TWI272259B - Cement accelerator and method - Google Patents
Cement accelerator and method Download PDFInfo
- Publication number
- TWI272259B TWI272259B TW091134482A TW91134482A TWI272259B TW I272259 B TWI272259 B TW I272259B TW 091134482 A TW091134482 A TW 091134482A TW 91134482 A TW91134482 A TW 91134482A TW I272259 B TWI272259 B TW I272259B
- Authority
- TW
- Taiwan
- Prior art keywords
- weight
- accelerator
- amine
- antifoaming agent
- glycolic acid
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 19
- 239000004568 cement Substances 0.000 title 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims abstract description 32
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 22
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000001412 amines Chemical class 0.000 claims abstract description 16
- 239000003381 stabilizer Substances 0.000 claims abstract description 14
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract 2
- 235000011128 aluminium sulphate Nutrition 0.000 claims abstract 2
- 239000001164 aluminium sulphate Substances 0.000 claims abstract 2
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 claims abstract 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 18
- 238000005507 spraying Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims 2
- 230000008030 elimination Effects 0.000 claims 1
- 238000003379 elimination reaction Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000004567 concrete Substances 0.000 abstract description 5
- 229960004275 glycolic acid Drugs 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 239000011378 shotcrete Substances 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- -1 alkyl alcohol amines Chemical class 0.000 description 2
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- OORRCVPWRPVJEK-UHFFFAOYSA-N 2-oxidanylethanoic acid Chemical compound OCC(O)=O.OCC(O)=O OORRCVPWRPVJEK-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 229940118662 aluminum carbonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical compound C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
- C04B2111/1006—Absence of well-defined organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Ceramic Products (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0128438.9A GB0128438D0 (en) | 2001-11-28 | 2001-11-28 | Method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200300749A TW200300749A (en) | 2003-06-16 |
| TWI272259B true TWI272259B (en) | 2007-02-01 |
Family
ID=9926568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW091134482A TWI272259B (en) | 2001-11-28 | 2002-11-27 | Cement accelerator and method |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7947334B2 (enExample) |
| EP (1) | EP1448494B1 (enExample) |
| JP (1) | JP4321760B2 (enExample) |
| KR (1) | KR100896851B1 (enExample) |
| CN (1) | CN100528794C (enExample) |
| AU (1) | AU2002365500B2 (enExample) |
| BR (1) | BRPI0214493B1 (enExample) |
| CA (1) | CA2466599C (enExample) |
| ES (1) | ES2412180T3 (enExample) |
| GB (1) | GB0128438D0 (enExample) |
| NO (1) | NO339019B1 (enExample) |
| PE (1) | PE20030502A1 (enExample) |
| TW (1) | TWI272259B (enExample) |
| WO (1) | WO2003045872A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2308180T3 (es) | 2003-05-30 | 2008-12-01 | CONSTRUCTION RESEARCH & TECHNOLOGY GMBH | Agregado para composiciones cementos pulverizables. |
