TWI236461B - Glass composition, its mixture and paste, green sheet, insulator, dielectric substance, thick film and FPD using the same - Google Patents

Abstract

The object of the invention is to provide a glass composition that is used to produce a glass substrate of FPD and dose not make the glass substrate camber. The image of FPD produced by the glass composition will not crosstalk, and the glass substrate has an improved reflectivity. The glass composition of the invention contains 5 to 35 mole% of P2O5, 50 to 65 mole% of ZnO, 0.1 to 10 mole% of SiO2, 0.1 to 10 mole% of B2O3, 1 to 20 mole% of one or more oxides of alkaline earth metal selected from the group consisting of MgO, CaO, SrO and BaO, and 0.1 to 10 mole% of Al2O3.

Description

1236461 A7 B7 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to PDP (plasma display panel: plasma display panal); PAL C (plasma addressed liquid crystal display) and other FPDs (Flat panel display) Suitable glass compositions and mixtures thereof, and the use of their slurry and unprocessed flakes. [Prior art] P D P usually arranges most of the small discharge elements in a vertical and horizontal (matrix) arrangement, and displays the characters and patterns by making necessary elements discharge and emit light. This PDP has a simple structure, is easy to be large-scale, has a memory function, and can be colorized. It also has a variety of advantages such as large and small depths compared with the picture tube used in televisions. Therefore, it has been researched and developed in recent years. In terms of electrode structure, the PDP can be classified into an AC-type metal electrode covered with a glass dielectric material and a DC-type metal electrode exposed in a discharge space. For example, the AC-type PDP is as shown in FIG. 9. A glass substrate 1 is formed by covering a glass substrate 3 different from the front glass through a plurality of ceramic partition walls 2 formed at predetermined intervals. On the opposite side of the glass substrate 3 from the glass substrate 1, a display electrode 3b and a dielectric layer 3c covered with a protective film 3a such as Mg0 (magnesium oxide) are formed between the glass substrate 1 and the glass substrate 3 and between them. The addressing electrode 4 a and the phosphor layer 4 b of the anode discharge electrode are formed in the minute space 4 (hereinafter referred to as a discharge element) forming a partition in the partition 2, and the addressing electrode 4 a is viewed (please read the back first) (Notes to fill in this page) Write the order --------- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Qin Dynasty. This paper is printed in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) ) -4-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 B7 V. Description of the invention (2) It needs to be protected by insulator 4c. A discharge gas (not shown) is injected into the discharge element 4. In the PDP 'thus configured, a voltage is applied between the display electrode 3 b and the address electrode 4 a and the phosphor layer 4 b in the discharge element 4 formed between the partition walls 2 is selectively discharged to emit light. Can display text and graphics. Conventionally, the glass composition of the partition wall 2 and the insulator 4 c formed on the glass substrate 1 has been disclosed as containing 70 to 95% by weight of glass powder and 5 to 30% by weight of the refractory filler. The heat-resistant pigment is a composition of 0 to 10% by weight (Japanese Patent Laid-Open No. 3-1 7 0 3 4 6). In this glass composition, the glass composition is composed of 55 to 65% by weight of corpse b0, 0 to 5% by weight 2zNo, 0 to 10% by weight 2B203, and 15 to 25% by weight 〇2, 0 · 5 ~ 5 wt% of A 1 2 0 a, 0.5 ~ 15 wt% of (311〇2 + but 1〇2), 0.5 ~ 10 wt% of (Mg〇 + Ca〇 + Sr〇 + Ba〇 ） "〇 · 1 to 2% by weight 2Ce〇2, 0 · 1 to 5% by weight 2La2 03. The glass composition thus constituted has a low thermal expansion coefficient when it is made of borosilicate glass, and When P b 0 is added, it shows a low softening point. However, since the foregoing glass composition contains P b 0, the density of the glass composition becomes larger. This glass composition is used as a partition wall on a glass substrate of PDP. At this time, there are problems that the weight of the glass substrate increases and problems that cause environmental pollution. If the weight of the glass substrate increases, the glass substrate is easily reversed when the glass substrate is calcined, that is, the paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -5--------- Order --------- Line | (Please read the back first Please note that you need to fill in this page.) Female 1236461 Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed A7 B7 V. Description of the invention (3) 'In order to prevent uneven heating in the glass substrate forging process, it is on the glass substrate Support is provided at several points below, but if the glass substrate is heavy, there is a problem that it is easy to be reversed due to its own weight. In addition, the above-mentioned previous glass composition 'because the specific dielectric ratio of the partition wall 2 is as large as 1 About 0 ~ 1, it leaks electrical signals in the adjacent wiring, which has the problem of easily causing crosstalk in the image. Furthermore, in the previous glass composition, it has the PDP partition wall 2 or the insulation layer 4 c. In use (under a plasma decompression atmosphere), the metal P b is precipitated and the discharge characteristics are reduced. In order to solve these problems, it has been revealed that the glass has a low softening temperature with resistance to ion discharge shock (Japanese Patent Laid-Open No. 4) 8-4 3 0 0 7) and plasma display panel (Japanese Patent Application Laid-Open No. 8-30 0 6 6 3 1) are glass containing no Pb component. Ion discharge resistance and low softening The glass is made of 30 ~ 43% by weight of anhydrous boric acid (B203), 18 ~ 33% by weight of vanadium pentoxide (V205, 17 ~ 22% by weight of zinc oxide (Zn〇), 8 ~ 12% by weight of sodium oxide (N a 2 0) as a main component, and contains at least one 6% by weight or less of silicic acid (S i 〇2), 5% by weight or less of alumina (A 1 2 03) Characteristic is zirconia (ZrO2) of 4% by weight or less. This ion-discharge-resistant low-softening-temperature glass has a coefficient of thermal expansion approximately the same as that of a window glass plate generally used, and has a softening temperature lower than that of a window glass plate, so that it does not cause slight cracks and is uniformly fused to Window glass. And 'because it does not contain any discharge through gas ions, etc. -------- order --------- line · (Please read the precautions on the back first ^ Fill this page) This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -6- 1236461 A7 B7 V. Description of the invention (4) Lead oxide (P b0) bismuth oxide (B i 2〇3) ) And other heavy metal oxides, so the long-term use of the glass of the PDP glass substrate, such as glass for the film, is not affected by the gas ion discharge, and it will not cause the film's blackening and transparency changes. The deterioration. On the other hand, in the plasma display disclosed in the above-mentioned Japanese Patent Application Publication No. 8-3 0 1 6 3 1, a partition wall is formed between each pixel of the display between opposing glass substrates, and the partition wall is formed by P 2 〇5 series of glass powder composed of glass powder, and low-expansion ceramic powder composed of glass ceramic composition calcined product is characterized by. In this plasma display panel, the glass ceramic composition is composed of 20 to 70% by weight of glass powder and 30 to 80% by weight of low-expansion ceramic powder, and the glass powder is 25 to 35% by weight卩 205, 0 ~ 50 mole% 2Zn〇, 〇 ~ 70 mole% 2Sn〇, 0 ~ 10 mole% 2Li2〇, 0 ~ 10 mole% 2Na2〇, 0 ~ 10 mole% 1 <; 20, 〇 ~ 20 mol% of (Li2O + Na2〇 + K2〇), 〇 ~ 10 mol% of [4], 〇 ~ 10 mol% 2Ca, 〇 ~ 8 mol% 8]: 〇, 〇 ~ 10 mol% 2Ba〇, 〇 ~ 20 mol% 2 (Mg〇 + Ca〇 + Sr〇 + Ba〇), 〇 ~ 10 mol% 2B203 0 to 10 mole% of the population of 1203. A plasma display panel having such a composition partition wall has a specific dielectric ratio of the partition wall of 7 to 10, which can reduce crosstalk of a displayed image compared with a partition wall containing P b. In addition, since the partition wall does not contain a P b component, it is most suitable for a small-density, large-sized PDP. What's more, because this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------: ______ (Please read the notes on the back first to write this page) Employees ’Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Print

1236461 A7 B7 V. Description of the invention (5) The thermal expansion coefficient is adjusted to be suitable for ordinary p DP glass substrates, so it will not be reversed when the partition wall is formed on the PDP glass substrate, and it will not be coated on the bottom layer. It can cause cracks, and the glass substrate is difficult to crack. [Problems to be Solved by the Invention] However, the low-softening temperature glass of ion discharge shock resistance shown in the above-mentioned Japanese Patent Application Laid-Open No. 4 8-4 3 0 07 is colored in brown because it contains V 2 0 5. It has the disadvantage of reducing the reflectance. In addition, since the plasma display panel shown in the aforementioned Japanese Patent Application Publication No. 8-3 0 1 6 3 1 contains a large amount of P 2 05 and an alkali metal oxide, the thermal expansion coefficient of glass with respect to a glass substrate becomes large. A large amount of ceramic filler must be added to adjust the thermal expansion coefficient to the glass substrate. Through the large amount of filler, the structure after calcination becomes porous, and the strength is reduced, and it also has the problem of reducing the discharge characteristics. . On the other hand, the above-mentioned glass and the like mainly use the partition wall 2 or the insulating layer 4 c, but the dielectric layer 3 c covering the glass substrate 3 through the partition wall 2 is not suitable for the above-mentioned glass. That is, since the glass substrate 3 having the dielectric layer 3 c serves as the front glass, the glass and the like used for the dielectric layer 3 c are required to be more than the glass and the like used for the partition wall 2 or the insulating layer 4 c. High transparency and permittivity. A first object of the present invention is to provide a glass composition for a partition wall or an insulation layer, and a mixture thereof, so that an FPD glass substrate is not reversed, and an FPD image is not disturbed to improve reflectivity, and uses the same Slurries, green sheets, insulators and FPDs. (Please read the precautions on the back first and fill in this page) β Order --------- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of Qinqin This paper is printed in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) _8_ 1236461 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (6) The second purpose of the present invention is to provide a low thermal expansion coefficient that is compatible with The glass composition for partition wall or insulation layer of FPD and the glass composition and its mixture, and the slurry, raw sheet, insulator and FPD using it. A third object of the present invention is to provide a glass composition for a partition wall or an insulating layer which can lower a softening point than a glass substrate and improve water resistance, and

The mixed body, the slurry, the unprocessed sheet, the insulator and the FPD, which are made by hand. The fourth object of the present invention is to provide a thermal expansion coefficient adjustment and coordination with the glass substrates, and to form a strong adhesion between the glass substrates Slurry and FPD for partition walls or insulating layers of thick films. A fifth object of the present invention is to provide a glass composition for a dielectric body having high transparency and a high dielectric constant, and a slurry, a green sheet, a dielectric body, and F P D using the same. [Means to Solve the Problem] The invention in item 1 of the scope of patent application contains Zn containing 3.5 at 0m% or more and less than 18a tom%, Zn containing 12.5a tom% or more and less than 24a tom%. One or two or more of 0, 〇2a t om% and less than 4atom%, O. Olatom% and less than 6.0atom%, B, Oatom% and less than 3 at om% selected from Mg Alkaline earth metals such as Ca, S a and Sr, and Ba, Al from 0.01 to om% and less than 6.0 at, and Al from 55a to 〇m% and less than 65. The Chinese paper standard (CNS) applies A4 specification (210 X 297 mm) -9 --------- Order --------- Line I (Please read the notes on the back first and fill in this page first) Write female 1236461 Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative A7 B7 V. Description of the invention (7) at ◦ m% glass as a glass composition. Is the invention in the second item of the patent application scope more than 5 mole% and less than 35 mole%? 205,50 mole% or more and less than 65 mole% 2Zη〇, 0.1 mole% or more and less than 10 mole% Si 102, 0.1 mole% or more and One or two or more kinds of oxides of alkaline earth metals selected from the group consisting of Mg0, Ca0, Sr0 and Ba0, less than 10 mole% 2B203, more than 1 mole% and less than 20 mole%, And a glass composition having a glass component of 0.1 mol% or more and less than 10 mol%. For the glass composition described in the first and second patent scopes of this application, if the glass components are mixed separately within the above range, the calcination temperature will be lowered, and the softening point of the insulator after firing will also be lowered. In addition, since the glass component does not contain a high-density P b component, the weight of the insulator can be reduced without polluting the environment. Furthermore, since P205 is small, the water resistance of the insulator can be improved. The invention in item 3 of the scope of patent application is the glass composition described in item 1 or item 2. The ceramic filler is a mixture of one or two or more kinds selected from alumina, titanium dioxide, Codielite, mullite, cold A ceramsite, spodumene, anorthite, barium feldspar, forsterite, and a ceramic mixture of aluminum titanate. The mixture described in item 3 is a ceramic filler in a glass composition, which can reduce the thermal expansion coefficient of the insulator obtained by firing the mixture, and make the thermal expansion coefficient of the insulator equal to the thermal expansion of the glass substrate. Coefficient integration. This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) -10-------- Order --------- Line | (Please read the precautions on the back first Θ (Fill in this page) Writer 1234661 A7 B7 V. Description of the invention (8) In the above glass composition or mixture, the polymer resin and solvent are mixed to make a slurry, or in the above glass composition or mixture, the high It is preferable that the molecular resin and the solvent are mixed to make a partition wall or an unprocessed sheet for an insulating layer. The glass composition or the mixture is calcined to form an insulator, or a partition wall or an insulating layer for FPD is preferable. Furthermore, the above-mentioned glass or mixture is prepared as a slurry containing a conductor powder, a resistor powder or a dielectric powder, a polymer resin, and a solvent, and coated, dried, fired, and formed on a substrate. Thick films for conductors, resistors, or dielectrics are preferred. Add polymer resin and solvent to the glass composition or mixture to make a slurry, and then use the screen printing method to make this slurry into ceramic capillary ribs or ceramic capillary inner layers, and then dry and calcined. The ceramic capillary rib or the inner layer of the ceramic capillary is made into an insulator, a partition wall or an insulating layer. Alternatively, by preparing a raw sheet from a slurry containing a polymer resin and a solvent in a glass composition or a mixture, and drying and firing the raw sheet, the raw sheet can be used as an insulator, a partition wall, or an insulating layer. . Since the firing temperature at this time is lower than the softening point of the glass substrate by more than 100 t, no reversal or the like occurs on the glass substrate. In addition, since the thermal expansion coefficient of the insulator, the partition wall or the insulating layer is substantially the same as the thermal expansion coefficient of the glass substrate, the inversion of the glass substrate can be further suppressed. The specific permittivity of the above-mentioned insulators, partition walls or insulating layers is as small as about 4 to 7 ', so that the electrical signals will not leak to the adjacent wiring, and the image will not be disturbed. More (Please read the precautions on the back ^ Fill this page first) Write too much -------- line j Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 specifications ( 210 X 297 mm) -11-1236461 A7 B7 V. Description of the invention (9) In addition, the amount of ceramic filler added to the glass composition may be a small amount, so it will not make the strength and Discharge characteristics are reduced. (Please read the notes on the back to fill in this page first.) The invention in item 11 of the scope of patent application is P containing more than 12 at 0 m% and less than 26a t om%, more than 3a tom om% and less than 17a tom % Zn, 〇la tom% or more and less than 3atom% Si, O. Olatom% or more and less than 5a tom% B, Oat om% or more and less than 13 a tom% Alkaline earth metals selected from Mg, Ca, Sr, and Ba, 0. Ola t om% or more and less than 5 at om% of A 1, and 55a t om% or more and less than 65 atom% of 0 as a glass component.组合 物。 Composition. The inventions in the scope of application for 12 items are those containing 30 mole% or more and less than 70 mole%:? 205, 2 and more than 20 mol% and less than 60 mol% 2 ^ 〇, 0.1 mol% and less than 10 mol% Si 102, 0.1 mol% Alkaline earth metal oxides selected from the group consisting of Mg0, Ca0, Sr0, and Ba0 above or below 20 mol% 2B203, 1 or more than 40 mol% or more , And those who are more than 0.1 mol% and less than 10 mol% 1220 are used as the glass composition for printing the glass components of the consumer cooperative of the Intellectual Property Bureau of the Ministry of Glass Economy. If the glass composition described in item 11 and item 12 of this application patent is mixed with glass components within the above range. Then, the softening point of the calcined dielectric becomes low, and the weight of the dielectric is reduced, and the dielectric constant and transparency of the dielectric can be improved. In the above glass composition, the polymer resin and the solvent are mixed to make this paper. The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -12- " 1236461 A7 B7 V. Description of the invention (10) It is preferable to mix a polymer resin and a solvent in the glass composition to prepare a green sheet for a dielectric. Further, it is preferable that the glass composition is calcined to form a dielectric body. Furthermore, it is preferable to prepare a slurry containing a dielectric powder, a polymer resin, and a solvent in the above glass, and apply it on a substrate, dry, and fire to form a thick dielectric film. In other words, the above-mentioned ceramic pore shape refers to a state where most of the high-molecular resin and the solvent remain after the slurry of the glass composition and the ceramic filler and the polymer resin and the solvent are applied. [Embodiment of Invention] Next, a first embodiment of the present invention will be described with reference to the drawings. The glass composition for a partition wall or an insulating layer is P containing 3.5 at 〇m% or more and less than 18 a tom%, Zn at 12 5 a tom% or more and less than 24 a tom%, 0.02 a tom% or more And one or two or more Si less than 4a tom%, 〇la tom% or more and less than 6.00at om%, 〇at om% or more and less than 3 a tom% selected from Mg, Alkaline earth metals of Ca, Sr, and Ba, 〇1 om% or more and less than 6.0 a tom om Al, and 55a 〇m% or more and less than 65 at om% 0 as glass components. If these elements are converted into oxides, the table contains 5 mole% or more and less than 35 mole% 2p205, 50 mole% or more and less than 65 mole% 2Zn0, and 0.1 mole% or more. And less than 10 mol%, 3 〇2, 〇.1 mol% or more, and this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 male f). 13- (Please read the back Note: Please fill in this page carefully) Write your husband's order -------- line j Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 B7 V. Description of the invention (11) Less than 10 mole% 2B203, i One or two or more mole% or more and less than 20 mole% of alkaline earth metal oxides selected from ¥ 20, 080, 31′〇, and B a〇, and 0.1 mole% or more In addition, less than 10 mol% of 厶 1 203 is used as a glass component. P205 is limited to 5 mol% or more and less than 35 mol%, because glass cannot be formed because it is less than 5 mol%, and if it exceeds 35 mol%, the calcined product has poor water resistance, and The thermal expansion coefficient of the calcined product is higher than the thermal expansion coefficient of the glass substrate. That is, from the viewpoint of preventing an increase in the thermal expansion coefficient, reducing a softening point, and preventing deterioration of water resistance, the above P205 is 15 mol% or more and Less than 25 mol% is preferred. Also, 'Z η〇 is limited to 50 mol% or more and less than 65 mol%' because the thermal expansion coefficient becomes higher if it is less than 50 mol%. The softening point becomes higher at 65 mol%. This ζ η is more preferably 50 to 60 mol%. S i〇2 is limited to 0.1 mol% or more and less than 100 mol%. This is because the thermal expansion coefficient will increase if it is less than 0.1 mol%, and the softening point will increase if it exceeds 10 mol%. It is more preferable that S i02 is 1 to 5 mol%. B2 〇3 is limited to 0.1 mol% or more and less than 10 mol%, because the softening point becomes higher because less than 0.1 mol%, and if it exceeds 10 mol%, it is composed of P205. complex And the softening point becomes higher, this B203 is more preferably 1 to 5 mole%. One or two or more kinds of alkaline earth metal oxides selected from Mg0, Ca0, Sr0 and Ba are defined. More than 1 mol% and less than this paper size Applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -14 _ (Please read the precautions on the back first, fill out this page) Order ----- ---- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Ministry of Economic Affairs 1236461 A7-^ _____ B7 ^ ___ V. Description of the invention 〇 2) 2 0%, because the softening point is higher than 1%. If it exceeds 20 mol%, it has the disadvantage that glass cannot be made. The oxide is more preferably 5 to 15 mol%. Also, 'Al2O3 is limited to 0.1 mol% or more and less than 10 mol%' because the water resistance of glass becomes lower than 0.1 mol%, and more than 10 mol% on the right. It forms a composite oxide with p 2 05 and has a higher softening point. This A 1 2 3 is more preferably 1 to 5 mole%.尙 ’The above B2 03 and A 1 2 03 also have orders? 205 Stabilizing function. On the other hand, the ceramic filler contains one or two or more selected from the group consisting of chromium oxide, aluminum oxide, titanium dioxide, Codielite, mullite, / 3-eucryptite, spodumene, anorthite, barium feldspar, magnesium olive Stone and aluminum titanate ceramics. The reason why the ceramic filler is mixed in the glass composition is that, for example, when the above-mentioned glass composition and P D P partition wall are used to form on a glass substrate, the thermal expansion coefficient of the partition wall and the thermal expansion coefficient of the glass substrate are integrated. [1] Method for producing powder of glass composition First, at least one kind of Mg, Ca, Sr, and Ba is selected as an alkaline earth metal. Next, phosphoric acid or phosphate (for example, Η 3 P 0 4 and (NΗ4) 3PO4 · 3Η2〇, etc.), and zinc oxide (Zη〇), and Si 102, and boric acid (Η3B〇3), And the above-mentioned alkaline earth metal salts (for example, CaC03 and CaS04), and powders of Al203, converted into oxides as P205: 5 mol% or more and less than 35 mol paper The dimensions are applicable to China National Standard (CNS) A4 specifications (210 X 297 public love) -15- (Please read the notes on the back first ¾ fill out this page) Write too much -------- line j intellectual property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives 1236461 A7 B7 V. Description of the invention (13)%, Zn0: 50 mol% or more and less than 65 mol%, Si〇2 • · 〇 · 1 mol% or more and less than 10 mol%, B203: 0.1 mol% or more and less than 10 mol%, one or two or more alkaline earth metal oxides selected from the group consisting of Mg〇, Ca〇, SrO, and Ba〇: 1 The ratio is more than Molar% and less than 20 Molar%, and the ratio of Al203: 0.1 Molar% and more than less than 10 Molar% is measured. Next, after mixing each of the above powders using a ball mill or the like for 0.5 to 6 hours, the mixed powder is put into a platinum can, and the mixture is kept in the air at 900 to 1220 ° C for 1 to 6 hours. cool down. This quenched product is broken up and classified using a sieve with a sieve number of 200 or more (the opening of the sieve is 8 5 // m or less) to obtain a glass composition powder. The powder particle size of the glass composition is preferably 0.1 to 3 0 // m. The powder particle size of the glass composition is limited to the range of 0.1 to 3 0 // m, because it is easy to agglomerate and its operation becomes complicated because it is less than 0.1 1 m. If it exceeds 3 0 // m, The specified shape cannot be formed. [2] Preparation method of the mixture The powder of the above glass composition is classified and oxidized with a sieve with a sieve number of 200 or more (the opening of the sieve is 8 5 // m or less). One or two or more ceramic powders are selected from the group consisting of pins, oxidized titanium, titanium dioxide, Codielite, Fuming andalusite, cold-eucryptite, spodumene, anorthite, barium feldspar, forsterite and aluminum titanate Ceramic filling powder), mixed with ball mill, etc. for 1 ~ 2 4 hours' to obtain the size of the mixed paper. Applicable to China National Standard (CNS) A4 (210 X 297 mm) -16- (Please read the note on the back first Matters (Fill in this page) Write a written order --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Qin Dynasty 1236461 A7 B7 V. Description of Invention (14) Oral. The powder particle size of the ceramic filler is preferably from 0.1 to 3 0 V m. The powder particle size of the ceramic filler is limited to 0.1 ~ 3 0 // m of the 'circle' is because it is less than 0 · 1 // m, it is easy to aggregate and its operation becomes complicated. If it exceeds 3 0 // m cannot be formed into the specified shape. [3] Manufacturing method of glass paste, glass ceramic mixed paste and unprocessed flakes For the powder or mixture of the above glass composition, polymer resins such as ethyl cellulose and acrylic resin are added, and α-terpene Alcohol, butyl carbitol acetate, and other solvents were thoroughly kneaded with three rolls or the like to obtain a slurry. The powder of the ceramic filler in the mixture is preferably in a range of 5 to 30% by weight relative to the weight of the powder of the glass composition, and 30% by volume or less relative to the powder volume of the glass composition is good. If the powder of the ceramic filler is 30% by weight or more and 30% by volume or less, the insulator obtained by firing is porous, which is not preferable. In addition, the mixing ratio of each component of the prize is preferably 70 to 90% by weight of the powder of the glass composition and ceramic filler, 1 to 5% by weight of the polymer resin, and 8 to 25% by weight of the solvent. Moreover, it is also possible to produce an unprocessed sheet using this slurry. 〔4〕 Insulator production method The powder or mixture of the above glass composition is formed into a specified shape by press molding method, or the above paste is filtered by a screen printing method and extruded into a paper with Chinese national standards ( CNS) A4 specifications (210 X 297 mm) -17-(Please read the notes on the back Θ to fill out this page) Write female — — — — — — — — — Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 B7 V. Description of the Invention After the (15) molding method, injection molding method, etc. are molded into a specified shape, the molded body is dried and calcined to obtain an insulator. [5] Method for producing conductive paste or resistor paste For the powder or mixture of the above glass composition, add conductive powder or resistor powder, polymer resin, and solvent, and use three rollers, etc. Knead to obtain slurry. As the conductive powder described above, Ag, Ag-Pd, Ag-Pt, Au, AI, etc. can be used, and the resistor powder is preferably Ru02, Pb2Ru〇6.5, Ag-Pd, or the like. In addition, as the polymer resin, ethyl cellulose, acrylic resin, and the like are used, and as the solvent, α-terpineol and butylcarbitol acetate are preferably used. That is, the mixing ratio of each component in the slurry is 5 to 45% by weight of powder of glass composition and ceramic filler, 50% to 90% by weight of conductive powder and resistor powder, and polymer resin is 1 to 5 wt%, and the solvent is preferably 4 to 25 wt%. The screen printing method of the above-mentioned slurry is patterned into a specified shape, and the thick conductive film or the thick film of the resistor can be obtained by drying and calcining. Next, the use of the above-mentioned glass-ceramic mixed slurry will be described. Sandblasting method for manufacturing FPD partition walls. As shown in FIG. 1, first, a paste film 11 is formed on a glass substrate 10 by a screen printing method using the above-mentioned paste. Secondly, the glass substrate 10 having the slurry film 11 is dried at a temperature of 100 to 2000 ° C for 10 to 30 minutes, and then carried out at a temperature of 300 to 400 ° C. This paper applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) -18-(Please read the precautions on the back but fill out this page) Write a woman's order --------- Xinqin Ministry of Economic Affairs Intellectual Property Bureau employee consumer cooperative print System 1236461 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (16) 0.5 to 3 hours fake calcination. On the surface of the slurry film 11 subjected to the pseudo-calcination, a photosensitive dry film photoresist 2 (hereinafter referred to as DFR) was laminated using a laminator, and a film shield 13 was placed on DFR12, and the central wavelength 2 was irradiated. 5 4 nm ultraviolet rays were exposed. Next, 'for the exposed glass substrate 10, a Na 2 C 0 3 aqueous solution having a concentration of 0.1 to 5% was sprayed, the unexposed portion was removed, and development was performed. The glass substrate 10 having a DFR pattern layer 16 for this development is subjected to sandblasting using coarse particles such as alumina, and the slurry film 11 of the 16 portion where the DFR pattern layer 16 is not formed is removed. Ceramic raw ribs 18 are formed on 10. Furthermore, the calcination is performed at a temperature of 5 0 to 6 0 ° C for 0 · 1 to 2 hours, and a partition wall 14 can be formed on the glass substrate 10. Fig. 2 shows a second embodiment of the present invention (a method for producing a partition wall for P D P by a thick film printing method). In this embodiment, on the surface of the glass substrate 10, the above-mentioned paste is superimposed in a pattern position designated by the thick film printing method and dried after overlapping the coating to form a slurry film 31 on the glass substrate 10. This process is repeated several times so that the slurry film 31 is formed at a specified height and then calcined, and then partition walls 34 can be formed on the glass substrate 10 at a specified interval. Alas, although it is not shown in the figure, a / 3 film can be formed on a glass substrate by using the above-mentioned paste to print through a filter screen, and the substrate is dried at a temperature of 100 to 200 t for 10 to 3 After 0 minutes, calcination is performed at a temperature of 5000 to 600 ° C for 0.5 to 3 hours to form a white insulating layer on the substrate. -------- Order --------- line * (please read the notes on the back and fill in this page first) and then fill in — this paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm) -19- 1236461 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (17) Figure 3 shows the third embodiment of the present invention (the production of the back panel of an AC-type PDP) method). First, on a glass substrate 10, a conductive paste, such as Ag, is formed by a screen printing method to form a strip pattern with a width of 50 to 200 mm at a specified interval, and the temperature is 100 to After being dried at 200 ° C for 10 to 30 minutes, the address electrode 51 was formed on the glass substrate 10 by calcining at a temperature of 5000 to 600 ° C for 0.1 to 1 hour. On this glass substrate 10, a slurry film is formed by a screen printing method using the slurry prepared in the above-mentioned first embodiment, and dried at a temperature of 100 to 2000 ° C for 10 to 300 minutes. The temperature is 5 0 ~ 6 0 0 ° C, and it is calcined for 0.5 to 3 hours to form a white insulating layer 52 on the glass substrate 10. Next, on this glass substrate 10, a slurry film 1 1 is formed by the screen printing method using the slurry prepared in the above-mentioned first embodiment, and dried at a temperature of 1 0 to 2 0 0 ° C 1 to 3 After 0 minutes, the calcination was performed at a temperature of 300 to 400 ° C for 0.5 to 3 hours. After laminating the DFR12 on the surface of the false-fired slurry film 11 using a laminator, a thin film shield 13 was placed on the D F R 12 and exposed to ultraviolet rays with a central wavelength of 2 5 4 nm. Next, for the exposed glass substrate 10, a Na 2 CO 3 aqueous solution having a concentration of 0.1 to 5% was sprayed, and the unexposed portions were removed and developed. For the glass substrate 10 having the DFR pattern layer 16 for development, the coarse particles such as alumina powder are used for sandblasting, and the slurry film 11 in which the DFR pattern layer 16 is not formed is removed, and then it is transparent. The white insulating layer 5 2 on the glass substrate 10 forms a ceramic raw rib 18. (Please read the precautions on the back first to fill out this page) β Order -------- Xin Tai This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -20- 1236461 Α7 Β7 V. Description of the invention (18) The glass substrate 10 is calcined at a temperature of 5000 to 600 ° C. 1-2 hours, the white insulating layer 52 on the glass substrate 10 can be transmitted through the glass substrate 10 to form an interval. Next door 1 4. Furthermore, 'the inner surface of the element 17 between the 14 and 14 partition walls is not shown in the figure, but a paste composed of phosphor powder that emits red, green, or blue through ultraviolet light can be used.' The screen printing method is used for insert printing, and it is dried at a temperature of 100 to 200 ° C for 10 to 30 minutes, and then calcined at a temperature of 450 to 550 ° C for 0,1 to 2 hours to obtain an AC-type PDP back sheet 5 0. 4 and 5 show a fourth embodiment of the present invention (method of forming a partition wall for PDP by using a comb-blade). First, on the surface of a glass substrate 10, the slurry of the first embodiment is applied. The formed slurry film 7 1 moves the scraper 72 or the glass substrate 10 in a certain direction with the edge 7 2 a of the blade 7 2 having the comb teeth 7 2 b in contact with the surface of the glass substrate 10. Ceramic capillary ribs 73 are formed on the surface of the substrate 10. Specifically, in a state where the edge 7 2 a of the blade 7 2 is inserted into the surface of the glass substrate 10 and in contact with the surface of the glass substrate 10, the glass substrate 10 is fixed and the blade 7 2 is shown as a solid arrow in FIG. 4. Move in a certain direction, or fix the paddle 72 and move the glass substrate 10 in a certain direction with a dotted arrow as shown in FIG. 4 to form a ceramic capillary rib 73. In the above-mentioned paddle 72, a plurality of comb teeth 7 2b are formed at equal intervals and in the same direction. This paddle 72 is made of metal, ceramic, or plastic that does not react with the slurry and does not dissolve in the slurry. In particular, in terms of scale accuracy and durability, ceramics or F e 'N i, C 〇 Basic This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -21 _ (Please read the precautions on the back and fill out this page) Metals 1236461 A7 B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (5. Invention Description 09) are preferred. The gap between each comb tooth 7 2 b is formed corresponding to the cross-sectional shape of the ceramic capillary rib material 7 3 formed by the paddle 72. Through the movement of the paddle 72 or the glass substrate 10, the position of the slurry on the surface of the glass substrate 10 corresponding to the comb teeth 7 2 b of the paddle 7 2 is between the comb teeth 7 2 b The space between the gaps is moved or swept, so that only the slurry located between the gaps of the comb teeth 7 2 b remains on the glass substrate 10, and ceramic capillary ribs 73 are formed on the surface of the glass substrate 10. In the case where the depth of the comb tooth groove is greater than the thickness of the slurry film 71, when the moving paddle 72 or the glass substrate 10 is moved, the swept slurry flows into the groove to form a ceramic having a thickness above the blade film 71 Capillary ribs 7 3. The ceramic capillary ribs 73 formed in this way are subsequently dried and turned into ceramic raw ribs (not shown), and they are heated to remove the binder, and then calcined may become The partition wall 7 4 shown in FIG. 5. At this time, the calcination temperature is less than 600 t. When using soda lime glass as the glass substrate 10, the softening point (7 3 5 ° C) of the glass substrate 10 is lower than 100 ° C (glass The softening point is a temperature of about 100 ° C minus the calcination temperature), so the glass substrate 10 will not be softened, and the glass substrate 10 will not reverse. In addition, the thermal expansion coefficient of the partition wall 74 is 6 5 to 8 7 X 1 0-7 / t: which is substantially the same as the thermal expansion coefficient of the glass substrate 10 (8 5 X 1 0-7 / t). The glass composition does not contain a high-density P b component, and since the weight of the ceramic capillary ribs 73 can be reduced, the inversion of the glass substrate 10 can be further suppressed. In addition, because the glass composition does not contain V205, white reflectance can be obtained. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -22--------- Order- -------- Line Thai (please read the precautions on the back Θ to fill out this page) 1236461 A7 ____ B7 V. Description of the invention (20) High partition wall 7 4 and the ratio of the above partition wall 7 4 The electrical rate is as small as about 4 ~ 7, so the nearby signal wiring will not leak, and the image will not be disturbed. Furthermore, since the amount of ceramic filler added to the glass composition is relatively small, the strength and discharge characteristics of the partition wall 74 after firing will not be reduced. FIGS. 6 and 7 show a fifth embodiment of the present invention (method of forming a partition wall for PDP and an insulation layer for PDP by using a blade with comb teeth). This embodiment is a method of coating the surface of a glass substrate 10 The slurry film 7 1 formed by the above slurry is put on the edge 7 2 a of the paddle 7 2 having comb teeth 7 2 b on the surface of the glass substrate 10 at a specified height, so that the paddle 7 2 or the glass substrate When the 10 moves in a certain direction, a ceramic capillary inner layer 9 1 can be formed on the surface of the glass substrate 10, and a ceramic capillary rib 9 2 is formed on the ceramic capillary inner layer 9 1 (FIG. 6). The ceramic capillary inner layer 91 and the ceramic capillary rib 92 can be dried to form a ceramic raw layer and a ceramic raw rib, and then reheated to remove the binder, and then calcined on glass. An insulating layer 9 3 shown in FIG. 7 is formed on the substrate 10, and a partition wall 94 is formed on the insulating layer 9 3. That is, in the above-mentioned fifth to fifth embodiments, although the partition wall for P D P and the insulating layer for P D P are formed from the slurry of the present invention, it can also form the partition wall for P A L C and the insulating layer for P A L C. Next, a sixth embodiment of the present invention will be described. Glass composition for dielectrics, containing 1 2 at om% or more and less than 26a tom% of P, 3a tom% or more and less than 17 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297) Love 1 -23- (Please read the precautions on the back first &#; fill in this page) β Order --------- Printed by the Consumer Property Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 V. Invention Note ¢ 1) m% of Zn η, 〇 · 〇m% of Si, 〇 · 〇m% of B, 〇atcat om% or more and less than 3 at om% or more and less than 5% or more and less than 1 3 at Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs of the Employees' Cooperative Cooperative Society of one or more of the alkaline earth metals selected from Mg, Ca, Sr and Ba 'Alkaline metals' 0 · Ola t0m% and less than 5a t om% Al, And 55a tom% or more and less than 65a tom% as glass components. If these elements are converted into oxides, it is expressed as containing 205, which is 30 mol% or more and less than 70 mol%, 20 mol% or more and less than 60 mol%, 2Zn, 0 ·. 1 mol% or more and less than 10 mol% 〇2, 0.1 mol% or more and less than 20 mol% 2B203, 1 mol% or more and less than 40 mol% Or two or more oxides of alkaline earth metals selected from the group consisting of Mg0, Ca0, Sr0, and Ba0, and A 1 203 that is 0.1 mol% or more and less than 10 mol% as glass components. P205 is limited to 30 mol% or more and less than 70 mol%, because glass cannot be formed below 30 mol%, and water resistance deteriorates when it exceeds 70 mol%. That is, it is more preferable that the p 2 0 is 45 mol% or more and less than 70 mol%. Also, it is defined that Z η〇 is more than 20 mole% and less than 60 mole%, because the thermal expansion coefficient becomes higher than less than 20 mole%, and the softening point becomes higher if it exceeds 60 mole%. This ζ η〇 # 5 〇 ～ 60 mol% is more preferable. The S i〇2 is limited to 0. mol% or more and less than 丨 0 mol%, because the thermal expansion coefficient becomes higher than less than 0.1 mol%. If it exceeds (please read the precautions on the back first to fill in This page) β Order ---------- Line Thai 1234661 A7 B7 V. Description of the invention ¢ 2) The softening point becomes higher when 10 mole%, and this S 102 is 1 ~ 5 mole% as Better. (Please read the precautions on the back before filling in this page.) Also, B2 03 is limited to 0.1 mol% or more and less than 20 mol%, because the softening point is less than 0.1 mol%. If it is higher than 20 mol%, it will form a composite oxide with p205 and the softening point will be high. This 8203 is more preferably from 10 to 20 mol%. One or two or more alkaline earth metal oxides selected from the group consisting of Mg0, Ca0, Sr0, and B a0 are limited to 1 mol% or more and less than 40 mol% because less than 1 mol% The softening point is high. If it exceeds 40 mol%, there is a disadvantage that it cannot be made into glass. The oxide is more preferably 200 to 40 mol%. In addition, A 1 203 is limited to 0.1 mol% or more and less than 10 mol%, because the water resistance of glass becomes lower than 0.1 mol%, and if it exceeds 10 mol% % Forms a composite oxide with P 2 05 and the softening point becomes higher. The A 1 2 0 3 is more preferably 1 to 5 mole%. [1] Method for making powder of glass composition Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs First, at least one kind of Mg, Ca, Sr and Ba is selected as the alkaline earth metal. Second, phosphoric acid or phosphate (for example, Η 3 Po4 and (NH4) 3Po4 · 3H2〇, etc.), and zinc oxide (Zn〇), and 5 〇2, and boric acid (H3B〇3), And the above-mentioned salts of alkaline earth metals (for example, CaC03 and CaS04), and powders of Al203, converted into oxides as p205: 30 mol% or more and less than 70 mol% , Zn〇: 20 mol% or more and less than 60 mol%, this paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) ^^ 5 ^ 1236461 Α7 Β7 V. Age of Invention)

