Classifications

• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
  • C21D8/0226—Hot rolling
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
  • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/002—Bainite

Definitions

• the present disclosure relates to methods of producing flat steel products that have a high yield strength and a bainitic microstructure, at least in part.
• Flat steel products of the type in question here are typically rolled products such as steel strips or sheets, and blanks and plates produced therefrom.
• High-strength flat steel products are growing in significance particularly in the field of motor vehicle construction, since they enable a reduction in the vehicle's intrinsic weight and an increase in the load capacity.
• a low weight not only contributes to optimal utilization of the technical performance capacity of the respective drive unit, but also promotes resource efficiency, optimization of costs and climate protection.
• a crucial reduction in the intrinsic weight of steel sheet constructions can be achieved by an enhancement of the mechanical properties, especially of the strength of the flat steel product being processed in each case.
• modern flat steel products intended for motor vehicle construction are also expected to have good toughness properties, good brittleness resistance characteristics and optimal suitability for cold forming and welding.
• EP 2 130 938 Al discloses a method of producing a hot-rolled flat steel product, in which a melt is cast to slabs containing, as well as iron and unavoidable impurities (in ° A by weight) 0.01%-0.1% by weight of C, 0.01%-0.1% by weight of Si, 0.1%-3% by weight of Mn, not more than 0.1% by weight of P, not more than 0.03% by weight of S, 0.001%-1% by weight of Al, not more than 0.01% by weight of N, 0.005%-0.08% by weight of Nb and 0.001% to 0.2% by weight of Ti, where the following condition applies to the respective Nb content % Nb and the respective C content % C: % Nb ⁇ % C ⁇ 4.34 ⁇ 10 ⁇ 3 .
• the steel slab is reheated up to a temperature range having a lower limit which is determined as a function of the C and Nb contents of the steel being cast in each case and an upper limit of 1170° C. Subsequently, the reheated slab is rough-rolled at an end temperature of 1080-1150° C. After waiting for 30-150 seconds, in the course of which the reheated slab is kept at 1000-1080° C., the preheated slab is then hot finish-rolled to give a hot strip.
• the forming level in the last draft of the hot rolling should be 3%-15%.
• the hot rolling is ended at a hot rolling end temperature corresponding at least to the Ar3 temperature of the steel being processed and of not more than 950° C.
• the hot strip obtained is cooled down at a cooling rate of more than 15° C./s to a coiling temperature of 450-550° C., at which it is coiled to a coil.
• the grain boundary density of the carbon present in solid solution is to be 1-4.5 atoms/nm 2 and the size of the cementite grains separated out at the particle boundaries not more than 1 ⁇ m.
• the flat steel products having these properties and having been produced by the known method, given sufficiently high-dose alloy contents, are to have tensile strengths of more than 780 MPa and yield strengths of up to 726 MPa.
• the hot strip produced in the known manner is to have a combination of properties of particular suitability for use in automobile construction.
• Optimal surface characteristics are to be attained by restricting the reheating temperature to which the slab is heated prior to hot rolling to the abovementioned temperature range and hence avoiding excessive formation of scale which would be incorporated into the hot strip surface in the course of hot rolling.
• Table 1 identifies compositions that have been smelted and cast to give slabs 1-26.
• Table 2a identifies process parameters established in the processing of each of slabs 1-16.
• Table 2b identifies process parameters established in the processing of each of slabs 17-26.
• Table 3 identifies mechanical properties and microstructure constituents of hot strips.
• the present disclosure relates to a method of producing a flat steel product having a yield strength of at least 700 MPa and having a bainitic microstructure to an extent of at least 70% by volume. Further, the present disclosure relates to a method of producing high-strength ‘heavy plate’ having a thickness of at least 3 mm.
• One example object of the present disclosure is to specify methods for producing high-strength steel sheets having mechanical properties optimized for use in automobile construction as well as having optimized surface characteristics. That said, it should be understood that all figures relating to contents of the steel compositions specified in the present disclosure are based on weight, unless explicitly mentioned otherwise. All indeterminate ‘% figures’ connected to a steel alloy should therefore be regarded as figures in ‘% by weight.
• a method of the invention for producing a flat steel product having a yield strength of at least 700 MPa and having a bainitic microstructure to an extent of at least 70% by volume has the following steps:
• the method of the invention is based on a steel alloy having alloy constituents and alloy contents matched to one another within tight limits, such that maximized mechanical properties and optimized surface characteristics are attained in each case in a procedure that can be conducted in an operationally reliable manner.
• alloy constituents and alloy contents of the steel alloy smelted in accordance with the invention in step a) are selected such that, in the case of compliance with the steps specified in accordance with the invention, it is reliably possible to produce a hot-rolled flat steel product having a combination of properties that makes it particularly suitable for use in lightweight steel construction, especially in the field of utility vehicle construction:
