TWM656529U - Heat dissipation compound and heat dissipation structure using the same - Google Patents
Heat dissipation compound and heat dissipation structure using the same Download PDFInfo
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- TWM656529U TWM656529U TW112213613U TW112213613U TWM656529U TW M656529 U TWM656529 U TW M656529U TW 112213613 U TW112213613 U TW 112213613U TW 112213613 U TW112213613 U TW 112213613U TW M656529 U TWM656529 U TW M656529U
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- Prior art keywords
- heat
- heat dissipation
- adhesive
- compound
- tungsten oxide
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- 230000017525 heat dissipation Effects 0.000 title claims abstract description 107
- 150000001875 compounds Chemical class 0.000 title claims abstract description 38
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000010410 layer Substances 0.000 claims abstract description 41
- 239000000853 adhesive Substances 0.000 claims abstract description 39
- 230000001070 adhesive effect Effects 0.000 claims abstract description 39
- 239000012790 adhesive layer Substances 0.000 claims abstract description 31
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000009413 insulation Methods 0.000 claims abstract description 19
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 34
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 34
- 239000002131 composite material Substances 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- 229920005989 resin Polymers 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 229910021389 graphene Inorganic materials 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 15
- 229920006243 acrylic copolymer Polymers 0.000 claims description 11
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 9
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000003208 petroleum Substances 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- 235000007586 terpenes Nutrition 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000011889 copper foil Substances 0.000 claims description 4
- 239000011888 foil Substances 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 13
- 239000003292 glue Substances 0.000 abstract description 7
- 230000006870 function Effects 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 20
- 238000012360 testing method Methods 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 14
- 239000002918 waste heat Substances 0.000 description 13
- 238000001514 detection method Methods 0.000 description 10
- PGLIUCLTXOYQMV-UHFFFAOYSA-N Cetirizine hydrochloride Chemical compound Cl.Cl.C1CN(CCOCC(=O)O)CCN1C(C=1C=CC(Cl)=CC=1)C1=CC=CC=C1 PGLIUCLTXOYQMV-UHFFFAOYSA-N 0.000 description 7
- 229940125904 compound 1 Drugs 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241000233805 Phoenix Species 0.000 description 1
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000012938 design process Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001931 thermography Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Abstract
Description
本新型關於一種複合物及應用該複合物的結構,特別是一種應用於電子產品中以提供有效散熱通道的散熱複合物及應用該散熱複合物的散熱結構。 The present invention relates to a composite and a structure using the composite, in particular to a heat dissipation composite used in electronic products to provide an effective heat dissipation channel and a heat dissipation structure using the heat dissipation composite.
隨著電子產品的體積越來越小,或是在特定的體積內塞入越來越多元件,甚至是將基礎元件,如處理器的製程更精細化,以便在其中加入更多的功能性結構,廢熱處理變成為了影響這些電子產品的一個顯著問題。由於廢熱的來源是由輸入電能在執行完電子元件的運作後轉換而來,越多的電子元件代表廢熱源與廢熱量越多,更何況許多電子元件是高耗能的。狹小密閉的容置空間容易讓累積的廢熱難以排除,由此引發使用者對使用這些電子產品時的體驗不佳。為了解決這個問題,在許多電子產品的設計過程中,散熱結構是重中之重。 As electronic products become smaller and smaller, or more and more components are packed into a specific volume, or even the process of basic components such as processors is refined to add more functional structures, waste heat treatment has become a significant problem affecting these electronic products. Since the source of waste heat is the input power converted after the operation of the electronic components, more electronic components mean more waste heat sources and waste heat, not to mention that many electronic components are high energy consumption. Small and closed storage spaces make it easy for accumulated waste heat to be difficult to remove, which causes users to have a bad experience when using these electronic products. To solve this problem, in the design process of many electronic products, heat dissipation structure is the top priority.
以筆記型電腦為例,這類型的產品都在有限的空間中塞入了如電池、鍵盤模組等較大體積的基礎元件,留給剩餘電子元件的空間不多。眾所周知,筆記型電腦中最耗電力的裝置是CPU(Central Processing Unit,即中央處理器)與GPU(Graphics Processing Unit,即圖形處理器),尤其在滿負載運轉時,單位時間產生的廢熱量驚人。雖然筆記型電腦具有風扇、導熱片與機殼的通風孔等設計,能將廢熱最大程度地由內部較低溫的傳導元件及外部空氣所循環帶離,但是使用者都有如下的體驗:在接近CPU或GPU的機殼處可以明顯感受到CPU或GPU 廢熱直接透過機殼傳導的高溫。為了降低這種問題帶來的不適感,一般筆記型電腦的散熱模組除了會使用銅鋁材料的散熱模組配合風扇形成的風路,將CPU或GPU的熱量傳導到散熱孔處外,同時也會在機殼與主機板間加上導熱片,增加導熱片上的熱量直接向機殼傳導並均勻擴散。如果加入一層隔熱片在導熱片與機殼間,可以減少廢熱向機殼傳導的量,但需要使用另一層固定膠固定於機殼上。如此一來,整個散熱片結構的厚度因為加隔熱片與固定膠而變厚,反過來又制約了筆電輕薄設計的需求。 Take laptops as an example. This type of product is packed with large basic components such as batteries and keyboard modules in a limited space, leaving little space for other electronic components. As we all know, the most power-consuming devices in laptops are the CPU (Central Processing Unit) and GPU (Graphics Processing Unit). Especially when running at full load, the amount of waste heat generated per unit time is alarming. Although laptops have fans, heat sinks, and vents in the case, which can remove waste heat to the greatest extent possible through internal lower-temperature conductive components and external air circulation, users have the following experience: the high temperature of the CPU or GPU waste heat can be clearly felt in the case near the CPU or GPU. In order to reduce the discomfort caused by this problem, the general laptop heat dissipation module not only uses a copper-aluminum heat dissipation module with a fan to form an air path to transfer the heat of the CPU or GPU to the heat dissipation holes, but also adds a heat sink between the case and the motherboard to increase the heat on the heat sink to be directly transferred to the case and evenly diffused. If a layer of heat insulation is added between the heat conductive sheet and the case, the amount of waste heat transferred to the case can be reduced, but another layer of fixing glue is required to fix it to the case. In this way, the thickness of the entire heat sink structure becomes thicker due to the addition of the heat insulation sheet and fixing glue, which in turn restricts the demand for a thin and light design of the laptop.
為了減少上述散熱模組的厚度,同時降低因為傳導所造成的廢熱直接傳出電子產品外殼的困擾,因而有本新型之提出。 In order to reduce the thickness of the above-mentioned heat dissipation module and at the same time reduce the trouble of waste heat being directly transmitted out of the outer casing of the electronic product due to conduction, the present invention is proposed.
本段文字提取和編譯本新型的某些特點。其它特點將被揭露於後續段落中。其目的在涵蓋附加的申請專利範圍之精神和範圍中,各式的修改和類似的排列。 This paragraph extracts and compiles certain features of this new invention. Other features will be revealed in subsequent paragraphs. Its purpose is to cover various modifications and similar arrangements within the spirit and scope of the attached patent application.
為了解決前述問題,本新型揭露一種散熱複合物。該散熱複合物包含:一導熱層;以及一隔熱黏著層,形成於該導熱層下方,由一黏著劑與氧化鎢溶液均勻混合製成。該黏著劑包含均勻混合的55至58重量份的丙烯酸酯類共聚物、20至22重量份的醋酸乙酯及15至20重量份的甲苯,該黏著劑與氧化鎢溶液混合時的重量比為1:0.1~1:0.3。 In order to solve the above-mentioned problems, the present invention discloses a heat dissipation composite. The heat dissipation composite comprises: a heat conductive layer; and a heat insulating adhesive layer formed below the heat conductive layer, which is made by uniformly mixing an adhesive and a tungsten oxide solution. The adhesive comprises 55 to 58 parts by weight of an acrylic copolymer, 20 to 22 parts by weight of ethyl acetate and 15 to 20 parts by weight of toluene uniformly mixed, and the weight ratio of the adhesive to the tungsten oxide solution when mixed is 1:0.1~1:0.3.
最好,該導熱層的材質為石墨烯、銅箔、鋁箔或其他導熱材料。 Preferably, the material of the thermal conductive layer is graphene, copper foil, aluminum foil or other thermal conductive materials.
最好,該隔熱黏著層的厚度介於0.1mm至0.15mm之間。 Preferably, the thickness of the thermal insulation adhesive layer is between 0.1 mm and 0.15 mm.
