TWI333971B - Exterior paint formulation - Google Patents

Exterior paint formulation Download PDF

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TWI333971B
TWI333971B TW094122094A TW94122094A TWI333971B TW I333971 B TWI333971 B TW I333971B TW 094122094 A TW094122094 A TW 094122094A TW 94122094 A TW94122094 A TW 94122094A TW I333971 B TWI333971 B TW I333971B
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Taiwan
Prior art keywords
acrylic
binder
gallons
composition
paint
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TW094122094A
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English (en)
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TW200615346A (en
Inventor
Ming-Ren Tarng
Mark Minamyer
Anh Pham
Stan Brownell
Annie Pham
Anil Alexander
Deven Shah
Kim L Nguyen
My Linh Pham
Sidney Maxey
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Behr Process Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Description

料/結合劑比。 依據本發明原理之一較佳形式的塗料之pvc可在4〜 55權重之間變彳於本發明之—實施例中該塗料係為一 ‘半光澤塗料” ’其會具有較低的PVC。而在本發明的另 -實施例中，該塗料係為鮮亮塗料，，，其會具有較高 的PVC。在本發明的又—實施例中，該塗料係為一 “暗淡 塗料，其具有一比鮮亮塗料更高的PVC。 表1列出一依較佳實施例原理之塗漆的主要配料之大 致範圍。聚合物（即結合劑）的總量較好是每1〇〇加侖介於3〇 〜60加侖之間。色料的總量，包括Ή〇2，較好是每1〇〇加侖 介於約15至150磅之間。該^仏含量較好係介於每加侖〇磅 至每100加侖約360磅之間。該防腐劑係約為每1〇〇加侖5至8 碎之間。附加的添加物大約為每1〇〇加余5〇至2〇〇碎之間。 水則為每100加侖約5〇至2〇〇磅之間。該塗料更可包含水以 外的其它溶劑，每加侖約為3〇至45磅之間。 表1 —配料範圍 種類 磅/100加侖 最少 最多 添加物 50.00 200.00 聚合物(樹脂） 450.00 635.00 色料 15.00 150.0 二氧化鈦 0.00 360.00 i方腐劑 5.0 8.0 水 50.00 200.00 溶劑 0.00 45.00 mi 600 1598 最少 最多 固體體積百分比 25 40 固體重量百分比 30 55 色料體積濃度 4 55 該較佳配方的製程包含兩個傳統的步驟：研磨和稀 釋。當在研磨時’該溶劑（水）、分散劑、除泡劑、氧化鋅、 1333971 乙二醇、胺基醇' 霞石黑花崗岩（nepheline syenite)、及 attapulgite點土等會被混合在一起。當在豨釋時，該結合 劑、防霉劑、流變修正劑、及殺生物劑等，將會被添加於 研磨製品中。 5 以下非限制性的範例係示出該等塗料配方的主要成分 .及該等塗料配方本身。表2係提供例1〜4之塗料配方成分的 材料範圍。 2—原料範圍
