TWI565409B - Method for preventing diseases in transplanted rice - Google Patents

Method for preventing diseases in transplanted rice Download PDF

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TWI565409B
TWI565409B TW101140661A TW101140661A TWI565409B TW I565409 B TWI565409 B TW I565409B TW 101140661 A TW101140661 A TW 101140661A TW 101140661 A TW101140661 A TW 101140661A TW I565409 B TWI565409 B TW I565409B
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rice
disease
caused
seed
composition
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TW201325455A (en
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澤田勝鏡
仁木理人
佐久間晴彥
波多野廣幸
中村新
狗田鐵也
砂川崇
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拜耳智慧財產有限公司
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/08Immunising seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Toxicology (AREA)
  • Soil Sciences (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

預防移栽稻米疾病之方法 Method for preventing transplanting rice diseases

本發明係關於預防移栽稻米之疾病及/或防治動物蟲害之方法。 The present invention relates to a method for preventing diseases of transplanted rice and/or controlling pests of animals.

直接播種在稻田中之稻種的殺蟲劑處理已為所知。然而,仍無以移栽稻米之預防疾病及/或防治動物蟲害為目的之實際種子處理(Technology of pesticide application(Section III;common technique of pesticide application,seed disinfection),出版:1998,頁數:133-139,由Pesticide Science Society of Japan編輯,Japan Plant Protection Association出版)。 Insecticide treatment of rice seeds directly planted in rice fields is known. However, there is still no technology for pesticide application (Section III; common technique of pesticide application, seed disinfection) for the purpose of preventing diseases and/or controlling animal pests in transplanted rice. Publication: 1998, pp. 133 -139, edited by Pesticide Science Society of Japan, published by Japan Plant Protection Association).

且有關種子感染疾病之消毒方法亦有描述,其中種子係在浸水後或發芽後以種子消毒劑處理,但有關稻田中疾病或昆蟲蟲害之預防並無說明(日本專利申請公開案第9224424號,日本專利申請公開案第11028006號,日本專利申請公開案第11049612號)。 Further, a disinfection method for a seed-infected disease is also described, in which the seed is treated with a seed disinfectant after being immersed in water or after germination, but the prevention of diseases or insect pests in the rice field is not described (Japanese Patent Application Laid-Open No. 9224424, Japanese Patent Application Publication No. 11028006, Japanese Patent Application Publication No. 11049612).

對於移栽稻米之疾病預防性處理及/或防治動物蟲害,係將農藥噴灑在稻田或育苗箱。然而,在稻米移栽至稻田後於稻田上噴灑農藥來預防稻米疾病及/或防治動物蟲害,具有需要大量農藥或農藥效用無法持久之問題。且,相較於稻田,於育苗箱噴灑農藥可降低農藥的量,但在某些情況下所用的農藥量仍很大且效用不夠持久。 For the preventive treatment of diseases of transplanted rice and/or the control of animal pests, pesticides are sprayed on rice fields or nursery boxes. However, spraying pesticides on rice fields to prevent rice diseases and/or controlling animal pests after transplanting rice into rice fields has the problem that a large amount of pesticides or pesticides are not durable. Moreover, spraying pesticides in the nursery box can reduce the amount of pesticides compared to rice fields, but in some cases the amount of pesticide used is still large and the effect is not long enough.

因此,本發明之目的係改善這些缺點,及相較於該等用於習用育苗箱處理之量顯著地降低農藥的用量,並提供移栽稻米預防疾病及/或防治動物蟲害之方法,該方法為簡單且較便宜,在稻田中具有長期殘效。 Accordingly, it is an object of the present invention to improve these disadvantages and to provide a method for preventing disease and/or controlling animal pests by transplanting rice as compared to the amount used for conventional seedling box treatment to significantly reduce the amount of pesticides. It is simple and cheap, and has long-term residual effects in rice fields.

經由專門的研究解決上述問題,本發明之發明者已發現,藉由在播種於育苗箱前以亞汰尼(isotianil)處理稻種,相較於習用的育苗箱處理可能顯著的降低農藥用量並使農藥效用持久。在本發明之定義中,持久效用係指在移栽後53天或更多天,仍觀察到疾病預防及/或防治動物蟲害。較佳地,在移栽後67天或更多天,仍觀察到疾病預防及/或防治動物蟲害。最佳地,在移栽後80天或更多天,仍觀察到疾病預防及/或防治動物蟲害。 Through special studies to solve the above problems, the inventors of the present invention have found that by treating rice seeds with isotianil before seeding in a nursery box, the amount of pesticides may be significantly reduced compared to the conventional nursery box treatment. Make pesticides last longer. In the definition of the present invention, long-lasting utility means that disease prevention and/or control of animal pests is still observed 53 days or more after transplanting. Preferably, disease prevention and/or control of animal pests is still observed 67 days or more after transplanting. Optimally, disease prevention and/or control of animal pests is still observed 80 days or more after transplanting.

另一方面,已發現在某些情況下,當以其他農藥例如撲殺熱(probenazol)、噻醯菌胺(tiadinil)及其類似物處理種子時導致了有害效應,且當以減量的農藥處理種子以降低有害效應時,在移栽至稻田後無法得到足夠的農藥效用。基於上述發現完成了本發明。 On the other hand, it has been found that in some cases, when the seeds are treated with other pesticides such as probenazol, tiadinil and the like, harmful effects are caused, and when the seeds are treated with reduced pesticides In order to reduce harmful effects, sufficient pesticide effects cannot be obtained after transplanting to rice fields. The present invention has been completed based on the above findings.

本發明之第一具體實施例為於稻田之移栽稻米中疾病預防及/或防治動物蟲害之方法,其中含亞汰尼之組成物係在稻種播種至育苗箱之前附著於其上,且其中該包含亞汰尼之組成物係以30至180g a.i./ha,較佳地40至140g a.i./ha,更佳地60至120g a.i./ha範圍內之活性成份量之方式來使用。 A first embodiment of the present invention is a method for preventing and/or controlling animal pests in transplanted rice in rice fields, wherein the composition containing the idini is attached to the rice seed before it is sown to the nursery box, and Wherein the composition comprising the rituximab is used in an amount of from 30 to 180 g ai/ha, preferably from 40 to 140 g ai/ha, more preferably from 60 to 120 g ai/ha.

一更佳的具體實施例為該方法,其中包含亞汰尼之組成物係以活性成份之量係在40至80 g a.i./ha之範圍內,最佳地50至70 g a.i./ha之範圍內的方式來使用。 A more preferred embodiment is the method wherein the composition comprising the idini is in the range of 40 to 80 g ai/ha, preferably 50 to 70 g ai/ha, in an amount of the active ingredient. The way inside is used.

本發明之第二具體實施例為該方法,其中該稻種為該等浸泡後和發芽前之種子或該等發芽後之種子。 A second embodiment of the invention is the method, wherein the rice seed is the seed after soaking and before germination or the seed after germination.

本發明之第三具體實施例為該方法,其中此組成物為包含亞汰尼、界面活性劑、有機溶劑和聚合物樹脂之水性懸浮液組成物。 A third embodiment of the invention is the method wherein the composition is an aqueous suspension composition comprising diatrines, a surfactant, an organic solvent, and a polymeric resin.

