US20190127562A1 - Polypropylene composite resin composition with fiber texture - Google Patents
Polypropylene composite resin composition with fiber texture Download PDFInfo
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- US20190127562A1 US20190127562A1 US15/845,443 US201715845443A US2019127562A1 US 20190127562 A1 US20190127562 A1 US 20190127562A1 US 201715845443 A US201715845443 A US 201715845443A US 2019127562 A1 US2019127562 A1 US 2019127562A1
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- C08L2201/00—Properties
- C08L2201/52—Aqueous emulsion or latex, e.g. containing polymers of a glass transition temperature (Tg) below 20°C
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/66—Substances characterised by their function in the composition
- C08L2666/72—Fillers; Inorganic pigments; Reinforcing additives
Definitions
- the present disclosure relates to a polypropylene composite resin composition with fiber texture and a molded article manufactured using the same.
- Vehicles which were merely used as a transportation means in the past, have become secondary living spaces. For this reason, user interest is gradually increasing in performances of vehicles as well as various functions and eco-friendliness thereof and, in particular, interiors thereof.
- VOCs volatile organic compounds
- Another technique is to impart fiber texture to a resin composition by directly adding a fibrous polymer to the resin composition, as disclosed in Korean Patent No. 10-1154317.
- this method has drawbacks in that texture expression is changed depending on the color of plastic components for vehicle interior materials and there are various limitations on applying embossed patterns.
- the present disclosure provides a polypropylene composite resin composition with fiber texture including a polypropylene resin including homo-polypropylene, a first ethylene-propylene copolymer, a second ethylene-propylene copolymer or a combination thereof, and an ethylene/ ⁇ -olefin copolymer.
- the polypropylene composite resin composition may include 50% by weight to 70% by weight of the polypropylene resin, and 5% by weight to 25% by weight of the ethylene/ ⁇ -olefin copolymer.
- the homo-polypropylene may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.).
- the first ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.) and may be obtained by polymerizing 50% by weight to 99% by weight of a propylene monomer with 1% by weight to 50% by weight of an ethylene monomer.
- the second ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 100 g/10 min (2.16 kg, 230° C.), may be obtained by polymerizing 90% by weight to 99.9% by weight of a propylene monomer with 0.1% by weight to 10% by weight of an ethylene monomer, and may have an isotactic index of 97% or more.
- the polypropylene resin may include the first ethylene-propylene copolymer and the second ethylene-propylene copolymer in a weight ratio of 1:1 to 3:1.
- the ethylene/ ⁇ -olefin copolymer may be a copolymer of ethylene and C 4 -C 8 alkylene.
- the ethylene/ ⁇ -olefin copolymer may have a Mooney viscosity of 5 ML1+4 (121° C.) to 50 ML1+4 (121° C.) and a glass transition temperature of ⁇ 60° C. to ⁇ 40° C.
- the polypropylene composite resin composition may further include an inorganic reinforcing material selected from the group consisting of talc having a sheet shape and a particle size of 0.5 ⁇ m to 10 ⁇ m; whisker having an acicular shape and having a length of 10 ⁇ m to 35 ⁇ m and a diameter of 0.3 ⁇ m to 1.5 ⁇ m, wollastonite, barium sulfate, calcium carbonate, silica, mica, calcium silicate, glass fibers, and a combination thereof.
- an inorganic reinforcing material selected from the group consisting of talc having a sheet shape and a particle size of 0.5 ⁇ m to 10 ⁇ m; whisker having an acicular shape and having a length of 10 ⁇ m to 35 ⁇ m and a diameter of 0.3 ⁇ m to 1.5 ⁇ m, wollastonite, barium sulfate, calcium carbonate, silica, mica, calcium silicate, glass fibers, and a combination thereof.
- the polypropylene composite resin composition may further include the inorganic reinforcing material in an amount of 1% by weight to 15% by weight.
- the polypropylene composite resin composition may further include a fibrous polymer selected from the group consisting of nylon, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), cellulose and a combination thereof, and having a diameter of 3 ⁇ m to 40 ⁇ m and a length of 0.3 mm to 4 mm.
- a fibrous polymer selected from the group consisting of nylon, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), cellulose and a combination thereof, and having a diameter of 3 ⁇ m to 40 ⁇ m and a length of 0.3 mm to 4 mm.
- the polypropylene composite resin composition may further include the fibrous polymer in an amount of 1.5% by weight to 5% by weight.
- the polypropylene composite resin composition may further include a wood ingredient selected from the group consisting of coniferous wood flour, broadleaved wood flour, a wood chip, softwood pulp (SWP), hardwood pulp (HWP) and a combination thereof, and having a particle size of 210 ⁇ m to 300 ⁇ m.
- a wood ingredient selected from the group consisting of coniferous wood flour, broadleaved wood flour, a wood chip, softwood pulp (SWP), hardwood pulp (HWP) and a combination thereof, and having a particle size of 210 ⁇ m to 300 ⁇ m.
- the polypropylene composite resin composition may further include the wood ingredient in an amount of 2% by weight to 10% by weight.
- the polypropylene composite resin composition may further include a stone ingredient selected from the group consisting of scoria, basalt and a combination thereof and having a particle size of 10 ⁇ m to 150 ⁇ m.
- the polypropylene composite resin composition may further include the stone ingredient in an amount of 1% by weight to 10% by weight.
- the polypropylene composite resin composition may further include an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and a combination thereof.
- an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and a combination thereof.
- the present disclosure provides a molded article manufactured using the polypropylene composite resin composition.
- the molded article may be an interior material for transport means.
- the polypropylene composite resin composition with fiber texture includes a polypropylene resin including homo-polypropylene, a first ethylene-propylene copolymer, a second ethylene-propylene copolymer or a combination thereof, and an ethylene/ ⁇ -olefin copolymer.
- polypropylene composite resin composition with fiber texture may further include an inorganic reinforcing material, a fibrous polymer, a wood ingredient and a stone ingredient.
- the polypropylene composite resin composition with fiber texture includes 50% by weight to 70% by weight of the polypropylene resin, 5% by weight to 25% by weight of the ethylene/ ⁇ -olefin copolymer, 1% by weight to 15% by weight of the inorganic reinforcing material, 1.5% by weight to 5% by weight of the fibrous polymer, 2% by weight to 10% by weight of the wood ingredient and 1% by weight to 10% by weight of the stone ingredient.
