UA89941C2 - Фенилизо(тио)цианаты и промежуточные соенинения, способы их получения - Google Patents
Фенилизо(тио)цианаты и промежуточные соенинения, способы их полученияInfo
- Publication number
- UA89941C2 UA89941C2 UAA200505013A UA2005005013A UA89941C2 UA 89941 C2 UA89941 C2 UA 89941C2 UA A200505013 A UAA200505013 A UA A200505013A UA 2005005013 A UA2005005013 A UA 2005005013A UA 89941 C2 UA89941 C2 UA 89941C2
- Authority
- UA
- Ukraine
- Prior art keywords
- phenyliso
- cyanates
- thio
- intermediates
- processes
- Prior art date
Links
- 150000001913 cyanates Chemical class 0.000 title abstract 3
- 239000000543 intermediate Substances 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000004476 plant protection product Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/76—Nitrogen atoms to which a second hetero atom is attached
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/34—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfuric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C307/00—Amides of sulfuric acids, i.e. compounds having singly-bound oxygen atoms of sulfate groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C307/04—Diamides of sulfuric acids
- C07C307/06—Diamides of sulfuric acids having nitrogen atoms of the sulfamide groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
- C07C331/16—Isothiocyanates
- C07C331/28—Isothiocyanates having isothiocyanate groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/20—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
- C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/70—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
- C07D295/26—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/14—Radicals substituted by singly bound hetero atoms other than halogen
- C07D333/20—Radicals substituted by singly bound hetero atoms other than halogen by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10250614 | 2002-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA89941C2 true UA89941C2 (ru) | 2010-03-25 |
Family
ID=32185288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA200505013A UA89941C2 (ru) | 2002-10-30 | 2003-10-29 | Фенилизо(тио)цианаты и промежуточные соенинения, способы их получения |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US7820846B2 (https=) |
| EP (2) | EP1560810B1 (https=) |
| JP (1) | JP4738812B2 (https=) |
| KR (1) | KR101055954B1 (https=) |
| CN (1) | CN100368392C (https=) |
| AR (1) | AR041861A1 (https=) |
| AU (1) | AU2003287972B2 (https=) |
| BR (2) | BR0315932A (https=) |
| CA (1) | CA2504410C (https=) |
| EA (1) | EA010872B1 (https=) |
| ES (1) | ES2565961T3 (https=) |
| HU (1) | HUE027607T2 (https=) |
| IL (1) | IL167983A (https=) |
| MX (1) | MXPA05004546A (https=) |
| PL (1) | PL214983B1 (https=) |
| UA (1) | UA89941C2 (https=) |
| WO (1) | WO2004039768A1 (https=) |
| ZA (1) | ZA200504331B (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8252925B2 (en) | 2004-07-22 | 2012-08-28 | Basf Aktiengesellschaft | Method for the production of 3-phenyl(thio)uracils and dithiouracils |
| DE102005057681A1 (de) * | 2005-12-01 | 2007-06-06 | Basf Ag | Verfahren zur Herstellung fluorierter m-Nitro-Benzoesäurechloride |
| EA200801432A1 (ru) * | 2005-12-01 | 2008-12-30 | Басф Се | Способ получения сульфонамидов |
| CN101821233B (zh) * | 2007-10-12 | 2016-06-29 | 巴斯夫欧洲公司 | 生产磺酸二酰胺的方法 |
| MX2012005501A (es) | 2009-11-13 | 2012-07-10 | Basf Se | Compuestos 3- (3, 4- dihidro-2h-benzo [1, 4] -oxazin-6-il)-1h-piri midin-2, 4-diona como herbicidas. |
| EP3974412A1 (en) * | 2011-09-28 | 2022-03-30 | Waters Technologies Corporation | Rapid fluorescence tagging of glycans and other biomolecules with enhanced ms signals |
| US10436790B2 (en) | 2011-09-28 | 2019-10-08 | Waters Technologies Corporation | Rapid fluorescence tagging of glycans and other biomolecules with enhanced MS signals |
| US11352325B2 (en) | 2011-09-28 | 2022-06-07 | Waters Technologies Corporation | Rapid fluorescence tagging of glycans and other biomolecules with enhanced MS signals |
| CN102702056B (zh) * | 2012-05-31 | 2014-09-24 | 北京师范大学 | 一种一锅法合成取代间苯二异硫氰酸酯的方法、合成的取代间苯二异硫氰酸酯化合物 |
| WO2016069764A1 (en) | 2014-10-30 | 2016-05-06 | Waters Technologies Corporation | Methods for the rapid preparation of labeled glycosylamines and for the analysis of glycosylated biomolecules producing the same |
| WO2016077548A1 (en) | 2014-11-13 | 2016-05-19 | Waters Technologies Corporation | Methods for liquid chromatography calibration for rapid labeled n-glycans |
| UA123514C2 (uk) | 2016-05-24 | 2021-04-14 | Басф Се | Гербіцидні урацилпіридини |
| US11035832B2 (en) | 2016-06-21 | 2021-06-15 | Waters Technologies Corporation | Methods of electrospray ionization of glycans modified with amphipathic, strongly basic moieties |
| CN109641846A (zh) | 2016-06-21 | 2019-04-16 | 沃特世科技公司 | 通过用于增强的ms信号的还原胺化的聚糖和其他生物分子的荧光标记 |
| EP3479103B1 (en) | 2016-07-01 | 2022-04-20 | Waters Technologies Corporation | Methods for the rapid preparation of labeled glycosylamines from complex matrices using molecular weight cut off filtration and on-filter deglycosylation |
| EP3587396A1 (en) | 2018-06-27 | 2020-01-01 | Basf Se | A method of isolating a n-(3-nitrobenzoyl)sulfamide |
| BR112023019613A2 (pt) | 2021-03-26 | 2023-11-14 | Adama Agan Ltd | Preparação de ácido 2-cloro-4-fluoro-5-nitrobenzoico |
| AR130348A1 (es) | 2022-08-31 | 2024-11-27 | Adama Agan Ltd | Preparación de ácido 2-cloro-4-fluoro-5-nitrobenzoico |
| WO2025124942A1 (en) | 2023-12-12 | 2025-06-19 | BASF Agro B.V. | Process for preparing a saflufenacil intermediate |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4309209A (en) | 1977-08-15 | 1982-01-05 | Chevron Research | Herbicidal method and composition |
| DK156573C (da) | 1981-06-16 | 1990-01-29 | Sumitomo Chemical Co | 2-(2-fluor-4-halogen-5-substitueret-phenyl)-hydantoinderivater, et herbicidt praeparat indeholdende disse, en fremgangsmaade til bekaempelse af ukrudt under anvendelse af disse samt anvendelse af disse som herbicid |
| US4452981A (en) | 1981-09-19 | 1984-06-05 | Sumitomo Chemical Company, Limited | 4-(2-Fluoro-4-halo-5-substituted phenyl)urazols, and their production and use |
| DE3433391A1 (de) * | 1984-09-12 | 1986-03-20 | Bayer Ag, 5090 Leverkusen | Acylierte saccharin-derivate |
| DE3924052A1 (de) | 1989-07-21 | 1991-01-24 | Bayer Ag | N- (indol-6-yl)-heterocyclen |
| US5238908A (en) | 1989-08-31 | 1993-08-24 | Rohm And Haas Company | Herbicidal glutaramic acids and derivatives |
| EP0556737B1 (de) | 1992-02-20 | 2000-01-12 | Clariant GmbH | Verfahren zur Herstellung von substituierten 2,3-Difluorpyridinen |
| DE19610786A1 (de) * | 1996-03-14 | 1997-09-18 | Bayer Ag | Verfahren zur Herstellung von substituierten aromatischen Thiocarbonsäureamiden |
| DE19627901A1 (de) * | 1996-07-11 | 1998-01-15 | Bayer Ag | Substituierte aromatische Carbonylverbindungen und ihre Derivate |
| DE19632005A1 (de) * | 1996-08-08 | 1998-02-12 | Bayer Ag | Substituierte p-Trifluormethylphenyluracile |
| DE19731784A1 (de) * | 1997-07-24 | 1999-02-04 | Bayer Ag | Substituierte N-Aryl-N-thioxocarbonyl-sulfonamide |
| IL125947A0 (en) | 1997-09-17 | 1999-04-11 | American Cyanamid Co | 3-(1,2-benzisothiazol- and isoxazol-5-yl)-2,4(1h,3h)-pyrimidinedione or thione and 3-(1,2-benzisothiazol- and isoxazol-5-yl)-4(3)-pyrimidinone or thione herbicidal agents |
