US20100205728A1 - Toilet Cleaner Dispenser with an Adjustable Substance Dispensing Amount - Google Patents
Toilet Cleaner Dispenser with an Adjustable Substance Dispensing Amount Download PDFInfo
- Publication number
- US20100205728A1 US20100205728A1 US12/711,347 US71134710A US2010205728A1 US 20100205728 A1 US20100205728 A1 US 20100205728A1 US 71134710 A US71134710 A US 71134710A US 2010205728 A1 US2010205728 A1 US 2010205728A1
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- US
- United States
- Prior art keywords
- toilet
- preparation
- container
- pump
- release
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
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- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/005—Devices adding disinfecting or deodorising agents to the bowl
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/08—Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material to be discharged, of ambient medium or of target ; responsive to condition of spray devices or of supply means, e.g. pipes, pumps or their drive means
- B05B12/12—Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material to be discharged, of ambient medium or of target ; responsive to condition of spray devices or of supply means, e.g. pipes, pumps or their drive means responsive to conditions of ambient medium or target, e.g. humidity, temperature position or movement of the target relative to the spray apparatus
- B05B12/122—Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material to be discharged, of ambient medium or of target ; responsive to condition of spray devices or of supply means, e.g. pipes, pumps or their drive means responsive to conditions of ambient medium or target, e.g. humidity, temperature position or movement of the target relative to the spray apparatus responsive to presence or shape of target
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/14—Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet
- B05B12/1409—Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet the selection means being part of the discharge apparatus, e.g. part of the spray gun
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/0805—Apparatus to be carried on or by a person, e.g. of knapsack type comprising a pressurised or compressible container for liquid or other fluent material
- B05B9/0811—Apparatus to be carried on or by a person, e.g. of knapsack type comprising a pressurised or compressible container for liquid or other fluent material comprising air supplying means actuated by the operator to pressurise or compress the container
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/085—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump
- B05B9/0855—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being motor-driven
- B05B9/0861—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being motor-driven the motor being electric
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- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
- E03D9/032—Devices connected to or dispensing into the bowl
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/14—Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet
- B05B12/1418—Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet for supplying several liquids or other fluent materials in selected proportions to a single spray outlet
Definitions
- the present invention relates to a toilet freshener with electromechanically effected release of adjustable amounts of preparations in or on a toilet bowl.
- Dispensing of cleaning and fragrancing compositions in the toilet area is currently performed primarily by “toilet fresheners”. These are single- or multi-chamber containers which are hung in the toilet bowl in such a way that an active substance is released from the toilet freshener into the toilet bowl during the flushing process of flushing the toilet bowl with water.
- Such devices are known, for example, from EP0828902 or DE10113036.
- a significant disadvantage of these toilet fresheners is that dispensing depends substantially on local flow conditions in the toilet bowl during the flushing process.
- flow conditions can vary widely, depending on the type of toilet and positioning of the toilet freshener in or on the toilet bowl. For example, with certain toilets it is possible that no active substance is released from the toilet freshener due to no or insufficient water flowing over the toilet freshener during the flushing process, resulting in the dispensing mechanism of the toilet freshener not being initiated.
- Toilet fresheners described in the art which supply a solid or gel-form active substance and are arranged under the rim of the toilet bowl directly in the flush water stream. Active substances are typically released from such toilet fresheners by penetration of flush water through openings in the toilet freshener, at least partially dissolving the active substances and discharging them away from the toilet freshener when the flush water exits through corresponding outlet openings.
- the amount of flow through it can vary due to very different flow conditions locally in flush water outlet from the toilet bowl rim, resulting in only a slight release of active substances.
- the amounts of active substance released can be influenced by the temperature of the flushing water, so that a greater release of active substance is observed in warmer months than is released in the colder months of the year.
- a significant advantage of the toilet freshener according to the invention is that active substances are dispensed into the toilet bowl in a manner appropriate to requirements, thereby achieving active substance use which is more effective and better conserves resources.
- a toilet freshener having at least a first container with a first preparation, wherein the container can be coupled to the dispenser of the toilet freshener.
- the toilet freshener further includes at least one power source, a control unit and a release element and/or pump which interact in such a way that at least two different, defined amounts of at least one preparation can be released from the toilet freshener into the toilet bowl.
- Release of a defined amount means in this connection that the amount released is independent of the amount and/or the duration of flush water flow and of the positioning of the toilet freshener in the or on the toilet bowl and is determined by the control unit of the toilet freshener.
- toilet freshener allows for positioning of the toilet freshener in any desired way on the toilet bowl to achieve optimum active substance release relative to the amount of flush water and duration of flushing.
- the toilet freshener according to the invention consists of various components which may in turn be combined into assemblies. These components include at least one pump, a release element, a control unit, a sensor unit, a power source, a container, a fastening means and a preparation. In a preferred embodiment, the pump, control unit, sensor unit and power source are combined into a “dispenser” assembly. The components and assemblies are described below.
- the dispenser can include the power source needed to operate the toilet freshener, its control unit, sensor unit and at least one pump.
- the dispenser includes a housing for protection from water splashing into the interior of the dispenser, as may occur when the toilet freshener is used in a toilet bowl.
- the dispenser arranged on the outer rim of the toilet bowl, further enabling protection from exposure to water splashes as well as convenient operation of the dispenser.
- the useful cross-sectional area of the toilet bowl is not reduced.
- any component of the toilet freshener which contacts these preparations should have appropriate acid and/or alkali resistance.
- suitable material selection should ensure that these components are as far as possible chemically inert (e.g., in relation to nonionic surfactants, enzymes and/or fragrances).
- encapsulation materials include multicomponent epoxide and acrylate encapsulation compounds such as methacrylate esters, urethane meth- and cyanoacrylates or two-component materials comprising polyurethanes, silicones, epoxy resins.
- a significant advantage of the invention is the separation of the toilet freshener into a dispenser and a container coupled with the dispenser, whereby the toilet freshener is flexible and adapted for the widest possible range of applications.
- a pump is a fluid power machine for moving or delivering in particular small quantities of fluid by converting mechanical drive power into flow power.
- Fluids are understood to be liquids and gases, and mixtures thereof and with solids.
- Pumps include positive-displacement pumps, oscillatory pumps, diaphragm pumps, piston pumps, rotary pumps, dynamic pumps, centrifugal pumps, electrohydrodynamic pumps, electroosmotic pumps, magnetohydrodynamic pumps, surface acoustic wave pumps, capillary pumps, electrowetting pumps, thermocapillary pumps.
- the pump is either connected directly to the power source or the control unit is interposed therebetween.
- the release of at least one preparation can occur merely by gravity without use of a pump.
- Release of the preparation from the container into the surrounding environment can be controlled in this configuration, for example, by a valve which opens to release the preparation and closes to prevent release.
- the valve can be controlled directly by the power source or by the control unit connected therebetween.
- the pump, sensor and control unit are advantageously configured so that a defined amount of active substance preparation is released into the toilet bowl irrespective of the arrangement of the toilet freshener in or on the toilet bowl and/or of the amount of flush water to which the toilet freshener is exposed.
- the pump likewise makes it possible for at least two different, defined amounts of at least one active substance preparation to be released.
- a significant advantage of this embodiment of the invention is that active substances are dispensed into the toilet bowl in a manner appropriate to requirements, thereby achieving active substance use which is more effective and better conserves resources.
- the pump is configured in such a way that it is able to release an active substance preparation with a viscosity of ⁇ 5000 mPa ⁇ s.
- Delivery rate of a micropump amounts conventionally to from 50 nl to 100 ml per minute, preferably from 250 nl to 30 ml per minute, particularly preferably from 500 nl to 5 ml per minute.
- the micropump has a structural volume of about 5 cm 3 or less, particularly preferably of about 3 cm 3 or less, particularly preferably of about 2 cm 3 or less.
- the specific delivery rate of a micropump (calculated from the ratio of the delivery rate to the structural volume of a micropump) is typically about 500 [l/min] or less.
- the specific delivery rate preferably lies from 1 to 300, particularly preferably from 1.5 to 200, particularly preferably from 2 to 150, very particularly preferred from 2.5 to 100 l/min.
- Diaphragm pumps are particularly advantageous for dispensing cleaning and active substance preparations as well as fragrances.
- Diaphragm pumps typically include an inlet valve and an outlet valve respectively leading into and out of a pump chamber, formed in part from a pump diaphragm, and an actuator.
- the actuator When the inlet valve is closed, the actuator causes compression of the pump chamber by acting mechanically on the pump diaphragm, whereby the fluid located in the pump chamber is conveyed out of the pump chamber via the open outlet valve.
- the outlet valve is closed and decompression of the pump chamber is effected by the actuator, whereby the fluid is then drawn into the pump chamber via the now open inlet valve.
- delivery direction of the micropump can be influenced or reversed.
- the diaphragm pump actuator can be electromotive, piezoceramic, bimetallic, memory metallic, pneumatic, peristaltic, electrostatic, electromagnetic or thermal drive units.
- the valves can be active or passive valves.
- Passive valves include clack valves, diaphragm valves or no-moving-parts valves.
- pressure-side release of the preparation from the dispenser can occur dropwise, as a jet or spray, by diffusion or by vaporization.
- the container housing the preparation may be advantageous to arrange the container housing the preparation on the pressure side of the pump. In this configuration, only a fluid containing no deposit-forming substances is delivered through the pump. In this case, it is particularly advantageous to use air as the fluid.
- the fluid is pumped into the container under pressure.
- the container has a pressure equalizing valve which, when a defined pressure in the container is exceeded, allows the product to flow out of the container.
- Release elements are any kind of device suitable for releasing an active substance into the surrounding environment of the dispenser.
- Release elements can include nozzles, spray heads, droplet dispensers, foam spray heads, piezo elements, porous elements, wick systems, capillary systems, nebulizers, ultrasound nebulizers, ionization nebulizers etc.
- Nozzles, spray heads, droplet dispensers, foam spray heads, piezo elements and the like are particularly suitable for releasing active substances into the toilet or onto the interior surfaces of the toilet bowl.
- Nozzles, atomizers, spray heads, piezo elements, sintered plates, porous elements, wick systems and the like are particularly suitable for releasing active substance preparations into the air.
- Release elements can have the same or different spray cone shapes when releasing the preparations. Accordingly, it is possible for one release element to produce a jet with a somewhat narrow or directed application area, while another release element produces a broad application field. Obviously, various combinations of the most varied spray cone shapes are possible.
- the release element can be arranged in movable manner on the toilet freshener that allows the user to orient the spray cone on the release element onto a desired application field.
- the release element can also permit adjustment of the spray cone shape.
- the release element can also provide electrostatic charging of active substance droplets, thereby improving the wetting, adhesion and/or distribution of the active substance on a surface and/or in the air.
- the release element can also be constructed as a fan configured either to improve air quality by drawing in malodors or optimize active substance distribution in or on the toilet bowl.
- Release elements can further be configured so that one or more active substances are released in different directions from one another.
- the following table provides a non-exhaustive list of some possible configurations regarding the direction of release.
- release element in a movable manner on the clip of the toilet freshener. Doing so allows the user to orient the release element and spray cone of the preparation in order to wet a defined application field in or on the toilet with the preparation.