| GB0321331D0 (en) * | 2003-09-12 | 2003-10-15 | Constr Res & Tech Gmbh | Accelerator composition for accelerating setting and/or hardening a cementitious composition |
| JP4452473B2 (ja) | 2003-09-19 | 2010-04-21 | Ｂａｓｆポゾリス株式会社 | 液状急結剤 |
| EP1713744A1 (de) * | 2004-02-06 | 2006-10-25 | Sika Technology AG | Wasserbasierender erstarrungs- und erhärtungsbeschleuniger für hydraulische bindemittel sowie verfahren zu dessen herstellung |
| GB0416791D0 (en) | 2004-07-28 | 2004-09-01 | Constr Res & Tech Gmbh | Setting accelerator for sprayed concrete |
| KR100732536B1 (ko) | 2004-08-25 | 2007-06-27 | 요업기술원 | 콘크리트 혼화용 비알칼리성 급결제 제조방법 |
| CN100381385C (zh) * | 2005-10-05 | 2008-04-16 | 克拉玛依市恒祥科技有限责任公司 | 油井水泥低温促凝剂 |
| CN100450956C (zh) * | 2006-12-07 | 2009-01-14 | 江苏博特新材料有限公司 | 喷射混凝土用液体无碱速凝剂 |
| BRPI0922295B1 (pt) | 2008-12-04 | 2019-09-24 | Construction Research & Technology Gmbh | Mistura aceleradora, processo para a preparação de um acelerador líquido, processo para o revestimento de substratos com concreto ou argamassa, concreto ou argamassa, e, camada endurecida. |
| EP2248780A1 (de) | 2009-05-06 | 2010-11-10 | BK Giulini GmbH | Abbinde- und Enthärtungsbeschleuniger |
| AU2010291308B2 (en) * | 2009-09-02 | 2014-08-14 | Construction Research & Technology Gmbh | Sprayable hydraulic binder composition and method of use |
| US9731999B2 (en) * | 2011-09-23 | 2017-08-15 | Iqbal Gill | Chemical admixtures for hydraulic cements |
| CN108101403B (zh) * | 2017-12-28 | 2019-09-27 | 科之杰新材料集团有限公司 | 一种环保型无碱液体速凝剂的制备方法 |
| CN108178548B (zh) * | 2017-12-28 | 2019-09-06 | 福建科之杰新材料有限公司 | 一种高耐久性无碱液体速凝剂的制备方法 |
| CN109020292B (zh) * | 2018-08-16 | 2020-04-10 | 科之杰新材料集团有限公司 | 一种环保增强型无碱液体速凝剂的制备方法 |
| CN109336446B (zh) * | 2018-09-28 | 2021-06-15 | 镇江苏博特新材料有限公司 | 一种高铝含量无碱无氯速凝剂的制备方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB650745A (en) | 1946-10-24 | 1951-02-28 | Kaspar Winkler | Improvements in and relating to hydraulic binding agents |
| CH648272A5 (de) | 1981-10-12 | 1985-03-15 | Sika Ag | Alkalifreier abbinde- und erhaertungsbeschleuniger sowie verfahren zur beschleunigung des abbindens und erhaertens eines hydraulischen bindemittels. |
| DE3140784A1 (de) * | 1981-10-14 | 1983-04-28 | Freudenberg, Carl, 6940 Weinheim | "saugfaehiges flaechengebilde und verfahren zu seiner herstellung" |
| CH680730A5 (enExample) * | 1990-07-09 | 1992-10-30 | Sika Ag | |
| CH681720A5 (enExample) | 1991-04-12 | 1993-05-14 | Sika Ag | |
| CH686513A5 (de) | 1993-12-06 | 1996-04-15 | Sika Ag | Verfahren zur Beschleunigung des Abbindens und Erhaertens eines Bindemitteln und Abbinde-und Erhaertungsbeschleuniger. |
| ATE156790T1 (de) * | 1994-03-03 | 1997-08-15 | Sika Ag | Chlorid- und nitritfreier abbinde- und erhärtungsbeschleuniger und verfahren zur beschleunigung des abbindens und erhärtens von hydraulischen bindemitteln und diese enthaltenden gemischen |
| GB9416114D0 (en) * | 1994-08-10 | 1994-09-28 | Sandoz Ltd | Improvements in or relating to organic compounds |
| GB9505259D0 (en) * | 1995-03-16 | 1995-05-03 | Sandoz Ltd | Improvements in or relating to organic compounds |
| ATE185540T1 (de) | 1995-05-09 | 1999-10-15 | Sika Ag | Alkalifreier, flüssiger abbinde- und erhärtungsbeschleuniger für zement |
| GB9513116D0 (en) * | 1995-06-28 | 1995-08-30 | Sandoz Ltd | Improvements in or relating to organic compounds |
| PL192018B1 (pl) * | 1995-12-05 | 2006-08-31 | Dolomatrix Internat Ltd | Kompozycja wiążąca typu cementu |
