US20090324530A1 - Hair conditioning composition having higher yield point and higher conversion rate of fatty compound to gel matrix - Google Patents

Hair conditioning composition having higher yield point and higher conversion rate of fatty compound to gel matrix Download PDF

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US20090324530A1
US20090324530A1 US12/491,478 US49147809A US2009324530A1 US 20090324530 A1 US20090324530 A1 US 20090324530A1 US 49147809 A US49147809 A US 49147809A US 2009324530 A1 US2009324530 A1 US 2009324530A1
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composition
melting point
hair
high melting
conditioning
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Jian-Zhong Yang
Toshiyuki Okada
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Procter and Gamble Co
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Procter and Gamble Co
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Assigned to THE PROCTER & GAMBLE COMPANY reassignment THE PROCTER & GAMBLE COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OKADA, TOSHIYUKI, YANG, JIAN-ZHONG
Publication of US20090324530A1 publication Critical patent/US20090324530A1/en
Priority to US13/525,691 priority patent/US8828370B2/en
Priority to US14/462,131 priority patent/US10413497B2/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95

Definitions

  • the present invention relates to a hair conditioning composition
  • a hair conditioning composition comprising: (a) a cationic surfactant; (b) a high melting point fatty compound; and (c) an aqueous carrier; wherein the cationic surfactant, the high melting point fatty compound, and the aqueous carrier form a gel matrix; wherein the composition has from about 90% to about 100% of a conversion rate of the high melting point fatty compound to the gel matrix; and wherein the composition has a yield point of about 33 Pa or more.
  • the present invention also relates to a method of manufacturing of hair conditioning composition.
  • the compositions of the present invention, and the compositions made by the method of the present invention provide improved conditioning benefits, especially, improved wet conditioning benefits after rinsing and improved dry conditioning, while maintaining wet conditioning benefit before rinsing.
  • conditioning agents such as cationic surfactants and polymers, high melting point fatty compounds, low melting point oils, silicone compounds, and mixtures thereof.
  • Most of these conditioning agents are known to provide various conditioning benefits.
  • some cationic surfactants when used together with some high melting point fatty compounds and aqueous carrier, are believed to provide a gel matrix which is suitable for providing a variety of conditioning benefits such as slippery feel during the application to wet hair and softness and moisturized feel on dry hair.
  • WO 2006/044209 discloses a hair conditioning composition
  • a hair conditioning composition comprising by weight: (a) from about 0.1% to about 10% of a cationic surfactant; (b) from about 2.5% to about 15% by weight of the composition of a high melting point fatty compound; and (c) and an aqueous carrier; wherein the cationic surfactant, the high melting point fatty compound, and the aqueous carrier form a lamellar gel matrix; wherein the d-spacing of the lamellar layers is in the range of 33 nm or less; and wherein the composition has a yield stress of about 30 Pa or more at 26.7° C.
  • This hair conditioning compositions are said to provide improved conditioning benefits, especially improved slippery feel during the application to wet hair.
  • WO 2006/044209 also describes that; preferably, the composition of the present invention comprises, by weight of the hair care composition, from about 60% to about 99% of a gel matrix including lamellar gel matrix.
  • the DSC profile shows a single peak having a peak top temperature of about 67° C. to about 73° C., at about 8 mJ/mg, and no peaks larger than 2 mJ/mg from 40° C. to about 65° C. as the peaks showing at a temperature of from 40° C. to 55° C. mean the existence of high melting fatty compounds and/or cationic surfactants which are not incorporated into the gel matrix.
  • Such wet conditioning benefits after rinsing include, for example, reduced friction of wet hair after rinsing and/or easiness to comb wet hair after rinsing.
  • hair conditioning compositions which provide an improved product appearance, i.e., richer, thicker, and/or more concentrated product appearance, and which consumer may feel higher conditioning benefits from its appearance.
