by a chain containing up to 6 carbon atoms, the quantity of organic compound incorporated being sufficient to afford substantial protection of the fibers against deterioration during the treatment with the aqueous peroxide containing solution.
- aqueous bleaching solution containing a peroxide in a quantity to provide an active oxygen content of up to about 5 g. per liter
- the step which comprises incorporating in such aqueous bleaching solution 0.001 to 0.05 mole per liter an organic compound containing at least two nitrogen atoms of which at least one is in the form of an amino group selected from the group consisting of primary and secondary amino groups and any other is in the form of a group selected from the group consisting of primary amino, secondary amino and tertiary amino groups, said nitrogen atoms being linked together by a chain containing up to 6 carbon atoms, the quantity of organic compound incorporated being sufficient to afford substantial protection of the fibers against deterioration during the treatment with the aqueous peroxide containing solution.
- the step which comprises incorporating in such aqueous washing solution 0.001 to 0.005 mole per liter an organic compound containing at least two nitrogen atoms of which at least one is in the form of an amino group selected from the group consisting of primary and sec: ondary amino groups and any other is in the form of a group selected from the group consisting of primary amino, secondary amino and tertiary amino groups, said nitrogen atoms being linked together by a chain containing up to 6 carbon atoms, the quantity of organic compound incorporated being sufiicient to afford substantial protection of the fibers against deterioration during the treatment with the aqueous peroxide containing solution.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Polyamides (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED14553A DE976170C (de) | 1953-03-12 | 1953-03-12 | Verfahren zur Behandlung von Polyamidfasern mit peroxydhaltigen Bleich- oder Waschmitteln |
| DED17356A DE945443C (de) | 1953-03-12 | 1954-03-20 | Faserschutzmittel |
| DED19111A DE1020433B (de) | 1953-03-12 | 1954-11-13 | Verfahren zur Behandlung von synthetischen Polyamidfasern mit peroxydhaltigen Bleich- oder Waschmitteln |
| DED19309A DE1025376B (de) | 1953-03-12 | 1954-12-11 | Verfahren zur Behandlung von Polyamidfasern mit peroxydhaltigen Bleich- oder Waschmitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2909404A true US2909404A (en) | 1959-10-20 |
Family
ID=27436738
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US419911A Expired - Lifetime US2909404A (en) | 1953-03-12 | 1954-03-11 | Protection of polyamide fibers during treatment with peroxide containing bleaching or washing agents |
| US62325A Expired - Lifetime US3153565A (en) | 1953-03-12 | 1960-10-13 | Process for the treatment of synthetic linear polycarbonamide textile fibers |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US62325A Expired - Lifetime US3153565A (en) | 1953-03-12 | 1960-10-13 | Process for the treatment of synthetic linear polycarbonamide textile fibers |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US2909404A (it) |
| BE (1) | BE536668A (it) |
| CH (2) | CH333466A (it) |
| DE (4) | DE976170C (it) |
| FR (2) | FR1121229A (it) |
| GB (2) | GB767025A (it) |
| NL (4) | NL112268C (it) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3050822A (en) * | 1961-03-09 | 1962-08-28 | Du Pont | Pill resistant polyamide fiber |
| US3153565A (en) * | 1953-03-12 | 1964-10-20 | Degussa | Process for the treatment of synthetic linear polycarbonamide textile fibers |
| US3293110A (en) * | 1962-06-26 | 1966-12-20 | Du Pont | Polymeric staple fiber blend containing weakened polyamide fibers |
