TWI398543B - 使用β-二酮亞胺金屬化合物之原子層沉積系統及方法 - Google Patents

使用β-二酮亞胺金屬化合物之原子層沉積系統及方法 Download PDF

Info

Publication number
TWI398543B
TWI398543B TW095120255A TW95120255A TWI398543B TW I398543 B TWI398543 B TW I398543B TW 095120255 A TW095120255 A TW 095120255A TW 95120255 A TW95120255 A TW 95120255A TW I398543 B TWI398543 B TW I398543B
Authority
TW
Taiwan
Prior art keywords
metal
group
formula
substrate
compound
Prior art date
Application number
TW095120255A
Other languages
English (en)
Chinese (zh)
Other versions
TW200704814A (en
Inventor
奎克 提蒙希
Original Assignee
美光科技公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 美光科技公司 filed Critical 美光科技公司
Publication of TW200704814A publication Critical patent/TW200704814A/zh
Application granted granted Critical
Publication of TWI398543B publication Critical patent/TWI398543B/zh

Links

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/63—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the formation processes
    • H10P14/6326—Deposition processes
    • H10P14/6328—Deposition from the gas or vapour phase
    • H10P14/6334—Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H10P14/6339—Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE or pulsed CVD
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40—Oxides
    • C23C16/409—Oxides of the type ABO3 with A representing alkali, alkaline earth metal or lead and B representing a refractory metal, nickel, scandium or a lanthanide
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
    • C23C16/45531—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations specially adapted for making ternary or higher compositions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C23C16/45525—Atomic layer deposition [ALD]
    • C23C16/45553—Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69—Inorganic materials
    • H10P14/692—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6938—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides
    • H10P14/69398—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides the material having a perovskite structure, e.g. BaTiO3
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69—Inorganic materials
    • H10P14/692—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6938—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides
    • H10P14/6939—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
    • H10P14/69—Inorganic materials
    • H10P14/692—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
    • H10P14/6938—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides
    • H10P14/6939—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal
    • H10P14/69397—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses the material containing at least one metal element, e.g. metal oxides, metal oxynitrides or metal oxycarbides characterised by the metal the material containing two or more metal elements

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Vapour Deposition (AREA)
  • Formation Of Insulating Films (AREA)
  • Pyridine Compounds (AREA)
  • Semiconductor Memories (AREA)
TW095120255A 2005-06-28 2006-06-07 使用β-二酮亞胺金屬化合物之原子層沉積系統及方法 TWI398543B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/168,160 US7416994B2 (en) 2005-06-28 2005-06-28 Atomic layer deposition systems and methods including metal beta-diketiminate compounds

Publications (2)

Publication Number Publication Date
TW200704814A TW200704814A (en) 2007-02-01
TWI398543B true TWI398543B (zh) 2013-06-11

Family

ID=37338887

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095120255A TWI398543B (zh) 2005-06-28 2006-06-07 使用β-二酮亞胺金屬化合物之原子層沉積系統及方法

Country Status (8)