  • conditioning compositions which provide improved conditioning benefits, especially, improved wet conditioning benefits after rinsing and improved dry conditioning, while maintaining wet conditioning benefit before rinsing. Additionally, there may exist a need for conditioning compositions which provide an improved product appearance.
  • the present invention is directed to a hair conditioning composition
  • a hair conditioning composition comprising:
  • the present invention is also directed to a method of manufacturing a hair conditioning composition
  • compositions of the present invention and the compositions made by the method of the present invention, provide improved conditioning benefits, especially, improved wet conditioning benefits after rinsing and improved dry conditioning, while maintaining wet conditioning benefit before rinsing.
  • FIG. 1 illustrates an embodiment of d-spacing measurement of the lamellar gel matrix comprising lamella bilayers 1 and water 2 .
  • mixtures is meant to include a simple combination of materials and any compounds that may result from their combination.
  • the hair conditioning composition of the present invention comprising:
  • the hair conditioning compositions deliver improved conditioning benefits, especially improved wet conditioning benefits after rinsing and improved dry conditioning, while maintaining wet conditioning benefit before rinsing, compared to compositions having a smaller conversion rate and/or smaller yield point.
  • the conditioning composition of the present invention may provide an improved product appearance, i.e., richer, thicker, and or more concentrated product appearance.
  • composition of the present invention it is preferred to prepare the composition by the method described below under the title “METHOD OF MANUFACTURING”.
  • the total amount of the cationic surfactant and the high melting point fatty compound is from about 7.0%, as described below under the title “METHOD OF MANUFACTURING”.
  • the composition of the present invention comprises a gel matrix including lamella gel matrix.
  • the gel matrix comprises the cationic surfactant, the high melting point fatty compound, and an aqueous carrier.
  • the gel matrix is suitable for providing various conditioning benefits, such as slippery feel during the application to wet hair and softness and moisturized feel on dry hair.
  • the cationic surfactant and the high melting point fatty compound are contained at a level such that the weight ratio of the cationic surfactant to the high melting point fatty compound is in the range of, preferably from about 1:1 to about 1:10, more preferably from about 1:1 to about 1:4, still more preferably from about 1:2 to about 1:4.
  • the composition of the present invention is substantially free of anionic surfactants and anionic polymers.
  • “the composition being substantially free of anionic surfactants and anionic polymers” means that: the composition is free of anionic surfactants and anionic polymers; or, if the composition contains anionic surfactants and anionic polymers, the level of such anionic surfactants and anionic polymers is very low.
  • the total level of such anionic surfactants and anionic polymers if included, 1% or less, preferably 0.5% or less, more preferably 0.1% or less by weight of the composition. Most preferably, the total level of such anionic surfactants and anionic polymers is 0% by weight of the composition.
  • composition of the present invention has a conversion rate of the high melting point fatty compound to gel matrix, such rate being in the range of from about 90% to about 100%, preferably from about 95% to about 100%, more preferably above 99% (excluding 99%) to about 100%, in view of providing wet conditioning benefits before rinsing such as spreadability, and also providing wet conditioning benefits after rinsing_and improved dry conditioning benefits.
  • Conversion rate (%) [Delta H (J/g) of an endothermic peak having a peak top temperature of from about 67° C. to about 75° C./A total delta H (J/g) of all endothermic peaks] ⁇ 100
  • Such delta H is detected by differential scanning calorimetry (hereinafter referred to as “DSC”) measurement of the composition.
  • DSC differential scanning calorimetry
  • Thermal events obtained by DSC measurement describe chemical and physical changes of the scanned sample that involve an enthalpy change or energy gradient when the temperature of the sample is fluctuated.
  • the phase behavior and interaction among components of hair conditioning compositions of the present invention may be understood by their DSC curves.
  • DSC measurement of compositions of the present invention is conducted by Seiko DSC 6000 instrument available from Seiko Instruments Inc. In a typical measurement procedure, a sample is prepared by sealing an appropriate amount of the composition into a container made for DSC measurement and sealed. The weight of the sample is recorded. A blank sample i.e.; an unsealed sample of the same container is also prepared.
