TWI263630B - Conversion catalyst for ethylbenzene containing xylenes and process for converting ethylbenzene containing xylenes by using catalyst - Google Patents
Conversion catalyst for ethylbenzene containing xylenes and process for converting ethylbenzene containing xylenes by using catalystInfo
- Publication number
- TWI263630B TWI263630B TW093118930A TW93118930A TWI263630B TW I263630 B TWI263630 B TW I263630B TW 093118930 A TW093118930 A TW 093118930A TW 93118930 A TW93118930 A TW 93118930A TW I263630 B TWI263630 B TW I263630B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalyst
- containing xylenes
- ethylbenzene containing
- xylenes
- converting
- Prior art date
Links
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000008096 xylene Substances 0.000 title abstract 3
- 150000003738 xylenes Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 title 1
- 239000013078 crystal Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
- C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
- C07C4/18—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
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- B01J35/30—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/36—Rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
- C07C2523/50—Silver
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/66—Silver or gold
- C07C2523/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003193267 | 2003-07-08 | ||
JP2003313585 | 2003-09-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW200505820A TW200505820A (en) | 2005-02-16 |
TWI263630B true TWI263630B (en) | 2006-10-11 |
Family
ID=33455603
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW093118930A TWI263630B (en) | 2003-07-08 | 2004-06-29 | Conversion catalyst for ethylbenzene containing xylenes and process for converting ethylbenzene containing xylenes by using catalyst |
Country Status (11)
Country | Link |
---|---|
US (1) | US7199070B2 (zh) |
EP (1) | EP1495805B1 (zh) |
KR (1) | KR101026787B1 (zh) |
AT (1) | ATE365072T1 (zh) |
CA (1) | CA2473066A1 (zh) |
DE (1) | DE602004007066T2 (zh) |
ES (1) | ES2287654T3 (zh) |
MY (1) | MY136850A (zh) |
PT (1) | PT1495805E (zh) |
SG (1) | SG108993A1 (zh) |
TW (1) | TWI263630B (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2022564A1 (en) * | 2007-07-31 | 2009-02-11 | Shell Internationale Researchmaatschappij B.V. | Catalyst composition, its preparation and use |
US8445398B2 (en) * | 2007-07-31 | 2013-05-21 | Exxonmobil Chemical Patents Inc. | Ion exchange process for making molecular sieve composition |
US8071832B2 (en) * | 2008-03-19 | 2011-12-06 | Toray Industries, Inc. | Method of converting ethylbenzene and process for producing p-xylene |
DE102008030818B4 (de) * | 2008-06-30 | 2022-03-03 | OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung | Oberflächenemittierender Halbleiterlaser mit mehreren aktiven Zonen |
CN102527430B (zh) * | 2010-12-29 | 2014-04-30 | 中国石油化工股份有限公司 | 银催化剂载体的制备方法、由此制备的载体、由该载体制成的银催化剂及其应用 |
US9018121B2 (en) | 2012-02-29 | 2015-04-28 | Exxonmobil Chemicals Patents Inc. | Bimetallic catalyst and use in xylene production |
CN110088068B (zh) | 2016-12-21 | 2022-12-06 | 环球油品有限责任公司 | 沸石uzm-55的物质组合物和结构及在芳族分子异构化中的用途 |
CN111448178B (zh) * | 2017-12-05 | 2023-01-06 | 埃克森美孚化学专利公司 | 二甲苯生产方法和系统 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4946606A (zh) | 1972-09-08 | 1974-05-04 | ||
US3856871A (en) | 1973-09-13 | 1974-12-24 | Mobil Oil Corp | Xylene isomerization |
