TWI366485B - Continuous process for the preparation of phenol from benzene in a fixed bed reactor - Google Patents

Continuous process for the preparation of phenol from benzene in a fixed bed reactor

Info

Publication number
TWI366485B
TWI366485B TW094138738A TW94138738A TWI366485B TW I366485 B TWI366485 B TW I366485B TW 094138738 A TW094138738 A TW 094138738A TW 94138738 A TW94138738 A TW 94138738A TW I366485 B TWI366485 B TW I366485B
Authority
TW
Taiwan
Prior art keywords
phenol
benzene
preparation
bed reactor
fixed bed
Prior art date
Application number
TW094138738A
Other languages
English (en)
Other versions
TW200626240A (en
Inventor
Daniele Bianchi
Rossella Bortolo
Chiara Busto
Carla Lazzari
Original Assignee
Polimeri Europa Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polimeri Europa Spa filed Critical Polimeri Europa Spa
Publication of TW200626240A publication Critical patent/TW200626240A/zh
Application granted granted Critical
Publication of TWI366485B publication Critical patent/TWI366485B/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW094138738A 2004-11-12 2005-11-04 Continuous process for the preparation of phenol from benzene in a fixed bed reactor TWI366485B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT002169A ITMI20042169A1 (it) 2004-11-12 2004-11-12 Processo continuo per la preparazione di fenolo da benzene in reattore a letto fisso

Publications (2)

Publication Number Publication Date
TW200626240A TW200626240A (en) 2006-08-01
TWI366485B true TWI366485B (en) 2012-06-21

Family

ID=34956456

Family Applications (1)

Application Number Title Priority Date Filing Date
TW094138738A TWI366485B (en) 2004-11-12 2005-11-04 Continuous process for the preparation of phenol from benzene in a fixed bed reactor

Country Status (11)

Country Link
US (2) US7759529B2 (zh)
EP (1) EP1814836B1 (zh)
JP (1) JP5185623B2 (zh)
KR (1) KR101217973B1 (zh)
CN (1) CN101039893B (zh)
DK (1) DK1814836T3 (zh)
EA (1) EA011767B1 (zh)
ES (1) ES2547243T3 (zh)
IT (1) ITMI20042169A1 (zh)
TW (1) TWI366485B (zh)
WO (1) WO2006050827A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101434515B (zh) * 2007-11-15 2012-10-10 中国石油化工股份有限公司 一种苯酚的制备方法
FR2971783B1 (fr) * 2011-02-17 2013-02-15 Rhodia Operations Procede d'hydroxylation de phenols et d'ethers de phenols
CN106966872B (zh) * 2016-01-13 2020-11-13 中国石油化工股份有限公司 一种芳烃氧化方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4147726A (en) * 1976-11-08 1979-04-03 Phillips Petroleum Company Acid-catalyzed hydrolysis of organic hydroperoxide employing a polar solvent and phenol as reaction medium
JPH02298350A (ja) * 1989-05-15 1990-12-10 Tosoh Corp 芳香族化合物のヒドロキシル化反応用触媒
US5214168A (en) * 1992-04-30 1993-05-25 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5233097A (en) * 1992-10-15 1993-08-03 Uop Oxidation of aromatics to hydroxyaromatics using aluminosilicates containing framework titanium
JPH08504125A (ja) * 1992-12-03 1996-05-07 ロイナ − カタリザトレン ゲゼルシャフト ミット ベシュレンクテル ハフツング 酸化触媒
SE9600970D0 (sv) * 1996-03-14 1996-03-14 Johan Sterte Förfarande för framställning av mycket tunna filmer av molekylsiktar
IT1289989B1 (it) * 1997-02-27 1998-10-19 Enichem Spa Processo per l'idrossilazione di idrocarburi aromatici
IT1296573B1 (it) * 1997-11-27 1999-07-14 Enichem Spa Procedimento per l'ossidazione di composti aromatici a idrossiaromatici
JP3072348B2 (ja) * 1997-12-16 2000-07-31 工業技術院長 低級オレフィンの製造方法
JP2952409B2 (ja) * 1998-03-09 1999-09-27 工業技術院長 低級オレフィン製造用触媒
EP0958861B1 (en) * 1998-05-19 2002-06-05 Polimeri Europa S.r.l. Activation method of titanium silicalite and its use in oxidation processes with hydrogen peroxide
DE19835907A1 (de) * 1998-08-07 2000-02-17 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
US7150994B2 (en) * 1999-03-03 2006-12-19 Symyx Technologies, Inc. Parallel flow process optimization reactor
IT1314189B1 (it) * 1999-10-18 2002-12-06 Enichem Spa Procedimento per la rigenerazione di catalizzatori zeoliticicontenenti titanio
CN1132699C (zh) * 1999-12-24 2003-12-31 中国石油化工集团公司 一种钛硅分子筛及其制备方法
ITMI20012410A1 (it) * 2001-11-15 2003-05-15 Enichem Spa Processo per la preparazione di composti aromatici idrossilati
ITMI20021187A1 (it) * 2002-05-31 2003-12-01 Polimeri Europa Spa Procedimento per il recupero di fenolo e difenoli
ITMI20022522A1 (it) * 2002-11-28 2004-05-29 Polimeri Europa Spa Processo integrato per la preparazione di fenolo da benzene con riciclo dei sottoprodotti.

Also Published As

Publication number Publication date
EP1814836B1 (en) 2015-06-17
JP2008519782A (ja) 2008-06-12
EP1814836A1 (en) 2007-08-08
WO2006050827A1 (en) 2006-05-18
EA011767B1 (ru) 2009-06-30
TW200626240A (en) 2006-08-01
US8563461B2 (en) 2013-10-22
US7759529B2 (en) 2010-07-20
DK1814836T3 (en) 2015-09-14
JP5185623B2 (ja) 2013-04-17
ITMI20042169A1 (it) 2005-02-12
ES2547243T3 (es) 2015-10-02
CN101039893A (zh) 2007-09-19
US20070255078A1 (en) 2007-11-01
CN101039893B (zh) 2010-05-12
KR20070084058A (ko) 2007-08-24
US20100184593A1 (en) 2010-07-22
EA200700628A1 (ru) 2007-12-28
KR101217973B1 (ko) 2013-01-02

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Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees