TW587412B - Interlayer connection structure and its forming method - Google Patents
Interlayer connection structure and its forming method Download PDFInfo
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587412 玖、發明說明 (發明說明應敘明:發明所屬之技術領域、先前技術、內容、實施方式及圖式簡單說明) 【發明戶斤屬之技術領域3 技術領域 本發明係有關於一種用以於多層配線基板等形成配線 層間之導電連接構造或層間之放熱構造的層間連接構造形 5 成方法,與藉該方法所形成之層間連接構造及多層配線基 板。 t先前技術3 背景技術 近年來隨著電子機器等的小型化和高機能化,亦漸提 10 高對於用以組裝電子零件之配線基板的多層化、薄層化、 精細圖案化等要求。因此,構成多層配線基板之絕緣層和 配線層也傾向於薄層化。又,當對應於高週波信號而控制 特性阻抗時,須高精度地控制絕緣層和配線層之厚度。 在製造多層配線基板時,須有於絕緣層上形成金屬層 15 和配線圖案之步驟,而該等方法一般是積層帶有樹脂之銅 箔的方法,和蝕刻以該方法所形成之金屬層,俾形成圖案 的方法等。眾所皆知的更有於轉寫用基材形成配線層,再 將其轉寫於設在配線基板最外層之熱接著性絕緣層的方法 20 此外,於多層配線基板需有用以將配線層間導電連接 之構造,因而有幾個構造是經由層間連接突起,而在層間 連接有形成於絕緣層兩面之配線層或金屬層的層間連接構 造。舉例言之,曰本專利公開公報特開平6-314878號中揭 示有一方法’係於下層之配線層’積層通 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 6 玖、發明說明 發明說明,續頁 孔部分有開口的抗鍍敷層後,藉電鍍銅而於開口内部形成 柱狀金屬體,接著除去抗鍍敷層,再於全面塗布絕緣性樹 脂使之平坦化後,形成上層之配線層,藉此將配線層間導 電連接。 又,WOOO/52977號中揭示有一方法,係在進行構成 柱狀金屬體之金屬的蝕刻時,將顯現抗蝕性之另一金屬包 覆於包括下層之配線層之非圖案部,俾形成保護金屬層, 且藉電解鍍敷於該保護金屬層全面以形成用以構成前述柱 狀金屬體之金屬的電鍍層後,進行可侵蝕該保護金屬層的 蝕刻,俾除去用以包覆非圖案部之保護金屬層後,再於全 面塗布絕緣性樹脂使之平坦化後,形成上層之配線層,藉 此將配線層間導電連接。 然而’如前所述般塗布絕緣性樹脂以形成絕緣層之方 法中,塗布、硬化、平坦化如此一系列的步驟很繁雜,同 時也難以維持絕緣層之厚度精度(平坦化度)。 另一方面,亦有幾個已知方法是於形成有配線層間連 接用金屬體突起(包含柱狀金屬體)之配線層上,積層熱 接著性樹脂片和帶有銅箔之樹脂片,藉此形成絕緣層。尤 其是當積層帶有銅箔之樹脂片時,由於同時亦積層銅箔, 故有可藉將其蝕刻形成上層之配線層的優點。 但是’依此所形成之導電連接構造中,正因銅箔是壓 接金屬遽突起,且兩者間易隔有樹脂,導致面與面之間難 以~ 地接觸等,因而配線層間之導電連接可靠性並不充 分。特別是若絕緣層包含有補強纖維時,補強纖維就會妨 次貝(發說贿不敷使用時,請註記並使用續頁) 587412 玖、發明說明 發明說明續頁 礙接觸,導致無法進行導電連接。 因此,本發明之目的在於提供一種可將隔在層間的絕 緣層厚度平坦化,且即使絕緣層包含有補強纖維時,也可 控制表面平坦化和絕緣層厚度的層間連接構造形成方法, 5與藉該方法所形成之層間連接構造及多層配線基板。 L發明内容3 發明開示 藉以下所述之本發明可達成前述目的。另,本發明之 層間連接構造之形成方法包含有第1發明〜第3發明。 10 即,第1發明係一種層間連接構造之形成方法,該層 間連接構造係經由層間連接突起,而在層間連接有形成於 絕緣層兩面之配線層或金屬層者,包含有:(la)於衝壓面 和形成有該層間連接突起的被積層體之間,至少將可容許 凹狀變形之片材,金屬層形成材,及熱接著性絕緣層形成 15材,依此順序配置的步驟;(lb)在該配置狀態下,藉衝壓 面進行加熱衝壓,俾獲得於對應於層間連接突起之位置具 有凸部,且於表面形成有金屬層之積層體的步驟;(lc)除 去該積層體之凸部,使層間連接突起露出的步驟;及(ld )將已露出之層間連接突起,與隔著絕緣層相近之金屬層 2〇 導電連接的步驟。 依第1發明之層間連接構造之形成方法,因為於衝壓 面和被積層體之間配置可容許凹狀變形之片材,再將金屬 層形成材,熱接著性絕緣層形成材,及被積層體加熱衝壓 ,所以可於對應於層間連接突起之位置,產生片材之凹狀 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 玖、發明說明 發明說明續頁 又开/俾確保絶緣層形成材之溢出處。因此,層間連接突 (周邊之、、’巴緣層厚度不易變化,又,因為在後續步驟中除 去相當於溢出處之凸部’所以層間連接突起之上方亦變得 平-攸而,可形成一邊將隔在層間的絕緣層厚度均一化 ’且即使絕緣層包含有補強纖維時,也可一邊將表面平坦 I間連接構造。又’由於熱接著性絕緣層形成材為片 支若/、k布方式比較,其係可適當地因應絕緣層之薄 層化還有,由於除去積層體之凸部,使層間連接突起露 出後’再將已露出之層間連接突起與其周圍之金屬層導電 連接’故可將絕緣層兩面之金屬層導電連接。另,由於在 使用可谷4凹狀變形之片材的方法中,即使層間連接突起 之形成位置不同時,亦可使用相同片材,故適於量產化。 宜使用具有脫模性之塾紙,金屬箱,或具有脫模性之 橡膠片作為刖述片材。此時’於片材可形成適於產生適度 凹狀變形而獲得之積層體的凸部’又,片材和積層體之金 屬層的脫模亦容易。 又第2發明係一種層間連接構造之形成方法,該層 間連接構造係經由層間連接突起,而在層間連接有形成於 絕緣層兩面之配線層或金屬層者,包含有:(2a)於衝壓面 與該層間連接突起相對之位置形成凹部,或配置用以形成 該凹部之板的步驟;(2b)於衝壓面和形成有該層間連接突 起的被積層體之間’至少將金屬層形成材及熱接著性絕緣 層形成材,依此順序配置的步驟;(2c)在該配置狀態下, 藉衝壓面進行加熱衝壓,俾獲得於對應於層間連接突起之 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 玖、發明說明 發明說明續頁 位置具有凸部,且於表面形成有金屬層之積層體的步驟;( 2d)除去該積層體之凸部,使層間連接突起露出的步驟; 及(2e )將已露出之層間連接突起,與隔著絕緣層相近之 金屬層導電連接的步驟。 依弟2毛明之層間連接構造之形成方法,由於配置與 層間連接突起相對之位置形成有凹部的衝壓面或用以形成 凹部之板面,藉此加熱衝壓金屬層形成材,熱接著性絕緣 層形成材及被積層體,故可確保於層間連接突起之形成位 置有絕緣層形成材之溢出處。因此,層間連接突起周邊之 絕緣層厚度不易變化,又,因為在後續步驟中除去相當於 溢出處之凸部,所以層間連接突起之上方亦變得平坦。從 而,可形成一邊將隔在層間的絕緣層厚度均一化,且即使 絕緣層包含有補強纖維時,也可一邊將表面平坦化的層間 連接構造。又,由於熱接著性絕緣層形成材為片狀,故若 與塗布方式比較,其係可適當地因應絕緣層之薄層化。還 有’由於除去積層體之凸部,使層間連接突起露出後,再 將已路出之層間連接突起與其周圍之金屬層導電連接,故 可將絕緣層兩面之金屬層導電連接。 第3發明係一種層間連接構造之形成方法,該層間連 接構造係經由層間連接突起,而在層間連接有形成於絕緣 層兩面之配線層或金屬層者,包含有··(3a)將形成有該層 間連接突起之被積層體,熱接著性絕緣層形成材,及金屬 層形成材積層而使之一體化,使該層間連接突起之上面位 於该金屬層形成材的表面附近的步驟;(3 b )至少將該金屬 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 發明說明續頁 玖、發明說明 曰七成材中與4層間連接突起之上面重疊的部份進行钱刻 场成開Π的步驟,(3e)至少除去自該開卩露出之絕緣層 的一部份,使該層間連接突起之上面露出的步驟;及(3d )由已露出之該層間連接突起之上面,至少擴及至該開口 之内周面以形成導電體層的步驟。 从依第3發明之層間連接構造之形成方法,由於使用熱 著h邑、、彖層形成材及金屬層形成材以積層,故表面之平 坦性良好,對於製程亦有利。又,由於熱接著性絕緣層形 成材為片ίί大i文右與塗布方式比較,其係可適當地因應絕 緣層之薄層化。旻谁_半 旯進步,由於將與該層間連接突起之上 面重疊的部份進㈣刻以形成開口,故經由該開π除去絕 緣層’藉此可使層間連接突起之上面露出。藉此,因為由 路出之4層間連接突起之上面,至少擴及至該開口之内 周面以形成導㈣層,所師習知技術之僅錢接構造是 不同的T進订確實之導電連接,故配線層等與層間連接 突起的導電連接可靠性較高。 ^ 面本毛明之層間連接構造,係經由層間連接 I而在層間連接有形成於絕緣層兩面之配線層或金屬 曰者/、特U在力·该層間連接突起之上面自絕緣層露出 〇 fW刀藉導f體層與隔著絕緣層相近之該配線層或金屬層 連接依本發明之層間連接構造,由於層間連接突起之上 面自絕緣層露出的部份藉導電體層與隔著絕緣層相近之該 配線層或金屬層預先連接,故可使用本發明之形成方法製 造」所以可形成將隔在層間的絕緣層厚度均一化,且即使 _次頁(說類不雜_,請註記並使用麵) 587412 發明說明If頁 也可將表面平坦化和控制絕緣 玖、發明說明 絕緣層包含有補強纖維時 層厚度的層間連接構造。 在前述中’前述導電體層以藉鍍敷形成者為佳。若導 5 電體層是藉錄敷形成時,可形成導電連接可靠性更高的層 間連接構造。 9 另一方面,本發明之多層配線基板,其特徵係於任一 層間設有如前述之層間連接構造者。依本發明之多層配線 基板’由於在任一層間存在有前述層間連接構造,故為一 具有可將隔在層間的絕緣層厚度均一化,且即使絕緣層包 1〇含有補強纖維時,也可將表面平坦化和控制絕緣層厚度, 導電連接可靠性高之層間連接構造的多層配線基板。 圖式簡單說明 第1圖(1)、(2)〜第2圖(3)、⑷、(5)係顯示第 1發明之層間連接構造形成方法之一例的步驟圖。 15 第3圖(a)、(b)係顯示第1發明之層間連接構造形 成方法之另一例的步驟圖。 第4圖(a)、⑴〜第5圖(a)係顯示第2發明之層 間連接構造形成方法之一例的步驟圖。 第6圖(1)、(2),第7圖⑺、⑷、(5),第8圖( 20 6)、⑺、⑴,第9圖(9)、(1〇)、(⑴係顯示第2發明 之層間連接構造形成方法之一例的步驟圖。 C實方方式]1 用以實施發明的最佳形態 (第1發明之層間連接構造之形成方法) 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 587412 發明說明 玖、發明說明 本實施形態中所顯示之例係形成經由層間連接突起Β ,而在層間連接有形成於核心基板兩面之配線層22,以及 隔著絕緣層26且形成於其上層之金屬層27的層間連接構 造。 5 首先,如第1圖(1)所示,準備一被積層體L,係於587412 发明 Description of the invention (The description of the invention should state: the technical field to which the invention belongs, the prior art, the content, the embodiments, and the drawings.) [Technical Field 3 of the Inventor's Family] Technical Field The present invention relates to a method for An interlayer connection structure forming a conductive connection structure or a heat release structure between layers in a multilayer wiring substrate or the like forms a method, and the interlayer connection structure and the multilayer wiring substrate formed by this method. Prior Art 3 Background Art In recent years, with the miniaturization and high performance of electronic devices and the like, there have been increasing demands for multilayering, thinning, and fine patterning of wiring boards for assembling electronic components. Therefore, the insulating layer and the wiring layer constituting the multilayer wiring substrate also tend to be thinner. When controlling the characteristic impedance in response to a high frequency signal, it is necessary to control the thickness of the insulating layer and the wiring layer with high accuracy. When manufacturing a multilayer wiring substrate, there must be a step of forming a metal layer 15 and a wiring pattern on an insulating layer. These methods are generally a method of laminating a copper foil with a resin, and etching a metal layer formed by the method.的 A method of forming a pattern and the like. A well-known method is to form a wiring layer on a transfer substrate, and then transfer it to a thermally-adhesive insulating layer provided on the outermost layer of the wiring substrate. In addition, in multilayer wiring substrates, it is necessary to use the There are several structures for conductive connection. Interlayer connection structures are formed by connecting wiring layers or metal layers formed on both sides of an insulating layer through interlayer connection protrusions. For example, Japanese Patent Laid-Open Publication No. Hei 6-314878 discloses a method of “attaching to a lower wiring layer” to build up a continuation page. (When the description page of the invention is insufficient, please note and use the continuation page.) 6发明 Description of the invention The description of the invention explains that after the anti-plating layer is opened on the continuation hole portion, a columnar metal body is formed inside the opening by electroplating copper, and then the anti-plating layer is removed, and then an insulating resin is coated on the entire surface to make it flat After conversion, an upper wiring layer is formed, thereby electrically connecting the wiring layers. In addition, WOOO / 52977 discloses a method in which, during etching of a metal constituting a columnar metal body, another metal exhibiting corrosion resistance is coated on a non-patterned portion including a lower wiring layer to form protection. After the metal layer is electrolytically plated on the entire surface of the protective metal layer to form an electroplated layer for forming the metal of the columnar metal body, an etching that can erode the protective metal layer is performed, and the non-patterned portion is removed by coating. After protecting the metal layer, the entire surface is coated with an insulating resin to flatten it, and then an upper wiring layer is formed, thereby electrically connecting the wiring layers. However, in the method of applying an insulating resin to form an insulating layer as described above, a series of steps such as coating, curing, and planarization are complicated, and it is difficult to maintain the thickness accuracy (planarity) of the insulating layer. On the other hand, there are several known methods of laminating a heat-adhesive resin sheet and a resin sheet with copper foil on a wiring layer on which a metal body protrusion (including a columnar metal body) is formed between wiring layer connections. This forms an insulating layer. Especially when the resin sheet with copper foil is laminated, since the copper foil is also laminated at the same time, there is an advantage in that it can be etched to form an upper wiring layer. However, in the conductive connection structure formed according to this, it is because the copper foil is a crimp metal bump and the resin is easily separated between the two, which makes it difficult to contact the ground from surface to surface, etc., so the conductive connection between the wiring layers Reliability is not sufficient. In particular, if the insulating layer contains reinforcing fibers, the reinforcing fibers may be harmful (please note and use the continuation sheet when using bribes is insufficient) 587412 connection. Therefore, an object of the present invention is to provide a method for forming an interlayer connection structure capable of flattening the thickness of an insulating layer between layers and controlling the surface flatness and the thickness of the insulating layer even when the insulating layer contains reinforcing fibers. The interlayer connection structure and the multilayer wiring substrate formed by this method. L SUMMARY OF THE INVENTION The invention can be achieved by the present invention described below. The method for forming an interlayer connection structure according to the present invention includes the first to third inventions. 