TWM656529U - Heat dissipation compound and heat dissipation structure using the same - Google Patents

Heat dissipation compound and heat dissipation structure using the same Download PDF

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TWM656529U
TWM656529U TW112213613U TW112213613U TWM656529U TW M656529 U TWM656529 U TW M656529U TW 112213613 U TW112213613 U TW 112213613U TW 112213613 U TW112213613 U TW 112213613U TW M656529 U TWM656529 U TW M656529U
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heat
heat dissipation
adhesive
compound
tungsten oxide
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TW112213613U
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Chinese (zh)
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黃政凱
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巽飛科技有限公司
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Abstract

A heat dissipation compound is disclosed. The heat dissipation compound includes: a thermal conductive layer; and a thermal insulation adhesive layer formed under the thermal conductive layer and made of an adhesive and tungsten carbide powder solution mixed. The adhesive includes uniformly mixed 55 to 58 parts by weight of acrylate copolymer, 20 to 22 parts by weight of ethyl acetate, and 15 to 20 parts by weight of toluene. The weight ratio when the adhesive is mixed with tungsten carbide powder solution is 1:0.1~1:0.3. The thermal insulation adhesive layer of the present invention replaces the fixing glue in the traditional heat sink and increases thermal insulation effect of traditional heat sinks, so that the thermal insulation adhesive layer with heat dissipation and adhesion functions allows a heat source to reduce heat conduction directly to the shell.

Description

散熱複合物及應用該散熱複合物的散熱結構 Heat dissipation compound and heat dissipation structure using the heat dissipation compound

本新型關於一種複合物及應用該複合物的結構,特別是一種應用於電子產品中以提供有效散熱通道的散熱複合物及應用該散熱複合物的散熱結構。 The present invention relates to a composite and a structure using the composite, in particular to a heat dissipation composite used in electronic products to provide an effective heat dissipation channel and a heat dissipation structure using the heat dissipation composite.

隨著電子產品的體積越來越小,或是在特定的體積內塞入越來越多元件,甚至是將基礎元件,如處理器的製程更精細化,以便在其中加入更多的功能性結構,廢熱處理變成為了影響這些電子產品的一個顯著問題。由於廢熱的來源是由輸入電能在執行完電子元件的運作後轉換而來,越多的電子元件代表廢熱源與廢熱量越多,更何況許多電子元件是高耗能的。狹小密閉的容置空間容易讓累積的廢熱難以排除,由此引發使用者對使用這些電子產品時的體驗不佳。為了解決這個問題,在許多電子產品的設計過程中,散熱結構是重中之重。 As electronic products become smaller and smaller, or more and more components are packed into a specific volume, or even the process of basic components such as processors is refined to add more functional structures, waste heat treatment has become a significant problem affecting these electronic products. Since the source of waste heat is the input power converted after the operation of the electronic components, more electronic components mean more waste heat sources and waste heat, not to mention that many electronic components are high energy consumption. Small and closed storage spaces make it easy for accumulated waste heat to be difficult to remove, which causes users to have a bad experience when using these electronic products. To solve this problem, in the design process of many electronic products, heat dissipation structure is the top priority.

以筆記型電腦為例,這類型的產品都在有限的空間中塞入了如電池、鍵盤模組等較大體積的基礎元件,留給剩餘電子元件的空間不多。眾所周知,筆記型電腦中最耗電力的裝置是CPU(Central Processing Unit,即中央處理器)與GPU(Graphics Processing Unit,即圖形處理器),尤其在滿負載運轉時,單位時間產生的廢熱量驚人。雖然筆記型電腦具有風扇、導熱片與機殼的通風孔等設計,能將廢熱最大程度地由內部較低溫的傳導元件及外部空氣所循環帶離,但是使用者都有如下的體驗:在接近CPU或GPU的機殼處可以明顯感受到CPU或GPU 廢熱直接透過機殼傳導的高溫。為了降低這種問題帶來的不適感,一般筆記型電腦的散熱模組除了會使用銅鋁材料的散熱模組配合風扇形成的風路,將CPU或GPU的熱量傳導到散熱孔處外,同時也會在機殼與主機板間加上導熱片,增加導熱片上的熱量直接向機殼傳導並均勻擴散。如果加入一層隔熱片在導熱片與機殼間,可以減少廢熱向機殼傳導的量,但需要使用另一層固定膠固定於機殼上。如此一來,整個散熱片結構的厚度因為加隔熱片與固定膠而變厚,反過來又制約了筆電輕薄設計的需求。 Take laptops as an example. This type of product is packed with large basic components such as batteries and keyboard modules in a limited space, leaving little space for other electronic components. As we all know, the most power-consuming devices in laptops are the CPU (Central Processing Unit) and GPU (Graphics Processing Unit). Especially when running at full load, the amount of waste heat generated per unit time is alarming. Although laptops have fans, heat sinks, and vents in the case, which can remove waste heat to the greatest extent possible through internal lower-temperature conductive components and external air circulation, users have the following experience: the high temperature of the CPU or GPU waste heat can be clearly felt in the case near the CPU or GPU. In order to reduce the discomfort caused by this problem, the general laptop heat dissipation module not only uses a copper-aluminum heat dissipation module with a fan to form an air path to transfer the heat of the CPU or GPU to the heat dissipation holes, but also adds a heat sink between the case and the motherboard to increase the heat on the heat sink to be directly transferred to the case and evenly diffused. If a layer of heat insulation is added between the heat conductive sheet and the case, the amount of waste heat transferred to the case can be reduced, but another layer of fixing glue is required to fix it to the case. In this way, the thickness of the entire heat sink structure becomes thicker due to the addition of the heat insulation sheet and fixing glue, which in turn restricts the demand for a thin and light design of the laptop.

為了減少上述散熱模組的厚度,同時降低因為傳導所造成的廢熱直接傳出電子產品外殼的困擾,因而有本新型之提出。 In order to reduce the thickness of the above-mentioned heat dissipation module and at the same time reduce the trouble of waste heat being directly transmitted out of the outer casing of the electronic product due to conduction, the present invention is proposed.

本段文字提取和編譯本新型的某些特點。其它特點將被揭露於後續段落中。其目的在涵蓋附加的申請專利範圍之精神和範圍中,各式的修改和類似的排列。 This paragraph extracts and compiles certain features of this new invention. Other features will be revealed in subsequent paragraphs. Its purpose is to cover various modifications and similar arrangements within the spirit and scope of the attached patent application.

