UA65558C2 - A process for the electrolytic production of metals - Google Patents
A process for the electrolytic production of metals Download PDFInfo
- Publication number
- UA65558C2 UA65558C2 UA99094919A UA99094919A UA65558C2 UA 65558 C2 UA65558 C2 UA 65558C2 UA 99094919 A UA99094919 A UA 99094919A UA 99094919 A UA99094919 A UA 99094919A UA 65558 C2 UA65558 C2 UA 65558C2
- Authority
- UA
- Ukraine
- Prior art keywords
- electrolyte
- metal
- metals
- fact
- titanium
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 105
- 239000002184 metal Substances 0.000 title claims abstract description 105
- 238000000034 method Methods 0.000 title claims abstract description 96
- 230000008569 process Effects 0.000 title claims abstract description 53
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 52
- 150000002739 metals Chemical class 0.000 title claims abstract description 21
- 239000003792 electrolyte Substances 0.000 claims abstract description 101
- 239000010936 titanium Substances 0.000 claims abstract description 92
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 79
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 28
- 239000007789 gas Substances 0.000 claims abstract description 19
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 17
- 239000000956 alloy Substances 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 238000005275 alloying Methods 0.000 claims abstract description 14
- 230000009467 reduction Effects 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000011244 liquid electrolyte Substances 0.000 claims abstract 3
- 238000000605 extraction Methods 0.000 claims abstract 2
- 239000011575 calcium Substances 0.000 claims description 21
- 229910052802 copper Inorganic materials 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
- 230000007246 mechanism Effects 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 14
- 229910052791 calcium Inorganic materials 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 13
- 230000016507 interphase Effects 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 150000002736 metal compounds Chemical class 0.000 claims description 8
- 230000033001 locomotion Effects 0.000 claims description 7
- 238000011068 loading method Methods 0.000 claims description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 5
- 230000008025 crystallization Effects 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 150000001805 chlorine compounds Chemical class 0.000 claims description 4
- 150000002222 fluorine compounds Chemical class 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 150000004694 iodide salts Chemical class 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims 2
- 150000002910 rare earth metals Chemical class 0.000 claims 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- 229910052768 actinide Inorganic materials 0.000 claims 1
- 150000001255 actinides Chemical class 0.000 claims 1
- 229910052790 beryllium Inorganic materials 0.000 claims 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims 1
- 150000001649 bromium compounds Chemical class 0.000 claims 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims 1
- 229910001634 calcium fluoride Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052747 lanthanoid Inorganic materials 0.000 claims 1
- 150000002602 lanthanoids Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
- 229910001338 liquidmetal Inorganic materials 0.000 abstract description 16
- 230000001105 regulatory effect Effects 0.000 abstract description 9
- 230000020169 heat generation Effects 0.000 abstract description 2
- 239000000470 constituent Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 12