| EP0798300B1 (de) | 1996-03-09 | 2000-05-31 | BK Giulini Chemie GmbH & Co. OHG | Aluminiumverbindungen |
| EP0812812B1 (en) | 1996-06-14 | 2003-01-29 | Mbt Holding Ag | Concrete spraying additives |
| AU723970B2 (en) * | 1996-06-14 | 2000-09-07 | Construction Research & Technology Gmbh | Concrete spraying additives |
| DK0946451T4 (da) | 1996-10-25 | 2005-12-27 | Bk Giulini Gmbh | Störknings- og hærdningsaccelerator for hydrauliske bindemidler |
| JP2000185952A (ja) | 1998-10-13 | 2000-07-04 | Taiheiyo Cement Corp | セメント用液体急結剤 |
| JP2003502269A (ja) | 1999-06-18 | 2003-01-21 | エムビーティー ホールディング アーゲー | コンクリート混和材 |
| JP2001130935A (ja) | 1999-10-29 | 2001-05-15 | Katekkusu:Kk | コンクリート急結剤 |
| GB9928977D0 (en) | 1999-12-08 | 2000-02-02 | Mbt Holding Ag | Process |
| DE50007784D1 (de) * | 2000-06-21 | 2004-10-21 | Sika Ag, Vorm. Kaspar Winkler & Co | Sulfat- und alkalifreier Abbinde- und Erhärtungsbeschleuniger |
| DK1167317T3 (da) * | 2000-06-21 | 2004-04-05 | Sika Schweiz Ag | Alkalifri afbindings- og hærdningsaccelerator |
| JP3704077B2 (ja) * | 2001-01-24 | 2005-10-05 | 花王株式会社 | アスファルト乳剤組成物 |
| US20030082116A1 (en) * | 2001-09-28 | 2003-05-01 | Closure Medical Corporation | Adhesive compositions containing dual function stabilizers and active agents |
| GB0123364D0 (en) | 2001-09-28 | 2001-11-21 | Mbt Holding Ag | Composition |
-
2001
- 2001-11-28 GB GBGB0128438.9A patent/GB0128438D0/en not_active Ceased
-
2002
- 2002-11-07 US US10/495,825 patent/US7947334B2/en not_active Expired - Fee Related
- 2002-11-07 ES ES02790348T patent/ES2412180T3/es not_active Expired - Lifetime
- 2002-11-07 AU AU2002365500A patent/AU2002365500B2/en not_active Ceased
- 2002-11-07 EP EP02790348.3A patent/EP1448494B1/en not_active Expired - Lifetime
- 2002-11-07 CA CA2466599A patent/CA2466599C/en not_active Expired - Fee Related
- 2002-11-07 JP JP2003547331A patent/JP4321760B2/ja not_active Expired - Fee Related
- 2002-11-07 BR BRPI0214493A patent/BRPI0214493B1/pt not_active IP Right Cessation
- 2002-11-07 CN CNB028235347A patent/CN100528794C/zh not_active Expired - Fee Related
- 2002-11-07 KR KR1020047008022A patent/KR100896851B1/ko not_active Expired - Fee Related
- 2002-11-07 WO PCT/EP2002/012483 patent/WO2003045872A1/en not_active Ceased
- 2002-11-08 PE PE2002001087A patent/PE20030502A1/es not_active Application Discontinuation
- 2002-11-27 TW TW091134482A patent/TWI272259B/zh not_active IP Right Cessation
-
2004
- 2004-06-25 NO NO20042692A patent/NO339019B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO339019B1 (no) | 2016-11-07 |
| BR0214493A (pt) | 2004-09-14 |
| ES2412180T3 (es) | 2013-07-10 |
| NO20042692L (no) | 2004-08-30 |
| PE20030502A1 (es) | 2003-06-14 |
| AU2002365500B2 (en) | 2007-11-15 |
| CN100528794C (zh) | 2009-08-19 |
| GB0128438D0 (en) | 2002-01-16 |
| TW200300749A (en) | 2003-06-16 |
| CA2466599C (en) | 2011-08-02 |
| US7947334B2 (en) | 2011-05-24 |
| EP1448494B1 (en) | 2013-05-08 |
| WO2003045872A1 (en) | 2003-06-05 |
| KR100896851B1 (ko) | 2009-05-12 |
| BRPI0214493B1 (pt) | 2015-12-01 |
| EP1448494A1 (en) | 2004-08-25 |
| JP2005510443A (ja) | 2005-04-21 |
| AU2002365500A1 (en) | 2003-06-10 |
| CA2466599A1 (en) | 2003-06-05 |
| JP4321760B2 (ja) | 2009-08-26 |
| US20060210716A1 (en) | 2006-09-21 |
| KR20040063973A (ko) | 2004-07-15 |
| CN1596233A (zh) | 2005-03-16 |
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