TWI340743B - A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin - Google Patents
A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefinInfo
- Publication number
- TWI340743B TWI340743B TW092117447A TW92117447A TWI340743B TW I340743 B TWI340743 B TW I340743B TW 092117447 A TW092117447 A TW 092117447A TW 92117447 A TW92117447 A TW 92117447A TW I340743 B TWI340743 B TW I340743B
- Authority
- TW
- Taiwan
- Prior art keywords
- epoxidation
- olefin
- catalyst
- epoxidation process
- Prior art date
Links
- 238000000034 method Methods 0.000 title 3
- 238000006735 epoxidation reaction Methods 0.000 title 2
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US39249902P | 2002-06-28 | 2002-06-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW200401773A TW200401773A (en) | 2004-02-01 |
TWI340743B true TWI340743B (en) | 2011-04-21 |
Family
ID=30000882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW092117447A TWI340743B (en) | 2002-06-28 | 2003-06-26 | A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin |
Country Status (14)
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
US8536083B2 (en) | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
CN101448804A (zh) * | 2006-04-21 | 2009-06-03 | 巴斯夫欧洲公司 | 在微通道反应器中制备环氧乙烷的方法 |
CA2685512C (en) | 2007-05-09 | 2016-12-06 | Shell Internationale Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
TWI464154B (zh) | 2007-05-09 | 2014-12-11 | Shell Int Research | 製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法 |
KR20100017691A (ko) * | 2007-05-09 | 2010-02-16 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 촉매, 이 촉매의 제조방법, 및 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산 방법 |
US7696368B2 (en) | 2007-05-11 | 2010-04-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Start-up of high selectivity catalysts in olefin oxide plants |
US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
JP5868703B2 (ja) | 2008-05-07 | 2016-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
EP2297124B1 (en) * | 2008-05-07 | 2013-08-21 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
WO2010009021A2 (en) * | 2008-07-14 | 2010-01-21 | Velocys Inc. | Process for making ethylene oxide using microchannel process technology |
EP2300447A1 (en) | 2008-07-14 | 2011-03-30 | Basf Se | Process for making ethylene oxide |
CN101497045B (zh) * | 2009-03-11 | 2011-03-30 | 华东理工大学 | 一种丙烯液相一步氧化制环氧丙烷用催化剂及制备方法 |
CN102414188B (zh) | 2009-04-21 | 2015-05-27 | 陶氏技术投资有限公司 | 使用高效催化剂的获得并保持指定的环氧烷生产参数的改进方法 |
US8524927B2 (en) | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
CN102666514B (zh) * | 2009-12-17 | 2015-11-25 | 科学设计公司 | 用于环氧化启动的方法 |
CN102666515B (zh) | 2009-12-23 | 2015-05-20 | 科学设计公司 | 高选择性氧化乙烯催化剂启动的方法 |
US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
US8742146B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
US8987483B2 (en) | 2010-12-15 | 2015-03-24 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
CA2832552C (en) | 2011-04-11 | 2020-09-01 | Dow Technology Investments Llc | Process for conditioning a high efficiency ethylene oxide catalyst |
JP6104888B2 (ja) | 2011-04-29 | 2017-03-29 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Eo触媒の選択率を改善する方法 |
WO2013043458A1 (en) * | 2011-09-22 | 2013-03-28 | Shell Oil Company | A process for the start-up of an epoxidation process |
CN103360346B (zh) * | 2012-04-06 | 2015-02-11 | 中国石油化工股份有限公司 | 一种高选择性银催化剂催化乙烯氧化制环氧乙烷的方法 |
EP2920159B1 (en) | 2012-12-31 | 2020-02-12 | Scientific Design Company Inc. | Start-up process for high selectivity ethylene oxide catalysts |
EP3087061B1 (en) | 2013-12-23 | 2018-04-11 | Scientific Design Company Inc. | Epoxidation process |