- the polypropylene composite resin composition with fiber texture may further include an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and a combination thereof.
- an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and a combination thereof.
- the polypropylene resin includes homo-polypropylene, a first ethylene-propylene copolymer, a second ethylene-propylene copolymer or a combination thereof.
- a combination of two or more thereof may be used, and a combination of the first ethylene-propylene copolymer and the second ethylene-propylene copolymer may be used in a certain weight ratio.
- the content of the polypropylene resin may be 50% by weight to 70% by weight.
- overall properties including tensile strength, flexural strength, impact strength and the like of the molded article may be deteriorated and when the content exceeds 70% by weight, fiber texture may not be expressed due to excessively low contents of other ingredients.
- the homo-polypropylene has a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.) and an isotactic index (measured by C13-NMR) of 94% to 97%.
- an isotactic index and the melt index satisfy these ranges, rigidity required for the molded article is met, and moldability and mechanical properties can be improved.
- the first ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.) and may be obtained by polymerizing 50% by weight to 99% by weight of a propylene monomer with 1% by weight to 50% by weight of an ethylene monomer.
- the content of the propylene monomer should be within the range defined above, in order to improve impact resistance and dimensional stability of the molded article.
- the second ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 100 g/10 min (2.16 kg, 230° C.), may be obtained by polymerizing 90% by weight to 99.9% by weight of a propylene monomer with 0.1% by weight to 10% by weight of an ethylene monomer, and may have an isotactic index of 97% or more, specifically 97.5% to 99.5%.
- the isotactic index is less than 97%, tensile strength, flexural strength, impact strength and surface hardness of the molded article may be deteriorated.
- the melt index is less than 1 g/10 min (2.16 kg, 230° C.)
- the molded article cannot be formed due to deteriorated flowability
- the melt index exceeds 100 g/10 min (2.16 kg, 230° C.)
- the impact resistance of the molded article may be significantly deteriorated.
- the second ethylene-propylene copolymer is a highly crystalline ethylene-propylene copolymer (highly crystalline polypropylene, HCPP) that has the melt index, content of the propylene monomer and the isotactic index, all satisfying the ranges defined above, which is distinguished from the first ethylene-propylene copolymer in terms of composition.
- HCPP highly crystalline polypropylene
- the polypropylene resin may include the first ethylene-propylene copolymer and the second ethylene-propylene copolymer in a weight ratio of 1:1 to 3:1. When the weight ratio exceeds 3:1, article moldability may be deteriorated and impact strength at room temperature may be deteriorated.
- the ethylene/ ⁇ -olefin copolymer is a copolymer of ethylene and ⁇ -olefin, is more specifically a copolymer of ethylene and C 4 -C 8 alkylene, and may be selected from the group consisting of an ethylene/ ⁇ -butylene copolymer, an ethylene/ ⁇ -octylene copolymer and a combination thereof.
- the ethylene/ ⁇ -olefin copolymer has a Mooney viscosity of 5 ML1+4 (121° C.) to 50 ML1+4 (121° C.) and a glass transition temperature of ⁇ 60° C. to ⁇ 40° C.
- the Mooney viscosity is within the range defined above, there is an advantage of maintaining or improving mechanical properties of the molded article. Meanwhile, when the glass transition temperature is less than ⁇ 60° C., rigidity and heat resistance of the molded article may be deteriorated and when the glass transition temperature exceeds ⁇ 40° C., impact strength at low temperature may be deteriorated.
- the content of the ethylene/ ⁇ -olefin copolymer may be 5% by weight to 25% by weight. When the content is less than 5% by weight, impact strength of the molded article may be deteriorated and when the content exceeds 25% by weight, heat resistance of the molded article may be deteriorated.
- the inorganic reinforcing material is an ingredient to reinforce the rigidity of the molded article and may be selected from the group consisting of talc, whisker, wollastonite, barium sulfate, calcium carbonate, silica, mica, calcium silicate, glass fibers and combinations thereof.
- the inorganic reinforcing material may be talc that has a sheet shape and a particle size of 0.5 ⁇ m to 10 ⁇ m.
- the particle size of the talc is less than 0.5 ⁇ m, productivity of the molded article may be deteriorated and when the particle size exceeds 10 ⁇ m, the overall mechanical properties of the molded article may be deteriorated.
- the inorganic reinforcing material may be whisker, or a whisker, that has an acicular shape, and has a length of 10 ⁇ m to 35 ⁇ m and a diameter of 0.3 ⁇ m to 1.5 ⁇ m.
- the length of the whisker is less than 10 ⁇ m, rigidity and heat resistance may be deteriorated, and when the length exceeds 35 ⁇ m, the resin composition may flow in a specific direction during injection molding, deforming the molded article.
- the content of the inorganic reinforcing material may be 1% by weight to 15% by weight, specifically 5% by weight to 10% by weight. When the content is less than 1% by weight, rigidity of the molded article may be deteriorated, and when the content exceeds 15% by weight, contents of other ingredients are excessively decreased, and moldability, scratch resistance and fouling resistance may be deteriorated.
- the fibrous polymer may be selected from the group consisting of nylon, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), cellulose and combinations thereof.
- the fibrous polymer may be a combination of materials with different colors and may be variably combined according to desired properties such as colors of the molded article and other products adjacent thereto.
- the fibrous polymer may have a diameter of 3 ⁇ m to 40 ⁇ m and a length of 0.3 mm to 4 mm.
- the diameter of the fibrous polymer is less than 3 ⁇ m, fiber texture may not be expressed, and when the diameter exceeds 40 ⁇ m, impact strength of the molded article may be deteriorated.
- the length of the fibrous polymer is less than 0.3 mm, fiber texture may not be expressed, and when the length exceeds 4 mm, the fibrous polymer may be entangled during manufacture of the molded article and dispersibility may be significantly deteriorated.
- the content of the fibrous polymer is 1.5% by weight to 5% by weight, specifically 2% by weight to 4% by weight, more specifically 2.5% by weight to 3% by weight.