  • the sample and blank sample are placed inside the instrument, and run under a measurement condition of from about ⁇ 50° C. to about 130° C. at a heating rate of from about 1° C./minute to about 10° C./minute.
  • the area of the peaks as identified are calculated and divided by the weight of the sample to obtain the enthalpy change in mJ/mg.
  • the position of the peaks is identified by the peak top position.
  • the DSC curve shows a endothermic peak of, preferably larger than about 3 mJ/mg, more preferably from about 4 mJ/mg, still more preferably from about 5 mJ, and preferably to about 10 mJ/mg, and such peak having a peak top temperature of from about 67° C. to about 75° C. which indicates the existence of a gel matrix.
  • the DSC curve of the compositions of the present invention shows, preferably no peaks larger than 2.5 mJ/mg, more preferably no peaks larger than 2 mJ/mg, still more preferably no peaks larger than 1 mJ/mg, at a temperature of from 40° C. to 55° C., preferably from 40° C. to about 65° C., as the peaks having peak top temperatures at such temperature range mean the existence of high melting fatty compounds and/or cationic surfactants which are not incorporated into the gel matrix. It is believed that a composition formed predominantly with such a gel matrix shows a relatively stable phase behavior during the temperature range of from about 40° C. to about 55° C., preferably from 40° C. to about 65° C.
  • the composition of the present invention has a yield point of about 33 Pa or more preferably about 35 Pa or more, more preferably 40 Pa or more, in view of providing improved wet conditioning benefits after rinsing, and improved dry conditioning.
  • the above yield point may be also preferred in view of providing richer, thicker, and/or more concentrated product appearance.
  • the yield point is up to about 80 Pa, more preferably up to about 75 Pa, still more preferably up to about 70 Pa, in view of spreadability and product appearance.
  • the yield point of the present invention is measured by dynamic oscillation stress sweep at 1 Hz frequency and 25° C., by means of a rheometer available from TA Instruments with a mode name of AR2000 using 40 mm diameter parallel type geometry having gap of 1000 ⁇ m.
  • the composition of the present invention is substantially free of thickening polymers.
  • “the composition being substantially free of thickening polymers” means that: the composition is free of thickening polymers; or, if the composition contains a thickening polymer, the level of such thickening polymer is very low. In the present invention, the level of such thickening polymers, if included, 1% or less, preferably 0.5% or less, more preferably 0.1% or less, still more preferably 0.06% by weight of the composition.
  • Such thickening polymers include, for example, guar polymers including nonionic and cationic guar polymers, cellulose polymers including nonionic, cationic, and/or hydrophobically modified cellulose polymers such as cetyl hydroxyethylcellulose, other synthetic polymers including nonionic and cationic synthetic polymers such as polyquaternium-37.
  • compositions characterized by the combination of the above specific conversion rate and specific yield point provide improved wet performance, especially wet conditioning after rinsing, even if such compositions having a larger d-spacing than those of the compositions of WO 2006/044209.
  • Such larger d-spacing herein means a d-spacing of above 33 nm (excluding 33 nm).
  • D-spacing in the present invention means a distance between two lamellar bilayers plus the width of one lamellar bilayer, in lamellar gel matrix, as shown in FIG. 1 .
  • d-spacing is defined according to the following equation:
  • n ⁇ 2 d sin( ⁇ ), wherein n is the number of lamellar bi-layers
  • compositions of the present invention comprise a cationic surfactant.
  • the cationic surfactant can be included in the composition at a level from about 1%, preferably from about 1.5%, more preferably from about 1.8%, still more preferably from about 2.0%, and to about 8%, preferably to about 5%, more preferably to about 4% by weight of the composition, in view of providing the benefits of the present invention.
  • the composition is substantially free of other cationic surfactants than those preferred in the present invention.
