TW518924B - Multi-layer printed wiring board and manufacturing method therefor - Google Patents

Multi-layer printed wiring board and manufacturing method therefor Download PDF

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Publication number
TW518924B
TW518924B TW91104208A TW91104208A TW518924B TW 518924 B TW518924 B TW 518924B TW 91104208 A TW91104208 A TW 91104208A TW 91104208 A TW91104208 A TW 91104208A TW 518924 B TW518924 B TW 518924B
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TW
Taiwan
Prior art keywords
insulating layer
layer
wiring pattern
thin film
printed circuit
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Application number
TW91104208A
Other languages
Chinese (zh)
Inventor
Nobuo Komatsu
Hitoshi Motoyoshi
Yoshiki Kawabata
Original Assignee
Sony Corp
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Publication date
Application filed by Sony Corp filed Critical Sony Corp
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Publication of TW518924B publication Critical patent/TW518924B/en

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  • Production Of Multi-Layered Print Wiring Board (AREA)
  • Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)

Abstract

The object of the present invention is to flatly form a wiring pattern on a connection hole, to make the connection hole finer, and further to make the wiring pattern thin. On a board 2, a 1st wiring pattern 3 is formed and on the board 2 provided with the 1st wiring pattern 3, a thin-film insulating layer 7 is formed; and a connection hole 8 is formed in the thin-film insulating layer 7 so that the 1st wiring pattern 3 is exposed to the outside, and a metal conductive layer 13 is formed on the thin-film insulating layer 7 having the connection hole 8 and then selectively removed to form metal bumps 9. An inter-layer insulating layer 11 is formed on the thin-film insulating layer 7, and a 2nd wiring pattern 12 is formed on the inter-layer insulating layer 11.

Description

518924 A.7 B7 五、發明説明(彳 ) 【發明的技術領域】 本發明係關於在層間絕緣膜上形成導電層之組裝型之多 層型印刷電路基板及多層型印刷電路基板之製造方法。 【先前技藝】 配合電子機器之小型化,一般對印刷電路基板之高密度 配線之要求甚為殷切。為因應此需要,在印刷電路基2 中,採用組裝型之多層型印刷電路基板,已成為時下的趨 勢。此種多層型印刷電路基板例如係在形成於基板上之第 配線圖案上形成層間絕緣層,在此層間絕緣層形成連接 孔,以便施行與第二配線圖案之層間之連接,在含連接孔 内面之層間絕緣層全面施行鍍銅,並完成圖案化,藉以形 成第二配線圖案所構成。 形成於第一配線圖案上之層間絕緣層係利用在基板表面 塗上油墨,或將乾膜疊層於基板表面所形成,形成於此層 間絕緣層之連接孔係利用照相蝕刻、雷射等所形成。 【發明所欲解決之問題】 然而,此多層型印刷電路基板由於係在含連接孔内面之 層間絕緣層表面施行鍍銅,並完成圖案化,以形成第二配 線圖案,因此,在形成連接孔之部分及其周圍會形成凹 口P,在第二配線圖案,即在多層型印刷電路基板之外層圖 案上形成凹部時,無法以安定之狀態安裝電子零件。 因此,雖然也可利用將導電膏充填於連接孔内,藉此填 埋連接孔之方式,使形成第二配線圖案,即形成外層圖案 上之連接孔之部分及其周圍不會形成凹部。但因該印刷電 -4-518924 A.7 B7 V. Description of the Invention (彳) [Technical Field of the Invention] The present invention relates to an assembled multi-layer printed circuit board and a method for manufacturing a multi-layer printed circuit board in which a conductive layer is formed on an interlayer insulating film. [Previous technology] With the miniaturization of electronic equipment, high-density wiring of printed circuit boards is generally required. In response to this need, in printed circuit boards 2, the use of assembled multilayer printed circuit boards has become a trend. Such a multilayer printed circuit board is formed, for example, by forming an interlayer insulating layer on a first wiring pattern formed on the substrate, and forming a connection hole in this interlayer insulating layer so as to perform connection with the layer of the second wiring pattern. The interlayer insulation layer is fully copper-plated and patterned to form a second wiring pattern. The interlayer insulating layer formed on the first wiring pattern is formed by applying ink on the surface of the substrate or laminating a dry film on the surface of the substrate. The connection holes formed on the interlayer insulating layer are formed by photoetching, laser, etc. form. [Problems to be Solved by the Invention] However, since this multilayer printed circuit board is copper-plated on the surface of the interlayer insulating layer including the inner surface of the connection hole and patterned to form a second wiring pattern, the connection hole is formed. A notch P is formed in and around the portion. When a second wiring pattern, that is, a recess is formed on the outer layer pattern of the multilayer printed circuit board, electronic components cannot be mounted in a stable state. Therefore, although it is also possible to fill the connection holes with the conductive paste, thereby filling the connection holes, the second wiring pattern, that is, the portion forming the connection hole on the outer layer pattern and its surroundings will not have a recess. But because of this printed electricity -4-