原料 含量範圍 (lbs/100gal) 水 70-220 共聚物分散劑 10-20 奈米微粒無機氧化物 4-20 一氧化鋅 0-7 磷酸共酯表面活化劑 3-6 碾物油除泡劑 4-8 花岗岩 ~~ 10-305 乙二醇 0-35 流變修正劑 15-30 100%丙稀酸底漆結合劑 340-430 iOo%丙稀g复上塗層結合劑 70-100 笨乙焊丙稀酸上塗層結4劊 0-180 凝結劑 -— 0-15 罐裝殺生物劑 _ 0.5-2 防霉劑 6-8 非離子流變修正劑 7-25 胺基醇 0-1 二氧化鈦 ' — 0-350 皂土 0-6 氟表面活化劑 一 0-0.4 不透明聚合物 0-110 Attapulgiteffc 土 0-8 非離子表面活化劑" — 0-5 锻燒ί夕藻土 0-45
(D 11 1333971
〜例1 一半光澤成品〜 例1是使用表2的基本成分所配製而成，其具有以下之 特定成分含量： 表3 種類 含量 重量百分比 研磨 水 73.92 6.98 共聚物分散劑 15.02 1.42 礦物油除泡劑 2.00 0.19 氧化鋅 5.00 0.47 奈米微粒金屬氧化物 3.00 0.28 乙二醇 32.00 3.02 胺基醇 0.50 0.05 非離子表面活化劑 4.00 0.38 霞石黑花崗岩 10.00 0.94 Attapulgite 黏土 5.00 0.47 稀釋 100%丙烯酸底漆載體 410.65 38.77 100%丙烯酸上塗料載體 86.44 8.16 礦物油除泡劑 3.00 0.28 1102料漿 297.00 28.04 凝結劑 8.00 0.76 締合RM 28.00 5.55 非離子HEURRM 8.00 0.76 不透明聚合物 58.80 5.55 磷酸共酯表面活化劑 1.00 0.09 防霉劑 6.94 0.65 罐裝殺生物劑 1.00 0.09 5 〜例2—鮮亮成品〜 例2是使用表2的基本成分所配製而成，其具有以下之 特定成分含量： 12 10 1333971 表4 研磨 含量 重量百分比 水 45.35 4.06 共聚物分散劑 15.02 1.35 礦物油除泡劑 3.00 0.27 奈米微粒金屬氧化物 15.00 1.34 乙二醇 37.00 3.32 胺基醇 0.50 0.04 非離子表面活化劑 2.00 0.18 霞石黑花崗岩 105.02 9.41 Attapulgitef占土 5.01 0.45 稀釋 100%丙烯酸底漆載體 410.60 36.82 100%丙烯酸上塗料載體 86.43 7.75 Γΐ〇2料漿 294.32 26.39 凝結劑 8.00 0.72 磷酸共酯表面活化劑 1.00 0.09 締合RM 25.00 2.24 非離子HEURRM 4.00 0.36 不透明聚合物 50.05 4.49 防霉劑 6.94 0.62 罐裝殺生物劑 1.00 0.09 〜例3 _暗淡成品〜 例3是使用表2的基本成分所配製而成，其具有以下之 φ 5 特定成分含量： 13 1333971 表5 研磨 含量 重量百分比 水 25.27 2.18 乙二醇 22.55 1.95 非離子表面活化劑 2.00 0.17 共聚物分散劑 15.3 1.32 氧化鋅 4.92 0.42 奈米微粒金屬氧化物 4.92 0.43 胺基醇 0.98 0.09 礦物油除泡劑 1.97 0.17 霞石黑花岗岩 94.7 8.18 Attapulgite 黏土 7.92 0.68 磷酸共酯表面活化劑 3.87 0.33 稀釋 Ti02料漿 350.05 30.26 水 82.22 7.1 鍛燒矽藻土 44.28 3.82 100%丙烯酸底漆載體 285.04 24.64 100%丙烯酸上塗料載體 60.02 5.19 不透明聚合物 105.79 9.15 凝結劑 7.87 0.68 締合RM 18.81 1.63 防霉劑 6.82 0.59 礦物油除泡劑 3.94 0.34 非離子HEURRM 6.43 0.56 罐裝殺生物劑 0.96 0.08
