US20130270155A1 - Process for desulfurization of diesel with reduced hydrogen consumption - Google Patents

Process for desulfurization of diesel with reduced hydrogen consumption Download PDF

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Publication number
US20130270155A1
US20130270155A1 US13/988,305 US201113988305A US2013270155A1 US 20130270155 A1 US20130270155 A1 US 20130270155A1 US 201113988305 A US201113988305 A US 201113988305A US 2013270155 A1 US2013270155 A1 US 2013270155A1
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United States
Prior art keywords
sulfur
ppm
diesel
hydrogen
adsorbent
Prior art date
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Abandoned
Application number
US13/988,305
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English (en)
Inventor
Sarvesh Kumar
Alok Sharma
Brijesh Kumar
Santanam Rajagopal
Ravinder Kumar Malhotra
Anand Kumar
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Indian Oil Corp Ltd
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Indian Oil Corp Ltd
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Publication date
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Assigned to INDIAN OIL CORPORATION LIMITED reassignment INDIAN OIL CORPORATION LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KUMAR, ANAND, KUMAR, BRIJESH, KUMAR, SARVESH, MALHOTRA, RAVINDER KUMAR, RAJAGOPAL, SANTANAM, SHARMA, ALOK
Publication of US20130270155A1 publication Critical patent/US20130270155A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including a sorption process as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Definitions

  • the present invention relates to desulfurization of diesel and in particular to a novel process for deep desulfurization of diesel with reduced hydrogen consumption. More particularly the subject invention pertains to an integrated process comprising diesel hydro de-sulfurisation (DHDS) or diesel hydrotreatment (DHDT) with reduced severity, to desulfurize high sulfur-containing (1-2%) diesel stream to a much lower level of sulfur content of 350-500 ppm in the treated diesel stream, followed by a novel adsorption procedure for effecting deep desulfurization to reduce overall sulfur content to less than 10 ppm with reduced hydrogen consumption, as compared to high severity DHDS or DHDT procedures followed in the prior art.
  • DHDS diesel hydro de-sulfurisation
  • DHDT diesel hydrotreatment
  • the residual sulfur below 500 ppm in diesel is mostly refractory sulfur. Removal of the refractory sulfur of the diesel through conventional hydrotreating requires severe operating conditions like higher pressure, lower ‘Liquid Hourly Space Velocity (LHSV)’, higher consumption of hydrogen, and use of highly active and expensive catalyst systems.
  • LHSV Liquid Hourly Space Velocity
  • the present invention provides a novel process to utilize a reactive adsorbent for reducing refractory sulfur present in diesel from 350-500 ppm to less than 10 ppm.
  • the process developed in the present invention can be utilized in the downstream of existing DHDS/DHDT units.
  • the hydrogen consumption is significantly low, since it is consumed only for saturation of olefinic bond generated by cleavage of the sulfur from the sulfur compounds.
  • the combination will result in reduced hydrogen consumption at refineries.
  • the DHDS procedure employs catalytic hydrogenation to upgrade the quality of diesel so as to conform to the environmental norms by mainly removing sulfur and nitrogen. In addition, this procedure brings about saturation of olefins and aromatic compounds.
  • Catalysts are formulated by combining varying amounts of nickel or cobalt with molybdenum oxides on an aluminium base. Important operating parameters of this procedure are, inter alia, temperature, pressure, nature of catalyst, feed flow rate, feed characteristics, etc.
  • the catalysts used therein are meant for carrying out reaction under less severe/drastic condition and at a faster rate.
  • Diesel contains sulfur compounds such as mercaptans, sulphides, and/or disulphides which are removed as H 2 S, as shown below:
  • US publication US20070261994A1 discloses a method for producing a super-low sulfur gas oil blending component or a super-low sulfur gas oil composition having a sulfur content of less than 5 ppm, under relatively mild conditions, without greatly increasing the hydrogen consumption and without remarkably decreasing the aromatic content.
  • the hydrogen consumption reduction is not clearly specified.
  • the composition of the catalyst used is different.
  • the present invention uses a process of splitting the treated diesel between two fractions, which is not present in this US publication.
  • U.S. Pat. No. 6,551,501B1 discloses a combined process for improved hydrotreating of diesel fuels, in which the feed to be hydrotreated is pretreated with a selective adsorbent prior to the hydrotreating step to remove polar materials, especially nitrogen containing compounds (N-compounds).
  • both the hydrotreatment and adsorption process are used to reduce the sulfur content in the fuel; however, the reduction of sulfur content in two publications is different.
  • the splitting of hydrocarbon and reduction of hydrogen consumption is not mentioned.
  • PCT application WO2008122706A2 discloses an improved method for deep desulphurisation of a gasoil comprising a catalytic hyrodesulphurisation unit preceded by an absorption unit for nitrogen compounds inhibiting the hydrodesulphurisation reaction.
  • the present invention uses either DHDT or DHDS process followed by adsorption process for sulfur removal.
  • the type of catalyst, reduction of hydrogen consumption and reduction of severity are not mentioned in the PCT publication.
  • the present invention provides an integrated process for deep desulfurization of diesel.
  • the integrated process comprises of DHDS or DHDT process which operates with reduced severity and a novel reactive adsorption process. While the DHDS or the DHDT process reduces the sulfur content of the diesel being treated to 350-500 ppm, the adsorption process further reduces the sulfur content to ⁇ 10 ppm.
  • the present invention further provides splitting of treated diesel containing about 350 ppm of refractory sulfur into two cuts viz Initial boiling point (IBP) 140-150° C.-280/300° C. and Final boiling point (FISP) 280/300° C.
  • the 280/300° C.-IBP cut contains preferably less than 20 ppm sulfur and more preferably less than 10 ppm sulfur which can be blended into diesel stream without any further treatment and the 280/300° C.-FBP cut containing about 500-600 ppm of refractory sulfur can be desulfurized using novel adsorption process capable of bringing down sulfur content of diesel to less than 10 ppm.
  • the process in accordance with this invention can be utilized in the downstream of existing DHDS/DHDT units.
  • the present invention shows consumption of hydrogen is significantly low as compared to the prior art, because hydrogen is consumed only for bringing about saturation of olefinic bonds generated by cleavage of sulfur from the sulfur-containing compounds.
  • the present invention discloses a novel process for desulfurization of diesel with reduced hydrogen consumption, which comprises hydrotreating high sulfur-containing diesel stream (1.0-2.0% by wt. of 5) over a NiMo catalyst to reduce sulfur-content to a level of 350-500 ppm, followed by subjecting the treated diesel stream to a novel adsorption procedure to bring down sulfur content to less than 10 ppm.
  • high sulfur diesel stream containing about 1.0-2.0 wt % sulfur can be hydrodesulfurized to a level of 350-500 ppm sulfur product utilizing conventional DHDS or DHDT process with subsequent processing by novel adsorption process to reduce sulfur content below 10 ppm.
  • treated diesel containing about 350 ppm of refractory sulfur is split into two cuts viz. IBP(140-150° C.)-280/300° C. and FBP 280/300° C.