518924 A7518924 A7

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接著,如圖4(B)所示,在形成配線圖案1〇2之基板l〇i 上,以覆蓋配線圖案102之方式形成導電體層1〇3。此導電 體層1 03係利用鎳-金合金、錫_鉛系焊料合金而以無電解式 電鍍法所形成。在此,導電體層1〇3係選擇使用蝕刻後述金 屬電鍍層104時具有耐性之金屬。 接著,如圖4(C)所示,在導電體層1〇3上利用銅、鎳等形 成金屬電鍍層104。其次,在金屬電鍍層1〇4上形成光罩, 藉蝕刻金屬電鍍層104而如圖4(D)所示,形成用於與外層之 配線圖案保持電性連接之金屬凸塊1〇5。此時之蝕刻對象僅 限於金屬電鍍層104,因此,設於基板1〇1上之導電體層 1〇3會殘留下來。即,導電體層103具有作為蝕刻金屬電鍍 層104之際之钱刻阻擋層之機能。 接著,如圖4(E)所示,利用設光罩並施行蝕刻之方式除 去導電體層103。其次,如圖4(F)所示,在未設金屬凸塊 105之區域,形成層間絕緣層1〇6,用以使外層之配線圖案 與内層之配線圖案102保持絕緣。然後,研磨層間絕緣層 10ό表面,使其與金屬凸塊丨05之端面一致。接著,如圖 4(G)所示,在層間絕緣層1〇6表面施以鍍銅,並使其電錢層 圖案化而形成作為外層之配線圖案107。 但圖4所示之方法因必須形成導電體層1 〇 3,以作為形成 金屬凸塊105之際所施行之蝕刻之蝕刻阻擋層,且在形成金 屬凸塊f〇 5之後,還必須除去該導電體層1 〇 3。即,此方法 為了形成金屬凸塊1 05,必須施行2次不同之電錢處理,以 形成導電體層103及金屬電鍍層104,並施行2次不同之敍 -6 - 本紙張尺度適用中國國家標準(CMS) A4規格(210 X 297公釐)Next, as shown in FIG. 4 (B), a conductor layer 10 is formed on the substrate 10i on which the wiring pattern 102 is formed so as to cover the wiring pattern 102. This conductive layer 103 is formed by a non-electrolytic plating method using a nickel-gold alloy and a tin-lead solder alloy. Here, the conductive layer 10 is selected from metals having resistance when the metal plating layer 104 described later is etched. Next, as shown in FIG. 4 (C), a metal plating layer 104 is formed on the conductor layer 103 using copper, nickel, or the like. Next, a photomask is formed on the metal plating layer 104, and the metal plating layer 104 is etched to form a metal bump 105 for maintaining electrical connection with the wiring pattern of the outer layer as shown in FIG. 4 (D). The etching target at this time is limited to the metal plating layer 104, and therefore, the conductive layer 103 provided on the substrate 101 will remain. That is, the conductor layer 103 has a function as a barrier layer for etching the metal plating layer 104. Next, as shown in FIG. 4 (E), the conductive layer 103 is removed by providing a photomask and performing etching. Next, as shown in FIG. 4 (F), an interlayer insulating layer 10 is formed in a region where the metal bump 105 is not provided, so as to keep the wiring pattern of the outer layer and the wiring pattern 102 of the inner layer insulated. Then, the surface of the interlayer insulating layer 10 is polished so that it is consistent with the end surface of the metal bumps 05. Next, as shown in FIG. 4 (G), copper plating is applied to the surface of the interlayer insulating layer 106, and the electric money layer is patterned to form a wiring pattern 107 as an outer layer. However, in the method shown in FIG. 4, it is necessary to form the conductive layer 10 as the etching stopper for the etching performed when the metal bump 105 is formed, and after the metal bump f05 is formed, the conductive layer must be removed. Bulk layer 1 03. That is, in order to form the metal bumps 105, this method must be performed two different times to form a conductive layer 103 and a metal plating layer 104, and perform two different terms. -6-This paper standard applies to Chinese national standards (CMS) A4 size (210 X 297 mm)

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」处f卩除去導電體層103及金屬電鍍層104 ’結果使得 ί7刷電路基板之製造工序變得相當複雜。另外,由於金屬 鬼105與配線圖案1〇2係經由導電體層Μ]相連接,故有 二要施行界面處理,以提高配線圖案與導電體層之 密接性及導電體層103與金屬凸塊1〇5之密接性。 、,發明之目的係在於提供可將連接孔上之配線圖案形成 平一狀將連接孔形成更微細,進而增進配線圖案之細線 化之夕層型印刷電路基板及此印刷電路基板之製造方法。 口另外本發明之目的係在於提供在達成上述目的之際也 可提高生產效率之多層型印刷電路基板及此印刷電路基板 之製造方法。 【解決問題之手段】 為解決上述問題,本發明之多層型印刷電路基板包含基 板,其係形成配線圖案者;薄膜絕緣層,其係以覆蓋配線 圖案之方式形成於基板上者;層間絕緣層,其係設於薄膜 絕緣層上者;金屬凸塊,其係被薄膜絕緣層與層間絕緣層 所包圍而由薄膜絕緣層突出,並被設於配線圖案上者;及 配線圖案,其係被設於層間絕緣層上,並被連接於金屬凸 塊者。 為解決上述問題,以上之多層型印刷電路基板之製造方 法包含配線圖案形成步驟,其係將配線圖案形成於基板 者,薄膜絕緣層形成步驟,其係以覆蓋配線圖案之方式, 將薄膜絕緣層形成於設有配線圖案之基板上者;連接孔形 成步驟,其係以使配線圖案面臨外部之方式,將連接孔形 -7- 本紙浪尺度適用中Λ家標準(CNS) Α视格(210X297公發)The result is that the conductor layer 103 and the metal plating layer 104 are removed. As a result, the manufacturing process of the circuit board is very complicated. In addition, since the metal ghost 105 and the wiring pattern 102 are connected through the conductive layer M2, there are two things to perform interface processing to improve the adhesion between the wiring pattern and the conductive layer, and the conductive layer 103 and the metal bump 105. Of tightness. An object of the present invention is to provide a layered printed circuit board and a method for manufacturing the printed circuit board, which can form the wiring pattern on the connection hole in a flat shape and further form the connection hole to further finer the wiring pattern. Another object of the present invention is to provide a multilayer printed circuit board and a method for manufacturing the printed circuit board that can improve production efficiency while achieving the above-mentioned objects. [Means for solving problems] In order to solve the above-mentioned problems, the multilayer printed circuit board of the present invention includes a substrate that forms a wiring pattern; a thin-film insulating layer that forms a wiring pattern on the substrate; an interlayer insulating layer , Which is provided on a thin-film insulating layer; metal bumps, which are surrounded by a thin-film insulating layer and an interlayer insulating layer, are protruded by the thin-film insulating layer, and are provided on a wiring pattern; and wiring patterns, which are It is provided on the interlayer insulation layer and is connected to the metal bump. In order to solve the above problems, the above-mentioned method for manufacturing a multilayer printed circuit board includes a wiring pattern forming step, which is a step of forming a wiring pattern on a substrate, and a thin film insulating layer forming step, which is a method of covering the wiring pattern with a thin film insulating layer. Formed on a substrate provided with a wiring pattern; the step of forming a connection hole is to form the connection hole in such a way that the wiring pattern faces the outside. 7- This paper is compliant with the Chinese Standard (CNS) Α Grid (210X297) Public)

