TWI709477B - 使用由硬質相與軟質相區域形成之粒狀聚合物之製造三維物體的方法 - Google Patents
使用由硬質相與軟質相區域形成之粒狀聚合物之製造三維物體的方法 Download PDFInfo
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- TWI709477B TWI709477B TW106112802A TW106112802A TWI709477B TW I709477 B TWI709477 B TW I709477B TW 106112802 A TW106112802 A TW 106112802A TW 106112802 A TW106112802 A TW 106112802A TW I709477 B TWI709477 B TW I709477B
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- Prior art keywords
- phase
- polymer particles
- particles
- glass transition
- transition temperature
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 43
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 230000008569 process Effects 0.000 title abstract description 7
- 239000011324 bead Substances 0.000 title abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 40
- 239000011230 binding agent Substances 0.000 claims abstract description 26
- 239000000725 suspension Substances 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 24
- 230000009477 glass transition Effects 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 12
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 11
- 238000000354 decomposition reaction Methods 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 238000010146 3D printing Methods 0.000 abstract description 6
- 239000004576 sand Substances 0.000 abstract description 5
- 229920000193 polymethacrylate Polymers 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 3
- 239000004952 Polyamide Substances 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 229920002647 polyamide Polymers 0.000 abstract description 2
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 14
- 239000007767 bonding agent Substances 0.000 description 10
- 238000007639 printing Methods 0.000 description 9
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 239000007858 starting material Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 150000002978 peroxides Chemical class 0.000 description 7
- 239000003431 cross linking reagent Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004908 Emulsion polymer Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 230000003362 replicative effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/34—Process control of powder characteristics, e.g. density, oxidation or flowability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/001—Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/165—Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Automation & Control Theory (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Tires In General (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16166134.3A EP3235867A1 (de) | 2016-04-20 | 2016-04-20 | Perlpolymerisat aus hartphase mit domänen einer weichphase |
| EP16166134.3 | 2016-04-20 | ||
| ??16166134.3 | 2016-04-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201806731A TW201806731A (zh) | 2018-03-01 |
| TWI709477B true TWI709477B (zh) | 2020-11-11 |
Family
ID=55919593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW106112802A TWI709477B (zh) | 2016-04-20 | 2017-04-17 | 使用由硬質相與軟質相區域形成之粒狀聚合物之製造三維物體的方法 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US10793731B2 (de) |
| EP (2) | EP3235867A1 (de) |
| JP (1) | JP6887441B2 (de) |
| KR (1) | KR102366882B1 (de) |
| CN (1) | CN109071909B (de) |
| AU (1) | AU2017253536B2 (de) |
| BR (1) | BR112018071479B1 (de) |