- the content is less than 1% by weight, the fiber texture may not be expressed, and when the content exceeds 5% by weight, the fibrous polymer may be entangled due to excessive content.
- the wood ingredient may be selected from the group consisting of coniferous wood flour, broadleaved wood flour, wood chip, softwood pulp (SWP), hardwood pulp (HWP) and combinations thereof.
- the coniferous wood flour means a by-product (sawdust) produced during processing of coniferous wood and the broadleaved wood flour means a by-product (sawdust) produced during processing of broadleaved wood.
- the coniferous wood flour and the broadleaved wood flour may be recycled from wood obtained during production of other products.
- the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure further includes the wood ingredient, in addition to the fibrous polymer, to maximize fiber texture.
- the wood ingredient may have a particle size of 210 ⁇ m to 300 ⁇ m.
- the particle size of the wood ingredient is less than 210 ⁇ m, an expression of fiber texture may be insufficient and when the particle size exceeds 300 ⁇ m, a problem such as carbonation occurs in manufacture of the article, possibly causing a deterioration in tensile strength and impact strength.
- the content of the wood ingredient may be 2% by weight to 10% by weight, specifically 2% by weight to 5% by weight, more specifically 3% by weight to 5% by weight.
- an expression of fiber texture may be insufficient and when the content exceeds 10% by weight, problems such as carbonation, odor and deterioration in heat resistance may occur due to excessive content.
- the stone ingredient is an ingredient for minimizing influences of formation of a molded article with an embossed pattern on the resin composition.
- the stone ingredient may be selected from the group consisting of scoria, basalt and combinations thereof.
- VOCs volatile organic compounds
- the scoria may include, as main ingredients, 40% by weight to 50% by weight of silicon oxide, 10 to 20% by weight of aluminum oxide, 12% by weight to 17% by weight of iron oxide, 2% by weight to 8% by weight of titanium oxide and a predetermined amount of sodium oxide and potassium oxide.
- scoria since scoria has a heat-resistant temperature of 1,200° C. or more, it can be used regardless of type of molded article and processing temperature.
- scoria and basalt When scoria and basalt are used in combination, they may be combined in a weight ratio of 1:0.2 to 1:0.5, although the ratio may be changed depending on color of the molded article. When the weight ratio exceeds 1:0.5, color balance of the resin composition may be difficult due to excessive content of black basalt.
- the stone ingredient may have a spherical shape, but the present disclosure is not limited thereto.
- the stone ingredient has a spherical shape, rather than a linear or acicular shape, is used, dispersibility of respective ingredients included in the resin composition can be improved.
- the stone ingredient may have a particle size of 10 ⁇ m to 150 ⁇ m, specifically 40 ⁇ m to 100 ⁇ m.
- the particle size of stone ingredient is less than 10 ⁇ m, improvement in dispersibility may be insufficient, and when the particle size exceeds 150 ⁇ m, physical properties including strength, rigidity and scratch resistance of the molded article may be unbalanced.
- the content of the stone ingredient may be 1% by weight to 10% by weight.
- the amount used may be excessively small and when the content of the stone ingredient exceeds 10% by weight, physical properties including strength, rigidity and scratch resistance of the molded article may be unbalanced.
- the polypropylene composite resin composition with fiber texture may further include an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and combinations thereof.
- an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and combinations thereof.
- Respective ingredients were prepared in accordance with the composition and the composition ratio, as shown in the following Table 1, and polypropylene composite resin compositions were then produced. Then, the compositions were injection-molded using an injection molding machine (model: LGE110, LS Cable & System Ltd.) at a cylinder temperature of 220° C. and a die temperature of 50° C. to produce specimens (molded articles).
- an injection molding machine model: LGE110, LS Cable & System Ltd.
- Inorganic reinforcing material talc, sheet shape, particle size of 8 ⁇ m to 10 ⁇ m (Koch Industries, Inc.)
- Inorganic reinforcing material magnesium-whisker, length of 10 ⁇ m to 35 ⁇ m (UBE Industries, Inc.)
- Fibrous polymer polyethylene terephthalate (PET), diameter of 7 ⁇ m, length of 3 mm, red
- Wood ingredient broadleaved wood flour, particle size of 40 ⁇ m to 100 ⁇ m (Woori Deck Co., Ltd.)
- Wood ingredient coniferous wood flour, particle size of 40 ⁇ m to 100 ⁇ m (Woori Deck Co., Ltd.)
- i Stone ingredient scoria, particle size of 100 ⁇ m, red brown
- Respective ingredients were prepared in accordance with the composition and the composition ratio, as shown in the following Table 2, and polypropylene composite resin compositions were then produced. Then, the compositions were injection-molded using an injection molding machine (model: LGE110, LS Cable & System Ltd.) at a cylinder temperature of 220° C. and a die temperature of 50° C. to produce specimens (molded articles).
- an injection molding machine model: LGE110, LS Cable & System Ltd.
- Comparative Examples 1 and 2 are specimens containing less than 1.5% by weight of the fibrous polymer.
- Comparative Examples 3 and 4 are specimens where the weight ratio of the first ethylene-propylene copolymer (polypropylene resin b of Table 2) and the second ethylene-propylene copolymer (polypropylene resin a of Table 2) exceeds 1:3 and the content of the wood ingredient exceeds 10% by weight.
- Comparative Examples 5 and 6 are specimens containing less than 2% by weight of the wood ingredient.
- MI Melt index
- IZOD impact strength measured in accordance with ASTM D-256 at room temperature (23° C.) and ⁇ 10° C. using Notched specimens.
- Odor A specimen that had an odor grade of 3 or less, based on MS 300-34, was considered to pass (test conditions: 80° C., determination of odor after standing at room temperature for 2 hours and for 1 hour).
- Fiber texture measured by the naked eye. When there was no fiber texture, poor ( ⁇ ) was recorded, when fiber texture was expressed, but color matching with components was insufficient, good ( ⁇ ) was recorded, and when fiber texture was expressed and color matching with components was good, excellent ( ⁇ ) was recorded.
- Comparative Examples 3 and 4 where the weight ratio of the first ethylene-propylene copolymer to the second ethylene-propylene copolymer exceeded 1:3 were disadvantageous in reducing the weight of molded articles due to high specific gravities and had deteriorated impact strength at room temperature.