Country Link
US (3) US7416994B2 (enExample)
EP (2) EP2290126B1 (enExample)
JP (1) JP5003978B2 (enExample)
KR (1) KR101274330B1 (enExample)
CN (1) CN101208456A (enExample)
AT (1) ATE509134T1 (enExample)
TW (1) TWI398543B (enExample)
WO (1) WO2007002672A2 (enExample)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7544398B1 (en) * 2005-04-26 2009-06-09 The Regents Of The Univesity Of California Controlled nano-doping of ultra thin films
US7572731B2 (en) * 2005-06-28 2009-08-11 Micron Technology, Inc. Unsymmetrical ligand sources, reduced symmetry metal-containing compounds, and systems and methods including same
US7439338B2 (en) * 2005-06-28 2008-10-21 Micron Technology, Inc. Beta-diketiminate ligand sources and metal-containing compounds thereof, and systems and methods including same
US7416994B2 (en) * 2005-06-28 2008-08-26 Micron Technology, Inc. Atomic layer deposition systems and methods including metal beta-diketiminate compounds
DE102005033579A1 (de) * 2005-07-19 2007-01-25 H.C. Starck Gmbh Verfahren zur Herstellung dünner Hafnium- oder Zirkonnitrid-Schichten
JP4708905B2 (ja) * 2005-08-05 2011-06-22 イビデン株式会社 薄膜エンベディッドキャパシタンス、その製造方法、及びプリント配線板
US8524931B2 (en) * 2007-01-17 2013-09-03 Advanced Technology Materials, Inc. Precursor compositions for ALD/CVD of group II ruthenate thin films
US7892964B2 (en) 2007-02-14 2011-02-22 Micron Technology, Inc. Vapor deposition methods for forming a metal-containing layer on a substrate
JP5248025B2 (ja) * 2007-03-01 2013-07-31 東京エレクトロン株式会社 SrTiO3膜の成膜方法およびコンピュータ読取可能な記憶媒体
WO2009012341A2 (en) * 2007-07-16 2009-01-22 Advancaed Technology Materials, Inc. Group iv complexes as cvd and ald precursors for forming metal-containing thin films
US7928019B2 (en) * 2007-08-10 2011-04-19 Micron Technology, Inc. Semiconductor processing
KR101200577B1 (ko) * 2007-09-04 2012-11-12 엘피다 메모리 가부시키가이샤 Sr-Ti-O계 막의 성막 방법 및 기억 매체
WO2009086263A1 (en) * 2007-12-28 2009-07-09 Sigma-Aldrich Co. Methods for preparing thin films using substituted pyrrolyl-metal precursors
US20100003532A1 (en) * 2008-06-06 2010-01-07 Feist Benjamin J Beta-diketiminate precursors for metal containing film deposition
US8471049B2 (en) * 2008-12-10 2013-06-25 Air Product And Chemicals, Inc. Precursors for depositing group 4 metal-containing films
CA2653581A1 (en) 2009-02-11 2010-08-11 Kenneth Scott Alexander Butcher Migration and plasma enhanced chemical vapour deposition
US8663735B2 (en) * 2009-02-13 2014-03-04 Advanced Technology Materials, Inc. In situ generation of RuO4 for ALD of Ru and Ru related materials
US8003521B2 (en) * 2009-04-07 2011-08-23 Micron Technology, Inc. Semiconductor processing
US7939442B2 (en) * 2009-04-10 2011-05-10 Micron Technology, Inc. Strontium ruthenium oxide interface
US8697486B2 (en) 2009-04-15 2014-04-15 Micro Technology, Inc. Methods of forming phase change materials and methods of forming phase change memory circuitry
JP2012124322A (ja) * 2010-12-08 2012-06-28 Elpida Memory Inc 半導体記憶装置の製造方法
KR101721294B1 (ko) * 2011-04-06 2017-03-29 레르 리키드 쏘시에떼 아노님 뿌르 레드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 증착을 위한 하프늄-함유 또는 지르코늄-함유 전구체
TWI586828B (zh) * 2012-02-10 2017-06-11 財團法人國家同步輻射研究中心 原子層沈積之摻雜方法
KR102168174B1 (ko) 2014-03-19 2020-10-20 삼성전자주식회사 니켈 화합물 및 이를 이용한 박막 형성 방법
KR102282139B1 (ko) * 2015-05-12 2021-07-28 삼성전자주식회사 반도체 장치
CN113652672B (zh) 2015-05-27 2023-12-22 Asm Ip 控股有限公司 用于含钼或钨薄膜的ald的前体的合成和用途
US10662527B2 (en) 2016-06-01 2020-05-26 Asm Ip Holding B.V. Manifolds for uniform vapor deposition
US10358407B2 (en) 2016-10-12 2019-07-23 Asm Ip Holding B.V. Synthesis and use of precursors for vapor deposition of tungsten containing thin films
CN109402608B (zh) * 2017-08-16 2020-12-08 北京北方华创微电子装备有限公司 一种原子层沉积设备的气路系统及其控制方法
US11492701B2 (en) 2019-03-19 2022-11-08 Asm Ip Holding B.V. Reactor manifolds
US12516414B2 (en) 2019-03-19 2026-01-06 Asm Ip Holding B.V. Reactor manifolds
US12249189B2 (en) 2019-08-12 2025-03-11 Micron Technology, Inc. Predictive maintenance of automotive lighting
US11155209B2 (en) * 2019-08-22 2021-10-26 Micron Technology, Inc. Virtual mirror with automatic zoom based on vehicle sensors
US12210401B2 (en) 2019-09-05 2025-01-28 Micron Technology, Inc. Temperature based optimization of data storage operations
KR20210048408A (ko) 2019-10-22 2021-05-03 에이에스엠 아이피 홀딩 비.브이. 반도체 증착 반응기 매니폴드
WO2021085210A1 (ja) 2019-11-01 2021-05-06 株式会社Adeka 新規化合物、該化合物を含有する薄膜形成用原料及び薄膜の製造方法
US11250648B2 (en) 2019-12-18 2022-02-15 Micron Technology, Inc. Predictive maintenance of automotive transmission
TWI865725B (zh) 2020-02-10 2024-12-11 荷蘭商Asm Ip私人控股有限公司 高深寬比孔內的氧化鉿之沉積
KR102879479B1 (ko) * 2020-06-15 2025-10-30 에스케이트리켐 주식회사 란탄족 전구체 및 이를 이용한 란탄족 함유 박막 및 상기 박막의 형성 방법 및 상기 란탄족 함유 박막을 포함하는 반도체 소자.
TWI918669B (zh) 2020-06-24 2026-03-21 荷蘭商Asm Ip私人控股有限公司 含鉬薄膜的氣相沉積
KR102898793B1 (ko) * 2020-06-24 2025-12-18 솔브레인 주식회사 박막 형성용 프리커서, 이의 제조방법 및 이를 포함하는 박막 제조 방법
KR20230009793A (ko) 2021-07-09 2023-01-17 삼성전자주식회사 이트륨 화합물과 이를 이용한 집적회로 소자의 제조 방법
KR20230106992A (ko) 2022-01-07 2023-07-14 삼성전자주식회사 박막 제조용 조성물 및 이를 이용한 반도체 장치 제조 방법
CN117904593B (zh) * 2024-03-15 2024-05-17 上海谱俊科技有限公司 金属工件、金属表面复合涂层及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020187578A1 (en) * 2001-06-12 2002-12-12 Kwon Hong Method for manufacturing memory device

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4202889C2 (de) 1992-02-01 1994-12-15 Solvay Deutschland Verfahren zur Abscheidung von ein Metall der ersten Übergangsmetallreihe oder Aluminium enthaltenden Schichten und 1,3-Diketiminato-Metall-Verbindungen
US5256244A (en) * 1992-02-10 1993-10-26 General Electric Company Production of diffuse reflective coatings by atomic layer epitaxy
US5972430A (en) 1997-11-26 1999-10-26 Advanced Technology Materials, Inc. Digital chemical vapor deposition (CVD) method for forming a multi-component oxide layer
US6225237B1 (en) * 1998-09-01 2001-05-01 Micron Technology, Inc. Method for forming metal-containing films using metal complexes with chelating O- and/or N-donor ligands
KR100418569B1 (ko) 2001-12-10 2004-02-14 주식회사 하이닉스반도체 단원자층증착을 이용한 고유전체 박막 형성방법
JP2003209317A (ja) * 2002-01-11 2003-07-25 Oki Electric Ind Co Ltd 半導体レーザモジュール
US6939578B2 (en) * 2002-01-18 2005-09-06 E. I. Du Pont De Nemours And Company Volatile copper(II) complexes for deposition of copper films by atomic layer deposition
GB0201141D0 (en) * 2002-01-18 2002-03-06 Ic Innovations Ltd Coordination complex
JP3670628B2 (ja) * 2002-06-20 2005-07-13 株式会社東芝 成膜方法、成膜装置、および半導体装置の製造方法
US20040247905A1 (en) * 2003-04-16 2004-12-09 Bradley Alexander Zak Volatile copper(I) complexes for deposition of copper films by atomic layer deposition
US20050227007A1 (en) * 2004-04-08 2005-10-13 Bradley Alexander Z Volatile copper(I) complexes for deposition of copper films by atomic layer deposition
JP2007511902A (ja) * 2003-10-29 2007-05-10 エーエスエム アメリカ インコーポレイテッド 薄膜成長用反応装置
US7439338B2 (en) 2005-06-28 2008-10-21 Micron Technology, Inc. Beta-diketiminate ligand sources and metal-containing compounds thereof, and systems and methods including same
US7416994B2 (en) 2005-06-28 2008-08-26 Micron Technology, Inc. Atomic layer deposition systems and methods including metal beta-diketiminate compounds
US7572731B2 (en) 2005-06-28 2009-08-11 Micron Technology, Inc. Unsymmetrical ligand sources, reduced symmetry metal-containing compounds, and systems and methods including same
US7892358B2 (en) * 2006-03-29 2011-02-22 Tokyo Electron Limited System for introducing a precursor gas to a vapor deposition system

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020187578A1 (en) * 2001-06-12 2002-12-12 Kwon Hong Method for manufacturing memory device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Hani M.EI-Kaderi et al.,"Synthesis, Structure, and Ligand Redistribution Equilibria of Mixed Ligand Complexes of the Heavier Group 2 Elements Containing Pyrazolato and beta-Diketiminato Ligands", Eur. J. Inorg. Chem., 11, 2005, 2081-2088 *

Also Published As

Publication number Publication date
US8188464B2 (en) 2012-05-29
WO2007002672A3 (en) 2007-02-22
EP2290126A2 (en) 2011-03-02
US20060292841A1 (en) 2006-12-28
EP1907600B1 (en) 2011-05-11
JP5003978B2 (ja) 2012-08-22
WO2007002672A9 (en) 2008-09-18
KR101274330B1 (ko) 2013-06-13
ATE509134T1 (de) 2011-05-15
EP2290126A3 (en) 2011-10-12
TW200704814A (en) 2007-02-01
US7416994B2 (en) 2008-08-26
WO2007002672A2 (en) 2007-01-04
US20100186668A1 (en) 2010-07-29
JP2008545277A (ja) 2008-12-11
US7709399B2 (en) 2010-05-04
EP1907600A2 (en) 2008-04-09
CN101208456A (zh) 2008-06-25
KR20080021709A (ko) 2008-03-07
EP2290126B1 (en) 2014-02-12
US20080280455A1 (en) 2008-11-13

Similar Documents

Publication Publication Date Title
JP5003978B2 (ja) アルカリ土類金属β‐ジケチミナート前駆体を用いた原子層堆積
US7892964B2 (en) Vapor deposition methods for forming a metal-containing layer on a substrate
US7576378B2 (en) Systems and methods for forming metal oxides using metal diketonates and/or ketoimines
US6958300B2 (en) Systems and methods for forming metal oxides using metal organo-amines and metal organo-oxides
US6984592B2 (en) Systems and methods for forming metal-doped alumina
CN101208295B (zh) 不对称配体源、降低对称性的含金属化合物以及包含其的系统和方法
US20060040480A1 (en) Systems and methods for forming niobium and/or vanadium containing layers using atomic layer deposition

Legal Events

Date Code Title Description
MK4A Expiration of patent term of an invention patent