| US3628906A (en) * | 1967-08-26 | 1971-12-21 | Degussa | Agent for protecting polyamide fibers or threads against the attack of bleaching and washing baths |
| FR2986798A1 (fr) * | 2012-02-14 | 2013-08-16 | Rhodia Operations | Nouvel agent inhibiteur de gonflement des argiles, compositions comprenant ledit agent et procedes mettant en oeuvre ledit agent |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1116393B (de) * | 1959-11-14 | 1961-11-02 | Rhodiaceta Ag | Verfahren zur Erhoehung der Lichtbestaendigkeit von geformten Polyamiden |
| US3480392A (en) * | 1967-08-24 | 1969-11-25 | Sinclair Research Inc | Hydroxylamine solutions stabilized with a hydroxamic acid and method for their preparation |
| US3480391A (en) * | 1967-08-24 | 1969-11-25 | Sinclair Research Inc | Hydroxylamine solutions stabilized with an amide oxime and method for their preparation |
| US3795625A (en) * | 1971-06-03 | 1974-03-05 | Monsanto Co | Bleaching compositions |
| US3975153A (en) * | 1975-08-25 | 1976-08-17 | Fmc Corporation | Activation of peroxygen bleaches using isophorone enol acetates and isophorone oximinoacetate |
| US4021361A (en) * | 1975-08-25 | 1977-05-03 | Fmc Corporation | Storage-stable detergent composition containing sodium perborate and activator |
| GB8714898D0 (en) * | 1987-06-25 | 1987-07-29 | Du Pont Canada | Protecting articles from bleaching solutions |
| US4959267A (en) * | 1988-11-23 | 1990-09-25 | Du Pont Canada Inc. | Fiber reinforced rubber products |
| EP0384912A3 (en) * | 1989-02-21 | 1991-09-11 | Monsanto Company | Hydroxamate bleach stabilizer |
| US5047163A (en) * | 1990-03-16 | 1991-09-10 | Lever Brothers Company, Division Of Conopco, Inc. | Activation of bleach precursors with sulfonimines |
| US5045223A (en) * | 1990-03-16 | 1991-09-03 | Lever Brothers Company, Division Of Conopco, Inc. | N-sulfonyloxaziridines as bleaching compounds |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2153416A (en) * | 1936-05-22 | 1939-04-04 | Hatters Fur Exchange Inc | Treatment of animal and vegetable fibers |
| US2287099A (en) * | 1937-02-15 | 1942-06-23 | Du Pont | Artificial wool |
| US2308992A (en) * | 1937-10-03 | 1943-01-19 | Procter & Gamble | Method for producing washing, cleansing, bleaching, and rinsing agents containing percompounds |
| US2412945A (en) * | 1945-07-27 | 1946-12-24 | Frederick C Bersworth | Detergent composition and method of preparing same |
| US2543852A (en) * | 1946-10-29 | 1951-03-06 | Sandoz Ltd | Surface active derivatives of nitrogen-containing sulfonic acids |
| US2688617A (en) * | 1951-07-17 | 1954-09-07 | American Cyanamid Co | Sulfonated dihalogeno diaminostilbenes |
| US2730428A (en) * | 1950-10-21 | 1956-01-10 | Tepha Ges Fur Pharmazeutische | Method and composition for washing and bleaching fibrous materials |
| US2778827A (en) * | 1949-10-28 | 1957-01-22 | Ciba Ltd | Process for the manufacture of derivatives of 4:4'-diaminostilbene-2:2'-disulfonic acid |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE737552C (de) * | 1935-06-22 | 1943-07-17 | Chem Fab Gruenau Ag | Verfahren zum Bleichen von Faserstoffen mittels Perverbindungen |
| GB549240A (en) * | 1941-05-10 | 1942-11-12 | William Baird | Pulverulent cleansing preparations |
| GB555998A (en) * | 1942-03-13 | 1943-09-15 | William Baird | Pulverulent cleansing preparations |
| US2661305A (en) * | 1949-11-01 | 1953-12-01 | Holliday Co Ltd L B | Method for improving the brightness of textile materials and product |
| US2620325A (en) * | 1951-06-25 | 1952-12-02 | Du Pont | Polymeric oximes and their preparation |
| NL295923A (it) * | 1953-03-12 | |||
| AT187509B (de) * | 1956-09-28 | 1956-10-25 | Degussa | Verfahren zur Behandlung von Polyamidfasern mit peroxydhaltigen Bleich- oder Waschmitteln |
-
0
- NL NL295923D patent/NL295923A/xx unknown
- BE BE536668D patent/BE536668A/xx unknown
- NL NL195727D patent/NL195727A/xx unknown