- Comparative Examples 3 and 4 which had wood ingredient contents exceeding 10% by weight, could express fiber texture well, but caused problems such as deterioration in scratch resistance and fouling resistance, and odor by carbonation.
- Examples 1 to 5 which satisfied all conditions required for the polypropylene composite resin composition according to exemplary embodiments of the present disclosure, exhibited low specific gravity, good balance between tensile strength, flexural strength, flexural modulus, and impact strength at room temperature or at low temperature, less odor by carbonation of the wood ingredient, excellent scratch resistance and fouling resistance, and superior expression of fiber texture.
- the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can be produced into molded articles by a method such as extrusion molding, injection molding, blow molding or compression molding.
- the molded article produced using the polypropylene composite resin composition with fiber texture according to exemplary embodiment of the present disclosure can be useful for interior materials of construction and transport means owing to luxurious appearance of fiber texture, but applications of the molded article include, without being limited to, containers, packing materials, household and kitchen appliances, electronic products, sports products, stationery and the like.
- the polypropylene composite resin composition with fiber texture can express, or enhance, the appearance of products in many ways because it is less affected by embossed patterns in the manufacture of products.
- Products manufactured from the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can be used under harsh environments such as extreme hot or cold areas for a long time due to excellent durability.
- Products manufactured from the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can protect users from external impact due to excellent impact resistance.
- the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can prevent environmental pollution because it is made of natural materials, in particular, recycled natural materials.
Abstract
Description
- This application claims, under 35 U.S.C. § 119(a), the benefit of priority to Korean Patent Application No. 10-2017-0144807 filed on Nov. 1, 2017 with the Korean Intellectual Property Office, the entire contents of which are incorporated herein by reference.
- The present disclosure relates to a polypropylene composite resin composition with fiber texture and a molded article manufactured using the same.
- Vehicles, which were merely used as a transportation means in the past, have become secondary living spaces. For this reason, user interest is gradually increasing in performances of vehicles as well as various functions and eco-friendliness thereof and, in particular, interiors thereof.
- With the trend toward advanced-aesthetics of vehicles, many attempts are made to improve aesthetics of vehicle interior materials such as pillar trims and door trims.
- One technique is to coat plastic components for vehicle interior materials or cover the same with fibers. This involves additional processes and materials, thus disadvantageously causing increased manufacturing costs and production of volatile organic compounds (VOCs) due to use of organic solvents and adhesive agents.
- Another technique is to impart fiber texture to a resin composition by directly adding a fibrous polymer to the resin composition, as disclosed in Korean Patent No. 10-1154317. However, this method has drawbacks in that texture expression is changed depending on the color of plastic components for vehicle interior materials and there are various limitations on applying embossed patterns.
- The above information disclosed in this Background section is only for enhancement of understanding of the background of the disclosure and therefore it may contain information that does not form the prior art that is already known in this country to a person of ordinary skill in the art.
- The present disclosure has been made in an effort to solve the above-described problems associated with the prior art.
- It is one object of the present disclosure to provide a polypropylene composite resin composition with excellent expression of fiber texture.
- It is another object of the present disclosure to provide a polypropylene composite resin composition with fiber texture which is less affected by embossed patterns.
- It is another object of the present disclosure to provide a polypropylene composite resin composition with fiber texture which exhibits excellent durability, impact resistance, impact scratch and fouling resistance.
- It is another object of the present disclosure to provide an eco-friendly polypropylene composite resin composition with fiber texture.
- The objects of the present disclosure are not limited to those described above. The objects of the present disclosure will be clearly understood from the following description and could be implemented by means defined in the claims and a combination thereof.
- In one aspect, the present disclosure provides a polypropylene composite resin composition with fiber texture including a polypropylene resin including homo-polypropylene, a first ethylene-propylene copolymer, a second ethylene-propylene copolymer or a combination thereof, and an ethylene/α-olefin copolymer.
- The polypropylene composite resin composition may include 50% by weight to 70% by weight of the polypropylene resin, and 5% by weight to 25% by weight of the ethylene/α-olefin copolymer.
- The homo-polypropylene may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.).
- The first ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.) and may be obtained by polymerizing 50% by weight to 99% by weight of a propylene monomer with 1% by weight to 50% by weight of an ethylene monomer.
- The second ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 100 g/10 min (2.16 kg, 230° C.), may be obtained by polymerizing 90% by weight to 99.9% by weight of a propylene monomer with 0.1% by weight to 10% by weight of an ethylene monomer, and may have an isotactic index of 97% or more.
- The polypropylene resin may include the first ethylene-propylene copolymer and the second ethylene-propylene copolymer in a weight ratio of 1:1 to 3:1.
- The ethylene/α-olefin copolymer may be a copolymer of ethylene and C4-C8 alkylene.
- The ethylene/α-olefin copolymer may have a Mooney viscosity of 5 ML1+4 (121° C.) to 50 ML1+4 (121° C.) and a glass transition temperature of −60° C. to −40° C.
- The polypropylene composite resin composition may further include an inorganic reinforcing material selected from the group consisting of talc having a sheet shape and a particle size of 0.5 μm to 10 μm; whisker having an acicular shape and having a length of 10 μm to 35 μm and a diameter of 0.3 μm to 1.5 μm, wollastonite, barium sulfate, calcium carbonate, silica, mica, calcium silicate, glass fibers, and a combination thereof.
- The polypropylene composite resin composition may further include the inorganic reinforcing material in an amount of 1% by weight to 15% by weight.
- The polypropylene composite resin composition may further include a fibrous polymer selected from the group consisting of nylon, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), cellulose and a combination thereof, and having a diameter of 3 μm to 40 μm and a length of 0.3 mm to 4 mm.
- The polypropylene composite resin composition may further include the fibrous polymer in an amount of 1.5% by weight to 5% by weight.
- The polypropylene composite resin composition may further include a wood ingredient selected from the group consisting of coniferous wood flour, broadleaved wood flour, a wood chip, softwood pulp (SWP), hardwood pulp (HWP) and a combination thereof, and having a particle size of 210 μm to 300 μm.