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 238000006722 reduction reaction Methods 0.000 description 12
- 238000012546 transfer Methods 0.000 description 12
- -1 titanium ions Chemical class 0.000 description 10
- 230000008901 benefit Effects 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910002804 graphite Inorganic materials 0.000 description 6
- 239000010439 graphite Substances 0.000 description 6
- 230000036961 partial effect Effects 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 229910008484 TiSi Inorganic materials 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000006698 induction Effects 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 230000002441 reversible effect Effects 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000011946 reduction process Methods 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 2
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 230000028161 membrane depolarization Effects 0.000 description 2
- 238000005058 metal casting Methods 0.000 description 2
- 239000012811 non-conductive material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 230000027756 respiratory electron transport chain Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000001360 synchronised effect Effects 0.000 description 2
- 238000012932 thermodynamic analysis Methods 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical class [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- 244000005894 Albizia lebbeck Species 0.000 description 1
- 238000004131 Bayer process Methods 0.000 description 1
- 208000015943 Coeliac disease Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000408551 Meza Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 241001483078 Phyto Species 0.000 description 1
- 241000935372 Tisias Species 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- 241000256856 Vespidae Species 0.000 description 1
- 229910001093 Zr alloy Inorganic materials 0.000 description 1
- CPTCUNLUKFTXKF-UHFFFAOYSA-N [Ti].[Zr].[Mo] Chemical compound [Ti].[Zr].[Mo] CPTCUNLUKFTXKF-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical class F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000005520 electrodynamics Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 238000005184 irreversible process Methods 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 101150088250 matK gene Proteins 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
- C25C3/28—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium of titanium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT97TO000080A ITTO970080A1 (it) | 1997-02-04 | 1997-02-04 | Procedimento per la produzione elettrolitica di metalli |
| PCT/IB1998/000019 WO1998033956A1 (en) | 1997-02-04 | 1998-01-08 | Process for the electrolytic production of metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA65558C2 true UA65558C2 (en) | 2004-04-15 |
Family
ID=11415304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA99094919A UA65558C2 (en) | 1997-02-04 | 1998-08-01 | A process for the electrolytic production of metals |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6074545A (cs) |
| EP (1) | EP0958409B1 (cs) |
| JP (1) | JP2001509842A (cs) |
| KR (1) | KR100485233B1 (cs) |
| CN (1) | CN1204298C (cs) |
| AR (1) | AR009447A1 (cs) |
| AT (1) | ATE237008T1 (cs) |
| AU (1) | AU736061B2 (cs) |
| BR (1) | BR9807156A (cs) |
| CZ (1) | CZ297064B6 (cs) |
| DE (1) | DE69813183D1 (cs) |
| EA (1) | EA002205B1 (cs) |
| IS (1) | IS5124A (cs) |
| IT (1) | ITTO970080A1 (cs) |
| NO (1) | NO321451B1 (cs) |
| NZ (1) | NZ337553A (cs) |
| SA (1) | SA98181043A (cs) |
| UA (1) | UA65558C2 (cs) |
| WO (1) | WO1998033956A1 (cs) |
