US20130139731A1 - Cementitious binders and wood particles-based incombustible coloured composite panel with structural high performance - Google Patents

Cementitious binders and wood particles-based incombustible coloured composite panel with structural high performance Download PDF

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Publication number
US20130139731A1
US20130139731A1 US13/678,859 US201213678859A US2013139731A1 US 20130139731 A1 US20130139731 A1 US 20130139731A1 US 201213678859 A US201213678859 A US 201213678859A US 2013139731 A1 US2013139731 A1 US 2013139731A1
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US
United States
Prior art keywords
composite panel
panel according
component
wood particles
chips
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/678,859
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English (en)
Inventor
Angela Maria Jesus DE SEQUEIRA SERRA NUNES
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SECIL-COMPANHIA GERAL DE CAL E CIMENTO SA
Secil Geral De Cal E Cimento Cia SA
Original Assignee
Secil Geral De Cal E Cimento Cia SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Secil Geral De Cal E Cimento Cia SA filed Critical Secil Geral De Cal E Cimento Cia SA
Assigned to SECIL-COMPANHIA GERAL DE CAL E CIMENTO, S.A. reassignment SECIL-COMPANHIA GERAL DE CAL E CIMENTO, S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: De Sequeira Serra Nunes, Angela Maria Jesus
Publication of US20130139731A1 publication Critical patent/US20130139731A1/en
Priority to US14/063,814 priority Critical patent/US8852338B2/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/02Portland cement
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/044Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres of concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • E04B1/941Building elements specially adapted therefor
    • E04B1/942Building elements specially adapted therefor slab-shaped
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/249932Fiber embedded in a layer derived from a water-settable material [e.g., cement, gypsum, etc.]