- The polypropylene composite resin composition may further include the wood ingredient in an amount of 2% by weight to 10% by weight.
- The polypropylene composite resin composition may further include a stone ingredient selected from the group consisting of scoria, basalt and a combination thereof and having a particle size of 10 μm to 150 μm.
- The polypropylene composite resin composition may further include the stone ingredient in an amount of 1% by weight to 10% by weight.
- The polypropylene composite resin composition may further include an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and a combination thereof.
- In another aspect, the present disclosure provides a molded article manufactured using the polypropylene composite resin composition.
- The molded article may be an interior material for transport means.
- Other aspects and exemplary embodiments of the disclosure are discussed infra.
- The objects described above, and other objects, features and advantages will be clearly understood from the following exemplary embodiments with reference to the annexed drawings. However, the present disclosure is not limited to the embodiments and will be embodied in different forms. The embodiments are suggested only to offer thorough and complete understanding of the disclosed contents and sufficiently inform those skilled in the art of the technical concept of the present disclosure.
- Like numbers refer to like elements throughout the description of the figures. In the drawings, the sizes of structures are exaggerated for clarity of the present disclosure. It will be understood that, although the terms first, second, etc. may be used herein to describe various elements, these elements should not be limited by these terms and are used only to distinguish one element from another. For example, within the scope defined by the present disclosure, a first element may be referred to as a second element and similarly, the second element may be referred to as the first element. Singular forms are intended to include plural forms as well, unless context clearly indicates otherwise.
- It will be further understood that the terms “comprises” and/or “has” when used in this specification, specify the presence of stated features, numbers, steps, operations, elements, components or combinations thereof, but do not preclude the presence or addition of one or more other features, numbers, steps, operations, elements, components, or combinations thereof.
- The polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure includes a polypropylene resin including homo-polypropylene, a first ethylene-propylene copolymer, a second ethylene-propylene copolymer or a combination thereof, and an ethylene/α-olefin copolymer.
- In addition, the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure may further include an inorganic reinforcing material, a fibrous polymer, a wood ingredient and a stone ingredient.
- More specifically, the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure includes 50% by weight to 70% by weight of the polypropylene resin, 5% by weight to 25% by weight of the ethylene/α-olefin copolymer, 1% by weight to 15% by weight of the inorganic reinforcing material, 1.5% by weight to 5% by weight of the fibrous polymer, 2% by weight to 10% by weight of the wood ingredient and 1% by weight to 10% by weight of the stone ingredient.
- In addition, the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure may further include an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and a combination thereof.
- Hereinafter, respective ingredients of the present disclosure will be described in more detail.
- 1) Polypropylene Resin
- The polypropylene resin includes homo-polypropylene, a first ethylene-propylene copolymer, a second ethylene-propylene copolymer or a combination thereof. When only one of the homo-polypropylene, the first ethylene-propylene copolymer and the second ethylene-propylene copolymer is used, impact resistance, heat resistance or the like of the molded article may be deteriorated. For this reason, a combination of two or more thereof may be used, and a combination of the first ethylene-propylene copolymer and the second ethylene-propylene copolymer may be used in a certain weight ratio.
- The content of the polypropylene resin may be 50% by weight to 70% by weight. When the content is less than 50% by weight, overall properties including tensile strength, flexural strength, impact strength and the like of the molded article may be deteriorated and when the content exceeds 70% by weight, fiber texture may not be expressed due to excessively low contents of other ingredients.
- a) Homo-Polypropylene
- The homo-polypropylene has a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.) and an isotactic index (measured by C13-NMR) of 94% to 97%. When the isotactic index and the melt index satisfy these ranges, rigidity required for the molded article is met, and moldability and mechanical properties can be improved.
- b) First Ethylene-Propylene Copolymer
- The first ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 60 g/10 min (2.16 kg, 230° C.) and may be obtained by polymerizing 50% by weight to 99% by weight of a propylene monomer with 1% by weight to 50% by weight of an ethylene monomer. The content of the propylene monomer should be within the range defined above, in order to improve impact resistance and dimensional stability of the molded article.
- c) Second Ethylene-Propylene Copolymer
- The second ethylene-propylene copolymer may have a melt index of 1 g/10 min (2.16 kg, 230° C.) to 100 g/10 min (2.16 kg, 230° C.), may be obtained by polymerizing 90% by weight to 99.9% by weight of a propylene monomer with 0.1% by weight to 10% by weight of an ethylene monomer, and may have an isotactic index of 97% or more, specifically 97.5% to 99.5%.
- When the isotactic index is less than 97%, tensile strength, flexural strength, impact strength and surface hardness of the molded article may be deteriorated.
- In addition, when the melt index is less than 1 g/10 min (2.16 kg, 230° C.), the molded article cannot be formed due to deteriorated flowability, and when the melt index exceeds 100 g/10 min (2.16 kg, 230° C.), the impact resistance of the molded article may be significantly deteriorated.
- In addition, when the content of the ethylene monomer is less than 0.1% by weight, impact resistance of the molded article may be deteriorated and when the content exceeds 10% by weight, rigidity may be deteriorated.
- The second ethylene-propylene copolymer is a highly crystalline ethylene-propylene copolymer (highly crystalline polypropylene, HCPP) that has the melt index, content of the propylene monomer and the isotactic index, all satisfying the ranges defined above, which is distinguished from the first ethylene-propylene copolymer in terms of composition.
- The polypropylene resin may include the first ethylene-propylene copolymer and the second ethylene-propylene copolymer in a weight ratio of 1:1 to 3:1. When the weight ratio exceeds 3:1, article moldability may be deteriorated and impact strength at room temperature may be deteriorated.
- 2) Ethylene/α-Olefin Copolymer
- The ethylene/α-olefin copolymer is a copolymer of ethylene and α-olefin, is more specifically a copolymer of ethylene and C4-C8 alkylene, and may be selected from the group consisting of an ethylene/α-butylene copolymer, an ethylene/α-octylene copolymer and a combination thereof.
- The ethylene/α-olefin copolymer has a Mooney viscosity of 5 ML1+4 (121° C.) to 50 ML1+4 (121° C.) and a glass transition temperature of −60° C. to −40° C.