• Cu, Ni, V, Mo and Sb occur as accompanying elements which get into the steel being processed in accordance with the invention as technically unavoidable contamination in the process of steel production.
• the contents thereof are restricted to amounts that are inactive in relation to the properties of the steel being processed in accordance with the invention that are the aim of the invention.
• Cu content is restricted to max. 0.12% by weight, the Ni content to less than 0.1% by weight, the V content to not more than 0.01% by weight, the Mo content to less than 0.004% by weight and the Sb content likewise to less than 0.004% by weight.
• the slab After the slab has been cast, it is reheated to the austenitization temperature of 1200-1300° C.
• the upper limit in the temperature range to which the slab is heated for austenitization should not be exceeded in order to avoid coarsening of the austenite grain and increased scale formation.
• Within the reheating temperature range, specified in accordance with the invention, of 1200-1300° C. there is not yet increased formation of red scale that would lower the surface quality of the flat steel product being produced in accordance with the invention. Red scale forms in the course of processing of slabs of the composition of the invention exclusively in the hot rolling operation (steps d), e) of the process of the invention), when too much primary scale is present on the slab surface after reheating.
• the lower limit for the reheating temperature is fixed such that the desired homogenization of the microstructure is assured with a homogeneous temperature distribution. Over and above this temperature, there is very substantially complete dissolution of the coarse Ti carbonitride and Nb carbonitride precipitates present in the respective slab in the austenite.
• fine Ti carbonitride or Nb carbonitride precipitates it is then possible for fine Ti carbonitride or Nb carbonitride precipitates to reform, and these, as elucidated, make an essential contribution to increasing the strength properties. In this way, it is assured that the flat steel products which have been produced and have the composition of the invention regularly have a minimum yield strength of 700 MPa.
• the reheating temperature in the austenitization of the respective slab is at least 1200° C., in order to achieve the desired effect of maximum dissolution of the TiC and NbC precipitates.
• an austenitization temperature below 1200° C. the amount of carbide precipitates of Ti and Nb dissolved in the austenite, by contrast, is sufficiently low that the effects utilized in accordance with the invention do not occur.
• the result of a reheating temperature below 1200° C. in the case of processing of flat steel products of a composition corresponding to the alloy selection optimized in accordance with the invention would therefore be that the required strength properties are not attained.
• the very substantial dissolution of the TiC and NbC precipitates can be assured in a particularly reliable manner when the reheating temperature is at least 1250° C.
• a flat steel product that meets the highest quality demands on its surface characteristics can be produced by completely removing scale present on the slab prior to the rough rolling. This can be accomplished by completely descaling the slab surface after discharge from the oven and as immediately as possible prior to the rough rolling. For this purpose, the slab can pass through a conventional scale washer.
• the time t_1 required for the transfer of the slab from the station (“reheating (step c)”) or the “removal of the primary scale (step c′)”) which optionally follows the reheating up to the start of the hot finish rolling (step e)) can be restricted to a maximum of 300 s. In an optimal manner, this includes the rough rolling. Within such a short transfer time, only such a small amount of primary scale is reformed that the red scale that forms therefrom in the course of hot rolling is not detrimental to the quality of the surface of the flat steel product obtained after the hot rolling.
• the transport time between the descaling aggregate and up to the rough rolling structure should be not more than 30 s. In the case of such a short transport time, only a harmless thin oxide layer, if any, can form on the previously descaled slab.
• step d) the slab processed in each case is rough-rolled at a rough rolling temperature of 950-1250° C.
• the draft achieved in the rough rolling is at least 50% in total.
• the lower limit for the range specified for the rough rolling temperature and the minimum value of the total draft ⁇ hv are fixed such that the recrystallization processes can proceed to completion in each rough-rolled slab. In this way, the formation of a fine-grain austenitic microstructure is assured prior to the finish rolling, which achieves optimized toughness and fracture elongation properties of the flat steel product produced in accordance with the invention.
• the residence time and delay time t_2 between the rough rolling and the finish rolling is limited to 50 s, in order to avoid unwanted austenite grain growth.
• step e The rough rolling is followed, in step e), by the hot rolling of the rough-rolled slab to give a hot-rolled flat steel product having a hot strip thickness of typically 3-15 mm.
• Flat steel products having such thicknesses are also referred to in the art as “heavy plate”.
• the end temperature of this hot rolling is 800-880° C.
• the comparably low hot rolling end temperature enhances the effect of the hot rolling.
• Dislocation-rich austenite is present in the microstructure of the hot strip obtained. After intensive cooling (step f)), this is transformed to a dislocation-rich, finely structured bainite, such that the yield strength is raised.
• the upper limit in the range of the hot rolling end temperature is fixed such that no recrystallization of the austenite takes place in the course of rolling in the hot rolling finishing train. This too contributes to the development of a fine-grain microstructure.
