US20140360583A1 - Solar module and method of manufacturing the same - Google Patents

Solar module and method of manufacturing the same Download PDF

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Publication number
US20140360583A1
US20140360583A1 US14/469,758 US201414469758A US2014360583A1 US 20140360583 A1 US20140360583 A1 US 20140360583A1 US 201414469758 A US201414469758 A US 201414469758A US 2014360583 A1 US2014360583 A1 US 2014360583A1
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US
United States
Prior art keywords
resin sheet
encapsulant
solar module
colored
solar cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/469,758
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English (en)
Inventor
Masanori Maeda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Corp
Panasonic Intellectual Property Management Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd filed Critical Sanyo Electric Co Ltd
Assigned to SANYO ELECTRIC CO., LTD. reassignment SANYO ELECTRIC CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MAEDA, MASANORI
Publication of US20140360583A1 publication Critical patent/US20140360583A1/en
Assigned to PANASONIC CORPORATION reassignment PANASONIC CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SANYO ELECTRIC CO., LTD.
Assigned to PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. reassignment PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PANASONIC CORPORATION
Priority to US16/226,634 priority Critical patent/US11049987B2/en
Abandoned legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10614—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising particles for purposes other than dyeing
    • B32B17/10623—Whitening agents reflecting visible light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy

Definitions

  • the invention relates to a solar module and a method of manufacturing the same.
  • Patent Document 1 proposes use of a white resin sheet as a resin sheet for forming an encapsulant for a solar module.
  • Using the white resin sheet to form a portion of the encapsulant located on the side of a rear surface of a solar cell may increase incident efficiency of light into the solar cell, thereby improving output characteristics of the solar module.
  • Patent Document 1 Japanese Patent Application Publication No. 2006-332092
  • One aspect of the invention improves output characteristics of a solar module.
  • a laminated body is obtained by arranging a colored resin sheet on one side of a solar cell, and arranging a transparent resin sheet on the other side of the solar cell.
  • a solar module including a colored encapsulant which is located on the one side of the solar cell and formed of the colored resin sheet and a transparent encapsulant, which is located on the other side of the solar cell and formed of the transparent resin sheet, is fabricated by pressurizing the laminated body while heating the laminated body to such a temperature that a storage elastic modulus of the transparent resin sheet is higher than a storage elastic modulus of the colored resin sheet.
  • a solar module includes an encapsulant and solar cells.
  • the solar cells are arranged in the encapsulant.
  • the encapsulant includes a colored encapsulant and a transparent encapsulant.
  • the colored encapsulant is on one side of the solar cells.
  • the transparent encapsulant is located on the other side of the solar cells.
  • An interface between the colored encapsulant and the transparent encapsulant is located more on the one side than a main surface of the other side of the solar cells and located more on the other side than a center in a thickness direction of the solar cells.
  • the embodiments above improve output characteristics of a solar module.
  • FIG. 1 is a schematic exploded cross-sectional view of a laminated body in an embodiment.
  • FIG. 2 is a schematic cross-sectional view of a solar module in an embodiment.
  • FIG. 3 is a schematic cross-sectional view of a solar module in a reference example.
  • solar module 1 When solar module 1 is manufactured, first, laminated body 20 as shown in FIG. 1 is fabricated. Specifically, first, solar cells 12 are prepared. Only one solar cell 12 may be prepared. Alternatively, at least one solar cell string 15 including a plurality of solar cells 12 connected by wiring materials 14 may be prepared. Here, an example of preparing solar cell string 15 including a plurality of solar cells 12 which are electrically connected by wiring materials 14 is described.
  • Solar cell 12 has light-receiving surface 12 a and rear surface 12 b .
  • light-receiving surface 12 a refers to a main surface which mainly receives light