  • The280/300° C.-IBP cut contains preferably less than 20 ppm sulfur and preferably less than 10 ppm sulfur. This cut can be blended into diesel stream without any further treatment.
  • the 280/300° C.-FBP cut containing about 500-600 ppm of refractory sulfur can be desulfurized using novel adsorption process.
  • the adsorption process comprises two numbers of fixed bed reactors, which are being operated in swing mode of adsorption and regeneration.
  • 280/300° C.-FBP cut along with hydrogen is contacted with the adsorbent in down or up flow mode at 350-400° C., 15-30 bar, hydrogen to hydrocarbon ratio of 100-400 Nm 3 /m 3 , liquid hourly space velocity of 0.5-2.0 h ⁇ 1 depending on the sulfur contents of feed.
  • the sulfur compounds are chemically adsorbed on the adsorbent followed by cleavage of the sulfur atom form the sulfur compound.
  • the hydrocarbon molecule of the sulfur compound is released back into the hydrocarbon stream.
  • the presence of hydrogen during the adsorption also prevents deactivation of adsorbent due to coking.
  • the treated diesel contains less than 10 ppm sulfur which can be blended with other cut to produce diesel pool containing less than 10 ppm sulfur. After reaching the breakthrough point, the adsorbent is regenerated at 350-500° C.
  • Regeneration of adsorbent is accomplished in situ by controlled oxidation of the adsorbed carbon and sulfur with lean air followed by activation with hydrogen.
  • the cycle time will vary from 4 to 10 days depending on feed sulfur and boiling range.
  • the adsorbent has higher strength and thermal stability compared to hydrotreating catalyst.
  • the regenerability study for the adsorbent has been conducted in pilot plant for 6 months ( 25 cycles) and there was no loss of activity and physical properties, hence the life of the adsorbent is expected to be similar to that of hydrotreating catalyst systems.
  • Adsorbent The adsorbent used in the process is disclosed in prior art (US 2007/0023325) which is comprised of a base component, a reactive component, and booster.
  • the base component of adsorbent is a porous material, which provides extrudibility and strength. Such materials include alumina, clay, magnesia, titania or a mixture of two or more such materials.
  • the reactive component of the adsorbent is a spinel oxide and prepared through solid-state reaction of the individual metal oxides. This component is responsible for detaching the sulfur atom from the sulfur compounds.
  • the activity booster component of the adsorbent is a bimetallic alloy generated in situ from mixed metal oxides.
  • the present invention also provides a process for regeneration of adsorbent comprises the steps of controlled oxidation of the adsorbed carbon and sulfur with lean air at a temperature ranging between 350° C. and 500° C., and activation with hydrogen wherein the process is carried out in situ.
  • FIG. 1 shows a flow diagram of hydroprocessing micro reactor unit (MRU);
  • FIG. 2 shows GC-SCD chromatograms of 350 and 10 ppm sulfur-product diesel
  • FIG. 3 depicts the integrated process scheme for deep desulfurization of high sulfur diesel feedstock
  • FIG. 4 gives a schematic representation of the novel adsorption procedure.
  • Diesel stream containing 1.53 wt % sulfur was hydrodesulfurized using commercial DHDS and DHDT catalyst system in a hydroprocessing micro-reactor unit (MRU).
  • MRU hydroprocessing micro-reactor unit
  • the process flow diagram of MRU is shown in FIG. 1 .
  • the severity of operating parameters was chosen to get 10-30 ppm sulfur product.
  • the details of feed/ product properties and operating conditions are given in Table-1:
  • Diesel stream containing 1.53 wt % sulfur was hydrodesulfurized using highly active commercial DHDS and DHDT catalyst system in a hydroprocessing micro-reactor unit (MRU). The severity of operating parameters was reduced to get 350 ppm sulfur product.
  • MRU hydroprocessing micro-reactor unit
  • the 350 ppm sulfur product was subsequently treated by novel adsorption process to reduce total sulfur content below 10 ppm.
  • the detailed GC-SCD analysis of 350 and 10 ppm sulfur product diesel is given below in Table-3.
  • the GC-SCD Chromatograms of 350 and 10 ppm sulfur product diesel is given below in FIG. 2 of the drawings.
  • the 350 ppm sulfur product diesel from DHDS or DHDT was split into two cuts viz. IBP to 280° C. and FBP to 280° C.
  • the 280° C. IBP cut contains less than 10 ppm sulfur.
  • the 280° C.-FBP cut containing 530 ppm of refractory sulfur was desulfurized using novel adsorption process to reduce sulfur below 10 ppm. The details of various cuts and final product diesel are given below in Table-4.
  • the liquid product from the separator of DHDS/DHDT is sent to splitter where wild naphtha [150 ( ⁇ )° C. cut] is separated from top of the column, 150-280° C. cut from the middle and 280(+)° C. cut from bottom is separated. Bottom or bottom along with middle cut further deep desulfurized using novel adsorption process to reduce total sulfur content below 10 ppm.
  • the Adsorption process scheme is given in FIG. 4 of the drawings.
  • cetane number of the product is not improved.
  • cetane number specification is same for Euro-III and Euro-IV diesel, the process is particularly suitable as a finishing step for further treatment of Euro-III diesel after DHDS/DHDT.
  • the existing DHDT unit can be operated at lesser severity, just sufficient to meet the cetane requirement, and further sulfur reduction can be achieved by employing the novel adsorption process. This will result in substantial saving of precious hydrogen. From the data (Table-5), it can be observed that by combining novel adsorption process with DHDS or DHDT units saves about 20 to 40% hydrogen consumption respectively.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
US13/988,305 2010-11-19 2011-11-16 Process for desulfurization of diesel with reduced hydrogen consumption Abandoned US20130270155A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN1309KO2010 2010-11-19
IN1309/KOL/2010 2010-11-19
PCT/IN2011/000795 WO2012066574A2 (fr) 2010-11-19 2011-11-16 Procédé de désulfuration de gazole à consommation d'hydrogène réduite