依照本新型,丙烯酸酯類共聚物可包含丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂,其中丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂的 重量比為10:10:5:4。增黏樹脂可為石油樹脂、松香樹脂、萜烯樹脂、萜烯酚醛樹脂或前述樹脂的至少二種之混合物。 According to the present invention, the acrylic copolymer may include butyl acrylate, isooctyl acrylate, vinyl acetate and tackifying resin, wherein the weight ratio of butyl acrylate, isooctyl acrylate, vinyl acetate and tackifying resin is 10:10:5:4. The tackifying resin may be a petroleum resin, a rosin resin, a terpene resin, a terpene phenolic resin or a mixture of at least two of the aforementioned resins.
依照本新型,該氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯、乙酸丁酯或異丙醇,該氧化鎢溶液中溶質與溶劑的重量比例介於3:7至4:6。 According to the present invention, the solute in the tungsten oxide solution is tungsten oxide, the solvent is ethyl acetate, butyl acetate or isopropanol, and the weight ratio of the solute to the solvent in the tungsten oxide solution is between 3:7 and 4:6.
本新型還揭露一種應用散熱複合物的散熱結構,安裝於具有一進氣開孔與一出氣開孔的一殼體中,用以將該殼體內部一熱源發出的熱量之大部分由流出該出氣開孔的空氣帶離該殼體。該散熱結構包含:前述散熱複合物所製成的一導熱片,該導熱片具有一第一端與一第二端,以該隔熱黏著層黏附於該殼體內部表面,其中該第一端面向該熱源,該第二端位於該出氣開孔附近;一風扇模組,轉動以將外部空氣經由該進氣開孔吸入並由該出氣開孔流出,帶走該熱源及該導熱片上的部分熱量;以及一電源模組,與該風扇模組電連接,用以提供該風扇模組轉動時所需的電力。 The present invention also discloses a heat dissipation structure using a heat dissipation compound, which is installed in a housing having an air inlet opening and an air outlet opening, and is used to carry most of the heat generated by a heat source inside the housing away from the housing by air flowing out of the air outlet opening. The heat dissipation structure comprises: a heat conductive sheet made of the aforementioned heat dissipation compound, the heat conductive sheet having a first end and a second end, and adhered to the inner surface of the housing by the heat insulating adhesive layer, wherein the first end faces the heat source, and the second end is located near the air outlet opening; a fan module, which rotates to inhale external air through the air inlet opening and flows out from the air outlet opening, taking away part of the heat from the heat source and the heat conductive sheet; and a power module, which is electrically connected to the fan module, and is used to provide the power required for the fan module to rotate.
本新型更揭露另一種應用散熱複合物的散熱結構,安裝於具有一散熱位置的一殼體中,用以將該殼體內部一熱源發出的熱量之大部分導引至該散熱位置以向該殼體外部排出。該散熱結構包含前述散熱複合物所製成的一導熱片,該導熱片具有一第一端與一第二端,以該隔熱黏著層黏附於該殼體內部表面。該第一端緊貼該熱源,該第二端位於該散熱位置。 The present invention further discloses another heat dissipation structure using a heat dissipation compound, which is installed in a housing having a heat dissipation position, and is used to guide most of the heat generated by a heat source inside the housing to the heat dissipation position for discharge to the outside of the housing. The heat dissipation structure includes a heat conductive sheet made of the aforementioned heat dissipation compound, the heat conductive sheet having a first end and a second end, and is adhered to the inner surface of the housing by the heat insulating adhesive layer. The first end is closely attached to the heat source, and the second end is located at the heat dissipation position.
本新型的隔熱黏著層取代了傳統導熱片中的隔熱材與固定膠,讓具有隔熱及黏附功能的隔熱黏著層增加了傳統導熱片的隔熱效果,並減少其厚度,熱黏著層在散熱過程中能讓熱源減少直接向殼體傳導熱量。因此,前述問題可以獲得解決。 This new type of thermal insulation adhesive layer replaces the thermal insulation material and fixing glue in the traditional thermal conductive sheet, so that the thermal insulation adhesive layer with thermal insulation and adhesion functions increases the thermal insulation effect of the traditional thermal conductive sheet and reduces its thickness. The thermal adhesive layer can reduce the heat source from directly transferring heat to the shell during the heat dissipation process. Therefore, the above-mentioned problem can be solved.