  • other main surface constitutes rear surface 12 b .
  • an electrode provided on rear surface 12 b has a larger area than an electrode provided on light-receiving surface 12 a.
  • laminated body 20 is fabricated by lamination of first protective material 10 , transparent resin sheet 16 , a plurality of solar cells 12 , colored resin sheet 17 , and second protective material 11 in this order.
  • colored resin sheet 17 is arranged on the side of rear surfaces 12 b of a plurality of solar cells 12 .
  • Transparent resin sheet 16 is arranged on the side of light-receiving surfaces 12 a of a plurality of solar cells 12 .
  • First protective material 10 is a material configured to protect the side of light-receiving surfaces 12 a of solar cells 12 .
  • First protective material 10 has translucency.
  • First protective material 10 is made of glass and the like, for example.
  • Second protective material 11 is a material configured to protect the side of rear surfaces 12 b of solar cells 12 .
  • second protective material 11 may include a resin sheet or a resin sheet including a reflection layer made of a metal, and the like.
  • Transparent resin sheet 16 is arranged on light-receiving surfaces 12 a of solar cells 12 .
  • the “transparent resin sheet” is a resin sheet which contains substantially no pigment or dye and transmits incident light.
  • Colored resin sheet 17 is arranged on rear surfaces 12 b of solar cells 12 .
  • a “colored resin sheet” is a resin sheet, which includes a pigment or a dye.
  • Colored resin sheet 17 preferably contains a white pigment made of titania and the like, for example.
  • Thicknesses of transparent resin sheet 16 and of colored resin sheet 17 are not limited, respectively. Thickness of transparent resin sheet 16 may be the same as or different from that of colored resin sheet 17 . Thicknesses of transparent resin sheet 16 and colored resin sheet 17 can be approximately 300 ⁇ m to 600 ⁇ m, respectively.
  • a lamination process in which laminated body 20 is laminated by pressurization while being heated is performed.
  • the heating temperature of laminated body 20 in the lamination process can be approximately 50° C. to 150° C., for example.
  • Pressure to be applied to laminated body 20 in the lamination process can be approximately 50 kPa to 100 kPa, for example.
  • Solar module 1 includes solar cells 12 .
  • solar module 1 is provided with solar cell string 15 including a plurality of solar cells 12 which are electrically connected by wiring materials 14 .
  • a plurality of solar cells 12 are arranged in encapsulant 13 which is arranged between first protective material 10 and second protective material 11 .
  • Encapsulant 13 has colored encapsulant 13 a and transparent encapsulant 13 b .
  • Colored encapsulant 13 a is arranged between second protective material 11 and rear surfaces 12 b of solar cells 12 .
  • Colored encapsulant 13 a is formed of colored resin sheet 17 .
  • colored encapsulant 13 a includes a pigment or a dye.
  • Transparent encapsulant 13 b is arranged between light-receiving surfaces 12 a of solar cells 12 and first protective material 10 .
  • Transparent encapsulant 13 b is formed of transparent resin sheet 16 .
  • On second protective material 11 maybe provided a terminal box to which wiring materials, electrically connected to a plurality of solar cells 12 , are electrically connected.
  • a frame may be provided outside of solar module 1 .
  • a resin sheet to be arranged on the side of a light-receiving surface of a solar cell and a resin sheet to be arranged on a rear surface are made of a same resin material.
  • a resin sheet formed of an ethylene vinyl acetate copolymer containing a pigment such as titania is arranged on the side of the rear surface of the solar cell, while a resin sheet formed of an ethylene vinyl acetate copolymer containing no pigment is arranged on the side of the light-receiving surface of the solar cell.
  • a resin sheet, a storage elastic modulus of which at the heating temperature of laminated body 20 in the lamination process is higher than colored resin sheet 17 is used as transparent resin sheet 16 . That is to say, at the heating temperature of laminated body 20 in the lamination process, the storage elastic modulus of transparent resin sheet 16 is higher than the storage elastic modulus of colored resin sheet 17 .
  • an interface between colored resin sheet 17 and transparent resin sheet 16 is located more on the side of the rear surface than light-receiving surfaces 12 a of solar cells 12 and located more on the side of light-receiving surfaces 12 a than a center in a thickness direction of solar cells 12 . Therefore, a part of colored resin sheet 17 can be effectively inhibited from coming around above light-receiving surfaces 12 a of solar cells 12 in the lamination process. Hence, it becomes possible to manufacture solar module 1 having improved output characteristics.
  • the interface between colored resin sheet 17 and transparent resin sheet 16 is located more on the side of light-receiving surfaces 12 a than the center in the thickness direction of solar cells 12 .
  • the efficiency of collecting light to light-receiving surfaces 12 a of solar cells 12 can be increased. Accordingly, further improved output characteristics can be obtained.
  • a method of making the storage elastic modulus of transparent resin sheet 16 at the heating temperature of laminated body 20 in the lamination process higher than the storage elastic modulus of colored resin sheet 17 at the heating temperature of laminated body 20 in the lamination process is not limited, in particular.
  • a resin sheet containing cross-linked resin made of an ethylene vinyl acetate copolymer (EVA) and the like is used as colored resin sheet 17
  • a resin sheet containing non-cross-linked resin made of a polyolefin such as polyethylene or polypropylene and the like maybe used as transparent resin sheet 16 .
  • colored encapsulant 13 a contains cross-linked resin
  • transparent resin sheet 16 contains non-cross-linked resin.
  • Cross-linked resin may have a gel fraction of 50% or higher.
  • Non-cross-linked resin may have the gel fraction of less than 50%.
  • a “gel fraction” shall be measured with the following measuring method.
  • One gram of resin to be measured is prepared. The resin is immersed in 100 ml of xylene at 120° C. for 24 hours. Then, residues are removed from xylene and dried at 80° C. for 16 hours. Then, mass of the residues after being dried is measured. From an obtained result, the gel fraction (%) is calculated based on the following expression (1).
  • the storage elastic modulus of transparent resin sheet 16 at the heating temperature of the laminated body 20 in the lamination process is preferably set to 1.5 times and more preferably set to 3.0 times higher than the storage elastic modulus of colored resin sheet 17 at the heating temperature of the laminated body 20 in the lamination process.
  • the storage elastic modulus of transparent resin sheet 16 at the heating temperature of laminated body 20 in the lamination process is too high, solar cells 12 may break up. Therefore, it is preferable that the storage elastic modulus of transparent resin sheet 16 at the heating temperature of laminated body 20 in the lamination process is equal to or less than 1 ⁇ 10 6 Pa.
  • the storage elastic modulus of colored resin sheet 17 at the heating temperature of laminated body 20 in the lamination process is preferably equal to or less than 5 ⁇ 10 5 Pa, more preferably, equal to or less than 3 ⁇ 10 5 Pa, and even more preferably, equal to or less than 1 ⁇ 10 5 Pa. It is preferable that the storage elastic modulus of transparent resin sheet 16 at the heating temperature of laminated body 20 in the lamination process is 8 ⁇ 10 6 Pa to 5 ⁇ 10 6 Pa.
  • the storage elastic modulus of transparent resin sheet 16 may be higher than the storage elastic modulus of colored resin sheet 17 , only at the heating temperature of laminated body 20 in the lamination process.
  • the storage elastic modulus of transparent resin sheet 16 maybe higher than the storage elastic modulus of colored resin sheet 17 not only at the heating temperature of laminated body 20 in the lamination process but also at any temperature which is lower than the heating temperature of laminated body 20 .
  • a solar cell may be a rear junction solar cell having a first electrode and a second electrode on the side of a rear surface.
  • a solar module may be provided with one solar cell.
  • the invention includes a variety of embodiments which are not described herein. Therefore, a technological scope of the invention shall be defined only by the invention specific matters according to the claims which are reasonable from the above description.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Photovoltaic Devices (AREA)
US14/469,758 2012-03-09 2014-08-27 Solar module and method of manufacturing the same Abandoned US20140360583A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US16/226,634 US11049987B2 (en) 2012-03-09 2018-12-20 Solar module and method of manufacturing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2012/056150 WO2013132654A1 (ja) 2012-03-09 2012-03-09 太陽電池モジュール及びその製造方法