〜例4 一暗淡成品〜 例4是使用表2的基本成分所配製而成，其具有以下之 特定成分含量： 14 10 1333971 表6 研磨 含量 重量百分比 水 197 21.15 乙二醇 30 3.22 非離子表面活化劑 1.00 0.85 共聚物分散劑 8.0 0.86 奈米微粒金屬氧化物 8.0 0.86 礦物油除泡劑 6.0 0.64 霞石黑花崗岩 90.0 9.64 皂土 6.0 0.64 稀釋 不透明聚合物 4.0 43 100%丙烯酸底漆載體 366.0 39.3 100%丙烯酸上塗料載體 77.0 8.27 第二丙烯酸上塗料載體 82.0 8.8 凝結劑 5.0 0.54 締合RM 18.0 1.9 防霉劑 6.92 0.74 非離子HEURRM 25 2.68 罐裝殺生物劑 1.0 0.1 〜黏性測試〜 各種黏性測試會被進行來測定依本發明原理之塗料在 5 不同基材上的黏著特性。將本發明的塗料相較於一供外部 使用之典型的市售塗料與底漆系統所作成的測試結果係被 示於表7中： 15 10 1333971
表7 -以ASTM D3359作成的黏性測試結果 黏性測試 測試條件 本發明的 丙烯酸外部底漆* 丙酸酸外部上塗料* 塗料配方 (控制） (控制） 醇酸 過夜， 臟 綠色 過夜， 臟 5B/4B 5B/4B 5B/5B 灰色 過夜， 魏 5B/5B 5B/5B 5B/5B 白堊 藍乳膠板 過夜， 濕 5B/5B 5B/4B 5B/5B 木材 香柏 過夜， 乾/濕 4B/5B 3B/3B 4B/5B 賴 過夜， it/濕 5B/5B 5B/4B 5B/5B 紅木 過夜， W浪 5B/5B 5B/4B 5B/5B PT綠木 過夜， 乾/濕 5B/5B 5B/5B 5B/5B 乙烯外壁板 新乙稀 過夜， 乾/濕 5B/5B 5B/5B 5B/5B 曝露曰久的乙烯 過夜， 乾/濕 5B/5B 5B/5B 5B/5B 金屬 電鍍鋼 過夜， 扮濕 4B/5B 3B/3B 0Β/0Β 三天， 5B/3B 4B/5B 0Β/0Β 鋁板 過夜， 乾/濕 2B/3B 3B/3B 0Β/0Β 三天， 乾/濕 4B/5B 4B/4B 0Β/0Β 其它雜項 光滑的黑色瓷磚 過夜， 乾/濕 5B/3B 2B/0B OB/OB 三天， 乾/濕 5B/5B 5B/2B 0Β/0Β 黏土瓷磚 過夜， 乾/濕 5B/3B 1B/0B 1B/0B 三天， 5B/5B 5B/5B 3B/0B 牛鼻碑 過夜， 娜、 5B/0B 4B/0B 4B/0B 三天， 乾/濕 5B/0B 5B/0B 2B/0B *受測試之控制的丙烯酸外部底漆和控制的丙烯酸外部上塗料係至 少可相較於市場上能輕易購得者。 5 此外，一組類似的測試會被進行來評估呈不同光澤之 本發明的塗料相較於目前市售之塗料的整體性能。如第8及 9表中的結果所示，依本發明原理所製備的塗料會比在同一 類別中的所有其它塗料更為優異。 16 ⑧ 10 1333971 表8—暗淡色澤標準檢核複合得分 測試 特優外部 暗淡塗料 商用丙烯酸 暗淡塗料** 可能得分 冷凉-溶化 1 0 2 熱穩定性 1.5 3 3 塗佈固著性 7.5 5 10 均平性 5 0 5 觸感 7.5 10 10 乾燥時間 2 2 2 抗下垂性 3 3 3 滾筒起泡 3 3 3 滾筒濺灑 1 0.5 1 3mil對比率 20 6 20 乾燥黏著 12 7.5 15 抗起泡性 9 9 9 濕黏著 15 15 15 水潰斑點 2 2 2 總得分 89.5 66 100 **受測的商用丙烯酸暗淡塗料至少可相較於市
場上能輕易購得者。 5 如表9中所示，本發明的光鮮塗料會具有更佳的均平 性、滾筒發泡、對比、及乾黏著性。 10 17 15 1333971 表9—光鮮色澤標準檢核複合得分 測試 特優外部 光鮮塗料 商用丙烯酸外 部光鮮塗料*** 商用矽酮丙烯酸 外部光鲜沴斜*** 可能得分 冷凉/溶化 2 1 2 2 热穩疋性 3 3 3 3 塗佈固著性 10 5 10 10 均平性 5 2.5 0 5 觸感 土A .LS· η士 βα 7.5 4 7.5 10 乾炼時間 2 2 2 2 3 抗下垂性 3 3 3 /农阂起泡 3 3 1.5 3 >装周趟》麗 1 1 1 1 3mil對比率 20 — 20 __14 20 乾燥黏著 抗起泡性 12 15 0 7 12 15 濕黏著 水潰斑點 9 2 15 〇 15 9 9 15 總得分 94.5 Z —2 2 *** 受^ UO.O 金 -- 82 100 5