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022011866A1 (fr) * 2020-07-16 2022-01-20 南京延长反应技术研究院有限公司 Système de réaction et procédé d'hydrogénation de diesel
US20220089960A1 (en) * 2020-09-21 2022-03-24 Indian Oil Corporation Limited Process and a system for production of multiple grade de-aromatized solvents from hydrocarbon streams
US11999914B2 (en) * 2020-09-21 2024-06-04 Indian Oil Corporation Limited Process and a system for production of multiple grade de-aromatized solvents from hydrocarbon streams

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030070965A1 (en) * 1999-11-01 2003-04-17 Shih Stuart S. Method for the production of very low sulfur diesel
US20100155302A1 (en) * 2008-12-18 2010-06-24 Kaminsky Mark P Purification of ultralow sulfur diesel fuel

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1057879A3 (fr) 1999-06-02 2001-07-04 Haldor Topsoe A/S Procédé combiné pour l'hydrotraitement de carburants diesel
FR2847587B1 (fr) * 2002-11-25 2006-03-17 Inst Francais Du Petrole Procede de desulfuration, de deazotation et/ou desaromatisation d'une charge hydrocarbonee sur un adsorbant complexant a base d'accepteur d'electrons pi
FR2878252B1 (fr) * 2004-11-23 2008-08-22 Inst Francais Du Petrole Procede de desulfuration d'une coupe hydrocarbonee en lit mobile simule
JP4987485B2 (ja) 2004-12-28 2012-07-25 Ｊｘ日鉱日石エネルギー株式会社 超低硫黄軽油基材又は超低硫黄軽油組成物の製造方法及び超低硫黄軽油組成物
FR2882562B1 (fr) * 2005-02-25 2010-05-14 Inst Francais Du Petrole Procede de desulfuration profonde par adsorption d'une coupe hydrocarbonee de type gazole
US8222180B2 (en) * 2005-08-01 2012-07-17 Indian Oil Corporation Limited Adsorbent composition for removal of refractory sulphur compounds from refinery streams and process thereof
FR2913235B1 (fr) 2007-03-02 2011-02-25 Inst Francais Du Petrole Procede ameliore de desulfuration et de deazotation d'une coupe hydrocarbonee de type gazole contenant des composes azotes.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030070965A1 (en) * 1999-11-01 2003-04-17 Shih Stuart S. Method for the production of very low sulfur diesel
US20100155302A1 (en) * 2008-12-18 2010-06-24 Kaminsky Mark P Purification of ultralow sulfur diesel fuel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
English Machine Translation of WO 2004/050800, obtained from WIPO website 11/16/2015. *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022011866A1 (fr) * 2020-07-16 2022-01-20 南京延长反应技术研究院有限公司 Système de réaction et procédé d'hydrogénation de diesel
US20220089960A1 (en) * 2020-09-21 2022-03-24 Indian Oil Corporation Limited Process and a system for production of multiple grade de-aromatized solvents from hydrocarbon streams
US11999914B2 (en) * 2020-09-21 2024-06-04 Indian Oil Corporation Limited Process and a system for production of multiple grade de-aromatized solvents from hydrocarbon streams

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WO2012066574A2 (fr) 2012-05-24
EP2640811A2 (fr) 2013-09-25
EP2640811B1 (fr) 2021-07-14
WO2012066574A3 (fr) 2012-09-27

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