- the release element(s) is/are advantageously configured so that, irrespective of the positioning of the toilet freshener on the toilet bowl, a defined amount of at least one active substance preparation is released in a directed and defined manner into the interior of a toilet bowl.
- Advantages of such a development include more specific exposure of surfaces of the toilet bowl to one or more active substances, as well as the ability to treat different surfaces with different active substances. For example, considering a German style flat-pan toilet, the pan portion can be wetted with an active substance for reducing adhesions, while an active substance for reducing lime deposits can be applied onto the funnel-shaped walls extending from the pan to the rim of the toilet.
- a control unit in the present application is a device suitable for influencing the transport of material, energy and/or information. To this end, the control unit acts on transducers with information which it processes for achieving the control objective.
- Transducers include, for example, pumps and/or valves.
- the toilet freshener does not make use of any mechanical control elements for product release, enabling the toilet freshener to be miniaturized so that it may also be used in applications in which the size of the toilet freshener is critical.
- the control unit can include a programmable microprocessor.
- a plurality of dispensing programs are stored in the microprocessor for selection and execution depending on the container coupled to the toilet freshener. It is also possible for the dispensing programs to be manually invoked by the user.
- the control unit is preferably arranged on the outwardly facing side of the toilet bowl, allowing it to be operated by the user, in particular, when the user is sitting on the toilet.
- control unit has a dispensing program for introducing at least two different active substance preparations into a toilet bowl or into the surrounding environment of the toilet bowl, wherein in at least two successive points in time t 1 and t 2 at least two different active substance preparations are released, with at least one active substance preparation introduced into the interior of a toilet bowl.
- Such a dispensing program allows optimized cleaning performance due to control of possible chemical reactions based on appropriately time-offset release of the corresponding preparation or preparations, some examples of which are listed in the following table.
- Cleaning product Cleaning product Cleaning product A may prevent adhesions in the toilet A in toilet bowl B in toilet bowl bowl by a protective film of cleaning product A being immediately during flushing applied in the toilet bowl immediately before the toilet is before use process used, which protective film is then flushed back off the toilet surface by cleaning product B during the flushing process.
- Another advantage is that a controlled release of one or more different fragrances can be implemented, thereby at least reducing dependence on the sense of smell. This can be accomplished by cyclic and pulsed release of fragrance as described in the art. Furthermore, dependence on smell can also be reduced by releasing different fragrances in succession.
- the toilet freshener can also dispense a defoamer into the toilet bowl before or during the flushing process. Excessive foaming before or during the flushing process often causes toilet paper to float on this foam so that it is not properly flushed away, but instead floats in the toilet bowl after completion of the flushing process. Consumers consider this unappealing. By dispensing the defoamer before or during the flushing process, excessive foaming can be prevented, ensuring that the toilet paper is reliably flushed away. In addition or as an alternative to the defoamer, cellulose-dissolving substances may also be added.
- the control can be constructed so that parameters in the dispensing programs are adjustable. For example, sensor threshold values can be adjusted during preconfiguration of the toilet freshener or by the user during use in order to trigger active substance release at a specific sensor threshold value. Setting one or more parameters can be achieved by an appropriately configured input device on the toilet freshener. In this way, control of the toilet freshener may be further optimized and adapted to a specific instance of use.
- control unit generates a control signal for releasing active substance preparation when flushing is initiated, and a control signal for terminating active substance release once flush water has stopped flowing through the toilet bowl.
- the first amount released and at least the second amount released originate from identical or different active substance preparations.
- the first amount released and at least the second amount released are released at different points in time.
- the release element and at least the first preparation are configured such that a foam is formed on release of the preparation into the surrounding environment.
- the pump, the release element and at least the first preparation are configured such that a foam is formed on release of the preparation into the surrounding environment.
- Foaming exhibits a plurality of possible advantages.
- a foam is capable of particularly effectively trapping and minimizing malodors thanks to its pore and cell structure.
- the foam may also be applied onto the surface of the toilet bowl as an “anti-caking” coating in order to reduce adhesions of excreted metabolites to these surfaces.
- the release element to take the form of a foam spray head and for the preparation to have a viscosity of less than 3000 mPa ⁇ s, such that a maximally stable, effectively adhering and fine-pored foam can be formed.
- the sensor unit can include one or more active and/or passive sensors for the qualitative and/or quantitative detection of mechanical, electrical, physical and/or chemical variables, which are then forwarded to the control unit as control signals.
- sensors in the sensor unit include timers, infrared sensors, brightness sensors, temperature sensors, motion sensors, strain sensors, rotational speed sensors, proximity sensors, flow sensors, color sensors, gas sensors, vibration sensors, pressure sensors, conductivity sensors, turbidity sensors, instantaneous acoustic pressure sensors, “lab-on-a-chip” sensors, force sensors, acceleration sensors, inclination sensors, pH sensors, moisture sensors, magnetic field sensors, RFID sensors, magnetic field sensors, Hall sensors, biochips, odor sensors, hydrogen sulfide sensors and/or MEMS sensors.
- the sensor unit can be in the form of a toggle, pressure or momentary-contact switch.
- Suitable flow sensors include diaphragm flow sensors, magnetic-inductive flow meters, mass flow metering using the Coriolis method, eddy flow metering, ultrasound flow metering, rotameter metering, annular piston flow metering, thermal mass flow metering or differential pressure flow metering.
- a viscosity curve as a function of temperature for at least one preparation in the control unit, so that dispensing is adjusted by the control unit in accordance with the temperature and thus the viscosity of the preparation.
- a device for direct determination of the viscosity of the preparation is provided.
- the senor is configured so that detection of a flushing process is achieved without any significant influenced on flow conditions in the toilet bowl.
