TWI355897B - - Google Patents
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- TWI355897B TWI355897B TW095109461A TW95109461A TWI355897B TW I355897 B TWI355897 B TW I355897B TW 095109461 A TW095109461 A TW 095109461A TW 95109461 A TW95109461 A TW 95109461A TW I355897 B TWI355897 B TW I355897B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
(4) 1355897 . 絹雲母、石英、硫黃、活性碳、碳酸鈣、矽藻土、輕石、 方解石、海泡石、白雲石 '二氧化矽、氧化鋁、蛭石、珠 層鐵等天然或合成鑛物物、大鋸屑、玉米之穗軸、椰子之 實殼、煙香基等細粒、明膠、凡士林、甲基纖維、含水羊 毛脂、及豬油例。 做爲液體載體例者如:二甲苯、甲苯 '烷基萘、苯基 二甲苯基乙烷、煤油、輕油、己烷、環己烷、流動石蠟, 4^等芳香族或脂肪族烴基、氯苯、二氯乙烷、二氯甲烷、三 氯乙烷等鹵化烴、甲醇、乙醇、異丙醇、丁醇、己醇、苄 醇 '乙二醇等醇、二乙醚、乙二醇二甲醚、二乙二醇單甲 醚、二乙二醇單乙醚、丙二醇單甲醚、四氫呋喃、1,4一 二氧陸圜等醚、乙酸乙酯、乙酸丁酯等酯、丙嗣、丁酮、 甲基異丁酮、環己酮等酮、乙腈、異丁腈等腈、碳酸丙烯 酯等之碳酸伸烷酯、二甲亞颯等亞颯、Ν,Ν _二甲基甲醯 胺、Ν,Ν-二甲基乙醯胺、Ν -甲基一2 -吡咯烷、Ν -乙 ^ 基一 2_吡咯烷酮、Ν_辛基_2_吡咯烷酮等吡咯烷酮、 1,3 —二甲基-2_咪唑啶酮、大豆油、棉實油等之植物油 、橘油、牛藤草油、檸檬油等植物精油及水之例。 做爲氣體狀載體例者如:丙烷氣體、丁烷氣體、氯氟 代烴、液化石油氣體(LPG )、二甲醚、碳酸氣體例。 又,做爲樹脂製劑之基材例者如:氯化乙烯系聚合物 、聚胺基甲酸乙酯等例,必要時可於此等基材中添加酞酸 酯(酞酸二甲酯、酞酸二辛酯等)、己二酸酯、硬脂酸等 可塑劑。做爲樹脂製劑之製造方法例者如:利用一般混煉 (5) 1355897 裝置使可尼丁(clothianidin)與MGK264混煉於該樹脂製 劑之基材中’藉由射出成形、擠壓成形、加壓成形等一般 成形方法所製造之方法例者。此所得成形體亦可直接適用 於本發明之防蠅’而’成形體更適於經由成形、裁切等步 驟做成動物用項錬、動物用耳標籤亦可。 另外,做爲製劑用補助劑例者如:聚環氧乙烷脂肪酸 酯、聚環氧乙烷脂肪酸醇醚等非離子性乳化劑、烷基磺酸 φ 鹽、烷基硫酸鹽、芳基磺酸鹽等離子性乳化劑、木質素磺 酸鹽等分散劑、羧甲基纖維素、阿拉伯膠、聚乙烯醇、聚 乙烯乙酸酯等固化劑、氧化劑、氧化鈦、普魯士藍、茜素 染料、偶氮染料、酞氰染料、等著色色料等例。 又,本發明防除劑亦可與其他殺蟲劑、殺線蟲劑、殺 蝨劑、害蟲驅避劑、殺菌劑、除草劑、植物生長調整劑等 活性成份共同使用。 該活性成份例如:Permethrin、phenothrin、 resmethrin、丙燃除蟲菊醋、除蟲菊酯' prallethrin、 cyphenothrin、cyfluthrin 、 fen valerate、fenpropathrin、 岩局蘭苷、biphenthrin、transfluthrin、2,3,5,6—四氟一4 —甲氧基甲苄基、1R —反式一3 —(2—甲基—1_丙烯基 )—2,2—二甲基環丙烷羧酸酯、2,3,5,6_四氟一 4 一甲氧 基甲苄基、1R -反式一 3 —(1-丙烯(E/Z=l/8)) — 2,2 —二甲基環丙烷羧酸酯、2,3,5,6 -四氟—4一甲苄基1R —反式一3— (1 — 丙烯(E/Z=l/8) ) - 2,2 —二甲基環 丙烷羧酸酯等之除蟲菊化合物、dichlorvos、 -8- (7) 1355897 惟,本發明未受限於此。 首先,顯示製劑例。 [製劑例1] 將可尼丁( clothianidin ) 2重量份與MGK264 7重量 份溶於二甲苯37.5重量份及二甲基甲醯胺37.5重量份,其 中加入聚環氧乙熔苯乙烯基苯醚10重量份及月桂苯磺酸鈣 φ 6重量份,充份攪拌後取得乳劑。 [製劑例2] 於乳鉢充份混合可尼丁( clothianidin ) 1.5重量份 、MGK2 64 3重量份 '合成含水氧化矽微粉末1重量份、 Driles Β (三共股份公司製、凝結劑)1重量份及黏土 7重 量份後,以果汁機進行混合攪拌。所得混合物中加入 cut cl ay 86.5重量份,充份攪拌混合後,取得粉劑。 [製劑例3] 可尼丁(clothianidin) 5重量份及MGK264 35重量 份中加入Sorpole 5060 (東邦化學工業股份公司註冊商標 、界面活性劑)5重量份,充份混合後,再加入合成含水 氧化矽微粉末32重量份,3 00篩號矽藻土 23重量份,以果 汁機進行混合後,取得水合劑。 [製劑例4] -10- 1355897
可尼丁( clothianidin ) 1 0 重量份、d - r e s m e t r i η 量份及MGK264 30重量份中加入Sorpole 5060 (東邦 工業股份公司註冊商標 '界面活性劑)5重量份,充 合後,加入合成含水氧化矽微粉末30重量份,300篩 藻土 2〇重量份,以果汁機進行混合取得水合劑。 [製劑例5] 可尼丁( clothianidin ) 1 重量份、M G K 2 6 4 2 重 、合成含水氧化矽微粉末5重量份、月桂苯磺酸鈉5重 、膨潤土 30重量份及黏土 57重量份,充份攪拌混合後 於此混合物中加入適量水,再攪拌,以增粒機進行製 通風乾燥取得粒劑。 [製劑例6] 可尼丁(clothianidin) 0.1 重量份及 MGK264 ( Φ 量份溶於12重量份之碳酸丙烯酯中,將該溶液塡入氣 罐內,加入乙醇使全體爲20重量份。此氣熔膠容器裝 騰部份,通過該沸騰部份後,再進行加壓塡充二甲醚 量份,藉由裝置啓動器取得氣熔膠劑。 以下,以試驗例顯示本發明防蠅劑對於蒼蠅具有 效果。 [試驗例1 ] 調整所定處理量濃度之可尼丁(clothianidin 5重 化學 份混 號矽 量份 量份 ,再. 粒, 重 溶膠 置沸 80重 防除 -11 - 1355897 do) [表2] 供試防除劑 處理量(# g/頭) 致死率(%) 可尼丁( clothianidin) 0.1 55 MGK264 0.5 0 可尼丁(clothianidin) +MGK264 0.1+0.5 50 (本發明防蠅劑)
[參考試驗例2] 調製所定處理濃度之可尼丁 ( clothianidin )、 MGK264、以及含有可尼丁(clothianidin)與 MGK264 混 合物之二乙二醇單乙醚稀釋液分別以1.5ml直擊噴霧於茶 翅蟑螂成蟲(雌、雄各5隻),噴霧30秒後將所有蟑螂移 至清潔容器,檢視3天後之致死率。表3顯示重覆試驗3次
[表3] 供試防除劑 處理量(# g/頭) 致死率(%) 可尼丁(clothianidin) 0.0025 83 MGK264 0.025 0 _ 可尼丁(clothianidin) +MGK264 0.0025+0.025 77 (本發明防蠅劑) (11) 1355897 表1 (對於蒼蠅之去除效果)與表2(對於蛾之消除效 果)以及表3(對於蟑螂之去除效果)之比較顯示,本發 明消除劑對於蒼蠅特別發揮明顯的相乘效果。 [產業上可利用性] 本發明防蠅劑明顯發揮相乘性,因此,顯示以更低藥 量之使用對於各種蒼繩均具良好消除。
Claims (1)
1355897 I含告本 p月J日修正丄丨 第095109461號專利申請案中文申請專利範^修正本 民國100年10月5日修正 十' 申請專利範圍 1· ~種蒼繩亞目害蟲防除劑’其特徵係含有以1-( 2-氯-5-噻唑基)甲基-3_甲基_2_硝基胍,與N- ( 2_乙基己 基)-5·原菠烯- 2,3-二羧基醯亞胺爲有效成份。 2 .·如申請專利範圍第1項之蒼蠅亞目害蟲防除劑,其 中1-(2-氯-5·噻唑基)甲基-3-甲基-2-硝基胍,與N-( 2- 乙基己基)-5-原菠烯-2,3-二羧基醯亞胺之重量比爲1: 1 〜1 : 5 〇。 3·如申請專利範圍第1項或第2項之蒼蠅亞目害蟲防 除劑’其係爲用以防除畜舍之蒼蠅。 4·—種蒼蠅亞目害蟲之防除方法,其特徵係將1-( 2-氯-5-噻唑基)甲基-3_甲基·2-硝基胍,與N-( 2-乙基己 基)·5·原菠烯-2,3-二羧基醯亞胺施用於蒼蠅或蒼蠅棲息 的場所。 5. 