US20130280412A1 - Flame treatment of a substrate - Google Patents

Flame treatment of a substrate Download PDF

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Publication number
US20130280412A1
US20130280412A1 US13/977,449 US201113977449A US2013280412A1 US 20130280412 A1 US20130280412 A1 US 20130280412A1 US 201113977449 A US201113977449 A US 201113977449A US 2013280412 A1 US2013280412 A1 US 2013280412A1
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US
United States
Prior art keywords
flame
radical emission
substrate
camera
burner
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US13/977,449
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English (en)
Inventor
Anders Sandstrom
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tetra Laval Holdings and Finance SA
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Tetra Laval Holdings and Finance SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tetra Laval Holdings and Finance SA filed Critical Tetra Laval Holdings and Finance SA
Assigned to TETRA LAVAL HOLDINGS & FINANCE S.A. reassignment TETRA LAVAL HOLDINGS & FINANCE S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SANDSTROM, ANDERS
Publication of US20130280412A1 publication Critical patent/US20130280412A1/en
Abandoned legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23N—REGULATING OR CONTROLLING COMBUSTION
    • F23N5/00—Systems for controlling combustion
    • F23N5/003—Systems for controlling combustion using detectors sensitive to combustion gas properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/08—Surface shaping of articles, e.g. embossing; Apparatus therefor by flame treatment ; using hot gases
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23N—REGULATING OR CONTROLLING COMBUSTION
    • F23N5/00—Systems for controlling combustion
    • F23N5/02—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium
    • F23N5/08—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using light-sensitive elements
    • F23N5/082—Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium using light-sensitive elements using electronic means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23N—REGULATING OR CONTROLLING COMBUSTION
    • F23N2229/00—Flame sensors
    • F23N2229/20—Camera viewing

