US20090315122A1 - Semiconductor device having ohmic recessed electrode - Google Patents
Semiconductor device having ohmic recessed electrode Download PDFInfo
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- US20090315122A1 US20090315122A1 US12/549,860 US54986009A US2009315122A1 US 20090315122 A1 US20090315122 A1 US 20090315122A1 US 54986009 A US54986009 A US 54986009A US 2009315122 A1 US2009315122 A1 US 2009315122A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
- H01L29/7786—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT
- H01L29/7787—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT with wide bandgap charge-carrier supplying layer, e.g. direct single heterostructure MODFET
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28575—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising AIIIBV compounds
- H01L21/28587—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising AIIIBV compounds characterised by the sectional shape, e.g. T, inverted T
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/417—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions carrying the current to be rectified, amplified or switched
- H01L29/41725—Source or drain electrodes for field effect devices
- H01L29/41766—Source or drain electrodes for field effect devices with at least part of the source or drain electrode having contact below the semiconductor surface, e.g. the source or drain electrode formed at least partially in a groove or with inclusions of conductor inside the semiconductor
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66446—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
- H01L29/66462—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table
- H01L29/1608—Silicon carbide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/20—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
- H01L29/2003—Nitride compounds
Definitions
- the present invention relates to a technique for reducing the ohmic resistance of an ohmic electrode having a recessed structure and formed in a semiconductor device.
- the present invention may be applied to the source electrode and drain electrode of a High Electron Mobility Transistor (HEMT), for example.
- HEMT High Electron Mobility Transistor
- a HEMT is known as a type of Field Effect Transistor (FET).
- FET Field Effect Transistor
- a feature of a HEMT is that a current path is formed by a two-dimensional electron gas layer generated on the interface between two types of semiconductor film having different band gaps.
- a HEMT comprises a channel-forming layer formed on a substrate and a Schottky layer formed on the channel-forming layer. Films having different band gaps are used as the channel-forming layer and Schottky layer. For example, a GaN film may be used as the channel-forming layer, and an AlGaN film may be used as the Schottky layer. The two-dimensional electron gas layer is formed on the interface between the channel-forming layer and the Schottky layer.
- a cap layer is formed on the surface of the Schottky layer.
- a source electrode, a drain electrode, and a gate electrode are disposed on the cap layer.
- the source electrode and drain electrode are ohmic electrodes.
- the gate electrode When a potential is applied to the gate electrode, a depletion layer is formed in the two-dimensional electron gas layer. A current flowing between the source electrode and the drain electrode is controlled by the depletion layer. In the two-dimensional electron gas layer, electron mobility is much greater than that of a normal semiconductor. Therefore, the HEMT operates at a higher speed than a typical FET.
- contact resistance between the ohmic electrodes and the two-dimensional electron gas layer is preferably reduced.
- Ohmic contact resistance between a metal electrode and a semiconductor may be calculated using the following Equation (1). This calculation method is disclosed in “3. Ultra High Speed Compound Semiconductor Devices”, edited by Masamichi Omori and supervised by Takuo Sugano, Baifukan, 6.2 Electrode Formation Technology (p. 196-202).
- Rc is ohmic contact resistance (ohm ⁇ mm)
- ⁇ c is contact resistivity (ohm ⁇ cm 2 )
- ⁇ is sheet resistance (ohm/sq)
- W is the gate width, and therefore the ohmic electrode width
- L is the ohmic electrode length.
- Le is the ohmic electrode length when the current flowing into the ohmic electrodes is 1/e of the entire current.
- an ohmic recess structure As a third technique for reducing ohmic contact resistance between a metal electrode and a semiconductor, an ohmic recess structure is known.
- an ohmic recess structure an ohmic electrode is buried in a recess formed in the surface of the semiconductor layer.
- K. Kaifu et al. 2005 The Electrochemical Society, “AlGaN/GaN HEMTs with Recessed Ohmic Electrodes on Si Substrates”, ECS Transactions Vol. 1, No. 2, pp. 259-265 is known as a document which discloses an ohmic recess structure.
- K. Kaifu et al. disclose a HEMT employing an ohmic recess in FIG. 2 thereof. As shown in this drawing, an ohmic electrode is buried in a recess formed in a GaN thin film by etching. K. Kaifu et al. reduce ohmic resistance by causing the two-dimensional electron gas layer to contact the bottom surface of the ohmic electrode directly.
- An object of the present invention is to provide a semiconductor device in which the electric resistance of an ohmic contact formed between a semiconductor film and an ohmic electrode can be reduced sufficiently, and in which variation in the ohmic resistance value caused by manufacturing irregularities is small.
- a semiconductor device comprises: a channel-forming layer formed on a semiconductor substrate; a Schottky layer formed on the channel-forming layer; a two-dimensional electron gas layer formed on an interface between the Schottky layer and the channel-forming layer by an electron supplied to the channel-forming layer from the Schottky layer; a gate electrode formed on the Schottky layer via a cap layer; and a recess-structured ohmic electrode containing a plurality of side faces which are in ohmic contact with the two-dimensional electron gas layer and non-parallel to a channel width direction.
- FIG. 1 is a plan view showing an outline of the structure of a semiconductor device according to a first embodiment
- FIG. 2A is an A-A′ sectional view of FIG. 1 ;
- FIG. 2B is a B-B′ sectional view of FIG. 1 ;
- FIG. 3A is a plan view illustrating a manufacturing process for the semiconductor device according to the first embodiment
- FIG. 3B is an I-I′ sectional view of FIG. 3A ;
- FIG. 4A is a plan view illustrating the manufacturing process for the semiconductor device according to the first embodiment
- FIG. 4B is a C-C′ sectional view of FIG. 4A ;
- FIG. 4C is a D-D′ sectional view of FIG. 4A ;
- FIGS. 5A and 5B are sectional views illustrating the manufacturing process for the semiconductor device according to the first embodiment
- FIG. 6 is a plan view showing an outline of the structure of a semiconductor device according to a second embodiment
- FIG. 7 is an E-E′ sectional view of FIG. 6 ;
- FIG. 8A is a plan view illustrating a manufacturing process for the semiconductor device according to the second embodiment
- FIG. 8B is an F-F′ sectional view of FIG. 8A ;
- FIG. 9 is a sectional view illustrating the manufacturing process for the semiconductor device according to the second embodiment.
- a semiconductor device according to a first embodiment of the present invention will be described below using an example in which the present invention is applied to a GaN-HEMT, or in other words a HEMT using a GaN layer as a semiconductor layer.
- FIGS. 1 , 2 A, and 2 B show an outline of the structure of the GaN-HEMT according to this embodiment.
- FIG. 1 is a plan view
- FIG. 2A is an A-A′ sectional view of FIG. 1
- FIG. 2B is a B-B′ sectional view of FIG. 1 .
- a GaN-HEMT 100 of this embodiment comprises laminated layers, including a buffer layer 102 , a channel-forming layer 103 , a Schottky layer 104 , and a cap layer 105 , formed on a semiconductor substrate 101 .
- An isolation region 106 , a source electrode 107 , a drain electrode 108 , and a gate electrode 109 are formed on the laminated layers.
- a substrate such as an SiC substrate, a sapphire substrate, or a silicon substrate is used, For example.
- the buffer layer 102 is a layer for obtaining enough property of the channel-forming layer 103 .
- the buffer layer 102 should be formed on the semiconductor substrate 101 to suppress the occur of the dislocation in the channel-forming layer 103 .
- the buffer layer 102 of GaN-HEMT may be formed by depositing GaN, AlGaN, AlN or the like.
- the buffer layer 102 which is formed by depositing GaN at high temperature, and the thickness of which is 2 ⁇ m at least, may be employed.
- the channel-forming layer 103 is a layer for forming a channel, or in other words a current path.
- a high-resistance GaN film for example, may be used as the channel-forming layer 103 .
- the Schottky layer 104 is a layer for generating electrodes for a two-dimensional electron gas. Since the electrons of the Schottky layer 104 move to the channel-forming layer 103 , a two-dimensional electron gas layer 110 is formed on the interface between the layers 103 and 104 .
- the two-dimensional electron gas layer 110 serves as the channel of the HEMT 100 .
- a high-resistance AlGaN film, for example, may be used as the Schottky layer 104 .
- the cap layer 105 is a layer for preventing oxidation of the Schottky layer 104 .
- the device characteristics of the GaN-HEMT 100 improves by forming the cap layer 105 .
- a GaN film, for example, may be used as the cap layer 105 .
- the isolation region 106 is formed for separating the GaN-HEMT 100 from other elements formed on the semiconductor substrate 101 .
- the isolation region 106 may be formed by the ion implantation of Ar, N or O, for example.
- the source electrode 107 is an ohmic electrode for supplying electrons to the two-dimensional electron gas layer 110 .
- the source electrode 107 comprises a lower portion 107 a buried in the laminated layers 103 to 105 , and an upper portion 107 b exposed on the surface of the layer 105 .
- the drain electrode 108 is an ohmic electrode for receiving electrons from the two-dimensional electron gas layer 110 .
- the drain electrode 108 comprises a lower portion 108 a buried in the laminated layers 103 to 105 , and an upper portion 108 b exposed on the surface of the layer 105 .
- the source electrode 107 and drain electrode 108 are formed by laminating together a titanium film and an aluminum film.
- the thickness of the titanium film is 15 nm, for example, and the thickness of the aluminum film is 100 nm, for example.
- the electrodes 107 , 108 are formed to deeper positions than the two-dimensional electron gas layer 110 .
- the respective side faces of the electrodes 107 , 108 can be brought into direct contact with the two-dimensional electron gas layer 110 .
- the electrodes 107 , 108 may be disposed in direct contact with the isolation region 106 .
- the side of each of the electrodes 107 , 108 which contacts the two-dimensional electron gas layer 110 i.e. the side which faces the other electrode, comprises a plurality of faces that are non-parallel to the channel direction.
- the contact side between the source electrode 107 and the two-dimensional electron gas layer 110 has a saw tooth form
- the contact surface between the drain electrode 108 and the two-dimensional electron gas layer 110 has a comb tooth form
- Both of the electrodes 107 , 108 may take saw tooth forms and both of the electrodes 107 , 108 may take comb tooth forms.
- Other non-planar forms such as a waveform, for example, maybe employed.
- the effects of the present invention can be obtained using any form, as long as the contact area between the electrodes 107 , 108 and the two-dimensional electron gas layer 110 is greater than that of a planar form.
- the pitch of the saw tooth form and comb tooth form There are no limitations on the pitch of the saw tooth form and comb tooth form. For example , if the gate length is 1 ⁇ m, the pitch may be set at 4 ⁇ m.
- the gate electrode 109 is an electrode for forming a depletion layer in the two-dimensional electron gas layer 110 .
- the ON/OFF status or the drain current value of the HEMT 100 is controlled by the depletion layer.
- the gate electrode 109 is formed by laminating together a nickel film and a gold film, for example.
- FIGS. 3A to 5B are views illustrating the manufacturing process for the HEMT 100 according to the present embodiment.
- FIG. 3A is a plan view
- FIG. 3B is an I-I′ sectional view of FIG. 3A
- FIG. 4A is a plan view
- FIG. 4B is a C-C′ sectional view of FIG. 4A
- FIG. 4C is a D-D′ sectional view of FIG. 4A
- FIG. 5A is a sectional view corresponding to FIG. 4B
- FIG. 5B is a sectional view corresponding to FIG. 4C .
- the buffer layer 102 , channel-forming layer 103 , Schottky layer 104 , and cap layer 105 are formed on the semiconductor substrate 101 , and then, using a ion implantation and other techniques, for example, the isolation region 106 is formed (see FIGS. 3A and 3B ).
- a resist pattern is formed using a normal photolithography method.
- Recesses 401 , 402 are then formed in the surface of the substrate 101 by etching using the resist pattern as a mask.
- the recesses 401 , 402 are formed to deeper positions than the two-dimensional electron gas layer 110 . In a typical HEMT, the depth of the recesses 401 , 402 is approximately 50 nm at most.
- the recesses 401 , 402 are formed in direct contact with the isolation region 106 .
- the right side of the recess 401 i.e.
- the side opposing the recess 402 is formed in a saw tooth shape, while the left side of the recess 402 , i.e. the side opposing the recess 401 , is formed in a comb tooth shape.
- ICP-RIE Inductive Coupled Plasma Reactive Ion Etching
- the reason for this is that with this etching technique, damage to the two-dimensional electron gas layer 110 is small.
- the etching may be performed using BC13 as an etching gas under the following conditions.
- the resist pattern is then removed, whereby the formation process of the recesses 401 , 402 is complete (see FIGS. 4A , 4 B, and 4 C).
- the source electrode 107 and drain electrode 108 are formed in the recesses 401 , 402 .
- the electrodes 107 , 108 are formed using a lift-off method. In this lift-off process, first a resist pattern exposing the recesses 401 , 402 and the periphery thereof is formed using a normal photolithography method.
- a titanium film and an aluminum film are formed consecutively in the recesses 401 , 402 and the periphery thereof by vacuum deposition using the resist pattern as a mask.
- the thickness of the titanium film is 15 nm, for example, while the thickness of the aluminum film is 100 nm, for example.
- the electrodes 107 , 108 are preferably formed with flat upper faces. The reason for this is that if hollows exist on the upper face of the electrodes 107 , 108 , a malfunction is more likely to occur in the HEMT.
- the resist pattern is then removed.
- the substrate 101 is then subjected to heat treatment in a nitrogen atmosphere.
- the heating temperature is 600° C., for example, and the heating time is two minutes, for example.
- the formation process of the source electrode 107 and drain electrode 108 is complete (see FIGS. 5A and 5B ).
- the gate electrode 109 is formed on the cap layer 105 using a lift-off method.
- a resist pattern exposing only the formation region of the gate electrode 109 is formed on the cap layer 105 using a normal photolithography method.
- the gate electrode 109 is preferably formed in the center of a region sandwiched between the electrodes 107 , 108 . Accordingly, the resist pattern is formed so as to expose only the center of the region between the electrodes 107 , 108 .
- a nickel film and a gold film are formed consecutively by vacuum deposition using the resist pattern as a mask.
- the resist pattern is then removed.
- the substrate 101 is then subjected to heat treatment in a nitrogen atmosphere.
- the heating temperature is 400° C., for example, and the heating time is two minutes, for example.
- the HEMT 100 shown in FIGS. 1 , 2 A, and 2 B is complete.
- the contact surface between the source electrode 107 and the two-dimensional electron gas layer 110 is formed in a saw tooth shape, and the contact surface between the drain electrode 108 and two-dimensional electron gas layer 110 is formed in a comb tooth shape.
- this embodiment is capable of providing the HEMT 100 , in which the practical gate width is increased beyond that of a conventional HEMT without altering the size of the HEMT.
- the value of the gate width W in Equation (1) is greater than that of a conventional HEMT.
- this embodiment is capable of providing the HEMT 100 , in which the ohmic resistance of the source electrode 107 and drain electrode 108 is small.
- the bottom faces of the ohmic electrodes do not have to contact the two-dimensional electron gas layer, and therefore variation in the ohmic resistance value caused by manufacturing irregularities is small.
- a semiconductor device according to a second embodiment of the present invention will be described using an example in which the present invention is applied to a GaN-HEMT, or in other words a HEMT using a GaN layer as a semiconductor layer.
- FIGS. 6 and 7 show an outline of the structure of the GaN-HEMT according to this embodiment.
- FIG. 6 is a plan view
- FIG. 7 is an E-E′ sectional view of FIG. 6 .
- constitutional elements having identical reference numerals to those of FIGS. 1 to 2B are identical to the corresponding elements in FIGS. 1 to 2B .
- a HEMT 600 according to this embodiment differs from the HEMT 100 according to the first embodiment in the structure of the source electrode and drain electrode.
- a source electrode 610 and a drain electrode 620 are ohmic electrodes.
- the source electrode 610 comprises a plurality of lower portion electrodes 611 and a single upper portion electrode 612 .
- the drain electrode 620 comprises a plurality of lower portion electrodes 621 and a single upper portion electrode 622 .
- the lower portion electrodes 611 , 621 are buried in the laminated films formed on the substrate 101 .
- the upper portion electrode 612 is electrically connected to all of the lower portion electrodes 611
- the upper portion electrode 622 is electrically connected to all of the lower portion electrodes 621 .
- the lower portion electrodes 611 , 621 are formed to deeper positions than the two-dimensional electron gas layer 110 .
- the side faces of the lower portion electrodes 611 , 621 can be brought into direct contact with the two-dimensional electron gas layer 110 .
- the lower portion electrodes 611 , 621 may directly contact the isolation region 106 .
- the lower portion electrodes 611 , 621 are formed in a columnar form such as a square column or circular column, for example.
- the effects of the present invention can be obtained using any form, as long as the contact area between the electrodes 610 , 620 and the two-dimensional electron gas layer 110 is greater than that of a conventional HEMT.
- the pitch of the lower portion electrodes 611 , 621 There are no limitations on the pitch of the lower portion electrodes 611 , 621 . For example, if the gate length is 1 ⁇ m, the pitch may be set at 1 ⁇ m.
- the lower portion electrodes 611 , 621 do not have to be disposed in a matrix form or at fixed intervals.
- the source electrode 610 and drain electrode 620 are formed by laminating together a titanium film and an aluminum film.
- the thickness of the titanium film is 15 nm, for example, and the thickness of the aluminum film is 100 nm, for example.
- FIGS. 8A to 9 are views illustrating the manufacturing process for the HEMT 600 according to this embodiment.
- FIG. 8A is a plan view
- FIG. 8B is an F-F′ sectional view of FIG. 8A
- FIG. 9 is a sectional view corresponding to FIG. 8B .
- the buffer layer 102 , channel-forming layer 103 , Schottky layer 104 , and cap layer 105 are formed on the semiconductor substrate 101 using a normal thin film formation technique, and then, using a ion implantation and other techniques, for example, the isolation region 106 is formed.
- a resist pattern is formed using a normal photolithography method.
- a plurality of recesses 801 , 801 , . . . and a plurality of recesses 802 , 802 , . . . are then formed in the surface of the substrate 101 by etching using the resist pattern as a mask.
- the recesses 801 , 802 are formed to deeper positions than the two-dimensional electron gas layer 110 . In a typical HEMT, the depth of the recesses 801 , 802 is approximately 50 nm at most.
- the etching method and conditions may be identical to those of the first embodiment.
- the resist pattern is then removed, whereby the formation process of the recesses 801 , 802 is complete (see FIGS. 8A and 8B ).
- the source electrode 610 and drain electrode 620 are formed in the recesses 801 , 802 using a lift-off method.
- a resist pattern exposing the recesses 801 , 802 and the periphery thereof is formed using a normal photolithography method.
- a titanium film and an aluminum film are formed consecutively in the recesses 801 , 802 and the periphery thereof by vacuum deposition using the resist pattern as a mask.
- the thickness of the titanium film is 15 nm, for example, while the thickness of the aluminum film is 100 nm, for example.
- the lower portion electrodes 611 , 621 and the upper portion electrodes 612 , 622 are formed simultaneously in a single step.
- the upper portion electrodes 612 , 622 are preferably formed with flat upper faces. The reason for this is that if recesses exist on the upper face of the upper portion electrodes 612 , 622 , a malfunction is more likely to occur in the HEMT.
- the resist pattern is then removed.
- the substrate 101 is then subjected to heat treatment in a nitrogen atmosphere.
- the heating temperature is 600° C., for example, and the heating time is two minutes, for example.
- the formation process of the source electrode 610 and drain electrode 620 is complete (see FIG. 9 ).
- the gate electrode 109 is formed on the cap layer 105 using a lift-off method.
- a resist pattern exposing only the formation region of the gate electrode 109 is formed on the cap layer 105 using a normal photolithography method.
- the gate electrode 109 is preferably formed in the center of a region sandwiched between the electrodes 610 , 620 . Accordingly, the resist pattern is formed so as to expose only the center of the region between the electrodes 610 , 620 .
- a nickel film and a gold film are formed consecutively by vacuum deposition using the resist pattern as a mask.
- the resist pattern is then removed.
- the substrate 101 is then subjected to heat treatment in a nitrogen atmosphere.
- the heating temperature is 400° C., for example, and the heating time is two minutes, for example.
- the HEMT 600 shown in FIGS. 8A to 9 is complete.
- the ohmic electrodes 610 , 620 comprise the plurality of columnar lower portion electrodes 611 , 621 , respectively.
- the contact area between the ohmic electrodes 610 , 620 and the two-dimensional electron gas layer 110 is even larger than that of the HEMT 100 according to the first embodiment.
- the bottom faces of the ohmic electrodes do not have to be brought into contact with the two-dimensional electron gas layer, and therefore variation in the ohmic resistance value caused by manufacturing irregularities is small.
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Abstract
The present invention provides a semiconductor device having a recess-structured ohmic electrode, in which the resistance is small and variation in the resistance value caused by manufacturing irregularities is small. In the semiconductor device of the present invention, a two-dimensional electron gas layer is formed on the interface between a channel-forming layer and a Schottky layer by electrons supplied from the Schottky layer. The ohmic electrode comprises a plurality of side faces in ohmic contact with the two-dimensional electron gas layer. At least a part of side faces of the ohmic electrodes are non-parallel to a channel width direction. In a preferred embodiment of the present invention, the side faces have a saw tooth form or a comb tooth form. Since the contact area between the ohmic electrode and the two-dimensional electron gas layer is increased, ohmic resistance is reduced.
Description
- This application is a divisional of U.S. patent application Ser. No. 11/636,430, filed Dec. 11, 2006, the subject matter of which application is incorporated herein by reference in its entirety, which claims the benefit of Japanese Patent Application No. 2005-357589, filed on Dec. 12, 2005, in the Japanese Patent Office, the disclosure of which is incorporated herein in its entirety by reference.
- 1. Field of the Invention
- The present invention relates to a technique for reducing the ohmic resistance of an ohmic electrode having a recessed structure and formed in a semiconductor device. The present invention may be applied to the source electrode and drain electrode of a High Electron Mobility Transistor (HEMT), for example.
- 2. Description of Related Art
- In the prior art, a HEMT is known as a type of Field Effect Transistor (FET). A feature of a HEMT is that a current path is formed by a two-dimensional electron gas layer generated on the interface between two types of semiconductor film having different band gaps.
- Typically, a HEMT comprises a channel-forming layer formed on a substrate and a Schottky layer formed on the channel-forming layer. Films having different band gaps are used as the channel-forming layer and Schottky layer. For example, a GaN film may be used as the channel-forming layer, and an AlGaN film may be used as the Schottky layer. The two-dimensional electron gas layer is formed on the interface between the channel-forming layer and the Schottky layer.
- A cap layer is formed on the surface of the Schottky layer. A source electrode, a drain electrode, and a gate electrode are disposed on the cap layer. The source electrode and drain electrode are ohmic electrodes.
- When a potential is applied to the gate electrode, a depletion layer is formed in the two-dimensional electron gas layer. A current flowing between the source electrode and the drain electrode is controlled by the depletion layer. In the two-dimensional electron gas layer, electron mobility is much greater than that of a normal semiconductor. Therefore, the HEMT operates at a higher speed than a typical FET.
- To improve the characteristics of the HEMT, contact resistance between the ohmic electrodes and the two-dimensional electron gas layer is preferably reduced.
- Ohmic contact resistance between a metal electrode and a semiconductor may be calculated using the following Equation (1). This calculation method is disclosed in “3. Ultra High Speed Compound Semiconductor Devices”, edited by Masamichi Omori and supervised by Takuo Sugano, Baifukan, 6.2 Electrode Formation Technology (p. 196-202).
-
Rc=((ρc×ρ□)0.5 /w×(1−e −L/Le)−1 (1) - In Equation (1), Rc is ohmic contact resistance (ohm×mm), ρc is contact resistivity (ohm×cm2), ρ□ is sheet resistance (ohm/sq), W is the gate width, and therefore the ohmic electrode width, and L is the ohmic electrode length. Further, Le is the ohmic electrode length when the current flowing into the ohmic electrodes is 1/e of the entire current.
- It is usually believed that if L is 3×Le or more, the ohmic contact resistance can be sufficiently reduced. When L=3×Le, 1−e−L/Le=0.95. Hence, when L is sufficiently longer than Le, the following Equation (2) is approximately established.
-
Rc=(ρc×ρ□)0.5 /w) (2) - The value of Le varies according to the sheet resistance and electron mobility of the two-dimensional electron gas layer. For example, when the sheet resistance is 400 ohm and the electron mobility is 4000 cm2/Vs, Le=1.5 μm. Le increases as the electron mobility of the two-dimensional electron gas layer decreases, and therefore the length L of the ohmic electrodes must be increased. For example, when the channel-forming layer is formed from GaN and the Schottky layer is formed from AlGaN, the electron mobility is approximately 1500 cm2/Vs. Hence, in a HEMT using a hetero junction of AlGaN and GaN, the source electrode and drain electrode must be made extremely long.
- As another technique for reducing ohmic contact resistance between a metal electrode and a semiconductor, a method of alloying the contact surfaces is known. However, when semiconductors having a large energy gap are used, the energy required for alloying is extremely large, and therefore the alloying is difficult. In a HEMT using a hetero-junction of AlGaN and GaN, alloying is essentially impossible.
- As a third technique for reducing ohmic contact resistance between a metal electrode and a semiconductor, an ohmic recess structure is known. In an ohmic recess structure, an ohmic electrode is buried in a recess formed in the surface of the semiconductor layer. For example, K. Kaifu et al. 2005 The Electrochemical Society, “AlGaN/GaN HEMTs with Recessed Ohmic Electrodes on Si Substrates”, ECS Transactions Vol. 1, No. 2, pp. 259-265 is known as a document which discloses an ohmic recess structure.
- K. Kaifu et al. disclose a HEMT employing an ohmic recess in
FIG. 2 thereof. As shown in this drawing, an ohmic electrode is buried in a recess formed in a GaN thin film by etching. K. Kaifu et al. reduce ohmic resistance by causing the two-dimensional electron gas layer to contact the bottom surface of the ohmic electrode directly. - However, according to an investigation conducted by the present inventor, the electric resistance of an ohmic contact formed between a semiconductor film and an ohmic electrode cannot be reduced sufficiently with the technique disclosed in K. Kaifu et al. This technique is also disadvantaged in that variation in the ohmic resistance value caused by manufacturing irregularities is large.
- An object of the present invention is to provide a semiconductor device in which the electric resistance of an ohmic contact formed between a semiconductor film and an ohmic electrode can be reduced sufficiently, and in which variation in the ohmic resistance value caused by manufacturing irregularities is small.
- To achieve this object, a semiconductor device according to the present invention comprises: a channel-forming layer formed on a semiconductor substrate; a Schottky layer formed on the channel-forming layer; a two-dimensional electron gas layer formed on an interface between the Schottky layer and the channel-forming layer by an electron supplied to the channel-forming layer from the Schottky layer; a gate electrode formed on the Schottky layer via a cap layer; and a recess-structured ohmic electrode containing a plurality of side faces which are in ohmic contact with the two-dimensional electron gas layer and non-parallel to a channel width direction.
- Other objects and advantages of the present invention will be described with reference to the following attached drawings, in which:
-
FIG. 1 is a plan view showing an outline of the structure of a semiconductor device according to a first embodiment; -
FIG. 2A is an A-A′ sectional view ofFIG. 1 ; -
FIG. 2B is a B-B′ sectional view ofFIG. 1 ; -
FIG. 3A is a plan view illustrating a manufacturing process for the semiconductor device according to the first embodiment; -
FIG. 3B is an I-I′ sectional view ofFIG. 3A ; -
FIG. 4A is a plan view illustrating the manufacturing process for the semiconductor device according to the first embodiment; -
FIG. 4B is a C-C′ sectional view ofFIG. 4A ; -
FIG. 4C is a D-D′ sectional view ofFIG. 4A ; -
FIGS. 5A and 5B are sectional views illustrating the manufacturing process for the semiconductor device according to the first embodiment; -
FIG. 6 is a plan view showing an outline of the structure of a semiconductor device according to a second embodiment; -
FIG. 7 is an E-E′ sectional view ofFIG. 6 ; -
FIG. 8A is a plan view illustrating a manufacturing process for the semiconductor device according to the second embodiment; -
FIG. 8B is an F-F′ sectional view ofFIG. 8A ; and -
FIG. 9 is a sectional view illustrating the manufacturing process for the semiconductor device according to the second embodiment. - Embodiments of the present invention will be described below using the drawings. In the drawings, the size, shape, and positional relationships of the various constitutional components are illustrated schematically to a degree which facilitates understanding of the present invention, and the numerical conditions described below are merely examples.
- A semiconductor device according to a first embodiment of the present invention will be described below using an example in which the present invention is applied to a GaN-HEMT, or in other words a HEMT using a GaN layer as a semiconductor layer.
-
FIGS. 1 , 2A, and 2B show an outline of the structure of the GaN-HEMT according to this embodiment.FIG. 1 is a plan view,FIG. 2A is an A-A′ sectional view ofFIG. 1 , andFIG. 2B is a B-B′ sectional view ofFIG. 1 . - As shown in
FIGS. 1 , 2A, and 2B, a GaN-HEMT 100 of this embodiment comprises laminated layers, including abuffer layer 102, a channel-forminglayer 103, aSchottky layer 104, and acap layer 105, formed on asemiconductor substrate 101. Anisolation region 106, asource electrode 107, adrain electrode 108, and agate electrode 109 are formed on the laminated layers. - As the
semiconductor substrate 101, a substrate such as an SiC substrate, a sapphire substrate, or a silicon substrate is used, For example. - The
buffer layer 102 is a layer for obtaining enough property of the channel-forminglayer 103. When the lattice constants of thesemiconductor substrate 101 and the channel-forminglayer 103 are different, thebuffer layer 102 should be formed on thesemiconductor substrate 101 to suppress the occur of the dislocation in the channel-forminglayer 103. Thebuffer layer 102 of GaN-HEMT may be formed by depositing GaN, AlGaN, AlN or the like. In the case where thesemiconductor layer 101 is made from SiC in which the lattice constant is 3.08 angstrom and the channel-forminglayer 103 is formed from GaN in which the lattice constant is 3.189 angstrom, thebuffer layer 102 which is formed by depositing GaN at high temperature, and the thickness of which is 2 μm at least, may be employed. - The channel-forming
layer 103 is a layer for forming a channel, or in other words a current path. A high-resistance GaN film, for example, may be used as the channel-forminglayer 103. - The
Schottky layer 104 is a layer for generating electrodes for a two-dimensional electron gas. Since the electrons of theSchottky layer 104 move to the channel-forminglayer 103, a two-dimensionalelectron gas layer 110 is formed on the interface between thelayers electron gas layer 110 serves as the channel of theHEMT 100. A high-resistance AlGaN film, for example, may be used as theSchottky layer 104. - The
cap layer 105 is a layer for preventing oxidation of theSchottky layer 104. The device characteristics of the GaN-HEMT 100 improves by forming thecap layer 105. A GaN film, for example, may be used as thecap layer 105. - The
isolation region 106 is formed for separating the GaN-HEMT 100 from other elements formed on thesemiconductor substrate 101. Theisolation region 106 may be formed by the ion implantation of Ar, N or O, for example. - The
source electrode 107 is an ohmic electrode for supplying electrons to the two-dimensionalelectron gas layer 110. Thesource electrode 107 comprises alower portion 107 a buried in thelaminated layers 103 to 105, and anupper portion 107 b exposed on the surface of thelayer 105. Thedrain electrode 108 is an ohmic electrode for receiving electrons from the two-dimensionalelectron gas layer 110. Thedrain electrode 108 comprises alower portion 108 a buried in thelaminated layers 103 to 105, and anupper portion 108 b exposed on the surface of thelayer 105. In this embodiment, as will be described below, thesource electrode 107 anddrain electrode 108 are formed by laminating together a titanium film and an aluminum film. The thickness of the titanium film is 15 nm, for example, and the thickness of the aluminum film is 100 nm, for example. As shown inFIGS. 1 , 2A, and 2B, theelectrodes electron gas layer 110. As a result, the respective side faces of theelectrodes electron gas layer 110. Further, theelectrodes isolation region 106. The side of each of theelectrodes electron gas layer 110, i.e. the side which faces the other electrode, comprises a plurality of faces that are non-parallel to the channel direction. In this embodiment, the contact side between thesource electrode 107 and the two-dimensionalelectron gas layer 110 has a saw tooth form, while the contact surface between thedrain electrode 108 and the two-dimensionalelectron gas layer 110 has a comb tooth form. Both of theelectrodes electrodes electrodes electron gas layer 110 is greater than that of a planar form. There are no limitations on the pitch of the saw tooth form and comb tooth form. For example , if the gate length is 1 μm, the pitch may be set at 4 μm. - The
gate electrode 109 is an electrode for forming a depletion layer in the two-dimensionalelectron gas layer 110. The ON/OFF status or the drain current value of theHEMT 100 is controlled by the depletion layer. Thegate electrode 109 is formed by laminating together a nickel film and a gold film, for example. - A manufacturing process for the
HEMT 100 according to the present embodiment will now be described.FIGS. 3A to 5B are views illustrating the manufacturing process for theHEMT 100 according to the present embodiment.FIG. 3A is a plan view,FIG. 3B is an I-I′ sectional view ofFIG. 3A ,FIG. 4A is a plan view,FIG. 4B is a C-C′ sectional view ofFIG. 4A , andFIG. 4C is a D-D′ sectional view ofFIG. 4A .FIG. 5A is a sectional view corresponding toFIG. 4B , andFIG. 5B is a sectional view corresponding toFIG. 4C . - First, using a normal thin film formation technique, the
buffer layer 102, channel-forminglayer 103,Schottky layer 104, andcap layer 105 are formed on thesemiconductor substrate 101, and then, using a ion implantation and other techniques, for example, theisolation region 106 is formed (seeFIGS. 3A and 3B ). - Next, a resist pattern, not shown in the drawing, is formed using a normal photolithography method.
Recesses substrate 101 by etching using the resist pattern as a mask. Therecesses electron gas layer 110. In a typical HEMT, the depth of therecesses recesses isolation region 106. The right side of therecess 401, i.e. the side opposing therecess 402, is formed in a saw tooth shape, while the left side of therecess 402, i.e. the side opposing therecess 401, is formed in a comb tooth shape. Inductive Coupled Plasma Reactive Ion Etching (ICP-RIE) is preferably employed as the etching method. The reason for this is that with this etching technique, damage to the two-dimensionalelectron gas layer 110 is small. The etching may be performed using BC13 as an etching gas under the following conditions. -
- Etching gas flow rate: 20 sccm
- Gas pressure: 40 mTorr
- Power of Inductive Coupled Plasma: 50 watts
- Power of Reactive Ion Etching: 30 watts
- Frequency: 13.56 megahertz
- Etching time: 10 to 15 minutes
- The resist pattern is then removed, whereby the formation process of the
recesses FIGS. 4A , 4B, and 4C). - Next, the
source electrode 107 anddrain electrode 108 are formed in therecesses electrodes recesses - Next, a titanium film and an aluminum film are formed consecutively in the
recesses electrodes electrodes - The resist pattern is then removed.
- If necessary, the
substrate 101 is then subjected to heat treatment in a nitrogen atmosphere. In this heat treatment, the heating temperature is 600° C., for example, and the heating time is two minutes, for example. Following the heat treatment, the formation process of thesource electrode 107 anddrain electrode 108 is complete (seeFIGS. 5A and 5B ). - Next, the
gate electrode 109 is formed on thecap layer 105 using a lift-off method. In this lift-off process, first a resist pattern exposing only the formation region of thegate electrode 109 is formed on thecap layer 105 using a normal photolithography method. Thegate electrode 109 is preferably formed in the center of a region sandwiched between theelectrodes electrodes - Next, a nickel film and a gold film are formed consecutively by vacuum deposition using the resist pattern as a mask.
- The resist pattern is then removed.
- If necessary, the
substrate 101 is then subjected to heat treatment in a nitrogen atmosphere. In this heat treatment, the heating temperature is 400° C., for example, and the heating time is two minutes, for example. Following the heat treatment, theHEMT 100 shown inFIGS. 1 , 2A, and 2B is complete. - In the
HEMT 100 according to this embodiment, as described above, the contact surface between thesource electrode 107 and the two-dimensionalelectron gas layer 110 is formed in a saw tooth shape, and the contact surface between thedrain electrode 108 and two-dimensionalelectron gas layer 110 is formed in a comb tooth shape. Hence, this embodiment is capable of providing theHEMT 100, in which the practical gate width is increased beyond that of a conventional HEMT without altering the size of the HEMT. In other words, with theHEMT 100 of this embodiment, the value of the gate width W in Equation (1) is greater than that of a conventional HEMT. Thus, this embodiment is capable of providing theHEMT 100, in which the ohmic resistance of thesource electrode 107 anddrain electrode 108 is small. - In addition, with the
HEMT 100 of this embodiment, the bottom faces of the ohmic electrodes do not have to contact the two-dimensional electron gas layer, and therefore variation in the ohmic resistance value caused by manufacturing irregularities is small. - Next, a semiconductor device according to a second embodiment of the present invention will be described using an example in which the present invention is applied to a GaN-HEMT, or in other words a HEMT using a GaN layer as a semiconductor layer.
-
FIGS. 6 and 7 show an outline of the structure of the GaN-HEMT according to this embodiment.FIG. 6 is a plan view, andFIG. 7 is an E-E′ sectional view ofFIG. 6 . InFIGS. 6 and 7 , constitutional elements having identical reference numerals to those ofFIGS. 1 to 2B are identical to the corresponding elements inFIGS. 1 to 2B . - As is evident from
FIGS. 6 and 7 , aHEMT 600 according to this embodiment differs from theHEMT 100 according to the first embodiment in the structure of the source electrode and drain electrode. - A
source electrode 610 and adrain electrode 620 are ohmic electrodes. Thesource electrode 610 comprises a plurality oflower portion electrodes 611 and a singleupper portion electrode 612. Similarly, thedrain electrode 620 comprises a plurality oflower portion electrodes 621 and a singleupper portion electrode 622. Thelower portion electrodes substrate 101. Theupper portion electrode 612 is electrically connected to all of thelower portion electrodes 611, and similarly, theupper portion electrode 622 is electrically connected to all of thelower portion electrodes 621. As shown inFIG. 7 , thelower portion electrodes electron gas layer 110. As a result, the side faces of thelower portion electrodes electron gas layer 110. Thelower portion electrodes isolation region 106. Thelower portion electrodes electrodes electron gas layer 110 is greater than that of a conventional HEMT. There are no limitations on the pitch of thelower portion electrodes lower portion electrodes source electrode 610 anddrain electrode 620 are formed by laminating together a titanium film and an aluminum film. The thickness of the titanium film is 15 nm, for example, and the thickness of the aluminum film is 100 nm, for example. - A manufacturing process for the
HEMT 600 according to this embodiment will now be described.FIGS. 8A to 9 are views illustrating the manufacturing process for theHEMT 600 according to this embodiment.FIG. 8A is a plan view,FIG. 8B is an F-F′ sectional view ofFIG. 8A , andFIG. 9 is a sectional view corresponding toFIG. 8B . - First, similarly to the first embodiment, the
buffer layer 102, channel-forminglayer 103,Schottky layer 104, andcap layer 105 are formed on thesemiconductor substrate 101 using a normal thin film formation technique, and then, using a ion implantation and other techniques, for example, theisolation region 106 is formed. - Next, a resist pattern is formed using a normal photolithography method. A plurality of
recesses recesses substrate 101 by etching using the resist pattern as a mask. Therecesses electron gas layer 110. In a typical HEMT, the depth of therecesses - The resist pattern is then removed, whereby the formation process of the
recesses FIGS. 8A and 8B ). - Next, the
source electrode 610 anddrain electrode 620 are formed in therecesses recesses - Next, a titanium film and an aluminum film are formed consecutively in the
recesses lower portion electrodes upper portion electrodes upper portion electrodes upper portion electrodes - The resist pattern is then removed.
- If necessary, the
substrate 101 is then subjected to heat treatment in a nitrogen atmosphere. In this heat treatment, the heating temperature is 600° C., for example, and the heating time is two minutes, for example. Following the heat treatment, the formation process of thesource electrode 610 anddrain electrode 620 is complete (seeFIG. 9 ). - Next, the
gate electrode 109 is formed on thecap layer 105 using a lift-off method. In this lift-off process, first a resist pattern exposing only the formation region of thegate electrode 109 is formed on thecap layer 105 using a normal photolithography method. Thegate electrode 109 is preferably formed in the center of a region sandwiched between theelectrodes electrodes - Next, a nickel film and a gold film are formed consecutively by vacuum deposition using the resist pattern as a mask.
- The resist pattern is then removed.
- If necessary, the
substrate 101 is then subjected to heat treatment in a nitrogen atmosphere. In this heat treatment, the heating temperature is 400° C., for example, and the heating time is two minutes, for example. Following the heat treatment, theHEMT 600 shown inFIGS. 8A to 9 is complete. - As described above, the
ohmic electrodes lower portion electrodes ohmic electrodes electron gas layer 110 is even larger than that of theHEMT 100 according to the first embodiment. As a result, this embodiment is capable of providing a HEMT in which ohmic resistance is even smaller than that of the first embodiment. For example, when L=3×Le in Equation (1) (i.e. when Equation (2) is established), the ohmic resistance is approximately one third that of a conventional HEMT. - Moreover, in the
HEMT 600 of this embodiment, similarly to theHEMT 100 of the first embodiment, the bottom faces of the ohmic electrodes do not have to be brought into contact with the two-dimensional electron gas layer, and therefore variation in the ohmic resistance value caused by manufacturing irregularities is small.
Claims (3)
1. A semiconductor device comprising:
a channel-forming layer formed on a semiconductor substrate;
a Schottky layer formed on said channel-forming layer;
a two-dimensional electron gas layer formed on an interface between said Schottky layer and said channel-forming layer by an electron supplied to said channel-forming layer from said Schottky layer;
a gate electrode formed on said Schottky layer via a cap layer; and
a recess-structured ohmic electrode containing a plurality of side faces which are in ohmic contact with said two-dimensional electron gas layer and non-parallel to a channel width direction.
2. The semiconductor device according to claim 1 , wherein a side of said ohmic electrode in ohmic contact with said two-dimensional electron gas layer has a saw tooth shape.
3. The semiconductor device according to claim 1 , wherein a side of said ohmic electrode in ohmic contact with said two-dimensional electron gas layer has a comb tooth shape.
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US11/636,430 US7601993B2 (en) | 2005-12-12 | 2006-12-11 | Semiconductor device having ohmic recessed electrode |
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Also Published As
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US7601993B2 (en) | 2009-10-13 |
JP2007165446A (en) | 2007-06-28 |
US20070132037A1 (en) | 2007-06-14 |
CN1983628A (en) | 2007-06-20 |
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