為了解決前述問題,本新型揭露一種散熱複合物。該散熱複合物包含:一導熱層;以及一隔熱黏著層,形成於該導熱層下方,由一黏著劑與氧化鎢溶液均勻混合製成。該黏著劑包含均勻混合的55至58重量份的丙烯酸酯類共聚物、20至22重量份的醋酸乙酯及15至20重量份的甲苯,該黏著劑與氧化鎢溶液混合時的重量比為1:0.1~1:0.3。 In order to solve the above-mentioned problems, the present invention discloses a heat dissipation composite. The heat dissipation composite comprises: a heat conductive layer; and a heat insulating adhesive layer formed below the heat conductive layer, which is made by uniformly mixing an adhesive and a tungsten oxide solution. The adhesive comprises 55 to 58 parts by weight of an acrylic copolymer, 20 to 22 parts by weight of ethyl acetate and 15 to 20 parts by weight of toluene uniformly mixed, and the weight ratio of the adhesive to the tungsten oxide solution when mixed is 1:0.1~1:0.3.

最好,該導熱層的材質為石墨烯、銅箔、鋁箔或其他導熱材料。 Preferably, the material of the thermal conductive layer is graphene, copper foil, aluminum foil or other thermal conductive materials.

最好,該隔熱黏著層的厚度介於0.1mm至0.15mm之間。 Preferably, the thickness of the thermal insulation adhesive layer is between 0.1 mm and 0.15 mm.

依照本新型,丙烯酸酯類共聚物可包含丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂,其中丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂的 重量比為10:10:5:4。增黏樹脂可為石油樹脂、松香樹脂、萜烯樹脂、萜烯酚醛樹脂或前述樹脂的至少二種之混合物。 According to the present invention, the acrylic copolymer may include butyl acrylate, isooctyl acrylate, vinyl acetate and tackifying resin, wherein the weight ratio of butyl acrylate, isooctyl acrylate, vinyl acetate and tackifying resin is 10:10:5:4. The tackifying resin may be a petroleum resin, a rosin resin, a terpene resin, a terpene phenolic resin or a mixture of at least two of the aforementioned resins.

依照本新型,該氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯、乙酸丁酯或異丙醇,該氧化鎢溶液中溶質與溶劑的重量比例介於3:7至4:6。 According to the present invention, the solute in the tungsten oxide solution is tungsten oxide, the solvent is ethyl acetate, butyl acetate or isopropanol, and the weight ratio of the solute to the solvent in the tungsten oxide solution is between 3:7 and 4:6.

本新型還揭露一種應用散熱複合物的散熱結構,安裝於具有一進氣開孔與一出氣開孔的一殼體中,用以將該殼體內部一熱源發出的熱量之大部分由流出該出氣開孔的空氣帶離該殼體。該散熱結構包含:前述散熱複合物所製成的一導熱片,該導熱片具有一第一端與一第二端,以該隔熱黏著層黏附於該殼體內部表面,其中該第一端面向該熱源,該第二端位於該出氣開孔附近;一風扇模組,轉動以將外部空氣經由該進氣開孔吸入並由該出氣開孔流出,帶走該熱源及該導熱片上的部分熱量;以及一電源模組,與該風扇模組電連接,用以提供該風扇模組轉動時所需的電力。 The present invention also discloses a heat dissipation structure using a heat dissipation compound, which is installed in a housing having an air inlet opening and an air outlet opening, and is used to carry most of the heat generated by a heat source inside the housing away from the housing by air flowing out of the air outlet opening. The heat dissipation structure comprises: a heat conductive sheet made of the aforementioned heat dissipation compound, the heat conductive sheet having a first end and a second end, and adhered to the inner surface of the housing by the heat insulating adhesive layer, wherein the first end faces the heat source, and the second end is located near the air outlet opening; a fan module, which rotates to inhale external air through the air inlet opening and flows out from the air outlet opening, taking away part of the heat from the heat source and the heat conductive sheet; and a power module, which is electrically connected to the fan module, and is used to provide the power required for the fan module to rotate.

本新型更揭露另一種應用散熱複合物的散熱結構,安裝於具有一散熱位置的一殼體中,用以將該殼體內部一熱源發出的熱量之大部分導引至該散熱位置以向該殼體外部排出。該散熱結構包含前述散熱複合物所製成的一導熱片,該導熱片具有一第一端與一第二端,以該隔熱黏著層黏附於該殼體內部表面。該第一端緊貼該熱源,該第二端位於該散熱位置。 The present invention further discloses another heat dissipation structure using a heat dissipation compound, which is installed in a housing having a heat dissipation position, and is used to guide most of the heat generated by a heat source inside the housing to the heat dissipation position for discharge to the outside of the housing. The heat dissipation structure includes a heat conductive sheet made of the aforementioned heat dissipation compound, the heat conductive sheet having a first end and a second end, and is adhered to the inner surface of the housing by the heat insulating adhesive layer. The first end is closely attached to the heat source, and the second end is located at the heat dissipation position.

本新型的隔熱黏著層取代了傳統導熱片中的隔熱材與固定膠,讓具有隔熱及黏附功能的隔熱黏著層增加了傳統導熱片的隔熱效果,並減少其厚度,熱黏著層在散熱過程中能讓熱源減少直接向殼體傳導熱量。因此,前述問題可以獲得解決。 This new type of thermal insulation adhesive layer replaces the thermal insulation material and fixing glue in the traditional thermal conductive sheet, so that the thermal insulation adhesive layer with thermal insulation and adhesion functions increases the thermal insulation effect of the traditional thermal conductive sheet and reduces its thickness. The thermal adhesive layer can reduce the heat source from directly transferring heat to the shell during the heat dissipation process. Therefore, the above-mentioned problem can be solved.

1:散熱複合物 1: Heat dissipation compound

2:筆記型電腦 2: Laptop computer

3:熱成像儀 3: Thermal imaging device

3’:溫度測試儀 3’: Temperature tester

4:智慧型手機 4: Smartphone

10:導熱層 10: Thermal conductive layer

20:隔熱黏著層 20: Heat-insulating adhesive layer

30:丙烯酸背膠 30: Acrylic adhesive

40:主導熱層 40: Main thermal conductive layer

100:上部機殼 100: Upper casing

110:LED螢幕模組 110:LED screen module

200:下部機殼 200: Lower casing

201:進氣開孔 201: Air intake opening

202:出氣開孔 202: Air outlet opening

210:鍵盤模組 210: Keyboard module

220:電路板 220: Circuit board

221:熱源 221: Heat source

230:電池模組 230:Battery module

240:風扇模組 240: Fan module

250:導熱片 250: Heat sink

251:第一端 251: First end

252:第二端 252: Second end

300:殼體 300: Shell

310:散熱位置 310: Heat dissipation location

320:熱源 320: Heat source

330:導熱片 330: Heat sink

331:第一端 331: First end

332:第二端 332: Second end

圖1為依照本新型實施方式的一種散熱複合物的結構示意圖。 Figure 1 is a schematic diagram of the structure of a heat dissipation composite according to the present novel embodiment.

圖2繪示一個筆記型電腦的剖面結構。 Figure 2 shows the cross-sectional structure of a laptop computer.

圖3繪示散熱複合物的另一種結構。 Figure 3 shows another structure of the heat sink compound.

圖4繪示一個智慧型手機的剖面結構。 Figure 4 shows the cross-sectional structure of a smart phone.

圖5繪示第一比較例與第一到第三實施例的測試結果。 FIG5 shows the test results of the first comparative example and the first to third embodiments.

圖6繪示第二比較例與第四到第六實施例的測試結果。 FIG6 shows the test results of the second comparative example and the fourth to sixth embodiments.

本新型將藉由參照下列的實施方式而更具體地描述。 The new invention will be described in more detail by referring to the following implementation methods.

請見圖1,該圖為依照本新型實施方式的一種散熱複合物1的結構示意圖。本新型的散熱複合物1包含了兩個層狀結構:一導熱層10與一隔熱黏著層20,隔熱黏著層20形成於導熱層10的下方。要注意的是,圖1中的散熱複合物1長度與厚度未依比例繪示,實際應用上長度會較厚度來得大得多。散熱複合物1可裁剪成任何的形狀,安裝於諸如電子產品的殼體中,用來將殼體內部熱源發出的熱量的大部分於該殼體中導引流動。導熱層10使用的是通常用於電子產品內部的散熱的材料,比如但不限於石墨烯、銅箔或鋁箔。在以下的實施例中,導熱層10使用石墨烯為例來說明,其尺寸會進一步於對應的實施例中說明。導熱層10的功能是吸收熱源發出的大部分熱量,由其一端傳導到另一端。然而,導熱層10吸收熱量的一部分也會傳導到電子產品的殼體上,讓使用者感受到不適感。因此,隔熱黏著層20具有隔熱的作用,減少接收來自導熱層10的熱量。 Please see Figure 1, which is a schematic diagram of the structure of a heat dissipation composite 1 according to the implementation method of the novel. The novel heat dissipation composite 1 includes two layered structures: a thermally conductive layer 10 and a thermally insulating adhesive layer 20, and the thermally insulating adhesive layer 20 is formed below the thermally conductive layer 10. It should be noted that the length and thickness of the heat dissipation composite 1 in Figure 1 are not drawn in proportion, and the length will be much larger than the thickness in actual application. The heat dissipation composite 1 can be cut into any shape and installed in the shell of an electronic product, for example, to guide most of the heat generated by the heat source inside the shell to flow in the shell. The thermally conductive layer 10 uses a material commonly used for heat dissipation inside electronic products, such as but not limited to graphene, copper foil or aluminum foil. In the following embodiments, the heat-conducting layer 10 is illustrated using graphene as an example, and its size will be further described in the corresponding embodiments. The function of the heat-conducting layer 10 is to absorb most of the heat emitted by the heat source and conduct it from one end to the other end. However, part of the heat absorbed by the heat-conducting layer 10 will also be conducted to the housing of the electronic product, causing discomfort to the user. Therefore, the heat-insulating adhesive layer 20 has a heat-insulating effect, reducing the heat received from the heat-conducting layer 10.

依照本新型,隔熱黏著層20取代了現有隔熱材與附著膠的功能,因此能減少電子產品的殼體預留給隔熱材安裝時的空間(厚度)。隔熱黏著層20由一黏著劑與氧化鎢溶液,在常溫下均勻混合製成。黏著劑包含了均勻混合的55至58重量份的丙烯酸酯類共聚物、20至22重量份的醋酸乙酯及15至20重量份的甲苯。黏著劑與氧化鎢溶液混合時的重量比為1:0.1~1:0.3。更進一步說明,丙烯酸酯類共聚物包含了丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂。混合比例方面,丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂的重量比為10:10:5:4。丙烯酸 丁酯、丙烯酸異辛酯與醋酸乙烯形成了溶液型丙烯酸樹脂系的敏膠黏劑,為了增加黏稠度,摻加了增黏樹脂。在以下的實施例中,增黏樹脂為石油樹脂。實作上,增黏樹脂還可以是松香樹脂、萜烯樹脂、萜烯酚醛樹脂或包含石油樹脂的前述樹脂的至少二種之混合物。氧化鎢溶液中溶質為氧化鎢,溶劑可以是乙酸乙酯、乙酸丁酯或異丙醇,且溶質與溶劑的重量比例介於3:7至4:6。由於隔熱黏著層20本身是具有阻熱功能膠,因此應用上可以維持非常薄的厚度,比如介於0.1mm至0.15mm之間。 According to the present invention, the heat-insulating adhesive layer 20 replaces the functions of the existing heat-insulating material and adhesive, thereby reducing the space (thickness) reserved for the installation of the heat-insulating material in the shell of the electronic product. The heat-insulating adhesive layer 20 is made by uniformly mixing an adhesive and a tungsten oxide solution at room temperature. The adhesive includes 55 to 58 parts by weight of an acrylic copolymer, 20 to 22 parts by weight of ethyl acetate, and 15 to 20 parts by weight of toluene, which are uniformly mixed. The weight ratio of the adhesive to the tungsten oxide solution is 1:0.1 to 1:0.3. To further explain, the acrylic copolymer includes butyl acrylate, isooctyl acrylate, vinyl acetate, and a tackifying resin. In terms of mixing ratio, the weight ratio of butyl acrylate, isooctyl acrylate, vinyl acetate and tackifier resin is 10:10:5:4. Butyl acrylate, isooctyl acrylate and vinyl acetate form a solution-type acrylic resin-based sensitive adhesive, and a tackifier resin is added to increase the viscosity. In the following embodiments, the tackifier resin is a petroleum resin. In practice, the tackifier resin can also be a rosin resin, a terpene resin, a terpene phenolic resin or a mixture of at least two of the above resins including a petroleum resin. In the tungsten oxide solution, the solute is tungsten oxide, the solvent can be ethyl acetate, butyl acetate or isopropyl alcohol, and the weight ratio of the solute to the solvent is between 3:7 and 4:6. Since the heat-insulating adhesive layer 20 itself is a heat-resistant adhesive, it can maintain a very thin thickness in application, such as between 0.1mm and 0.15mm.

為了驗證本新型的散熱複合物1在阻擋熱源廢熱經由外殼發散的功效,本新型以下述的三個實施例製備不同的散熱複合物1,應用於具有熱源的測試殼體中,並與對應安裝石墨烯導熱片的第一比較例進行實機測試。 In order to verify the effectiveness of the heat dissipation compound 1 of the present invention in preventing the waste heat of the heat source from being dissipated through the outer shell, the present invention prepares different heat dissipation compounds 1 in the following three embodiments, applies them to a test shell with a heat source, and conducts actual machine tests with the first comparative example of installing a graphene thermal conductive sheet.

第一實施例 First embodiment

在本實施例中,製備尺寸為90mm*50mm*0.125mm的石墨烯導熱層10。隔熱黏著層20製備方面,先取丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與石油樹脂各20公克、20公克、10公克、與8公克,於容器中混合製成丙烯酸酯類共聚物約58公克。接著將丙烯酸酯類共聚物倒入另一容器中,以22公克的醋酸乙酯與20公克的甲苯製成的溶液裏,混合均勻,形成約100公克的黏著劑。最後將10公克的氧化鎢溶液撒向裝盛黏著劑的容器中,在常溫(25-28℃)常壓(1大氣壓)下,持續均勻地攪拌,比如15分鐘,使氧化鎢溶液與黏著劑完全混合。在第一到第三實施例中,氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯,氧化鎢與乙酸乙酯的重量比例介於3:7。將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第一散熱複合物。 In this embodiment, a graphene thermal conductive layer 10 with a size of 90mm*50mm*0.125mm is prepared. In the preparation of the thermal insulation adhesive layer 20, 20 grams, 20 grams, 10 grams, and 8 grams of butyl acrylate, isooctyl acrylate, vinyl acetate, and petroleum resin are first taken, mixed in a container to prepare about 58 grams of acrylic copolymer. Then, the acrylic copolymer is poured into another container and mixed evenly with a solution made of 22 grams of ethyl acetate and 20 grams of toluene to form about 100 grams of adhesive. Finally, 10 grams of tungsten oxide solution is sprinkled into the container containing the adhesive, and stirred continuously and evenly at room temperature (25-28°C) and normal pressure (1 atmosphere), for example, 15 minutes, to completely mix the tungsten oxide solution and the adhesive. In the first to third embodiments, the solute in the tungsten oxide solution is tungsten oxide, the solvent is ethyl acetate, and the weight ratio of tungsten oxide to ethyl acetate is between 3:7. The mixture is applied to one side of the thermal conductive layer 10, and the thickness is controlled to be between about 0.1mm and 0.15mm to form a first heat dissipation composite.

第二實施例 Second embodiment

在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第一實施例。不同點在 於本實施例將20公克的氧化鎢溶液倒向裝盛黏著劑的容器中,在常溫常壓下持續均勻地攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第二散熱複合物。 In this embodiment, the size of the graphene thermal conductive layer 10 is also 90mm*50mm*0.125mm. In terms of the preparation of the thermal insulation adhesive layer 20, the preparation method and preparation quantity of the adhesive are the same as those in the first embodiment. The difference is that in this embodiment, 20 grams of tungsten oxide solution is poured into a container containing the adhesive, and continuously and evenly stirred at room temperature and pressure to completely mix the tungsten oxide solution and the adhesive. Similarly, the mixture is applied to one side of the thermal conductive layer 10, and the thickness is controlled to be between about 0.1mm and 0.15mm to prepare a second heat dissipation composite.

第三實施例 Third embodiment

在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第一實施例。不同點在於本實施例將30公克的氧化鎢溶液倒向裝盛黏著劑的容器中,常溫常壓下持續均勻地攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第三散熱複合物。 In this embodiment, the size of the graphene thermal conductive layer 10 is also 90mm*50mm*0.125mm. In terms of the preparation of the thermal insulation adhesive layer 20, the preparation method and preparation quantity of the adhesive are the same as those in the first embodiment. The difference is that in this embodiment, 30 grams of tungsten oxide solution is poured into a container containing the adhesive, and the tungsten oxide solution and the adhesive are continuously and evenly stirred at room temperature and pressure to completely mix. Similarly, the mixture is applied to one side of the thermal conductive layer 10, and the thickness is controlled to be approximately between 0.1mm and 0.15mm to prepare a third heat dissipation composite.

第一比較例 First comparison example

在此比較例中,為了讓導熱結構上有客觀一致的結構,採用了90mm*50mm*0.125mm的石墨烯片,下方以一層常州威斯雙聯公司的背膠將石墨烯片固定在與前述實施例中的散熱複合物相同的測試位置上。要注意的是,該背膠的厚度也控制在0.1mm至0.15mm之間。 In this comparative example, in order to make the heat conduction structure objectively consistent, a 90mm*50mm*0.125mm graphene sheet was used, and a layer of backing glue from Changzhou Weiss Shuanglian Company was used to fix the graphene sheet at the same test position as the heat dissipation compound in the above-mentioned embodiment. It should be noted that the thickness of the backing glue is also controlled between 0.1mm and 0.15mm.

以下介紹散熱複合物與石墨烯膠合物測試的環境。請見圖2,該圖繪示一個筆記型電腦2的剖面結構,第一比較例與三個實施例是安裝在一個筆記型電腦2中進行測試。更精確地說,筆記型電腦2有一個上部機殼100(尺寸為320mm*220mm*2.4mm)與一個下部機殼200(尺寸為320mm*220mm*17.1mm),材質為PC(Polycarbonate,聚碳酸酯)+ABS(Acrylonitrile Butadiene Styrene,丙烯腈-丁二烯-苯乙烯共聚物)合併而成的熱可塑性塑膠;上部機殼包含了一個LCD(Liquid-Crystal Display,即液晶顯示屏)螢幕模組110,下部機殼200包含了其它重要的電子或機構模組,比如鍵盤模組210、電路板220、電池模組230、風扇模組240與導熱片250。電路板220上有許多主被動元件,其中包含了產生熱量最大宗的元件,簡稱為熱源221。主要的熱源221有CPU與GPU(Graphics Processing Unit,即圖形處理器),第一比較例與三個實施例應用在對CPU的散熱成效比較,熱源221為CPU。CPU使用的是AMD公司型號Ryzen 7040 Phoenix,熱設計功耗為30W。Ryzen 7040 Phoenix CPU是整合了GPU,與GPU的記憶體共享並集成在同一顆晶片上。因此,使用不同軟體來進行燒機測試,可以驅動CPU部分或GPU部分,使其以最大功率進行運轉,同時發出的廢熱量的速率也最高。Ryzen 7040 Phoenix CPU內部包含了6G的VRAM(Video RAM,即視訊隨機存取記憶體)。其它在電路板220上會產生熱量的主動元件如窄電壓直流IC、音源IC編解碼IC等,其耗電量相對Ryzen 7040 Phoenix CPU來得低,在比較上對第一比較例與三個實施例的影響都一樣。電池模組230在不使用外部電力下,由一個5700WH直流電鋰電池負責供電。風扇模組240為Lenovo型號X200的風扇,導熱片250則分別為石墨烯片、第一散熱複合物、第二散熱複合物與第三散熱複合物。 The following is an introduction to the test environment of the heat dissipation compound and the graphene glue compound. Please see FIG2 , which shows a cross-sectional structure of a notebook computer 2 , in which the first comparative example and the three embodiments are installed for testing. More specifically, the notebook computer 2 has an upper casing 100 (size: 320mm*220mm*2.4mm) and a lower casing 200 (size: 320mm*220mm*17.1mm), and the material is a thermoplastic plastic formed by combining PC (Polycarbonate) + ABS (Acrylonitrile Butadiene Styrene); the upper casing includes an LCD (Liquid-Crystal Display) screen module 110, and the lower casing 200 includes other important electronic or mechanical modules, such as a keyboard module 210, a circuit board 220, a battery module 230, a fan module 240 and a heat sink 250. There are many active and passive components on the circuit board 220, including the components that generate the most heat, referred to as heat sources 221. The main heat sources 221 are CPU and GPU (Graphics Processing Unit). The first comparative example and the three embodiments are applied to compare the heat dissipation effect of the CPU, and the heat source 221 is the CPU. The CPU used is AMD's model Ryzen 7040 Phoenix, with a thermal design power consumption of 30W. The Ryzen 7040 Phoenix CPU is integrated with a GPU, and the memory is shared with the GPU and integrated on the same chip. Therefore, using different software to perform a burn-in test can drive the CPU part or the GPU part to run at maximum power, and at the same time, the rate of waste heat generated is also the highest. The Ryzen 7040 Phoenix CPU contains 6G of VRAM (Video RAM, i.e. video random access memory) inside. Other active components that generate heat on the circuit board 220, such as narrow voltage DC IC, audio source IC codec IC, etc., consume less power than the Ryzen 7040 Phoenix CPU, and have the same impact on the first comparative example and the three embodiments. The battery module 230 is powered by a 5700WH DC lithium battery when no external power is used. The fan module 240 is a fan of Lenovo model X200, and the heat conducting sheet 250 is a graphene sheet, a first heat dissipation compound, a second heat dissipation compound, and a third heat dissipation compound.

測試時,熱源221的熱量是向四周環境發散。由於風扇模組240啟動帶入外部低溫空氣,所以熱量流動(以數個箭號表示)主要向下及向側面。要注意的是,下部機殼200包含了一進氣開孔201與一出氣開孔202。導熱片250具有一第一端251與一第二端252。第一端251面向熱源221,第二端252位於出氣開孔202附近。當風扇模組240轉動時,會將外部空氣經由進氣開孔201吸入並由出氣開孔202流出(氣流方向由箭號表示,底色越深者表示溫度越高),帶走熱源221及導熱片250上的部分熱量,還是有少屬熱量會直接經由傳導,從下部機殼200散佚到空氣中。 During the test, the heat of the heat source 221 is dissipated to the surrounding environment. Since the fan module 240 is activated to bring in the external low-temperature air, the heat flow (indicated by several arrows) is mainly downward and to the side. It should be noted that the lower housing 200 includes an air inlet opening 201 and an air outlet opening 202. The heat conductive sheet 250 has a first end 251 and a second end 252. The first end 251 faces the heat source 221, and the second end 252 is located near the air outlet opening 202. When the fan module 240 rotates, it draws in external air through the air inlet opening 201 and flows out through the air outlet opening 202 (the airflow direction is indicated by the arrow, the darker the background, the higher the temperature), taking away some of the heat from the heat source 221 and the heat conducting sheet 250, while a small amount of heat will be directly dissipated from the lower housing 200 into the air through conduction.

筆記型電腦2下方擺設FOTRIC型號T530的熱成像儀3,用以偵測下部機殼200下方的溫度變化。圖2中的星號是熱成像儀3偵測到筆記型電腦2下方的溫度最高點,剛好位在熱源221的中央正下方。測試時,使用YOKOGAWA型號MX100的溫度測試儀3’針對該溫度最高點進行取樣量測溫度,取樣速率為每秒 鐘偵測一次,Ryzen 7040 Phoenix CPU運行穩定度測試軟體prime95。全部測試時間為7200秒,也就是取得了7200筆的溫度記錄。 A FOTRIC model T530 thermal imager 3 is placed under the laptop 2 to detect temperature changes under the lower case 200. The asterisk in Figure 2 is the highest temperature point detected by the thermal imager 3 under the laptop 2, which is just below the center of the heat source 221. During the test, a YOKOGAWA model MX100 temperature tester 3' was used to sample and measure the temperature of the highest temperature point, with a sampling rate of once per second. The Ryzen 7040 Phoenix CPU ran the stability test software prime95. The total test time was 7200 seconds, which means that 7200 temperature records were obtained.

第一比較例與三個實施例的測試結果呈現於圖5中。由圖5可以看出,在第一比較例中,溫度偵測點的溫度在前700秒由起始溫度開始快速上升後,接著就是緩慢的提升。在超過50℃後,還未見停止跡象。在第一實施例中,溫度偵測點的溫度在上升到50℃左右時便停滯,雖然在700秒到3700秒間溫度偵測點的溫度高於第一比較例中同時的溫度,但到了3700秒後第一實施例的溫度偵測點的溫度就一直低於第一比較例的偵測數據。第二實施例的第二散熱複合物的散熱效果最好,整條溫度曲線都在所有曲線之下,也就是說以第二散熱複合物作為導熱片250的筆記型電腦2,用戶在熱源221下方感受到的溫度較其它使用散熱複合物或石墨烯片的筆記型電腦2來得低。第三實施例的第三散熱複合物的散熱效果雖然好於石墨烯片,但效果介於第一散熱複合物與第二散熱複合物之間。由此可以得知,在黏著劑中加入超過本身重量30%以上的氧化鎢溶液,除了製造成本增加,隔熱效果並未隨之增加。 The test results of the first comparative example and the three embodiments are shown in FIG5 . As can be seen from FIG5 , in the first comparative example, the temperature of the temperature detection point rises rapidly from the starting temperature in the first 700 seconds, and then rises slowly. After exceeding 50°C, there is no sign of stopping. In the first embodiment, the temperature of the temperature detection point stagnates when it rises to about 50°C. Although the temperature of the temperature detection point is higher than the temperature in the first comparative example at the same time between 700 seconds and 3700 seconds, the temperature of the temperature detection point of the first embodiment has been lower than the detection data of the first comparative example after 3700 seconds. The second heat dissipation compound of the second embodiment has the best heat dissipation effect, and the entire temperature curve is below all curves, that is, the temperature felt by the user under the heat source 221 of the notebook computer 2 using the second heat dissipation compound as the heat conductive sheet 250 is lower than that of other notebook computers 2 using heat dissipation compounds or graphene sheets. Although the heat dissipation effect of the third heat dissipation compound of the third embodiment is better than that of the graphene sheet, the effect is between the first heat dissipation compound and the second heat dissipation compound. It can be seen from this that adding more than 30% of the weight of tungsten oxide solution to the adhesive will not only increase the manufacturing cost, but also the heat insulation effect will not increase.

前述的第一比較例與三個實施例是在使用丙烯酸酯類共聚物、醋酸乙酯與甲苯在58:22:20重量比下製得的黏著劑進行的。接著以一第二比較例、一第四實施例、一第五實施例與一第六實施例,說明在不同成分比例下的黏著劑對測試結果的影響。 The first comparative example and the three examples mentioned above were conducted using an adhesive made of acrylic copolymer, ethyl acetate and toluene at a weight ratio of 58:22:20. Next, a second comparative example, a fourth example, a fifth example and a sixth example are used to illustrate the effect of adhesives at different component ratios on the test results.

第四實施例 Fourth embodiment

在本實施例中,製備尺寸為90mm*50mm*0.125mm的石墨烯導熱層10。隔熱黏著層20製備方面,先取丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與石油樹脂依照10:10:5:4的重量比,於容器中混合製成丙烯酸酯類共聚物約55公克。接著將丙烯酸酯類共聚物倒入另一容器中,以20公克的醋酸乙酯與15公克的甲苯製成的溶液裏,混合均勻,形成約90公克的黏著劑。最後將9公克的氧化鎢溶液倒向 裝盛黏著劑的容器中,在常溫(25-28℃)常壓(1大氣壓)下持續均勻攪拌,比如15分鐘,使氧化鎢溶液與黏著劑完全混合。在第四到第六實施例中,氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯,氧化鎢與乙酸乙酯的重量比例介於4:6。將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第四散熱複合物。 In this embodiment, a graphene thermal conductive layer 10 with a size of 90mm*50mm*0.125mm is prepared. In terms of the preparation of the thermal insulation adhesive layer 20, butyl acrylate, isooctyl acrylate, vinyl acetate and petroleum resin are first mixed in a container according to a weight ratio of 10:10:5:4 to prepare about 55 grams of acrylic copolymer. Then the acrylic copolymer is poured into another container and mixed evenly with a solution made of 20 grams of ethyl acetate and 15 grams of toluene to form about 90 grams of adhesive. Finally, 9 grams of tungsten oxide solution is poured into the container containing the adhesive and stirred evenly at room temperature (25-28°C) and normal pressure (1 atmosphere) for, for example, 15 minutes to completely mix the tungsten oxide solution and the adhesive. In the fourth to sixth embodiments, the solute in the tungsten oxide solution is tungsten oxide, the solvent is ethyl acetate, and the weight ratio of tungsten oxide to ethyl acetate is between 4:6. The mixture is applied to one side of the thermal conductive layer 10, and the thickness is controlled to be between about 0.1mm and 0.15mm to produce a fourth heat dissipation composite.

第五實施例 Fifth embodiment

在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第四實施例。不同點在於本實施例將18公克的氧化鎢溶液倒向裝盛黏著劑的容器中,在常溫常壓下,持續均勻攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第五散熱複合物。 In this embodiment, the size of the graphene thermal conductive layer 10 is also 90mm*50mm*0.125mm. In terms of the preparation of the thermal insulation adhesive layer 20, the preparation method and preparation quantity of the adhesive are the same as those of the fourth embodiment. The difference is that in this embodiment, 18 grams of tungsten oxide solution is poured into a container containing the adhesive, and the tungsten oxide solution and the adhesive are continuously and evenly stirred at room temperature and pressure to completely mix. Similarly, the mixture is applied to one side of the thermal conductive layer 10, and the thickness is controlled to be approximately between 0.1mm and 0.15mm to prepare a fifth heat dissipation composite.

第六實施例 Sixth embodiment

在本實施例中,石墨烯導熱層10的尺寸同樣為90mm*50mm*0.125mm。隔熱黏著層20製備方面,黏著劑的製作方法與製作數量同第四實施例。不同點在於本實施例將27公克的氧化鎢溶液倒向裝盛黏著劑的容器中,在常溫常壓下,持續均勻攪拌,使氧化鎢溶液與黏著劑完全混合。相同地,將混合物塗抹在導熱層10的一面,控制厚度約在0.1mm至0.15mm之間,製成一第六散熱複合物。 In this embodiment, the size of the graphene thermal conductive layer 10 is also 90mm*50mm*0.125mm. In terms of the preparation of the thermal insulation adhesive layer 20, the preparation method and preparation quantity of the adhesive are the same as those of the fourth embodiment. The difference is that in this embodiment, 27 grams of tungsten oxide solution is poured into a container containing the adhesive, and the tungsten oxide solution and the adhesive are continuously and evenly stirred at room temperature and pressure to completely mix. Similarly, the mixture is applied to one side of the thermal conductive layer 10, and the thickness is controlled to be between about 0.1mm and 0.15mm to prepare a sixth heat dissipation composite.

第二比較例 Second comparison example

在此比較例中,為了讓導熱結構上有客觀一致的結構,採用了和第一比較例中相同規格的90mm*50mm*0.125mm的石墨烯片,其下方也以一層常州威斯雙聯的背膠將石墨烯片固定在與前述實施例中的散熱複合物相同的測試位置上。該背膠的厚度控制在0.1mm至0.15mm之間。 In this comparative example, in order to make the heat conduction structure objectively consistent, a graphene sheet of the same specifications as in the first comparative example was used, with a layer of Changzhou Weiss double-linked backing adhesive underneath to fix the graphene sheet at the same test position as the heat dissipation compound in the aforementioned embodiment. The thickness of the backing adhesive is controlled between 0.1mm and 0.15mm.

測試環境方面,第二比較例及第四到第六實施例使用了如前述的筆記型電腦2,佈設方式如圖2及相關文字所述。測試時,使用YOKOGAWA型號 MX100的溫度測試儀3’針對該溫度最高點進行取樣量測溫度,取樣速率為每秒鐘偵測一次,Ryzen 7040 Phoenix CPU運行穩定度測試軟體FurMark+TCT(AMD平台使用之測試軟體),用於測試Ryzen 7040 Phoenix CPU中的GPU效能。全部測試時間為7200秒,因此也取得了7200筆的溫度記錄。 In terms of the test environment, the second comparative example and the fourth to sixth embodiments used the aforementioned laptop 2, and the layout was as described in Figure 2 and the related text. During the test, a temperature tester 3' of YOKOGAWA model MX100 was used to sample and measure the temperature at the highest temperature point, with a sampling rate of once per second. The Ryzen 7040 Phoenix CPU ran the stability test software FurMark+TCT (test software used by the AMD platform) to test the GPU performance in the Ryzen 7040 Phoenix CPU. The total test time was 7200 seconds, so 7200 temperature records were obtained.

第二比較例與第四到第六實施例的測試結果呈現於圖6中。由圖6可以看出,在第二比較例中,溫度偵測點的溫度在前500秒由起始溫度開始快速上升後,接著就是緩慢的提升。在超過58℃後,還未見停止跡象。在第四實施例中,溫度偵測點的溫度在上升到50℃左右時便停滯,雖然在300秒到3000秒間溫度偵測點的溫度高於第二比較例中同時的溫度,但到了3000秒後第四實施例的溫度偵測點的溫度就一直低於第二比較例的偵測數據,最高溫度約在54℃左右。第五實施例的第五散熱複合物的散熱效果最好,整條溫度曲線都在所有曲線之下。第六實施例的第六散熱複合物的散熱效果雖然好於石墨烯片,但效果介於第四散熱複合物與第五散熱複合物之間。由此可以得知,在此款黏著劑中加入超過本身重量30%以上的氧化鎢溶液,除了製造成本增加,散熱效果並未隨之增加。 The test results of the second comparative example and the fourth to sixth embodiments are shown in FIG6 . As can be seen from FIG6 , in the second comparative example, the temperature of the temperature detection point rises rapidly from the starting temperature in the first 500 seconds, and then rises slowly. After exceeding 58°C, there is no sign of stopping. In the fourth embodiment, the temperature of the temperature detection point stagnates when it rises to about 50°C. Although the temperature of the temperature detection point is higher than the temperature in the second comparative example at the same time between 300 seconds and 3000 seconds, the temperature of the temperature detection point of the fourth embodiment is always lower than the detection data of the second comparative example after 3000 seconds, and the highest temperature is about 54°C. The fifth heat dissipation composite of the fifth embodiment has the best heat dissipation effect, and the entire temperature curve is below all curves. Although the heat dissipation effect of the sixth heat dissipation compound of the sixth embodiment is better than that of the graphene sheet, the effect is between the fourth heat dissipation compound and the fifth heat dissipation compound. It can be seen that adding more than 30% of the weight of tungsten oxide solution to this adhesive will increase the manufacturing cost but not the heat dissipation effect.

依照本新型,散熱複合物1還可以有其它的結構。請見圖3,該圖繪示散熱複合物1的另一種結構。散熱複合物1在導熱層10異於隔熱黏著層20的那一面進一步塗佈一層丙烯酸背膠30,用黏接一主導熱層40。主導熱層40的材料也可以是石墨烯、銅箔或鋁箔或其它散熱材料中的一種,形狀可以和導熱層10的相同或相異。若兩者形狀相同,可以增加散熱複合物1的導熱效能。如果主導熱層40與導熱層10的形狀不同,可以局部強化導熱效能,或是將廢熱導向不同的出氣開孔。 According to the present invention, the heat dissipation compound 1 can also have other structures. See Figure 3, which shows another structure of the heat dissipation compound 1. The heat dissipation compound 1 is further coated with a layer of acrylic backing 30 on the side of the heat conductive layer 10 that is different from the heat insulating adhesive layer 20, and is bonded to a main heat conductive layer 40. The material of the main heat conductive layer 40 can also be one of graphene, copper foil or aluminum foil or other heat dissipation materials, and the shape can be the same as or different from that of the heat conductive layer 10. If the shapes of the two are the same, the heat conduction performance of the heat dissipation compound 1 can be increased. If the shapes of the main heat conductive layer 40 and the heat conductive layer 10 are different, the heat conduction performance can be locally enhanced, or the waste heat can be directed to different air outlet openings.

如用於測試前述實施例之散熱複合物效能的筆記型電腦2,是本新型應用的一個最佳實例,在其中形成了一種應用散熱複合物的散熱結構。廣義的來說,應用散熱複合物的散熱結構安裝於具有如圖2所示的進氣開孔201與出氣開 孔202的一殼體(下部機殼200)中,用以將該殼體內部一熱源221發出的熱量之大部分由流出出氣開孔202的空氣帶離該殼體。應用散熱複合物的散熱結構包含了以上述散熱複合物1製成的導熱片250、風扇模組240與電源模組。導熱片250具有第一端251與第二端252,以隔熱黏著層20黏附於該殼體內部表面。第一端251面向熱源221,第二端252位於出氣開孔202附近。風扇模組240轉動以將外部空氣經由進氣開孔201吸入並由出氣開孔202流出,帶走熱源221及導熱片250上的部分熱量。電源模組可以是圖2中的電池模組230,也可以是筆記型電腦2或是其它電子產品中的變壓器,可將市電的交流電轉換為工作直流電。電源模組與風扇模組240電連接,用以提供風扇模組240轉動時所需的電力。 The notebook computer 2 used to test the performance of the heat dissipation compound of the above-mentioned embodiment is a best example of the application of the present invention, in which a heat dissipation structure using the heat dissipation compound is formed. Generally speaking, the heat dissipation structure using the heat dissipation compound is installed in a housing (lower housing 200) having an air inlet opening 201 and an air outlet opening 202 as shown in FIG. 2, so as to carry most of the heat generated by a heat source 221 inside the housing away from the housing by air flowing out of the air outlet opening 202. The heat dissipation structure using the heat dissipation compound includes a heat conductive sheet 250 made of the above-mentioned heat dissipation compound 1, a fan module 240 and a power module. The heat conductive sheet 250 has a first end 251 and a second end 252, and is adhered to the inner surface of the housing by a heat insulating adhesive layer 20. The first end 251 faces the heat source 221, and the second end 252 is located near the air outlet opening 202. The fan module 240 rotates to inhale the external air through the air inlet opening 201 and out of the air outlet opening 202, taking away part of the heat from the heat source 221 and the heat conductive sheet 250. The power module can be the battery module 230 in FIG. 2, or it can be a transformer in a notebook computer 2 or other electronic products, which can convert the AC power of the mains into working DC power. The power module is electrically connected to the fan module 240 to provide the power required for the fan module 240 to rotate.

在前述的應用實例中,導熱片可配合風扇模組來進行導熱與散熱工作。在實作中,以本新型散熱複合物1所製成的導熱片也可應用於沒有風扇模組與內部空氣流動的電子裝置中,單純依靠傳導作用將熱源產生的熱量導引到適當的殼體位置後,排向外部空間且可降低機殼表面溫度。最好的應用例子就是智慧型手機或平板。 In the aforementioned application examples, the heat conducting sheet can be used in conjunction with the fan module to conduct and dissipate heat. In practice, the heat conducting sheet made of the novel heat dissipating compound 1 can also be used in electronic devices without fan modules and internal air flow. It can simply rely on conduction to guide the heat generated by the heat source to the appropriate position of the casing, and then discharge it to the external space and reduce the surface temperature of the casing. The best application example is a smart phone or tablet.

請見圖4,該圖繪示一個智慧型手機4的剖面結構。一種應用散熱複合物的散熱結構可安裝於具有一散熱位置310的智慧型手機4的一殼體300中,用以將殼體300內部一熱源320(如處理器)發出的熱量之大部分導引至該散熱位置310以向殼體300外部排出。實作上,散熱位置310可以是智慧型手機4的殼體300側方的喇叭孔,藉由散熱位置310附近流動的空氣將傳導的熱量帶走。該應用散熱複合物的散熱結構主要是以前述散熱複合物所製成的一導熱片330。導熱片330具有一第一端331與一第二端332,以隔熱黏著層黏附於殼體300的內部表面。安裝上,第一端331緊貼熱源320,第二端332位於散熱位置310附近。 Please see FIG. 4, which shows a cross-sectional structure of a smart phone 4. A heat dissipation structure using a heat dissipation compound can be installed in a housing 300 of a smart phone 4 having a heat dissipation position 310, so as to guide most of the heat generated by a heat source 320 (such as a processor) inside the housing 300 to the heat dissipation position 310 for discharge to the outside of the housing 300. In practice, the heat dissipation position 310 can be a speaker hole on the side of the housing 300 of the smart phone 4, and the air flowing near the heat dissipation position 310 takes away the conducted heat. The heat dissipation structure using the heat dissipation compound is mainly a heat conductive sheet 330 made of the aforementioned heat dissipation compound. The heat conductive sheet 330 has a first end 331 and a second end 332, and is adhered to the inner surface of the housing 300 by a heat insulating adhesive layer. During installation, the first end 331 is close to the heat source 320, and the second end 332 is located near the heat dissipation position 310.

雖然本新型已以實施方式揭露如上,然其並非用以限定本新型,任何所屬技術領域中具有通常知識者,在不脫離本新型之精神和範圍內,當可作些許之更動與潤飾,因此本新型之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed in the form of implementation as above, it is not intended to limit the present invention. Anyone with common knowledge in the relevant technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the scope of the patent application attached hereto.

1:散熱複合物 1: Heat dissipation compound

10:導熱層 10: Thermal conductive layer

20:隔熱黏著層 20: Heat-insulating adhesive layer

Claims (10)

一種散熱複合物,包含:一導熱層;以及一隔熱黏著層,形成於該導熱層下方,由一黏著劑與氧化鎢溶液均勻混合製成,其中,該黏著劑包含均勻混合的55至58重量份的丙烯酸酯類共聚物、20至22重量份的醋酸乙酯及15至20重量份的甲苯,該黏著劑與氧化鎢溶液混合時的重量比為1:0.1~1:0.3。 A heat dissipation composite comprises: a heat conductive layer; and a heat insulating adhesive layer formed below the heat conductive layer, which is made by uniformly mixing an adhesive and a tungsten oxide solution, wherein the adhesive comprises 55 to 58 parts by weight of an acrylic copolymer, 20 to 22 parts by weight of ethyl acetate and 15 to 20 parts by weight of toluene uniformly mixed, and the weight ratio of the adhesive to the tungsten oxide solution when mixed is 1:0.1~1:0.3. 如請求項1所述的散熱複合物,其中該導熱層的材質為石墨烯、銅箔或鋁箔。 The heat dissipation composite as described in claim 1, wherein the material of the heat conductive layer is graphene, copper foil or aluminum foil. 如請求項1所述的散熱複合物,其中該隔熱黏著層的厚度介於0.1mm至0.15mm之間。 The heat dissipation composite as described in claim 1, wherein the thickness of the thermal insulation adhesive layer is between 0.1 mm and 0.15 mm. 如請求項1所述的散熱複合物,其中丙烯酸酯類共聚物包含丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂。 The heat dissipation composite as described in claim 1, wherein the acrylic copolymer comprises butyl acrylate, isooctyl acrylate, vinyl acetate and a tackifying resin. 如請求項4所述的散熱複合物,其中丙烯酸丁酯、丙烯酸異辛酯、醋酸乙烯與增黏樹脂的重量比為10:10:5:4。 The heat dissipation composite as described in claim 4, wherein the weight ratio of butyl acrylate, isooctyl acrylate, vinyl acetate and tackifying resin is 10:10:5:4. 如請求項4所述的散熱複合物,其中增黏樹脂為石油樹脂、松香樹脂、萜烯樹脂、萜烯酚醛樹脂或前述樹脂的至少二種之混合物。 The heat dissipation composite as described in claim 4, wherein the tackifying resin is a petroleum resin, a rosin resin, a terpene resin, a terpene phenolic resin or a mixture of at least two of the aforementioned resins. 如請求項1所述的散熱複合物,其中該氧化鎢溶液中溶質為氧化鎢,溶劑為乙酸乙酯、乙酸丁酯或異丙醇。 The heat dissipation composite as described in claim 1, wherein the solute in the tungsten oxide solution is tungsten oxide, and the solvent is ethyl acetate, butyl acetate or isopropyl alcohol. 如請求項1所述的散熱複合物,其中該氧化鎢溶液中溶質與溶劑的重量比例介於3:7至4:6。 The heat dissipation composite as described in claim 1, wherein the weight ratio of the solute to the solvent in the tungsten oxide solution is between 3:7 and 4:6. 一種應用散熱複合物的散熱結構,安裝於具有一進氣開孔與一出氣開孔的一殼體中,用以將該殼體內部一熱源發出的熱量之大部分由流出該出氣開孔的空氣帶離該殼體,包含:以請求項1至8中任一項的散熱複合物所製成的一導熱片,該導熱片具有一第一端與一第二端,以該隔熱黏著層黏附於該殼體內部表面,其中該第一端面向該熱源,該第二端位於該出氣開孔附近;一風扇模組,設置於該殼體內部接近該進氣開孔處,轉動以將外部空氣經由該進氣開孔吸入並由該出氣開孔流出,帶走該熱源及該導熱片上的部分熱量;以及一電源模組,設置於該殼體內部接近該出氣開孔處,與該風扇模組電連接,用以提供該風扇模組轉動時所需的電力。 A heat dissipation structure using a heat dissipation compound is installed in a shell having an air inlet opening and an air outlet opening, and is used to carry most of the heat generated by a heat source inside the shell away from the shell by air flowing out of the air outlet opening, comprising: a heat conductive sheet made of the heat dissipation compound of any one of claims 1 to 8, the heat conductive sheet having a first end and a second end, and adhered to the inner surface of the shell by the heat insulating adhesive layer, wherein the first The first end faces the heat source, and the second end is located near the air outlet opening; a fan module is arranged inside the housing near the air inlet opening, and rotates to inhale external air through the air inlet opening and flow out from the air outlet opening, taking away part of the heat from the heat source and the heat conductive sheet; and a power module is arranged inside the housing near the air outlet opening, and is electrically connected to the fan module to provide the power required for the fan module to rotate. 一種應用散熱複合物的散熱結構,安裝於具有一散熱位置的一殼體中,用以將該殼體內部一熱源發出的熱量之大部分導引至該散熱位置以向該殼體外部排出,其特徵在於:包含以請求項1至8中任一項的散熱複合物所製成的一導熱片,該導熱片具有一第一端與一第二端,以該隔熱黏著層黏附於該殼體內部表面,其中該第一端緊貼該熱源,該第二端位於該散熱位置附近。 A heat dissipation structure using a heat dissipation compound is installed in a housing having a heat dissipation position, and is used to guide most of the heat generated by a heat source inside the housing to the heat dissipation position for discharge to the outside of the housing. It is characterized in that it comprises a heat conductive sheet made of the heat dissipation compound of any one of claims 1 to 8, the heat conductive sheet has a first end and a second end, and is adhered to the inner surface of the housing by the heat insulating adhesive layer, wherein the first end is closely attached to the heat source, and the second end is located near the heat dissipation position.
TW112213613U 2023-12-13 Heat dissipation compound and heat dissipation structure using the same TWM656529U (en)

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