- When the Mooney viscosity is within the range defined above, there is an advantage of maintaining or improving mechanical properties of the molded article. Meanwhile, when the glass transition temperature is less than −60° C., rigidity and heat resistance of the molded article may be deteriorated and when the glass transition temperature exceeds −40° C., impact strength at low temperature may be deteriorated.
- The content of the ethylene/α-olefin copolymer may be 5% by weight to 25% by weight. When the content is less than 5% by weight, impact strength of the molded article may be deteriorated and when the content exceeds 25% by weight, heat resistance of the molded article may be deteriorated.
- 3) Inorganic Reinforcing Material
- The inorganic reinforcing material is an ingredient to reinforce the rigidity of the molded article and may be selected from the group consisting of talc, whisker, wollastonite, barium sulfate, calcium carbonate, silica, mica, calcium silicate, glass fibers and combinations thereof.
- More specifically, the inorganic reinforcing material may be talc that has a sheet shape and a particle size of 0.5 μm to 10 μm. When the particle size of the talc is less than 0.5 μm, productivity of the molded article may be deteriorated and when the particle size exceeds 10 μm, the overall mechanical properties of the molded article may be deteriorated.
- In addition, the inorganic reinforcing material may be whisker, or a whisker, that has an acicular shape, and has a length of 10 μm to 35 μm and a diameter of 0.3 μm to 1.5 μm. When the length of the whisker is less than 10 μm, rigidity and heat resistance may be deteriorated, and when the length exceeds 35 μm, the resin composition may flow in a specific direction during injection molding, deforming the molded article.
- The content of the inorganic reinforcing material may be 1% by weight to 15% by weight, specifically 5% by weight to 10% by weight. When the content is less than 1% by weight, rigidity of the molded article may be deteriorated, and when the content exceeds 15% by weight, contents of other ingredients are excessively decreased, and moldability, scratch resistance and fouling resistance may be deteriorated.
- 4) Fibrous Polymer
- The fibrous polymer may be selected from the group consisting of nylon, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), cellulose and combinations thereof.
- The fibrous polymer may be a combination of materials with different colors and may be variably combined according to desired properties such as colors of the molded article and other products adjacent thereto.
- The fibrous polymer may have a diameter of 3 μm to 40 μm and a length of 0.3 mm to 4 mm. When the diameter of the fibrous polymer is less than 3 μm, fiber texture may not be expressed, and when the diameter exceeds 40 μm, impact strength of the molded article may be deteriorated. In addition, when the length of the fibrous polymer is less than 0.3 mm, fiber texture may not be expressed, and when the length exceeds 4 mm, the fibrous polymer may be entangled during manufacture of the molded article and dispersibility may be significantly deteriorated.
- The content of the fibrous polymer is 1.5% by weight to 5% by weight, specifically 2% by weight to 4% by weight, more specifically 2.5% by weight to 3% by weight. When the content is less than 1% by weight, the fiber texture may not be expressed, and when the content exceeds 5% by weight, the fibrous polymer may be entangled due to excessive content.
- 5) Wood Ingredient
- The wood ingredient may be selected from the group consisting of coniferous wood flour, broadleaved wood flour, wood chip, softwood pulp (SWP), hardwood pulp (HWP) and combinations thereof.
- The coniferous wood flour means a by-product (sawdust) produced during processing of coniferous wood and the broadleaved wood flour means a by-product (sawdust) produced during processing of broadleaved wood. The coniferous wood flour and the broadleaved wood flour may be recycled from wood obtained during production of other products.
- The polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure further includes the wood ingredient, in addition to the fibrous polymer, to maximize fiber texture.
- The wood ingredient may have a particle size of 210 μm to 300 μm. When the particle size of the wood ingredient is less than 210 μm, an expression of fiber texture may be insufficient and when the particle size exceeds 300 μm, a problem such as carbonation occurs in manufacture of the article, possibly causing a deterioration in tensile strength and impact strength.
- The content of the wood ingredient may be 2% by weight to 10% by weight, specifically 2% by weight to 5% by weight, more specifically 3% by weight to 5% by weight. When the content is less than 2% by weight, an expression of fiber texture may be insufficient and when the content exceeds 10% by weight, problems such as carbonation, odor and deterioration in heat resistance may occur due to excessive content.
- 6) Stone Ingredient
- The stone ingredient is an ingredient for minimizing influences of formation of a molded article with an embossed pattern on the resin composition.
- The stone ingredient may be selected from the group consisting of scoria, basalt and combinations thereof. When volcanic stone such as scoria or basalt is used as the stone ingredient, volatile organic compounds (VOCs) are adsorbed on the stone. As a result, it is possible to prevent the VOCs from negatively affecting user health.
- For example, the scoria may include, as main ingredients, 40% by weight to 50% by weight of silicon oxide, 10 to 20% by weight of aluminum oxide, 12% by weight to 17% by weight of iron oxide, 2% by weight to 8% by weight of titanium oxide and a predetermined amount of sodium oxide and potassium oxide. In addition, since scoria has a heat-resistant temperature of 1,200° C. or more, it can be used regardless of type of molded article and processing temperature.
- When scoria and basalt are used in combination, they may be combined in a weight ratio of 1:0.2 to 1:0.5, although the ratio may be changed depending on color of the molded article. When the weight ratio exceeds 1:0.5, color balance of the resin composition may be difficult due to excessive content of black basalt.
- In addition, the stone ingredient may have a spherical shape, but the present disclosure is not limited thereto. When the stone ingredient has a spherical shape, rather than a linear or acicular shape, is used, dispersibility of respective ingredients included in the resin composition can be improved.
- The stone ingredient may have a particle size of 10 μm to 150 μm, specifically 40 μm to 100 μm. When the particle size of stone ingredient is less than 10 μm, improvement in dispersibility may be insufficient, and when the particle size exceeds 150 μm, physical properties including strength, rigidity and scratch resistance of the molded article may be unbalanced.
- The content of the stone ingredient may be 1% by weight to 10% by weight. When the content of the stone ingredient is less than 1% by weight, the amount used may be excessively small and when the content of the stone ingredient exceeds 10% by weight, physical properties including strength, rigidity and scratch resistance of the molded article may be unbalanced.