本發明之第四具體實施例為該方法,其中此組成物係包括至少一種選自三氟敏(trifloxystrobin)、戊苯吡菌胺(penflufen)、益達胺(imidacloprid)、賽果培(thiacloprid)、賜諾殺(spinosad)和益斯普(ethiprole)之另外的農藥。 A fourth embodiment of the present invention is the method, wherein the composition comprises at least one selected from the group consisting of trifloxystrobin, penflufen, imidacloprid, and thiacloprid. ), additional pesticides from spinosad and ethiprole.

本發明之第五具體實施例為該方法,其中在移栽後53天或更多天,仍觀察到疾病預防及/或防治動物蟲害。根據一較佳的具體實施例,在移栽後67天或更多天,仍觀察到疾病預防及/或防治動物蟲害。根據一更佳的具體實施例,在移栽後80天或更多天,仍觀察到疾病預防及/或防治動物蟲害。 A fifth embodiment of the present invention is the method wherein disease prevention and/or control of animal pests is still observed 53 days or more after transplanting. According to a preferred embodiment, disease prevention and/or control of animal pests is still observed 67 days or more after transplanting. According to a more preferred embodiment, disease prevention and/or control of animal pests is still observed 80 days or more after transplanting.

本發明之第六具體實施例為該方法,其中此方法係用於預防疾病。 A sixth embodiment of the invention is the method wherein the method is for preventing disease.

本發明之第七具體實施例為該方法,其中該疾病係由絲狀真菌及/或微生物所引發。 A seventh embodiment of the invention is the method wherein the disease is caused by a filamentous fungus and/or microorganism.

本發明之第八具體實施例為該方法,其中該疾病係選自稻熱病[由稻梨孢菌(Pyricularia oryzae)所引發]、稻米胡麻斑病或赤黴病[由宫部旋孢腔菌(Cochliobolus miyabeanus)所引發]、稻紋枯病[由立枯絲核菌(Rhizoctonia solani)所引發]、稻葉枯病[由稻生黃單胞菌(Xanthomonas oryzae pv.oryzae)所引發]及稻細菌性殼枯病[由穎殼伯克氏菌(Burkholderia glumae)所引發]。 An eighth embodiment of the present invention is the method, wherein the disease is selected from the group consisting of rice fever [initiated by Pyricularia oryzae ], rice mayard or scab [from Helminthosporium (caused by Cochliobolus miyabeanus ), rice sheath blight [caused by Rhizoctonia solani ], rice leaf blight [caused by Xanthomonas oryzae pv. oryzae ] and rice Bacterial shell blight [triggered by Burkholderia glumae ].

本發明之第九具體實施例為該方法,其中此方法係用於防治動物蟲害。 A ninth embodiment of the invention is the method, wherein the method is for controlling animal pests.

本發明之第十具體實施例為該方法,其中該動物蟲害係選自稻水象鼻蟲(Lissorhoptrus oryzophilus)、負泥蟲(Oulema oryzae Kuwayama)、飛蝨科(Delphacidae)、黑尾葉蟬(Nephotettix cincticeps)、稻潛葉蠅(Hydrellia griseola)(稻潛葉蠅)、單帶挵蝶(Parnara guttata)(稻包蟲)、稻螟蛉夜蛾(Naranga aenescens Moore)、瘤野螟(Cnaphalocrocis medinalis)、二化螟(Chilo suppressalis)和稻薊馬(Stenchaetothrips biformis)(稻薊馬)。 A tenth embodiment of the present invention is the method, wherein the animal pest is selected from the group consisting of Lissorhoptrus oryzophilus , O ulema oryzae Kuwayama , Delphacidae , and Black-tailed spider mites . ( Nephotettix cincticeps ), Hydrellia griseola (rice leaf miner), Parnara guttata (rice worm), Naranga aenescens Moore , Cnaphalocrocis medinalis ), Chilo suppressalis and Stenchaetothrips biformis (rice horse ).

相較於習用育苗箱處理中所用的農藥,如上述,本發明之方法能以較小量的農藥於稻田之移栽稻米中長期降低疾病之發生及/或防治動物蟲害。 Compared with the pesticide used in the conventional nursery box treatment, as described above, the method of the present invention can reduce the occurrence of diseases and/or control animal pests for a long time with a small amount of pesticides transplanted rice in rice fields.

本發明係根據具體實施例詳述於下。本發明說明書中所提及之參考文獻的整體內容係包括在本說明書之內容中。 The invention is described in detail below in accordance with specific embodiments. The entire contents of the references mentioned in the specification of the present invention are included in the contents of the present specification.

本發明係關於稻田之移栽稻米中預防疾病及/或防治動物蟲害,其特徵在於含亞汰尼之組成物係在播種於育苗箱後附著在稻種上。 The present invention relates to the prevention of diseases and/or the control of animal pests in transplanted rice in rice fields, characterized in that the composition containing the idini is attached to the rice seeds after being sown in the nursery box.

亞汰尼(3,4-二氯-異噻唑-5-氰基苯胺,3,4-二氯-2'-氰基-1,2-噻唑-5-甲醯苯胺(IUPAC名稱),3,4-二氯-N-(2- 氰基苯基)-5-異噻唑甲醯胺(CAS名稱))為已顯示作為例如除草劑毒性之安全劑及類似劑(例如WO 2004/103072、WO 2007/057112、WO 2009/124708)之農藥。 Dartini (3,4-dichloro-isothiazol-5-cyanoaniline, 3,4-dichloro-2'-cyano-1,2-thiazol-5-carboxanilide (IUPAC name), 3 4-Dichloro- N- (2-cyanophenyl)-5-isothiazolylcarbamide (CAS name) is a safener and similar agent that has been shown to be toxic, for example, as a herbicide (eg, WO 2004/103072, WO 2007/057112, WO 2009/124708) pesticides.