Si〇2: 0 · 1 mole% or more and less than 10 mole%, B 2 0 3: ο · 1 mole% or more and less than 0 mole%, one or two or more selected from MgO, Ca 〇, Sr〇 and Ba〇 Alkaline earth metal oxides: 1 mole% or more and less than 40 mole%, ai203: a ratio of 0.1 mole% or more and less than 10 mole% . Next, after mixing each of the above powders using a ball mill or the like for 0.5 to 6 hours, the mixed powder is put into a platinum can and maintained in the atmosphere at 900 to 1220 ° C for 1 to 6 hours. cool down. This quenched product is broken up and classified using a sieve with a sieve number of 200 or more (the opening of the sieve is 8 5 // m or less) to obtain a glass composition powder. The powder particle size of the glass composition is preferably from 0.1 to 3 0 // m. The powder particle size of the glass composition is limited to the range of 0.1 to 3 0 // m because it is easy to agglomerate and its operation becomes complicated because it is less than 0 · 1 // m. If it exceeds 3 0 // m, then The specified shape cannot be formed. [2] Preparation method of glass slurry and unprocessed flakes To the above-mentioned glass composition powder, polymer resins such as ethyl cellulose and acrylic resin, and α-terpineol and butylcarbitol acetate are added. The solvent was thoroughly kneaded with three rolls or the like to obtain a slurry. The mixing ratio of each component of the slurry is preferably 70 to 90% by weight of the powder of the glass composition, 1 to 5% by weight of the polymer resin, and 8 to 25% by weight of the solvent. Moreover, it is also possible to produce an unprocessed sheet using this slurry. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -26-

(Please read the note on the back first and write L to fill in this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 B7 V. Invention Description Port 4) [3] Method for making dielectrics (please read the note on the back first Matters written on this page) After the powder of the glass composition is formed into a specified shape by a press molding method, or the above slurry is formed into a specified shape by a screen printing method, an extrusion molding method, or an injection molding method, etc. The dielectric body can be obtained by drying and calcining the formed body. [4] Preparation method of dielectric slurry To the above-mentioned powder of the glass composition, a dielectric powder, a polymer resin, and a solvent are added, and three kneading rollers are sufficiently mixed to obtain a slurry. As the above-mentioned dielectric powder, BaTiOs, (Ba, Sr) Tio3, etc. can be preferably used. In addition, as the polymer resin, ethyl cellulose, acrylic resin, and the like are used, and as the solvent, α-terpineol and butylcarbitol acetate are preferably used. A: The mixing ratio of each component in the slurry is 5 to 45% by weight of the powder of the glass composition, 50 to 90% by weight of the dielectric powder, 1 to 5% by weight of the polymer resin, and 4 to 25% by weight is preferred. The screen printing method of the above slurry can be patterned into a specified shape, and dried and calcined to obtain a thick dielectric film. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [5] The manufacturing method of the dielectric layer of the front panel using the glass composition is shown in Figure 8. First, I TO was sputtered on a glass substrate 1 10 The transparent electrode is formed into a strip pattern with a width of 50 to 2000, and a conductive paste such as Ag is patterned on the transparent electrode by a screen printing method. Thereafter, it is dried at a temperature of 100 ~ 2 0 ° C for 1 ~ 0. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). -27-Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 B7 5. Description of the invention Calcium) After 30 minutes, calcining at a temperature of 5000 ~ 600 ° C. 〇 · 1 ~ 1 hour, then a pass electrode (Pass) is formed on the glass substrate 1 1 0 1 1 1 . Thereafter, a slurry film is formed on the glass substrate 1 10 by using a glass paste and a screen printing method, and dried at a temperature of 100 to 150 ° C for 10 to 30 minutes, and then at a temperature of 500 to 600 ° C. After firing for 0.5 to 3 hours, a transparent dielectric layer 1 12 can be formed on the glass substrate 1 10. On the substrate 1 1 0 where the transparent dielectric layer 1 12 is formed, by forming a M g0 film 1 1 3 by a deposition method, a front panel 1 100 for an AC-type PDP can be obtained. [Example] Next, the details Examples and comparative examples of the slurry for a partition wall or an insulating layer according to the present invention will be described. < Example 1 > Preparations containing P205 20 mole%, Zn〇60 mole%, Si022 mole%, B2033 mole%, Mg08 mole%, A1 20% by mole of glass powder (glass composition) 80% by weight, and 20% by weight of alumina powder having an average particle diameter of 1.8 were prepared as a ceramic filler, and the two were thoroughly mixed. The above-mentioned glass powder is specifically (NH4) 3P04 · 3H2O, Zn〇, 8 丨 2, and 1203 as P205, as it is, as Mg Co3 of ^ 2〇, They are mixed with the specified ingredients, and melted in the air at 1 150 ° C for 30 minutes and flow out on the carbon plate, and are crushed after curing (the average grain size of paper is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) -28--------- Order --------- Line I (Please read the note on the back 4 (fill out this page) Write 1231231 A7 B7 Ministry of Economy Wisdom Printed by the Consumer Cooperative of the Property Bureau. V. Invention Description (26) Diameter 3 ~ 5 // m) can be obtained. This mixed powder with ethyl cellulose of organic binder and α-terpineol of solvent is used to A weight ratio of 1/1/4 is matched, and the slurry is fully kneaded to obtain a slurry. The slurry for the partition wall or the insulating layer thus treated is regarded as Example 1 尙, the following Examples 2 to 2 3 and Comparative Examples The glass powders 1 to 12 are the same as above, and will be (NΗ4) 3 PO4 · 3Η2, Z η〇, S 〇2, and A 1 203 as P2O5, as they are, and are oxidized as alkaline earth metals. Thing M g〇, Ca〇, Sr〇 or Ba〇 MgC〇3, C a Co3, S r C03 or B a C03, respectively mixed with the specified ingredients, and in the air at 1 150 ° C melts for 30 minutes and flows out on the carbon plate, and can be obtained after solidification and crushing (average particle size: 3 ~ 5 // m). ≪ Example 2 > In addition to the glass powder containing C a 0 8 Mo The ear% instead of M g0 in Example 1 was processed in the same manner as in Example 1 to prepare a slurry. This partition wall or insulating layer slurry was considered as Example 2. < Example 3 > r 0 8 mol% instead of M g 0 in Example 1, the same process as in Example 1 was used to prepare the slurry, and this partition wall or insulating layer slurry was considered as Example 3. < Example 4 > The powder contains B a 0 8 mol% instead of the examples. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -29--------- Order ------ --- Wire '(Please read the precautions on the back before filling this page) 1236461 A7 B7 V. Description of the invention ¢ 7) Except for M g0 of this interval test 1, the same process as in Example 1 is used to produce bulk or insulating layer Think of slurry Example 4. < Exemplary Example 5 > Except that the glass powder contained P2052 Molar%, ζ π0.60 Molar%, 31202 Molar%, B2033 Molar:%, Sr Except for mol% 〇8, and mol% σ20.1%, the same treatment as in Example 1 was performed to prepare a slurry for a partition wall or an insulating layer. This slurry was used as Example 5. < Example 6 > Except that the glass powder contained 20 mol% of P205, 2 mol% of η〇60, mol% of SiO2, 2mol% of B203, and 0.1% of mol. Other than 8 mol% and Al203 9.9 mol%, the same treatment as in Example 1 was performed to prepare a slurry. The slurry $ _ for this partition wall or insulation layer was used in Example 6. < Example 7 > Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, except that the glass powder contained P2055 219 mole%, Z η 0 60 mole%, Si 〇2 0.1 mole% ,; Except for 62 mol%, S r 0 8 mol%, and Al203 mol%, the same treatment as in Example 1 was performed to prepare a slurry. This partition wall or a slurry for an insulating layer is referred to as Example 7. ^ The paper size is subject to the Chinese National Standard (CNS) A4. ^ Each (210 x 297 mm) -30- ^^--1236461 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of invention ¢ 8) < Example 8 Except that the glass powder contained 20 mol% of P205, mol of η 0 52 · 1, mol of Si 0 2 9.9, mol of Β 2 〇a 5 mol, and mol of Sr〇8 %, Al203 except for 5 mol% 'were processed in the same manner as in Example 1 to prepare the paddle. This partition wall or a slurry for an insulating layer was regarded as Example 8. < Example 9 > Except that the glass powder contained Ps 05 2 4 5 mol%, Z η 0 50 mol%, SiO 2 8 mol%, B2 03 4.5 mol%, Except for S r 0 8 mol% and A1203 5 mol%, a slurry was prepared in the same manner as in Example 1. This slurry for a partition wall or an insulating layer was regarded as Example 9. < Example 1 0 > Except that the glass powder contained P2052 Molar%, ζ η 0 64 · 9 Molar%, S i 022 Molar%, B2035 Molar%, Except for S r 0 8 mol% and Al203 mol 5%, the same treatment as in Example 1 was performed to prepare a slurry. This paddle material for a partition wall or an insulating layer is regarded as Example 10. < Example 1 1 > Except that the glass powder contained P2055 Molar%, ζ η 0 64 · 9 Molar%, Si029.1 Molar%, B203 China National Standard (CNS) A4 Specification (210 x 297 mm) -31--------- Order --------- Line Thai (Please read the precautions on the back first 41Fill this page ) f 1236461 A7 B7 V. Description of the invention ii) Except for Mohr%, sr0 8 Molar%, and Al203 5 Molar%, the same process as in Example 1 was used to prepare the slurry. This partition wall or insulating layer paste was regarded as Example 11. < Example 1 2 > Except that the glass powder contained P2053 4 · 9 mol%, Z η0 · 50 mol%, SiO2 · 2 · 1 mol%, and Β203. · Except for 1 mole%, S r 0 8 mole%, a1203 4.9 mole% except for the same treatment as in Example 1 to prepare a slurry. This slurry for a partition wall or an insulating layer is referred to as Example 12. < Example 1 3 > In addition to preparations containing B203, 30 mole%, Zη0, 20 mole%, Ba05 mole%, Sr05 mole%, Mg20 mole%, BaF2 20 Other than 60% by weight of glass powder of mole%, the same treatment as in Example 12 to form a slurry. This partition wall or a paste for an insulating layer was regarded as Example 13. < Example 1 4 > Preparations containing P205 20 mole%, zno60 mole%, SiO2 mole%, B2035 mole%, Mg04 mole%, Ca 0.4 mol%, Al203 mol% of glass powder 70% by weight, and 30% by weight of titanium dioxide powder having an average particle size of 4.4 · z / zm was prepared as a ceramic filler, and the two were thoroughly mixed . The size of this paper applies to China National Standard (CNS) A4 (210 X 297 mm) -32-

Order line Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention description po) Except for the above description, the same process is used to make the slurry. This partition wall or a paddle for an insulating layer was regarded as Example 14. < Example 1 5 > In addition to preparations containing P205 20 mole%, Zn〇60 mole%, Si022 mole%, B2033 mole%, Mg04 mole%, Ca〇4 mole%, Sr〇2 mole%,

