TWI652374B - 雙極電解池及電解過程執行方法 - Google Patents
雙極電解池及電解過程執行方法 Download PDFInfo
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- TWI652374B TWI652374B TW103138628A TW103138628A TWI652374B TW I652374 B TWI652374 B TW I652374B TW 103138628 A TW103138628 A TW 103138628A TW 103138628 A TW103138628 A TW 103138628A TW I652374 B TWI652374 B TW I652374B
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- Prior art keywords
- electrode
- pair
- electrolytic cell
- electrodes
- gap
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- 238000000034 method Methods 0.000 claims abstract description 26
- 230000008569 process Effects 0.000 claims abstract description 19
- 238000005868 electrolysis reaction Methods 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 4
- 239000005416 organic matter Substances 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 3
- 229910003460 diamond Inorganic materials 0.000 claims description 3
- 239000010432 diamond Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 230000015556 catabolic process Effects 0.000 claims description 2
- 238000006731 degradation reaction Methods 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000002351 wastewater Substances 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 claims 1
- 229910003446 platinum oxide Inorganic materials 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 abstract description 6
- 210000004027 cell Anatomy 0.000 description 8
- 230000008901 benefit Effects 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 239000012267 brine Substances 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical group 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- -1 platinum metal Chemical compound 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4616—Power supply
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT002015A ITMI20132015A1 (it) | 2013-12-03 | 2013-12-03 | Cella elettrolitica dotata di coppie concentriche di elettrodi |
| ??MI2013A002015 | 2013-12-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201522715A TW201522715A (zh) | 2015-06-16 |
| TWI652374B true TWI652374B (zh) | 2019-03-01 |
Family
ID=49920461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103138628A TWI652374B (zh) | 2013-12-03 | 2014-11-07 | 雙極電解池及電解過程執行方法 |
Country Status (14)
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|---|---|
| US (1) | US10023966B2 (enExample) |
| EP (1) | EP3077577B1 (enExample) |
| JP (1) | JP6511053B2 (enExample) |
| KR (1) | KR102277620B1 (enExample) |
| CN (1) | CN105793474B (enExample) |
| AU (1) | AU2014359318B2 (enExample) |
| BR (1) | BR112016009720B1 (enExample) |
| EA (1) | EA030848B1 (enExample) |
| ES (1) | ES2663499T3 (enExample) |
| IL (1) | IL245083B (enExample) |
| IT (1) | ITMI20132015A1 (enExample) |
| MX (1) | MX357177B (enExample) |
| TW (1) | TWI652374B (enExample) |
| WO (1) | WO2015082527A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107534160B (zh) | 2015-02-17 | 2021-05-11 | 懿华水处理技术有限责任公司 | 减小体积的电氯化电池及其制造方法 |
| IT201600123656A1 (it) * | 2016-12-06 | 2018-06-06 | Industrie De Nora Spa | Struttura di supporto elettrodica per celle elettrolitiche coassiali |
| CN108298741B (zh) * | 2018-02-06 | 2020-07-14 | 中国石油大学(华东) | 一种含油污水电絮凝高效净化装置 |
| US11668017B2 (en) | 2018-07-30 | 2023-06-06 | Water Star, Inc. | Current reversal tolerant multilayer material, method of making the same, use as an electrode, and use in electrochemical processes |
| EP3864403A1 (en) | 2018-10-12 | 2021-08-18 | F. Hoffmann-La Roche AG | Detection methods for epitachophoresis workflow automation |
| US11624119B2 (en) * | 2020-07-26 | 2023-04-11 | Thomas E Loop | Centrifugal molten electrolysis reactor for oxygen, volatiles, and metals extraction from extraterrestrial regolith |
| US20220195612A1 (en) * | 2020-12-22 | 2022-06-23 | De Nora Tech, Llc | Electrolyser for electrochlorination processes and a self-cleaning electrochlorination system |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029396A (zh) | 2007-03-29 | 2007-09-05 | 上海大学 | 一种铜镍合金(白铜)的防腐蚀方法 |
| WO2011163656A1 (en) | 2010-06-25 | 2011-12-29 | Gold Holdings, Llc | Method of treating organic material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2349286C3 (de) * | 1973-10-01 | 1982-11-18 | Götz, Friedrich, Dipl.-Phys., 5628 Heiligenhaus | Vielfachelektrolysezelle zur Erzeugung eines Gemisches von Wasserstoff und Sauerstoff |
| US3984303A (en) * | 1975-07-02 | 1976-10-05 | Diamond Shamrock Corporation | Membrane electrolytic cell with concentric electrodes |
| GB1539521A (en) * | 1975-10-08 | 1979-01-31 | Magneto Chemie Bv | Electrolytic cells |
| JPS6263694A (ja) * | 1985-09-12 | 1987-03-20 | Permelec Electrode Ltd | 内面活性筒状電極及びその製造方法 |
| US5102515A (en) * | 1990-07-20 | 1992-04-07 | Ibbott Jack Kenneth | Method and apparatus for treating fluid |
| US5234555A (en) * | 1991-02-05 | 1993-08-10 | Ibbott Jack Kenneth | Method and apparatus for ionizing fluids utilizing a capacitive effect |
| JPH06254564A (ja) * | 1992-05-25 | 1994-09-13 | Tokyo Risui Kogyo Kk | 電解水生成器の電極および電解槽 |
| JP2000093973A (ja) | 1998-07-24 | 2000-04-04 | Mitsubishi Electric Corp | 多重円筒状電極を用いた殺菌装置 |
| US6156168A (en) * | 1999-03-16 | 2000-12-05 | Paul Kayfetz | Electrolytic device |
| CN101365826A (zh) | 2006-01-10 | 2009-02-11 | 海德罗克斯控股有限公司 | 用于生产可燃流体的方法和设备 |
| TW200840120A (en) * | 2007-03-20 | 2008-10-01 | Industrie De Nora Spa | Electrochemical cell and method for operating the same |
| US20090139856A1 (en) * | 2008-05-06 | 2009-06-04 | Chiarini Jr Edward Louis | Multiple electrode stack and structure for the electrolysis of water |
| JP3154457U (ja) * | 2008-08-29 | 2009-10-22 | 洋二 早川 | 水環境電池を利用した噴霧装置 |
| KR101061227B1 (ko) * | 2008-11-27 | 2011-08-31 | 최장수 | 수중 플라즈마 방전을 이용한 수산기 라디칼 수와 수소산소가스 발생장치 및 이를 이용한 시스템 |
| US20110147204A1 (en) * | 2009-12-17 | 2011-06-23 | Green On Demand, LLP (G.O.D.) | Apparatus for on demand production of hydrogen by electrolysis of water |
| DE102010041582A1 (de) * | 2010-09-29 | 2012-03-29 | Siemens Aktiengesellschaft | Kombiniertes Verfahren zur Desinfektion, Verfahren zur Aufbereitung von Schlämmen |
| MX2014006561A (es) * | 2011-12-02 | 2014-09-22 | Aquamost Inc | Aparato y metodo para tratar soluciones acuosas y contaminantes en las mismas. |
| ITMI20121048A1 (it) * | 2012-06-18 | 2013-12-19 | Industrie De Nora Spa | Cella elettrolitica dotata di coppie concentriche di elettrodi |
| GB2513368B (en) * | 2013-04-25 | 2016-01-27 | Radical Filtration Ltd | Process apparatus |
-
2013
- 2013-12-03 IT IT002015A patent/ITMI20132015A1/it unknown
-
2014
- 2014-11-07 TW TW103138628A patent/TWI652374B/zh active
- 2014-12-03 AU AU2014359318A patent/AU2014359318B2/en active Active
- 2014-12-03 EA EA201691158A patent/EA030848B1/ru not_active IP Right Cessation
- 2014-12-03 JP JP2016536698A patent/JP6511053B2/ja active Active
- 2014-12-03 CN CN201480064850.6A patent/CN105793474B/zh active Active
- 2014-12-03 ES ES14806272.2T patent/ES2663499T3/es active Active
- 2014-12-03 MX MX2016005653A patent/MX357177B/es active IP Right Grant
- 2014-12-03 KR KR1020167017119A patent/KR102277620B1/ko active Active
- 2014-12-03 EP EP14806272.2A patent/EP3077577B1/en active Active
- 2014-12-03 BR BR112016009720-3A patent/BR112016009720B1/pt active IP Right Grant
- 2014-12-03 WO PCT/EP2014/076369 patent/WO2015082527A1/en not_active Ceased
- 2014-12-03 US US15/032,701 patent/US10023966B2/en active Active
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- 2016-04-13 IL IL245083A patent/IL245083B/en active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029396A (zh) | 2007-03-29 | 2007-09-05 | 上海大学 | 一种铜镍合金(白铜)的防腐蚀方法 |
| WO2011163656A1 (en) | 2010-06-25 | 2011-12-29 | Gold Holdings, Llc | Method of treating organic material |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2014359318A1 (en) | 2016-05-05 |
| EP3077577A1 (en) | 2016-10-12 |
| ES2663499T3 (es) | 2018-04-13 |
| EA030848B1 (ru) | 2018-10-31 |
| JP2017503916A (ja) | 2017-02-02 |
| US20160251763A1 (en) | 2016-09-01 |
| US10023966B2 (en) | 2018-07-17 |
| BR112016009720B1 (pt) | 2021-10-13 |
| EP3077577B1 (en) | 2018-02-07 |
| EA201691158A1 (ru) | 2016-09-30 |
| IL245083A0 (en) | 2016-06-30 |
| MX2016005653A (es) | 2016-08-11 |
| AU2014359318B2 (en) | 2018-08-02 |
| CN105793474B (zh) | 2017-11-10 |
| HK1221268A1 (zh) | 2017-05-26 |
| JP6511053B2 (ja) | 2019-05-08 |
| TW201522715A (zh) | 2015-06-16 |
| KR102277620B1 (ko) | 2021-07-19 |
| IL245083B (en) | 2019-01-31 |
| ITMI20132015A1 (it) | 2015-06-04 |
| MX357177B (es) | 2018-06-28 |
| BR112016009720A2 (enExample) | 2017-08-01 |
| CN105793474A (zh) | 2016-07-20 |
| WO2015082527A1 (en) | 2015-06-11 |
| KR20160093650A (ko) | 2016-08-08 |
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