US2599127A - Sterilizing detergent composition and method of use - Google Patents
Sterilizing detergent composition and method of use Download PDFInfo
- Publication number
- US2599127A US2599127A US9636A US963648A US2599127A US 2599127 A US2599127 A US 2599127A US 9636 A US9636 A US 9636A US 963648 A US963648 A US 963648A US 2599127 A US2599127 A US 2599127A
- Authority
- US
- United States
- Prior art keywords
- alkyl
- detergent composition
- quaternary ammonium
- sterilizing
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000001954 sterilising effect Effects 0.000 title claims description 9
- 238000000034 method Methods 0.000 title claims description 6
- 239000003599 detergent Substances 0.000 title description 14
- 239000000203 mixture Substances 0.000 title description 8
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 235000013305 food Nutrition 0.000 claims description 3
- 238000009991 scouring Methods 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 239000008267 milk Substances 0.000 description 5
- 210000004080 milk Anatomy 0.000 description 5
- 235000013336 milk Nutrition 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- -1 alkyl quaternary ammonium compounds Chemical class 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 125000004945 acylaminoalkyl group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000282465 Canis Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 102100029469 WD repeat and HMG-box DNA-binding protein 1 Human genes 0.000 description 1
- 101710097421 WD repeat and HMG-box DNA-binding protein 1 Proteins 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HQQSBEDKMRHYME-UHFFFAOYSA-N pefloxacin mesylate Chemical compound [H+].CS([O-])(=O)=O.C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC(F)=C1N1CCN(C)CC1 HQQSBEDKMRHYME-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C7/00—Other dairy technology
- A23C7/02—Chemical cleaning of dairy apparatus; Use of sterilisation methods therefor
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Definitions
- This invention relates to a method. of cleaning milk bottles and other returnable containersfor food products and beverages and to detergent compositions more particularly for use in machinesfor washing milk bottles, beer bottles and like containers for edible and potable'products' and for cleaning apparatus and equipment concerned in the manufacture and transport of such products.
- Detergents for these purposes are 're-' quired to have a combination of properties peculiar to the particular purpose for which they are required. Not only must they have the power of quickly removing tracesof food products adhering firmly to the bottle or other object to be cleaned but in order that, e. g., bottle washing machines may function correctly any excessive foaming must be avoided and it is also necessary to commercially sterilize the bottles or other equipment. At the same time it is necessary that in sterilizing no poisonous material should be used.
- the invention is based on the discovery that tetra-alkyl quaternary ammonium halides or hydroxides in which two of the alkyl groups contain not less than six and not more than nine-- carbon atoms in each hydrocarbon group while the other two alkyl groups contain up to nine carbon atoms but preferably not more than three carbon atoms in each group. have the property of being compatible with all the alkaline de tergent compounds other than silicate-containing I detergents used in bottle washing and like equiptrations in which they have to be employed to give the required sterilization.
- water-soluble or water-miscible quaternary ammonium halides or hydroxides have the aforesaid properties if one or more of the hydrogen atoms in the six to nine carbon alkyl chains are alkyl-substituted or if one or more of the hydrogen atoms in asix to nine carbon alkyl chain (other than a hydrogen atom attached to the omega carbon atom) in a seven to nine carbon atom chain is substituted by an alkoxy alkyl or acylamino alkyl group or are alkyl chain groups containing a polar group and having six to nine straigh H chain carbon atoms in the chain.
- a method of cleans-'- ing and sterilizing milk bottles and like returnable containers comprises scouring the said containers with an aqueous solution containing a tetra-alkyl quaternary ammonium compound having the following general formula: V
- R1 and R2 are organic radicals selected from the group consisting of alkyls, alkoxy alkyls, acylamino alkyls including cidaL arid yconsiderableg detergent, pro'perti'esaiw-ithr as'so diunrhydroxide;
- R3 and B4 are selected from the same group of organic radicals as R1 and R2 but containing any number of carbon atoms up to nine and including watenscluble aryl substituentswofythe said; radicalsa V L According to a further feature of the invention there is provided a sterilizing detergent COmpOSi-:
- the machines can give the requisite steriliza- A quaternary ammonium compound selected from: rtlreeaboveedefined groupa when dissolved? in;
- aiweak alkali such a'sasodiumzcarbonate-instead of thelusuali-strongalkali; such i- 'ltupreferrdi composition-P ior carryingout?
- the; method; according *to -theinventions comprises: a. tetra iaikyl :quaternaryvanimon'iumihalideor by.
- te "-ary afnfricnium compounds as hereinscribed in detergent compositions withcausti ,-':allra;1is;- can be used in, for example, f V be washin ;equipment without any objectidnaloleafoamingeand the bottles thus cleaned terial counts than those normally gems hitherto used and'the "bottle washing machines are maintained in a Moreare vvith concentratie e n s ⁇ ; 4
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB968146A GB618433A (en) | 1947-03-17 | 1946-03-28 | Improvements in sterilising detergent compositions |
| GB736447A GB650304A (en) | 1947-03-17 | 1947-03-17 | Improvements in and relating to sterilising detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2599127A true US2599127A (en) | 1952-06-03 |
Family
ID=32232354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US9636A Expired - Lifetime US2599127A (en) | 1946-03-28 | 1948-02-19 | Sterilizing detergent composition and method of use |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2599127A (is") |
| BE (2) | BE483659A (is") |
| FR (1) | FR944007A (is") |
| NL (1) | NL67159C (is") |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2893166A (en) * | 1954-09-09 | 1959-07-07 | Union Starch & Refining Compan | Stabilized soil and method of producing it with quaternary nitrogen salt |
| US3077929A (en) * | 1959-12-14 | 1963-02-19 | Phillips Petroleum Co | Use of quaternary ammonium salts for paraffin removal |
| US3355392A (en) * | 1963-10-18 | 1967-11-28 | West Laboratories Inc | Alkaline germicidal cleaner with color indicator |
| US3468640A (en) * | 1964-09-22 | 1969-09-23 | Chevron Res | Gasoline compositions |
| US4336165A (en) * | 1979-06-22 | 1982-06-22 | S. C. Johnson & Son, Inc. | Defoaming powdered carpet cleaning composition for use in extraction cleaning |
| US4601954A (en) * | 1984-03-30 | 1986-07-22 | Servicemaster Industries, Inc. | Disinfectant formulation |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2060850A (en) * | 1932-11-08 | 1936-11-17 | Du Pont | Quaternary ammonium compounds and process for the production thereof |
| US2108765A (en) * | 1938-02-15 | Preserving and disinfecting media | ||
| US2314111A (en) * | 1940-10-29 | 1943-03-16 | Standard Oil Co | Coating mineral aggregates |
| US2356587A (en) * | 1937-04-13 | 1944-08-22 | Hentrich Winfrid | Quaternary ammonium compounds |
| US2374213A (en) * | 1945-04-24 | Cleansing compositions |
-
0
- BE BE472178D patent/BE472178A/xx unknown
- NL NL67159D patent/NL67159C/xx active
- BE BE483659D patent/BE483659A/xx unknown
-
1947
- 1947-03-27 FR FR944007D patent/FR944007A/fr not_active Expired
-
1948
- 1948-02-19 US US9636A patent/US2599127A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2108765A (en) * | 1938-02-15 | Preserving and disinfecting media | ||
| US2374213A (en) * | 1945-04-24 | Cleansing compositions | ||
| US2060850A (en) * | 1932-11-08 | 1936-11-17 | Du Pont | Quaternary ammonium compounds and process for the production thereof |
| US2356587A (en) * | 1937-04-13 | 1944-08-22 | Hentrich Winfrid | Quaternary ammonium compounds |
| US2314111A (en) * | 1940-10-29 | 1943-03-16 | Standard Oil Co | Coating mineral aggregates |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2893166A (en) * | 1954-09-09 | 1959-07-07 | Union Starch & Refining Compan | Stabilized soil and method of producing it with quaternary nitrogen salt |
| US3077929A (en) * | 1959-12-14 | 1963-02-19 | Phillips Petroleum Co | Use of quaternary ammonium salts for paraffin removal |
| US3355392A (en) * | 1963-10-18 | 1967-11-28 | West Laboratories Inc | Alkaline germicidal cleaner with color indicator |
| US3468640A (en) * | 1964-09-22 | 1969-09-23 | Chevron Res | Gasoline compositions |
| US4336165A (en) * | 1979-06-22 | 1982-06-22 | S. C. Johnson & Son, Inc. | Defoaming powdered carpet cleaning composition for use in extraction cleaning |
| US4601954A (en) * | 1984-03-30 | 1986-07-22 | Servicemaster Industries, Inc. | Disinfectant formulation |
Also Published As
| Publication number | Publication date |
|---|---|
| NL67159C (is") | |
| BE472178A (is") | |
| FR944007A (fr) | 1949-03-24 |
| BE483659A (is") |
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