10 That is, the first invention is a method for forming an interlayer connection structure, and the interlayer connection structure is connected to a wiring layer or a metal layer formed on both sides of the insulating layer through the interlayer connection protrusion, including: (la) in Steps of arranging at least 15 sheets that can tolerate concave deformation, a metal layer forming material, and a heat-adhesive insulating layer between the stamped surface and the laminated body on which the interlayer connection protrusions are formed; lb) In this configuration, a step of heating and pressing by a pressing surface to obtain a laminated body having a convex portion at a position corresponding to the interlayer connection protrusion and having a metal layer formed on the surface; (lc) removing the laminated body A step of exposing the interlayer connection protrusions to the convex portion; and (ld) a step of electrically connecting the exposed interlayer connection protrusions to the metal layer 20 adjacent to the insulating layer. According to the method for forming the interlayer connection structure according to the first invention, a sheet material that can tolerate concave deformation is arranged between the punched surface and the laminated body, and then the metal layer is formed into a material, the heat-adhesive insulating layer is formed into a material, and the laminated layer is formed. The body is heated and punched, so that it can generate a concave 0 sheet of the sheet at the position corresponding to the connection protrusions between the layers. (When the description page of the invention is insufficient, please note and use the continued page.) On / off ensure that the insulating layer forming material overflows. Therefore, the interlayer connection protrusions (peripheral, 'bar margin layer thickness is not easy to change, and because the convex portion equivalent to the overflow is removed in a subsequent step'), the top of the interlayer connection protrusions also become flat, which can be formed. While uniformizing the thickness of the insulating layer between the layers, and even when the insulating layer contains reinforcing fibers, the surface can be connected to a flat surface. The structure of the insulating layer is also due to the thermal adhesiveness. Comparing the layout methods, it can appropriately respond to the thinning of the insulating layer. Moreover, the interlayer connection protrusions are exposed after removing the convex part of the laminate, and then the exposed interlayer connection protrusions are conductively connected to the surrounding metal layer. Therefore, the metal layers on both sides of the insulating layer can be electrically connected. In addition, in the method using a concave-shaped deformable sheet, the same sheet can be used even when the formation positions of the interlayer connection protrusions are different, so it is suitable Mass production. It is suitable to use a release paper, a metal box, or a rubber sheet with release properties as the description sheet. At this time, 'on the sheet can be formed to produce a moderate concave deformation. The obtained convex portion of the laminated body is also easy to release the sheet and the metal layer of the laminated body. The second invention is a method for forming an interlayer connection structure, which is formed through interlayer connection protrusions and A wiring layer or a metal layer formed on both sides of the insulating layer is connected between the layers, including: (2a) a step of forming a recess at a position where the stamping surface is opposed to the interlayer connection protrusion, or a step of arranging a plate for forming the recess; ) A step of arranging at least a metal layer forming material and a heat-adhesive insulating layer forming material between the stamping surface and the laminated body on which the interlayer connection protrusions are formed; (2c) In this configuration state, borrow The stamping surface is heated and punched. 俾 Obtain the 0-continued page corresponding to the interlayer connection protrusions. (When the description page of the invention is insufficient, please note and use the continuation page.) 玖 The invention description invention description has a convex part at the position of the continued page. A step of forming a laminated body with a metal layer on the surface; (2d) a step of removing the protruding portion of the laminated body to expose the interlayer connection protrusions; and (2e) exposing the exposed interlayer connection protrusions, The step of conductively connecting to a metal layer close to the insulating layer. According to the method of forming the interlayer connection structure of Yidi 2 Maoming, because a punched surface having a recessed portion or a plate surface used to form the recessed portion is arranged opposite to the interlayer connection protrusion, This heats the stamped metal layer forming material, the thermally-adhesive insulating layer forming material, and the laminated body, so it is possible to ensure that there is an overflow of the insulating layer forming material at the position where the interlayer connection protrusions are formed. Therefore, the thickness of the insulation layer around the interlayer connection protrusions. It is not easy to change, and because the convex portion corresponding to the overflow is removed in the subsequent step, the upper part of the interlayer connection protrusion is also flattened. Therefore, the thickness of the insulating layer between the layers can be made uniform on one side, and even if the insulating layer is formed, When reinforcing fibers are included, the interlayer connection structure can be flattened while the surface is flat. Furthermore, since the heat-adhesive insulating layer forming material is sheet-shaped, it can appropriately respond to the thin layer of the insulating layer when compared with the coating method. Into. In addition, since the interlayer connection protrusions are exposed after the protruding portions of the laminated body are removed, the interlayer connection protrusions that have been evacuated are electrically connected to the surrounding metal layers, so the metal layers on both sides of the insulating layer can be electrically connected. The third invention is a method for forming an interlayer connection structure. The interlayer connection structure is formed by connecting wiring layers or metal layers formed on both sides of an insulating layer through interlayer connection protrusions. (3a) will be formed A step of integrating the laminated body of the interlayer connection protrusion, the heat-adhesive insulating layer forming material, and the metal layer forming material to integrate the upper layer of the interlayer connection protrusion near the surface of the metal layer forming material; (3 b) At least this metal 0 continuation page (if the description page of the invention is not enough, please note and use the continuation page) Invention Description Continuation Page 玖, Invention Description The step of turning the engraved field into an opening, (3e) removing at least a part of the insulating layer exposed from the slit, and exposing the top of the interlayer connection protrusion; and (3d) from the exposed interlayer connection protrusion The step of forming the conductive layer on the inner peripheral surface of the opening at least. According to the method for forming an interlayer connection structure according to the third invention, since the heating layer, the sintered layer forming material, and the metal layer forming material are used for lamination, the flatness of the surface is good, which is also advantageous for the manufacturing process. In addition, since the material for forming the heat-adhesive insulating layer is a thin sheet, compared with the coating method, it can appropriately respond to the thinning of the insulating layer.旻 Who_half 旯 Progress, since the portion overlapping with the upper surface of the interlayer connection protrusion is engraved to form an opening, the insulating layer is removed through the opening π to thereby expose the upper surface of the interlayer connection protrusion. By this, because the upper surface of the four interlayer connection protrusions from the road extends at least to the inner peripheral surface of the opening to form a conductive layer, the only connection structure of the conventional technique is different. Therefore, the reliability of the conductive connection between the wiring layer and the like and the inter-layer connection protrusion is high. ^ The surface-to-layer connection structure of Maoming Maoming is connected to the wiring layer or metal layer formed on both sides of the insulating layer via the interlayer connection I. The upper part of the interlayer connection protrusion is exposed from the insulating layer.fW The knife body f is connected to the wiring layer or the metal layer which is close to the insulating layer according to the interlayer connection structure of the present invention. Because the part of the interlayer connection protrusion exposed from the insulating layer is close to the insulating layer by the conductive layer. This wiring layer or metal layer is connected in advance, so it can be manufactured using the forming method of the present invention. ”Therefore, the thickness of the insulating layer between the layers can be made uniform, and even if the next page ) 587412 Description of the invention The If page can also flatten the surface and control the insulation, and the invention explains the interlayer connection structure when the insulation layer contains reinforcing fibers. Among the foregoing, the aforementioned conductive layer is preferably formed by plating. If the conductive layer is formed by applying a layer, an interlayer connection structure with higher reliability of conductive connection can be formed. 9 On the other hand, the multilayer wiring board of the present invention is characterized in that an interlayer connection structure as described above is provided between any layers. The multilayer wiring board according to the present invention has the aforementioned interlayer connection structure between any layers, so it has a uniform thickness of the insulating layer between the layers, and even if the insulating layer package 10 contains reinforcing fibers, it can also Multi-layer wiring board with an interlayer connection structure having a flat surface and controlled insulation layer thickness and high reliability of conductive connection. Brief Description of Drawings Figures 1 (1), (2) to 2 (3), ⑷, and (5) are step diagrams showing an example of a method for forming an interlayer connection structure of the first invention. 15 Figures 3 (a) and (b) are step diagrams showing another example of the method of forming the interlayer connection structure of the first invention. Figures 4 (a), ⑴ to 5 (a) are step diagrams showing an example of a method for forming an interlayer connection structure of the second invention. Figure 6 (1), (2), Figure 7 ⑺, ⑷, (5), Figure 8 (20 6), ⑺, ⑴, Figure 9 (9), (1〇), (⑴ system display Step diagram of an example of the method for forming an interlayer connection structure of the second invention. C Real method] 1 The best form for implementing the invention (the method of forming the interlayer connection structure of the first invention) 0 Continued page (Please note and use the continuation sheet when using it.) 587412 Description of the Invention 玖, Description of the Invention The example shown in this embodiment is formed by inter-layer connection protrusions B, and wiring layers 22 formed on both sides of the core substrate are connected between the layers, and Interlayer connection structure of the metal layer 27 formed on the upper layer via the insulating layer 26. 5 First, as shown in FIG. 1 (1), a laminated body L is prepared and tied to
基材21兩面將配線層22形成圖案,且更於該配線層22形 成層間連接突起Β者。此時,配線層22形成圖案的方法 不拘,可用例如以使用抗蝕刻層之方法,或使用圖案電鍍 用抗蝕層之方法等而製成者。通常可使用銅、鎳、錫等作 10 為構成配線層22之金屬,而以銅為佳。可使用由玻璃纖維 和聚醯亞胺樹脂、環氧樹脂等各種反應硬化性樹脂構成之 基材作為基材21。配線層22之厚度例如約為5〜50//m。The wiring layer 22 is patterned on both sides of the substrate 21, and interlayer connection protrusions B are formed on the wiring layer 22. At this time, the method for forming the pattern of the wiring layer 22 is not limited, and it can be produced by, for example, a method using an etching resistant layer or a method using a pattern plating resist. Generally, copper, nickel, tin, etc. can be used as the metal constituting the wiring layer 22, and copper is preferred. As the substrate 21, a substrate composed of glass fiber, various reaction-curable resins such as polyimide resin, and epoxy resin can be used. The thickness of the wiring layer 22 is, for example, about 5 to 50 // m.
於配線層22上形成層間連接突起B之方法不拘,只 要其為可導電連接配線層22和層間連接突起B的方法即 15 可,例如可舉藉金屬層之蝕刻而形成的方法,藉金屬之電 鍍而形成的方法,藉導電性糊而形成的方法等為例。 藉金屬層之蝕刻而形成的方法,其詳細形成方法揭示 於WO公報00/52977號和WO00/30420號中。藉金屬之電 鍍而形成的方法,其詳細形成方法揭示於日本專利公開公 20 報特開平6-314878號等中。 本實施形態中係說明藉WO公報00/52977號中記載之 形成方法,於配線層22上形成層間連接突起B之例。依 該形成方法,層間連接突起B係由底導電層10,保護金屬 層11及電鍍層24所構成。 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 13 坎、發明說明 發明說明續頁 八肢而CT層間連接突起B之形成方法包含有:在進 仃構成柱狀金屬體之金屬的㈣時,將顯現抗純之另一 至屬包覆於大略全面’包括下層之配線層22之非圖案部, 俾幵/成保4金屬層11的步驟;藉電賴敷於該保護金屬層 之大略王面升y成用以構成柱狀金屬體之金屬的電鍵層24 的步驟,·於形成該電錢層24之前述柱狀金屬體的表面部分 形成遮敝層的步驟;進行前述電鍍層24之蝕刻的步驟; 及,進行至少可侵蝕前述保護金屬層11之蝕刻,俾至少除 去用以包覆則述非圖案部之保護金屬層n的步驟。此時, 於王面,包括預先已形成圖案之下層之配線層22的非圖案 邛,進行無電電鍍以形成底導電層· 1〇後,更進一步大略於 全面進行電鍍以形成保護金屬層u。 如第1圖(2)所示,本發明之(la)步驟係於衝壓面 1和形成有層間連接突起B的被積層體L之間,至少將可 谷許凹狀變形之片材2,金屬層形成材3,及熱接著性絕緣 層形成材4,依此順序配置者。在本實施形態中所顯示之 例,係使用預先積層金屬層形成材3和絕緣層形成材4而 使之一體化的帶有樹脂之鋼箔Rc,且配置與衝壓面丨另成 個體的片材2。 市面上有販售各式該種帶有樹脂之銅箔RC,不論使用 该等RC中何者皆可。又,亦可分別各自配置金屬層形成 材3和絕緣層形成材4。 可使用銅、鎳、錫等,任一金屬作為將成為金屬層27 之金屬層形成材3,不過從導電性、易蝕刻、成本等觀點 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 發明說明 玫、發明說明 來看,以廣泛用於配線圖案之銅為最佳。又 層形成材3靠絕緣層形成材4之侧的表面,進行目的為提 高與樹脂等之接著性的黑化處理。金屬層形成材3之厚^ 例如约為5〜50// m。 又 絶緣層形成材4,只要為任何積層時可變形且可藉加 熱等而固化,同時具有配線基板所要求之耐熱性的材料即 可。具體言之,可舉聚醯亞胺樹脂、酴醛樹脂、環氧樹脂 等各種反應硬化性樹脂,和該等樹脂與㈣纖維、芳族^ 醯胺纖維等之複合體(聚酯膠片)等為例。其中又以可藉 加熱衝壓而硬化以與被積層μ積層_體化的材料為佳。精 絕緣層形成材4之厚度以在接著後,層料接突起Β 上面是位於金屬層之上面附近或更上方如此的厚度為佳。 具體言之’絕緣層形成材4之厚度宜為層間連接突起Β之 高度-40"m〜+2(^m’尤以層間連接突起Β之高度—汕 WM0㈣更佳。另,由於本發明並非藉加熱衝壓將層 間連接突起B和金屬層形成材3壓接以導電連接者,故有 可不格外嚴密要求絕緣層形成材4之厚度精度的優點。 月材2只要疋加熱衝壓時可容許凹狀變形之材料即可 ’可舉墊紙、橡膠片、合成橡膠片、不織布、織布、多孔 質片、發泡體片' 金屬箱和該等複合體等為例。特別是以 墊紙、橡膠片、合成橡膠片、發泡體片、該等複合體等之 可译性變形者為佳。又,從用以防止金屬層形成材3於加 熱衝壓時產生凹狀變形的觀點看來,宜於金屬層形成材3 使用可容許凹狀變形之金屬落作相隔。該金屬落_、 13繪次頁(翻說明頁不敷使腦,請註記^^使用續頁) 587412 玖、發明說明 發明說明續頁 紹/白等易變形金屬為佳。更進一步,宜使用具有脫模性之 塾紙’或具有脫模性橡膠片。 片材2之厚度宜較層間連接突起B高度之一半還厚, 亦且較層間連接突起B高度更厚。藉調整片材2之厚度和 5硬度,可控制藉加熱衝壓而形成之積層體之凸部5的高度 狀 叙而s,片材2減少厚度,或增加硬度,便可 減^所形成之積層體之凸部5的高度和體積。 方;兩面同時積層時的配置方式,可於下層衝壓面工和 上層衝壓面1之間’依第1 ® (2)所示順序積層配置各層 10 。 如第2圖(3)所示,本發明之(lb)步驟係在前述之 配置狀恕下,藉衝壓面1進行加熱衝壓,俾獲得於對應於 層間連接突起B之位置具有凸部5,且於表面形成有金屬 層27的積層體者。在該步驟中,由於片材2藉有層間連接 15突起B之存在而於加熱衝壓時產生凹狀變形,故於積層體 會形成對應其之凸部5。尤其是當於絕緣層形成才才4包含 有補強纖維時,凸部5之高度和體積也會增加。 加熱加壓之方法,可使用加熱加壓裝置(熱積層機、 加熱衝壓機)等以進行。此時,為避免空氣混入,亦可使 20環境為真空(真空積層機)。可對應於絕緣層形成材4與金 屬層形成材3之材質和厚度,適當地設定加熱溫度、壓力 荨條件,不過且對應於形成於被積層體L之層間連接突起 B的總數而將壓力調整在〇.5〜3〇MPa的範圍。藉此,絕緣 層形成材4與金屬層形成材3會對應於被積層體L之表面 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 玖、發明說明 一…u =狀而變形,俾形成已硬化之絕緣層26與金 成後,積層體通常進行脫模、冷卻等。 / 如弟2圖(4)所示,本發明 料明之(lc)步驟係除去前述 貝層肢之凸部5,使層間連接突起B露出者。此時,亦可 同時除去層間連接突起B較積層體之金屬層U上面還高 之部分,使其平坦化。 ^ 宜使用研削和研磨之方法作為凸部5的除去方法,可 舉使用具有配置多數金剛石製等硬質刀於旋轉板半徑方^ 之硬質旋轉刀的研削裝置,和使用砂光機、砂帶、研磨機 、平面研削盤、硬質磨粒成形品等的方法為例。若使用研 削裝置,便-邊旋轉該硬質旋轉刀,一邊使其沿業經固定 支持之配線基板移動,藉此可將基板上面平坦化。又,研 磨方法,可舉藉砂帶、拋光研磨等而輕微地研磨的方法為 例若依本發明於積層體形成有凸部5,便可輕易地僅研 削該部分,更確實地進行全體的平坦化。 如第2圖(5)所示,本發明之(ld)步驟係將已露出 之層間連接突起B,與隔著絕緣層26相近之金屬層27導 電連接者。本實施形態中所顯示之例係對金屬層27之大略 王面包含層間連接突起B之上面,藉電鍵形成導電體層 28。藉此,經由與層間連接突起B之上面接合之導電體層 28 ’可將層間連接突起b與金屬層27導電連接。 藉電鍍所作之導電體層28的形成,可藉無電電鍍,或 無電電鍍和電解電鍍之組合,濺鍍或蒸鍍和電解電鍍之組 合等以進行。不過,在提高導電連接之可靠性方面,以利 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 發明說明續頁 導電體層28 坎、發明說明 用無電電鍍和電解電狀組合以形成者為佳 之厚度宜為1〜30//m。 =中通常使用銅、錄、錫等的鑛液,該等金屬 :氣屬層27之金屬相同’也可與之相異,其中以銅 〜。市面上有販售各種無電電鍵之電鑛液,其係可對庫 於各種金屬且眾所皆知者。—般而言,液體組成係包含有 金屬離子源、驗性源、還原劑、t合劑、穩定劑等。另, 亦可在無電電鍍之前,先使鈀等之電鍍觸媒沉澱。至於電 錢亦可使用業已周知之方法進行。 本發明中,更進一步,可進行導電體層28和金屬層 27之_以形成金屬圖案。當導電體層28與構成金屬層 27之金屬是相同時,可同時進行_,若是不同時,只要 依次進行钱刻即可。 如第2圖(5)所示,可依以上所述者進行之本發明的 層間連接構造係經由層間連接突^ B,而在層間連接有形 成於絕緣層26兩面之配線層22或金屬層27者,其特徵在 於·该層間連接突起B之上面自絕緣層26露出的部份藉 導電體層28 (以電鍍層為佳)與隔著絕緣層26相近之該 配線層22或金屬層27連接。 另一方面,本發明之多層配線基板,其特徵係於任一 層間設有如前述之層間連接構造者。圖示之例係於第丨層 和第2層及第3層和第4層之連接中,採用本發明之層間 連接構造的4層基板。更進一步於兩側之上層形成同樣的 層間連接構造,藉此可形成更多層化的多層配線基板。又 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 587412 玫、發明說明 |翻_續頁 ’對於核心基板和兩面金屬箔積層板,亦可形成本發明之 層間連接構造。 (第1發明之另一實施形態) 以下說明本發明之另一實施形態。 (1)前述實施形態所顯示之例,係使用預先積層金屬 層形成材和絕緣層形成材而使之一體化的帶有樹脂之銅箱 ’且配置與衝壓面另成個體的片材,不過亦可為如第3圖 (a)〜(b)所示之配置方式。 第3圖(a )所示之例係已先於衝壓面1形成片材2者 10 。可於衝壓面1直接形成片材2,也可使用接著劑或黏著 劑以與片材2接著。又,亦可於片材2之表面設置脫模層 。以使用脫模性及耐熱性皆優之矽膠片尤佳。 15 第3圖(b)所示之例係於衝壓面1和被積層體L之 間,分別配置片材2,金屬層形成材3及絕緣層形成材斗, 同時於片材2和金屬層形成材3之間追加配置脫模片6。 脫模片6,可舉氟樹脂膠片、矽樹脂膠片、各種脫模紙、 纖維補強氟樹脂膠片、纖維補強矽樹脂膠片等為例。 前述貫施形The method of forming the interlayer connection protrusion B on the wiring layer 22 is not limited, as long as it is a method that can electrically connect the wiring layer 22 and the interlayer connection protrusion B, which is 15, for example, a method formed by etching of a metal layer, A method of forming by electroplating, a method of forming by conductive paste, and the like are examples. A method for forming the metal layer by etching is disclosed in detail in WO Publication Nos. 00/52977 and WO00 / 30420. A method for forming by metal plating is disclosed in detail in Japanese Patent Laid-Open Publication No. 6-314878 and the like. In this embodiment, an example in which the interlayer connection protrusion B is formed on the wiring layer 22 by the formation method described in WO Publication No. 00/52977 will be described. According to this formation method, the interlayer connection protrusion B is composed of the bottom conductive layer 10, the protective metal layer 11 and the plating layer 24. 0 Continued pages (please note and use continuation pages when the invention description page is not enough) 13 ridge, invention description Continued page Eight limbs and the method for forming the CT interlayer connection protrusion B includes: forming a columnar metal into the shaft In the case of metallic metal, another step of anti-pureness will be shown, which is covered with a substantially complete 'non-patterned part including wiring layer 22 of the lower layer, step of metal layer 11 / Cheng Bao 4; The step of protecting the roughly king surface of the metal layer into an electric bond layer 24 for forming the metal of the columnar metal body, and the step of forming a masking layer on the surface portion of the aforementioned columnar metal body forming the electric money layer 24; Performing the step of etching the aforementioned plating layer 24; and performing the step of etching at least the protective metal layer 11 and removing at least the protective metal layer n covering the non-patterned portion. At this time, electroless plating is performed on the king surface, including the unpatterned layer 邛 of the wiring layer 22, which is a patterned lower layer in advance, to form a bottom conductive layer. After that, the plating is further performed on a full scale to form the protective metal layer u. As shown in FIG. 1 (2), the step (la) of the present invention is between the stamping surface 1 and the laminated body L formed with the interlayer connection protrusion B, and at least the sheet 2 that can be deformed in a concave shape is deformed. The metal layer forming material 3 and the heat-adhesive insulating layer forming material 4 are arranged in this order. In the example shown in this embodiment, the resin-coated steel foil Rc is integrated by using the metal layer forming material 3 and the insulating layer forming material 4 laminated in advance, and the arrangement and the pressing surface are separate pieces.材 2。 Material 2. There are various types of copper foil RC with resin on the market, no matter which of these RCs are used. Alternatively, the metal layer-forming material 3 and the insulating layer-forming material 4 may be arranged separately. Copper, nickel, tin, etc. can be used. Any metal can be used as the metal layer forming material 3 which will become the metal layer 27. However, from the viewpoints of conductivity, easy etching, cost, etc. Note and use the continuation sheet) Invention description From the point of view of the invention, copper is widely used in wiring patterns. The surface of the layer-forming material 3 on the side of the insulating layer-forming material 4 is subjected to a blackening treatment for the purpose of improving adhesion to resin and the like. The thickness of the metal layer forming material 3 is, for example, approximately 5 to 50 // m. The insulating layer forming material 4 may be any material that can be deformed during curing and can be cured by heating or the like, and that has heat resistance required for the wiring board. Specifically, various reaction hardening resins such as polyimide resin, acetal resin, epoxy resin, and composites (polyester film) of these resins with fluorene fiber, aromatic ^ amine fiber, and the like can be mentioned. As an example. Among them, a material which can be hardened by heating and pressing to be laminated with the laminated layer µ is preferable. The thickness of the fine insulating layer forming material 4 is preferably such that the upper surface of the layer-connecting protrusions B is near or above the upper surface of the metal layer. Specifically, the thickness of the 'insulating layer forming material 4 should be the height of the interlayer connection protrusion B -40 " m ~ + 2 (^ m', especially the height of the interlayer connection protrusion B-Shan WM0㈣ is more preferable. In addition, since the present invention is not If the interlayer connection protrusion B and the metal layer forming material 3 are crimped to form a conductive connection by hot stamping, there is an advantage that the thickness accuracy of the insulating layer forming material 4 can not be particularly strictly required. As long as the moon material 2 can be recessed when hot stamping Deformed materials can be 'such as pad paper, rubber sheets, synthetic rubber sheets, non-woven fabrics, woven fabrics, porous sheets, foam sheets' metal boxes and these composites, for example. Especially pad paper, rubber It is preferable to have translatable deformation of a sheet, a synthetic rubber sheet, a foam sheet, these composites, etc. In addition, from the viewpoint of preventing the metal layer forming material 3 from being deformed in a concave shape during hot stamping, it is preferable. In the metal layer forming material 3, a