  • “other cationic surfactant” includes, for example, tertiary amines, tertiary amine salts, and di-long alkyl cationic surfactants having two long alkyl chains, for example those having from about 12 to about 40 carbon atoms, such as dicetyl dimethyl ammonium chloride and distearyl dimethyl ammonium chloride.
  • the composition being substantially free of other cationic surfactants means that: the composition is free of other cationic surfactants; or, if the composition contains other cationic surfactants, the level of such other cationic surfactants is very low. In the present invention, the level of such other cationic surfactants, if included, 1% or less, preferably 0.5% or less, more preferably 0.1% or less by weight of the composition. Most preferably, the level of such other cationic surfactants is 0% by weight of the composition.
  • One of the preferred cationic surfactants of the present invention is a salt of a mono-long alkyl quaternized ammonium and an anion, wherein the anion is selected from the group consisting of halides such as chloride and bromide, C1-C4 alkyl sulfate such as methosulfate and ethosulfate, and mixtures thereof. More preferably, the anion is selected from the group consisting of halides such as chloride and mixtures thereof.
  • the mono-long alkyl quaternized ammonium salts useful herein are those having the formula (I):
  • R 71 , R 72 , R 73 and R 74 is selected from an aliphatic group of from 12 to 40 carbon atoms or an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkylaryl group having up to about 40 carbon atoms; the remainder of R 71 , R 72 , R 73 and R 74 are independently selected from an aliphatic group of from 1 to about 8 carbon atoms or an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkylaryl group having up to about 8 carbon atoms; and X ⁇ is a salt-forming anion selected from the group consisting of halides such as chloride and bromide, C1-C4 alkyl sulfate such as methosulfate and ethosulfate, and mixtures thereof.
  • halides such as chloride and bromide
  • the aliphatic groups can contain, in addition to carbon and hydrogen atoms, ether linkages, and other groups such as amino groups.
  • the longer chain aliphatic groups e.g., those of about 16 carbons, or higher, can be saturated or unsaturated.
  • one of R 71 , R 72 , R 73 and R 74 is selected from an alkyl group of from 16 to 40 carbon atoms, more preferably from 18 to 26 carbon atoms, still more preferably from 22 carbon atoms; and the remainder of R 71 , R 72 , R 73 and R 74 are independently selected from CH 3 , C 2 H 5 , C 2 H 4 OH, CH 2 C 6 H 5 , and mixtures thereof.
  • cationic surfactants are those having a longer alkyl group, i.e., C18-22 alkyl group.
  • Such cationic surfactants include, for example, behenyl trimethyl ammonium chloride, methyl sulfate or ethyl sulfate, and stearyl trimethyl ammonium chloride, methyl sulfate or ethyl sulfate. Further preferred are behenyl trimethyl ammonium chloride, methyl sulfate or ethyl sulfate, and still further preferred is behenyl trimethyl ammonium chloride.
  • cationic surfactants having a longer alkyl group provide improved deposition on the hair, thus can provide improved conditioning benefits such as improved softness on dry hair, compared to cationic surfactant having a shorter alkyl group. It is also believed that such cationic surfactants can provide reduced irritation, compared to cationic surfactants having a shorter alkyl group.
  • the high melting point fatty compound can be included in the composition at a level of from about 2%, preferably from about 4%, more preferably from about 5%, still more preferably from about 5.5%, and to about 15%, preferably to about 10% by weight of the composition, in view of providing the benefits of the present invention.
  • the high melting point fatty compound useful herein have a melting point of 25° C. or higher, preferably 40° C. or higher, more preferably 45° C. or higher, still more preferably 50° C. or higher, in view of stability of the gel matrix.
  • such melting point is up to about 90° C., more preferably up to about 80° C., still more preferably up to about 70° C., even more preferably up to about 65° C., in view of easier manufacturing and easier emulsification.