1:散熱複合物 1: Heat dissipation compound
2:筆記型電腦 2: Laptop computer
3:熱成像儀 3: Thermal imaging device
3’:溫度測試儀 3’: Temperature tester
4:智慧型手機 4: Smartphone
10:導熱層 10: Thermal conductive layer
20:隔熱黏著層 20: Heat-insulating adhesive layer
30:丙烯酸背膠 30: Acrylic adhesive
40:主導熱層 40: Main thermal conductive layer
100:上部機殼 100: Upper casing
110:LED螢幕模組 110:LED screen module
200:下部機殼 200: Lower casing
201:進氣開孔 201: Air intake opening
202:出氣開孔 202: Air outlet opening
210:鍵盤模組 210: Keyboard module
220:電路板 220: Circuit board
221:熱源 221: Heat source
230:電池模組 230:Battery module
240:風扇模組 240: Fan module
250:導熱片 250: Heat sink
251:第一端 251: First end
252:第二端 252: Second end
300:殼體 300: Shell
310:散熱位置 310: Heat dissipation location
320:熱源 320: Heat source
330:導熱片 330: Heat sink
331:第一端 331: First end
332:第二端 332: Second end
圖1為依照本新型實施方式的一種散熱複合物的結構示意圖。 Figure 1 is a schematic diagram of the structure of a heat dissipation composite according to the present novel embodiment.
圖2繪示一個筆記型電腦的剖面結構。 Figure 2 shows the cross-sectional structure of a laptop computer.
圖3繪示散熱複合物的另一種結構。 Figure 3 shows another structure of the heat sink compound.
圖4繪示一個智慧型手機的剖面結構。 Figure 4 shows the cross-sectional structure of a smart phone.
圖5繪示第一比較例與第一到第三實施例的測試結果。 FIG5 shows the test results of the first comparative example and the first to third embodiments.
圖6繪示第二比較例與第四到第六實施例的測試結果。 FIG6 shows the test results of the second comparative example and the fourth to sixth embodiments.
本新型將藉由參照下列的實施方式而更具體地描述。 The new invention will be described in more detail by referring to the following implementation methods.
請見圖1,該圖為依照本新型實施方式的一種散熱複合物1的結構示意圖。本新型的散熱複合物1包含了兩個層狀結構:一導熱層10與一隔熱黏著層20,隔熱黏著層20形成於導熱層10的下方。要注意的是,圖1中的散熱複合物1長度與厚度未依比例繪示,實際應用上長度會較厚度來得大得多。散熱複合物1可裁剪成任何的形狀,安裝於諸如電子產品的殼體中,用來將殼體內部熱源發出的熱量的大部分於該殼體中導引流動。導熱層10使用的是通常用於電子產品內部的散熱的材料,比如但不限於石墨烯、銅箔或鋁箔。在以下的實施例中,導熱層10使用石墨烯為例來說明,其尺寸會進一步於對應的實施例中說明。導熱層10的功能是吸收熱源發出的大部分熱量,由其一端傳導到另一端。然而,導熱層10吸收熱量的一部分也會傳導到電子產品的殼體上,讓使用者感受到不適感。因此,隔熱黏著層20具有隔熱的作用,減少接收來自導熱層10的熱量。
Please see Figure 1, which is a schematic diagram of the structure of a
依照本新型,隔熱黏著層20取代了現有隔熱材與附著膠的功能,因此能減少電子產品的殼體預留給隔熱材安裝時的空間(厚度)。隔熱黏著層20由一黏著劑與氧化鎢溶液,在常溫下均勻混合製成。黏著劑包含了均勻混合的55至58重量份的丙烯酸酯類共聚物、20至22重量份的醋酸乙酯及15至20重量份的甲苯。黏著劑與氧化鎢溶液混合時的重量比為1:0.1~1:0.3。更進一步說明,丙烯酸酯類共聚物包含了丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂。混合比例方面,丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂的重量比為10:10:5:4。丙烯酸
丁酯、丙烯酸異辛酯與醋酸乙烯形成了溶液型丙烯酸樹脂系的敏膠黏劑,為了增加黏稠度,摻加了增黏樹脂。在以下的實施例中,增黏樹脂為石油樹脂。實作上,增黏樹脂還可以是松香樹脂、萜烯樹脂、萜烯酚醛樹脂或包含石油樹脂的前述樹脂的至少二種之混合物。氧化鎢溶液中溶質為氧化鎢,溶劑可以是乙酸乙酯、乙酸丁酯或異丙醇,且溶質與溶劑的重量比例介於3:7至4:6。由於隔熱黏著層20本身是具有阻熱功能膠,因此應用上可以維持非常薄的厚度,比如介於0.1mm至0.15mm之間。
According to the present invention, the heat-insulating
為了驗證本新型的散熱複合物1在阻擋熱源廢熱經由外殼發散的功效,本新型以下述的三個實施例製備不同的散熱複合物1,應用於具有熱源的測試殼體中,並與對應安裝石墨烯導熱片的第一比較例進行實機測試。
In order to verify the effectiveness of the
第一實施例 First embodiment
在本實施例中,製備尺寸為90mm*50mm*0.125mm的石墨烯導熱層10。隔熱黏著層20製備方面,先取丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與石油樹脂各20公克、20公克、10公克、與8公克,於容器中混合製成丙烯酸酯類共聚物約58公克。接著將丙烯酸酯類共聚物倒入另一容器中,以22公克的醋酸乙酯與20公克的甲苯製成的溶液裏,混合均勻,形成約100公克的黏著劑。最後將10公克的氧化鎢溶液撒向裝盛黏著劑的容器中,在常溫(25-28℃)常壓(1大氣壓)下,持續均勻地攪拌,比如15分鐘,使氧化鎢溶液與黏著劑完全混合。在第一到第三實施例中,氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯,氧化鎢與乙酸乙酯的重量比例介於3:7。將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第一散熱複合物。
In this embodiment, a graphene thermal
第二實施例 Second embodiment
在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第一實施例。不同點在
於本實施例將20公克的氧化鎢溶液倒向裝盛黏著劑的容器中,在常溫常壓下持續均勻地攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第二散熱複合物。
In this embodiment, the size of the graphene thermal
第三實施例 Third embodiment
在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第一實施例。不同點在於本實施例將30公克的氧化鎢溶液倒向裝盛黏著劑的容器中,常溫常壓下持續均勻地攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第三散熱複合物。
In this embodiment, the size of the graphene thermal
第一比較例 First comparison example
在此比較例中,為了讓導熱結構上有客觀一致的結構,採用了90mm*50mm*0.125mm的石墨烯片,下方以一層常州威斯雙聯公司的背膠將石墨烯片固定在與前述實施例中的散熱複合物相同的測試位置上。要注意的是,該背膠的厚度也控制在0.1mm至0.15mm之間。 In this comparative example, in order to make the heat conduction structure objectively consistent, a 90mm*50mm*0.125mm graphene sheet was used, and a layer of backing glue from Changzhou Weiss Shuanglian Company was used to fix the graphene sheet at the same test position as the heat dissipation compound in the above-mentioned embodiment. It should be noted that the thickness of the backing glue is also controlled between 0.1mm and 0.15mm.
以下介紹散熱複合物與石墨烯膠合物測試的環境。請見圖2,該圖繪示一個筆記型電腦2的剖面結構,第一比較例與三個實施例是安裝在一個筆記型電腦2中進行測試。更精確地說,筆記型電腦2有一個上部機殼100(尺寸為320mm*220mm*2.4mm)與一個下部機殼200(尺寸為320mm*220mm*17.1mm),材質為PC(Polycarbonate,聚碳酸酯)+ABS(Acrylonitrile Butadiene Styrene,丙烯腈-丁二烯-苯乙烯共聚物)合併而成的熱可塑性塑膠;上部機殼包含了一個LCD(Liquid-Crystal Display,即液晶顯示屏)螢幕模組110,下部機殼200包含了其它重要的電子或機構模組,比如鍵盤模組210、電路板220、電池模組230、風扇模組240與導熱片250。電路板220上有許多主被動元件,其中包含了產生熱量最大宗的元件,簡稱為熱源221。主要的熱源221有CPU與GPU(Graphics
Processing Unit,即圖形處理器),第一比較例與三個實施例應用在對CPU的散熱成效比較,熱源221為CPU。CPU使用的是AMD公司型號Ryzen 7040 Phoenix,熱設計功耗為30W。Ryzen 7040 Phoenix CPU是整合了GPU,與GPU的記憶體共享並集成在同一顆晶片上。因此,使用不同軟體來進行燒機測試,可以驅動CPU部分或GPU部分,使其以最大功率進行運轉,同時發出的廢熱量的速率也最高。Ryzen 7040 Phoenix CPU內部包含了6G的VRAM(Video RAM,即視訊隨機存取記憶體)。其它在電路板220上會產生熱量的主動元件如窄電壓直流IC、音源IC編解碼IC等,其耗電量相對Ryzen 7040 Phoenix CPU來得低,在比較上對第一比較例與三個實施例的影響都一樣。電池模組230在不使用外部電力下,由一個5700WH直流電鋰電池負責供電。風扇模組240為Lenovo型號X200的風扇,導熱片250則分別為石墨烯片、第一散熱複合物、第二散熱複合物與第三散熱複合物。