metal drop that can tolerate concave deformation is used as a spacer. The metal drop _ and 13 are drawn on the next page (not enough pages to turn the description page, please note ^ ^ use the continuation page) 587412 发明, invention description invention Description Continued Shao / White and other deformable metals Further, it is better to use a release paper or a rubber sheet having a release property. The thickness of the sheet 2 should be thicker than half of the height of the interlayer connection protrusion B, and also thicker than the height of the interlayer connection protrusion B. By adjusting the thickness and hardness of the sheet 2, the height of the convex part 5 of the laminated body formed by heating and pressing can be controlled, and the thickness of the sheet 2 can be reduced or the hardness can be reduced. The height and volume of the convex part 5 of the laminated body. Square; when the two sides are laminated at the same time, the layers 10 can be laminated and arranged in the order shown in Section 1 ® (2) between the lower stamping surface worker and the upper stamping surface 1. As shown in FIG. 2 (3), the step (lb) of the present invention is based on the foregoing configuration, and the heating surface is pressed by the pressing surface 1 to obtain a convex portion 5 at a position corresponding to the interlayer connection protrusion B. And a laminated body having a metal layer 27 formed on the surface. In this step, since the sheet 2 has a concave deformation during heating and punching due to the presence of the interlayer connection 15 protrusion B, the laminated body will form a convex corresponding to it. Section 5. Especially when the insulating layer is formed only 4 When reinforcing fibers are included, the height and volume of the convex portion 5 will also increase. The method of heating and pressing can be performed by using a heating and pressing device (thermal laminator, heating press), etc. At this time, in order to avoid air mixing, also 20 environment can be vacuum (vacuum laminator). It can be set to the heating temperature and pressure conditions according to the material and thickness of the insulating layer forming material 4 and metal layer forming material 3, but it also corresponds to the layer to be formed. The total number of interlayer connection protrusions B in L is adjusted to a pressure in the range of 0.5 to 30 MPa. As a result, the insulating layer forming material 4 and the metal layer forming material 3 correspond to the surface of the laminated body L. Continued (When the description page of the invention is not enough, please note and use the continuation page.) 玖, the description of the invention ... u = shape and deformation, 后 After the hardened insulating layer 26 and gold are formed, the laminated body is usually demolded, cooled, etc. / As shown in FIG. 2 (4), the step (lc) of the present invention is to remove the convex part 5 of the limbs and expose the interlayer connection protrusion B. At this time, the portion where the interlayer connection protrusion B is higher than the upper surface of the metal layer U of the laminated body can be removed at the same time to make it flat. ^ It is preferable to use grinding and grinding as the method for removing the convex portion 5, and a grinding device having a hard rotary knife with a hard knife arranged with a large number of diamonds and other hard tools at the radius of the rotary plate, and a sander, a belt, Examples of the method include a grinder, a flat grinding disc, and a hard abrasive molded product. If a grinding device is used, the hard rotary blade can be rotated while it is being moved along a fixedly supported wiring board, thereby flattening the upper surface of the board. In addition, the polishing method may be a method of slightly grinding by using a belt, polishing, or the like. For example, if the convex portion 5 is formed on the laminated body according to the present invention, it is possible to easily grind only that portion, and more reliably perform the entire process. flattened. As shown in FIG. 2 (5), the step (ld) of the present invention is a conductive connection between the exposed interlayer connection protrusion B and the metal layer 27 which is close to the insulating layer 26. The example shown in this embodiment is a rough outline of the metal layer 27 including the upper surface of the interlayer connection protrusion B, and the conductive layer 28 is formed by an electric bond. Thereby, the interlayer connection protrusion b and the metal layer 27 can be electrically connected via the conductor layer 28 'bonded to the upper surface of the interlayer connection protrusion B. The formation of the conductor layer 28 by electroplating can be performed by electroless plating, a combination of electroless plating and electrolytic plating, sputtering or a combination of vapor deposition and electrolytic plating, and the like. However, in terms of improving the reliability of the conductive connection, it is beneficial to continue the next page (when the description page of the invention is insufficient, please note and use the next page) Invention Description Continuation Page 28 conductor layer, electroless plating and electrolytic The thickness of the shape-like combination is preferably 1 to 30 // m. In general, mineral liquids such as copper, copper, tin, etc. are used in these metals: The metal of the gaseous layer 27 is the same as that of the metal layer, and may be different from it. Among them, copper is used. There are various types of electro-mineral fluids without electrical keys on the market, which are known to all kinds of metals. In general, the liquid composition system includes a metal ion source, an empirical source, a reducing agent, a t-agent, a stabilizer, and the like. Alternatively, a plating catalyst such as palladium may be deposited before electroless plating. As for money, it can also be done using well-known methods. In the present invention, further, the conductive layer 28 and the metal layer 27 may be formed to form a metal pattern. When the conductor layer 28 and the metal constituting the metal layer 27 are the same, _ can be performed at the same time, and if they are different, it is only necessary to sequentially perform the money engraving. As shown in FIG. 2 (5), the interlayer connection structure of the present invention that can be performed according to the above is via the interlayer connection protrusion ^ B, and the wiring layer 22 or the metal layer formed on both sides of the insulating layer 26 is connected between the layers. 27, which is characterized in that the part of the interlayer connection protrusion B exposed from the insulating layer 26 is connected to the wiring layer 22 or the metal layer 27 adjacent to the insulating layer 26 through a conductor layer 28 (preferably a plating layer). . On the other hand, the multilayer wiring board of the present invention is characterized in that an interlayer connection structure as described above is provided between any layers. The example shown in the figure is a 4-layer substrate using the interlayer connection structure of the present invention in the connection between the first and second layers, and the third and fourth layers. Furthermore, the same interlayer connection structure is formed on the upper layers on both sides, thereby forming a multi-layered multilayer wiring substrate. Another 0 continuation pages (please note and use continuation pages when the invention description page is insufficient) 587412 Rose, invention description | turning_continuation page 'For core substrate and double-sided metal foil laminates, it can also form the interlayer connection of the present invention structure. (Another Embodiment of the First Invention) Next, another embodiment of the present invention will be described. (1) The example shown in the foregoing embodiment is a copper case with resin using a pre-laminated metal layer forming material and an insulating layer forming material and integrated, and the arrangement and the pressing surface are separated into individual sheets, but It can also be arranged as shown in Figs. 3 (a) to (b). The example shown in FIG. 3 (a) is a case in which a sheet 2 has been formed before the press surface 1 10. The sheet 2 may be directly formed on the punching surface 1, or an adhesive or an adhesive may be used to adhere to the sheet 2. A release layer may be provided on the surface of the sheet 2. It is better to use silicone film with excellent mold release and heat resistance. 15 The example shown in Fig. 3 (b) is between the stamping surface 1 and the laminated body L, and the sheet 2, the metal layer forming material 3, and the insulating layer forming a bucket are respectively arranged, and the sheet 2 and the metal layer are simultaneously arranged. A release sheet 6 is additionally disposed between the forming materials 3. The release sheet 6 can be exemplified by a fluororesin film, a silicone resin film, various release papers, a fiber-reinforced fluororesin film, a fiber-reinforced silicone resin film, and the like. Previously described
^ 吓$π呆匕形成有層 間連接突起之配線層,形成本發明之層間連接構造的方法 ,不過對於在未形成配線圖案,或於形成配線圖案前之金 屬層業已形成有層間連接突起者,亦可與前述之實施形態 相同般進行,俾形成本發明之層間連接構造。此時,除所 使用之被積層體不同以外’亦可以相同步驟實施。依此所 獲得者,可使用作為兩面金屬落積層&,亦可同_刻前 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) χ 19…、 20 玖、發明說明 發明說明,續頁 述金屬層和金屬箔以形成圖案。又,亦可不將金屬層形成 圖案,而是利用作為密封層或電源層。 (3 )别述實施形態所顯示之例,係藉電鍍形成導電體 層,不過亦可藉導電性糊之塗布、濺鍍蒸鍍、真空蒸鍍等 乂進行又,亦可將該等方法與電解電鍍等組合以形成導 電體層。 虽塗布導電性糊時,只須使用絲網印刷法、擠壓法等 塗布即可,而導電性糊則可使用任何可用於配線基板者。 (4 )鈉述貫施形態所顯示之例,係以於兩面業已形成 有配線層之核心基板作為被積層體,且在兩側的衝屋面進 订加熱衝壓,俾於兩面形成層間連接構造,不過亦可僅於 基板之單面側形成層間連接構造。此時,亦可僅設置單側 之用以加熱的衝壓面。 (第2發明之層間連接構造之形成方法) 第2發明係一種層間連接構造之形成方法,該層間連 接構造係經由層間連接突起,而在層間連接有形成於絕緣 層兩面之配線層或金屬層者,包含有:(2a)於衝壓面與該 層間連接突起相對之位置形成凹部,或配置用以形成該凹 部之板的步驟;(2b)於衝壓面和形成有該層間連接突起的 被積層體之間,至少將金屬層形成材及熱接著性絕緣層形 成材’依此順序配置的步驟;(2c)在該配置狀態下,藉衝 壓面進行加熱衝壓,俾獲得於對應於層間連接突起之位置 具有凸部’且於表面形成有金屬層之積層體的步驟;⑶) 除去該積層體之凸部,使層間連接突起露出的步驟; Ξ續次良(翻說日頎不敷使騎,記鎌用續頁) 坎、發明說明 發明說明續頁 2e)將已露出之層間連接突起,與隔著絕緣層相近之金屬 層導電連接的步驟。其中僅有(2a)步驟和(2c)步驟係 與則述之層間連接構造之形成方法相異。 以下僅就相異點加以說明。 首先,說明在第4圖(a)所示之狀態下進行配置之情 乂 ”亥貝知开’悲係在(2a)步驟中,於衝壓面1與層間連 接突起B相對之位置形成凹部la。 衝壓面1之凹部la的開口形狀和大小可因應於層間連 接突起B而決定,凹部1&的開口面積宜較層間連接突起b 之上面面積還大。又,宜將凹部la的深度設定成凹部& 的4積與層間連接突起B之體積大略相同,或超越其體積 ,尤以設定成與層間連接突起B之體積大略相同為佳。具 體言之,例如凹部^之深度是5#m以上,以1〇#m以上 為佳。 衝壓面之凹部la的整體形狀,可舉圓錐台、圓柱、四 角錘台、四角柱等為例,不過以如圓錐台或四角錘台般, 侧壁是錐狀者為佳。 於衝壓面1形成凹部la的方法,可舉使用抗蝕刻層之 半蝕刻、鑄造、NC加工等為例。特別是,利用形成層間 連接突起B時的圖案以進行半蝕刻,在精度及成本方面是 有利的。 (2b)步驟中,於衝壓面1和形成有層間連接突起B 的被積層體L之間,至少將金屬層形成材3及熱接著性絕 緣層形成材4,依此順序配置。另,亦可使衝壓面丨和金 0續次頁(發明說頓不敷使用時,請註記並使用顯) 玖、發明說明 發明說明續頁 屬層形成材3之間隔有適當之墊材、脫模片等。 接著,說明在第4圖(b)所示之狀態下進行配置之情 形。該實施形態係在(2a )步驟中,於衝壓面1與声間連 接突起B相對之位置配置用以形成凹部的板7。該板7於 凹部之形成位置設有貫通孔7a。板7之材質可為金屬、樹 脂等任一者。 形成貫通孔7a的方法,可舉使用抗蝕刻層之蝕刻或半 蝕刻、鑄造、NC加工、衝孔、鑽孔等為例。可對應於被 積層體L而適當地調整板7的位置。 更進一步,說明在第5圖(a)所示之狀態下進行配置 之情形。該實施形態之例係在(2a)步驟中,於衝壓面! 與層間連接突起B相對之位置配置用以形成凹部仏的板8 時,先於板8形成金屬層形成材3之層,用以在(孔)步 驟中配置金屬層形成材3。在(2a)步驟中,亦可先於衝 Μ面1與層間連接突起B相對之位置形成凹部ia,再同樣 地於衝壓面1形成金屬層形成材3之層。 此外,亦可在於板8或衝形成金屬層形成材3 之層時’隔入脫模層。脫模層係藉將金屬層形成材3之層 電解電鍍而形成,以金屬製者為佳。當金屬層為銅時,金 屬製脫模層以錄、不錢鋼、特別是藉無電電錄而形成之鎳 等為佳。若脫模層是陶冑、樹脂等絕緣性材時,可利用無 電電錢等與電解電錢之組合形成金屬層。 (第3發明之層間連接構造之形成方法) ★本實施形態所顯示之例’係對於形成於核心基板兩面 0續次頁(發麵頓不敷使觸,請註記並使用續頁) 587412 發明說明 連接構造。 玖、發明說明 之配線層之層間連接突起,形成本發明之導電 首先,如第6圖(1 )所示,與第1發明相同,準備一 被積層體L,係於基材21兩面上將配線層22形成圖案者 5 其次,如第6圖(2)所示,在層間於配線層22上形^ The formation of the wiring layer with interlayer connection protrusions to form the interlayer connection structure of the present invention, but for those who have not formed the wiring pattern or the metal layer before the wiring pattern has been formed, It can also be carried out in the same manner as the aforementioned embodiment to form the interlayer connection structure of the present invention. At this time, it is possible to carry out the same procedure except that the laminated body used is different. According to this, you can use it as a double-sided metal deposition & or the same as the previous page 0 (the description page of the invention is not enough, please note and use the continuation page) χ 19 ..., 20 发明, invention DESCRIPTION OF THE INVENTION The description of the invention is continued on the metal layer and the metal foil to form a pattern. Instead of forming a pattern on the metal layer, it may be used as a sealing layer or a power source layer. (3) In addition to the example shown in the embodiment, the conductor layer is formed by electroplating, but it can also be performed by the application of conductive paste, sputtering evaporation, vacuum evaporation, etc., and these methods and electrolysis can also be used. Electroplating and the like are combined to form a conductor layer. Although the conductive paste may be applied by a screen printing method, an extrusion method, or the like, the conductive paste may be used for any wiring substrate. (4) The example shown in the form of sodium perforation is based on the core substrate on which the wiring layer has been formed on both sides as the laminated body, and the heat-punching is carried out on the punching roof on both sides, and the interlayer connection structure is formed on both sides. However, the interlayer connection structure may be formed only on one side of the substrate. In this case, it is also possible to provide only one side of the stamped surface for heating. (Formation method of the interlayer connection structure of the second invention) The second invention is a method of forming an interlayer connection structure. The interlayer connection structure is connected to the wiring layer or the metal layer formed on both sides of the insulating layer through the interlayer connection protrusion. The method includes: (2a) forming a recess at a position where the punching surface is opposite to the interlayer connection protrusion, or arranging a plate for forming the recess; (2b) forming a recess on the punching surface and the interlayer connection protrusion. The steps of arranging at least the metal layer forming material and the heat-adhesive insulating layer forming material in this order between the bodies; (2c) In this configuration state, the pressing surface is subjected to heating and pressing to obtain the protrusions corresponding to the interlayer connection. A step of forming a laminated body having a convex portion at a position and forming a metal layer on the surface; ⑶) a step of removing the convex portion of the laminated body and exposing inter-layer connection protrusions; (Continued page for the sickle). Description of the invention Continued page 2e) The step of conducting the conductive connection between the exposed interlayer connection protrusions and the metal layer close to the insulating layer. Only steps (2a) and (2c) are different from the method of forming the interlayer connection structure described above. Only the differences will be described below. First, a description will be given of the arrangement in the state shown in FIG. 4 (a). “Heibei Kaikai” is a step (2a) in which a recessed portion la is formed at the position where the punching surface 1 and the interlayer connection protrusion B are opposite to each other. The opening shape and size of the recessed portion la of the pressing surface 1 can be determined according to the interlayer connection protrusion B. The opening area of the recessed portion 1 & should be larger than the area of the upper surface of the interlayer connection protrusion b. Also, the depth of the recessed portion la should be set to The 4 product of the recess & is approximately the same as or more than the volume of the interlayer connection protrusion B, and is preferably set to be approximately the same as the volume of the interlayer connection protrusion B. Specifically, for example, the depth of the recess ^ is 5 # m Above, 10 # m or more is preferred. The overall shape of the recessed part la of the pressing surface can be exemplified by a conical table, a cylinder, a square hammer table, a square column, etc., but the side wall is like a conical table or a square hammer table. A tapered shape is preferred. The method of forming the recessed la in the punching surface 1 can be exemplified by semi-etching using an anti-etching layer, casting, NC processing, etc. In particular, the pattern when forming the interlayer connection protrusions B is used for half Etching, accuracy and cost In the step (2b), at least the metal layer forming material 3 and the heat-adhesive insulating layer forming material 4 are formed between the pressing surface 1 and the laminated body L on which the interlayer connection protrusion B is formed, in this order. Configuration. In addition, the stamping surface and gold 0 can be continued (if the invention is not enough, please note and use the display) 发明 Description of the invention Description of the invention Continuation page The interval between the layer-forming materials 3 has a proper pad Material, mold release sheet, etc. Next, the case where it is arranged in the state shown in FIG. 4 (b) will be described. In this embodiment, in the step (2a), the punching surface 1 and the acoustic connection projection B are opposed to each other. A plate 7 is formed at a position for forming a recessed portion. The plate 7 is provided with a through hole 7a at the position where the recessed portion is formed. The material of the plate 7 can be any of metal and resin. The method of forming the through hole 7a can be anti-etching. The layer etching or semi-etching, casting, NC machining, punching, drilling, etc. are taken as examples. The position of the plate 7 can be appropriately adjusted according to the laminated body L. Further, the description is shown in FIG. 5 (a). The configuration is performed in the state. The example of this embodiment is in step (2a) In the punching surface! When the plate 8 for forming the recessed part 配置 is disposed at a position opposite to the interlayer connection protrusion B, the layer of the metal layer forming material 3 is formed before the plate 8 to arrange the metal layer formation in the (hole) step. Material 3. In the step (2a), a recessed portion ia may be formed before the punching surface 1 and the interlayer connection protrusion B are opposite to each other, and then the layer of the metal layer forming material 3 may be similarly formed on the punching surface 1. Alternatively, When the plate 8 or the layer of the metal layer forming material 3 is formed, the release layer is separated. The release layer is formed by electrolytic plating of the layer of the metal layer forming material 3. It is preferably made of metal. When the metal layer is In the case of copper, the metal release layer is preferably steel, stainless steel, especially nickel formed by non-electrical recording. If the mold release layer is an insulating material such as ceramics or resin, non-electrical electricity can be used. Forms a metal layer in combination with electrolytic money. (Formation method of the interlayer connection structure of the third invention) ★ The example shown in this embodiment is "continued pages on the two sides of the core substrate (continued, please note and use the continued pages) 587412 Invention The connection structure will be explained.玖 Interlayer connection protrusions of the wiring layer described in the invention to form the electrical conductivity of the present invention First, as shown in FIG. 6 (1), as in the first invention, a laminated body L is prepared and attached to both sides of the substrate 21. The wiring layer 22 is patterned 5 Next, as shown in FIG. 6 (2), the wiring layer 22 is formed on the wiring layer 22 between layers.
成用以導電連接之層間連接突起Β。層間連接突起Β之形 成方法只要是可導電連接配線層22和層間連接突起Β的 方法即可,例如可舉藉金屬層之蝕刻而形成的方法,或藉 金屬之電鍍而形成的方法等為例。前者之詳細形成方法揭 10 示於WO公報00/52977號和WO00/30420號中,而後者之 詳細形成方法揭示於曰本專利公開公報特開平6-314878號 等中。Interlayer connection protrusions B are formed for conductive connection. The method for forming the interlayer connection protrusion B may be a method that can electrically connect the wiring layer 22 and the interlayer connection protrusion B. For example, a method formed by etching a metal layer or a method formed by electroplating of a metal is taken as an example. . The detailed formation method of the former is disclosed in WO Publication Nos. 00/52977 and WO00 / 30420, and the detailed formation method of the latter is disclosed in Japanese Patent Laid-Open Publication No. 6-314878 and the like.
本實施形態中係說明藉WO公報00/52977號中記載之 形成方法,於配線層22上形成柱狀金屬體24之例。依該 15 形成方法,柱狀金屬體24和配線層22之間隔有底導電層 10與保護金屬層.11。本發明中未必需要該等層,當以其他 金屬構成柱狀金屬體24和配線層22時等,則可省略。 另一方面,本發明係使用熱接著性絕緣層形成材及金 屬層形成材,且於被積層體積層該等材而使之一體化,不 20 過絕緣層形成材及金屬層形成材可為個別分開者,也可為 預先積層而一體化者。本實施形態所顯示之例係使用業已 形成有接著性絕緣層26a之金屬箔27。市面上有販售各式 該種積層板,可使用其中任一者。舉例言之,可使用任一 金屬作為金屬箔27,不過從導電性、易蝕刻、成本等觀點 0續次頁(發明說明頁不敷使用時,ΐ靑註記並使用續頁) 23 1、發明說明 發明說明續頁 來看’以廣泛用於配線圖案之銅為最佳。又,^7可在金屬~ 箱27表面靠絕緣層細之側,進行目的為提高與樹腊等之 接著性的黑化處理。 接著|±、、、巴、、彖層26a,只要為任何積層時可變形且可藉 加熱等而ϋ化,同時具有配線基板所要求之耐熱性的㈣ 即可。具體言之’可舉聚醯亞胺樹月旨、環氧樹脂等各種反 應硬化性樹脂’和該等樹脂與陶究纖維、芳族聚酿胺纖維 等之複合體(聚醋膠片)等為例。其中又以可藉加熱加壓 (熱積層)而硬化以與核心基板一體化,並使製程簡易化 的材料為佳。 絕緣層26a之厚度以在接著後,層間連接突起24上面 疋位於刖述金屬箔27之表面附近如此的厚度為佳。具體言 之,只須相當於自基材21表面至層間連接突起24之上面 的高度即可。另,由於本發明並非藉前述積層步驟而將層 間連接突起24和金屬箔27壓接以導電連接者,故有可不 格外嚴密要求絕緣層26a之厚度精度的優點。 如第7圖(3)所示,本發明之(3a)步驟係積層業已 形成有層間連接突起24之配線層22,和業已形成有接著 性絕緣層26a之金屬箔27而使之一體化,俾層間連接突起 24之上面24a位於金屬箔27的表面附近。在此,所謂金 屬箔27的表面附近,係可接近金屬箔27,尤以10/zm以 下之距離為佳。另,亦可使用形成配線圖案前之金屬層以 取代配線層22 (此乃敘述於後)。 積層一體化之方法,係於業已形成有層間連接突起24 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 玖、發明說明 發明說明續頁 /土板等的上下’積層配置附有絕緣層26a之金屬箱 再力…、加壓(熱積層、加熱衝壓)即可。此時,為 避免工氣〉t匕入’亦可蚀提^立炎古 力J使%土兄為真空(真空積層)。另,可對 μ方、巴彖層26a之材質而適當地設定加熱溫度之類條件等 藉此彳心成對應於核心基板表面形狀而變形且硬化之 絕緣層2 6 a。 如第7圖(4)〜(5)所示’本發明之(3b)步驟係至 少,前述金屬箱27中與前述層間連接突起B之上面24a 重疊的部份進行餘刻以形成開口 27a。在此,相當於層間 1〇連接突起B之柱狀金屬體24的上面施不必為完全平坦 ’若是以電鍍所形成時,其易成為曲面。此時,以柱狀金 屬體24之周壁以外部分為上面24a。 又,在本發明中,所謂與層間連接突起B之上面2乜 重且的。(Μ刀制曰層間連接突起B之上面投影於金屬 15治27之區域與開口 27a之區域重疊(包括完全一致,部分 致包έ有其中一方的情形)的部分。本發明從擴大導 電連接之面積的觀點看來,以層間連接突起Β,即柱狀金 屬體24之上面24a投影於金屬箔27之區域的8〇%以上, 尤其是100%係包含於開口 27a之區域者為佳。然而,由 2〇於若金屬箔27之開口 27a的面積過大,則殘留於其周圍的 金屬泊27之寬度亦變大,故不利於配線圖案的精細化。因 此’開口 27a之面積宜為層間連接突起β之上面24a之面 積的0.8〜5倍。 餘刻亦可為乾式蝕刻,不過以濕式蝕刻為佳,其中尤 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 玫、發明說明 發明說明續頁 Μ使用乾膜抗蝕劑等感光性樹脂之方法為佳。所謂感光性 Μ月旨係、指包含有可藉光而起光分解、光架橋、或光聚合之 -刀子里及/或而分子量成份的樹脂組成物。至於包覆,可 ♦J 積層乾膜之方法和塗布感光性樹脂組成物並使其硬化 之方法等。乾膜(光阻劑)係有有機溶劑顯像型和鹼性水 溶液顯像型’並利用具有加熱壓著滾筒之乾膜積層機等進 仃熱麗著(積層)。感光性樹脂組成物的塗布可利用各種塗 布機以進行。 接著,將形成開口 27a之部分或其相反部分曝光顯像 ,並除去前者。該種曝光係一邊隔有光罩用膜,或光電繪 圖機等的直接曝光線,並使用曝光機,通常是藉紫外線等 以進行。至於顯像,可使用對應於乾膜種類之顯像液等, 舉例言之,對於有機溶劑顯像型可使用三氯乙烷等,對於 驗性水溶液顯像型可使用碳酸鈉等。 依前述者進行,可形成第7圖(4)所示之具有開口 38a的抗#刻層38。接著’如第7圖(5)所示,使用對應 於金屬箔27之材質的蝕刻液以形成開口 27a。蝕刻液可舉 市面販售之鹼性蝕刻液、氣化物蝕刻液、過硫酸銨、過氯 化氫/硫酸等為例。 蝕刻完成後,視需要而除去抗蝕刻層38,可對應於抗 蝕刻層38之種類,適當地選擇藥劑除去、剝離除去等。舉 例言之,若為乾膜抗蝕劑,例如對於有機溶劑顯像型可使 用二氯甲烷等,對於鹼性水溶液顯像型可使用氫氧化鈉等 以進行剝離。另,抗蝕刻層38之除去亦可與其次之(3c) 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 587412 玖、發明說明 發明說明_頁 ίο 15 步驟同時進行。 如第8圖(6)所示,本發明之(3c)步驟係至少除去 自開口 27a露出之絕緣層26的一部份,使層間連接突起 24之上面24a露出。在此,不須使層間連接突起24之上 面24a全部露出,不過從擴大導電連接之面積的觀點看來 ,宜使上面24a全部露出。 可使用拋光研磨、砂帶、機械研削、雷射照射、電漿 蝕刻、轉寫剝離等作為除去絕緣層26之方法,不過宜使用 藉噴砂加工、或化學蝕刻而選擇性地除去自開口 27a露出 之絕緣層26的方法。由於喷砂器等的噴砂加工,即使對於 表面之凹部亦可獲得研削效果,且可較金屬更快除去樹脂 等絕緣層,故可更確實地使柱狀金屬體之上面露出。又, 化學蝕刻也可同樣地選擇性地除去絕緣層。 喷砂加工可舉乾式或濕式之喷砂、金屬粒子噴砂等為 例。化學蝕刻則可使用可選擇性地分解樹脂之藥液等。另 ,除去絕緣層26時,亦可利用先前設置之抗蝕刻層38作 為遮蔽材,此時,於(3c )步驟後再除去抗蝕刻層38。 如第8圖(7)所示,本發明之(3d)步驟係由已露出 之層間連接突起24之上面24a,至少擴及至開口 27a之内 周面以形成導電體層29。本實施形態所顯示之例,係藉電 鍍於包括上面24a之金屬箔27的大略全面形成導電體層 29。藉此,經由接合於上面24a之導電體層29a,接合於 開口 27a之内周面的導電體層29b,及其周圍之導電體層 29c,可將層間連接突起24和金屬箔27導電連接。In this embodiment, an example in which the columnar metal body 24 is formed on the wiring layer 22 by the forming method described in WO Publication No. 00/52977 will be described. According to the formation method of 15, the bottom conductive layer 10 and the protective metal layer 11 are spaced between the columnar metal body 24 and the wiring layer 22. These layers are not necessarily required in the present invention, and may be omitted when the columnar metal body 24 and the wiring layer 22 are formed of other metals. On the other hand, the present invention uses a heat-adhesive insulating layer forming material and a metal layer forming material, and integrates these materials in the layered volume to integrate them. The insulating layer forming material and the metal layer forming material may be Individuals can also be integrated for pre-layering. The example shown in this embodiment uses a metal foil 27 on which an adhesive insulating layer 26a has been formed. There are various types of laminates on the market, and any of them can be used. For example, any metal can be used as the metal foil 27, but from the viewpoints of conductivity, easy etching, cost, etc. 0 continued pages (when the description page of the invention is not enough, please note and use the continued pages) 23 1. Invention The description of the description of the invention is continued on the following page. It is best to use copper widely used for wiring patterns. In addition, ^ 7 can be subjected to a blackening treatment on the surface of the metal ~ box 27 on the side of the thinner insulating layer for the purpose of improving the adhesion with the wax. The | ±, ,, bar, and plutonium layers 26a may be any plutonium that can be deformed during heating and can be cured by heating or the like, and has the heat resistance required for the wiring substrate. Specifically, 'may include various reaction-curable resins such as polyimide resins, epoxy resins, etc.', and composites (polyvinyl acetate film) of these resins with ceramic fibers, aromatic polyamine fibers, and the like are example. Among them, a material that can be hardened by heat and pressure (thermal build-up) to integrate with the core substrate and simplify the manufacturing process is preferred. The thickness of the insulating layer 26a is preferably such that the upper surface of the interlayer connection protrusion 24 is located near the surface of the metal foil 27 described below after the connection. Specifically, it only needs to correspond to the height from the surface of the substrate 21 to the upper surface of the interlayer connection protrusion 24. In addition, since the present invention is not a person who crimps the interlayer connection protrusion 24 and the metal foil 27 to the conductive connection by the aforementioned lamination step, there is an advantage that the thickness accuracy of the insulating layer 26a can not be particularly strictly required. As shown in FIG. 7 (3), the step (3a) of the present invention integrates the wiring layer 22 on which the interlayer connection protrusion 24 has been formed, and the metal foil 27 on which the adhesive insulating layer 26a has been formed. The upper surface 24 a of the interlayer connection protrusion 24 is located near the surface of the metal foil 27. Here, the vicinity of the surface of the metal foil 27 is accessible to the metal foil 27, and a distance of 10 / zm or less is preferable. Alternatively, a metal layer before forming a wiring pattern may be used instead of the wiring layer 22 (this is described later). The method of lamination integration is based on the interlayer connection protrusions that have been formed. Continued pages (When the description page of the invention is insufficient, please note and use the continued page.) The metal box with the insulating layer 26a is arranged to be laminated, and then the force can be applied by pressing (heat lamination, hot stamping). At this time, in order to avoid working pressure> t dagger ’can also etch Li Yan Gu Li J so that% soil brother is vacuum (vacuum lamination). In addition, conditions such as the heating temperature can be appropriately set for the material of the μ-square and the bark layer 26a, so that the insulating layer 2 6 a can be deformed and hardened in accordance with the surface shape of the core substrate. As shown in Figs. 7 (4) to (5), the step (3b) of the present invention is at least, the part of the metal box 27 overlapping with the upper surface 24a of the interlayer connection protrusion B is etched to form an opening 27a. Here, the upper surface of the columnar metal body 24 corresponding to the interlayer 10 connection protrusion B need not be completely flat. 'If it is formed by electroplating, it tends to be a curved surface. At this time, the portion other than the peripheral wall of the columnar metal body 24 is the upper surface 24a. In addition, in the present invention, the upper surface 2 of the so-called interlayer connection protrusion B is heavy. (M knife system refers to the area where the upper surface of the interlayer connection protrusion B is projected on the metal 15 and 27 overlaps with the area of the opening 27a (including the case where it is completely consistent, and some of them include one of the cases). The present invention expands the conductive connection. From an area point of view, it is preferable to use interlayer connection protrusions B, that is, 80% or more of the area where the upper surface 24a of the columnar metal body 24 is projected on the metal foil 27, especially 100% is included in the area of the opening 27a. However, If the area of the opening 27a of the metal foil 27 is too large, the width of the metal moire 27 remaining around it will also increase, which is not conducive to the refinement of the wiring pattern. Therefore, the area of the opening 27a should be an interlayer connection. 0.8 to 5 times the area of the upper surface 24a of the protrusion β. The dry etching can also be used in the rest, but wet etching is preferred, especially 0. Continued pages (When the description page of the invention is insufficient, please note and use the continued page ) Description of the invention, description of the invention Description of the continuation sheet M It is better to use a photosensitive resin such as a dry film resist. The so-called photosensitive M is intended to include light that can be decomposed by light, photobridged, or photopolymerized. Of-knife And / or the resin composition of molecular weight components. As for the coating, the method of laminating dry film and the method of coating and curing the photosensitive resin composition can be used. The dry film (photoresist) is organic solvent. The image type and the alkaline aqueous solution development type are heat-sealed (laminated) by a dry film laminator having a heating and pressing roller, etc. The coating of the photosensitive resin composition can be performed by various coaters. Next, the The part where the opening 27a is formed or the opposite part is exposed and developed, and the former is removed. This type of exposure is a direct exposure line separated by a mask film or a photoelectric plotter and the like, and an exposure machine is usually used, such as ultraviolet rays. For the development, a developing solution or the like corresponding to the type of the dry film can be used, for example, trichloroethane or the like can be used for an organic solvent development type, or sodium carbonate can be used for a diagnostic aqueous solution development type. According to the foregoing, an anti-etching layer 38 having an opening 38a as shown in FIG. 7 (4) can be formed. Then, as shown in FIG. 7 (5), an etching solution corresponding to the material of the metal foil 27 is used to An opening 27a is formed. Examples of the etching solution include commercially available alkaline etching solutions, gaseous etching solutions, ammonium persulfate, hydrogen chloride / sulfuric acid, etc. After the etching is completed, the anti-etching layer 38 may be removed as necessary, which may correspond to the anti-etching layer 38. The type is appropriately selected, such as chemical removal, peeling removal, etc. For example, if it is a dry film resist, for example, methylene chloride can be used for an organic solvent development type, and hydroxide can be used for an alkaline aqueous solution development type. Sodium etc. for peeling. In addition, the removal of the anti-etching layer 38 can also be followed by (3c) 0 Continued pages (If the description page is not enough, please note and use the continued page) 587412 Step 15 is performed simultaneously. As shown in FIG. 8 (6), step (3c) of the present invention is to remove at least a part of the insulating layer 26 exposed from the opening 27a, and expose the upper surface 24a of the interlayer connection protrusion 24. Here, it is not necessary to fully expose the upper surface 24a of the interlayer connection protrusion 24, but from the viewpoint of enlarging the area of the conductive connection, it is desirable to fully expose the upper surface 24a. As the method of removing the insulating layer 26, polishing, abrasive tape, mechanical grinding, laser irradiation, plasma etching, transfer peeling, etc. may be used, but it is preferable to selectively remove the exposure from the opening 27a by sandblasting or chemical etching. Of the insulating layer 26. The sandblasting process such as sandblasting can obtain the grinding effect even on the concave portion of the surface, and the insulating layer such as resin can be removed faster than metal, so that the upper surface of the columnar metal body can be exposed more reliably. In addition, the chemical etching can similarly and selectively remove the insulating layer. Sand blasting can be exemplified by dry or wet blasting and metal particle blasting. For chemical etching, a chemical solution or the like that can selectively decompose resin can be used. In addition, when the insulating layer 26 is removed, the previously provided anti-etching layer 38 can also be used as a shielding material. At this time, the anti-etching layer 38 is removed after the step (3c). As shown in FIG. 8 (7), the step (3d) of the present invention is to form the conductive layer 29 by extending the upper surface 24a of the exposed interlayer connection protrusion 24 to at least the inner peripheral surface of the opening 27a. In the example shown in this embodiment, the conductor layer 29 is formed almost entirely by electroplating the metal foil 27 including the upper surface 24a. Thereby, the interlayer connection protrusion 24 and the metal foil 27 can be electrically connected through the conductor layer 29a bonded to the upper surface 24a, the conductor layer 29b bonded to the inner peripheral surface of the opening 27a, and the conductor layer 29c around it.
0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 27 20 /叶丄z /叶丄z 玫、發明說明 翻說明續頁 藉電鍍所作之導電體層29的形成,可藉無 無電電鑛和電解電鑛之組合等以進行,不過’在提高導電 連接之可靠性方面,刹 以利用恶電電鍍和電解電鍍之組合以 形成者為佳。此時,導電體層29之厚度宜為卜5〇㈣。0 Continued pages (Please note and use the continuation page when the invention description page is insufficient.) 27 20 / 叶 丄 z / 叶 丄 z Mei, the description of the invention is continued, the formation of the conductive layer 29 by electroplating can be borrowed. The combination of non-electric power ore and electrolytic power ore is carried out. However, in terms of improving the reliability of the conductive connection, it is better to use a combination of bad electroplating and electrolytic plating to form it. At this time, the thickness of the conductive layer 29 is preferably 50 Å.
10 15 無電電鍍中通常使用銅、鎳、錫等的電鍵液,該等金 ^«成金心27之金屬相同,也可與之相異,其中以 ..*為佳冑面上有販售各種無電電錢之電鐘液,其係可對 應於各種金屬且眾所皆知者…般而言,液體組成係包含 有金屬離子源、驗性源、還原劑、螯合劑、穩㈣等。另 亦可在無電電叙前,先使等之電賴媒沉殿。至於電 鑛亦可使用業已周知之方法進行。 如第8圖⑴〜第9圖(1〇)所示,本實施形態更進 -步可進行導電體層29和金屬箱27之蝕刻,以實施形成 金屬圖案之㈤步驟。當導電體層29與構成金屬箱27 之金屬是相同時,可同時進行蝕刻,若是不同日夺,只要依10 15 Electroless plating usually uses copper, nickel, tin and other key liquids. The gold ^ «Cheng Jinxin 27 is the same metal, but it can also be different from it. Among them, various types are sold on the surface. * The electric clock liquid without electricity and electricity can correspond to a variety of metals and is well known ... Generally speaking, the liquid composition system includes a metal ion source, an empirical source, a reducing agent, a chelating agent, a stable solution, and the like. In addition, you can also make the waiting electricity to sink to the hall before the electricity is released. As for the power smelting, it is also possible to use a well-known method. As shown in FIGS. 8 (a) to 9 (10), this embodiment is further advanced. The conductor layer 29 and the metal box 27 can be etched to perform the step of forming a metal pattern. When the conductor layer 29 and the metal constituting the metal box 27 are the same, the etching can be performed at the same time.
次進行#刻即可。 首先,如第8圖(8)所示,積層乾膜抗姓劑,且如第 9圖(9)所示,對應於金屬圖案之形狀進行曝光,並顯像 以形成抗餘刻層30a。接著,如第9圖(1〇)所示,使用 20對應於導電體層29和金屬謂27之材質的姓刻液以進行餘 刻,俾形成金屬圖案27b。之後,如第9圖(11)所示, 除去抗餘刻層30a。該等步驟之進行可與(3b)步驟相同 如第9圖(U)所示,可依以上所述者進行之本發明 1¾買次頁(發日顧贿不雖鹏,記避用續頁) 28 一 玖、發明說明 發明說明續頁 的層間連接構造係包含有:用以在層間進行^^接之厂 間連接突起24;配置於該層間連接突起24之周圍且至少 使該層間連接突起24之上面24a的一部份露出的絕緣層 26,積層於该絕緣層26,且與該層間連接突起24之上面 24a重璺並開口的金屬圖案27b ;及,由層間連接突起 之上面24a,至少擴及至該金屬圖案27b之開口 2乃的内 周面以形成導電體層29。 (第3發明之另一實施形態) 以下說明本發明之另一實施形態。 (1 )前述實施形態所顯示之例,係利用w〇公報 00/52977號中記載之方法以形成層間連接突起,不過與第 1發明相同,其亦可利用其他方法以形成。 (2)前述實施形態所顯示之例,係對於業已形成有層 間連接突起之配線層,形成本發明之導電連接構造的方法 不過對於在未形成配線圖案,或於形成配線圖案前之金 屬層業已形成有層間連接突起者,亦可與前述之實施形態 相同般進行,俾形成本發明之導電連接構造。 此時,只須將沒有配線圖案之金屬層和業已形成有接 著〖生纟巴緣層之金屬箔積層而使之一體化,俾層間連接突起 之上面係位於該金屬箔的表面附近,其後之步驟幾乎完全 相同。不過,依此所獲得者,可使用作為兩面金屬箔積層 板’亦可同時蝕刻前述金屬層和金屬箔以形成圖案。又, 亦可不將金屬層形成圖案,而是利用作為或電源層。 (3)前述實施形態所顯示之例,係將包含層間連接突 _次頁(發明說頓不敷使鱗3請註記並賴顯) 坎、發明說明 發明說明續頁 I之上面之至屬4的大略全面進行電鍍以形成導電體層, 不過亦可利用電鍍由已露出之層間連接突起之上面,至少 擴及至開口之内周面以形成導電體層。 此時’設置具有與開口一致或較其稍小重疊的抗鐘層 5後,形成導電體層。此時,以可選擇性地在開口部内側進 行錢敷為佳’若是進行電錢時,亦可在設置抗錢層前,先 I成為導電性底層之無電錢層。又,利用無電錢形成導電 to層蚪,可選擇性地讓觸媒吸附於開口部内側。 (4)别述貫施形態所顯示之例,係藉鍍敷形成導電體 10層,不過亦可藉充填導電性糊、賤鎮、真空蒸錢等形成。 又,亦可將該等方法與電鍍組合以形成導電體層。 當充填導電性糊時,可經由金屬羯之開口,利用絲網 印刷、法等進行充填,導電性糊則可使用用於配線基板者 。又,充填導電性糊,以進行到與金屬絲面大略高度者 15為佳’藉此可使金屬圖案平坦化,也易於在層間連接突起 的正上方形成上層層間連接突起。 至於濺鍍和真空蒸鍍,只要其可形成導電性之薄膜, 則可使用任何習知周知的薄膜形成方法。另,亦可在設置 前述(3)中抗鑛層前,先進行⑽和真空蒸鍵,以形成利 20用電鍍形成導電體層時的底導電層。 產業上可利用性 依本發明可提供一種可將隔在層間的絕緣層厚度平坦 化,且即使絕緣層包含有補強纖維時,也可控制表面平坦 化和絕緣層厚度的層間連接構造形成方法,與藉該方法所 0續次頁(發明說明頁不敷使用時,請註記並使用續頁) 玖、發明說明 發明說明續頁 幵/成之層間連接構造及多層配線基板。因此,本發明之產 業上可利用性很高。 【圖式簡單說明】 第1圖(1)、(2)〜第2圖(3)、(4)、⑴係顯示第 1考X明之層間連接構造形成方法之一例的步驟圖。 第3圖(a)、(b)係顯示第1發明之層間連接構造带 成方法之另一例的步驟圖。 第4圖(a)、(b)〜第5圖(a)係顯示第2發明之層 間連接構造形成方法之一例的步驟圖。 第 6 圖(1)、(2),第 7 圖(3)、(4)、(5),第8圖( 6)、(7)、(8),第 9 圖(9)、(1〇)、(11)係顯示第 2 發明 之層間連接構造形成方法之一例的步驟圖。 0續次頁(發明說明頁不敷使用時’請註記並使用續頁) 587412Just # ticks. First, as shown in FIG. 8 (8), a dry film anti-surname agent is laminated, and as shown in FIG. 9 (9), exposure is performed in accordance with the shape of the metal pattern, and development is performed to form an anti-etching layer 30a. Next, as shown in FIG. 9 (10), 20 is used as the last name engraving liquid corresponding to the material of the conductor layer 29 and the metal index 27 to form a metal pattern 27b. Thereafter, as shown in FIG. 9 (11), the anti-etch-off layer 30a is removed. These steps can be carried out in the same way as step (3b). As shown in Figure 9 (U), the present invention can be carried out according to the above mentioned. 1¾ Buy the next page. ) 28. Description of the invention Description of the invention The interlayer connection structure on the continuation page includes: inter-plant connection protrusions 24 for connecting between the layers; arranged around the inter-layer connection protrusions 24 and at least making the inter-layer connection protrusions A part of the exposed insulating layer 26 on the upper surface 24a of 24 is laminated on the insulating layer 26, and the metal pattern 27b is re-opened with the upper surface 24a of the interlayer connection protrusion 24; and the upper surface 24a is connected by the interlayer connection, It extends to at least the inner peripheral surface of the opening 2 of the metal pattern 27b to form a conductor layer 29. (Another Embodiment of the Third Invention) Next, another embodiment of the present invention will be described. (1) The examples shown in the foregoing embodiments are formed by using the method described in WO 00 Publication No. 00/52977 to form interlayer connection protrusions. However, similar to the first invention, they may be formed by other methods. (2) The example shown in the foregoing embodiment is a method of forming the conductive connection structure of the present invention for a wiring layer on which interlayer connection protrusions have been formed, but has not been applied to a metal layer before a wiring pattern has been formed or before a wiring pattern has been formed. The interlayer connection protrusions may be formed in the same manner as in the aforementioned embodiment to form the conductive connection structure of the present invention. At this time, it is only necessary to integrate the metal layer without the wiring pattern and the metal foil that has been formed next to the edge layer, and the upper surface of the interlayer connection protrusion is located near the surface of the metal foil, and thereafter The steps are almost exactly the same. However, the obtained one can be used as a double-sided metal foil laminate, and the aforementioned metal layer and metal foil can be simultaneously etched to form a pattern. The metal layer may be used as a power source layer instead of a pattern. (3) The example shown in the previous embodiment will include the interlayer connection process_second page (invention is not enough to make the scale 3, please note and show it). The electroplating is generally performed to form the conductor layer, but electroplating can also be used to form the conductor layer from the exposed interlayer connection protrusions to at least the inner peripheral surface of the opening. At this time, after the anti-clock layer 5 is provided which coincides with or slightly overlaps with the opening, a conductor layer is formed. At this time, it is better to selectively apply money on the inside of the opening portion. If electric money is used, it can also be a non-electrical layer with a conductive bottom layer before the anti-money layer is provided. In addition, the conductive to layer is formed by using no electricity, and the catalyst can be selectively adsorbed inside the opening. (4) In addition to the example shown in the form of continuous application, 10 layers of conductors are formed by plating, but they can also be formed by filling with conductive paste, base ball, vacuum steaming, and the like. In addition, these methods may be combined with electroplating to form a conductor layer. When filling the conductive paste, it can be filled by screen printing, method, etc. through the opening of the metal foil, and the conductive paste can be used for wiring substrates. Furthermore, it is preferable to fill the conductive paste with a height of approximately 15 from the surface of the metal wire. As a result, the metal pattern can be flattened, and it is easy to form an upper interlayer connection protrusion directly above the interlayer connection protrusion. As for sputtering and vacuum evaporation, as long as it can form a conductive thin film, any conventionally known thin film forming method can be used. In addition, before the anti-mine layer in (3) is provided, first, vacuum bonding and vacuum bonding may be performed to form a bottom conductive layer when the conductive layer is formed by electroplating. INDUSTRIAL APPLICABILITY According to the present invention, a method for forming an interlayer connection structure capable of flattening the thickness of an insulating layer between layers and controlling the surface flatness and the thickness of the insulating layer even when the insulating layer contains reinforcing fibers can be provided. Continue to the next page by this method (note the use of the continuation page if the description page of the invention is insufficient) 玖. Interlayer connection structure and multilayer wiring board of the invention description continuation page. Therefore, the industrial availability of the present invention is high. [Brief description of the drawings] Figures 1 (1), (2) to 2 (3), (4), and 2 (3), (4), and 2 (3), (4), and (2) are step diagrams showing an example of the method for forming the interlayer connection structure in the first test. Figures 3 (a) and (b) are step diagrams showing another example of the method for forming the interlayer connection structure belt of the first invention. 4 (a), (b) to 5 (a) are step diagrams showing an example of a method for forming an interlayer connection structure of the second invention. Figure 6 (1), (2), Figure 7 (3), (4), (5), Figure 8 (6), (7), (8), Figure 9 (9), (1 〇) and (11) are step diagrams showing an example of a method for forming an interlayer connection structure of the second invention. 0 Continued pages (when the invention description page is insufficient, please note and use the continuation page) 587412
玖、發明說明 【圖式之主要元件代表符號表】 體層 30a,38…抗蝕刻層 L...被積層體 RC·..帶有樹脂之銅箔 1.. .衝壓面 1 a,8a·.·凹部 2…片材 3.. .金屬層形成材 4.. .絕緣層形成材 5.. .凸部 6.. .脫模片 7,8···板 7a.··貫通孔 10—底導電層 11.. .保護金屬層 21…基材 22···配線層 24,B..·層間連接突起(電 鍍層;柱狀金屬體) 24a…上面 26,26a...絕緣層 27.··金屬層(金屬箔) 27a,38a·.·開口 27b。..金屬圖案 28,29,29a,29b,29c…導電 32发明 Description of the invention [Representative symbols of the main elements of the drawing] Body layers 30a, 38 ... Anti-etching layer L ... Laminated body RC ... Copper foil with resin 1. Pressed surface 1 a, 8a ... .. Recess 2 ... Sheet 3. Metal layer forming material 4. Insulating layer forming material 5 .. Protrusion 6 .. Release sheet 7, 8 ... Plate 7a ... Through hole 10 — Bottom conductive layer 11 ... Protective metal layer 21 ... Substrate 22 ... Wiring layer 24, B ..... Interlayer connection protrusion (plating layer; columnar metal body) 24a ... Upper surface 26, 26a ... Insulating layer 27 .. Metal layer (metal foil) 27a, 38a .. Opening 27b. .. metal pattern 28, 29, 29a, 29b, 29c ... conductive 32
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JP2001290761A JP2003101232A (en) | 2001-09-25 | 2001-09-25 | Conductive connection structure and method of forming the same |
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US8400776B2 (en) | 2006-07-28 | 2013-03-19 | Dai Nippon Printing Co., Ltd. | Multilayered printed wiring board |
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US8400776B2 (en) | 2006-07-28 | 2013-03-19 | Dai Nippon Printing Co., Ltd. | Multilayered printed wiring board |
US8942003B2 (en) | 2006-07-28 | 2015-01-27 | Dai Nippon Printing Co., Ltd. | Multilayered printed wiring board |
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