在本發明方法中,含亞汰尼之組成物可為各種調配物形式,及例如可濕性粉劑、粒狀可濕性粉劑、水溶性調配物、液體調配物、可塗覆液體、水性懸浮液、微膠製備物,可列為具體實例。亦可使用種子塗層製備物。這些調配物可藉由已知的方法來獲得,例如藉由將亞汰尼與展開劑,亦即液體或固體稀釋劑或載劑混合,在某些情況下與介面活性劑,亦即乳化劑及/或分散劑混合。就使用水作為展開劑之情況,例如可使用有機溶劑作為輔助溶劑。在本發明中,就可操作性之觀點而言,水性懸浮液為較佳的。作為水性懸浮液,就耐久性效用之觀點而言,除了亞汰尼外,包含水、界面活性劑、液體稀釋劑(有機溶劑)和聚合物樹脂,特別是丙烯酸樹脂(包括丙烯酸烷基酯及/或甲基丙烯酸烷基酯之(共)聚合物樹脂)之水性懸浮液組成物為較佳的。若需要,消泡劑、防腐劑、增稠劑、分散劑、防凍劑及其類似物可加到該水性懸浮液組成物中。水性懸浮液組成物中較佳的亞汰尼含量係從1至50質量份,特別是從5至40質量份。較佳的界面活性劑含量係從0.01至10質量份,特別是0.1至5質量份。較佳的稀釋劑含量係從1至50質量份,特別是5至30質量份。較佳的丙烯酸樹脂含量係從0.1至20質量份,特別是從1至10質量份。就其他添加的成 份例如消泡劑、防腐劑和增稠劑,較佳的總含量係從0至10質量份,特別是從0至5質量份。水性懸浮液組成物中較佳的係以粒狀聚合物樹脂作為聚合物樹脂,且該等研磨成細粉狀的樹脂及其類似物為特佳的。 In the method of the present invention, the dynamide-containing composition may be in the form of various formulations, and, for example, a wettable powder, a granulated wettable powder, a water-soluble formulation, a liquid formulation, a coatable liquid, an aqueous suspension Liquid and microgel preparations can be listed as specific examples. Seed coating preparations can also be used. These formulations can be obtained by known methods, for example by mixing nitidin with a developing agent, ie a liquid or solid diluent or carrier, in some cases with an surfactant, ie an emulsifier. And / or a mixture of dispersants. In the case where water is used as the developing agent, for example, an organic solvent can be used as the auxiliary solvent. In the present invention, an aqueous suspension is preferred from the viewpoint of workability. As an aqueous suspension, in addition to idini, water, a surfactant, a liquid diluent (organic solvent) and a polymer resin, particularly an acrylic resin (including an alkyl acrylate and An aqueous suspension composition of / (or a polymer resin of alkyl methacrylate) is preferred. An antifoaming agent, a preservative, a thickener, a dispersing agent, an antifreezing agent, and the like may be added to the aqueous suspension composition, if necessary. The preferred enthalpy content in the aqueous suspension composition is from 1 to 50 parts by mass, particularly from 5 to 40 parts by mass. A preferred surfactant content is from 0.01 to 10 parts by mass, particularly from 0.1 to 5 parts by mass. The preferred diluent content is from 1 to 50 parts by mass, particularly from 5 to 30 parts by mass. The acrylic resin content is preferably from 0.1 to 20 parts by mass, particularly from 1 to 10 parts by mass. Additions to other additions A preferred total content of, for example, an antifoaming agent, a preservative and a thickener is from 0 to 10 parts by mass, particularly from 0 to 5 parts by mass. The aqueous suspension composition is preferably a particulate polymer resin as a polymer resin, and such finely ground resins and the like are particularly preferred.

就液體稀釋劑或載劑之實例,可提及的有芳香系烴類(例如二甲苯、甲苯、烷基萘及其類似物)、氯化芳香系或氯化脂系烴類(例如氯苯、氯化乙烷、氯化甲烷及其類似物)、脂系烴類[例如環己烷及其類似物、石蠟(例如礦物油餾份及其類似物)]、醇類(例如C2-10醇類如丁醇、乙二醇、多醇類如丙二醇及其類似物,和其醚類、酯類及其類似物)、酮類(例例如丙酮、甲基乙基酮、甲基異丙基酮、環己酮及其類似物)、強極性溶劑(例如二甲基甲醯胺、二甲基亞碸及其類似物)、水及其類似物。 As examples of the liquid diluent or carrier, there may be mentioned aromatic hydrocarbons (for example, xylene, toluene, alkylnaphthalene and the like), chlorinated aromatic or chlorinated aliphatic hydrocarbons (for example, chlorobenzene). , ethane chloride, chlorinated methane and the like), aliphatic hydrocarbons [such as cyclohexane and its analogs, paraffin (such as mineral oil fractions and the like)], alcohols (such as C 2- 10 alcohols such as butanol, ethylene glycol, polyols such as propylene glycol and the like, and ethers, esters and the like thereof, and ketones (for example, acetone, methyl ethyl ketone, methyl isoform) Propyl ketone, cyclohexanone and its analogs), strong polar solvents (such as dimethylformamide, dimethylhydrazine and the like), water and the like.

就固體稀釋劑或載劑之實例,可提及的有輾碎的天然礦物(例如高嶺土、黏土、白堊土、石英、綠坡縷石、蒙脫石、矽藻土及其類似物)、碾碎的合成礦物(例如膨潤土、矽酸、礬土、矽酸鹽、矽砂及其類似物)及其類似物。就顆粒調配物固體載劑之實例,可提及的有碾碎和雜樣岩石(例如方解石、大理石、浮石、海泡石、白雲石及其類似物、無機和有機粉末之合成的顆粒、細榖粒及類似的有機物質(例如鋸屑、椰殼、玉米穗、菸草桿及其類似物)。 As examples of solid diluents or carriers, there may be mentioned mashed natural minerals (for example, kaolin, clay, chalk, quartz, attapulgite, montmorillonite, diatomaceous earth and the like), mill Broken synthetic minerals (eg, bentonite, citric acid, alumina, citrate, cerium and the like) and analogs thereof. As examples of particulate formulation solid carriers, there may be mentioned crushed and mixed rocks (for example, calcite, marble, pumice, sepiolite, dolomite and the like, synthetic particles of inorganic and organic powders, fine Peel and similar organic matter (such as sawdust, coconut shell, ear of corn, tobacco rod and the like).

就界面活性劑之實例,可提及的有非離子和陰離子界面活性劑[例如聚氧乙烯脂肪酸酯、聚氧乙烯脂肪酸醇 醚(例如烷基芳基聚二醇醚、烷基磺酸酯、烷基硫酸酯、芳基磺酸酯)、三苯乙烯基苯酚及其乙氧基化合物]、白蛋白水解物及其類似物。 As examples of the surfactant, there may be mentioned nonionic and anionic surfactants [for example, polyoxyethylene fatty acid esters, polyoxyethylene fatty acid alcohols). Ethers (eg, alkyl aryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates), tristyryl phenols and their ethoxylates], albumin hydrolysates, and the like Things.

就分散劑之實例,可提及的有木質素-亞硫酸鹽廢液、甲基纖維素及其類似物。 As examples of the dispersing agent, there may be mentioned lignin-sulfite waste liquid, methyl cellulose and the like.

黏著劑亦可加到調配物中(粉末調配物、顆粒調配物、乳液),且就該黏著劑之實例,可提及的有羧甲基纖維素、天然和合成的聚合物(例如阿拉伯膠、聚乙烯醇、聚乙酸乙烯酯及其類似物)。 Adhesives may also be added to the formulation (powder formulation, granule formulation, emulsion), and as examples of such adhesives, there may be mentioned carboxymethylcellulose, natural and synthetic polymers (eg gum arabic) , polyvinyl alcohol, polyvinyl acetate and the like).

亦可使用調色劑,且就該調色劑之實例,可提及的有無機色素(例如氧化鐵、二氧化鈦、普魯士藍及其類似物)和有機染劑例如茜素染劑、偶氮染劑和金屬酞菁染劑,以及微量元素例如鐵、錳、硼、鈷、鉬、鋅之金屬鹽類及其類似物。 A toner may also be used, and as examples of the toner, inorganic pigments (e.g., iron oxide, titanium oxide, Prussian blue, and the like) and organic dyes such as alizarin dye, azo dye may be mentioned. Agents and metal phthalocyanine dyes, as well as trace elements such as metal salts of iron, manganese, boron, cobalt, molybdenum, zinc and the like.