| US6251829B1 (en) | 2000-04-18 | 2001-06-26 | Rohm And Haas Company | Herbicidal benzoyloxy carboxylates and carboxamides |
| HU229494B1 (en) * | 2000-05-04 | 2014-01-28 | Basf Ag | Uracil substituted phenyl sulfamoyl carboxamides |
| EP1284972A1 (en) | 2000-05-17 | 2003-02-26 | Cor Therapeutics, Inc. | Methods for producing amino substituted chromanes and intermediates therefor |
| KR100759298B1 (ko) * | 2000-07-05 | 2007-09-18 | 바젤 폴리올레핀 게엠베하 | 티탄을 함유하는 현탁된 크롬 촉매 및 에틸렌의 호모중합체 및 공중합체를 제조하기 위한 그 촉매의 용도 |
| DE10036653A1 (de) | 2000-07-26 | 2002-02-07 | Clariant Gmbh | Verfahren zur Herstellung von substituierten Benzoylchloriden |
| EP1315733A2 (de) | 2000-09-08 | 2003-06-04 | Basf Aktiengesellschaft | Verfahren zur herstellung anellierter tetrahydro-[1h]-triazole |
-
2003
- 2003-10-29 KR KR1020057007661A patent/KR101055954B1/ko not_active Expired - Lifetime
- 2003-10-29 AU AU2003287972A patent/AU2003287972B2/en not_active Expired
- 2003-10-29 US US10/532,931 patent/US7820846B2/en active Active
- 2003-10-29 ES ES12174668.9T patent/ES2565961T3/es not_active Expired - Lifetime
- 2003-10-29 AR ARP030103955A patent/AR041861A1/es active IP Right Grant
- 2003-10-29 EP EP03779818A patent/EP1560810B1/de not_active Expired - Lifetime
- 2003-10-29 MX MXPA05004546A patent/MXPA05004546A/es active IP Right Grant
- 2003-10-29 PL PL376995A patent/PL214983B1/pl unknown
- 2003-10-29 EA EA200500598A patent/EA010872B1/ru not_active IP Right Cessation
- 2003-10-29 JP JP2004547601A patent/JP4738812B2/ja not_active Expired - Lifetime
- 2003-10-29 WO PCT/EP2003/012013 patent/WO2004039768A1/de not_active Ceased
- 2003-10-29 UA UAA200505013A patent/UA89941C2/ru unknown
- 2003-10-29 HU HUE12174668A patent/HUE027607T2/en unknown
- 2003-10-29 CA CA2504410A patent/CA2504410C/en not_active Expired - Lifetime
- 2003-10-29 EP EP12174668.9A patent/EP2537829B1/de not_active Expired - Lifetime
- 2003-10-29 BR BR0315932-9A patent/BR0315932A/pt active IP Right Grant
- 2003-10-29 BR BRPI0315932A patent/BRPI0315932B1/pt unknown
- 2003-10-29 CN CNB2003801046055A patent/CN100368392C/zh not_active Expired - Lifetime
-
2005
- 2005-04-12 IL IL167983A patent/IL167983A/en unknown
- 2005-05-27 ZA ZA200504331A patent/ZA200504331B/en unknown
-
2010
- 2010-09-21 US US12/886,986 patent/US8232421B2/en not_active Expired - Fee Related
-
2012
- 2012-06-28 US US13/535,544 patent/US8541611B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004039768A1 (de) | 2004-05-13 |
| AR041861A1 (es) | 2005-06-01 |
| PL214983B1 (pl) | 2013-10-31 |
| AU2003287972B2 (en) | 2010-04-22 |
| EP1560810B1 (de) | 2012-08-01 |
| US7820846B2 (en) | 2010-10-26 |
| BR0315932A (pt) | 2005-09-13 |
| US8232421B2 (en) | 2012-07-31 |
| ZA200504331B (en) | 2006-07-26 |
| MXPA05004546A (es) | 2005-10-18 |
| AU2003287972A1 (en) | 2004-05-25 |
| JP2006504763A (ja) | 2006-02-09 |
| IL167983A (en) | 2010-11-30 |
| BRPI0315932B1 (pt) | 2019-08-13 |
| EP1560810A1 (de) | 2005-08-10 |
| CA2504410A1 (en) | 2004-05-13 |
| CA2504410C (en) | 2012-03-20 |
| JP4738812B2 (ja) | 2011-08-03 |
| EP2537829B1 (de) | 2016-03-02 |
| CN1717388A (zh) | 2006-01-04 |
| PL376995A1 (pl) | 2006-01-23 |
| HUE027607T2 (en) | 2016-10-28 |
| ES2565961T3 (es) | 2016-04-07 |
| EA200500598A1 (ru) | 2006-06-30 |
| EA010872B1 (ru) | 2008-12-30 |
| CN100368392C (zh) | 2008-02-13 |
| EP2537829A1 (de) | 2012-12-26 |
| US20120271049A1 (en) | 2012-10-25 |
| KR101055954B1 (ko) | 2011-08-09 |
| US20110009640A1 (en) | 2011-01-13 |
| KR20050090380A (ko) | 2005-09-13 |
| US20060004220A1 (en) | 2006-01-05 |
| US8541611B2 (en) | 2013-09-24 |
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