EP3548471B1 (en) | 2016-12-02 | 2021-05-19 | Shell Internationale Research Maatschappij B.V. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
CN113121474A (zh) * | 2019-12-30 | 2021-07-16 | 中国石油化工股份有限公司 | 乙烯环氧化银催化剂的开车方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2219575A (en) * | 1939-06-16 | 1940-10-29 | Carbide & Carbon Chem Corp | Catalyst and process for making olefin oxides |
FR2412538A1 (fr) * | 1977-12-22 | 1979-07-20 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d'oxyde d'ethylene |
IL84232A (en) * | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
US4950773A (en) * | 1988-01-28 | 1990-08-21 | Eastman Kodak Company | Selective epoxidation of olefins |
CN1009437B (zh) * | 1988-02-03 | 1990-09-05 | 中国石油化工总公司 | 乙烯氧化制环氧乙烷高效银催化剂 |
US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
CA1339317C (en) * | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
JP3233652B2 (ja) * | 1991-05-21 | 2001-11-26 | 株式会社日本触媒 | エチレンオキシド製造用銀触媒 |
US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
AU7614394A (en) * | 1993-08-23 | 1995-03-21 | Shell Internationale Research Maatschappij B.V. | Ethylene oxide catalyst |
DE69600628T2 (de) * | 1995-02-01 | 1999-02-25 | Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage | Alkylenoxidkatalysator und verfahren |
US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
JPH11191963A (ja) * | 1997-12-25 | 1999-07-13 | Fujitsu Ltd | 電源装置 |
US6372925B1 (en) * | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
CN1181118C (zh) * | 2001-12-03 | 2004-12-22 | 蔡晨宁 | 共聚酰亚胺及其合成方法 |
-
2003
- 2003-06-24 AU AU2003243758A patent/AU2003243758A1/en not_active Abandoned
- 2003-06-24 WO PCT/US2003/019828 patent/WO2004002971A1/en active IP Right Grant
- 2003-06-24 KR KR1020047021328A patent/KR101098051B1/ko not_active Expired - Fee Related
- 2003-06-24 EP EP03761993A patent/EP1532125B1/en not_active Revoked
- 2003-06-24 DE DE60304197T patent/DE60304197T2/de not_active Revoked
- 2003-06-24 CN CNB038153122A patent/CN100376561C/zh not_active Expired - Fee Related
- 2003-06-24 JP JP2004517759A patent/JP4624101B2/ja not_active Expired - Fee Related
- 2003-06-24 BR BRPI0312011-2A patent/BR0312011B1/pt not_active IP Right Cessation
- 2003-06-24 CA CA2490892A patent/CA2490892C/en not_active Expired - Fee Related
- 2003-06-24 MX MXPA04012742 patent/MX257124B/es active IP Right Grant
- 2003-06-24 RU RU2005102014/04A patent/RU2311229C2/ru not_active IP Right Cessation
- 2003-06-26 TW TW092117447A patent/TWI340743B/zh not_active IP Right Cessation
- 2003-06-26 MY MYPI20032403A patent/MY134316A/en unknown
-
2004
- 2004-12-09 IN IN3915DE2004 patent/IN2004DE03915A/en unknown
-
2010
- 2010-07-23 JP JP2010165897A patent/JP5431262B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
MY134316A (en) | 2007-12-31 |
TW200401773A (en) | 2004-02-01 |
MXPA04012742A (es) | 2005-05-24 |
DE60304197T2 (de) | 2006-12-14 |
MX257124B (es) | 2008-05-14 |
JP5431262B2 (ja) | 2014-03-05 |
RU2311229C2 (ru) | 2007-11-27 |
EP1532125A1 (en) | 2005-05-25 |
JP2011006426A (ja) | 2011-01-13 |
JP2006502982A (ja) | 2006-01-26 |
KR101098051B1 (ko) | 2011-12-26 |
AU2003243758A1 (en) | 2004-01-19 |
CN1665796A (zh) | 2005-09-07 |
EP1532125B1 (en) | 2006-03-22 |
BR0312011A (pt) | 2005-03-22 |
JP4624101B2 (ja) | 2011-02-02 |
DE60304197D1 (de) | 2006-05-11 |
BR0312011B1 (pt) | 2014-08-05 |
IN2004DE03915A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2009-11-20 |
RU2005102014A (ru) | 2005-07-20 |
CN100376561C (zh) | 2008-03-26 |
CA2490892C (en) | 2012-03-20 |
WO2004002971A1 (en) | 2004-01-08 |
KR20050024406A (ko) | 2005-03-10 |
CA2490892A1 (en) | 2004-01-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Annulment or lapse of patent due to non-payment of fees |