| CA (1) | CA3021423A1 (de) |
| DK (1) | DK3445821T3 (de) |
| ES (1) | ES2905683T3 (de) |
| HR (1) | HRP20220324T1 (de) |
| HU (1) | HUE057957T2 (de) |
| IL (1) | IL262272B (de) |
| MX (1) | MX2018012466A (de) |
| PL (1) | PL3445821T3 (de) |
| PT (1) | PT3445821T (de) |
| SG (1) | SG11201809193RA (de) |
| SI (1) | SI3445821T1 (de) |
| TW (1) | TWI709477B (de) |
| WO (1) | WO2017182364A1 (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3231588A1 (de) | 2016-04-12 | 2017-10-18 | Evonik Röhm GmbH | Sprühgetrocknetes weichphasenemulsionspolymerisat für das auffüllen der zwickel in perlpolymerisatschichten im binder jetting verfahren |
| WO2018059912A1 (de) | 2016-09-28 | 2018-04-05 | Evonik Röhm Gmbh | Herstellung und verwendung von porösen perlpolymerisaten im 3d druck gemäss dem binder jetting verfahren |
| CN108220643B (zh) * | 2018-01-29 | 2019-06-28 | 华中科技大学 | 一种钨颗粒增强非晶基复合材料的制备方法 |
| US20200298466A1 (en) * | 2019-03-22 | 2020-09-24 | Lawrence Livermore National Security, Llc | Additive manufacture of hierarchically porous materials with high resolution |
| KR102383639B1 (ko) * | 2020-03-26 | 2022-04-06 | 최성환 | 주물사 소재를 이용한 냉각코어의 3d 프린팅 방법 |
| US12041988B2 (en) | 2020-06-26 | 2024-07-23 | Mark Lamoncha | Protective face mask for attachment to protective eye-ware |
| US11766080B2 (en) | 2020-06-26 | 2023-09-26 | Mark Lamoncha | Face shield for attachment to goggles or eyeglasses |
| US11865261B2 (en) | 2020-07-14 | 2024-01-09 | Mark Lamoncha | Respirator mask |
| EP4108361A1 (de) | 2021-06-22 | 2022-12-28 | Evonik Operations GmbH | Materialsystem zum 3d-drucken |
| EP4108362A1 (de) | 2021-06-22 | 2022-12-28 | Evonik Operations GmbH | Materialsystem zum 3d-drucken |
| EP4108692A1 (de) | 2021-06-22 | 2022-12-28 | Evonik Operations GmbH | Materialsystem für 3d-drucken |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080281019A1 (en) * | 2007-02-22 | 2008-11-13 | Z Corporation | Three dimensional printing material system and method using plasticizer-assisted sintering |
| CN105164210A (zh) * | 2013-06-19 | 2015-12-16 | 惠普发展公司，有限责任合伙企业 | 用于三维(3d)打印的组合物 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523106A (en) * | 1994-02-03 | 1996-06-04 | Nabisco, Inc. | Juice-based expanded snacks and process for preparing them |
| DE10227224B4 (de) * | 2002-06-18 | 2005-11-24 | Daimlerchrysler Ag | Verwendung eines Granulates zum Herstellen eines Gegenstandes mit einem 3D-Binderdruck-Verfahren |
| WO2004073961A2 (de) * | 2003-02-18 | 2004-09-02 | Daimlerchrysler Ag | Beschichtete pulverpartikel für die herstellung von dreidimensionalen körpern mittels schichtaufbauender verfahren |
| DE102007025656A1 (de) * | 2006-08-20 | 2008-02-21 | Daimler Ag | Selbstaushärtendes Material und Verfahren zum schichtweisen Aufbau dreidimensionaler Bauteile |
| DE102007061445A1 (de) | 2007-12-20 | 2009-06-25 | Daimler Ag | Flüssigharz und Verfahren zur Herstellung eines Polymerkörpers unter Verwendung des Flüssigharzes |
| US10399147B2 (en) * | 2012-02-20 | 2019-09-03 | Smith & Nephew, Inc. | Porous structures and methods of making same |
| EP2920255B1 (de) | 2012-11-19 | 2019-03-13 | Hewlett-Packard Development Company, L.P. | Zusammensetzungen für dreidimensionales (3d) drucken |
| EP2941449B1 (de) * | 2013-04-23 | 2019-09-25 | Rohm and Haas Company | Polymerpulverzusammensetzung und verfahren zu deren herstellung |