又,除了亞汰尼之外,若需要,可混合其他的殺蟲劑,例如種子消毒劑、殺昆蟲劑和殺真菌劑。可列出下列組合藥劑作為實例。該等成份可單獨或組合使用。 Also, in addition to the idini, other insecticides such as seed disinfectants, insecticides and fungicides may be mixed if desired. The following combination agents can be listed as examples. These ingredients can be used singly or in combination.

1)丙唏酸酯(Strobilurin)殺真菌劑,係選自嘧菌酯(azoxystrobin)、甲香菌酯(coumethoxystrobin)、丁香菌酯(coumoxystrobin)、醚菌胺(dimoxystrobin)、烯肟菌酯(enoxastrobin)、氟菌螨酯(flufenoxystrobin)、氟嘧菌酯(fluoxastrobin)、克收欣(kresoxim-methyl)、苯氧菌胺(metominostrobin)肟醚菌胺(orysastrobin)、啶氧菌酯(picoxystrobin)、唑菌胺酯(pyraclostrobin)、唑 胺菌酯(pyrametostrobin)唑菌酯(pyraoxystrobin)和三氟敏(trifloxystrobin)。 1) Strobilurin fungicides selected from the group consisting of azoxystrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestrobin ( Enoxastrobin), flufenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin , pyraclostrobin, azole Pyramatetostrobin pyraoxystrobin and trifloxystrobin.

2)SDHI殺真菌劑,係選自聯苯吡菌胺(bixafen)、啶醯菌胺(boscalid)、萎鏽靈(carboxin)、氟嘧菌胺(diflumetorim)、甲呋菌胺(fenfuram)、氟吡菌醯胺(fluopyram)、福多寧(flutolanil)、氟唑菌醯胺(fluxapyroxad)、福拉比(furametpyr)、拌種胺(furmecyclox)、(isopyrazam)、滅普寧(mepronil)、氧化萎銹靈(oxycarboxin)、戊苯吡菌胺(penflufen)、吡噻菌胺(penthiopyrad)、先正達(sedaxane)、賽氟滅(thifluzamide)、(benzovindiflupyr)及麥鏽靈(benodanil)。 2) SDHI fungicides, selected from the group consisting of bixafen, boscalid, carboxin, diflumetorim, fenfuram, Fluopyram, fluolanil, fluxapyroxad, furametpyr, furmecyclox, isopyrazam, mepronil, oxidation Oxycarboxin, penflufen, penthiopyrad, sedaxane, thifluzamide, benzovindiflupyr, and benodanil.

3)新類尼古丁殺蟲劑,係選自亞滅培(acetamiprid)、可尼丁(clothianidin)、達特南(dinotefuran)、益達胺(imidacloprid)、烯啶蟲胺(nitenpyram)、賽果培(thiacloprid)和賽速安(thiamethoxam)。 3) New nicotine insecticides selected from the group consisting of acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, and fruit. Peacloprid and thiamethoxam.

4)雷諾定(Ryanodine)受體調節劑,係選自氯蟲醯胺(Chloranthraniliprole)、氰蟲醯胺(cyanthraniliprole)和氟蟲醯胺(flubendiamide) 4) Ryanodine receptor modulator selected from the group consisting of Chloranthraniliprole, cyanthraniliprole and flubendiamide

5)賜諾司(Spinosyn)殺蟲劑,係選自賜諾殺(spinosad)和賜諾特(spinetoram) 5) Spinosyn insecticide, selected from spinosad and spinetoram

6)苯基吡唑殺蟲劑,係選自益斯普(ethiprole)和芬普尼(fipronil) 6) Phenylpyrazole insecticide, selected from ethiprole and fipronil

7)咪唑類殺真菌劑,係選自甲基-1-(正丁基胺甲醯基)-2-苯并咪唑-胺甲酸酯[免賴得(benomyl)]、1,2-雙(3-甲氧基羰基-2-硫脲基)苯[甲基多保淨(thiophanate methyl)]及戊-4-烯基N-糠基-N-咪唑-1-基羰基-DL-高丙氨酸酯[稻瘟酯(pefurazoate)]。 7) an imidazole fungicide selected from the group consisting of methyl-1-(n-butylamine-mercapto)-2-benzimidazole-amine formate [benomyl], 1,2-double (3-methoxycarbonyl-2-thioureido)benzene [thiophanate methyl] and pent-4-enyl N-fluorenyl-N-imidazol-1-ylcarbonyl-DL-high Alanine ester [pefurazoate].

8)固醇脫甲基抑制劑,係選自(E)-4-氯-α,α,α-三氟-N-(1-咪唑-1-基-丙氧基亞乙基)-鄰-甲苯胺[賽福座(triflumizole)]、N-丙基-N-{2-(2、4、6-三氯苯氧基)乙基}咪唑-1-甲醯胺[撲克拉(prochloraz)]、2-[(4-氯苯基)甲基]-5-(1-甲基乙基)-1-(1H-1,2,4-三唑-1-基甲基)環戊醇[種菌唑(ipconazole)] 8) a sterol demethylation inhibitor selected from the group consisting of (E)-4-chloro-α,α,α-trifluoro-N-(1-imidazol-1-yl-propoxyethylene)-o- -Toluidine [triflumizole], N-propyl-N-{2-(2,4,6-trichlorophenoxy)ethyl}imidazole-1-carboxamide [Polycola (prochloraz) )], 2-[(4-chlorophenyl)methyl]-5-(1-methylethyl)-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopenta Alcohol [ipconazole]

9)銅殺真菌劑,係選自氫氧化銅、鹼性氯化銅、葡萄糖酸銅、壬基苯酚磺酸銅 9) A copper fungicide selected from the group consisting of copper hydroxide, basic copper chloride, copper gluconate, and copper nonylphenolsulfonate

10)其他,係選自雙(二甲基硫代胺甲醯基)二硫化物(TMTD)、5-乙基-5,8-二氫-8-側氧[1,3]間二氧雜戊烯并[4,5-g]喹啉-7-羧酸、4-(2,2-二氟-1,3-苯并間二氧雜戊烯-4-基)吡咯-3-甲腈。 10) Others, selected from the group consisting of bis(dimethylthiocarbamoxime) disulfide (TMTD), 5-ethyl-5,8-dihydro-8-side oxygen [1,3] dioxane Heteropentene[4,5-g]quinoline-7-carboxylic acid, 4-(2,2-difluoro-1,3-benzodioxol-4-yl)pyrrole-3- Formonitrile.

較佳地為下列農藥之組合:亞汰尼+三氟敏;亞汰尼+戊苯吡菌胺;亞汰尼+益達胺;亞汰尼+賽果培;亞汰尼+賜諾殺;亞汰尼+益斯普。 Preferably, it is a combination of the following pesticides: dysparin + trifluoro-sensitive; dysidine + pentopyramine; ididani + idadamine; idini + 赛果培; 迪尼尼+斯诺杀; Yardini + Yisip.

