US20060100111A1 - Method for producing a solution having lubricating properties intended to be used as an additive to a liquid - Google Patents

Method for producing a solution having lubricating properties intended to be used as an additive to a liquid Download PDF

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Publication number
US20060100111A1
US20060100111A1 US10/526,501 US52650105A US2006100111A1 US 20060100111 A1 US20060100111 A1 US 20060100111A1 US 52650105 A US52650105 A US 52650105A US 2006100111 A1 US2006100111 A1 US 2006100111A1
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US
United States
Prior art keywords
solution
additive
boric
liquid
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/526,501
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English (en)
Inventor
Mats Selin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from SE0202659A external-priority patent/SE0202659D0/xx
Application filed by Individual filed Critical Individual
Publication of US20060100111A1 publication Critical patent/US20060100111A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/02—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1291—Silicon and boron containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Definitions

  • the present invention refers to a method for producing a solution having lubrication properties intended to be used as an additive to a liquid preferably a liquid fuel or a lubricant and a solution made according to said method, which when blended gives the liquid friction-reducing, lubricating and corrosion ihibiting characteristics.
  • boron can establish a complex ligand bond to other metals. This occurs after an exposure over time, from hours to days.
  • the boron compounds in question are aligned to two dimensional pallets, that slides on each other, which causes a reduced friction.
  • boron acts as a corrosion ihibitor for metals as the boric acid bonds to a thin layer on the underlying metal surface and prevents oxidation due to the electro negativity, which makes boron an effective reduction substance that prevents corrosion of exposed surfaces.
  • oil is blended with a high concentration of boric acid, and the blend is diluted at a ratio of approximately 10% to different lubricating oils.
  • boric acid can be used as an additive to fuels to accomplish a friction reducing effect.
  • the method is to mix boric acid in a base oil or a concentrate based on a diesel fuel.
  • the particle size of the boric compound normally in the range of 0.5 to 20 micron, is made by “jet-milling”, a method in doing so.
  • an additive, diesel additive as example, made by this method over time has a limited stability.
  • the boric acid particles are aggregating and are falling out and gathered on the bottom of the container. This happens within a period of months or less. This could lead to severe consequences for any engine, as example a diesel engine. Even when the boric acid particles are mixed in a base oil and thereafter eventually are diluted in fuel or the like, the same risk exists.
  • the object of the present invention is to eliminate the disadvantages as mentioned above, and to make an additive to a fluid or liquid, preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect.
  • a fluid or liquid preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect.
  • a method for producing a solution having lubricating properties of the kind mentioned above which in a distinguishing way fulfils its purpose and also an application of the mentioned solution as an additive to a liquid, such as fluid fuel or a lubricant to give the liquid friction reducing, lubricating and corrosion restraining characteristics.
  • the invention means that a boric compound with lubricating characteristics exits in the form of a solution.
  • the borat ions will at that consist of a homogenous phase together with the solvent, and which solution, under stable conditions at that may consist of a high concentration of borate, thanks to the used solvent, and preferably an alcohols hydrogen bonds, counteracts the elctro negativity of the boric compound and it's tendency to covalent bonds.
  • the boric compounds which according to an example, are dissolved according to the foregoing invention are preferably Boric BOH 3 or dibortrioxide B 2 O 3 (boric oxide), which offers good friction reducing characteristics.
  • the solvent can consist of water and/or an alcohol, individually or blended to a mixture.
  • the solvent should also be a liquid hydrogen.
  • the most alcohols should be used, as example ethanol, methanol etc. and the solution is made by shaking boric acid or bortrioxide together with alcohol or water, eventuially also by adding small mechanical elements to further increase the mechanical work.
  • the boric compound may be in a concentration of up to 250,000 ppm or more if necessary.
  • the fuel mixture should consist of a concentration of boric compound in the range of 10 to 1,000 ppm, preferably in the range of 100 to 200 ppm.
  • the composition consisting lubricant and the solution should have a concentration of boric compounds of around 400 ppm/4%.
  • the solution is used as an additive, which is added in a proportion to a lubricant, hydro carbon fuel or a bio fuel such as the boric compound is bonded on surfaces exposed by friction at which the friction is reduced.
  • the solution allows for an optimal dissolvement in the fluid and thereby the mentioned advantages of a stable solution which is friction reducing, lubricating and corrosion inhibiting.
  • the fluid may be as example hydro carbon fuels such as diesel or gasoline or other and the solution may also be injected separately in an combustion machine such as an hydrogen engine or other engine where friction reduction and corrosion inhibiting is needed.
  • the invention also incorporates a solution as such made as an additive by dissolving a boric compound, a boric acid and/or bortrioxide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)
US10/526,501 2002-09-09 2003-09-08 Method for producing a solution having lubricating properties intended to be used as an additive to a liquid Abandoned US20060100111A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
SE0202659-9 2002-09-09
SE0202659A SE0202659D0 (sv) 2002-09-09 2002-09-09 Smörjmedel och smörjmedelsadditiv
SE0302070-8 2003-07-14
SE0302070A SE524898C3 (sv) 2002-09-09 2003-07-14 Förfarande för framställning av en lösning med smörjande egenskaper avsedd att användas såsom tillsats till en vätska, användning av lösningen och lösningen
PCT/SE2003/001366 WO2004022676A1 (en) 2002-09-09 2003-09-08 A method for producing a solution having lubricating properties intended to be used as an additive to a liquid

Publications (1)

Publication Number Publication Date
US20060100111A1 true US20060100111A1 (en) 2006-05-11

Family

ID=27767292

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/526,501 Abandoned US20060100111A1 (en) 2002-09-09 2003-09-08 Method for producing a solution having lubricating properties intended to be used as an additive to a liquid

Country Status (7)

Country Link
US (1) US20060100111A1 (ja)
EP (1) EP1539904A1 (ja)
JP (1) JP2005538209A (ja)
AU (1) AU2003261686A1 (ja)
BR (1) BR0314167A (ja)
SE (1) SE524898C3 (ja)
WO (1) WO2004022676A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011008131A2 (ru) * 2009-07-16 2011-01-20 Naumov Vladimir Nikolaevich Водорастворимое смазочное средство для обработки конвейерных лент
US20130239463A1 (en) * 2012-03-15 2013-09-19 William E. Olliges Use Of Hexylene Glycol Fuel Additive Containing Boric Oxide

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005083042A1 (en) * 2004-03-02 2005-09-09 Mats Selin Additive for two stroke fuel with lubrificating properties adapted to replace traditional two stroke oil and two stroke fuel
US7494959B2 (en) * 2005-08-10 2009-02-24 Advanced Lubrication Technology Inc. Multi-phase lubricant compositions containing emulsified boric acid
US7419515B2 (en) * 2005-08-10 2008-09-02 Advanced Lubrication Technology, Inc. Multi-phase distillate fuel compositions and concentrates containing emulsified boric acid
CN100526444C (zh) * 2005-12-20 2009-08-12 中国科学院兰州化学物理研究所 硼酸盐超细颗粒润滑添加剂的制备方法
EP2427535A4 (en) * 2009-05-08 2017-03-15 Triboron International AB Method for producing a stable boric solution
US20190119589A1 (en) * 2016-04-08 2019-04-25 Triboron International Ab Oil-replacement additive for reducing emissions from two-stroke engines
CA3041781C (en) * 2016-10-27 2022-11-08 Triboron International Ab Methods for preventing microbial growth and microbiologically influenced corrosion in a biodegradable and/or renewable fuel, hydraulic fluid and/or lubricant

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440656A (en) * 1981-11-23 1984-04-03 Mobil Oil Corporation Borated alkoxylated alcohols and lubricants and liquid fuels containing same
US4524004A (en) * 1983-10-28 1985-06-18 Mobil Oil Corporation Borated N-hydrocarbyl-hydrocarbylene diamines as multifunctional lubricant/fuel additives and compositions thereof
US4539126A (en) * 1983-11-15 1985-09-03 Shell Oil Company Borated basic metal salt and lubricating oil composition
US4557844A (en) * 1984-01-30 1985-12-10 Mobil Oil Corporation Aminated boron- and phosphorus-containing compounds and lubricant or fuel compositions containing same
US4741848A (en) * 1986-03-13 1988-05-03 The Lubrizol Corporation Boron-containing compositions, and lubricants and fuels containing same
US5033415A (en) * 1987-06-22 1991-07-23 Mobil Oil Corporation Friction reducing additives and compositions thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440656A (en) * 1981-11-23 1984-04-03 Mobil Oil Corporation Borated alkoxylated alcohols and lubricants and liquid fuels containing same
US4524004A (en) * 1983-10-28 1985-06-18 Mobil Oil Corporation Borated N-hydrocarbyl-hydrocarbylene diamines as multifunctional lubricant/fuel additives and compositions thereof
US4539126A (en) * 1983-11-15 1985-09-03 Shell Oil Company Borated basic metal salt and lubricating oil composition
US4557844A (en) * 1984-01-30 1985-12-10 Mobil Oil Corporation Aminated boron- and phosphorus-containing compounds and lubricant or fuel compositions containing same
US4741848A (en) * 1986-03-13 1988-05-03 The Lubrizol Corporation Boron-containing compositions, and lubricants and fuels containing same
US5033415A (en) * 1987-06-22 1991-07-23 Mobil Oil Corporation Friction reducing additives and compositions thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011008131A2 (ru) * 2009-07-16 2011-01-20 Naumov Vladimir Nikolaevich Водорастворимое смазочное средство для обработки конвейерных лент
WO2011008131A3 (ru) * 2009-07-16 2011-03-10 Naumov, Vladimir Nikolaevich Водорастворимое смазочное средство для обработки конвейерных лент
US20130239463A1 (en) * 2012-03-15 2013-09-19 William E. Olliges Use Of Hexylene Glycol Fuel Additive Containing Boric Oxide
US9212329B2 (en) * 2012-03-15 2015-12-15 William E. Olliges Use of hexylene glycol fuel additive containing boric oxide

Also Published As

Publication number Publication date
SE524898C3 (sv) 2005-06-01
JP2005538209A (ja) 2005-12-15
SE0302070D0 (sv) 2003-07-14
AU2003261686A1 (en) 2004-03-29
BR0314167A (pt) 2005-07-19
SE524898C2 (sv) 2004-10-19
WO2004022676A1 (en) 2004-03-18
SE0302070L (sv) 2004-03-10
EP1539904A1 (en) 2005-06-15

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