- NL NL112774D patent/NL112774C/xx active
- FR FR1094713D patent/FR1094713A/fr not_active Expired
- NL NL112268D patent/NL112268C/xx active
-
1953
- 1953-03-12 DE DED14553A patent/DE976170C/de not_active Expired
-
1954
- 1954-02-25 GB GB5593/54A patent/GB767025A/en not_active Expired
- 1954-03-09 CH CH333466D patent/CH333466A/de unknown
- 1954-03-11 US US419911A patent/US2909404A/en not_active Expired - Lifetime
- 1954-03-20 DE DED17356A patent/DE945443C/de not_active Expired
- 1954-11-13 DE DED19111A patent/DE1020433B/de active Pending
- 1954-12-11 DE DED19309A patent/DE1025376B/de active Pending
-
1955
- 1955-03-18 CH CH339688D patent/CH339688A/de unknown
- 1955-03-18 GB GB7993/55A patent/GB784911A/en not_active Expired
- 1955-03-21 FR FR1121229D patent/FR1121229A/fr not_active Expired
-
1960
- 1960-10-13 US US62325A patent/US3153565A/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2153416A (en) * | 1936-05-22 | 1939-04-04 | Hatters Fur Exchange Inc | Treatment of animal and vegetable fibers |
| US2287099A (en) * | 1937-02-15 | 1942-06-23 | Du Pont | Artificial wool |
| US2308992A (en) * | 1937-10-03 | 1943-01-19 | Procter & Gamble | Method for producing washing, cleansing, bleaching, and rinsing agents containing percompounds |
| US2412945A (en) * | 1945-07-27 | 1946-12-24 | Frederick C Bersworth | Detergent composition and method of preparing same |
| US2543852A (en) * | 1946-10-29 | 1951-03-06 | Sandoz Ltd | Surface active derivatives of nitrogen-containing sulfonic acids |
| US2778827A (en) * | 1949-10-28 | 1957-01-22 | Ciba Ltd | Process for the manufacture of derivatives of 4:4'-diaminostilbene-2:2'-disulfonic acid |
| US2730428A (en) * | 1950-10-21 | 1956-01-10 | Tepha Ges Fur Pharmazeutische | Method and composition for washing and bleaching fibrous materials |
| US2688617A (en) * | 1951-07-17 | 1954-09-07 | American Cyanamid Co | Sulfonated dihalogeno diaminostilbenes |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3153565A (en) * | 1953-03-12 | 1964-10-20 | Degussa | Process for the treatment of synthetic linear polycarbonamide textile fibers |
| US3050822A (en) * | 1961-03-09 | 1962-08-28 | Du Pont | Pill resistant polyamide fiber |
| US3293110A (en) * | 1962-06-26 | 1966-12-20 | Du Pont | Polymeric staple fiber blend containing weakened polyamide fibers |
| US3628906A (en) * | 1967-08-26 | 1971-12-21 | Degussa | Agent for protecting polyamide fibers or threads against the attack of bleaching and washing baths |
| FR2986798A1 (fr) * | 2012-02-14 | 2013-08-16 | Rhodia Operations | Nouvel agent inhibiteur de gonflement des argiles, compositions comprenant ledit agent et procedes mettant en oeuvre ledit agent |
| WO2013120844A1 (fr) * | 2012-02-14 | 2013-08-22 | Rhodia Operations | Nouvel agent inhibiteur de gonflement des argiles, compositions comprenant ledit agent et procedes mettant en œuvre ledit agent |
| RU2577049C1 (ru) * | 2012-02-14 | 2016-03-10 | Родиа Операсьон | Новый ингибитор набухания глин, композиции, содержащие указанный ингибитор, и способы, использующие указанный ингибитор |
| US9637681B2 (en) | 2012-02-14 | 2017-05-02 | Rhodia Operations | Agent for inhibiting the swelling of clays, compositions comprising said agent and methods implementing said agent |
Also Published As
| Publication number | Publication date |
|---|---|
| NL295923A (it) | |
| FR1094713A (it) | 1955-05-24 |
| CH333466A (de) | 1958-10-31 |
| NL112268C (it) | |
| BE536668A (it) | |
| GB767025A (en) | 1957-01-30 |
| DE1025376B (de) | 1958-03-06 |
| DE945443C (de) | 1956-07-12 |
| NL195727A (it) | |
| NL112774C (it) | |
| GB784911A (en) | 1957-10-16 |
| US3153565A (en) | 1964-10-20 |
| FR1121229A (fr) | 1956-07-25 |
| CH339688A (de) | 1959-07-15 |
| DE976170C (de) | 1963-04-11 |
| DE1020433B (de) | 1957-12-05 |
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