| ZA (1) | ZA98897B (cs) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9812169D0 (en) * | 1998-06-05 | 1998-08-05 | Univ Cambridge Tech | Purification method |
| AU2002244540B2 (en) * | 2001-04-10 | 2007-01-18 | Bhp Billiton Innovation Pty Ltd | Electrolytic reduction of metal oxides |
| AUPR443801A0 (en) * | 2001-04-10 | 2001-05-17 | Bhp Innovation Pty Ltd | Removal of oxygen from metal oxides and solid metal solutions |
| AUPR712101A0 (en) | 2001-08-16 | 2001-09-06 | Bhp Innovation Pty Ltd | Process for manufacture of titanium products |
| US7504017B2 (en) | 2001-11-22 | 2009-03-17 | Qit-Fer Et Titane Inc. | Method for electrowinning of titanium metal or alloy from titanium oxide containing compound in the liquid state |
| KR101038701B1 (ko) * | 2002-03-13 | 2011-06-02 | 비에이치피 빌리튼 이노베이션 피티와이 리미티드 | 전해 전지에서 금속 산화물을 환원시키는 방법 |
| AUPS107102A0 (en) * | 2002-03-13 | 2002-04-11 | Bhp Billiton Innovation Pty Ltd | Electrolytic reduction of metal oxides |
| US7410562B2 (en) * | 2003-08-20 | 2008-08-12 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
| US7381366B2 (en) * | 2003-12-31 | 2008-06-03 | General Electric Company | Apparatus for the production or refining of metals, and related processes |
| JP2005264320A (ja) * | 2004-02-20 | 2005-09-29 | Sumitomo Titanium Corp | Ｃａ還元によるＴｉ又はＴｉ合金の製造方法 |
| JP4342413B2 (ja) * | 2004-02-20 | 2009-10-14 | 株式会社大阪チタニウムテクノロジーズ | Ｃａ還元によるＴｉ又はＴｉ合金の製造方法 |
| JP4247792B2 (ja) * | 2004-10-12 | 2009-04-02 | 東邦チタニウム株式会社 | 溶融塩電解による金属の製造方法および製造装置 |
| AU2005293039A1 (en) * | 2004-10-12 | 2006-04-20 | Osaka Titanium Technologies Co., Ltd. | Method for producing metal by molten salt electrolysis and method for producing metal titanium |
| US8555809B2 (en) * | 2010-01-14 | 2013-10-15 | Rohm And Haas Electronic Materials, Llc | Method for constant concentration evaporation and a device using the same |
| US8980068B2 (en) | 2010-08-18 | 2015-03-17 | Allen R. Hayes | Nickel pH adjustment method and apparatus |
| CN102978664B (zh) * | 2011-09-05 | 2015-12-02 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种金属钒的制备方法及由该方法得到的金属钒 |
| CN102400179A (zh) * | 2011-11-22 | 2012-04-04 | 中国铝业股份有限公司 | 一种惰性电极铝电解槽电极导杆的保护方法 |
| EP2794943B8 (en) | 2011-12-22 | 2019-07-10 | Universal Achemetal Titanium, LLC | A method for extraction and refining of titanium |
| CN102553664B (zh) * | 2012-01-06 | 2013-12-18 | 中国科学院上海应用物理研究所 | 熔盐电化学实验装置 |
| GB201208698D0 (en) | 2012-05-16 | 2012-06-27 | Metalysis Ltd | Electrolytic method,apparatus and product |
| CN103834971B (zh) * | 2012-11-23 | 2016-08-17 | 宁波创润新材料有限公司 | 电极及熔盐电解装置 |
| CN103911630B (zh) * | 2013-01-05 | 2016-06-01 | 汉中锌业特种材料有限公司 | 30ka液态阴极金属钙电解槽 |
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| WO2016061577A1 (en) * | 2014-10-17 | 2016-04-21 | Infinium, Inc. | Method and apparatus for liquid metal electrode connection in production or refining of metals |
| CN104313645B (zh) * | 2014-10-28 | 2017-08-08 | 苏州萨伯工业设计有限公司 | 含钪铝合金材料的制备装置及制备工艺 |
| CN104789991B (zh) * | 2015-05-13 | 2017-01-25 | 江西理工大学 | 电解精炼及原位定向凝固制备高纯稀土金属的方法和装置 |
| CN105441987A (zh) * | 2015-12-21 | 2016-03-30 | 江西稀有金属钨业控股集团有限公司 | 一种液态阴极生产稀土金属及合金的稀土熔盐电解槽 |
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| CN109996896B (zh) | 2016-09-14 | 2021-10-26 | 通用金属钛有限责任公司 | 生产钛-铝-钒合金的方法 |
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| CN108728870B (zh) * | 2017-08-07 | 2021-02-12 | 南京佑天金属科技有限公司 | 晶条铪的生产系统及其方法 |
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| CN109609975B (zh) * | 2019-02-01 | 2020-02-18 | 清苑县伟豪铝业有限公司 | 电解原位制备铝合金的方法 |
| CN113445080B (zh) * | 2021-06-09 | 2023-01-17 | 北京科技大学 | 一种基于液态阴极-可溶性含钛阳极直接电解制备钛合金的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB786460A (en) * | 1954-11-10 | 1957-11-20 | Norton Grinding Wheel Co Ltd | Process and apparatus for the electrolytic extraction of titanium metal |