雖然無特別的限制,但從調配物和用於處理之農藥 量最適化的觀點來看,以殺蟲劑調配物之總量計,亞汰尼作為活性成份較佳的係在0.01至85%重量比之範圍內,更佳地從0.1至80%重量比,特佳地從5至70%重量比。 Although there are no special restrictions, but from the formulation and pesticides used for treatment From the viewpoint of the optimum amount of the insecticide, the rydenene is preferably contained in the range of 0.01 to 85% by weight, more preferably 0.1 to 80% by weight, based on the total amount of the insecticide formulation. , particularly preferably from 5 to 70% by weight.

對於將包含亞汰尼之組成物附著在稻種之方法並無特別的限制。就粉體塗覆之方法,例如有一種方法,其中係將稻種和農藥置於轉鼓中並藉由旋轉該鼓筒將稻種均勻的塗覆上農藥。就噴灑農藥之方法,例如有(1)一種其中係藉由使用適當的噴嘴將農藥直接噴灑在由漏斗和類似物落下的稻種之方法,(2)一種其中係以一震動中的導流板將漏斗與育苗箱連接,並當稻種彈跳通過板子時,使用適當的噴嘴將農藥直接噴灑在稻種上之方法,及(3)一種其中係將一稻種通過的鼓筒安裝在漏斗和預苗箱上方之間,並將農藥噴灑在通過鼓筒的稻種上。就農藥噴灑於小量稻種之方法,可使用其中係將稻種置於旋轉機器如灰泥攪拌機中,並將一預定劑量的農藥以適當的噴嘴均勻地噴灑在稻種上之方法。又,亦可使用其中將稻種置於稻種體積二至三倍大的塑膠袋或適當的容器中,及在加入包含亞汰尼的組成物之後,將其緊閉(就塑膠袋而言,係將袋內填滿空氣後將袋口緊閉,使整個袋子為膨脹的)、搖動和攪動,使農藥散佈至整個容器內或袋內之方法。就噴灑大量的稻種之情況而言,可在與育苗箱之播種機器相連通的運輸工具中安裝一噴嘴來噴灑農藥,且若需要可將稻種和農藥混合。 There is no particular limitation on the method of attaching the composition containing the idini to the rice seed. As for the powder coating method, for example, there is a method in which rice seeds and pesticides are placed in a rotating drum and the rice seeds are uniformly coated with the pesticide by rotating the drum. As for the method of spraying the pesticide, for example, there is (1) a method in which a pesticide is directly sprayed on a rice seed dropped by a funnel or the like by using a suitable nozzle, and (2) a flow in which a vibration is conducted. a method of attaching a funnel to a nursery box, and spraying the pesticide directly onto the rice seed using a suitable nozzle when the rice seed bounces through the board, and (3) a drum in which a rice seed is passed through the funnel Between the top of the pre-box and the pesticide, the pesticide is sprayed on the rice through the drum. In the method of spraying a small amount of rice seeds on a rice seed, a method in which the rice seeds are placed in a rotary machine such as a mortar mixer and a predetermined dose of the pesticide is uniformly sprayed on the rice seeds with a suitable nozzle can be used. In addition, it is also possible to use the rice seed in a plastic bag or a suitable container which is two to three times the volume of the rice seed, and after adding the composition containing the idini, it is tightly closed (in the case of a plastic bag) It is a method in which the bag is filled with air and the bag mouth is closed, so that the whole bag is inflated, shaken and agitated, so that the pesticide is dispersed into the entire container or in the bag. In the case of spraying a large amount of rice seeds, a nozzle may be installed in the transportation means connected to the seeding machine of the seedling box to spray the pesticide, and if necessary, the rice seed and the pesticide may be mixed.

根據另一處理稻種之方法,係將預發芽的稻種置於專門開發用來處理預發芽稻種而非乾燥稻種之種子處理機中處理。此種子處理機包括一帶有內徑之圓桶和一具有漿軸和螺旋式圍繞漿軸之斜軌的螺錐,供種子與至少一種農藥混合。此螺錐係納入圓桶內,且在螺錐之斜軌和圓桶間有一容許量。為了在處理期間不傷害其芽之情況下處理預發芽的種子(本處:混合過程),需要決定內徑與容許量之比率。較佳地,容許量和圓筒內徑之比率係設為1:10。 According to another method of treating rice seeds, the pre-germinated rice seeds are treated in a seed processor specially developed to treat pre-germinated rice species rather than dry rice seeds. The seed processor includes a drum having an inner diameter and a spiral cone having a slurry shaft and a helical ramp around the pulp shaft for mixing the seed with at least one pesticide. This spiral cone is incorporated into the drum and has a tolerance between the ramp and the drum of the spiral cone. In order to treat the pre-germinated seeds without treatment of the buds during the treatment (here: mixing process), it is necessary to determine the ratio of the inner diameter to the allowable amount. Preferably, the ratio of the allowable amount to the inner diameter of the cylinder is set to 1:10.

此種子處理機進一步係包括一用於包含至少一種農藥之桶子和一空氣壓縮機供加壓至少一種噴灑在圓筒的農藥。至少一種農藥可經由至少一噴嘴噴灑至圓筒(PCT/EP2012/058927,未公開)。 The seed processor further includes a bucket for containing at least one pesticide and an air compressor for pressurizing at least one pesticide sprayed onto the cylinder. At least one pesticide can be sprayed onto the cylinder via at least one nozzle (PCT/EP2012/058927, unpublished).

較佳的,所使用的包含亞汰尼之組成物,就乾燥種子重量而言(浸泡前稻種之重量),係在0.1至7g a.i./kg之範圍內,特別是從2至4 g a.i./kg。較佳的,就浸泡後的稻種重量或就發芽後的稻種重量而言,其係使用0.125至10g a.i./kg之範圍內,特別是從2.5至5g a.i./kg。較佳的,就稻子秧苗移栽到稻田後的單位面積而言,係使用30至180g a.i./ha之範圍,較佳地在40至140g a.i./ha之範圍,更佳地在60至120g a.i./ha之範圍,更佳地在40至80g a.i./ha之範圍,最佳地在50至70g a.i./ha之範圍。 Preferably, the composition comprising sinidin is used in the range of 0.1 to 7 g ai/kg, in particular from 2 to 4 g ai, in terms of dry seed weight (weight of rice before soaking) /kg. Preferably, the weight of the rice seed after soaking or the weight of the rice seed after germination is in the range of 0.125 to 10 g a.i./kg, especially from 2.5 to 5 g a.i./kg. Preferably, the unit area of the rice seedlings after transplanting into the rice field is in the range of 30 to 180 g ai/ha, preferably in the range of 40 to 140 g ai/ha, more preferably 60 to 120 g ai. The range of /ha is more preferably in the range of 40 to 80 g ai/ha, most preferably in the range of 50 to 70 g ai/ha.

此量遠低於一般施予稻種之農藥量。 This amount is much lower than the amount of pesticide commonly applied to rice seeds.

就稻種而言,在浸泡後和發芽前或發芽後,為較佳 的。有關稻種的浸泡方法亦無限制,且較佳的,例如以60至140℃‧天的累積溫度(例如,以13至14℃進行7至10天),讓稻種吸收足夠的水分。在浸泡處理後,將其以含亞汰尼之組成物塗抹、噴灑或諸如此類之後,僅需於育苗箱中將稻種播種、發芽並培育。就發芽後處理稻種之情況而言,例如在浸泡後,藉由塗抹或噴灑或諸如此類讓含亞汰尼之組成物附著在於20至40℃,較佳的25至35℃發芽10至30小時,較佳的20至24小時後已膨脹的稻種上。處理後將稻種播種在育苗箱(例如大小為60cm×30cm×3cm)。 In the case of rice seeds, it is preferred after soaking and before or after germination. of. The soaking method for the rice seed is also not limited, and preferably, for example, the cumulative temperature of ‧ days at 60 to 140 ° C (for example, 7 to 10 days at 13 to 14 ° C) allows the rice seed to absorb sufficient moisture. After the soaking treatment, after smearing, spraying or the like with the composition containing the idini, the rice seeds only need to be sown, germinated and cultivated in the nursery box. In the case of treating the rice seed after germination, for example, after soaking, the yttrium-containing composition is attached by smearing or spraying or the like at 20 to 40 ° C, preferably at 25 to 35 ° C for 10 to 30 hours. Preferably, the rice is expanded after 20 to 24 hours. After the treatment, the rice seeds are sown in a nursery box (for example, the size is 60 cm x 30 cm x 3 cm).

將稻種播種在育苗箱後培育稻子秧苗及覆蓋土壤、移栽秧苗至稻田以及移栽後培育稻子的方法並無特別的限制,且可採用一般習知的方法。例如,將種子覆蓋土壤後,將育苗箱放置於培育架並讓種子發芽,及然後將育苗箱移至育苗室並進一步培育。僅需要使用耕耘機及其類似物將培育的秧苗移栽到稻田中。有關將稻子移栽到稻田後的培育方法亦無限制,且稻子可依照習用的方法來培育。 The method of cultivating the rice seedlings in the seedling box, cultivating the rice seedlings, covering the soil, transplanting the seedlings to the rice fields, and cultivating the rice after transplanting is not particularly limited, and a generally known method can be employed. For example, after the seeds are covered with soil, the seedling boxes are placed on the incubator and the seeds are allowed to germinate, and then the seedling boxes are moved to the nursery room and further cultivated. It is only necessary to transplant the cultivated seedlings into the rice fields using a tiller and the like. There is no restriction on the method of cultivating the rice after transplanting it into the rice field, and the rice can be cultivated according to a conventional method.

雖然對利用本發明方法之預計疾病並無特別的限制,但此農藥可用於對抗例如,寄生粘菌綱(Plasmodiophoromycetes)、卵菌綱(Oomycetes)、結合菌綱(Zygomycetes、子囊菌綱(Ascomycetes)、擔子菌綱(Basidiomycetes)、不完全綱(Deuteromycete)s和細菌綱(Bacteria)。特言之,衍生自植物病原之疾病係選自馬鹿苗病[藤倉赤黴(Gibberella fujikuroi)]、稻熱病[稻梨孢菌 (Pyricularia oryzae)]、稻米胡麻斑病[宫部旋孢腔菌(Cochliobolus miyabeanus)]、稻紋枯病[由立枯絲核菌(Rhizoctonia solani)所引發]、稻細菌性殼枯病[由穎殼伯克氏菌(Burkholderia glumae)所引發]、稻葉枯病[由稻生黃單胞菌(Xanthomonas oryzae pv.oryzae)所引發]、稻細菌性穀枯病[莢殼伯克霍爾德氏菌(Burkholderia glumae)]和細菌性褐條病[燕麥食酸菌(Acidovorax avenae)]。特言之,可有效預防衍生自絲狀真菌及/或微生物之疾病,例如稻熱病、稻米胡麻斑病、赤黴病、稻紋枯病、稻白葉枯病和細菌性穀枯病。 Although there is no particular limitation on the intended disease using the method of the present invention, the pesticide can be used against, for example, Plasmodiophoromycetes, Oomycetes, Zygomycetes, Ascomycetes. , Basidiomycetes, Deuteromycete s, and Bacteria. In particular, the disease derived from plant pathogens is selected from the group consisting of red deer disease ( Gibberella fujikuroi ), rice fever [ Pyricularia oryzae ], rice husk disease [ Cochliobolus miyabeanus ], rice sheath blight [triggered by Rhizoctonia solani ], rice bacterial Shell blight [triggered by Burkholderia glumae ], rice leaf blight [caused by Xanthomonas oryzae pv. oryzae ], rice bacterial blight [pod shell] Burkholderia glumae and bacterial ovals ( Acidovorax avenae ). In particular, it can effectively prevent diseases derived from filamentous fungi and/or microorganisms, such as rice. Fever, rice husk , scab, rice sheath blight, rice bacterial blight and bacterial blight.

在本發明之定義中,所有的稻米蟲害可藉由本發明方法來防治。根據本發明一較佳的具體實施例,可防治的稻米蟲害係選自稻水象鼻蟲(Lissorhoptrus oryzophilus)、負泥蟲(Oulema oryzae Kuwayama)、飛蝨科(Delphacidae)、黑尾葉蟬(Nephotettix cincticeps)、稻潛葉蠅(Hydrellia griseola)(稻潛葉蠅)、單帶挵蝶(Parnara guttata)(稻包蟲)、稻螟蛉夜蛾(Naranga aenescens Moore)、瘤野螟(Cnaphalocrocis medinalis)、二化螟(Chilo suppressalis)和稻薊馬(Stenchaetothrips biformis)(稻薊馬)。 In the definition of the invention, all rice pests can be controlled by the method of the invention. According to a preferred embodiment of the present invention, the controllable rice pest is selected from the group consisting of Lissorhoptrus oryzophilus , Oulema oryzae Kuwayama , Delphacidae , and Black-tailed spider mites ( N ephotettix cincticeps ), Hydrellia griseola (rice leaf miner), Parnara guttata (rice worm), Naranga aenescens Moore , Cnaphalocrocis medinalis ), Chilo suppressalis and Stenchaetothrips biformis (rice horse ).

係以下列實例為基礎來說明本發明。 The invention is illustrated on the basis of the following examples.