The following is an introduction to the test environment of the heat dissipation compound and the graphene glue compound. Please see FIG2 , which shows a cross-sectional structure of a
測試時,熱源221的熱量是向四周環境發散。由於風扇模組240啟動帶入外部低溫空氣,所以熱量流動(以數個箭號表示)主要向下及向側面。要注意的是,下部機殼200包含了一進氣開孔201與一出氣開孔202。導熱片250具有一第一端251與一第二端252。第一端251面向熱源221,第二端252位於出氣開孔202附近。當風扇模組240轉動時,會將外部空氣經由進氣開孔201吸入並由出氣開孔202流出(氣流方向由箭號表示,底色越深者表示溫度越高),帶走熱源221及導熱片250上的部分熱量,還是有少屬熱量會直接經由傳導,從下部機殼200散佚到空氣中。
During the test, the heat of the
筆記型電腦2下方擺設FOTRIC型號T530的熱成像儀3,用以偵測下部機殼200下方的溫度變化。圖2中的星號是熱成像儀3偵測到筆記型電腦2下方的溫度最高點,剛好位在熱源221的中央正下方。測試時,使用YOKOGAWA型號MX100的溫度測試儀3’針對該溫度最高點進行取樣量測溫度,取樣速率為每秒
鐘偵測一次,Ryzen 7040 Phoenix CPU運行穩定度測試軟體prime95。全部測試時間為7200秒,也就是取得了7200筆的溫度記錄。
A FOTRIC model T530 thermal imager 3 is placed under the
第一比較例與三個實施例的測試結果呈現於圖5中。由圖5可以看出,在第一比較例中,溫度偵測點的溫度在前700秒由起始溫度開始快速上升後,接著就是緩慢的提升。在超過50℃後,還未見停止跡象。在第一實施例中,溫度偵測點的溫度在上升到50℃左右時便停滯,雖然在700秒到3700秒間溫度偵測點的溫度高於第一比較例中同時的溫度,但到了3700秒後第一實施例的溫度偵測點的溫度就一直低於第一比較例的偵測數據。第二實施例的第二散熱複合物的散熱效果最好,整條溫度曲線都在所有曲線之下,也就是說以第二散熱複合物作為導熱片250的筆記型電腦2,用戶在熱源221下方感受到的溫度較其它使用散熱複合物或石墨烯片的筆記型電腦2來得低。第三實施例的第三散熱複合物的散熱效果雖然好於石墨烯片,但效果介於第一散熱複合物與第二散熱複合物之間。由此可以得知,在黏著劑中加入超過本身重量30%以上的氧化鎢溶液,除了製造成本增加,隔熱效果並未隨之增加。
The test results of the first comparative example and the three embodiments are shown in FIG5 . As can be seen from FIG5 , in the first comparative example, the temperature of the temperature detection point rises rapidly from the starting temperature in the first 700 seconds, and then rises slowly. After exceeding 50°C, there is no sign of stopping. In the first embodiment, the temperature of the temperature detection point stagnates when it rises to about 50°C. Although the temperature of the temperature detection point is higher than the temperature in the first comparative example at the same time between 700 seconds and 3700 seconds, the temperature of the temperature detection point of the first embodiment has been lower than the detection data of the first comparative example after 3700 seconds. The second heat dissipation compound of the second embodiment has the best heat dissipation effect, and the entire temperature curve is below all curves, that is, the temperature felt by the user under the
前述的第一比較例與三個實施例是在使用丙烯酸酯類共聚物、醋酸乙酯與甲苯在58:22:20重量比下製得的黏著劑進行的。接著以一第二比較例、一第四實施例、一第五實施例與一第六實施例,說明在不同成分比例下的黏著劑對測試結果的影響。 The first comparative example and the three examples mentioned above were conducted using an adhesive made of acrylic copolymer, ethyl acetate and toluene at a weight ratio of 58:22:20. Next, a second comparative example, a fourth example, a fifth example and a sixth example are used to illustrate the effect of adhesives at different component ratios on the test results.