| AU2014349205A1 (en) | 2013-08-20 | 2016-02-25 | Adam Bayne Hopkins | Density enhancement methods and compositions |
| US20150054195A1 (en) | 2013-08-20 | 2015-02-26 | Arthur Greyf | Method for 3-D Printing a Custom Bone Graft |
| JP6241244B2 (ja) | 2013-12-10 | 2017-12-06 | セイコーエプソン株式会社 | 三次元造形物製造装置、三次元造形物の製造方法および三次元造形物 |
| US11602892B2 (en) * | 2013-12-23 | 2023-03-14 | 3D Systems, Inc. | Three dimensional printing materials, systems, and methods |
| US10544311B2 (en) * | 2014-01-16 | 2020-01-28 | Hewlett-Packard Development Company, L.P. | Polymeric powder composition for three-dimensional (3D) printing |
| EP3212383A4 (de) * | 2014-10-29 | 2017-11-08 | Hewlett-Packard Development Company, L.P. | Verfahren zum dreidimensionalen (3d) drucken |
| US10391755B2 (en) * | 2015-10-23 | 2019-08-27 | Ricoh Company, Ltd. | Solid freeform fabrication material set, method of fabricating solid freeform object, method of fabricating dental prosthesis, and device for fabricating solid freeform object |
| CN105440199B (zh) * | 2015-12-15 | 2017-08-22 | 中山职业技术学院 | 一种聚丙烯酸酯基3d打印材料及其制备方法 |
| EP3231588A1 (de) | 2016-04-12 | 2017-10-18 | Evonik Röhm GmbH | Sprühgetrocknetes weichphasenemulsionspolymerisat für das auffüllen der zwickel in perlpolymerisatschichten im binder jetting verfahren |
| US20190111479A1 (en) * | 2017-10-12 | 2019-04-18 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing |
-
2016
- 2016-04-20 EP EP16166134.3A patent/EP3235867A1/de not_active Withdrawn
-
2017
- 2017-04-12 AU AU2017253536A patent/AU2017253536B2/en not_active Ceased
- 2017-04-12 EP EP17716264.1A patent/EP3445821B1/de active Active
- 2017-04-12 KR KR1020187030162A patent/KR102366882B1/ko active IP Right Grant
- 2017-04-12 CN CN201780024549.6A patent/CN109071909B/zh active Active
- 2017-04-12 BR BR112018071479-8A patent/BR112018071479B1/pt active IP Right Grant
- 2017-04-12 JP JP2018555247A patent/JP6887441B2/ja active Active
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080281019A1 (en) * | 2007-02-22 | 2008-11-13 | Z Corporation | Three dimensional printing material system and method using plasticizer-assisted sintering |
| CN105164210A (zh) * | 2013-06-19 | 2015-12-16 | 惠普发展公司，有限责任合伙企业 | 用于三维(3d)打印的组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112018071479A2 (pt) | 2019-02-19 |
| PT3445821T (pt) | 2022-02-01 |
| BR112018071479B1 (pt) | 2023-01-24 |
| US20190127598A1 (en) | 2019-05-02 |
| AU2017253536B2 (en) | 2020-12-03 |
| DK3445821T3 (da) | 2022-03-14 |
| KR20180136951A (ko) | 2018-12-26 |
| CN109071909A (zh) | 2018-12-21 |
| KR102366882B1 (ko) | 2022-02-23 |
| SI3445821T1 (sl) | 2022-03-31 |
| PL3445821T3 (pl) | 2022-03-28 |
| AU2017253536A1 (en) | 2018-12-06 |
| CN109071909B (zh) | 2022-10-18 |
| IL262272B (en) | 2022-04-01 |
| HUE057957T2 (hu) | 2022-06-28 |
| US10793731B2 (en) | 2020-10-06 |
| MX2018012466A (es) | 2019-02-21 |
| ES2905683T3 (es) | 2022-04-11 |
| IL262272A (en) | 2018-11-29 |
| EP3235867A1 (de) | 2017-10-25 |
| JP2019514730A (ja) | 2019-06-06 |
| SG11201809193RA (en) | 2018-11-29 |
| TW201806731A (zh) | 2018-03-01 |
| EP3445821A1 (de) | 2019-02-27 |
| WO2017182364A1 (de) | 2017-10-26 |
| CA3021423A1 (en) | 2017-10-26 |
| EP3445821B1 (de) | 2021-12-22 |
| HRP20220324T1 (hr) | 2022-05-13 |
| JP6887441B2 (ja) | 2021-06-16 |
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