BaO 2 mole% and Al203 5 mole% of glass powder 70% by weight were treated in the same manner as in Example 13 to form a slurry. This slurry for a partition wall or an insulating layer was regarded as Example 15. < Example 16 > Preparations containing 20 mol% of P205, 60 mol% of Zn, 2mol% of SiO2, 5mol% of B203, 8mol% of Sr0, and Al2. 35 mol% of glass powder is 80 mol%, and 20 mol% of chromium dioxide powder having an average particle diameter of 4 · 3 // m is prepared as a ceramic filler, and the two are thoroughly mixed. Except for the above, the slurry was prepared in the same manner as in Example 1. This slurry for a partition wall or an insulating layer was regarded as Example 16 ° < Example 17 > It was prepared to contain p205 20 mole%, Zn〇60 mole%, Si 0 2 2 mole%, B2 〇3 5 mol%, Sr〇8 mol%, Al203 mol% of glass powder 80 mol%, and this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)- 33-------------------- Order -------- Line Thai (Please read the notes on the back before filling this page) 1236461 A7 B7 Ministry of Economy Printed by the Intellectual Property Bureau's Consumer Cooperatives V. Description of the invention y) Prepare 20% by weight Cochelhe powder with an average particle size of 4 · 9 // m as a ceramic filler, and mix the two thoroughly. Except for the above, the slurry was prepared in the same manner as in Example 1. This paddle material for the partition wall or insulation layer was regarded as Example 17 ° < Example 1 8 > It was prepared to contain 20% by mole of P205 and 60% by mole of Zn. %, Si0 2 Mole%, B203 3 Mole%, Sr0 8 Mole%, Al203 3 Mole% 80% by weight of glass powder, and prepare 20% by weight average particle size 2 · 6 // m / 3/3-Spodumene powder is used as ceramic filler, and the two are thoroughly mixed. Except for the above, the same process as in Example 1 was used to prepare the slurry. This slurry for a partition wall or an insulating layer was regarded as Example < Example 1 9 > It was prepared to contain P205 20 mole%, ZnO 60 mole%, Si02 2 mole%, and B2055 mole. 80% by weight of glass powder, Sr〇8 mol%, Al203 mol%, and 20% by weight average particle size 2 · 9 // mi $ —Spodumene powder as ceramic filler, Mix the two together. Except for the above, the same process as in Example 1 was used to prepare the slurry. This slurry for the partition wall or insulating layer is regarded as an example < Example 2〇 > This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm)

-34T _ ϋ · ϋ 1 11 Yishenkou, a ϋ 1 ϋ ϋ I _ (Please read the notes on the back first # Fill this page)

1236461 A7 B7 V. Description of the invention (32) It is prepared to contain P205 20 mole%, zno60 mole%, S1022 mole%, B2035 mole%, Sr〇8 mole%, Al2O3 5 mol% of glass powder 70% by weight, and 30% by weight of calcium feldspar powder having an average particle diameter of 4.5 as ceramic filler and the two are thoroughly mixed. Except for the above, the processing of making the prize materials in the first embodiment is the same. This slurry for a partition wall or an insulating layer is regarded as Example 20 ° < Example 2 1 > It is prepared to contain P205 20 mole%, Zn〇60 mole%, Si〇2 mole%, B2 〇3 5mol%, Sr〇8mol%, Al2035mol% of glass powder 70% by weight, and 30% by weight of barium feldspar powder with an average particle diameter of 4.0 // m as a ceramic filler Mix and mix the two together. Except the above, the slurry was prepared in the same manner as in Example 1. This slurry for a partition wall or an insulating layer is regarded as Example 2 1 ° < Example 2 2 > It is prepared to contain P205 20 mol%, Zn〇60 mol%, SiO2 2 mol%, B2 03 5 mol%, Sr0 8 mol%, A 1 205 5 mol% of glass powder 70% by weight, and 30% by weight of forsterite powder having an average particle diameter of 2 · 9 was prepared as Fill the ceramic and mix the two thoroughly. Except for the above, the slurry was prepared in the same manner as in Example 1. Treat this partition or insulation material as an example (Please read the precautions on the back before filling this page)

--------- line | Printed by the Consumers 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm) · 35-1236461 A7 B7 Five' invention Explanation P) <Example 2 3 &gt; Prepare to contain P205 20 mole%, Z η 0 60 mole%, S1022 mole%, B203 5 mole%, Sr〇8

70% by weight of glass powder, 50% by weight of Al 2 O 3, and 30% by weight of aluminum titanate powder having an average particle size of 3 · 8 // m as ceramic filler, and the two are thoroughly mixed . Except for the above, slurry was prepared in the same place as in Example 1. This slurry for a partition wall or an insulating layer was regarded as Example 23. &Lt; Comparative Example 1 &gt; Except that the glass powder contains P205 10 mole%, Z η 0 55 mole%, Si02 2 mole%, B203 03 mole%, and 4 sr. 20 Except for Mohr% and Al203 mol%, the same treatment as in Example 1 was used to prepare a slurry. This partition wall or a slurry for an insulating layer is referred to as Comparative Example 1. Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 〇 2P contains the final powder &gt; Glass 2 Orders Except for the removal ratio &lt; Er Mo ο 2

Z 〇 〇 7 cases of ear mole compared to the visual slurry layer s I margin absolute% 3 or ear 03 wall c c 1 ο 6 A in addition to% ear mole 8

In case B, the percentage will be implemented. Ear material Mojiang 5 Production 3 Processing 〇 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1236461 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. What is the invention description? 4) &lt; Comparative Example 3 &gt; Except that the glass powder contained P205 20 mol%, Z η 0 62 mol%, SiO2 5 mol%, B203 mol%, and Sr. Other than 8 mol%, the same treatment as in Example 1 was used to prepare a slurry. This partition wall or insulating material is regarded as Comparative Example 3. &lt; Comparative Example 4 &gt; Except that the glass powder contained P2051 Molar%, Z η 0 52 Molar%, Si022 Molar%, B2033 Molar%, 5 r 0 8 Except for Mohr%, Al203 and 15 Molar%, the same treatment as in Example 1 was used to prepare a slurry. This partition wall or a slurry for an insulating layer is referred to as Comparative Example 4. &lt; Comparative example 5 &gt; Except that the glass powder contained P205 20 mole%, Z η 0 6 ◦ mole%, Si〇2 mole%, Sr〇13 mole%, A 1 2 0 3 Other than 5 mol%, the same process as in Example 1 was used to prepare a slurry. This slurry for a partition wall or an insulating layer is regarded as Comparative Example 5. &lt; Comparative Example 6 &gt; Except that the glass powder contained P2055 Molar%, Z η 0 55 Molar%, Si022 Molar%, B203 03 Molar%, S r 0 8 Except for Mohr% and Al203 mol%, paddles were prepared in the same manner as in Example 1. Consider this paste for partitions or insulation layers (please read the precautions on the back before filling this page)

Binding ---- binding ---------. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) _ 37-1236461 A7 B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs System five, invention description p) Example 6. &lt; Comparative Example 7 &gt; Except that the glass powder contained P2055 mol%, Zn〇55 mol%, Si〇2 15 mol%, Sr〇8 mol%, and A 1 205 mol. Except for ear%, the slurry was processed in the same manner as in Example 1. This partition wall or a slurry for an insulating layer is regarded as Comparative Example 7. &lt; Comparative Example 8 &gt; Except that the glass powder contained P 2 05 15 mol%, Z η 0 55 5 mol%, Si 2 0 15 mol%, B 2 03 5 mol%, and S r Other than 0.5 mol% and Al203 mol%, the same treatment as in Example 1 was performed to prepare a slurry. This partition wall or a slurry for an insulating layer is regarded as Comparative Example 8. &lt; Comparative Example 9 &gt; Except that the glass powder contained P205, 24 mol%, Z π 0, 45 mol%, Si02, 7 mol%, B2O3, 8 mol%, SrO, 8 mol%, and AI2O3. Except for 8 mol%, the same treatment as in Example 1 was performed to prepare a slurry. Consider this material for the wall or insulation layer as Comparative Example 9 ° &lt; Comparative Example 1 〇 &gt; Except that the glass powder contains P205 1 mol%, Z π 0 This paper size applies the Chinese national standard ( CNS) A4 specification (210 X 297 mm) -------- Order --------- ^^^ 1. (Please read the note 3 on the back before filling this page)

1236461 A7 B7 V. Description of the invention p6) 70 mol%, S! 02 2 mol%, b203 mol%, Sr0mol%, A1 2035% mol%, The same process as in Example 1 was performed to make the paddle. This paddle material for a partition wall or an insulating layer is regarded as Comparative Example 10 ° &lt; Comparative Example 1 1 &gt; Except that the glass powder contains P2052 Molar%, Z η 0 64 Molar%, Si〇2 9 Except for Mohr%, B2033 Moll%, S r 0 8 Mohr%, and A1203 Mohr%, the same treatment as in Example 1 was performed to prepare a slurry. This slurry for a partition wall or an insulating layer was regarded as a comparative example &lt; Comparative Example 1 2 &gt; except that the glass powder was made to contain P205 35 mole%, Z η 0 50 mole%, and 3202 moles. Except for %%, B2033 mole%, Sr0 8mol%, and Al2032 mole%, the same treatment as in Example 1 was performed to prepare a slurry. This slurry for a partition wall or an insulating layer is regarded as a comparative example &lt; comparative test and evaluation &gt; components of the glass composition contained in the purple materials of Examples 1 to 2 and Comparative Examples 1 to 12 and their respective components. The mixing ratio is shown in Table 1 as "mol%", and is shown in Table 2 as "at om%". Also in Tables 1 and 2, the components and amounts of ceramic fillers are included. (Heavy paper size applies to China National Standard (CNS) A4 specifications (210 X 297 public love) ------------ (Please read the precautions on the back before filling this page)) Order --- ----- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Qin Dynasty -ay-1236461 A7 B7 V. Description of Invention (37) Amount%). The pastes of the above-mentioned Examples 1 to 2 3 and Comparative Examples 1 to 12 were printed on a glass substrate in a pattern with a vertical and horizontal width of 2 5 mm X 2 5 mm, respectively, and were dried at 150 ° C for 1 0 After several minutes, calcination was performed at various calcination temperatures, and the lowest calcination temperature with good adhesion to the glass substrate was regarded as the calcination temperature of the glass composition and the ceramic filler (glass / ceramic) paddle. In addition, the above-mentioned hair material was poured into a mold groove of 5mmx 5mmx 2 Omm, and was calcined at the above-mentioned calcination temperature, and the thermal expansion coefficient (X 1 0-7 / ° C) and reflection of the glass substrate formed after the calcination were measured. Rate (%). The above reflectance is a measure of the reflectance of visible light (380 to 800 nm) of the fired glass / ceramic film on the glass substrate. The calcining temperature, thermal expansion coefficient and reflectance are shown in Table 3. -------------------- Order --------- Line · (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by employee consumer cooperatives The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -40-1236461 A7 B7 V. Description of Invention (38) (Table 1) Glass-making composition (mol%) Ceramic filler P205 Zn〇S10 B2O3 MgO Ca〇SrO BaO AI2O3 Component addition amount (% by weight) Example 1 20.0 60.0 2.0 5.0 8---5.0 Alumina 20 &quot; 2 20.0 60.0 2.0 5.0-8--5.0 Alumina 20 &quot; 3 20.0 60.0 2.0 5.0--8-5.0 Alumina 20 &quot; 4 20.0 60.0 2.0 5.0---8 5.0 Alumina 20 &quot; 5 20.0 60.0 2.0 9.9--8-0.1 alumina 20 ”6 20.0 60.0 2.0 0.1--8-9.9 alumina 20” 7 21.9 60.0 0.1 5.0--8-5.0 alumina 20 〃 8 20.0 52.1 9.9 5.0--8-5.0 oxidation Aluminum 20 &quot; 9 24.5 50.0 8.0 4.5--8-5.0 Alumina 20 / r 10 20.0 64.9 2.0 5.0--8-0.1 Alumina 20 &quot; 11 5.0 64.9 9.1 8.0--8-5 .0 Alumina 20 &quot; 12 34.9 50.0 2.1 0.1--8-4.9 Alumina 20 &quot; 13 20.0 60.0 2.0 5.0 4 4--5.0 Titanium Dioxide 30 &quot; 14 20.0 60.0 2.0 5.0 2 2 4-5.0 // 30, , 15 20.0 60.0 2.0 5.0 2 2 4-5.0 // 30 / r 16 20.0 60.0 2.0 5.0 1- 8-5.0 Zirconia 20 &quot; 17 20.0 60.0 2.0 5.0--8-5.0 Codielite 20 &quot; 18 20.0 60.0 2.0 5.0 --8-5.0 / 3-Spodumene 20 &quot; 19 20.0 60.0 2.0 5.0--8-5.0 Spodumene 20 &quot; 20 20.0 60.0 2.0 5.0--8-5.0 Age Feldspar 20 &quot; 21 20.0 60.0 2.0 5.0- -8-5.0 Barium feldspar 20 ”22 20.0 60.0 2.0 5.0--8-5.0 Forsterite 20 ， 23 20.0 60.0 2.0 5.0--8-5.0 Aluminum titanate 20 Comparative Example 1 10.0 55.0 2.0 5.0--20-8.0 Cannot form glass. &quot; 2 20.0 60.0 7.0 5.0----8.0 Alumina 20 〃 3 20.0 62.0 5.0 5.0--8--Show deliquescent property. &quot; 4 18.0 52.0 2.0 5.0--8-15.0 Oxidation 20 吕 5 20.0 60.0 2.0---13-5.0 Alumina 20 &quot; 6 15.0 55.0 2.0 15.0--8-5.0 Cannot form glass "7 15.0 55.0- 15.0--10-5.0 alumina 20 〃 8 15.0 55.0 15.0 5.0--5-5.0 alumina 20 &quot; 9 24.0 45.0 7.0 8.0--8-8.0 alumina 20 &quot; 10 10.0 70.0 2.0 5.0--8-5.0 Cannot form glass. ”11 2.0 64.0 9.0 9.0--8-8.0 Alumina 20” 12 35.0 50.0 2.0 3.0--8-2.0 Alumina 20 (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 Specification (210 χ 297 mm) -41-1236461 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Distributing [Table 2] Description (39) 1 1 1 1 1 I Glass composition (Mol%) Ceramic charge 1 P Zn Si B Mg Ca Sr Ba A1 〇Total ceramic component addition amount Jiwt%) 1 Example 1 12.05 18.07 0.60 3.01 2.41 0.00 0.00 0.00 3.01 60.84 100.00 Alumina K / KJ / 1 ψ. οοι '2 12.05 18.07 0.60 3.01 0.00 2.41 0.00 0.00 3.01 60.84 100.00 // ®, 00 丨 3 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 // ¢) .001 4 12.05 18.07 0,60 3.01 0.00 0.00 0.00 2.41 3.01 60.84 100.00 // Τη ~ t) .00 | * 5 12.05 18.07 0.60 5.96 0.00 0.00 2.41 0.00 0.06 60.84 100.00 // Μ〇〇1 6 12.05 18.07 0.60 0.06 0.00 0.00 2.41 0.00 5.96 60.84 100.00 // $). 00 7 12.90 17.67 0.03 2.94 0.00 0.00 2.36 0.00 2.94 61.16 100.00 // contention ^ .QQj 8 11.77 15.33 2.91 2.94 0.00 0.00 2.35 0.00 2.94 61.75 100.00 // 9 13.65 13.93 2.23 2.51 0.00 0.00 2.23 0.00 2.79 62.67 100.00 // | ο.ο ^ 10 12.61 20.45 0.63 3.15 0.00 0.00 2.52 0.00 0.06 60.57 100.00 fo. ooi 11 3.66 23.76 3.33 5.86 0.00 0.00 2.93 0.00 3.66 56.79 100.00 // moo; 12 17.82 12.77 0.54 0.05 0.00 0.00 2.04 0.00 2.50 64.27 100.00 // 20.001 13 12.05 18.07 0.60 3.01 1.20 1.20 0.00 0.00 3.01 60.84 100.00 titanium dioxide 20.00! 14 12.05 18.07 0.60 3.01 0.60 0.60 1.20 0.00 3.01 60.84 100.00 // 20.001 '15 12.05 18.07 0.60 3.01 0.60 0.60 1.20 0.00 3.01 60.84 100.00 20.0 On 16 1 2.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 Oxidation Pin 20.00] 17 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 Caduelite 20.001 18 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 / 3-Silverite 20.00! 19 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 Spodumene 20.001 20 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 # 5 Feldspar 20.0〇Γ 21 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 Mined 22 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 Forsterite 23 12.05 18.07 0.60 3.01 0.00 0.00 2.41 0.00 3.01 60.84 100.00 Aluminum titanate 20.00] Comparative Example 1 6.87 18.90 0.69 3.44 0.00 0.00 6.87 0.00 5.50 57.73 100.00 Unformable glass. 1 2 11.56 17.34 2.02 2.89 0.00 0.00 0.00 0.00 4.62 61.56 100.00 Alumina 20.0〇] 3 12.50 19.38 1.56 3.13 0.00 0.00 2.50 0.00 0.00 60.94 100.0 Display military performance. 1 4 10.23 14.77 0.57 2.84 0.00 0.00 2.27 0.00 8.52 60.80 100.00 Alumina 20.00: 5 12.62 18.93 0.63 0.00 0.00 0.00 4.10 0.00 3.15 60.57 100.00 Alumina 20.0 1 6 8.90 16.32 0,59 8.90 0.00 0.00 2.37 0.00 2.97 59.94 100.00 Intangible) Fiber &quot; Γ 7 8.96 16.42 0.00 8.96 0.00 0.00 2.99 0.00 2.99 59.70 100.00 Alumina 20.00 丨 8 9.38 17.19 4.69 3.13 0.00 0.00 1.56 0.00 3.13 60.94 100.00 // 20.001 9 12.80 12.00 1.87 4.27 0.00 0.00 2.13 0.00 4.27 62.67 100.00 // 20.0〇j 10 7.09 24.82 0.71 3.55 0.00 0.00 2.84 0.00 3.55 57.45 100.00 Invisible enamel: glass.丨 11 1.48 23.70 3.33 6.67 0.00 0.00 2.96 0.00 5.93 55.93 100.00 Alumina 20.00 丨 12 17.86 12.76 0.51 1.53 0.00 0.00 2.04 0.00 1.02 64.29 100.00 // 20.001 -—1 ~~ This paper size applies the Chinese National Standard (CNS) A4 specification ( 210 X 297 mm) -42- 1236461 A7 B7 Description of the invention (40 runs) s S Calcination temperature (° C) _Coefficient of thermal expansion (X 10'7 / ° C) Reflectance (%)

84 82 81 80 81 79 ^ 2TTU T3 Ύ〇H11 (Please read the precautions on the back before filling this page)

5 1X 16 7 li 20 1 * · 2 ο 7 ο 7 ο 7 7 7 5 5 7 5 7 5 7 8 5 8 3 8 4 8 80 2 8 3 0 8 8 0 8 than 23 Example 7 5 1X 8 glass Forming method without IX 8 18 7 3 8 --- Order --------- line j Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 5 6 ο 4 7 5 IX ο ΊΧ 8 5 8 The forming method has no fixed measurement and the dagger will not turn back to life I. The determination of the dagger is turned to the reverse hair because of the fixed measurement energy. Reverse hair growth due to glass

This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 43 1236461 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (41) As explained in Table 3, Example 1 The calcination temperature of ~ 2 3 is as low as less than 600. (: Comparatively, the calcination temperatures of Comparative Examples 2, 4, 5, 8, 9, and 11 were as high as 600 t or more, and the glass components specified in Comparative Examples 1, 6, and 10 were not vitrified. Alas, the glass of Comparative Example 3 has deliquescent properties. In addition, the thermal expansion coefficients of Examples 1 to 23 are (7 7 to 8 7) X 1 0 to 7 / ° C, and Comparative Examples 7 and 1 2 The thermal expansion coefficients are as high as 10 1 X 1 0-7 / ° C and 1 2 0X 1 0_7 / ° C. The thermal expansion coefficients of Examples 1 to 23 are the thermal expansion coefficients of the PDP glass substrate (soda lime glass) (8 5 X 1 0-7 / ° C) is almost the same. Furthermore, the 'reflectivity of Examples 1 to 2 3 is extremely high to 7 8 to 8 5%. Next', the dielectric paste for the present invention will be described in detail. Examples and comparative examples. &Lt; Example 2 4 &gt; Prepared to contain P205 35 mole%, Zη0 35 mole%,

The raw material powders of SiO2 2 mol%, b203 mol%, Mg20 20 mol%, and A1203 mol% were thoroughly mixed in a mortar. The above-mentioned raw material powder is specifically made of (NH4) 3p04.3H2O, Zn0, Si02 &amp; Al2O3 which is p205 as Mg 0 and Mg C03 of M g 0, respectively. The specified ingredients are mixed and melted in the atmosphere at 1 150 ° C for 30 minutes and flow out on the carbon plate. After curing, they can be crushed (average particle size 3 ~ 5 // m). The mixed powder, ethyl cellulose of organic binder and α-terpineol of the solvent are applied in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) at a weight ratio of this paper standard -44-- ------------------ Order --------- line (Please read the precautions on the back before filling this page) 1236461 A7 B7 Intellectual Property Bureau, Ministry of Economic Affairs Printed by the employee consumer cooperative V. Invention description (42) 10/1/4 ratio, and fully mixed to obtain slurry. The dielectric paste obtained in this way was regarded as Example 24. That is, the glass powders of the following Examples 2 5 to 3 8 and Comparative Examples 1 3 to 2 4 are also the same as above, and will be (N Η 4) 3 p 〇 4 · 3 Η 2 0 Λ Zn. , Si〇2 and A 1 203 are as they are. As test metal oxides MgO, Ca0, Sr0, or MgC03, CaC03, SrC03 or BaC03, respectively. Mix with the specified ingredients, melt in the air at 1,150 t for 30 minutes and flow out on the carbon plate. After curing, crush (average particle size 3 ~ 5 // m) shells! J is available. &lt; Example 2 5 &gt; A glass powder was processed in the same manner as in Example 24 except that the glass powder was replaced with Ca 0 2 0 mol% to M g0 in Example 1 to prepare a slurry. This dielectric paste was regarded as Example 25. &lt; Example 2 6 &gt; A glass slurry was prepared in the same manner as in Example 2 except that the glass powder contained sr02 0 mol% instead of M g 0 in Example 1. The slurry for this dielectric was treated as For Example 2 6. &lt; Example 2 7 &gt; Except that the glass powder contained B a ◦ 2 〇 旲% instead of M g〇 in Example 1, the same treatment as in Example 2 4 was used to make the slurry, and this introduction (please read the back first) Please note this page and fill in this page again) -f order --------- line 0 This paper size Gu _ Jia Xian (CNS) A4 specifications ⑵〇X 297 mm) 45

Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, printed iN invention description θ) The paste for electric bodies is regarded as Example 2 7 ◦ Example 2 8 &gt; In addition to the glass powder containing P2055 Molar%, Other than Z mol%, S 1 022 mol%, B 2 309 mol%, S r 0 18 mol%, Al 203 mol% other than the same examples 2 4 treatment to make slurry. This slurry for a dielectric material was regarded as Example 28. &lt; Example 2 9 &gt; Except that the glass powder contained P2053 Molar%, Zη0 35 Molar%, Si022 Molar%, B2033 Molar%, S Except for r 0 18 mol% and Al203 9.9 mol%, the same treatment as in Example 24 was performed to prepare a slurry. This slurry for a dielectric was regarded as Example 29. &lt; Example 3 0 &gt; Except that the glass powder contained P205 5 1 · 8 mole%, Z η 0 6 · mol%, S i 0 2 0 · 1 mole%, b 2 0 3. Except for 1 mol%, Sr05 mol%, and Al203 mol%, the same process as in Example 24 was performed. This slurry for a dielectric material was regarded as Example 30. &lt; Example 3 1 &gt; This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -4 ^ ----- 丨! Order --------— ^^^ 1. (Please read the note on the back? Matters before filling out this page)

1236461 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention f4) In addition to making the glass powder to contain P205 40 · 1 mole%

Zn〇20 Molar%, Si 〇29.9 Molar%, b2053 Molar%, Sr 020 Molar%, Al2305 Molar% other than 'Consistent Example 2 4 treatment Make paddle material. This slurry for a dielectric was regarded as Example 31. <Binsch Example 3 2> Except that the glass powder contained P2053mol%, zn〇40mol%, Si025mol%, B2033mol%, and Sr〇15 Except for Mohr%, Al203 and Molar%, the same procedure as in Example 24 was used to produce prize materials. This slurry for a dielectric was regarded as Example 3 2 0 &lt; Example 3 3 &gt; except that the glass powder was made to contain P 2 70 7 mol%, Z π 0 21.7 mol%, S i 〇2 〇1 mol%, B 2 〇a 0.1 mol%, Sr 〇8 mol%, Al203 mol 0.1%, except the same treatment as in Example 24 to prepare a slurry. This dielectric slurry was regarded as Example 33. &lt; Example 3 4 &gt; Except that the glass powder contained P205 39% by mole, Z η 050% by mole, Si022% by mole, B2 033% by mole, and Sr Except for 0 mol% and A 1 203 5 mol%, the same paper size as in this example applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- --------- Order --------- ^^^ 1 · (Please read the precautions on the back before filling this page) 1236461 A7 _________B7 __ 5. Description of the invention θ) 2 4 Make slurry. This dielectric material was regarded as Example 34. &lt; Example 3 5 &gt; Except that the glass powder contained P2O5 2 0 mole%, Z η 0 30 mole%, Sl022 mole%, B2033 mole%, and Sr〇40 mole. Other than ear%, Al203 3 mole%, the same processing as in Example 2 4 was used to produce prize materials. This dielectric material was regarded as Example 3 5 &lt; Example 36 6 &gt; except that the glass powder contained P205 35 mole%, Z η 0 35 mole%, and Si02 2 mole. Except for ear%, B203 3 mole%, M g 〇〇〇mol%, 〇03〇ΙΟ Mor%, Al203 0 5mol%, the same treatment as in Example 24 to produce oar material. Electric paste is regarded as Example 3 6 ° (Please read the precautions on the back before filling this page)

Order --------- &lt; Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 〇2 Ρ 内 有为 粉粉 &gt; Li 7 Bo 3 Orders are exempted 〇 ζ Λ% Earmo 5 3 Omo, 5 g% 3 Μ ear

A%

S ear mo 5 〇 ear mo 2

B 〇, Mo Zuo% ο ear 1 1 Mo 3 0 4 r 2 3 S Example, Shi% solid ear Tong Mo, 5 except for 0% a ear 2 C Mo _ 5 is used as a dielectric material for video slurry This will be ο slurry 7 3 cases t t 97 2 X 10 2 / V Gage A4 S) N (C standard standard home use a moderate rule paper A7 B7 1236461 i. Description of the invention (46) &lt; Example 3 8 &gt; Except that the glass powder contains P2053 mole%, Zη035 mole%, Si022 mole%, B2033 mole%,

Other than Mg0 5 Mole%, Ca0 5 Mole%, Sr0 5 Mole%, B a 0 5 Mole%, and Al2O3 5 Mole%, the same treatment as in Example 24 was performed to prepare a slurry. This slurry for a dielectric was regarded as Example 3 8 ° &lt; Comparative Example 1 3 &gt; Except that the glass powder contained P2055 28 mol%, Z η 0 21 mol%, and SiO2 2 mol. Except for ear%, B203 5 mole%, Sr 0 20 mole%, and Al203 03 mole%, the same treatment as in Example 24 was performed to prepare a slurry. This slurry for a dielectric was regarded as Comparative Example 1 3 &lt; Comparative Example 1 4 &gt; except that the glass powder was made to contain P205 7 2 mole%, Z η 0 21 mole%, and Si02 1 mole. Except for ear%, B203 1 mole%, S r 0 4 mole%, and Al203 03 mole%, the same treatment as in Example 24 was performed to prepare a slurry. This dielectric slurry was regarded as Comparative Example 1 to 4. &lt; Comparative Example 1 5 &gt; Except that the glass powder contained 5 49 mol%, Zn〇21 mol%, Si〇2 5 mol%, B203 5% mol%, and the Chinese paper standard was applied to this paper size. (CNS) A4 size (210 x 297 mm) -49-(Please read the precautions on the back before filling this page)

-------- Order --------- line j Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 V. Invention Description (47) sr The slurry was prepared in the same manner as in Example 24 except that it was 0.15 mol% and Al203 mol%. This slurry for a dielectric was regarded as Comparative Example 1 5 &lt; Comparative Example 1 6 &gt; 205 3 2 Mole%, ζ π 0 62 Mole%, Si〇2 0.5 Mole%, B2O03 0. 5 Mole%, S r 0 2 Mole%, Al2O2 Mole Except for ear%, the same treatment as in Example 2 4 was performed to prepare a slurry. This dielectric paste was regarded as Comparative Example 16. &lt; Comparative Example 17 &gt; Except that the glass powder contained P2055 Molar%, ζπ〇35Molar%, Si〇2molar%, Sr〇20Molar%, A1 2〇. Other than 35 mol%, the same treatment as in Example 24 was used to prepare a slurry. This dielectric slurry was regarded as Comparative Example 17. &lt; Comparative Example 18 &gt; Except that the glass powder contained P2055 mole%, ζηη35mol%, SiO2 11 mole%, 3202 mole%, Sr. Except for 10 mol% and Al203 mol%, the same treatment as in Example 24 was used to prepare a slurry. This slurry for a dielectric is regarded as Comparative Example 18. This i-scale is applicable to China National Standard (CNS) A4 specifications (210 X 297 Public Love -50- (Please read the precautions on the back before filling this page)

1236461

V. Description of the invention (48) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs &lt; Comparative Example 1 9 &gt; Except that the glass powder contains p205 35 mole%, Zη0 35 mole%, si. Except for 25 mol%, Sr20 mol%, and A 1 2 0 35 mol%, the same treatment as in Example 24 was performed to prepare a slurry. This slurry for a dielectric was regarded as Comparative Example 19. &lt; Comparative Example 2 〇 &gt; Except that the glass powder contained ρ2053 mol%, 211.035mol%, SiO2 4mol%, B203 mol%, and SrO 10mol. Except for ear% and Al203 mol%, the same treatment as in Example 24 was used to prepare a slurry. This slurry for a dielectric was regarded as Comparative Example 20. &lt; Comparative Example 2 1 &gt; Except that the glass powder contained P2055 Molar%, 2110445 Molar%, Si02.5 Molar%, B 2 0 a 9 Molar%, Sr Other than 0.005 mol% and Al203 mol%, the same treatment as in Example 24 was performed to prepare a slurry. This slurry for a dielectric material is referred to as Comparative Example 21. &lt; Comparative Example 2 2 &gt; Except that the glass powder contained P2053 31 mole%, 211021 mole%, Si022 mole%, and B2033 mole%.

Other than Sr〇41 mole% and Al203 ~ 2 mole%

This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) T5T (Please read the precautions on the back before filling this page)

-------- Order --------- line | 1236461 A7 B7 V. Description of the invention (49) W 2 4 treatment to make slurry. This slurry for a dielectric was regarded as Comparative Example 2 2 &lt; Comparative Example 2 3 &gt; except that the glass powder was made to contain P205 35 mole%, 211035 mole%, and SiO2 8 mole. Except for ear%, Bads 7 mole%, and sr 0 1 15 mole%, the same treatment as in Example 24 was performed to prepare a slurry. This dielectric slurry was regarded as Comparative Example 23. &lt; Comparative Example 2 4 &gt; Except that the glass powder contained P2053 Molar%, 211035 Molar%, Si022 Molar%, B2033 Molar%, S r 0 15 Except for Mohr% and Al203 mol%, the same treatment as in Example 24 was performed to prepare a slurry. This slurry for a dielectric was regarded as Comparative Example 24. &lt; Comparative test and evaluation &gt; The components of the glass composition contained in the slurry of Examples 2 4 to 28 and Comparative Examples 1 to 2 4 and the mixing ratio of each component are shown by "mole%" In Table 4, those represented by "at om%" are shown in Table 5. The pastes of Example 2 4 to 3 8 and Comparative Example 1 3 to 2 4 above were printed on soda-lime glass substrates in a pattern with a vertical X horizontal of 25 mm X 25 mm, respectively, and at 150 ° C After 10 minutes of drying, it is calcined at various calcination temperatures, and will have good adhesion to the glass substrate and the lowest calcination (please read the precautions on the back before filling this page)

-------- Order --------- Printed by the Consumers Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of Qinqin This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm)- 52-1236461 A7 _B7_ V. Description of the invention (50) The firing temperature is regarded as the firing temperature of the slurry of this glass composition. In addition, the slurry was poured into a mold groove of 5mmx 5mmx 2 Omm, and calcined at the calcining temperature described above, and the thermal expansion coefficient (X 1 0 ^ 7 / ° C) and visible light of the glass substrate formed after calcination were measured. Transmission rate (%) and specific dielectric rate (%). The coefficient of thermal expansion (X 1〇_7 / ° C), visible light transmittance (%) and specific permittivity (%) are shown in Table 6 ° (Please read the precautions on the back before filling this page) f Order- -------- Yuant Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -53- 1236461 A7 B7 V. Description of invention P ) [Table 4] Printed glass group of the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, finished product (mole%) P205 Zn〇Si〇2 B2 03 Mg〇Ca〇SrO Ba〇Ab〇3 Example 24 35.0 35.0 2.0 3.0 20 • 5.0 &quot; 25 35.0 35.0 2.0 3.0 20 _-5.0 &quot; 26 35.0 35.0 2.0 3.0-_ 20 _ 5.0 &quot; 27 35.0 35.0 2.0 3.0-. 20 5.0 ”28 35.0 35.0 2.0 9.9 Sun 18-0.1 &quot; 29 35.0 35.0 2.0 0.1--18 9.9 ”30 31.8 60.0 0.1 0.1-_ 5 3.0 &quot; 31 40.1 20.0 9.9 5.0-_ 20-5.0 &quot; 32 30.0 40.0 5.0 5.0 15 • 5.0 &quot; 33 70.0 21.7 0.1 0.1 -• 8 _ 0.1 &quot; 34 39.0 50.0 2.0 3.0-1-5.0 &quot; 35 20.0 30.0 2.0 5.0-40 3.0 &quot; 36 35.0 35 .0 2.0 3.0 10 10 _ 5.0 &quot; 37 35.0 35.0 2.0 3.0 5 5 10 5.0 &quot; 38 35.0 35.0 2.0 3.0 5 5 5 5 5.0 Comparative Example 13 28.0 37.0 2.0 5.0 _ 20 _ 8.0 &quot; 14 72.0 21.0 1.0 1.0 -One 4-1.0 &quot; 15 49.0 21.0 5.0 5.0-15 5.0, 16 32.0 62.0 0.5 0.5--2 2.0 &quot; 17 35.0 35.0 One 5.0-one 20 one 5.0 &quot; 18 35.0 35.0 11.0 4.0-one 10 _ 5.0 &quot; 19 35.0 35.0 5.0 _-20 5.0 &quot; 20 35.0 35.0 4.0 11.0-10-5.0 &quot; 21 35.0 45.0 5.5 9.0-0.5 8.0 &quot; 22 31.0 21.0 2.0 3.0-41 2.0 &quot; 23 35.0 35.0 8.0 7.0 15 _ ”24 35.0 35.0 2.0 2.0-15-11.0 (Please read the precautions on the back before filling this page) f · 11111 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -54-1236461 A7 B7 V. Description of invention since 2) [Table 5] Printed glass composition (at om%) of employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs P Zn Si B Mg Ca Sr Ba A1 〇 Total Example 24 17.46 8.73 0.50 1.50 4.99 0.00 0 · 00 0.00 2.49 64.34 100.00 // 25 17.46 8.73 0.50 1.50 0.00 4.99 0.00 0.00 2.49 64.34 100.00 // 26 17.46 8.73 0.50 1.50 0.00 0.00 4.99 0 · 00 2.49 64.34 100.00 // 27 17.46 8.73 0.50 1.50 0.00 0.00 0.00 4.99 2.49 64.34 100.00 // 28 17.20 8.60 0.49 4.86 0.00 0.00 4.42 0.00 0.05 64.37 100.00 // 29 17.20 8.60 0.49 0.05 0.00 0.00 4.42 0.00 4.86 64.37 100.00 // 30 17.26 16.29 0.03 0.05 0.00 0.00 1.36 0.00 1.63 63.38 100.00 // 31 18.21 4.54 2.25 2.27 0.00 0.00 4.54 0.00 2.27 65.92 100.00 // 32 15.58 10.39 1.30 2.60 0.00 0.00 3.90 0.00 2.60 63.64 100.00 // 33 25.42 3.94 0.02 0.04 0.00 0.00 1.45 0.00 0.04 69.09 100.00 // 34 18.53 11.88 0.48 1.43 0.00 0.00 0.24 0.00 2.38 65.08 100.00 // 35 12.27 9.20 0.61 3.07 0.00 0.00 12.27 0.00 1.84 60.74 100.00 // 36 17.46 8.73 0.50 1.50 2.49 2.49 0.00 0.00 2.49 64.34 100.00 // 37 17.46 8.73 0.50 1.50 1.25 1.25 2.49 0.00 2.49 64.34 100.00 // 38 17.46 8.73 0.50 1.50 1.25 1.25 1.25 1.25 2.49 64.34 100.00 Comparative Example 13 14.70 9.71 0.52 2.62 0.00 0.00 5.25 0.00 4.20 62.99 100.00 // 14 25.40 3.70 0.18 0.35 0.00 0.00 0.71 0.00 0.35 69.31 100.00 // 15 20.42 4.38 1.04 2.08 0.00 0.00 3.13 0.00 2.08 66.88 100.00 ”16 17.49 16.94 0.14 0.27 0.00 0.00 0.55 0.00 1.09 63.52 100.00 // 17 17.28 8.64 0.00 2.47 0.00 0.00 4.94 0.00 2.47 64.20 100.00 // 18 16.95 8.47 2.66 1.94 0.00 0.00 2.42 0.00 2.42 65.13 100.00 // 19 17.72 8,86 1.27 0.00 0.00 0.00 5.06 0.00 2.53 64.56 100.00 // 20 16.39 8.20 0.94 5.15 0.00 0.00 2.34 0.00 2,34 64.64 100.00 // 21 16.00 10.29 1.26 4.11 0.00 0.00 0.11 0.00 3.66 64.57 100.00 // 22 16.67 5.65 0.54 1.61 0.00 0.00 11.02 0.00 1.08 63.44 100.00 // 23 17.33 8.66 1.98 3.47 0.00 0.00 3.71 0.00 0.00 64.85 100.00 // 24 16.83 8.41 0.48 0.96 0.00 0.00 3.61 0.00 5.29 64.42 100.00 (Please read the precautions on the back before filling in this page) f ------- order --------- line j This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm)-55- 1236461 A7 B7 V. Description of Invention (53) [Table 6] Calcination temperature (° C) printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Expansion coefficient (X i〇-7rc) Visible light transmittance (%) Specific permittivity (%) Example 24 570 83 82.5 15.2 &quot; 25 570 79 81.5 13.0 &quot; 26 550 75 85.8 15.1 &quot; 27 570 81 79.4 14.0 &quot; 28 550 76 78.2 14.9 &quot; 29 580 76 81.1 13.9 &quot; 30 5 80 74 81.0 11.1 &quot; 31 570 80 78.5 14.2 &quot; 32 550 79 77.2 13.0 &quot; 3 3 550 82 84.2 11.2 &quot; 34 570 78 76.5 10.8 &quot; 35 580 81 77.7 16.1 &quot; 36 570 82 81.0 12.8 &quot; 37 550 80 81.8 13.8 &quot; 38 570 82 80.8 13.0 Comparative Example 1 3 Cannot turn into glass &quot; 14 Display deliquescent &quot; 15 570 91 75.1 11.1 &quot; 16 680 80 69.5 8.3 &quot; 17 640 102 68.1 14.9 &quot; 18 690 71 78.5 11.2 &quot; 19 610 74 31.0 13.9 &quot; 20 610 78 78.5 7.2 &quot; 21 550 81 57.9 5.8 &quot; 22 cannot be turned into glass &quot; 23 Display deliquescent &quot; 24 680 72 51.7 10.1 (Please read the precautions on the back before filling this page) f Order -------- line t This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -56-1236461 A7 B7 5. Description of the invention (54) As explained in Tables 4 to 6, the calcination temperatures of Examples 2 to 3 to 8 are as low as less than 60 ° C, and the calcination temperatures of Comparative Examples 16 to 20 and 24 are as high as 60. Above 0 ° C, the glass components specified in Comparative Examples 1 3 and 2 2 were not vitrified. Alas, the glass agents of Comparative Examples 1 4 and 23 showed deliquescence. In addition, the thermal expansion coefficients of Examples 2 to 3 to 8 are (7 4 to 8 2) X 1 0 to 7 / ° C. In contrast, the thermal expansion coefficients of Comparative Examples 15 and 17 are as high as 9 1 X 1 0 -7 / t: and 1 2 0 X 1 〇-7 / t :. In Example 2, the thermal expansion coefficient of 4 to 38 is approximately the same as the thermal expansion coefficient of the P D P glass substrate (soda lime glass) (85 5 X 1 0-7 / ° C). Furthermore, the visible light transmittance of Example 2 4 to 3 8 is extremely high to 7 7 · 2 to 84 · 2%, and this dielectric rate also shows a local problem of 10 · 8 to 16 · 1%, and The electric body showed proper maggots. [Effects of the Invention] As described above, according to the present invention, the glass component of the glass composition contains 5 mol% or more and less than 35 mol% iP205, 50 mol% or more and less than 65 Mole% 2Zn0, 0.1 Mole% or more and less than 10 Molei 02, 0.1 Mole% or more and less than 10 Mole% 2B203, 1 Mole% or more and less One or more than 20 mole% of oxides of alkaline earth metals selected from the group consisting of “20, 080, 81′〇, and B a〇, and more than 0.1 mole% and less than 10 旲A 1 203%, so the calcination temperature becomes lower, and the softening point of the insulator obtained by calcining the glass composition becomes lower. In addition, because the above-mentioned glass paper size applies the Chinese National Standard (CNS) A4 specification ( 210 X 297 mm) -57-(Please read the notes on the back before filling out this page) Order -------- Line i Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1236461 A7 B7 V. Description of the invention (55) The component does not contain a high-density pb component, so the weight of the insulator can be reduced, the environment will not be polluted, and the discharge will not be caused during use. In addition, compared with the previous plasma display which contains a large amount of p205 and an alkali metal oxide, the thermal expansion coefficient of the glass is larger than that of the glass substrate, the P205 in the present invention is smaller. And because it does not contain an alkali metal oxide, it can suppress the thermal expansion coefficient of the insulator from rising, and can improve the water resistance of the insulator. In addition, in the above glass composition, if the ceramic pin is mixed with the oxidation pin and oxidation of the ceramic filler When ceramics such as aluminum and titanium dioxide are made into a mixture, the thermal expansion coefficient of the insulator obtained by calcining the mixture can be reduced. And the thermal expansion coefficient of this insulator can be integrated with the thermal expansion coefficient of the glass substrate. A composition or a mixture, adding a conductive powder or a resistor powder, a polymer resin, and a solvent to prepare a slurry, and coating and calcining the slurry on a glass substrate to produce a thick conductive film or a thick conductive film, A thick film having high adhesion to the substrate can be obtained. When a polymer resin and a solvent are added to the glass composition or the mixture, As a slurry or an unprocessed sheet, the paste or the unprocessed sheet is calcined to make an insulator, a partition wall for FPD or an insulating layer for jT pd. Because the firing temperature of the glass composition can be made softer than that of the glass substrate The temperature is lower than 100 ° C, and the thermal expansion coefficient of the insulator, partition wall or insulating layer is almost the same as the thermal expansion coefficient of the glass substrate, so the glass substrate does not reverse. In addition, the insulator, partition wall or insulating layer The specific permittivity is as small as about 4 ~ 7, so the electrical signal will not leak to the adjacent wiring, and there will be no image interference. In addition, the ceramic filling material applies the Chinese National Standard (CNS) for this paper size. A4 specifications (210 X 297 mm) · 58-(Please read the precautions on the back before filling out this page) Order -------- line j Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives 1236461 A7 B7 5 Explanation of the invention (57) '[Fig. 4] A perspective view showing a forming state of a ceramic capillary rib material according to a fourth embodiment of the present invention. [Fig. 5] A cross-sectional view of a partition wall for P D P obtained by drying, heating and calcining the ceramic capillary ribs in the cross section taken along line A-A in Fig. 4 is shown. [Fig. 6] A perspective view corresponding to Fig. 4 showing a molding state of a rib with a ceramic capillary inner layer according to a fifth embodiment of the present invention. [Fig. 7] A cross-sectional view corresponding to Fig. 5 showing a partition wall with an insulating layer obtained by drying, heating and sintering a rib with a ceramic capillary inner layer in a cross section taken along line B-B in Fig. 6 . [FIG. 8] A process drawing for making a front panel of a sixth embodiment of the present invention. [Fig. 9] An enlarged sectional view of a main part of P D P. (Please read the precautions on the back before filling out this page) -------- tr --------- line «i · Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Description of Symbols] 10 Glass substrate 14, 34, 74, 94 Partition wall 52, 93 Insulating layer 112 Dielectric layer The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -60-

Claims (1)

A8 B8 C8 D8 [2364 丨 VI. Patent Application No. 89 1 05 890 Patent Application Chinese Patent Application Amendment Amendment on March 23, 1994 (please read the precautions on the back before filling out this page) 1 · An FPD room Glass composition for partition wall or insulation layer, which contains 3.5 mole% or more and less than 18 mole% 2P, 12.5 mole% or more and less than 24 mole% 2η, 0.02 mole% or more And one or two or more of less than 4 moles, 0.001 mole% or more and less than 6.0 mole%, 0 mole% or more and less than 3 mole% are selected from Mg, Alkaline earth metals grouped by Ca, Sr, and Ba, 0.01 mole% or more and less than 6.0 mole%, 61, and 55 mole% or more and less than 65 mole%, as Glass composition. Printed by the Consumer Cooperatives of the Smart Wealth House Bureau of the Ministry of Economic Affairs 2 · A glass composition for F P D partitions or insulation layers, which is more than 5 mole% and less than 35 mole%? 2 mol, 50 mol% or more and less than 65 mol% 2η〇, 0.1 mol% or more and less than 10 mol i2, 0.1 mol% or more and less than 10 Mole% 2B203, 1 or more than 1 Mole% and less than 20 Mole% selected from the group consisting of oxides of alkaline earth metals in the group of Mg0, Ca0, SrO, and Ba0, and厶 1,203, which is 1 mol% or more and less than 10 mol%, is used as a glass component. 3. The glass composition according to item 1 or 2 of the scope of patent application, which is a mixture of one or two or more selected from the group consisting of oxide pins, alumina, titania, Codie 1 ite, andalusite, and cold-eucryptite , Spodumene, feldspar, barium feldspar, forsterite, and aluminum titanate are ceramic mixtures of ceramics. This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1236461 A8 B8 C8 D8 Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. Scope of patent application4. The glass composition of item 2, which further contains the mixture of the glass composition of item 3 in the scope of the patent application, the polymer resin, and the solvent is used as the slurry for the partition wall or the insulating layer. The glass composition according to item 2 or item 2, which contains the mixture, conductor powder or resistor powder or dielectric powder, polymer resin, and solvent as described in item 3 of the patent application scope, and is used as a prize for thick films. . 6 · If the glass composition in the scope of patent application item 1. or item 2, it is a mixture containing the glass composition in the scope of patent application item 3, a polymer resin, and a solvent as a partition wall or an insulating layer Use with raw flakes. 7 · If the glass composition of the scope of application for item 1 or 2 is applied, it is formed by calcining the mixture of the glass composition of scope of application for item 3 and used as an insulator. 8 · The glass composition according to item 4 of the scope of patent application, which is formed by calcining the slurry, and is used as a partition wall or insulation layer. Thick film. 9 · The glass composition according to item 5 of the scope of patent application, which is formed by calcining the slurry, and is used as a thick film for conductors, resistors or dielectrics. 10. If the glass composition of the first or second item of the scope of the patent application is used, the partition wall or the insulating layer is formed by calcining the mixture of the glass composition of the third aspect of the patent application, and is used as the FPD. 1 1 · A glass composition for F P D partition wall or insulation layer, which contains 12 mol% or more and less than 26 mol 3 mol% (Please read the precautions on the back before filling this page) Binding. The paper size of the book is applicable to China National Standards (CNS) A4 (210X297 mm) ABCD 1236461 6. Apply for patents that are above the scope and less than 17 mol% 2] 1, 〇.〇1 mol% and above One or two or more kinds of 3 i, 〇i mol% or more and less than 5 mol% B, 0 mol% or less, and less than 5 mol%, or one or two or more kinds selected from Mg, Alkaline earth metals grouped by Ca, Sr, and Ba, 〇1 mol% or more and less than 5 mol1, and 55 mol% or more and less than 65 mol% as glass components. 1 2 · A glass composition for an F P D partition wall or an insulating layer, which contains 30 mol% or more and less than 70 mol%? 205, 200 mol% or more and less than 60 mol% 2Zn 〇, 丄 mol% or more and less than 10 mol% 3 mol, 0.2 mol% or more and less 32 mol of 20 mol% or more, and one or more of mol% or more and less than 40 mol% is selected from the group of alkaline earth metals grouped by Mg〇, Ca〇, s′〇, and Ba〇. Oxides, and 8 mol% or more and less than 100 mol% were used as the glass component. 1 3 · If the glass composition of item 丄 i or 丄 2 of the scope of patent application, it contains polymer resin and solvent, and is used as a dielectric paste. 1 4. If the glass composition of item 范 (1) or (2) of the patent application park contains a polymer resin and a solvent, it is used as an unprocessed sheet for a dielectric. 1 5 · If the glass composition of item 11 or item 2 of the scope of patent application is formed by calcination, it is used as a dielectric. 1 6 · If the glass composition of item 1 丨 or item i 2 of the scope of patent application 'is used, the dielectric layer is formed by firing and used as FpD. This paper size is in accordance with Chinese National Standard (CNS) A4 specification (; 21 × 297 mm). Please read the note on the back of item I to re-bind. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. -3-