| US3030285A (en) * | 1955-05-31 | 1962-04-17 | Union Carbide Corp | Semi-continuous electrolytic process |
| US3087873A (en) * | 1960-06-15 | 1963-04-30 | Timax Associates | Electrolytic production of metal alloys |
| US3383294A (en) * | 1965-01-15 | 1968-05-14 | Wood Lyle Russell | Process for production of misch metal and apparatus therefor |
| BE698705A (cs) * | 1967-05-19 | 1967-11-03 | ||
| US3909375A (en) * | 1972-04-17 | 1975-09-30 | Conzinc Riotinto Ltd | Electrolytic process for the production of metals in molten halide systems |
| JPS61186489A (ja) * | 1985-02-13 | 1986-08-20 | Hiroshi Ishizuka | アルカリ金属または土金属の溶融塩化物電解装置 |
| IT1199898B (it) * | 1985-07-22 | 1989-01-05 | Ginatta Marco Elettrochim | Impianto per la produzione elettrolitica in bagno di sali fusi di metalli reattivi |
| IT1219222B (it) * | 1988-04-19 | 1990-05-03 | Ginatta Spa | Procedimento per la produzione elettrolitica di un metallo polivalente ed apparecchiatura per l'attuazione del procedimento |
| US5242563A (en) * | 1992-03-12 | 1993-09-07 | The United States Of America As Represented By The Secretary Of The Navy | Molten salt reactor for potentiostatic electroplating |
-
1997
- 1997-02-04 IT IT97TO000080A patent/ITTO970080A1/it not_active IP Right Cessation
-
1998
- 1998-01-08 KR KR10-1999-7006991A patent/KR100485233B1/ko not_active IP Right Cessation
- 1998-01-08 CN CNB988022486A patent/CN1204298C/zh not_active Expired - Fee Related
- 1998-01-08 DE DE69813183T patent/DE69813183D1/de not_active Expired - Lifetime
- 1998-01-08 BR BR9807156-4A patent/BR9807156A/pt not_active Application Discontinuation
- 1998-01-08 WO PCT/IB1998/000019 patent/WO1998033956A1/en active IP Right Grant
- 1998-01-08 NZ NZ337553A patent/NZ337553A/en unknown
- 1998-01-08 AT AT98900019T patent/ATE237008T1/de not_active IP Right Cessation
- 1998-01-08 CZ CZ0273599A patent/CZ297064B6/cs not_active IP Right Cessation
- 1998-01-08 EP EP98900019A patent/EP0958409B1/en not_active Expired - Lifetime
- 1998-01-08 AU AU81918/98A patent/AU736061B2/en not_active Ceased
- 1998-01-08 JP JP53266598A patent/JP2001509842A/ja not_active Ceased
- 1998-01-08 EA EA199900722A patent/EA002205B1/ru not_active IP Right Cessation
- 1998-02-04 AR ARP980100498A patent/AR009447A1/es active IP Right Grant
- 1998-02-04 ZA ZA98897A patent/ZA98897B/xx unknown
- 1998-02-04 US US09/018,539 patent/US6074545A/en not_active Expired - Fee Related
- 1998-03-25 SA SA98181043A patent/SA98181043A/ar unknown
- 1998-08-01 UA UA99094919A patent/UA65558C2/uk unknown
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1999
- 1999-07-13 NO NO19993455A patent/NO321451B1/no unknown
- 1999-07-20 IS IS5124A patent/IS5124A/is unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998033956A1 (en) | 1998-08-06 |
| JP2001509842A (ja) | 2001-07-24 |
| ZA98897B (en) | 1998-08-17 |
| KR100485233B1 (ko) | 2005-04-25 |
| NO993455L (no) | 1999-09-28 |
| NO993455D0 (no) | 1999-07-13 |
| IS5124A (is) | 1999-07-20 |
| AR009447A1 (es) | 2000-04-12 |
| KR20000070740A (ko) | 2000-11-25 |
| CN1246897A (zh) | 2000-03-08 |
| NO321451B1 (no) | 2006-05-15 |
| EA199900722A1 (ru) | 2000-02-28 |
| CZ273599A3 (cs) | 2000-04-12 |
| ATE237008T1 (de) | 2003-04-15 |
| EP0958409B1 (en) | 2003-04-09 |
| AU8191898A (en) | 1998-08-25 |
| CN1204298C (zh) | 2005-06-01 |
| US6074545A (en) | 2000-06-13 |
| CZ297064B6 (cs) | 2006-08-16 |
| EA002205B1 (ru) | 2002-02-28 |
| NZ337553A (en) | 2001-04-27 |
| BR9807156A (pt) | 2000-01-25 |
| SA98181043A (ar) | 2005-12-03 |
| AU736061B2 (en) | 2001-07-26 |
| DE69813183D1 (de) | 2003-05-15 |
| EP0958409A1 (en) | 1999-11-24 |
| ITTO970080A1 (it) | 1998-08-04 |
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