- ultrasonic sensors may be used for this purpose.
- a dispensing process in which a defined amount of a preparation is released, for example, over a time of about 20 seconds or less, preferably about 10 seconds or less, particularly preferably about 5 seconds or less.
- a power source refers to a component of the dispenser capable of providing power suitable for autonomous operation of the dispenser.
- the power source preferably provides electrical power.
- the power source can be, for example, a battery, a mains power supply, solar cells or the like.
- the power source replaceable (e.g., in the form of a replaceable battery).
- the power source can be a mechanical power source such as a dynamo, which converts mechanical or fluidic energy into electrical power. This can then be stored in suitable storage elements such as a capacitor or storage battery.
- a container refers to a packaging container suitable for enclosing or holding preparations, and which can be coupled to the dispenser for release of the preparation.
- a particularly preferred arrangement is one in which two containers are provided, preferably separate from one another, each containing an active substance fluid.
- the storage containers can be separate from one another in order to prevent premature mixing of the active substance fluids. They may be physically separate containers or separate compartments in a single container body.
- the volume ratio of the structural volume of the dispenser and the capacity of the container preferably amounts to ⁇ 1, particularly preferably ⁇ 0.1, particularly preferably ⁇ 0.05. This ensures that, in the case of a predetermined overall structural volume of dispenser and container, the predominant proportion of the structural volume is occupied by the container and the preparation contained therein.
- the container can have a capacity of ⁇ 5000 ml, in particular ⁇ 1000 ml, preferably ⁇ 500 ml, particularly preferably ⁇ 250 ml, very particularly preferably ⁇ 50 ml.
- the invention is suitable for dimensionally stable containers such as pots, tins, capsules, cartridges, bottles, canisters, cans, cartons, drums or tubes, but may also be used for flexible containers such as pouches or bags, particularly if they are used in accordance with the bag-in-bottle principle.
- a container can also include a plurality of chambers which can be filled with different compositions. It is also conceivable for a plurality of containers to be combined into a unit (e.g., into a cartridge).
- the container has an RFID label containing at least information about the container's content and which is readable by the sensor unit.
- This information can be used to select a dispensing program stored in the control unit. By doing so, it can be ensured that the ideal dispensing program is always used for a specific preparation. It is also possible that, in the absence of an RFID label or in the case of an RFID label with an incorrect or defective ID, the dispenser does not dispense, but instead an optical or acoustic signal is produced which notifies the user of the error.
- the containers can also have structural elements which interact with corresponding elements of the dispenser like a key in a lock, such that only containers of a particular type are coupled to the dispenser.
- This embodiment makes it possible for information about the container coupled to the dispenser to be transferred to the control unit so that the dispenser can be controlled in a manner consistent with the contents of the corresponding container.
- the container can be under pressure. This is useful when the preparation is sprayed or released without requiring a pump in between. In this case, release of the preparation can be controlled or regulated, for example, by a control valve in active connection with the control unit.
- This embodiment has the additional advantage that no power need be provided by the power source for transporting the preparation, allowing the power source to be made smaller or have a longer anticipated life.
- the toilet freshener can also include fasteners for fixing the toilet freshener to the toilet bowl.
- Fastener include suction cups, adhesive tape, clips or the like.
- the toilet freshener can be fastened to the toilet cistern, the toilet seat or to the toilet lid. Fasteners known in the art can be used for this purpose.
- compositions containing at least one substance from the group of cleaning agents and/or fragrances are compositions containing at least one substance from the group of cleaning agents and/or fragrances.
- preparations include substances for modifying surfaces, in particular ceramic surfaces.
- Bleach phases in particular chlorine-containing bleach phases, preferably hypochlorite-based bleach phases, are likewise suitable as preparations according to the invention, wherein the bleach phases can contain additional ingredients such as thickeners, surfactants or emulsifiers, neutralizing agents, dyes, fragrances etc.
- limescale removing active substance phases preferably acidic limescale removing active substance phases.
- limescale removing active substance phases can optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives etc.
- Foam boosters are advantageous for pretreating the toilet bowl with a carpet of foam in order, for example, to prevent adhesion of excreted metabolites on the surface of the toilet and/or to reduce and/or trap malodors.
- Preparations having an antibacterial and/or fungicidal and/or antiviral active substance phase are likewise suitable according to the invention, wherein in addition to the antibacterial and/or fungicidal and/or antiviral active substance and water, the active substance phase can also contain other ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives etc.
- enzyme-containing active substance phases can optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
- the preparations used according to the invention can be absorbent, in particular, odor-absorbing active substance phases.
- the phases can also contain other ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives etc.
- the toilet freshener according to the invention allows the use of different combinations of preparations in the storage containers, wherein one of the storage containers can contain a fragrance phase as defined above.
- Examples of useful preparation combinations include a perfumed fragrance phase combined with chlorine bleach (which are not stable when stored together), perfumed fragrance phase with highly concentrated surfactant phase (foam boosters), fragrance phase with limescale removing, acidic active substance phase, fragrance phase with antibacterial active substance phase, various acid systems, fragrance phase combined with enzyme-containing active substance phase, perfumed acid phase combined with water-coloring phase, fragrance phase with odor-absorbing phase, perfumed acid phase with active oxygen, perfumed acid phase with active substance phase, polyacrylate-thickened etc.
- high-viscosity to gel-like active substance fluids having viscosities of a few thousand mPa ⁇ s, in particular from about 200 to about 5000 mPa ⁇ s, preferably about 500 to about 3500 mPa ⁇ s (measured with RotoVisko LVTV II, spindle 31, 5 rpm, 20° C.).