Definitions

  • the invention generally relates to the field of treatment of a substrate such as a paper, paperboard or carton with a flame.
  • the present invention relates to flame treatment of a substrate, such as a paper, paperboard or carton.
  • the substrate is flame treated in order to oxidize its surface to make it more polar.
  • Combustion chemistry involves mixing a fuel and oxygen, for example propane and air and provide ignition.
  • the combustion reaction is in fact not only one reaction but many reactions.
  • the flame contains many reactive species, such as hydroxyl radicals, carbonyl radicals, carboxyl radicals, oxygen atoms and ions etc.
  • the reactive species are used to increase the surface energy of the substrate and improve adhesion.
  • the flame also heats and dries the substrate, which also can improve adhesion to a plastic material. There are many factors affecting the result, for example the mixture of the fuel and air (oxygen).
  • the flame treatment device contains an analyzer controlling the mixture of air and fuel.
  • the mixture of air and fuel is important to obtain a flame having repeatable characteristics which is desired in order to obtain a uniform treatment of the substrate.
  • the substrate should be located on a suitable distance from the flame in order to obtain the desired treatment.
  • FIG. 1 is a schematic view of a flame (2) emanating from a burner (1).
  • the flame may be defined as comprising two parts, an outer part (2) and an inner part (3).
  • the temperature of the flame is not consistent throughout the flame and normally the edge of the inner part (3) is considered having the highest temperature.
  • the substrate (5) should be arranged to obtain sufficient treatment, where sufficient is when positional relationship between the flame and the substrate remains within pre-determined limits (6).
  • One object of the present invention to control the flame treatment of a substrate.
  • One object is to arrange a substrate suitable for flame treatment in in order to obtain sufficient treatment of the substrate.
  • One object is to provide sufficient treatment in a continuos process, i.e. where the substrate is a continuously moving web-shaped material, such as a paper web, carton web or a paperboard web.
  • Objects of the present invention are achieved by a method for optimizing adhesion by controlling flame treatment of a substrate, in which treatment a flame emanating from a burner is applied to a substrate, said method comprising controlling the mass flow of fuel and air fed to the burner, acquiring radical emission data by monitoring radical emission emanating from the flame using a flame analyzer, processing the radical emission data, comparing the thus acquired radical emission data with radical emission data from a database, and outputting the result of the comparison.
  • One object is achieved by the above mentioned method and wherein an error signal is generate when the acquired radical emission data deviate from the radical emission data in the database.
  • One object is achieved by further comprising adjusting at least one of the mass flow of fuel and/or air fed to the burner, a relative angle between the burner and the substrate, and the distance between the burner and the substrate when the acquired radical emission data deviate from the radical emission data in the database.
  • One object of the present invention is achieved by a system for controlling flame treatment of a substrate, said system comprising a burner, a flame analyzer comprising a camera and a filter, wherein the flame analyzer is arranged to monitor radical emission emanating from the flame.
  • FIG. 1 is a schematic illustration of a flame.
  • FIG. 2 is a schematic illustration of the system of the invention.
  • any fuel and mixture of different compatible fuels may be used, non-limiting examples thereof are natural gas, liquid petroleum gas (LPG) and methane.
  • the fuel mixture is normally a mixture between one or more fuel(s) and oxygen.
  • Air is often used as the oxygen source and the air-fuel ratio is often expressed as percent excess combustion air.
  • excess combustion air of 15 percent means that 15 percent more than the required stoichiometric air is being used.
  • the excess oxygen is normally within about ⁇ 5% to about +5%.
  • the gas flow is generally within 5-50 m 3 .
  • Other parameters affecting the treatment of the substrate are the distance between the burner and the substrate; as well as the angle between the burner and the substrate. According to the present invention the angle between the burner and the substrate is normally about 90°. The angle may however be anywhere within the interval 60-120°.
  • the invention relates to a method for controlling flame treatment of a substrate, in which treatment a flame emanating from a burner is applied to a substrate, said method comprising controlling the mass flow of fuel and air fed to the burner, monitoring radical emission from the flame using a flame analyzer, wherein the positional relationship between a portion of the flame and the substrate may be deduced.
  • the invention relates to a system for controlling flame treatment of a substrate, said system comprising a burner, a flame analyzer comprising a camera and a filter, wherein the flame analyzer is arranged to monitor radical emission emanated by the flame.
  • limits for the radical emission data is determined by measuring the radical emission from the flame (i.e. intensity) and comparing the emission with the treatment obtained, i.e if acceptable adhesion and/or surface tension is obtain. It is thus possible to determine the lower and upper limit of the radical emission where an acceptable substrate treatment is obtained.
  • One way of determining the radical emission limits is by a design of experiment (DoE) approach having surface tension and adhesion as substrate response. The experiment includes varying the gas flow, air/gas mixture and the distance between the burner and the substrate. The experiment results in determining upper and lower limits where acceptable treatment of the substrate is obtain.
  • DoE design of experiment
  • the obtained limits are used to create a database which is used to compare the acquired radical emission data with radical emission data from a database, and by measuring the radical emission and comparing with the database acceptable substrate treatment can be obtained.
  • the acquired radical emission data which for example relates to the intensity of the radicals at a position of the flame is compared to values in a database and when an unacceptable deviation is obtained this is outputted in order for an operator to take action.
  • an additional step adjusting at least one of the following: the mass flow of fuel and/or air fed to the burner, a relative angle between the burner and the substrate, and the distance between the burner and the substrate is per performed.
  • an unacceptable deviation is a deviation of about more than 20% such as more than 10%, such as more than 5% such as more than 1%.
  • the radical emission is a measurement of the concentration of the radicals in the flame and the limits thus relates to concentrations of radicals where acceptable treatment of the substrate is obtained.
  • the radical is selected from hydroxyl radical the maximum hydroxyl radical intensity occurs near the location of maximum flame temperature.
  • Hydroxyl radicals are thus suitably used within the present invention and as discussed below the concentration of hydroxyl radicals (OH radicals) are suitably measured at about 310 nm, where interference of other radicals are within acceptable level. It is also possible to obtain an acceptance equation defining the shape and profile of the radical emission emanating from the flame. It has thus been discovered that the hydroxyl radical have an impact on the level of surface oxidation of the treated substrate.
  • the radical emission may be monitored over the whole flame or over selected portions of the flame.
  • One example is to measure the radical emission intensity close to the substrate or even including the part where the flame hits the substrate. Monitoring also the part where the flame hits the substrate could be beneficial as it will allow improved monitoring of the edges of the substrate.
  • the flame analyzer may analyze only part of the obtained information.
  • One embodiment of the present invention relates to monitoring one or more, such as two, three or four radical emissions.
  • the emission of hydroxyl radicals could be combined with monitoring CN radical emission and/or CH radical emission.
  • the system of the invention was used to imaging flame characteristics during testing of different settings of the flame treatment parameters. From these measurements, flame characteristics resulting in surface tension and/or adhesion between the substrate and a plastic film or material extruded to the substrate was correlated to be within the specification set for surface tension or adhesion.
  • Measuring the emission of radicals made it possible to correlate what level of radical emission that would lead to acceptable adhesion or surface tesion between the substrate and the film or material extruded on the substrate. Based on the determination it was possible to set the limits for the radical emission.
  • Adhesion between the substrate and the film or material extruded on the substrate is normally determined by the tape test or by using test equipment such a those marketed by Instron®. The adhesion tests are those conventionally used and sufficient adhesion is within the capability of the skilled person to determine for example by using the tape test.
  • the measurement using the Instron® equipment is performed according to ISO8510-2 using 180°, speed 50 mm/min and sample width of 15 mm. Sufficient treatment is considered to be above 10 N/m, such as above 30N/m.
  • a flame analyzer which in one embodiment at least comprises a camera, for example a camera having at least one image sensor that detects light in the ultraviolet (UV) range, such as a charge coupled device (CCD) camera.
  • a camera for example a camera having at least one image sensor that detects light in the ultraviolet (UV) range, such as a charge coupled device (CCD) camera.
  • UV ultraviolet
  • CCD charge coupled device
  • Suitable cameras are marketed as Princeton Instruments I-Max camera, SVS-Vistek camera, AVT-Stingray camera and AVT-Prosilca camera, equipped with a CCD UV-sensor.
  • the camera may if necessary also be equipped with one or more filter(s) allowing only light of certain wavelengths to pass.
  • Emission from radicals typically resides in narrow wavelength regions, and thus it may be possible to select a specific radical by use of a suitable filter in front of the detector.
  • Suitable filters for this purpose are bandpass filters, transmitting emission in a narrow wavelength region.
  • Bandpass filters are defined by their “central wavelength”, corresponding to the centre of the transmission interval or the wavelength of the maximum transmittance, and by their “bandpass region” corresponding to the width of the transmission interval.
  • the property “Full Width at Half Maximum” (FWHM) is well established and may also be used for quantification of the bandpass region.
  • radicals emit in the range 330-340 nm and a suitable filter is Asahi XBPA340, having a maximum transmittance at about 340 nm and the full FWHM is 10 nm; OH radicals emit in the range 281-343 nm and a suitable filter is Asahi XBPA310, having a maximum transmittance at about 310 nm and the FWHM is 10 nm; CN radicals emit in the range 380-390 nm and a suitable filter is Asahi XBPA390, having a maximum transmittance at about 390 nm and the FWHM is 10 nm; C2 radicals emit in the range 470-564 nm and a suitable filter is Asahi
  • the filter preferably has ⁇ max at 310 ⁇ 5 nm, for example the Asahi XBPA310, having a maximum transmittance at about 310 nm and the FWHM is 10 nm being suitably used.
  • the flame analyzer comprises the above mention camera and a filter and a processing unit.
  • the processing unit analyzes the images obtained by the camera and generates alarm and/or control signals.
  • the camera may either take an image over the whole flame treatment area or the camera makes an image over one part of the flame treatment area followed by an image of a subsequent part of the flame treatment area until images over the complete area are obtained. It is also possible to have the camera focusing on one area of the flame treatment area (i.e. a specific portion of the flame) only but in certain aspects it is preferred to use the complete flame treatment area (i.e. assemble the individual images take to get an image of the whole flame).
  • the camera is preferably taking many images per time unit, such as between 2-200 images during the period of 1-10 s.
  • the burner from where a flame emanates may be any suitable burner but it is preferred that the burner is of a dimension correlated to the substrate it is to treat, i.e. the width of the web substrate corresponds to the width of the flame. It is also possible according to the present invention to use a burner emanating one or more flame(s).
  • the flame may be of any type but typically flames considered as a longer type are used. It is however also possible to use flames of a shorter type, such as up to about 10 mm. It is also possible to use one or more flames, originating from one or more burner(s), i.e. stacked flames. In certain aspects stacked flames are beneficial as the treatment is performed over a bigger area at the same time and using stacked flames may improve the treatment.