Definitions

  • This invention relates to a new type of incombustible cement wood, its use allowing an increased safety of the buildings against fire action, simultaneously providing the remaining properties of high durability, mechanical strength, acoustic behaviour and aesthetical interest, which are usual for this kind of material.
  • the panels or coatings made from solid wood or wood derivatives have a high bending strength, such as in the case of plywood, medium density fiberboards (MDF) or particle boards (OSB), they also have a low performance in terms of water resistance, dimensional stability, in addition to high susceptibility to attacks from fungi, insects and microorganisms, as well as low performance in what concerns its reaction to fire (in most cases with a classification equivalent to euroclass D).
  • MDF medium density fiberboards
  • OSB particle boards
  • the patent U.S. Pat. No. 5,342,566 is in line with the previous ones, however it comprises the use of light-weight fillers, such as perlite, combined with gypsum and cellulose fibers, for the production of multilayer panels.
  • the possibility to use fibers of different origins is mentioned, such as glass or another mineral, and/or polypropylene in percentages ranging from 10 to 20%. All of these panels are considered incombustible according to ASTM E 136, but their formula does not contain cement and that is the reason why they have a limited scope of application, particularly in what concerns demands of a structural nature and exposure to outer environment.
  • the main advantage of the invention is based in the fact that it is an incombustible panel, without generating incandescent drops and with a reduced smoke production, thus helping to minimize the risk of fire deflagration and propagation in the buildings and therefore contributing to an increased safety of people and property in case of fire. Simultaneously, it shows a good performance in terms of thermal and acoustic behaviour, resistance to impact, tensile and bending strength, resistance to humidity, as well as stability from the dimensional point of view and resistance to fungi, insects and microorganisms, in addition to being economically competitive and very easily applied. Considering all of these characteristics, it can be used in a wide variety of domains, inclusively with structural and architectural functions in inner and outer spaces.
  • composition is aimed at minimizing the incorporation of organic matter in the form of wood chips in order to not compromise the panel's mechanical strengths (in special, the bending strength), and the combination of the calcium sulphate in the form of semi-hydrate with the cement, according to the carefully determined proportions so as to control eventual expansive reactions which might be generated, provides a very good behaviour as regards fire, causing the material to be incombustible.
  • This new benefit significantly increases the scope of application of the product and improves the behaviour of buildings under the action of fire.
  • the object of this invention is an incombustible composite panel of high performance, made of Portland cement, gypsum and wood particles, comprising in weight percentage of the components with reference to the total weight of the composition:
  • the resinous wood which is commonly used to obtain the component 2) is pinewood.
  • the wood particles used therein are in the form of chips.
  • the thickness of the said chips ranges from 0.25 to 0.32 mm.
  • 50 to 70% of the said chips are ⁇ 1 mm long and 26 to 40%, preferably about 1 ⁇ 3, have a length of 1 to 4 mm.
  • the percentage of the component 3) is of about 11%.
  • the surface accelerator being used as the component 4) is a sodium silicate solution with a density between 1.10 and 1.15 g/cm 3 , wherein the sodium silicate has a SiO 2 /Na 2 O ratio between 3.19 and 3.53.
  • the aluminium sulphate which is used as the component 5 normally has a density ranging from 1.05 to 1.10 g/cm 3 .
  • the calcium carbonate being used as the component 6) is generally limestone filler, which is the result of the fine grinding of lime materials.
  • the pigments being commonly used as the component 7) are metal oxide pigments.
  • the composite panel according to the invention pertains to Class A in compliance with ASTM E 136 and to Class A2 in compliance with EN 13501-1 and DIN 4102, having a good performance in terms of mechanical strengths, generally with a tensile strength under bending >9 N/mm 2 and a tensile strength perpendicular to the plane >0.5 N/mm 2 , elasticity modulus >4000 N/mm 2 and thermal conductivity ⁇ 0.23 W/m 2 .K.
  • This formula aims both at minimizing the incorporation of wood chips and introducing a mixture of binders with the incorporation of Portland cement and semi-hydrated calcium sulphate, in order to ensure the characteristic minimum bending strength above 9 N/mm 2 .
  • the cements used are grey or white Portland cements, depending on the desired colour of the panel and according to the EN 197-1, which present fast-developing strengths (designation “R” of the relevant standard).
  • gypsum in the form of semi-hydrated calcium sulphate in controlled percentages, will not only provide the mixture with an acceleration of the setting process, but also an improvement of the panel's thermal behaviour and fire resistance.
  • the wood chips used which can be from pinewood or other resinous wood, are then broken and thinned to the following dimensions:
  • the water to be used shall be clean (colourless and odourless), preferably drinking water, and free from oils or other impurities which might contaminate the colour of the concrete, so as to comply with the provisions of the EN 1008.
  • the pigments suitable to the manufacture of the said mixture shall be inorganic and have the desired colour.
  • the manufacturing of the board is in accordance with the industrial process of the previously mentioned Viroc panel, in an appropriate installation. It comprises a wood treatment step, with debarking, cutting and defibrillation to the previously referred dimensions, followed by mixing of the constituents for at least 90s in an industrial mixer, followed by the conformation of the board using a conformation equipment, followed by pressing for the purposes of dimensional stabilization. Subsequently, it is cured in a hardening chamber, air-matured and finally dried in a drying tunnel. After this, the plate is cut, rectified and packed.
  • the logs of wood are reduced into chips.
  • the latter are thinned and divided into a group of larger chips with 1 to 4 mm and another group of thinner chips with a thickness lower than 1 mm.
  • the chips are introduced in the mixer wherein after 30 seconds half of the water required for the process is also introduced (this varying according to the equipment used) and after another period of 30 seconds, the remaining portion of water is added. Again after 30 seconds, the aluminium sulphate is introduced and then, after 60 seconds, the sodium silicate solution.
  • the cement and the gypsum are premixed for 60 s, and then added to the remaining constituents in the main mixer.
  • the mixture's conformation step is started, in which the said mixture is distributed with an even thickness over steel plates, thus forming a mattress.
  • a stack of alternate plates and mattresses is formed with a number of stages according to the thickness of the boards to be manufactured.
  • the stack is pressed and introduced in a hardening chamber, in which, under the effect of pressure, temperature and humidity and length of stay, it will gain the required strength in order to be handled.
  • This set of boards is decompressed and the boards are separated from the plates.
  • the panels are subjected to a precut operation and subsequently they are stacked and left to mature in a covered park. After maturation, the boards are introduced in the drying tunnel in order to remove the excess moisture.
  • the boards are cut to the desired size and treated in the surface.
  • this type of panels in façades offers several benefits due to the fact that it is a building material which can be used on outer spaces as well, with a good behaviour while enduring sun exposure, wet and dry cycles of rainwater, freeze and thaw cycles, and also due to its acoustic and mechanical strengths, in addition to its easy application and workability, which enables it to be applied as is, or a finishing can be adopted such as painting or coating with ceramic materials.
  • Another possible application is for the purpose of building structural or dividing walls, both in inner and outer spaces.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • Building Environments (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Panels For Use In Building Construction (AREA)
US13/678,859 2011-11-16 2012-11-16 Cementitious binders and wood particles-based incombustible coloured composite panel with structural high performance Abandoned US20130139731A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/063,814 US8852338B2 (en) 2011-11-16 2013-10-25 Cementitious binders and wood particles-based incombustible coloured composite panel with structural high performance

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PT106007A PT106007A (pt) 2011-11-16 2011-11-16 Painel compósito incombustível, à base de cimento portland, gesso e partículas de madeira
PT106007 2011-11-16

Related Child Applications (1)

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US14/063,814 Continuation US8852338B2 (en) 2011-11-16 2013-10-25 Cementitious binders and wood particles-based incombustible coloured composite panel with structural high performance

Publications (1)

Publication Number Publication Date
US20130139731A1 true US20130139731A1 (en) 2013-06-06

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US14/063,814 Expired - Fee Related US8852338B2 (en) 2011-11-16 2013-10-25 Cementitious binders and wood particles-based incombustible coloured composite panel with structural high performance

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BR (1) BR102012029312A2 (pt)
PT (1) PT106007A (pt)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015069609A1 (en) * 2013-11-05 2015-05-14 United States Gypsum Company Gypsum board comprising silica gel
JP2020183339A (ja) * 2019-05-09 2020-11-12 宇部興産株式会社 モルタル・コンクリート用混和材、これを含むセメント組成物、モルタル組成物及びコンクリート組成物、並びに、モルタル硬化物及びコンクリート硬化物の製造方法
JP2020183338A (ja) * 2019-05-09 2020-11-12 宇部興産株式会社 モルタル・コンクリート用混和材、これを含むセメント組成物、モルタル組成物及びコンクリート組成物、並びに、モルタル硬化物及びコンクリート硬化物の製造方法
JP7359686B2 (ja) 2019-12-24 2023-10-11 Ube三菱セメント株式会社 モルタル・コンクリート用混和材、これを含むセメント組成物、モルタル組成物及びコンクリート組成物、並びに、モルタル硬化物及びコンクリート硬化物の製造方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10225983B2 (en) 2017-03-27 2019-03-12 Cnh Industrial America Llc Remote hydraulic positioning of an implement stabilizer wheel

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US3827895A (en) * 1972-03-27 1974-08-06 W Copeland Mod-wall concrete
KR970005867B1 (ko) 1988-11-18 1997-04-21 유나이티드 스테이트 집섬 캄파니 석고 합성물 및 그 제조방법
US5135805A (en) 1990-07-27 1992-08-04 Georgia-Pacific Corporation Method of manufacturing a water-resistant gypsum composition
US5342566A (en) 1990-08-23 1994-08-30 Carl Schenck Ag Method of manufacturing fiber gypsum board
US6221521B1 (en) 1998-02-03 2001-04-24 United States Gypsum Co. Non-combustible gypsum/fiber board
JP2001089206A (ja) * 1999-09-21 2001-04-03 Sekisui Chem Co Ltd 低吸水性木片セメント板
US8070878B2 (en) * 2007-07-05 2011-12-06 United States Gypsum Company Lightweight cementitious compositions and building products and methods for making same
US8070876B1 (en) * 2011-05-05 2011-12-06 Haihong Jiang Fireproof insulating cementitious foam comprising phase change materials

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015069609A1 (en) * 2013-11-05 2015-05-14 United States Gypsum Company Gypsum board comprising silica gel
JP2020183339A (ja) * 2019-05-09 2020-11-12 宇部興産株式会社 モルタル・コンクリート用混和材、これを含むセメント組成物、モルタル組成物及びコンクリート組成物、並びに、モルタル硬化物及びコンクリート硬化物の製造方法
JP2020183338A (ja) * 2019-05-09 2020-11-12 宇部興産株式会社 モルタル・コンクリート用混和材、これを含むセメント組成物、モルタル組成物及びコンクリート組成物、並びに、モルタル硬化物及びコンクリート硬化物の製造方法
JP7359686B2 (ja) 2019-12-24 2023-10-11 Ube三菱セメント株式会社 モルタル・コンクリート用混和材、これを含むセメント組成物、モルタル組成物及びコンクリート組成物、並びに、モルタル硬化物及びコンクリート硬化物の製造方法

Also Published As

Publication number Publication date
BR102012029312A2 (pt) 2015-04-07
US20140047997A1 (en) 2014-02-20
US8852338B2 (en) 2014-10-07
PT106007A (pt) 2014-09-12

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Owner name: SECIL-COMPANHIA GERAL DE CAL E CIMENTO, S.A., PORT

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DE SEQUEIRA SERRA NUNES, ANGELA MARIA JESUS;REEL/FRAME:029677/0612

Effective date: 20121205

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION