TWI745483B - Divided sputtering target - Google Patents
Divided sputtering target Download PDFInfo
- Publication number
- TWI745483B TWI745483B TW106138959A TW106138959A TWI745483B TW I745483 B TWI745483 B TW I745483B TW 106138959 A TW106138959 A TW 106138959A TW 106138959 A TW106138959 A TW 106138959A TW I745483 B TWI745483 B TW I745483B
- Authority
- TW
- Taiwan
- Prior art keywords
- target
- flat
- divided
- distance
- sputtering target
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/34—Gas-filled discharge tubes operating with cathodic sputtering
- H01J37/3411—Constructional aspects of the reactor
- H01J37/3414—Targets
- H01J37/3423—Shape
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Analytical Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
本揭示之實施形態係關於一種分割濺鍍靶。 The embodiment of the present disclosure relates to a split sputtering target.
以往,已知有一種利用接合材來將排列成平面狀之複數個靶材接合於基材而形成的分割濺鍍靶(參照例如專利文獻1)。 Conventionally, there has been known a split sputtering target formed by bonding a plurality of target materials arranged in a plane to a base material using a bonding material (see, for example, Patent Document 1).
專利文獻1:日本特開2004-315931號公報 Patent Document 1: Japanese Patent Application Publication No. 2004-315931
然而,在習知之分割濺鍍靶中,在藉由以隔著間隔之方式配置複數個靶材而形成的分割部中,接合材容易附著在靶材的側面。於是,當該接合材附著於靶材的側面時,會有於進行濺鍍成膜之際造成金屬微粒子(particle)產生的情形。 However, in the conventional split sputtering target, the bonding material easily adheres to the side surface of the target in the split portion formed by arranging a plurality of targets at intervals. Therefore, when the bonding material adheres to the side surface of the target material, metal particles may be generated during sputtering film formation.
另一方面,在分割部中相對向之靶材的側面彼此的間隔狹窄,而且靶材之側面又是從基材垂直地立 起,因此難以從上方辨識該側面。因此,難以確認接合材對於靶材之側面的附著狀態。再者,由於牢固地附著於靶材之側面的接合材並無法容易地去除,因此會有起因於附著在側面之接合材而在成膜時產生金屬微粒子的疑虞。 On the other hand, the space between the side surfaces of the opposing targets in the divided portion is narrow, and the side surfaces of the target materials stand perpendicularly from the base material. Therefore, it is difficult to recognize the side surfaces from above. Therefore, it is difficult to confirm the adhesion state of the bonding material to the side surface of the target material. Furthermore, since the bonding material firmly attached to the side surface of the target cannot be easily removed, there is a possibility that metal particles may be generated during film formation due to the bonding material attached to the side surface.
實施形態之一態樣係鑑於上述課題而研創者,其目的在於提供一種分割濺鍍靶,該分割濺鍍靶係可容易地確認接合材對於在分割部中相對向之靶材之側面的附著狀態,且可容易地去除附著於在分割部中相對向之靶材之側面的接合材。 One aspect of the embodiment was developed in view of the above-mentioned problems, and its purpose is to provide a split sputtering target that can easily confirm the adhesion of the bonding material to the side surface of the target facing the split part. The state, and the bonding material adhering to the side surface of the target material facing the divided part can be easily removed.
實施形態之一態樣的分割濺鍍靶係將複數個靶材接合於基材而形成者,在該分割濺鍍靶中:藉由以隔著間隔之方式配置複數個靶材而形成的分割部當中,在至少一部分的前述分割部所配置的一對前述靶材的側面的至少一部分係分別形成有平坦面,且關於在前述分割部中相對向之前述平坦面彼此的間隔,距離前述基材最遠之部分的間隔係比距離前述基材最近之部分的間隔大,而前述平坦面之表面粗糙度Ra係0.3μm以下。 The divided sputtering target of one aspect of the embodiment is formed by joining a plurality of targets to a base material. In the divided sputtering target: a divided sputtering target formed by arranging a plurality of targets at intervals In the section, at least a portion of the side surfaces of the pair of the target materials arranged in at least a portion of the divided section are respectively formed with flat surfaces, and the distance between the flat surfaces facing each other in the divided section is a distance from the base. The distance between the farthest part of the material is larger than the distance between the part closest to the substrate, and the surface roughness Ra of the flat surface is 0.3 μm or less.
依據實施形態之一態樣,可提供一種分割濺鍍靶,該分割濺鍍靶係可容易地確認接合材對於在分割部中相對向之靶材之側面的附著狀態,並且可容易地去除附著於在分割部中相對向之靶材之側面的接合材。 According to one aspect of the embodiment, it is possible to provide a split sputtering target which can easily confirm the adhesion state of the bonding material to the side surface of the target facing the split part, and can easily remove the adhesion The bonding material on the side surface of the target material facing each other in the divided part.