  • the width of the flame is about the same as the width of the web-shaped substrate that is being treated.
  • the processing unit may be used to evaluate many effects of the radical emission; some examples are fluctuation of flame, i.e. pulsing over time, evenness of flame, i.e. the flame consistency over the flame treatment area, flame shape and burner position.
  • the processing unit is thus using image analysis to determine if the radical emission is within the limits.
  • the intensity distribution of one or more image(s) in the flame direction is compared to a predefined curve.
  • the flame analyzer may generate an alarm when one or more of the pre-determined criterias are outside the limits.
  • the alarm may be an absolute or relative alarm.
  • An absolute alarm is when one or more of the pre-determined criterias are not fulfilled.
  • a relative alarm is for example when the intensity of the radical emission is reduced over time and an alarm generated. Alternatively a relative alarm may be generated when there are unacceptable differences over the treatment area.
  • the alarm may be generates as any suitable type of alarm.
  • the flame analyzer generates a signal instead of or complementary to the alarm.
  • the signal is send to an appropriate device that is used to alter the criterias of the radical emission.
  • Examples of such devices are devices adjusting the fuel mixture and/or the rate of gas flow rate.
  • Other examples are devices adjusting the angle between the burner and the substrate, preferably by tilting the burner; and devices adjusting the distance between the burner and the substrate, preferably by adjusting the burner.
  • the flame analyzer generates a signal and optionally an alarm to a device adjusting the distance between the burner and the substrate. In one embodiment the flame analyzer generates an alarm only and the distance between the burner and the substrate is adjusted manually. The adjustment, manual or automatic, should be such that an acceptable radical emission, determined by the flame analyzer, is obtained after the adjustment; or the adjustment procedure is repeated until the radical emission is within the limits.
  • the flame analyzer further comprises an output device for displaying information about the system.
  • information Non-limiting examples of information that may be displayed on the output device are images, alarms, control signals and the overall status of the system.
  • the substrate of the invention is in one embodiment paper, paperboard or carton, for example a web-shaped paper, paperboard or carton.
  • the substrate is a plastic film, for example a multi-layered film or a stretched film such as an oriented film, e.g. a mono- or biaxially oriented film, e.g. a BOPP film.
  • a plastic film for example a multi-layered film or a stretched film such as an oriented film, e.g. a mono- or biaxially oriented film, e.g. a BOPP film.
  • the invention as defined herein and in the accompanying claims generally improves the safety for the operator as the manual adjustment of the distance between the burner and the substrate does not require visual inspection of the flame. The flame may thus be hidden for the operator.
  • the invention improves the process control treating a substrate by a flame.
  • the control is improved and thus adhesion between substrate and a further material extruded onto the substrate may be improved and optimized.
  • the invention also provides a method for controlling the settings of flame treatment according to a pre-determined specification, and facilitating the control thereof.
  • the invention also ensure that performance settings are consistent between different manufacturing cites and thus improving the control and the specification of the final material, wherever produced.
  • the invention enables sufficient adhesion over substantially the whole surface of the substrate.
  • the present invention relates to treatment of paper, paperboard or carton used in a lamination process, such as an extrusion lamination process, for preparing a material suitable for preparing a package.
  • Said package being used in food and dairy filling equipment, such as aseptic packaging.
  • the present invention is used in the converting line where a paper, or paperboard or carton is laminated to a packaging laminate used in packaging containers of the single use disposable type for liquid foods.
  • a packaging laminate used in packaging containers of the single use disposable type for liquid foods.
  • One such commonly occurring packaging container is marketed under the trademark Tetra Brik Aseptic® and is principally employed for aseptic packaging of liquid foods such as milk, fruit juices etc, sold for long term ambient storage.
  • FIG. 2 a schematic illustration of the system of the invention is disclosed.
  • the system discloses a burner (1) from which a flame (2) emanates.
  • the flame hits a substrate (3) to be treated.
  • the substrate (3) is arranged within a variable distance from the substrate (1).
  • the distance (4) is obtained by monitoring radical emission from the flame (2) by a a flame analyzer which in FIG. 2 comprises a camera (5) having a filter (6) and a processing unit (7), such as a computer, said processing unit (7) may be integrated with the camera or a separate unit.
  • the processing unit (7) use the information received by the flame analyzer to determine if the radical emission is within pre-determined limits.
  • the flame analyzer may also comprise an output device (8), for example a monitor or a printer.
  • the flame analyzer is arranged to monitor (9) at least part of the flame.
  • the limits may be used to generate an alarm in order to discard substrate that has not been sufficiently treated.
  • the distance (4) between the substrate (3) and the burner (1) may be adjusted, manually or automatically until the radical emission is within the limits. Such adjustment allows the substrate to be sufficiently treated.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Recrystallisation Techniques (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Drying Of Semiconductors (AREA)
  • Control Of Combustion (AREA)
  • Investigating Materials By The Use Of Optical Means Adapted For Particular Applications (AREA)
  • Photometry And Measurement Of Optical Pulse Characteristics (AREA)
US13/977,449 2010-12-29 2011-12-22 Flame treatment of a substrate Abandoned US20130280412A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE1001236 2010-12-29
SE1001236-7 2010-12-29
PCT/EP2011/073761 WO2012089611A2 (en) 2010-12-29 2011-12-22 Flame treatment of a substrate