如第1 ’ 2，3，4及5圖所 口W不’依本發明之原理所製成的 塗料會在黏著力、單寧酸随 ........ 阻^性 '去污性、掩蔽能力及抗 圖係示出具有鮮亮光澤及白色 〜白色基底之市售外部鮮亮塗 侵姓性等具有改良效果。第j 基底之本發明的塗料相較於 料的測S式結果之多轴特性圖 10 點著力、泛黃性、去污性、 掩蔽能力、耐刷洗性、抗佟 . κ麵性、及單寧酸阻隔性等皆會 被測試。第2圖示出依本發明 Θ原理之暗淡白色基底塗料相較 :市售之白色基底外部暗淡塗料的測試結果之多轴特性 圖。第3圖示出本發明之半来 擎白色基底塗料相較於一市售 之白色基底半光科部塗料的測試結果之多軸特性圖。在 依本發明之原理的配方中 ^有的特性皆有改善，惟除耐刷 洗性和泛黃化特性會減少。 弟4圖示出本發明之一暗淡白色 18 15 基底塗料相較於一第二種市售之白色基底外部暗淡塗料的 多軸特性圖。在依本發明原理之配方卞所有的特性皆有改 善。第5圖示出本發明之一光鮮白色基底塗料相較於一第二 種市售之白色基底外部光鮮塗料的多轴特性圖。所有的特 性在依本發明之原理的配方中皆有改善。 雖若干實施例已在本申請案中被示出並加以說明，惟 應凊瞭解仍有各種修正變化能被實施於本發明，而不超出 本發明的廣義概念。 【圖式*簡單· ^^明】 第1圖為本發明《具有光鮮色澤#白色基底的塗料相 較於市售之白色基底的外部光鮮塗料的測試結果多轴特性 圖； 第2圖為依本發明原理之暗淡白色基底塗料相較於市 售之白色基底的外部暗淡塗料之測試結果多軸特性圖； 第3圖為本發明之半光澤白色基底塗料相較於市售之 白色基底的外部半光澤塗料之測試結果多軸特性圖； 第4圖不出本發明之暗淡白色基底塗料相較於第二種 市售之白色基底的外部暗淡塗料的多抽特性圖；及 第5圖示出本發明之光鮮白色基底塗料相較於第二種 市售之白色基底的外部光鮮塗料的多軸特性圖。 【主要兀件符就說明】

Claims (1)

1333971 第94122094號專利申請案申請專利範圍修正本 98.11.2^ ·：
十、申請專利範圍： 1. 一種塗料組成物，包含： 一第一丙烯酸底漆結合劑，每100加侖約有285〜 630磅； 一第二丙烯酸上塗層結合劑，每100加侖約有50〜 95磅； 一第三丙烯酸結合劑為每100加侖大於0且高達180 磅，該第三丙烯酸結合劑係由苯乙烯丙烯酸結合劑所組 成； 一第一金屬氧化物包含染色用二氧化鈦；以及 一第二金屬氧化物包含一奈米微粒尺寸之金屬氧 化物色料，每100加侖約有2〜20磅； 其中該塗料組成物具有一大約4〜55的色料體積濃 度(PVC)，及一大約0.10〜3.0的色料對結合劑比。 2. 如申請專利範圍第1項之組成物，其中該奈米微粒尺寸 之金屬氧化物色料包含氧化辞。 3. 如申請專利範圍第1項之組成物，其中該奈米微粒尺寸 之金屬氧化物色料包含平均顆粒尺寸小於約100奈米的 微粒。 4. 如申請專利範圍第3項之組成物，其中該奈米微粒尺寸 之金屬氧化物色料包含平均顆粒尺寸約為30〜65奈米 的微粒。 5. 如申請專利範圍第1項之組成物，其中該第一丙烯酸底 漆結合劑主要係由丙烯酸所組成。 20 1333971 6. 如申請專利範圍第1項之組成物，其中該第二丙烯酸上 塗層結合劑主要係由丙烯酸所組成。 7. 如申請專利範圍第1項之組成物，其中該第一丙烯酸底 漆結合劑包含自行交鏈的聚合物。 5 8.如申請專利範圍第1項之組成物，其中該第一丙烯酸結 合劑包含一用來作為底漆载體的100%丙烯酸結合劑。 9. 如申請專利範圍第1項之組成物，其中該第一底漆結合 劑對該第二上塗層結合劑之比係約為80 : 20。 10. —種塗料組成物，包含： 10 —丙烯酸底漆結合劑，其於每100加侖塗料中之量 係於340〜430 lbs; —丙烯酸上塗層結合劑，其於每100 加侖塗料中之量係於70〜100 lbs ; 一苯乙烯丙烯酸上塗層結合劑，其於每100加侖塗 料中之量係大於0至180 lbs ; 15 二氧化鈦，其於每1〇〇加侖塗料中之量係大於〇至 350 lbs ； 氧化辞，其於每100加侖塗料中之量係大於0至7 lbs ;及 一奈米微粒無機氧化物，其於每100加侖塗料中之 20 量係於4〜20 lbs。 21
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