US4163028A (en) | 1977-07-22 | 1979-07-31 | Mobil Oil Corporation | Xylene isomerization |
US4159282A (en) | 1978-06-09 | 1979-06-26 | Mobil Oil Corporation | Xylene isomerization |
JPS57200319A (en) | 1981-06-03 | 1982-12-08 | Toray Ind Inc | Conversion of xylenes containing ethylbenzene |
US4899011A (en) | 1986-01-15 | 1990-02-06 | Mobil Oil Corporation | Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics |
FR2619319B1 (fr) * | 1987-08-14 | 1990-01-12 | Inst Francais Du Petrole | Catalyseur du type aluminosilicate renfermant au moins un metal noble et son utilisation en isomerisation d'une coupe c8 aromatique |
US5004855A (en) * | 1987-08-25 | 1991-04-02 | Toray Industries, Inc. | Process for conversion of ethylbenzene in C8 aromatic hydrocarbon mixture |
EP0500413B1 (fr) * | 1991-02-19 | 1995-09-20 | Institut Français du Pétrole | Utilisation d'un catalyseur de type galloaluminosilicate en aromatisation des hydrocarbures contenant entre 2 et 7 atomes de carbone par molecule |
DE4137013A1 (de) * | 1991-11-11 | 1993-05-13 | Basf Ag | Verfahren zur herstellung von aminen durch reduktive aminierung |
US5672796A (en) * | 1992-02-13 | 1997-09-30 | Amoco Corporation | Catalyst and process for hydrocarbon aromatization |
US5877374A (en) * | 1997-04-02 | 1999-03-02 | Chevron Chemical Company | Low pressure hydrodealkylation of ethylbenzene and xylene isomerization |
US6028238A (en) * | 1998-04-14 | 2000-02-22 | Mobil Oil Corporation | Xylene isomerization |
US6051520A (en) * | 1998-05-19 | 2000-04-18 | Phillips Petroleum Company | Hydrotreating catalyst composition and processes therefor and therewith |
US6462248B1 (en) * | 1998-09-09 | 2002-10-08 | Toray Industries, Inc. | Method for producing aromatic compounds having alkyl group with at least three carbon atoms |
US6051744A (en) * | 1998-12-17 | 2000-04-18 | Chevron Chemical Company Llc | Low pressure hydrodealkylation of ethylbenzene and xylene isomerization |
DE60012323T2 (de) * | 2000-09-06 | 2005-08-18 | Uop Llc, Des Plaines | Verfahren zur Isomerisierung von Xylolen mit gleichzeitiger Umsetzung von Ethylbenzol |
-
2004
- 2004-06-29 TW TW093118930A patent/TWI263630B/zh active
- 2004-07-05 AT AT04254026T patent/ATE365072T1/de not_active IP Right Cessation
- 2004-07-05 DE DE602004007066T patent/DE602004007066T2/de active Active
- 2004-07-05 ES ES04254026T patent/ES2287654T3/es active Active
- 2004-07-05 EP EP04254026A patent/EP1495805B1/en not_active Not-in-force
- 2004-07-05 PT PT04254026T patent/PT1495805E/pt unknown
- 2004-07-06 KR KR1020040052198A patent/KR101026787B1/ko active IP Right Grant
- 2004-07-07 SG SG200404353A patent/SG108993A1/en unknown
- 2004-07-07 US US10/885,314 patent/US7199070B2/en not_active Expired - Fee Related
- 2004-07-07 CA CA002473066A patent/CA2473066A1/en not_active Abandoned
- 2004-07-07 MY MYPI20042704A patent/MY136850A/en unknown
Also Published As
Publication number | Publication date |
---|---|
US7199070B2 (en) | 2007-04-03 |
EP1495805A1 (en) | 2005-01-12 |
DE602004007066D1 (de) | 2007-08-02 |
ATE365072T1 (de) | 2007-07-15 |
US20050010074A1 (en) | 2005-01-13 |
EP1495805B1 (en) | 2007-06-20 |
ES2287654T3 (es) | 2007-12-16 |
SG108993A1 (en) | 2005-02-28 |
KR20050006043A (ko) | 2005-01-15 |
DE602004007066T2 (de) | 2007-09-27 |
MY136850A (en) | 2008-11-28 |
CA2473066A1 (en) | 2005-01-08 |
TW200505820A (en) | 2005-02-16 |
KR101026787B1 (ko) | 2011-04-04 |
PT1495805E (pt) | 2007-07-13 |
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