實例1Example 1

將稻種以一方法作種子處理,其中發芽的稻種(已膨 脹)係藉由將乾燥種子浸泡處理所得來,及將每1 kg乾稻種含3g的活性成份(亞汰尼)之調配物(水性懸浮液組成物係由亞汰尼:約20重量份,界面活性劑(三苯乙烯基苯酚):約1重量份,丙烯酸樹脂:約3重量份,以丙二醇作為稀釋劑:10重量份,其他添加劑(消泡劑、防腐劑、增稠劑及其類似物):總計5重量份或更低而其於的份量為水)放入依塑膠袋中並充分混合。接著,將150g的稻種(就乾稻種重量而言)播種到每個育苗箱中(60cm×30cm×3cm)並立刻覆蓋土壤。將種子覆蓋土壤後,將育苗箱放到育苗架上並於30℃放置3天。出芽後,將育苗箱移至育苗室並根據習用方法使其綠化及培育。將培育的秧苗以機械移栽(約2.5發葉期),每10a 20箱(亦即每0.1 ha 20箱)。根據當地習用的方法進行施肥管理及諸如此類。 The rice seed is treated as a seed by a method in which the germinated rice seed (expanded) The swelling is obtained by soaking the dried seeds, and containing 3 g of the active ingredient (denidini) per 1 kg of dry rice (the aqueous suspension composition is from the nitidine: about 20 parts by weight) , surfactant (tristyrylphenol): about 1 part by weight, acrylic resin: about 3 parts by weight, using propylene glycol as a diluent: 10 parts by weight, other additives (antifoaming agent, preservative, thickener and The analogs: a total of 5 parts by weight or less and the portion thereof is water) are placed in a plastic bag and thoroughly mixed. Next, 150 g of rice seeds (in terms of dry rice weight) were sown into each seedling box (60 cm x 30 cm x 3 cm) and immediately covered with soil. After the seeds were covered with soil, the nursery boxes were placed on a nursery rack and placed at 30 ° C for 3 days. After budding, the nursery box is moved to the nursery room and greened and cultivated according to conventional methods. The cultivated seedlings were mechanically transplanted (about 2.5 leaf stage), 20 boxes per 10a (that is, 20 boxes per 0.1 ha). Fertilization management and the like according to local practices.

實例2Example 2

根據實例中之相同條件製備稻子樣本,但是係使用每1 kg乾稻種具有6 g活性成份之相同調配物。 A rice sample was prepared according to the same conditions as in the examples, but using the same formulation having 6 g of active ingredient per 1 kg of dry rice.

比較性實例1Comparative example 1

於如同實例1之相同條件下製備稻子樣本,但不使用亞汰尼調配物。 A rice sample was prepared under the same conditions as in Example 1, but without the use of a nitidine formulation.

比較性實例2Comparative example 2

於生長箱上施予一調配物(含2%亞汰尼之顆粒組成物)取代種子處理來製備稻子樣本。即,將2.2 L的培養土放入育苗箱中並將1 L的水灌溉到培養土上,及接著播種150g的種子(就乾稻種重量而言),然後於每箱均勻 地噴灑50g的該調配物並立刻將培養箱覆蓋土攘。在種子覆蓋上土壤後,將培養箱放置在培養架上並於其上以30℃放置3天。出芽後,將育苗箱移至育苗室並根據習用方法使其綠化及培育。將培育的秧苗以機械移栽(約2.5發葉期),每10a 20箱(亦即每0.1 ha 20箱)。根據當地習用的方法進行施肥管理及諸如此類。 A rice sample was prepared by applying a formulation (containing 2% of the arsenic particle composition) on the growth chamber instead of seed treatment. That is, 2.2 L of the culture soil was placed in a nursery box and 1 L of water was irrigated onto the culture soil, and then 150 g of seeds (in terms of dry rice weight) were sown, and then uniformly distributed in each box. 50 g of this formulation was sprayed and the incubator was immediately covered with soil. After the seeds were covered with soil, the incubator was placed on a culture rack and placed thereon at 30 ° C for 3 days. After budding, the nursery box is moved to the nursery room and greened and cultivated according to conventional methods. The cultivated seedlings were mechanically transplanted (about 2.5 leaf stage), 20 boxes per 10a (that is, 20 boxes per 0.1 ha). Fertilization management and the like according to local practices.

疾病症狀之試驗Test of disease symptoms

實例1、實例2和比較性實例2之稻子樣本中的稻熱病疾病預防係於移栽53天、67天和80天後,使用比較性實例1之稻子樣本作為標準來檢測。根據下列公式計算疾病預防值。 The rice fever disease prevention in the rice samples of Example 1, Example 2, and Comparative Example 2 was detected using the rice sample of Comparative Example 1 as a standard after 53 days, 67 days, and 80 days of transplanting. The disease prevention value is calculated according to the following formula.

疾病預防值=100-(經處理的稻子組中疾病的發生率/未處理的稻子組中疾病的發生率)×100 Disease prevention value = 100 - (incidence of disease in treated rice group / incidence of disease in untreated rice group) × 100

疾病的發生率: The incidence of disease:

0 無葉子病斑 0 leafless lesions

0.2 在一稻子植栽中約10處葉斑(下部葉片型) 0.2 About 10 leaf spots in a rice plant (lower leaf type)

0.5 植栽的葉斑面積比率低於1% 0.5 plant leaf area ratio is less than 1%

1 植栽的葉斑面積比率為1至5% 1 Planting leaf spot area ratio is 1 to 5%

2 植栽的葉斑面積比率低於5%及至高10% 2 Plant leaf area ratio is less than 5% and up to 10%

3 植栽的葉斑面積比率高於10%及至高20% 3 Plant leaf area ratio is higher than 10% and up to 20%

4 植栽的葉斑面積比率高於20%及至高40% 4 Plant leaf area ratio is higher than 20% and up to 40%

5 植栽的葉斑面積比率高於40%及至高80% 5 Plant leaf area ratio is higher than 40% and up to 80%

6 植栽的葉斑面積比率高於80% 6 Planting leaf spot area ratio is higher than 80%

基於疾病預防值驗測之結果,對抗稻熱病之疾病預防效用係評斷為5級: 0:預防值為0(相當於位處理組),1:預防值為1至20,2:預防值為21至40,3:預防值為41至60,4:預防值為61至80,5:預防值為81至100)。 Based on the results of the disease prevention value test, the disease prevention utility against rice fever is judged to be 5: 0: The prevention value is 0 (equivalent to the treatment group), 1: the prevention value is 1 to 20, 2: the prevention value is 21 to 40, 3: the prevention value is 41 to 60, and 4: the prevention value is 61 to 80, 5: The prevention value is 81 to 100).

結果係如表1所示(a.i.:活性成份)。 The results are shown in Table 1 (a.i.: active ingredient).

如表1之結果所示,在播種於育苗箱前稻種之種子處理的疾病預防效用顯示極度的優勢,僅使用一半量之調配物(15ml/kg種子)而具有相當播種中處理之效用,即 使是在移栽80天後。就此結果,認為相較於在播種時處理之習用處理方法,以此法可更有效地利用農藥,且本方法產生高度的疾病預防效用。 As shown by the results in Table 1, the disease prevention effect of seed treatment of rice seeds before seeding in the nursery box showed an extreme advantage, using only half the amount of the formulation (15 ml/kg seed) and having the effect of treatment in the sowing. which is It was 80 days after transplanting. As a result of this, it is considered that the method can utilize the pesticide more effectively than the conventional treatment method at the time of seeding, and the method produces a high degree of disease prevention effect.

實例1-2Example 1-2

根據實例1中之相同條件製備稻子樣本,但是係使用每1 kg乾稻種具有2 g活性成份之相同調配物。 A rice sample was prepared according to the same conditions as in Example 1, except that the same formulation having 2 g of active ingredient per 1 kg of dry rice species was used.