如申請專利範圍第4項之蒼蠅亞目害蟲之防除方法 ,其中該1-(2-氯-5-噻唑基)甲基-3·甲基-2-硝基胍’與 N_(2-乙基己基)-5-原菠烯_2,3-二竣基醯亞胺之重量比 爲1: 1〜1: 50之範圍。 6. 如申請專利範圍第4項或第5項之蒼蠅亞目害蟲之 防除方法,其係將1-(2-氯-5-噻唑基)甲基-3-甲基-2·硝 基胍、與N- (2 -乙基己基)-5 -原菠烯_2,3·二羧基醯亞胺 施用於畜舍。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005118047A JP4604809B2 (ja) | 2005-04-15 | 2005-04-15 | ハエ亜目害虫防除剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW200719829A TW200719829A (en) | 2007-06-01 |
TWI355897B true TWI355897B (zh) | 2012-01-11 |
Family
ID=37467269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW095109461A TW200719829A (en) | 2005-04-15 | 2006-03-20 | Controlling agent for insect pest of suborder brachycera |
Country Status (3)
Country | Link |
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JP (1) | JP4604809B2 (zh) |
KR (1) | KR101312892B1 (zh) |
TW (1) | TW200719829A (zh) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2546003B2 (ja) * | 1988-12-27 | 1996-10-23 | 武田薬品工業株式会社 | グアニジン誘導体、その製造法及び殺虫剤 |
JP4324308B2 (ja) * | 2000-04-26 | 2009-09-02 | 住友化学株式会社 | ハエ類の防除方法 |
DE10320505A1 (de) * | 2003-05-08 | 2004-11-25 | Bayer Healthcare Ag | Mittel zum Bekämpfen von Parasiten an Tieren |
BRPI0609976A2 (pt) * | 2005-04-04 | 2011-10-11 | Valent Biosciences Corp | concentrado pesticida, produto pronto-para-uso, método para usar o produto, e, processo para produzir um concentrado pesticida |
-
2005
- 2005-04-15 JP JP2005118047A patent/JP4604809B2/ja not_active Expired - Fee Related
-
2006
- 2006-03-20 TW TW095109461A patent/TW200719829A/zh not_active IP Right Cessation
- 2006-04-06 KR KR1020060031326A patent/KR101312892B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TW200719829A (en) | 2007-06-01 |
JP2006298768A (ja) | 2006-11-02 |
JP4604809B2 (ja) | 2011-01-05 |
KR20060109311A (ko) | 2006-10-19 |
KR101312892B1 (ko) | 2013-09-30 |
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