1‧‧‧分割濺鍍靶 1‧‧‧Split Sputtering Target
10‧‧‧靶材 10‧‧‧Target
11‧‧‧側面 11‧‧‧Side
12‧‧‧平坦面 12‧‧‧Flat surface
12a‧‧‧上端部 12a‧‧‧upper end
12b‧‧‧下端部 12b‧‧‧Lower end
13‧‧‧接合面 13‧‧‧Joint surface
14‧‧‧垂直面 14‧‧‧Vertical plane
15‧‧‧濺鍍面 15‧‧‧Sputtering surface
16‧‧‧倒角部 16‧‧‧Chamfer
20‧‧‧基材 20‧‧‧Substrate
30‧‧‧接合材 30‧‧‧Joint material
40‧‧‧分割部 40‧‧‧Splitting Department
θ‧‧‧角度 θ‧‧‧angle
Lt、Lb‧‧‧間隔 Lt、Lb‧‧‧Interval
Ta‧‧‧厚度 Ta‧‧‧Thickness
Tp‧‧‧高度 Tp‧‧‧Height
第1圖係實施形態之分割濺鍍靶的立體圖。 Fig. 1 is a perspective view of the divided sputtering target of the embodiment.
第2圖係沿著第1圖所示之箭頭A-A線的剖面圖。 Figure 2 is a cross-sectional view taken along the arrow A-A line shown in Figure 1.
第3圖係實施形態之變形例1的分割部之剖面形狀的放大剖面圖。 Fig. 3 is an enlarged cross-sectional view of the cross-sectional shape of the divided portion of Modification 1 of the embodiment.
第4圖係實施形態之變形例2的分割部之剖面形狀的放大剖面圖。 Fig. 4 is an enlarged cross-sectional view of the cross-sectional shape of the divided portion of Modification 2 of the embodiment.
第5圖係實施形態之變形例3的分割部之剖面形狀的放大剖面圖。 Fig. 5 is an enlarged cross-sectional view of the cross-sectional shape of the division part of Modification 3 of the embodiment.
以下,參照檢附圖式針對本案揭示之分割濺鍍靶的實施形態加以說明。此外,圖式之各要素的尺寸的關係、各要素的比率等會有與現實不同的情形。此外,在圖式之彼此間,會有包含彼此之尺寸的關係或比率不同之部分。 Hereinafter, the embodiment of the split sputtering target disclosed in this case will be described with reference to the drawing style. In addition, the relationship between the dimensions of the elements of the drawing, the ratio of the elements, etc. may be different from reality. In addition, among the drawings, there will be parts that include the relationship or ratio of each other's dimensions.
首先,參照第1圖說明實施形態之分割濺鍍靶1之概略。第1圖係實施形態之分割濺鍍靶1的立體圖。 First, the outline of the divided sputtering target 1 of the embodiment will be described with reference to FIG. 1. FIG. Fig. 1 is a perspective view of the divided sputtering target 1 of the embodiment.
分割濺鍍靶1係具有複數個靶材10、基材20、及接合材30。並且,在基材20上排列配置有複數個靶材10,且以接合材30將該等靶材10與基材20予以接合,而形成分割濺鍍靶1。 The split sputtering target 1 has a plurality of
複數個靶材10係例如分別形成為大致相同 尺寸之平板狀。靶材10係例如形成為俯視矩形狀,且以隔著預定間隔之方式排列配置在基材20上。 The plurality of
例如,在第1圖中,以矩陣狀排列配置有六片靶材10。此外,複數個靶材10並不需要配置成矩陣狀,例如亦可排列配置成一行。 For example, in Figure 1, six
靶材10的材質係例如ITO(Indium Tin Oxide,氧化銦錫)。另一方面,靶材10的材質並不限定於ITO,可使用IGZO(Indium Gallium Zinc Oxide,氧化銦鎵鋅)或AZO(Aluminum Zinc Oxide,氧化鋁鋅)等。 The material of the
基材20係具有對應於期望之分割濺鍍靶1之尺寸的形狀。基材20的材質係例如導電性或熱傳導性佳的銅、或磷酸銅、鈦、鋁、不鏽鋼等。 The
接合材30係將靶材10與基材20予以接合。接合材30係可採用例如以銦或錫等為主成分的銲材。例如,對靶材10採用ITO時,接合材30係可使用銦。 The joining
在此,如第1圖所示,在分割濺鍍靶1中,靶材10彼此係以隔著一定間隔之方式配置,藉此在鄰接的一對靶材10之間形成有分割部40。接著,針對該分割部40之詳細構成,參照第2圖加以說明。 Here, as shown in FIG. 1, in the split sputtering target 1, the
第2圖係沿著第1圖所示之箭頭A-A線的剖面圖,針對分割部40及其附近予以放大的放大剖面圖。如第2圖所示,在分割部40中,鄰接之一對靶材10的側面11彼此係相對向。 Fig. 2 is a cross-sectional view taken along the arrow A-A line shown in Fig. 1, and is an enlarged cross-sectional view of the divided
在此,在實施形態中,於該對向之兩方的 側面11的至少一部分,分別形成有平坦面12。在第2圖中,在相對向之側面11的整體,分別形成有平坦面12。 Here, in the embodiment,
並且,關於在分割部40中相對向之平坦面12彼此的間隔,距離基材20最遠之部分的間隔Lt係比距離基材20最近之部分的間隔Lb大。其中,間隔Lt係在平坦面12中距離基材20最遠之上端部12a彼此的距離,而間隔Lb係在平坦面12中距離基材20最近之下端部12b彼此的距離。換言之,在分割部40中,由平坦面12彼此所形成的間隙,係朝上方開放成末端較寬狀。 In addition, with regard to the interval between the
藉此,在從上方辨識之際,可容易地進行側面11(平坦面12)的辨識。因此,依據實施形態,可容易地確認接合材30對於在分割部40相對向之靶材10之側面11的附著狀態。 Thereby, when recognizing from above, the recognition of the side surface 11 (flat surface 12) can be easily performed. Therefore, according to the embodiment, the adhesion state of the
在實施形態中,平坦面12之表面粗糙度Ra為0.3μm以下。其中,該表面粗糙度係算術平均粗糙度Ra,以下之記載亦同。如此,藉由將平坦面12加工成表面粗糙度Ra為0.3μm以下,從而可容易地將附著在平坦面12之接合材30予以去除。 In the embodiment, the surface roughness Ra of the
這是由於藉由將平坦面12之表面粗糙度Ra設為0.3μm以下,可減低在平坦面12表面之投錨效果(錨固效果),而可減低接合材30對於平坦面12之附著力之故。 This is because by setting the surface roughness Ra of the
亦即,在實施形態中,藉由使距離基材20最遠之部分的間隔Lt比距離基材20最近之部分的間隔Lb大,並且將平坦面12之表面粗糙度Ra設為0.3μm以下, 而可容易地確認接合材30對於在分割部40中相對向之靶材10之側面11的附著狀態,且可容易地去除附著於在分割部40中相對向之靶材10之側面11的接合材30。因此,若利用實施形態之分割濺鍍靶1,即可長時間穩定地實施濺鍍成膜。 That is, in the embodiment, by making the interval Lt of the part farthest from the
此外,在分割部40中,距離基材20最遠之部分的間隔Lt、與距離基材20最近之部分的間隔Lb之差較佳為0.1mm以上。藉此,由平坦面12彼此所形成的間隙係形成為朝上方末端變寬狀,故而可更容易地確認接合材30對於在分割部40中相對向之靶材10之側面11的附著狀態。 In addition, in the divided
此外,距離基材20最遠之部分的間隔Lt、與距離基材20最近之部分的間隔Lb之差係較佳為0.2mm以上,更佳為0.3mm以上。 In addition, the difference between the interval Lt of the part farthest from the
再者,在分割部40中,距離基材20最遠之部分的間隔Lt係可為0.2mm以上0.7mm以下,以0.3mm以上0.6mm以下為更佳。此外,距離基材20最近之部分的間隔Lb係可為0.1mm以上0.5mm以下,以0.1mm以上0.3mm以下為更佳。 Furthermore, in the divided
藉由將間隔Lt及間隔Lb設定為上述之間隔,確保由上方辨識側面11(平坦面12)的辨識性,並且減低由分割部40朝上方露出之接合材30的面積。因此,依據實施形態,在將分割濺鍍靶1予以濺鍍成膜之際,可抑制由分割部40所露出之接合材30成為雜質的情形。 By setting the interval Lt and the interval Lb to the above-mentioned intervals, the visibility of the side surface 11 (flat surface 12) visible from above is ensured, and the area of the
再者,在實施形態中,藉由將平坦面12加工成表面粗糙度Ra為0.3μm以下,由於如上所述可減低在平坦面12之投錨效果,因此可抑制接合材30附著於平坦面12之情形。 Furthermore, in the embodiment, by processing the
藉此,可抑制在進行濺鍍成膜之際起因於附著於側面11(平坦面12)之接合材30之金屬微粒子的產生。因此,依據實施形態,可穩定地實施由分割濺鍍靶1所進行之濺鍍成膜。 Thereby, it is possible to suppress the generation of metal fine particles caused by the
此外,平坦面12的表面粗糙度Ra係以0.1μm以下為佳,以0.001μm以上0.05μm以下為更佳。如此,藉由將平坦面12的表面粗糙度Ra設為更小,即可更加抑制接合材30附著於平坦面12之情形。再者,藉由將表面粗糙度Ra設定為0.001μm以上,即可抑制加工成本之上升,因此可抑制分割濺鍍靶1之製造成本的上升。 In addition, the surface roughness Ra of the
再者,在實施形態中,如第2圖所示,在剖面觀看側面11時,平坦面12、與接合於基材20之靶材10的接合面13所成之角度θ係可小於90°。亦即,可使相對向之兩方的平坦面12分別朝可從上方辨識之方向傾斜。 Furthermore, in the embodiment, as shown in FIG. 2, when the
藉此,可將形成於平坦面12之上端部12a的角部設為鈍角。因此,依據實施形態,由於可使形成於上端部12a之角部不容易破裂,因此可使分割濺鍍靶1之可靠性提升。 Thereby, the corner part formed in the
再者,藉由將形成於平坦面12之上端部12a的角部設為鈍角,從而在進行濺鍍成膜之際,可抑制從該 角部產生之電弧現象。這是由於該電弧現象雖會在進行濺鍍成膜之際因電荷集中在靶材10之角部而產生,但藉由將該角部設為鈍角,即可抑制電荷之集中。因此,依據實施形態,可穩定地實施由分割濺鍍靶1所進行之濺鍍成膜。 Furthermore, by making the corners formed on the
此外,在相對向之兩方的平坦面12中,一方之平坦面12的角度θ、與另一方之平坦面12的角度θ係可為相同角度,亦可為不同角度。 In addition, among the two facing
再者,並不一定需使相對向之兩方的平坦面12皆傾斜。例如,如第3圖所示,亦可形成為僅使一方(第3圖中之左側)的平坦面12傾斜,並且使另一方(第3圖中之右側)的平坦面12從接合面13大致垂直地立起。第3圖係顯示實施形態之變形例1之分割部40的剖面形狀的放大剖面圖。 Furthermore, it is not necessary to incline the two
即便如依第3圖所示之剖面形狀來構成分割部40時,由平坦面12彼此所形成的間隙亦朝斜上方形成末端變寬狀,因此與實施形態同樣地,可使側面11(平坦面12)之辨識變得容易。 Even when the dividing
第4圖係顯示實施形態之變形例2之分割部40的剖面形狀的放大剖面圖。在該變形例2中,於平坦面12與接合面13之間的側面11,形成有從接合面13垂直地立起的垂直面14。亦即,在變形例2中,側面11係具有上側的平坦面12、及下側的垂直面14,且在該平坦面12與垂直面14之間,配置有平坦面12的下端部12b。 Fig. 4 is an enlarged cross-sectional view showing the cross-sectional shape of the dividing
即使在該變形例2中,藉由使上端部12a 彼此之間隔Lt比平坦面12之下端部12b彼此的間隔Lb變大,從而亦可容易地確認接合材30對於在分割部40相對向之靶材10之側面11的附著狀態。 Even in this modification 2, by making the distance Lt between the
再者,在變形例2中,可將垂直面14之高度Tp相對於靶材10之厚度Ta的比率設為0.2以下。藉此,可將由平坦面12彼此所形成之末端變寬狀之間隙的大小,充分地確保為可使垂直面14被辨識的程度。 Furthermore, in Modification 2, the ratio of the height Tp of the
此外,在變形例2中,垂直面14與接合面13不一定需呈垂直,垂直面14與接合面13所成之角度係只要在90°±3°之範圍內即可。 In addition, in Modification 2, the
第5圖係顯示實施形態之變形例3之分割部40的剖面形狀的放大剖面圖。在該變形例3中,於平坦面12與濺鍍面15之間的側面11,形成有倒角部16。亦即,在變形例3中,側面11係具有下側的平坦面12、及上側的倒角部16,在該平坦面12與倒角部16之間,配置有平坦面12的上端部12a。 Fig. 5 is an enlarged cross-sectional view showing the cross-sectional shape of the dividing
即使在該變形例3中,使上端部12a彼此之間隔Lt比平坦面12之下端部12b彼此的間隔Lb變大,從而亦可容易地確認接合材30對於在分割部40中相對向之靶材10之側面11的附著狀態。 Even in this modification 3, the distance Lt between the
再者,在變形例3中,藉由在平坦面12之上側形成倒角部16,而可進一步將形成在平坦面12之上端部12a的角部設為鈍角。因此,依據變形例3,可使形成在上端部12a之角部更不容易破裂。並且,在進行濺鍍 成膜之際,可更進一步抑制從該角部產生之電弧現象。 Furthermore, in Modification 3, by forming the chamfered
此外,亦可將變形例2所示之垂直面14、及變形例3所示之倒角部16皆形成在靶材10的側面11。亦即,亦可從上往下依序將側面11形成為倒角部16、平坦面12、垂直面14。此外,此時係在倒角部16與平坦面12之間配置有平坦面12的上端部12a,且在垂直面14與平坦面12之間配置有平坦面12的下端部12b。 In addition, both the
在此說明之實施形態及變形例中,可在形成於靶材10之分割部40的至少一部分形成上述的平坦面12。藉此,在形成該平坦面12之分割部40中,可容易地確認接合材30對於側面11的附著狀態。 In the embodiment and modification examples described here, the above-mentioned
再者,更宜在形成於靶材10之全部的分割部40形成上述的平坦面12。藉此,在靶材10之全部的分割部40中,可容易地確認接合材30對於側面11的附著狀態,並且在全部的分割部40中,可容易地去除附著在側面11的接合材30。 Furthermore, it is more preferable to form the above-mentioned
再者,可使形成於靶材10之分割部40中相對向之全部的平坦面12,分別從上方朝可辨識之方向傾斜。藉此,可將形成在全部之平坦面12之上端部12a的角部設為鈍角,且在靶材10之分割部40之全部中,可使形成在上端部12a之角部不容易破裂,因此可使分割濺鍍靶1之可靠性更進一步提升。 Furthermore, all the
再者,由於可進一步抑制濺鍍成膜時的電弧現象,因此可更穩定地實施由分割濺鍍靶1所進行的濺 鍍成膜。 Furthermore, since the arc phenomenon during the sputtering film formation can be further suppressed, the sputtering film formation by the divided sputtering target 1 can be performed more stably.
實施例1 Example 1
調配由BET(Brunauer-Emmett-Teller,布厄特)法所測定的比表面積(BET比表面積)為5m2/g的SnO2粉末10質量%、與BET比表面積為5m2/g的In2O3粉末90質量%,並且藉由氧化鋯球在罐中進行球磨機混合,以調製原料粉末。 10% by mass of SnO 2 powder with a specific surface area (BET specific surface area) of 5 m 2 /g as measured by the BET (Brunauer-Emmett-Teller, Buert) method and In 2 with a BET specific surface area of 5 m 2 /g The O 3 powder was 90% by mass, and the zirconia balls were mixed with a ball mill in a tank to prepare raw material powders.
在該罐中,分別相對於原料粉末100質量%添加0.3質量%之丙烯酸乳膠黏合劑、0.5質量%之多羧酸胺、及20質量%之水,並進行球磨機混合而調製漿。接著,使所調製之漿液流入至隔著過濾器而配置之金屬製的模具,並予以排水而獲得成形體。 In this tank, 0.3% by mass of acrylic latex binder, 0.5% by mass of polycarboxylic acid amine, and 20% by mass of water were added to 100% by mass of the raw material powder, and mixed with a ball mill to prepare a slurry. Next, the prepared slurry was poured into a metal mold arranged with a filter interposed therebetween, and drained to obtain a molded body.
將該成形體以升溫速度300℃/h從常溫加熱至1600℃,並保持12小時後,以降溫速度50℃/h進行冷卻,從而進行成形體之鍛燒,以製作鍛燒體。並且,將該鍛燒體切斷成預定之尺寸。 The formed body was heated from room temperature to 1600°C at a temperature increase rate of 300°C/h, and maintained for 12 hours, and then cooled at a temperature decrease rate of 50°C/h, thereby calcining the formed body to produce a calcined body. Then, the calcined body is cut into a predetermined size.
對所得之鍛燒體進行研磨加工,以獲得兩片厚度8mm的ITO靶材10。將兩靶材10的側面予以切斷,設置具有θ=89.6°之傾斜的側面11。接著,以三井研磨磨石股份有限公司製之#1000的磨石對兩靶材10之側面11進行研磨,再以Noritake股份有限公司製鑽石研磨墊#5000研磨成表面粗糙度Ra在0.02μm以下,以形成平坦 面12。表面粗糙度Ra係使用三豐股份有限公司製之表面粗糙度測定機進行測定。 The obtained calcined body was subjected to grinding processing to obtain two
接著,將所得之兩片靶材10排列於銅製之基材20並予以接合,以獲得分割濺鍍靶1。此外,該接合材30係使用銦,且以使距離基材20最遠之部分的間隔Lt為0.2mm、距離基材20最近之部分的間隔Lb為0.1mm(亦即,Lt-Lb=0.1mm)之方式排列配置在基材20上。 Next, the obtained two pieces of
實施例2至33 Examples 2 to 33
藉由與實施例1相同之方法來獲得兩片ITO靶材10。兩靶材10的平坦面12與接合面13的角度θ、及平坦面12的表面粗糙度Ra係加工成第1表的數值。並且,以使距離基材20最遠之部分的間隔Lt及距離基材20最近之部分的間隔Lb、而且Lt-Lb成為第1表的數值之方式將兩靶材10排列並接合在基材20上,以獲得分割濺鍍靶1。 Two pieces of
比較例1 Comparative example 1
藉由與實施例1相同之方法來獲得兩片ITO靶材10。兩靶材10係加工成平坦面12與接合面13的角度為θ=90°、及平坦面12的表面粗糙度Ra為0.02μm以下。再者,以使距離基材20最遠之部分的間隔Lt成為0.5mm、距離基材20最近之部分的間隔Lb成為0.5mm(亦即,Lt-Lb為零)之方式,將兩靶材10排列接合於基材20上,以獲得分割濺鍍靶1。 Two pieces of
比較例2 Comparative example 2
藉由與實施例1相同之方法來獲得兩片ITO靶材10。兩靶材10的平坦面12與接合面13之角度θ係加工成第1表的數值,而且平坦面12的表面粗糙度Ra係加工成0.4μm。再者,以使距離基材20最遠之部分的間隔Lt及距離基材20最近之部分的間隔Lb、而且Lt-Lb成為第1表之數值的方式,將兩靶材10排列接合於基材20上,以獲得分割濺鍍靶1。 Two pieces of
接著,以目視評價由上述所得之實施例1至33及比較例1、2的分割濺鍍靶1之分割部40的辨識性。 評價基準係如下所述。 Next, the visibility of the divided
◎:辨識性非常好 ◎: Very good recognizability
○:辨識性好 ○: Good identification
△:辨識性略差 △: Slightly poor recognizability
×:辨識性差 ×: Poor recognition
接著,針對實施例1至33及比較例1、2的分割濺鍍靶1,進行附著於分割部40之側面11之銦的去除作業。該去除作業係以目視確認分割部40,並且利用金屬製之刮勺對確認出附著有銦之部位進行去除。 Next, with respect to the divided sputtering targets 1 of Examples 1 to 33 and Comparative Examples 1 and 2, the removal of indium attached to the
接著,從實施例1至33及比較例1、2的分割濺鍍靶1剝取二片靶材10,以目視評價銦對於側面11為何種的附著程度。評價基準係如下所述。 Next, two pieces of
◎:無In附著 ◎: No In adhesion
○:略有In附著 ○: Slight In adhesion
△:有少量之In附著 △: A small amount of In adheres
×:有多量之In附著 ×: There is a large amount of In attached
第1表顯示:上述之實施例1至33及比較例1、2中之靶材10的厚度Ta;距離基材20最遠之部分的間隔Lt;距離基材20最近之部分的間隔Lb;Lt-Lb;靶材1及靶材2中之平坦面12與接合面13的角度θ;對於分割部40之辨識性的評價結果;以及銦對於側面11之附著量的評價結果。 Table 1 shows: the thickness Ta of the
比對在分割部40中間隔Lb與間隔Lt相同的比較例1、與在分割部40中間隔Lt比間隔Lb大的實施例1至33可知,藉由使間隔Lt設為比間隔Lb更大,可提 升分割部40的辨識性。 Comparing Comparative Example 1 in which the interval Lb and the interval Lt in the dividing
再者,比對平坦面12之表面粗糙度Ra大於0.3μm的比較例2、與平坦面12之表面粗糙度Ra在0.3μm以下的實施例1至33可知,藉由將平坦面12之表面粗糙度Ra設為0.3μm以下,可容易地去除附著在於分割部40中相對向之靶材10之側面11的接合材30(銦)。 Furthermore, comparing the comparative example 2 in which the surface roughness Ra of the
此外,比較例1雖平坦面12的表面粗糙度Ra為0.3μm以下,但由於分割部40的辨識性差,因此難以確認附著在側面11的接合材30(銦)。因此,無法容易地去除接合材30,且大量的接合材30附著在側面11。 In addition, although the surface roughness Ra of the
以上,雖針對本發明之實施形態加以說明,但本發明並不限定於上述之實施形態,只要不脫離其主旨,皆可進行各種變更。例如,在實施形態中雖記載平板狀之分割濺鍍靶,但亦可將上述之實施形態技術應用於圓筒狀的分割濺鍍靶。 Although the embodiments of the present invention have been described above, the present invention is not limited to the above-mentioned embodiments, and various changes can be made without departing from the gist. For example, although the flat plate-shaped divided sputtering target is described in the embodiment, the above-mentioned embodiment technique can also be applied to a cylindrical divided sputtering target.
如以上所述,實施形態之分割濺鍍靶1係將複數個靶材10接合在基材20而形成者,在該分割濺鍍靶1中:藉由以隔著間隔之方式配置複數個靶材10而形成的分割部40當中,在至少一部的分割部40所配置的一對靶材10的側面11的至少一部分係分別形成有平坦面12。並且,關於在分割部40中相對向之平坦面12彼此的間隔,距離基材20最遠之部分的間隔Lt係比距離基材20最近之部分的間隔Lb大,而平坦面12之表面粗糙度Ra係0.3μm以下。藉此,可容易地確認接合材30對於在分割部40中 相對向之靶材10之側面11的附著狀態,且可容易地去除附著在於分割部40相對向之靶材10之側面11的接合材30。 As described above, the divided sputtering target 1 of the embodiment is formed by bonding a plurality of
再者,在實施形態之分割濺鍍靶1中,由平坦面12彼此所形成之距離基材20最遠之部分的間隔Lt、與由平坦面12彼此所形成之距離基材20最近之部分的間隔Lb之差為0.1mm以上。藉此,可更容易地確認接合材30對於在分割部40中相對向之靶材10之側面11的附著狀態。 Furthermore, in the split sputtering target 1 of the embodiment, the interval Lt between the part formed by the
此外,在實施形態之分割濺鍍靶1中,於側面11中,在平坦面12與接合於基材20之接合面13之間,更形成有從接合面13大致垂直地立起的垂直面14,並將垂直面14之高度Tp相對於靶材10之厚度Ta的比率設為0.2以下。藉此,可將由平坦面12彼此所形成之末端變寬狀之間隙的大小,充分地確保在可目視辨識垂直面14之程度。 In addition, in the split sputtering target 1 of the embodiment, in the
此外,在實施形態之分割濺鍍靶1中,由平坦面12彼此所形成之距離基材20最遠之部分的間隔Lt為0.2mm以上0.7mm以下,而由平坦面12彼此所形成之距離基材20最近之部分的間隔Lb為0.1mm以上0.5mm以下。藉此,在對分割濺鍍靶1進行濺鍍成膜之際,可抑制從分割部40露出的接合材30成為雜質之情形。 In addition, in the split sputtering target 1 of the embodiment, the distance Lt between the portions formed by the
再者,在實施形態之分割濺鍍靶1中,由平坦面12彼此所形成之距離基材20最遠之部分的間隔Lt 為0.3mm以上0.6mm以下,而由平坦面12彼此所形成之距離基材20最近之部分的間隔Lb為0.1mm以上0.3mm以下。藉此,在對分割濺鍍靶1進行濺鍍成膜之際,可更為抑制從分割部40露出之接合材30成為雜質之情形。 Furthermore, in the split sputtering target 1 of the embodiment, the distance Lt between the portions formed by the
此外,在實施形態之分割濺鍍靶1中,平坦面12的表面粗糙度Ra為0.1μm以下。藉此,仍可抑制接合材30附著於平坦面12之情形。 In addition, in the divided sputtering target 1 of the embodiment, the surface roughness Ra of the
此外,在實施形態之分割濺鍍靶1中,平坦面12的表面粗糙度Ra為0.001μm以上0.05μm以下。藉此,可更為抑制接合材30附著於平坦面12之情形。 In addition, in the divided sputtering target 1 of the embodiment, the surface roughness Ra of the
再者,在實施形態之分割濺鍍靶1中,在全部的分割部40所配置的靶材10的側面11的至少一部分係形成有平坦面12,且關於在全部的分割部40中相對向之平坦面12彼此的間隔,距離基材20最遠之部分的間隔Lt係比距離基材20最近之部分的間隔Lb大,而平坦面12的表面粗糙度Ra係0.3μm以下。藉此,在靶材10之全部的分割部40中,可容易地確認接合材30對於側面11之附著狀態,並且可容易地去除附著於靶材10之側面11的接合材30。 Furthermore, in the split sputtering target 1 of the embodiment, a
此外,在實施形態之分割濺鍍靶1中,在全部的分割部40所配置的靶材10的側面11的至少一部分係形成有平坦面12,且在全部的分割部40中,由平坦面12彼此所形成之距離基材20最遠之部分的間隔Lt、與由平坦面12彼此所形成之距離基材20最近之部分的間隔Lb 的差為0.1mm以上。藉此,在靶材10之全部的分割部40中,可更容易地確認接合材30對於靶材10之側面11的附著狀態。 In addition, in the divided sputtering target 1 of the embodiment, the
更進一步之效果或變形例係可藉由該業者而容易地導出。因此,本發明之更廣泛之態樣係如以上所述,並非限定於所述之特定詳細說明及代表性之實施形態。因此,可在不脫離由所附之申請專利範圍及其等效物所定義之總括性發明概念之精神或範圍之情形下,可進行各式各樣之變更。 Further effects or modifications can be easily derived by the industry. Therefore, the broader aspects of the present invention are as described above, and are not limited to the specific detailed description and representative embodiments. Therefore, various changes can be made without departing from the spirit or scope of the general inventive concept defined by the scope of the attached patent application and its equivalents.
1‧‧‧分割濺鍍靶 1‧‧‧Split Sputtering Target
10‧‧‧靶材 10‧‧‧Target
11‧‧‧側面 11‧‧‧Side
12‧‧‧平坦面 12‧‧‧Flat surface
12a‧‧‧上端部 12a‧‧‧upper end
12b‧‧‧下端部 12b‧‧‧Lower end
13‧‧‧接合面 13‧‧‧Joint surface
20‧‧‧基材 20‧‧‧Substrate
30‧‧‧接合材 30‧‧‧Joint material
40‧‧‧分割部 40‧‧‧Splitting Department
θ‧‧‧角度 θ‧‧‧angle
Lt、Lb‧‧‧間隔 Lt、Lb‧‧‧Interval
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017072070 | 2017-03-31 | ||
JP2017-072070 | 2017-03-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201837212A TW201837212A (en) | 2018-10-16 |
TWI745483B true TWI745483B (en) | 2021-11-11 |
Family
ID=63674634
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW106138959A TWI745483B (en) | 2017-03-31 | 2017-11-10 | Divided sputtering target |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP6960989B2 (en) |
KR (1) | KR102402982B1 (en) |
CN (1) | CN110431252A (en) |
TW (1) | TWI745483B (en) |
WO (1) | WO2018179553A1 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201249600A (en) * | 2011-06-08 | 2012-12-16 | Thintech Materials Technology Co Ltd | Processing method for silicon target surface |
TWI554628B (en) * | 2015-02-24 | 2016-10-21 | Jx金屬股份有限公司 | Separated sputtering target |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08144052A (en) * | 1994-11-22 | 1996-06-04 | Tosoh Corp | Ito sputtering target |
JP4470029B2 (en) * | 1999-06-01 | 2010-06-02 | 東ソー株式会社 | Split ITO sputtering target |
JP4694104B2 (en) | 2003-04-18 | 2011-06-08 | 大日本印刷株式会社 | Sputtering target |
JP5228245B2 (en) * | 2007-08-31 | 2013-07-03 | 株式会社三井金属韓国 | Sputtering target |
JP2009127125A (en) * | 2007-11-28 | 2009-06-11 | Mitsui Mining & Smelting Co Ltd | Sputtering target material and sputtering target obtained therefrom |
WO2012063525A1 (en) * | 2010-11-08 | 2012-05-18 | 三井金属鉱業株式会社 | Divided sputtering target and method for producing same |
JP4961514B1 (en) * | 2010-11-08 | 2012-06-27 | 三井金属鉱業株式会社 | Split sputtering target and manufacturing method thereof |
JP5438825B2 (en) * | 2011-04-18 | 2014-03-12 | Jx日鉱日石金属株式会社 | Sputtering target |
WO2016002633A1 (en) * | 2014-07-03 | 2016-01-07 | 住友金属鉱山株式会社 | Target material for sputtering and method for manufacturing same |
JP5947413B1 (en) * | 2015-02-13 | 2016-07-06 | Jx金属株式会社 | Sputtering target and manufacturing method thereof |
-
2017
- 2017-10-27 KR KR1020197027915A patent/KR102402982B1/en active IP Right Grant
- 2017-10-27 JP JP2019508538A patent/JP6960989B2/en active Active
- 2017-10-27 CN CN201780088428.8A patent/CN110431252A/en active Pending
- 2017-10-27 WO PCT/JP2017/038946 patent/WO2018179553A1/en active Application Filing
- 2017-11-10 TW TW106138959A patent/TWI745483B/en active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201249600A (en) * | 2011-06-08 | 2012-12-16 | Thintech Materials Technology Co Ltd | Processing method for silicon target surface |
TWI554628B (en) * | 2015-02-24 | 2016-10-21 | Jx金屬股份有限公司 | Separated sputtering target |
Also Published As
Publication number | Publication date |
---|---|
TW201837212A (en) | 2018-10-16 |
WO2018179553A1 (en) | 2018-10-04 |
JPWO2018179553A1 (en) | 2020-02-13 |
CN110431252A (en) | 2019-11-08 |
KR102402982B1 (en) | 2022-05-27 |
KR20190131038A (en) | 2019-11-25 |
JP6960989B2 (en) | 2021-11-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9969054B2 (en) | Grinding tool and method of manufacturing the same | |
RU2492973C2 (en) | Cutting plate | |
KR101343703B1 (en) | Diamond cutting member and method of making the same | |
WO2010150350A1 (en) | Ultrasonic bonding tool, method for manufacturing ultrasonic bonding tool, ultrasonic bonding method, and ultrasonic bonding apparatus | |
TWI383060B (en) | Sputtering target | |
TWI757427B (en) | Ramping insert having non-positive cutting geometry and ramping tool | |
TWI745483B (en) | Divided sputtering target | |
TWI653209B (en) | Target, method for producing target and planar target | |
JP6110224B2 (en) | Target assembly and manufacturing method thereof | |
KR100332476B1 (en) | Sputtering target assembly of oxide sintered body | |
JP2016132181A (en) | Multi-point diamond tool | |
TW202123410A (en) | Metallic plate, metal-resin composite, semiconductor device, and metallic plate production method | |
CN111663107A (en) | Sputtering target and method for producing same | |
CN210974858U (en) | Bottom plate easy for separating sputtered material | |
JP2023115709A (en) | adhesive structure | |
KR102084319B1 (en) | A method for bending a frame | |
JP2008161987A (en) | Chisel, long band-shaped thin blade and die cutting blade unit | |
CN110450046B (en) | Polishing disk and chemical mechanical polishing apparatus | |
JP6385901B2 (en) | Chamfering wheel and chamfering method using the same | |
TWM286541U (en) | Assembled composite circuit board | |
KR20140138021A (en) | Cutter wheel and method of manufacturing the same | |
JP2020021756A5 (en) | ||
EP2951347B1 (en) | Cast refiner plate segment with blunt surfaces for safe handling | |
TW201825420A (en) | Scribing wheel effectively suppressing the generation of glass swarf with a simple configuration | |
TWI769268B (en) | Diamond Knife Blade and Substrate Breaking Method |