  • the high melting point fatty compound can be used as a single compound or as a blend or mixture of at least two high melting point fatty compounds. When used as such blend or mixture, the above melting point means the melting point of the blend or mixture.
  • the high melting point fatty compound useful herein is selected from the group consisting of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, and mixtures thereof. It is understood by the artisan that the compounds disclosed in this section of the specification can in some instances fall into more than one classification, e.g., some fatty alcohol derivatives can also be classified as fatty acid derivatives. However, a given classification is not intended to be a limitation on that particular compound, but is done so for convenience of classification and nomenclature. Further, it is understood by the artisan that, depending on the number and position of double bonds, and length and position of the branches, certain compounds having certain required carbon atoms may have a melting point of less than the above preferred in the present invention. Such compounds of low melting point are not intended to be included in this section. Nonlimiting examples of the high melting point compounds are found in International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992.
  • fatty alcohols are preferably used in the composition of the present invention.
  • the fatty alcohols useful herein are those having from about 14 to about 30 carbon atoms, preferably from about 16 to about 22 carbon atoms. These fatty alcohols are saturated and can be straight or branched chain alcohols.
  • Preferred fatty alcohols include, for example, cetyl alcohol (having a melting point of about 56° C.), stearyl alcohol (having a melting point of about 58-59° C.), behenyl alcohol (having a melting point of about 71° C.), and mixtures thereof. These compounds are known to have the above melting point. However, they often have lower melting points when supplied, since such supplied products are often mixtures of fatty alcohols having alkyl chain length distribution in which the main alkyl chain is cetyl, stearyl or behenyl group. In the present invention, more preferred fatty alcohols are cetyl alcohol, stearyl alcohol and mixtures thereof.
  • high melting point fatty compounds useful herein include: cetyl alcohol, stearyl alcohol, and behenyl alcohol having tradenames KONOL series available from Shin Nihon Rika (Osaka, Japan), and NAA series available from NOF (Tokyo, Japan); pure behenyl alcohol having tradename 1-DOCOSANOL available from WAKO (Osaka, Japan).
  • the carrier useful in the present invention includes water and water solutions of lower alkyl alcohols and polyhydric alcohols.
  • the lower alkyl alcohols useful herein are monohydric alcohols having 1 to 6 carbons, more preferably ethanol and isopropanol.
  • the polyhydric alcohols useful herein include propylene glycol, hexylene glycol, glycerin, and propane diol.
  • the aqueous carrier is substantially water.
  • Deionized water is preferably used.
  • Water from natural sources including mineral cations can also be used, depending on the desired characteristic of the product.
  • the compositions of the present invention comprise from about 20% to about 99%, preferably from about 30% to about 95%, and more preferably from about 80% to about 90% water.
  • the silicone compounds have an average particle size of from about Imicrons to about 50 microns, in the composition.
  • the silicone compounds useful herein, as a single compound, as a blend or mixture of at least two silicone compounds, or as a blend or mixture of at least one silicone compound and at least one solvent, have a viscosity of preferably from about 1,000 to about 2,000,000 mPa ⁇ s at 25° C.
  • Suitable silicone fluids include polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, amino substituted silicones, quaternized silicones, and mixtures thereof. Other nonvolatile silicone compounds having conditioning properties can also be used.
  • Preferred polyalkyl siloxanes include, for example, polydimethylsiloxane, polydiethylsiloxane, and polymethylphenylsiloxane.
  • Polydimethylsiloxane which is also known as dimethicone, is especially preferred.
  • These silicone compounds are available, for example, from the General Electric Company in their Viscasil® and TSF 451 series, and from Dow Corning in their Dow Corning SH200 series.
  • the above polyalkylsiloxanes are available, for example, as a mixture with silicone compounds having a lower viscosity.
  • Such mixtures have a viscosity of preferably from about 1,000 mPa ⁇ s to about 100,000 mPa ⁇ s, more preferably from about 5,000 mPa ⁇ s to about 50,000 mPa ⁇ s.
  • Such mixtures preferably comprise: (i) a first silicone having a viscosity of from about 100,000 mPa ⁇ s to about 30,000,000 mPa ⁇ s at 25° C., preferably from about 100,000 mPa ⁇ s to about 20,000,000 mPa ⁇ s; and (ii) a second silicone having a viscosity of from about 5 mPa ⁇ s to about 20,000 mPa ⁇ s at 25° C., preferably from about 5 mPa ⁇ s to about 5,000 mPa ⁇ s.
  • Such mixtures useful herein include, for example, a blend of dimethicone having a viscosity of 18,000,000 mPa ⁇ s and dimethicone having a viscosity of 200 mPa ⁇ s available from GE Toshiba, and a blend of dimethicone having a viscosity of 18,000,000 mPa ⁇ s and cyclopentasiloxane available from GE Toshiba.
  • the silicone compounds useful herein also include a silicone gum.
  • silicone gum means a polyorganosiloxane material having a viscosity at 25° C. of greater than or equal to 1,000,000 centistokes. It is recognized that the silicone gums described herein can also have some overlap with the above-disclosed silicone compounds. This overlap is not intended as a limitation on any of these materials.
  • the “silicone gums” will typically have a mass molecular weight in excess of about 200,000, generally between about 200,000 and about 1,000,000.
  • silicone gums are available, for example, as a mixture with silicone compounds having a lower viscosity.
  • Such mixtures useful herein include, for example, Gum/Cyclomethicone blend available from Shin-Etsu.
  • Silicone compounds useful herein also include amino substituted materials.
  • Preferred aminosilicones include, for example, those which conform to the general formula (1):
  • G is hydrogen, phenyl, hydroxy, or C 1 -C 8 alkyl, preferably methyl; a is 0 or an integer having a value from 1 to 3, preferably 1; b is 0, 1 or 2, preferably 1; n is a number from 0 to 1,999; m is an integer from 0 to 1,999; the sum of n and m is a number from 1 to 2,000; a and m are not both 0; R 1 is a monovalent radical conforming to the general formula CqH 2q L, wherein q is an integer having a value from 2 to 8 and L is selected from the following groups: —N(R 2 )CH 2 —CH 2 —N(R 2 ) 2 ; —N(R 2 ) 2 ; —N(R 2 ) 3 A ⁇ ; —N(R 2 )CH 2 —CH 2 —NR 2 H 2 A ⁇ ; wherein R 2 is hydrogen, phenyl, benzyl, or a
  • Such highly preferred amino silicones can be called as terminal aminosilicones, as one or both ends of the silicone chain are terminated by nitrogen containing group.
  • the above aminosilicones when incorporated into the composition, can be mixed with solvent having a lower viscosity.
  • solvents include, for example, polar or non-polar, volatile or non-volatile oils.
  • oils include, for example, silicone oils, hydrocarbons, and esters.
  • preferred are those selected from the group consisting of non-polar, volatile hydrocarbons, volatile cyclic silicones, non-volatile linear silicones, and mixtures thereof.
  • the non-volatile linear silicones useful herein are those having a viscosity of from about 1 to about 20,000 centistokes, preferably from about 20 to about 10,000 centistokes at 25° C.
  • non-polar, volatile hydrocarbons especially non-polar, volatile isoparaffins
  • Such mixtures have a viscosity of preferably from about 1,000 mPa ⁇ s to about 100,000 mPa ⁇ s, more preferably from about 5,000 mPa ⁇ s to about 50,000 mPa ⁇ s.
  • alkylamino substituted silicone compounds include those having alkylamino substitutions as pendant groups of a silicone backbone. Highly preferred are those known as “amodimethicone”. Commercially available amodimethicones useful herein include, for example, BY 16-872 available from Dow Corning.