實例2-2Example 2-2

根據實例1中之相同條件製備稻子樣本並同樣使用每1 kg乾稻種具有3 g活性成份之相同調配物。 A rice sample was prepared according to the same conditions as in Example 1 and the same formulation having 3 g of active ingredient per 1 kg of dry rice species was also used.

實例3-2Example 3-2

根據實例1中之相同條件製備稻子樣本,但是係使用每1 kg乾稻種具有4 g活性成份之相同調配物。 A rice sample was prepared according to the same conditions as in Example 1, except that the same formulation having 4 g of active ingredient per 1 kg of dry rice was used.

實例4-2Example 4-2

根據實例2中之相同條件製備稻子樣本並同樣使用每1 kg乾稻種具有6 g活性成份之相同調配物。 A rice sample was prepared according to the same conditions as in Example 2 and the same formulation having 6 g of active ingredient per 1 kg of dry rice species was also used.

比較性實例1-2和2-2Comparative Examples 1-2 and 2-2

所有的條件分別與實例1和2相同。 All conditions are the same as in Examples 1 and 2, respectively.

表2之疾病症狀試驗Table 2 disease symptom test

實例1-2、實例2-2、實例3-2、實例4-2和比較性實例實例2-2之稻子樣本中的稻熱病疾病預防係於移栽66天和80天後,使用比較性實例1-2之稻子樣本(未處理稻子組)作為標準來檢測。疾病預防值係根據該疾病症試驗之相同公式來計算。 Example 1-2, Example 2-2, Example 3-2, Example 4-2, and Comparative Example The rice fever disease prevention in the rice sample of Example 2-2 was compared after 66 days and 80 days of transplanting. The rice samples of Example 1-2 (untreated rice group) were tested as a standard. The disease prevention value is calculated according to the same formula of the disease test.

[表2] [Table 2]

如表2之結果所示,在播種於育苗箱前稻種之種子處理的疾病預防效用顯示極度的優勢,僅使用低於三分之一量的調配物(10ml/kg種子)而具有相當播種中處理之效用,即使是在移栽80天後。就此結果,認為,相較於在播種時處理之習用處理方法,以此法可更有效地利用農藥,且本方法產生高度的疾病預防效用。 As shown by the results in Table 2, the disease prevention effect of seed treatment of rice seeds before seeding in the nursery box showed an extreme advantage, using only less than one-third of the formulation (10 ml/kg seed) with considerable sowing. The effect of the middle treatment, even after 80 days of transplanting. From this result, it is considered that the pesticide can be more effectively utilized by this method than the conventional treatment method at the time of seeding, and the method produces a high degree of disease prevention effect.

Claims (11)

一種含亞汰尼(isotianil)之組成物於稻田之移栽稻米中預防疾病及/或防治動物蟲害之用途,其中該組成物包含亞汰尼(isotianil)作為唯一活性成份,且在稻種播種至育苗箱之前附著於其上,且其中該包含亞汰尼之組成物係以30至180g a.i./ha範圍內之活性成份量方式來使用。 Use of an isotianil-containing composition for preventing disease and/or controlling animal pests in rice transplanted rice fields, wherein the composition comprises isotianil as the sole active ingredient and is planted in rice seeds It is attached to the seedling box before it, and the composition containing the idini is used in an amount of the active ingredient in the range of 30 to 180 g ai/ha. 如申請專利範圍第1項之用途,其中該活性成份之量係在40至140g a.i./ha之範圍內。 The use of the first item of the patent application, wherein the amount of the active ingredient is in the range of 40 to 140 g a.i./ha. 如申請專利範圍第1或2項之用途,其中該稻種為該等浸泡後和發芽前或該等發芽後之稻種。 The use of the first or second aspect of the patent application, wherein the rice seed is the rice seed after the soaking and before or after the germination. 如申請專利範圍第1或2項之用途,其中該組成物為包括亞汰尼、界面活性劑、有機溶劑和聚合物樹脂之水性懸浮液組成物。 The use of claim 1 or 2, wherein the composition is an aqueous suspension composition comprising diatrines, a surfactant, an organic solvent, and a polymer resin. 如申請專利範圍第1或2項之用途,其中在移栽後53天或更多天,仍觀察到疾病預防及/或防治動物蟲害。 For the use of claim 1 or 2, wherein disease prevention and/or control of animal pests is still observed 53 days or more after transplanting. 如申請專利範圍第1或2項之用途,其中該用途係用於預防疾病。 The use of claim 1 or 2, wherein the use is for the prevention of a disease. 如申請專利範圍第1或2項之用途,其中該疾病係由絲狀真菌及/或微生物所引發。 The use of claim 1 or 2 wherein the disease is caused by a filamentous fungus and/or microorganism. 如申請專利範圍第1或2項之用途,其中該疾病係選自稻熱病、稻米胡麻斑病或赤黴病、稻紋枯病、稻葉枯病及稻細菌性殼枯病。 The use of the first or second aspect of the patent application, wherein the disease is selected from the group consisting of rice fever, rice leaf spot or scab, rice sheath blight, rice leaf blight and rice bacterial shell blight. 如申請專利範圍第8項之用途,其中該稻熱病由稻梨孢菌(Pyricularia oryzae)所引發,該稻米胡麻斑病或赤黴病由宫部旋孢腔菌(Cochliobolus miyabeanus)所引發,該稻紋枯病由立枯絲核菌(Rhizoctonia solani)所引發,該稻葉枯病由稻生黃單胞菌(Xanthomonas oryzae pv.oryzae)所引發,及該稻細菌性殼枯病由穎殼伯克氏菌(Burkholderia glumae)所引發。 The use of the eighth aspect of the patent application, wherein the rice fever is caused by Pyricularia oryzae , which is caused by Cochliobolus miyabeanus , which is caused by Rice sheath blight is caused by Rhizoctonia solani , which is caused by Xanthomonas oryzae pv. oryzae , and the bacterial blight of the rice is covered by the shell Initiated by Burkholderia glumae . 如申請專利範圍第1或2項之用途,其中該用途係用於防治動物蟲害。 The use of the first or second aspect of the patent application, wherein the use is for controlling animal pests. 如申請專利範圍第1或2項中任一項之用途,其中該動物蟲害係選自稻水象鼻蟲(Lissorhoptrus oryzophilus)、負泥蟲(Oulema oryzae Kuwayama)、飛蝨科(Delphacidae)、黑尾葉蟬(Nephotettix cincticeps)、稻潛葉蠅(Hydrellia griseola)、單帶挵蝶(Parnara guttata)、稻螟蛉夜蛾(Naranga aenescens Moore)、瘤野螟(Cnaphalocrocis medinalis)、二化螟(Chilo suppressalis)和稻薊馬(Stenchaetothrips biformis)。 The use of any one of claims 1 or 2, wherein the animal pest is selected from the group consisting of Lissorhoptrus oryzophilus , Oulema oryzae Kuwayama , Delphacidae , black. Nephotettix cincticeps , Hydrellia griseola , Parnara guttata , Naranga aenescens Moore , Cnaphalocrocis medinalis , Chilo suppressalis ) and the scorpion horse ( Stenchaetothrips biformis ).
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