第四實施例 Fourth embodiment
在本實施例中,製備尺寸為90mm*50mm*0.125mm的石墨烯導熱層10。隔熱黏著層20製備方面,先取丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與石油樹脂依照10:10:5:4的重量比,於容器中混合製成丙烯酸酯類共聚物約55公克。接著將丙烯酸酯類共聚物倒入另一容器中,以20公克的醋酸乙酯與15公克的甲苯製成的溶液裏,混合均勻,形成約90公克的黏著劑。最後將9公克的氧化鎢溶液倒向
裝盛黏著劑的容器中,在常溫(25-28℃)常壓(1大氣壓)下持續均勻攪拌,比如15分鐘,使氧化鎢溶液與黏著劑完全混合。在第四到第六實施例中,氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯,氧化鎢與乙酸乙酯的重量比例介於4:6。將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第四散熱複合物。
In this embodiment, a graphene thermal
第五實施例 Fifth embodiment
在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第四實施例。不同點在於本實施例將18公克的氧化鎢溶液倒向裝盛黏著劑的容器中,在常溫常壓下,持續均勻攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第五散熱複合物。
In this embodiment, the size of the graphene thermal
第六實施例 Sixth embodiment
在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第四實施例。不同點在於本實施例將27公克的氧化鎢溶液倒向裝盛黏著劑的容器中,在常溫常壓下,持續均勻攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第六散熱複合物。
In this embodiment, the size of the graphene thermal
第二比較例 Second comparison example
在此比較例中,為了讓導熱結構上有客觀一致的結構,採用了和第一比較例中相同規格的90mm*50mm*0.125mm的石墨烯片,其下方也以一層常州威斯雙聯的背膠將石墨烯片固定在與前述實施例中的散熱複合物相同的測試位置上。該背膠的厚度控制在0.1mm至0.15mm之間。 In this comparative example, in order to make the heat conduction structure objectively consistent, a graphene sheet of the same specifications as in the first comparative example was used, with a layer of Changzhou Weiss double-linked backing adhesive underneath to fix the graphene sheet at the same test position as the heat dissipation compound in the aforementioned embodiment. The thickness of the backing adhesive is controlled between 0.1mm and 0.15mm.
測試環境方面,第二比較例及第四到第六實施例使用了如前述的筆記型電腦2,佈設方式如圖2及相關文字所述。測試時,使用YOKOGAWA型號
MX100的溫度測試儀3’針對該溫度最高點進行取樣量測溫度,取樣速率為每秒鐘偵測一次,Ryzen 7040 Phoenix CPU運行穩定度測試軟體FurMark+TCT(AMD平台使用之測試軟體),用於測試Ryzen 7040 Phoenix CPU中的GPU效能。全部測試時間為7200秒,因此也取得了7200筆的溫度記錄。
In terms of the test environment, the second comparative example and the fourth to sixth embodiments used the
第二比較例與第四到第六實施例的測試結果呈現於圖6中。由圖6可以看出,在第二比較例中,溫度偵測點的溫度在前500秒由起始溫度開始快速上升後,接著就是緩慢的提升。在超過58℃後,還未見停止跡象。在第四實施例中,溫度偵測點的溫度在上升到50℃左右時便停滯,雖然在300秒到3000秒間溫度偵測點的溫度高於第二比較例中同時的溫度,但到了3000秒後第四實施例的溫度偵測點的溫度就一直低於第二比較例的偵測數據,最高溫度約在54℃左右。第五實施例的第五散熱複合物的散熱效果最好,整條溫度曲線都在所有曲線之下。第六實施例的第六散熱複合物的散熱效果雖然好於石墨烯片,但效果介於第四散熱複合物與第五散熱複合物之間。由此可以得知,在此款黏著劑中加入超過本身重量30%以上的氧化鎢溶液,除了製造成本增加,散熱效果並未隨之增加。 The test results of the second comparative example and the fourth to sixth embodiments are shown in FIG6 . As can be seen from FIG6 , in the second comparative example, the temperature of the temperature detection point rises rapidly from the starting temperature in the first 500 seconds, and then rises slowly. After exceeding 58°C, there is no sign of stopping. In the fourth embodiment, the temperature of the temperature detection point stagnates when it rises to about 50°C. Although the temperature of the temperature detection point is higher than the temperature in the second comparative example at the same time between 300 seconds and 3000 seconds, the temperature of the temperature detection point of the fourth embodiment is always lower than the detection data of the second comparative example after 3000 seconds, and the highest temperature is about 54°C. The fifth heat dissipation composite of the fifth embodiment has the best heat dissipation effect, and the entire temperature curve is below all curves. Although the heat dissipation effect of the sixth heat dissipation compound of the sixth embodiment is better than that of the graphene sheet, the effect is between the fourth heat dissipation compound and the fifth heat dissipation compound. It can be seen that adding more than 30% of the weight of tungsten oxide solution to this adhesive will increase the manufacturing cost but not the heat dissipation effect.
依照本新型,散熱複合物1還可以有其它的結構。請見圖3,該圖繪示散熱複合物1的另一種結構。散熱複合物1在導熱層10異於隔熱黏著層20的那一面進一步塗佈一層丙烯酸背膠30,用黏接一主導熱層40。主導熱層40的材料也可以是石墨烯、銅箔或鋁箔或其它散熱材料中的一種,形狀可以和導熱層10的相同或相異。若兩者形狀相同,可以增加散熱複合物1的導熱效能。如果主導熱層40與導熱層10的形狀不同,可以局部強化導熱效能,或是將廢熱導向不同的出氣開孔。
According to the present invention, the
如用於測試前述實施例之散熱複合物效能的筆記型電腦2,是本新型應用的一個最佳實例,在其中形成了一種應用散熱複合物的散熱結構。廣義的來說,應用散熱複合物的散熱結構安裝於具有如圖2所示的進氣開孔201與出氣開
孔202的一殼體(下部機殼200)中,用以將該殼體內部一熱源221發出的熱量之大部分由流出出氣開孔202的空氣帶離該殼體。應用散熱複合物的散熱結構包含了以上述散熱複合物1製成的導熱片250、風扇模組240與電源模組。導熱片250具有第一端251與第二端252,以隔熱黏著層20黏附於該殼體內部表面。第一端251面向熱源221,第二端252位於出氣開孔202附近。風扇模組240轉動以將外部空氣經由進氣開孔201吸入並由出氣開孔202流出,帶走熱源221及導熱片250上的部分熱量。電源模組可以是圖2中的電池模組230,也可以是筆記型電腦2或是其它電子產品中的變壓器,可將市電的交流電轉換為工作直流電。電源模組與風扇模組240電連接,用以提供風扇模組240轉動時所需的電力。
The
在前述的應用實例中,導熱片可配合風扇模組來進行導熱與散熱工作。在實作中,以本新型散熱複合物1所製成的導熱片也可應用於沒有風扇模組與內部空氣流動的電子裝置中,單純依靠傳導作用將熱源產生的熱量導引到適當的殼體位置後,排向外部空間且可降低機殼表面溫度。最好的應用例子就是智慧型手機或平板。
In the aforementioned application examples, the heat conducting sheet can be used in conjunction with the fan module to conduct and dissipate heat. In practice, the heat conducting sheet made of the novel
請見圖4,該圖繪示一個智慧型手機4的剖面結構。一種應用散熱複合物的散熱結構可安裝於具有一散熱位置310的智慧型手機4的一殼體300中,用以將殼體300內部一熱源320(如處理器)發出的熱量之大部分導引至該散熱位置310以向殼體300外部排出。實作上,散熱位置310可以是智慧型手機4的殼體300側方的喇叭孔,藉由散熱位置310附近流動的空氣將傳導的熱量帶走。該應用散熱複合物的散熱結構主要是以前述散熱複合物所製成的一導熱片330。導熱片330具有一第一端331與一第二端332,以隔熱黏著層黏附於殼體300的內部表面。安裝上,第一端331緊貼熱源320,第二端332位於散熱位置310附近。
Please see FIG. 4, which shows a cross-sectional structure of a
雖然本新型已以實施方式揭露如上,然其並非用以限定本新型,任何所屬技術領域中具有通常知識者,在不脫離本新型之精神和範圍內,當可作些許之更動與潤飾,因此本新型之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed in the form of implementation as above, it is not intended to limit the present invention. Anyone with common knowledge in the relevant technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the scope of the patent application attached hereto.
1:散熱複合物 1: Heat dissipation compound
10:導熱層 10: Thermal conductive layer
20:隔熱黏著層 20: Heat-insulating adhesive layer
Claims (10)
Publications (1)
Publication Number | Publication Date |
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TWM656529U true TWM656529U (en) | 2024-06-11 |
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