- the preparations have a viscosity of about 2000 mPa ⁇ s or less, in particular about 1000 mPa ⁇ s or less (measured with RotoVisko LVTV II, spindle 31, 5 rpm, 20° C.).
- Viscosity to watery preparations are particularly suitable if the preparation is sprayed into or onto the toilet bowl.
- low-viscosity active substance preparations in toilet fresheners allows for substantially faster and more accurate dispensing, as well as dispensing with the use of thickening systems.
- active substance systems which can only be prepared in low viscosities can be used, for example, based on chlorine, HCl, etc.
- the preparation can be pressurized. This is advantageous when the preparation is sprayed or released without requiring a pump in between. In this case, release of the preparation can be controlled or regulated by a control valve actively connected to the control unit.
- This embodiment has the further advantage that no power is required by the power source for transporting the preparation, allowing the power source to be made smaller or have a longer anticipated life.
- FIG. 1 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a preparation container on the suction side of the pump.
- FIG. 2 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a preparation container on the pressure side of the pump.
- FIG. 3 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a two-chamber preparation container on the suction side of the pump.
- FIG. 4 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a passive valve-controlled two-chamber preparation container on the suction side of the pump.
- FIG. 4A is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with an active valve-controlled two-chamber preparation container on the suction side of the pump.
- FIG. 5 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with two pump-connected preparation containers.
- FIG. 6 is a flow chart illustrating one method of controlling a toilet freshener according to the present invention with a pump.
- FIG. 7 is a flow chart illustrating one method of controlling a toilet freshener according to the present invention with a pump and multi-chamber preparation container.
- FIG. 8 is a flow chart illustrating one method of controlling a toilet freshener according to the present invention with a plurality of pumps and multi-chamber preparation container.
- FIG. 9 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with an RFID label on a preparation container.
- FIG. 10 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a removable refill container.
- FIG. 11 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a refill container fixed to a dispenser.
- FIG. 12 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a battery built into the refill container.
- FIG. 13 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a two-chamber refill container and two pumps.
- FIG. 14 is a schematic block diagram of one embodiment of a toilet freshener according to the present invention with a two-chamber refill container, pump, and control valve.
- FIG. 15 is a perspective view of one embodiment of a toilet freshener according to the present invention with an extendible clip.
- FIG. 16 is a perspective view of one embodiment of a toilet freshener according to the present invention with a removable container and wick system.
- FIG. 17 is a side view of one embodiment of a toilet freshener according to the present invention with a release element arranged at the end of the clip.
- FIG. 18 is a top view of one embodiment of a toilet freshener according to the present invention with a release element arranged at the end of the clip, with the freshener attached to a toilet bowl.
- FIG. 19 is a perspective view of one embodiment of a toilet freshener according to the present invention with individually replaceable containers.
- FIG. 20 is a perspective view of one embodiment of a release element according to the present invention with integrated sensor unit and two release nozzles.
- FIG. 21 is a perspective view of one embodiment of a release element according to the present invention with integrated sensor unit, two release nozzles and two spray cones.
- FIG. 22 is a perspective view of one embodiment of a toilet freshener according to the present invention with release element and two spray cones, looking down onto a toilet bowl.
- FIG. 23 is a side view of one embodiment of a toilet freshener according to the present invention with release element arranged under the toilet rim and two differently oriented spray cones.
- FIG. 24 is a side view of one embodiment of a toilet freshener according to the present invention with the release element arranged under the toilet rim and a spray cone directed under the rim of the toilet.
- FIG. 25 is a perspective view of one embodiment of a toilet freshener according to the present invention with two individually replaceable containers and a viewing flap in closed and open positions.
- FIG. 1 shows a toilet freshener 1 according to the invention consisting of a dispenser 2 and a container 9 connected with the dispenser 2 and containing a preparation 10 .
- the dispenser 2 includes a power source 3 , a control unit 4 , a sensor unit 5 and a pump 6 , wherein all components are preferably incorporated in a housing.
- the pump 6 is connected to the power source 3 via the control unit 4 .
- the control unit 4 is in turn connected to the sensor unit 5 , which directs the control signals for controlling the pump 6 to the control unit 4 .
- the pump 6 has a pressure line 7 and a suction line 8 , with the suction line 8 connected to the container 9 containing the preparation 10 .
- the pump 6 delivers the flowable preparation 10 via the suction line 8 from the container 9 into the pressure line 7 , from which the preparation 10 is released into the surrounding environment of the toilet freshener 1 .
- the pressure line 7 can be configured so that it counteracts gelation of the released preparation (e.g., by selection of a suitable diameter).
- the container 9 can have a pressure equalizing valve 11 for equalizing the pressure between the surrounding environment and the interior of the container 9 when the pump 6 is pumping preparation 10 out of the container 9 .
- the pump 6 can be actuated by the control unit 4 so that the delivery direction of the pump 6 is reversed, and preparation still present in the pump 6 and lines 7 and 8 is delivered back into the container 9 .
- This back-flushing can be advantageous when the preparation 10 thickens, clogging the lines 7 or 8 .
- FIG. 2 shows a further embodiment of the dispenser from FIG. 1 wherein the container 9 is connected to the pressure side of the pump 6 .
- the pump 6 builds up pressure in the container 9 by pumping ambient air into the container 9 , thereby expelling the preparation from the container 9 .
- a valve 11 can be provided on the preparation outlet side of the container 9 , permitting release of the preparation 10 from the container 9 when a defined pressure is reached in the container 9 . This can be useful when dispensing is by a defined spray jet or spray mist, and not dropwise.
- a non-return valve 11 a can be provided in the pressure line 7 between the pump 6 and the container 9 , preventing pressure built up in the container 9 from escaping through the pressure line 7 when the pump 6 is at a standstill.