Related Parent Applications (1)

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PCT/JP2012/056150 Continuation WO2013132654A1 (ja) 2012-03-09 2012-03-09 太陽電池モジュール及びその製造方法

Related Child Applications (1)

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US16/226,634 Continuation US11049987B2 (en) 2012-03-09 2018-12-20 Solar module and method of manufacturing the same

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US20140360583A1 true US20140360583A1 (en) 2014-12-11

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US14/469,758 Abandoned US20140360583A1 (en) 2012-03-09 2014-08-27 Solar module and method of manufacturing the same
US16/226,634 Active 2032-10-23 US11049987B2 (en) 2012-03-09 2018-12-20 Solar module and method of manufacturing the same

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Country Status (5)

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US (2) US20140360583A1 (de)
EP (1) EP2824715B1 (de)
JP (1) JP6112426B2 (de)
CN (1) CN104160515B (de)
WO (1) WO2013132654A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10629763B2 (en) 2016-03-31 2020-04-21 Panasonic Intellectual Property Management Co., Ltd. Solar cell module
EP3716344A1 (de) * 2019-03-27 2020-09-30 Panasonic Corporation Herstellungsverfahren eines solarzellenmoduls

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015053314A1 (ja) * 2013-10-10 2015-04-16 三井化学株式会社 太陽電池封止用シートセットおよび太陽電池モジュール
JPWO2017134784A1 (ja) * 2016-02-03 2018-04-12 三菱電機株式会社 太陽電池モジュール及びその製造方法

Citations (4)

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US6066796A (en) * 1997-02-14 2000-05-23 Canon Kabushiki Kaisha Solar cell module
US20040229404A1 (en) * 1998-02-27 2004-11-18 Canon Kabushiki Kaisha Semiconductor encapsulant resin having an additive with a gradient concentration
US20050051204A1 (en) * 2003-09-10 2005-03-10 Kasumi Oi Encapsulant layer for photovoltaic module, photovoltaic module and method for manufacturing regenerated photovoltaic cell and regenerated transparent front face substrate
US20120055539A1 (en) * 2011-09-05 2012-03-08 Taeyoon Kim Solar cell module

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JP3323560B2 (ja) * 1992-12-10 2002-09-09 株式会社ブリヂストン 太陽電池封止材膜
JP4467222B2 (ja) * 2002-02-27 2010-05-26 株式会社ブリヂストン 太陽電池
JP2005050928A (ja) * 2003-07-30 2005-02-24 Kyocera Corp 太陽電池モジュールおよび太陽電池モジュールの製造方法ならびに太陽電池モジュールの設置構造
JP4784152B2 (ja) 2005-05-23 2011-10-05 凸版印刷株式会社 太陽電池モジュール
US20080053516A1 (en) * 2006-08-30 2008-03-06 Richard Allen Hayes Solar cell modules comprising poly(allyl amine) and poly (vinyl amine)-primed polyester films
ES2602652T3 (es) * 2009-06-05 2017-02-21 Bridgestone Corporation Película sellante para célula solar, y célula solar que utiliza la misma
JP2011159711A (ja) * 2010-01-29 2011-08-18 Sanyo Electric Co Ltd 太陽電池モジュール
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JP2011216804A (ja) * 2010-04-02 2011-10-27 Bridgestone Corp 太陽電池用封止膜、これを用いた太陽電池、及び太陽電池の製造方法
JP2012004146A (ja) * 2010-06-14 2012-01-05 Bridgestone Corp 太陽電池用封止膜及びこれを用いた太陽電池
KR102011615B1 (ko) * 2010-07-28 2019-08-16 다이니폰 인사츠 가부시키가이샤 태양 전지 봉지재 및 그것을 이용하여 제작된 태양 전지 모듈
CA2809765A1 (en) * 2010-08-31 2012-03-08 Mitsubishi Plastics, Inc. Solar battery cover film for and solar battery module manufactured using same

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Publication number Priority date Publication date Assignee Title
US6066796A (en) * 1997-02-14 2000-05-23 Canon Kabushiki Kaisha Solar cell module
US20040229404A1 (en) * 1998-02-27 2004-11-18 Canon Kabushiki Kaisha Semiconductor encapsulant resin having an additive with a gradient concentration
US20050051204A1 (en) * 2003-09-10 2005-03-10 Kasumi Oi Encapsulant layer for photovoltaic module, photovoltaic module and method for manufacturing regenerated photovoltaic cell and regenerated transparent front face substrate
US20120055539A1 (en) * 2011-09-05 2012-03-08 Taeyoon Kim Solar cell module

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10629763B2 (en) 2016-03-31 2020-04-21 Panasonic Intellectual Property Management Co., Ltd. Solar cell module
EP3716344A1 (de) * 2019-03-27 2020-09-30 Panasonic Corporation Herstellungsverfahren eines solarzellenmoduls

Also Published As

Publication number Publication date
EP2824715A1 (de) 2015-01-14
US11049987B2 (en) 2021-06-29
JP6112426B2 (ja) 2017-04-12
CN104160515A (zh) 2014-11-19
WO2013132654A1 (ja) 2013-09-12
US20190123227A1 (en) 2019-04-25
EP2824715B1 (de) 2019-12-18
JPWO2013132654A1 (ja) 2015-07-30
EP2824715A4 (de) 2015-10-07
CN104160515B (zh) 2016-10-12

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