• the lower limit temperature is at least 800° C. in order that no ferrite forms in the course of rolling.
• ⁇ hf the phase transformation from highly formed austenite takes place. This has a positive effect on the fine granularity, such that small grain sizes are present in the microstructure of the flat steel product produced in accordance with the invention.
• intensive cooling sets in within not more than 10 s, in the course of which the hot-rolled flat steel product is cooled down at a cooling rate dT of at least 40 K/s to a coiling temperature of 550-620° C.
• the cooling delay after the hot rolling is not more than 10 s, in order to prevent unwanted changes in microstructure between the hot rolling and controlled accelerated cooling.
• the choice of coiling temperature has a crucial influence on precipitation hardening.
• the coiling temperature range is chosen in accordance with the invention such that it is firstly below the bainite starting temperature, and secondly at the precipitation maximum for the formation of carbonitride deposits.
• the cooling conditions are chosen in accordance with the invention such that the hot-rolled flat steel product, immediately prior to the coiling, has a bainitic microstructure having a phase content of at least 70% by volume. Further bainite formation then proceeds in the coil.
• the high cooling rate prevents the formation of unwanted phase constituents.
• the cooling rate of the cooling after the hot rolling can be restricted to 150 K/s.
• the yield strength of the hot-rolled flat steel products produced in accordance with the invention in the manner elucidated above is reliably 700-850 MPa.
• the fracture elongation is at the same time at least 12%.
• flat steel products of the invention attain tensile strengths of 750-950 MPa.
• the notch impact energy determined for products of the invention is in the range of 50-110 J at ⁇ 20° C. and in the range of 30-110 J at ⁇ 40° C.
• Flat steel products produced in accordance with the invention have a fine-grain microstructure with a mean grain size of not more than 20 ⁇ m, in order to achieve good fracture elongation and toughness.
• the aforementioned properties are present in a hot-rolled flat steel product in the rolled state after coiling. There is no need for any further heat treatment to establish or develop particular properties that are important for the intended use as high-strength sheet metal in utility vehicle construction.
• the slabs consisting of steels A-E have been heated through to a reheating temperature TW.
• the reheated slabs have been transported within less than 30 s to a scale washer in which primary scale adhering thereon has been removed from the slabs.
• the slabs that emerge from the scale washer have then been transported to a rough rolling stand, where they have been rough-rolled with a rough rolling temperature TVW and a total draft ⁇ hv achieved by means of the rough rolling.
• the rough-rolled slabs have been hot-finish-rolled in a hot finish rolling relay to give hot strips having a thickness BD and a width BB.
• the hot rolling operation has been ended in each case with a total draft in the hot finish rolling relay ⁇ hf at a hot rolling end temperature TEW.
• the time that has passed between exit from the scale washer and the commencement of hot finish rolling was less than 300 s in each case.
• the hot-finish-rolled flat steel product emerging from the last stand after a delay t_p of 1-7 s, in which it is cooled down gradually under air, has been cooled down by means of intensive cooling with water at a cooling rate dT of 50-120 K/s to a coiling temperature HT.
• the flat steel products After the cooling, the flat steel products already have a bainitic microstructure to an extent of at least 70% by volume.
• Tables 2a, 2b report the process parameters established in the processing of each of slabs 1-26 (reheating temperature TW, rough rolling temperature TVW, total draft ⁇ hv achieved by means of the rough rolling, time t_ 1 between the descaling conducted after the preheating and prior to the rough rolling and commencement of the hot finish rolling, time t_ 2 between rough rolling and hot rolling, total draft ⁇ hf achieved by means of the finish rolling, end rolling temperature TEW, cooling delay t_p between the end of the hot rolling and the commencement of forced cooling, cooling rate dT, coiling temperature HT, strip thickness BD and strip width BB).
• microstructure studies were effected by means of a light microscope and scanning electron microscope. For this purpose, the samples were taken from a quarter of the width of the strip, prepared as a longitudinal section and etched with nital (i.e. alcoholic nitric acid containing a nitric acid content of 3% by volume) or sodium disulfite.
• nital i.e. alcoholic nitric acid containing a nitric acid content of 3% by volume
• sodium disulfite sodium disulfite.
• the microstructure constituents were determined by means of a surface analysis at a sample location of 1 ⁇ 3 sheet thickness, as described in H. Schumann and H. Oettel “Metall react” [Metallography] 14th edition, 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
• the mechanical properties and the microstructure constituents of the hot strips produced in accordance with the invention are reported in table 3.
• the sheet metal strips produced by the method of the present invention have high strength properties coupled with good toughness properties and good fracture elongation.
• the yield strengths of the hot strips produced in the manner elucidated above are between 700 MPa and 790 MPa. Fracture elongation is at least 12%, and tensile strength 750-880 MPa.
• Notch impact energy at ⁇ 20° C. is in the range of 60 to 100 J. At ⁇ 40° C. the notch impact energy is 40 to 75 J and at ⁇ 60° C. the notch impact energy is 30-70 J.