- FIG. 3 shows the dispenser 2 from FIG. 1 wherein a two-chamber container formed from the containers 9 and 13 is connected to the suction line 8 of the pump 6 .
- the containers 9 and 13 can each contain different compositions 10 and 14 .
- the containers 9 and 13 can each have pressure equalizing valves 11 , 12 .
- the outlet openings at the bottom of the containers 9 and 13 are connected to the suction line 8 and pump 6 so that the preparations 10 and 14 are pumped through the suction line 8 in a defined ratio to one another. It may be necessary to adjust the flow conditions in the pressure lines 8 leading to the outlet openings at the bottom of the containers 9 and 13 .
- Incompatibility of two preparations can result in, for example, an exothermic reaction, thickening, flocculation, pH value modification, color change or the like.
- a third container can be provided that contains a flushing fluid for cleaning at least one of the preparations 10 , 14 from the lines 7 , 8 and the pump 6 .
- Air can also be used for flushing the lines 7 , 8 and the pump 6 .
- FIG. 4 illustrates a further embodiment of the toilet freshener 1 from FIG. 3 .
- the pressure lines 8 leading to the outlet openings at the bottom of the containers 9 and 13 each have a passive valve 15 and 16 , allowing defined setting of the dispensing ratios of the preparations 10 and 14 from the containers 9 and 13 .
- the valves 15 and 16 can also be designed as temperature-sensitive bimetallic valves that open or close when a defined temperature is reached.
- the valves 15 and 16 can be different bimetallic valves so that, for example, only one preparation may be conveyed by the pump 6 from one of containers 9 or 13 once a defined temperature has been reached.
- a common feature of the dispensers according to FIGS. 1-4 is that the control unit 4 controls the pump 6 by processing the signals from the sensor unit 5 .
- a basic control algorithm 20 is shown in FIG. 6 in the form of a flow diagram.
- the control algorithm 20 is activated as soon as the dispenser 2 is switched on.
- the control unit 4 receives the signals from the sensor unit 5 .
- the received sensor signal is compared with a threshold value stored in the control unit 4 .
- a selection condition is used to check whether the sensor signal and the threshold value are in a defined relationship to one another. If the condition is met, the pump 6 is then activated by process step 25 . If the condition is not met, sensor signals continue to be received and evaluated by the control unit according to process step 22 .
- the pump 6 remains in an activated state until a sensor signal arises which, on comparison with a threshold value stored in the control unit 4 , causes the micropump to be switched off. According to this procedure, preparation is pumped out of the containers for as long as the sensor signal varies between two predefined threshold values, respectively, for switching the pump 6 on and off.
- valves 15 and 16 are also possible to configure the valves 15 and 16 as components actively controlled by the control unit 4 . In this manner, the mixing ratio of the two preparations 10 and 14 can be actively influenced in a time-variable manner.
- control scheme underlying this embodiment is shown in FIG. 7 by flow diagram 30 .
- FIG. 5 shows a further possibility for actively influencing the mixing ratios in time-variable manner.
- each of the containers 9 and 13 is coupled with a pump 6 and 19 individually controlled by the control unit 4 .
- the corresponding control algorithm is shown in FIG. 8 .
- FIG. 9 shows the dispenser from FIG. 1 wherein an RFID label 42 suitable for identifying the size and the contents 10 of the container 9 is arranged on the container 9 .
- the sensor unit 5 comprises an RFID receive unit capable of reading the information from the RFID label 42 arranged on the container 9 . This information is sent as a control signal to the control unit 4 to bring about dispensing of the preparation 10 based on the contents of the container 9 .
- control signals triggered by the RFID label 42 can be used to select a dispensing program stored in the control unit.
- a multipurpose dispenser for a plurality of dispensing applications is provided, such as for dispensing of preparations in dishwashers, washing machines, dryers, toilets or living spaces.
- a person skilled in the art may also provide other means which provide automatic identification of the container 9 and its contents 10 by the dispenser.
- an additional release device 43 can be provided at the pressure-side opening of the pressure line 7 .
- This release device 43 provides distribution of the preparation into the surrounding environment of the dispenser 1 different from dropwise release. This can, for example, involve jet- or spray mist-like release of the preparation or release based on vaporization or diffusion.
- the release device 43 can be in the form, for example, of a nozzle, atomizer, distributor plate or porous surface. In particular, the release device can be configured to counteract gelation of the released preparations.
- FIG. 10 shows the toilet freshener from FIG. 1 with a container 9 detachable from the dispenser 2 .
- the container 9 has at its lower, bottom end a connection port 47 which can be introduced into the receptacle 48 provided on the dispenser 1 .
- the connection port 47 can be closed by closure means so that initially, in the unused state of the container 9 , leakage of preparation 10 from the container 9 is prevented; however, by inserting the container 9 into the dispenser 2 or the connection port 47 into the receptacle 48 , the closure means is destroyed, allowing release of the preparation 10 from the container 9 by the dispenser 2 into the surrounding environment.
- FIG. 11 shows the toilet freshener in its assembled state.
- the control unit 4 can also be coupled with an acoustic transducer 46 for converting a voltage or current of the control unit into an audible acoustic signal.
- the control unit 4 can include memory for a plurality of acoustic signals and/or music and/or speech recordings, which can be retrieved and executed manually or on the basis of a sensor trigger signal (i.e., forwarded to the acoustic transducer 46 ).
- a light 44 can be connected to the control unit 2 , wherein the light 44 is turned on or off in accordance with a predefined operating state of the dispensing unit 2 .
- the light can take the form of, for example, an LED or LCD display.
- the dispenser 2 can be switched on or off with the actuating element 45 . It is additionally conceivable for different programs stored in the control unit 4 to be retrieved and executed by the actuating element 45 .
- FIG. 12 shows a further development of the toilet freshener according to the invention in which the power source 3 in the form of a battery is incorporated in the container 9 .
- the battery 3 is electrically conductively connected with the dispenser 2 via an appropriately configured coupling.
- the capacity of the battery 3 is designed to supply the dispenser 2 with power over the period of use until the preparation 10 has been completely emptied from the container 9 .
- FIG. 13 shows the structure of the toilet freshener according to the invention illustrated in FIG. 5 in a more detailed schematic diagram.
- the chamber 9 is subdivided into two chambers by a wall 49 in which a first preparation 10 and a second preparation 14 are stored.
- Each chamber communicates with the surrounding environment via a pressure equalizing valve 11 or 12 and has at its bottom end in each case a connection port 47 a or 47 b.
- FIGS. 15-17 show a further embodiment of the toilet freshener according to the invention.
- the toilet freshener includes the dispenser 2 and the container 9 , which is detachably fixed to the dispenser 2 .
- the dispenser has a raised rear wall from which extends perpendicularly the fastening means 52 in the form of a clip.
- the clip 52 is positioned between the rim of the toilet and the toilet seat, where it is fixed to the toilet bowl by the toilet seat resting on it.
- a suction cup can additionally be provided on the dispenser for additionally securing the toilet freshener to the toilet by vacuum.
- a pressure or strain sensor is arranged as a sensor unit 5 on the upwardly directed top side of the fastening means 52 .
- the sensor unit 5 When pressure is exerted on this sensor unit 5 (e.g., by someone sitting on a toilet seat), the sensor unit 5 generates a corresponding signal which is relayed to the control unit 4 of the dispenser 2 .
- the container 9 can be separable from the dispenser, as seen in FIG. 16 .
- the container 9 has a wick system 50 in its interior, by which the preparation is released by the release element 43 a from the container 9 into the surrounding environment by evaporation.
- the connection port 47 and receptacle 48 in the dispenser 2 form a liquid-tight connection when container 9 and dispenser 2 are in the assembled state.
- a release element 43 in the form of a nozzle head is provided on the clip 52 .
- the nozzle head 43 is arranged in movable manner on the clip 52 , such that it may be oriented by the user.
- a telescopic element 53 is arranged, by means of which the length of the clip 52 and thus the point of application of the nozzle head 43 is settable.
- the nozzle head 43 produces a spray cone 54 from the preparation, which, as seen in FIG. 18 , wets a defined application field within the toilet bowl 55 .
- FIG. 19 A further, alternative development of the toilet freshener according to the invention is shown in FIG. 19 .
- the containers 9 and 13 are firmly connected to the dispenser 2 and may be refilled via an opening (not shown in FIG. 19 ).
- FIG. 20 shows a release element 43 , arranged at the distal end of the clip 52 with an integrated sensor 5 and two nozzles 56 and 57 .
- the sensor 5 is in the form of an infrared sensor or ultrasound sensor.
- the nozzles 56 and 57 can be configured to produce identical or different spray cones 54 a , 54 b , as illustrated in FIG. 21 . As shown in FIG. 22 , the spray cones 54 a and 54 b can be directed onto the same application field in the interior of a toilet bowl 55 . However, it is also apparent from FIGS. 23 and 24 that it is possible to direct the two spray cones in different directions.
- the release element 43 is fixed by a hook on the inside on the lower rim of the toilet bowl 55 .
- the release element 43 is therefore displaceably arranged on the clip 52 , as indicated by the arrow in FIG. 23 .
- the toilet freshener 1 is fixed by the fastening means 50 , here in the form of a suction cup, to the external rim of the toilet bowl 55 .
- the release element 43 has a first nozzle 56 and a second nozzle 57 which are spaced apart and arranged in the release element 43 so that their respective spray cones 54 a and 54 b point in different, non-overlapping directions.
- Spray cone 54 a from the first nozzle 56 is accordingly directed into the interior of the toilet bowl 55
- spray cone 54 b from the second nozzle 57 is directed onto the rim of the toilet bowl.
- a spray cone 54 b can be directed under the rim of the toilet bowl 55 .
- the spray cones 54 a and 54 b can be identical or different compositions.
- a sensor unit 5 in the form of a capacitive sensor projects from the release element under the rim of the toilet 55 , enabling the sensor 5 to be exposed to water when flushing is actuated.
- the sensor 5 is shaped so that it has no significant influence on the path of the flushing water in the toilet bowl 55 .
- FIG. 25 shows a further development of the containers 9 and 13 and of the dispenser 2 .
- the receptacle for the containers 9 and 13 in the dispenser is closable by a flap 58 arranged swivelably on the dispenser 2 . With the flap 58 in the open state, the two containers 9 and 13 can be separately removed from or inserted into the receptacle of the dispenser 2 .
- FIG. 25 shows a further development of toilet freshener 1 having two individually replaceable containers 9 and 13 and a viewing flap 58 in closed and in open position.
- the viewing flap 58 is hinged to the rear wall of the toilet freshener and shaped so that the viewing flap 58 preferably completely covers the containers 9 and 13 inserted in the toilet freshener 1 .
- the viewing flap 58 can be equipped with closures which provide child-proof closure of the viewing flap 58 with the toilet freshener, thereby preventing unintended access to the containers 9 and 13 .