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US20130280412A1 true US20130280412A1 (en) 2013-10-24

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US (1) US20130280412A1 (es)
EP (1) EP2659065B1 (es)
JP (1) JP5996551B2 (es)
CN (1) CN103237941A (es)
BR (1) BR112013013578A2 (es)
MX (1) MX341340B (es)
RU (1) RU2582135C2 (es)
WO (1) WO2012089611A2 (es)
ZA (1) ZA201304628B (es)

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US10751752B2 (en) * 2016-10-13 2020-08-25 Permasteelisa North America Corp. Method of increasing surface adhesion of an architectural metal finish

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DE102013225669A1 (de) 2013-12-11 2015-06-11 China Triumph International Engineering Co., Ltd. Verfahren zur Herstellung eines Halbzeugs für Dünnschichtsolarzellen
JP2017028114A (ja) * 2015-07-23 2017-02-02 パナソニックＩｐマネジメント株式会社 光検出器、光検出装置、固体撮像装置およびカメラシステム
KR101743670B1 (ko) * 2015-10-15 2017-06-08 한국생산기술연구원 광학필터와 촬상장치를 이용한 화염 감시 및 구조계측 시스템 및 이에 의한 화염 감시 및 구조계측 방법
JP6948678B1 (ja) * 2020-11-16 2021-10-13 東京瓦斯株式会社 空気比調整方法、空気比調整システム及びプログラム
JP6948679B1 (ja) * 2020-11-16 2021-10-13 東京瓦斯株式会社 空気比推定システム、空気比推定方法及びプログラム
JP6996724B1 (ja) 2021-06-18 2022-01-17 東京瓦斯株式会社 情報提供方法、情報提供システム及びプログラム

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WO2012089611A3 (en) 2012-10-11
JP2014504657A (ja) 2014-02-24
EP2659065A2 (en) 2013-11-06
WO2012089611A2 (en) 2012-07-05
JP5996551B2 (ja) 2016-09-21
EP2659065B1 (en) 2016-10-12
RU2013134988A (ru) 2015-02-10
CN103237941A (zh) 2013-08-07
RU2582135C2 (ru) 2016-04-20
BR112013013578A2 (pt) 2016-09-06
MX341340B (es) 2016-08-17
MX2013007312A (es) 2013-07-29
ZA201304628B (en) 2014-08-27

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