Landscapes

• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Mechanical Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Physics & Mathematics (AREA)
• Thermal Sciences (AREA)
• Crystallography & Structural Chemistry (AREA)
• Heat Treatment Of Sheet Steel (AREA)
• Heat Treatment Of Steel (AREA)

Applications Claiming Priority (4)

Related Parent Applications (1)

Related Child Applications (1)

Publications (2)

Family

ID=50382300

Family Applications (2)

Family Applications After (1)

Country Status (15)

Cited By (2)

Families Citing this family (21)

Citations (7)

Family Cites Families (9)

• 2014
  • 2014-03-25 PL PL17191293T patent/PL3305935T3/pl unknown
  • 2014-03-25 PL PL14161606T patent/PL2924140T3/pl unknown
  • 2014-03-25 ES ES17191293T patent/ES2745046T3/es active Active
  • 2014-03-25 ES ES14161606.0T patent/ES2659544T3/es active Active
  • 2014-03-25 DK DK14161606.0T patent/DK2924140T3/en active
  • 2014-03-25 SI SI201430572T patent/SI2924140T1/en unknown
  • 2014-03-25 DK DK17191293.4T patent/DK3305935T3/da active
  • 2014-03-25 EP EP14161606.0A patent/EP2924140B1/fr active Active
  • 2014-03-25 SI SI201431325T patent/SI3305935T1/sl unknown
  • 2014-03-25 EP EP17191293.4A patent/EP3305935B9/fr active Active
• 2015
  • 2015-03-18 RU RU2016141474A patent/RU2675183C2/ru active
  • 2015-03-18 MX MX2016012491A patent/MX2016012491A/es unknown
  • 2015-03-18 KR KR1020167029332A patent/KR20160137588A/ko not_active Application Discontinuation
  • 2015-03-18 BR BR112016022053-6A patent/BR112016022053B1/pt active IP Right Grant
  • 2015-03-18 CN CN201580016149.1A patent/CN106133154A/zh active Pending
  • 2015-03-18 UA UAA201610736A patent/UA117959C2/uk unknown
  • 2015-03-18 CA CA2941202A patent/CA2941202C/fr active Active
  • 2015-03-18 US US15/127,529 patent/US10280477B2/en active Active
  • 2015-03-18 JP JP2016558769A patent/JP6603669B2/ja active Active
  • 2015-03-18 WO PCT/EP2015/055685 patent/WO2015144529A1/fr active Application Filing
• 2019
  • 2019-03-06 US US16/294,468 patent/US10934602B2/en active Active

Patent Citations (7)

Non-Patent Citations (4)

Also Published As

Similar Documents

Legal Events