- the lights 44 and actuating element 45 are arranged on the front of the toilet freshener so that they are not covered when the inspection or viewing flap 58 is closed, but are instead freely accessible.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE102007040323.4A DE102007040323B4 (de) | 2007-08-24 | 2007-08-24 | WC-Spüler mit einstellbarer Wirkstoffabgabemenge |
DE102007040323.4 | 2007-08-24 | ||
PCT/EP2008/054195 WO2009027114A1 (de) | 2007-08-24 | 2008-04-08 | Wc-spüler mit einstellbarer wirkstoffabgabemenge |
Related Parent Applications (1)
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PCT/EP2008/054195 Continuation WO2009027114A1 (de) | 2007-08-24 | 2008-04-08 | Wc-spüler mit einstellbarer wirkstoffabgabemenge |
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US20100205728A1 true US20100205728A1 (en) | 2010-08-19 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US12/711,347 Abandoned US20100205728A1 (en) | 2007-08-24 | 2010-02-24 | Toilet Cleaner Dispenser with an Adjustable Substance Dispensing Amount |
Country Status (6)
Country | Link |
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US (1) | US20100205728A1 (ru) |
EP (1) | EP2179099A1 (ru) |
DE (2) | DE202007018952U1 (ru) |
RU (1) | RU2479694C2 (ru) |
UA (1) | UA98805C2 (ru) |
WO (1) | WO2009027114A1 (ru) |
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US7971368B2 (en) * | 2005-07-26 | 2011-07-05 | Mitsubishi Electric Corporation | Hand drying apparatus |
USD667944S1 (en) * | 2010-11-09 | 2012-09-25 | S.C. Johnson & Son, Inc. | Dispenser mounting device |
US20130025038A1 (en) * | 2010-04-09 | 2013-01-31 | Henkel Ag & Co. Kgaa | Dispensing device having a piezoelectric element |
CN106948444A (zh) * | 2017-04-20 | 2017-07-14 | 黄军军 | 一种基于2.4g无线通信模块的智能马桶 |
US9834918B2 (en) | 2012-03-13 | 2017-12-05 | Delta Faucet Company | Toilet with overflow protection |
WO2018148328A1 (en) * | 2017-02-08 | 2018-08-16 | The Buttler, Llc | Self-contained toilet bowl dispenser and light |
US10337181B2 (en) | 2014-11-24 | 2019-07-02 | Delta Faucet Company | Toilet usage sensing system |
US10370837B2 (en) | 2017-05-16 | 2019-08-06 | Homemation Llc | Self-contained toilet bowl dispenser and light |
US10378194B2 (en) | 2017-02-08 | 2019-08-13 | Homemation Llc | Self-contained toilet bowl dispenser and light |
US10669705B2 (en) | 2016-07-05 | 2020-06-02 | Willert Home Products, Inc. | Toilet bowl treatment apparatus and method of making same |
US20200392712A1 (en) * | 2019-06-13 | 2020-12-17 | Henkel Ag & Co. Kgaa | Dosing system and method for dispensing at least one chemical composition inside the tank of a toilet |
USD991427S1 (en) | 2021-08-05 | 2023-07-04 | Homemation, Inc. | Fragrance dispenser |
USD1008036S1 (en) | 2021-08-05 | 2023-12-19 | Homemation, Inc. | Fragrance container |
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GB0717950D0 (en) * | 2007-09-14 | 2007-10-24 | Reckitt Benckiser Inc | Automatic toilet bowl treatment device |
DE102016007999A1 (de) * | 2016-07-01 | 2018-01-04 | GROHEDAL Sanitärsysteme GmbH | Toilette mit Reinigungskomponente zum Reinigen der Beckeninnenoberfläche |
DE102017111399A1 (de) | 2017-05-24 | 2018-11-29 | Buck-Chemie Gmbh | Reinigungsmittel umfassendes WC-Körbchen |
DE102017111481A1 (de) | 2017-05-24 | 2018-11-29 | Buck-Chemie Gmbh | Reinigungsmittel umfassendes WC-Körbchen |
DE102017114464A1 (de) * | 2017-06-29 | 2019-01-03 | Buck-Chemie Gmbh | Reinigungsmittel umfassendes WC-Körbchen |
DE102021213270A1 (de) | 2021-11-25 | 2023-05-25 | Robert Bosch Gesellschaft mit beschränkter Haftung | Medienausgabevorrichtung |
WO2023128932A1 (en) * | 2021-12-27 | 2023-07-06 | Eczacibasi Yapi Gerecleri Sanayi Ve Ticaret Anonim Sirketi | System facilitating the cleaning of a toilet bowl |
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US20130025038A1 (en) * | 2010-04-09 | 2013-01-31 | Henkel Ag & Co. Kgaa | Dispensing device having a piezoelectric element |
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US10378194B2 (en) | 2017-02-08 | 2019-08-13 | Homemation Llc | Self-contained toilet bowl dispenser and light |
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US20200392712A1 (en) * | 2019-06-13 | 2020-12-17 | Henkel Ag & Co. Kgaa | Dosing system and method for dispensing at least one chemical composition inside the tank of a toilet |
US11492791B2 (en) * | 2019-06-13 | 2022-11-08 | Henkel Ag & Co. Kgaa | Dosing system and method for dispensing at least one chemical composition inside the tank of a toilet |
USD991427S1 (en) | 2021-08-05 | 2023-07-04 | Homemation, Inc. | Fragrance dispenser |
USD1008036S1 (en) | 2021-08-05 | 2023-12-19 | Homemation, Inc. | Fragrance container |
Also Published As
Publication number | Publication date |
---|---|
DE102007040323A1 (de) | 2009-02-26 |
EP2179099A1 (de) | 2010-04-28 |
DE102007040323B4 (de) | 2015-12-17 |
RU2010110909A (ru) | 2011-09-27 |
RU2479694C2 (ru) | 2013-04-20 |
DE202007018952U1 (de) | 2009-11-26 |
UA98805C2 (ru) | 2012-06-25 |
WO2009027114A1 (de) | 2009-03-05 |
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