- 7) Additives
- The polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure may further include an additive selected from the group consisting of a deodorant, a lubricant, an antioxidant, a heat stabilizer, a light stabilizer, a release agent, a pigment, an antistatic agent, an antibacterial agent, a processing aid, a smoke suppressant, an anti-dripping agent, a glass fiber, an anti-abrasion agent, a coupling agent, a compatibilizing agent and combinations thereof.
- Hereinafter, the present disclosure will be described in more detail with reference to examples. However, these examples should not be construed as limiting the scope of the present disclosure.
- Respective ingredients were prepared in accordance with the composition and the composition ratio, as shown in the following Table 1, and polypropylene composite resin compositions were then produced. Then, the compositions were injection-molded using an injection molding machine (model: LGE110, LS Cable & System Ltd.) at a cylinder temperature of 220° C. and a die temperature of 50° C. to produce specimens (molded articles).
-
TABLE 1 Exam- Exam- Exam- Exam- Exam- Ingredients ple 1 ple 2 ple 3 ple 4 ple 5 Polypropylene resina 35 43.5 43 42.5 44.5 Polypropylene resinb 24 25 20 15 15 Ethylene/α-olefin 20 10 15 20 20 copolymerc Inorganic reinforcing 5 5 5 5 5 materiald Inorganic reinforcing 5 5 5 5 5 materiale Fibrous polymerf 1.5 2 2.5 3 3 Wood ingredientg 5 — — — — Wood ingredienth — 5 5 5 3 Stone ingredienti 1 1 1 1 1 Antioxidant 3.5 3.5 3.5 3.5 3.5 In Table 1, aPolypropylene resin: highly crystalline ethylene-propylene copolymer, melt index of 30 g/10 min (2.16 kg, 230° C.), weight average molecular weight of 221,000 g/mol, isotactic index of 98.5% to 99% (SK company) bPolypropylene resin: ethylene-propylene copolymer, melt index of 30 g/10 min (2.16 kg, 230° C.), weight average molecular weight of 210,000 g/mol cEthylene/α-olefin copolymer: ethylene/α-octene copolymer, Mooney viscosity of 5 ML1 + 4 (121° C.) to 25 ML1 + 4 (121° C.), glass transition temperature of −55° C. to −62° C. dInorganic reinforcing material: talc, sheet shape, particle size of 8 μm to 10 μm (Koch Industries, Inc.) eInorganic reinforcing material: magnesium-whisker, length of 10 μm to 35 μm (UBE Industries, Inc.) fFibrous polymer: polyethylene terephthalate (PET), diameter of 7 μm, length of 3 mm, red gWood ingredient: broadleaved wood flour, particle size of 40 μm to 100 μm (Woori Deck Co., Ltd.) hWood ingredient: coniferous wood flour, particle size of 40 μm to 100 μm (Woori Deck Co., Ltd.) iStone ingredient: scoria, particle size of 100 μm, red brown - Respective ingredients were prepared in accordance with the composition and the composition ratio, as shown in the following Table 2, and polypropylene composite resin compositions were then produced. Then, the compositions were injection-molded using an injection molding machine (model: LGE110, LS Cable & System Ltd.) at a cylinder temperature of 220° C. and a die temperature of 50° C. to produce specimens (molded articles).
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TABLE 2 Comparative Comparative Comparative Comparative Comparative Comparative Example Example Example Example Example Example Ingredients 1 2 3 4 5 6 Polypropylene resina 35 34.5 42.5 40.5 43 42 Polypropylene resinb 35 30 8 12 18 20 Ethylene/α-olefin 10 15 20 20 20 20 copolymerc Inorganic reinforcing 5 5 5 5 5 5 materiald Inorganic reinforcing 5 5 5 5 5 5 materiale Fibrous polymerf 0.5 1 3 3 3 3 Wood ingredientg 5 5 — — — — Wood ingredienth — — 12 10 1.5 0.5 Stone ingredienti 1 1 1 1 1 1 Antioxidant 3.5 3.5 3.5 3.5 3.5 3.5 a to i of Table 2 are the same as those of Table 1. - Comparative Examples 1 and 2 are specimens containing less than 1.5% by weight of the fibrous polymer.
- Comparative Examples 3 and 4 are specimens where the weight ratio of the first ethylene-propylene copolymer (polypropylene resinb of Table 2) and the second ethylene-propylene copolymer (polypropylene resina of Table 2) exceeds 1:3 and the content of the wood ingredient exceeds 10% by weight.
- Comparative Examples 5 and 6 are specimens containing less than 2% by weight of the wood ingredient.
- Physical properties of specimens produced in Examples and Comparative Examples were measured in accordance with the following method. Results are shown in Table 3.
- 1) Melt index (MI): measured in accordance with ASTM D-1238 (Test conditions: 230° C., load: 21.2N).
- 2) Specific gravity: the center of a specimen, where flexural strength was measured, was measured in accordance with ASTM D792.
- 3) Tensile strength: measured in accordance with ASTM D-638 (Test conditions: 50 mm/min).
- 4) Flexural strength and flexural modulus: measured in accordance with ASTM D-790 at a load application rate of 30 mm/min.
- 5) IZOD impact strength: measured in accordance with ASTM D-256 at room temperature (23° C.) and −10° C. using Notched specimens.
- 6) Odor: A specimen that had an odor grade of 3 or less, based on MS 300-34, was considered to pass (test conditions: 80° C., determination of odor after standing at room temperature for 2 hours and for 1 hour).
- 7) Scratch: measured in accordance with MS 213-05 (Article 4.9). As scratch figure increases, scratch by external force increases. Thus, a specimen having a high scratch figure is unsuitable as a molded article.
- 8) Fouling: measured in accordance with MS210-05 (Article 4.13). As fouling figure increases, contamination by foreign material increases. Thus, a specimen having a high fouling figure is unsuitable as a molded article.
- 9) Fiber texture: measured by the naked eye. When there was no fiber texture, poor (Δ) was recorded, when fiber texture was expressed, but color matching with components was insufficient, good (∘) was recorded, and when fiber texture was expressed and color matching with components was good, excellent (⊚) was recorded.
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TABLE 3 Examples Comparative Examples Items 1 2 3 4 5 1 2 3 4 5 6 MI [g/10 min] 25.6 35.1 29.4 24.1 27.2 35.7 31.1 25.8 26.4 25.9 24.2 Specific gravity 0.98 0.99 0.99 0.99 0.99 0.98 0.98 1.04 1.03 0.98 0.97 [g/cm3] Tensile strength 23.4 26.1 24.8 23.7 22.7 26.9 25.1 24.8 24.1 21.3 21 [MPa] Flexural strength 31 37.1 34.1 30.1 27.1 37.2 34.3 33.5 31.9 26.4 26.1 [MPa] Flexural modulus 1690 1980 1870 1720 1610 2040 1890 1820 1810 1560 1520 [MPa] IZOD impact 169 110 138 172 211 102 140 88 102 229 235 strength at room temperature, [J/m] IZOD impact 40 35 38 42 58 36 37 32 35 64 66 strength, −10° C., [J/m] Odor [grade] 4.5 4 4 4 3 4.5 4.5 5 4.5 3 3 Scratch [ΔL] 2.1 1.9 1.7 1.6 0.7 1.8 1.9 3.1 2.5 0.7 0.6 Fouling [ΔY] 2.3 2.4 2.4 2.2 1.8 2.3 2.4 3.4 3 1.6 1.1 Fiber texture ◯ ◯ ⊚ ⊚ ⊚ Δ Δ ⊚ ⊚ Δ Δ - As can be seen from Table 3, the specimens of Comparative Examples 1 and 2 containing less than 1.5% by weight of the fibrous polymer could not express fiber texture well.
- In addition, specimens of Comparative Examples 3 and 4 where the weight ratio of the first ethylene-propylene copolymer to the second ethylene-propylene copolymer exceeded 1:3 were disadvantageous in reducing the weight of molded articles due to high specific gravities and had deteriorated impact strength at room temperature. In addition, Comparative Examples 3 and 4, which had wood ingredient contents exceeding 10% by weight, could express fiber texture well, but caused problems such as deterioration in scratch resistance and fouling resistance, and odor by carbonation.
- On the other hand, when the content of wood ingredient was less than 2% by weight, the specimens of Comparative Examples 5 and 6 could not express fiber texture well.
- Examples 1 to 5, which satisfied all conditions required for the polypropylene composite resin composition according to exemplary embodiments of the present disclosure, exhibited low specific gravity, good balance between tensile strength, flexural strength, flexural modulus, and impact strength at room temperature or at low temperature, less odor by carbonation of the wood ingredient, excellent scratch resistance and fouling resistance, and superior expression of fiber texture.
- The disclosure has been described in detail with reference to exemplary test examples and examples thereof. However, it will be appreciated by those skilled in the art that changes may be made in these examples without departing from the principles and spirit of the disclosure, the scope of which is defined in the appended claims and their equivalents.
- The polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can be produced into molded articles by a method such as extrusion molding, injection molding, blow molding or compression molding.
- The molded article produced using the polypropylene composite resin composition with fiber texture according to exemplary embodiment of the present disclosure can be useful for interior materials of construction and transport means owing to luxurious appearance of fiber texture, but applications of the molded article include, without being limited to, containers, packing materials, household and kitchen appliances, electronic products, sports products, stationery and the like.
- As is apparent from the foregoing, with the polypropylene composite resin composition according to exemplary embodiments of the present disclosure, it is possible to provide products with an excellent expression of fiber texture.
- The polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can express, or enhance, the appearance of products in many ways because it is less affected by embossed patterns in the manufacture of products.
- Products manufactured from the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can be used under harsh environments such as extreme hot or cold areas for a long time due to excellent durability.
- Products manufactured from the polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can protect users from external impact due to excellent impact resistance.
- The polypropylene composite resin composition with fiber texture according to exemplary embodiments of the present disclosure can prevent environmental pollution because it is made of natural materials, in particular, recycled natural materials.
- The objects of the present disclosure are not limited to those described above. It should be understood that effects of the present disclosure encompass all effects that can be inferred from the foregoing description.
- The disclosure has been described in detail with reference to exemplary embodiments thereof. However, it will be appreciated by those skilled in the art that changes may be made in these embodiments without departing from the principles and spirit of the disclosure, the scope of which is defined in the appended claims and their equivalents.
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EP (1) | EP3480249A1 (en) |
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US10450452B2 (en) * | 2016-08-03 | 2019-10-22 | Borealis Ag | Fiber reinforced polypropylene composite |
CN112552596A (en) * | 2020-12-11 | 2021-03-26 | 台州市森力塑胶有限公司 | Degradable polypropylene wood-plastic composite modified material |
WO2021120864A1 (en) * | 2019-12-17 | 2021-06-24 | 金发科技股份有限公司 | Polypropylene composition, preparation method therefor and use thereof |
CN114318627A (en) * | 2021-12-27 | 2022-04-12 | 安徽乙纤新材料科技有限公司 | Production process of antibacterial reinforced plastic net |
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CN113004618A (en) * | 2021-03-15 | 2021-06-22 | 绍兴市柯桥区东纺纺织产业创新研究院 | Preparation method of low-odor glass fiber reinforced polypropylene wood-plastic composite material |
CN114249946B (en) * | 2021-12-07 | 2023-11-14 | 西华大学 | Preparation method of ultralow VOC polypropylene-based automobile special material |
CN114133664A (en) * | 2021-12-07 | 2022-03-04 | 西华大学 | Superfine slag micro powder filled polypropylene-based automobile special material and preparation method thereof |
JP2023162008A (en) * | 2022-04-26 | 2023-11-08 | 株式会社イノアックコーポレーション | Resin composition and automotive member |
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CN109749247B (en) | 2022-04-29 |
JP6676033B2 (en) | 2020-04-08 |
KR20190049214A (en) | 2019-05-09 |
EP3480249A1 (en) | 2019-05-08 |
KR102463607B1 (en) | 2022-11-03 |
CN109749247A (en) | 2019-05-14 |
JP2019085547A (en) | 2019-06-06 |
US10472508B2 (en) | 2019-11-12 |
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