  • the silicone compounds may further be incorporated in the present composition in the form of an emulsion, wherein the emulsion is made my mechanical mixing, or in the stage of synthesis through emulsion polymerization, with or without the aid of a surfactant selected from anionic surfactants, nonionic surfactants, cationic surfactants, and mixtures thereof.
  • composition of the present invention may include other additional components, which may be selected by the artisan according to the desired characteristics of the final product and which are suitable for rendering the composition more cosmetically or aesthetically acceptable or to provide them with additional usage benefits.
  • additional components generally are used individually at levels of from about 0.001% to about 10%, preferably up to about 5% by weight of the composition.
  • a wide variety of other additional components can be formulated into the present compositions. These include: other conditioning agents such as hydrolyzed collagen with tradename Peptein 2000 available from Hormel, vitamin E with tradename Emix-d available from Eisai, panthenol available from Roche, panthenyl ethyl ether available from Roche, hydrolyzed keratin, proteins, plant extracts, and nutrients; preservatives such as benzyl alcohol, methyl paraben, propyl paraben and imidazolidinyl urea; pH adjusting agents, such as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; coloring agents, such as any of the FD&C or D&C dyes; perfumes; and sequestering agents, such as disodium ethylenediamine tetra-acetate; ultraviolet and infrared screening and absorbing agents such as benzophenones; and antidandruff agents such as zinc pyrithione.
  • Low melting point oils useful herein are those having a melting point of less than 25° C.
  • the low melting point oil useful herein is selected from the group consisting of: hydrocarbon having from 10 to about 40 carbon atoms; unsaturated fatty alcohols having from about 10 to about 30 carbon atoms such as oleyl alcohol; unsaturated fatty acids having from about 10 to about 30 carbon atoms; fatty acid derivatives; fatty alcohol derivatives; ester oils such as pentaerythritol ester oils including pentaerythritol tetraisostearate, trimethylol ester oils, citrate ester oils, and glyceryl ester oils; poly ⁇ -olefin oils such as polydecenes; and mixtures thereof.
  • the conditioning compositions of the present invention can be in the form of rinse-off products or leave-on products, and can be formulated in a wide variety of product forms, including but not limited to creams, gels, emulsions, mousses and sprays.
  • the conditioning composition of the present invention is especially suitable for rinse-off hair conditioner.
  • the conditioning composition of the present invention is preferably used for a method of conditioning hair, the method comprising following steps:
  • Effective amount herein is, for example, from about 0.1 ml to about 2 ml per 10 g of hair, preferably from about 0.2 ml to about 1.5 ml per 10 g of hair.
  • the conditioning composition of the present invention provides improved conditioning benefits, especially improved wet conditioning benefits after rinsing and improved dry conditioning, while maintaining wet conditioning benefit before rinsing.
  • the conditioning composition of the present invention may also provide improved product appearance to consumer.
  • a reduced dosage of the conditioning composition of the present invention may provide the same level of conditioning benefits as those of a full dosage of conventional conditioner compositions. Such reduced dosage herein is, for example, from about 0.3 ml to about 0.7 ml per 10 g of hair.
  • the present invention is also directed to a method of manufacturing a hair conditioning composition
  • the method further comprises the step of adding additional ingredients such as silicone compounds, perfumes, preservatives, if included, to the gel matrix.
  • additional ingredients such as silicone compounds, perfumes, preservatives, if included
  • the premix has a temperature of from about 25° C., more preferably from about 40° C., still more preferably from about 50° C., even more preferably from about 55° C., further preferably from about 65° C., and to about 150° C., more preferably to about 95° C., still more preferably to about 90° C., even more preferably to about 85° C., when mixing it with the aqueous carrier.
  • the aqueous carrier has a temperature of from about 10° C., more preferably from about 15° C., still more preferably from about 20° C., and to about 65° C., more preferably to about 55° C., still more preferably to about 52° C., when mixing it with the premix.
  • the temperature of the aqueous carrier, when mixing it with the premix is at least about 5° C. lower than, more preferably at least about 10° C. lower than the temperature of the premix.
  • the temperature of the aqueous carrier, when mixing it with the premix is from about 2° C. to about 60° C. lower than, more preferably from about 2° C. to about 40° C. lower than, still more preferably from about 2° C. to about 30° C. lower than the melting point of the high melting point fatty compounds.
  • the premix and the aqueous carrier are mixed by using a high shear homogenizer.
  • high shear homogenizers useful herein include, for example: Sonolator® available from Sonic Corporation, Manton Gaulin type homogenizer available from the APV Manton Corporation, the Microfluidizer available from Microfluidics Corporation, Becomix® available from A. Berents Gmbh&Co.
  • the total amount of the cationic surfactant and the high melting point fatty compound is from about 7.0%, preferably from about 7.5%, more preferably from about 8.0% by weight of the composition, in view of providing the benefits of the present invention, and to about 15%, preferably to about 14%, more preferably to about 13%, still more preferably to about 10% by weight of the composition, in view of spreadability and product appearance.
  • the mixing step (3) comprises the following detailed steps: (3-1) feeding either of the oil phase or the aqueous phase into a high shear field having an energy density of about 1.0 ⁇ 10 2 J/m 3 or more; (3-2) feeding the other phase directly to the field; and (3-3) for an emulsion.
  • the method further requires at least one of the following: the mixing step (3) is conducted by using a homogenizer having a rotating member; the surfactant is a mono-alkyl cationic surfactant and the composition is substantially free of di-alkyl cationic surfactants; and the surfactant is a cationic surfactant and the oil phase contains from 0 to about 50% of the aqueous carrier by weight of the oil phase, preferably the oil phase is substantially free of water.
  • compositions (wt %) Components Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. i Ex. ii Ex. iii Behenyl trimethyl ammonium chloride 2.3 2.8 3.4 — 2.8 2.8 1.8 Behenyl trimethyl ammonium methyl — — — 2.8 — — — — sulfate Cetyl alcohol 1.5 1.9 2.2 1.9 1.9 1.9 1.2 Stearyl alcohol 3.7 4.7 5.5 4.6 4.7 4.7 2.9 Aminosilicone *1 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Isopropanol — 0.6 — 0.6 — — — Dipropylene glycol — — 0.7 — — — — Cetyl hydroxyethyl cellulose *2 — — — — — 0.5 — — Disodium EDTA 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13 Preservatives 0.4 0.4 0.4 0.4
  • compositions of “Ex. 1” through “Ex. 4” and the composition of “Ex. iii” are suitably made as follows:
  • compositions of “Ex. i” and “Ex. ii” as shown above can be prepared by any conventional method well known in the art. They are suitably made as follows:
  • Dry conditioning performance is evaluated by hair friction force measured by an instrument named Instron Tester (Instron 5542, Instron, Inc,; Canton, Mass., USA). 2 g of the composition is applied to 20 g of hair sample. After spreading the composition on the hair sample, rinsing it with warm water for 30 seconds, and the hair sample is left to dry over night. The friction force (g) between the hair surface and a urethane pad along the hair is measured.
  • the product appearance is evaluated by 6 panelists, when dispensing 0.4 ml of a conditioner product from a package.
  • the embodiments disclosed and represented by the previous “Ex. 1” through “Ex. 4” are hair conditioning compositions of the present invention which are particularly useful for rinse-off use. Such embodiments have many advantages. For example, they provide improved conditioning benefits, especially improved wet conditioning benefits after rinsing and improved dry conditioning, while maintaining wet conditioning benefit before rinsing.

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US13/525,691 US8828370B2 (en) 2008-06-25 2012-06-18 Hair conditioning composition having higher yield point and higher conversion rate of fatty compound to gel matrix
US14/462,131 US10413497B2 (en) 2008-06-25 2014-08-18 Hair conditioning composition having higher yield point and higher conversion rate of fatty compound to gel matrix

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