US2066371A - Method of desulphurizing artificial filaments of viscose - Google Patents
Method of desulphurizing artificial filaments of viscose Download PDFInfo
- Publication number
- US2066371A US2066371A US704204A US70420433A US2066371A US 2066371 A US2066371 A US 2066371A US 704204 A US704204 A US 704204A US 70420433 A US70420433 A US 70420433A US 2066371 A US2066371 A US 2066371A
- Authority
- US
- United States
- Prior art keywords
- desulphurizing
- substances
- viscose
- scrooping
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000297 Rayon Polymers 0.000 title description 7
- 238000000034 method Methods 0.000 title description 4
- 239000000126 substance Substances 0.000 description 21
- 239000003795 chemical substances by application Substances 0.000 description 18
- 239000002253 acid Substances 0.000 description 8
- 230000007935 neutral effect Effects 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- -1 fatty acid esters Chemical class 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 150000001243 acetic acids Chemical class 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- JJQHTLAUSSTREE-UHFFFAOYSA-N hexane-3,3-diamine Chemical compound CCCC(N)(N)CC JJQHTLAUSSTREE-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical class CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- BRMSVEGRHOZCAM-UHFFFAOYSA-M sodium;2-dodecanoyloxyethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)OCCS([O-])(=O)=O BRMSVEGRHOZCAM-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/02—Chemical after-treatment of artificial filaments or the like during manufacture of cellulose, cellulose derivatives, or proteins
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01B—MACHINES OR ENGINES, IN GENERAL OR OF POSITIVE-DISPLACEMENT TYPE, e.g. STEAM ENGINES
- F01B25/00—Regulating, controlling or safety means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01B—MACHINES OR ENGINES, IN GENERAL OR OF POSITIVE-DISPLACEMENT TYPE, e.g. STEAM ENGINES
- F01B2250/00—Accessories of steam engines; Arrangements or control devices of piston pumps, compressors without crank shafts or condensors for so far as they influence the functioning of the engines
- F01B2250/004—Devices for draining or idling of steam cylinders or for uncoupling piston and connecting rod
Definitions
- the fibre does not swell so highly, so that chemical attack on'the filament, and more particularly mechanical injury to the. fibre, cannot take place so readily.
- bobbins, vats and so forth are less attacked than when sodium sulphide and soda lye. are used, although in view of the high temperature of the desulphurizing bath, the chemical attack is still very considerable.
- one of the following substances is used for desulphurizing filaments, more particularly artificial silk, the working procedure being as usual, that is to say 1 to 2'hours treatment at 80 to 90 C., 1.5 to 2% solution being used.
- R1 is a polyatomic residue
- R2 and R3 are any desired'organic residues or hydrogen
- M is a metal
- R1 is a polyatomic residue
- R2 and R3 are any desired'organic residues or hydrogen
- M is a metal
- the fatty acid esters of the low aliphatic oxysulphonic acid salts generally formulae e; g. the oleic acid ester of. the sodium salt of oxyethyl sulphonic acid:
- fatty acid amides of the low aliphatic aminosulphonic acid salts (general formulae CnH2n--1CONH-A1k-SO3M and CnH2n+1-CO--NHA1k-SO3M) e. g. the oleic acid amide of the sodium salt of aminoethyl sulphonic acids:
- desulphurization with the said substances has the advantage that the substances have a completely neutral reaction in aqueous solution, so that scarcely any attack on thebobbins, vats and so forth can take place. It is true that it has already been proposed to desulphurize with neutral substances, e. g. with alcohol vapours and alcoholic solutions of glycerin, grape sugar and cane sugar (U. S. Patent No. 1,651,404 and French Patent No. 655,- '729).
- the "said substances act as desulphuriz'ing agents.
- the desulphurizing action is a property of the free sulphonic acids; in the :case of substances coming in class 4, it is, for
- the known advantages of the said substances as scrooping agents come particularly to thefore when the substances are simultaneously used for desulphurizing purposes. More particularly-the simultaneous desulphurization and scrooping with the same treatment baths is advantageous when the whole of the after-treatment is carried out on the bobbin or in the pot, since in such cases the purity of the treatment liquids is a matter of' primary importance.
- the artificial filament after-treated according to the invention is characterized not only by its cleanness, but also to anoutstanding and pre-eminent extent by its softness and flexibility.
- WhatI claim is 1.
- the step of desulphurizing the filament by, treatment with a neutral aqueous solution of at least one substance selected from thefollowing group of neutral water-soluble wetting and scroo'ping' agents of fatty character: salts of sulphuric acid esters of high molecular alcohols and the fatty acid esters of low aliphatic oxy-sulphonic acid salts.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE428955X | 1933-01-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2066371A true US2066371A (en) | 1937-01-05 |
Family
ID=6477533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US704204A Expired - Lifetime US2066371A (en) | 1933-01-12 | 1933-12-27 | Method of desulphurizing artificial filaments of viscose |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2066371A (en(2012)) |
| BE (1) | BE400821A (en(2012)) |
| FR (2) | FR428955A (en(2012)) |
| GB (2) | GB428955A (en(2012)) |
| NL (1) | NL38535C (en(2012)) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2418660A (en) * | 1943-04-24 | 1947-04-08 | Du Pont | Manufacture of regenerated cellulose structures |
| US2585141A (en) * | 1945-09-05 | 1952-02-12 | Celanese Corp | Treatment of viscose products |
| US2670266A (en) * | 1949-12-08 | 1954-02-23 | Du Pont | Textile bleach-finish process |
-
0
- NL NL38535D patent/NL38535C/xx active
- BE BE400821D patent/BE400821A/xx unknown
-
1911
- 1911-04-26 FR FR428955A patent/FR428955A/fr not_active Expired
-
1933
- 1933-12-27 US US704204A patent/US2066371A/en not_active Expired - Lifetime
-
1934
- 1934-01-11 FR FR766877D patent/FR766877A/fr not_active Expired
- 1934-01-12 GB GB1226/34A patent/GB428955A/en not_active Expired
- 1934-01-12 GB GB1243/35A patent/GB429165A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2418660A (en) * | 1943-04-24 | 1947-04-08 | Du Pont | Manufacture of regenerated cellulose structures |
| US2585141A (en) * | 1945-09-05 | 1952-02-12 | Celanese Corp | Treatment of viscose products |
| US2670266A (en) * | 1949-12-08 | 1954-02-23 | Du Pont | Textile bleach-finish process |
Also Published As
| Publication number | Publication date |
|---|---|
| GB429165A (en) | 1935-05-24 |
| GB428955A (en) | 1935-05-22 |
| FR766877A (fr) | 1934-07-05 |
| BE400821A (en(2012)) | |
| FR428955A (fr) | 1911-09-12 |
| NL38535C (en(2012)) |
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