裝 玎Pretend

成於薄膜絕緣層者;金屬導電層形成步驟,其 電鍍處理將金屬導電声开;Λ ’、 弟 屯滑形成於形成連接孔之薄膜絕緣層上 ;金屬凸塊形成步驟’其係利用選擇性除去金屬導;層 之方式’形成由_絕緣層突出之金屬凸塊者;層間絕ς 層形成步驟,其係以包圍金屬凸塊之方式將層間絕緣層形 成於薄膜絕緣層上者;及另一配線圖案形成步驟,其係利 用與第-電鍍處理同種之第二電鍍處理,將另一配線圖案 形成於層間絕緣層上者。 【發明之實施形態】 以下,參照圖式將應用本發明之多層型印刷電路基板及 此印刷電路基板之製造方法予以說明之。 如圖1所示,應用本發明之多層型印刷電路基板係i係具 有基板2,此基板2為使玻璃纖維浸潰於環氧樹脂等絕緣性 樹脂所形成之絕緣性基板。在此基板2之兩面,利用蝕刻貼 在基板2兩面之銅箔之方式形成構成内層之第一配線圖案 3、3 。又,在基板2上形成有可使第一配線圖案3、3間保 持電性連接之連接孔4,此連接孔4内設有電鑛層5,可使第 一配線圖案3 ' 3保持電性連接。又,此連接孔4為了使基板 2平坦化,被導電性或絕緣性之膏6永久性填埋。 在基板2之兩面,以覆蓋第一配線圖案3、3方式形成薄膜 絕緣層7、7。薄膜絕緣層7、7係利用鹼性顯影型光阻材 料、適光用絕緣油墨等絕緣材料所形成。此薄膜絕緣層7 ' 7之厚度為1/im〜30//m。此係因為薄膜絕緣層7、7之厚 度小於1 V m時,與第一配線圖案3、3之密接性會變差,在 -8- 本紙張尺度適用中國國家標準(CMS) A4規格(210X297公發) 518924 A7 ______B7 五、發明説明(6 ) 施行此薄膜絕緣層7、7之表面改質之際,薄膜絕緣層7、7 有發生剝離之虞;薄膜絕緣層7、7之厚度大於3〇//m時, 金屬導電層13、13對次一工序所形成之連接孔8 ' 8内之第 一配線圖案3、3之密接性,即電鍍之密接性會變差,且即 使為形成第二配線圖案12、12而研磨金屬導電層13、13之 表面也不會使之平滑。又,薄膜絕緣層7、7之厚度更好的 情況為5/zm〜20/zm。 在薄膜絕緣層7、7之第一配線圖案3、3上形成連接孔8、 8,在此連接孔8、8中,以由薄膜絕緣層7、7突出方式形成 金屬凸塊9、9,以便與第一配線圖案3、3接觸而使内層之 第一配線圖案3、3與外層之第二配線圖案保持電性連接。 金屬凸塊9、9例如係由氯化亞鐵、氯化亞銅所形成。 又,在薄膜絕緣層7、7上,以包圍金屬凸塊9、9方式形 成層間絕緣層11、11,以便使内層之第一配線圖案3、3與 外層之第二配線圖案保持絕緣。層間絕緣層丨i、丨丨係由環 氧樹脂 '酚醛樹脂、脲醛樹脂等熱硬化性樹脂或聚醚、聚 醚酿I、聚醚颯、聚苯撐醚、聚醯亞胺、聚醯二亞胺等熱可 塑性樹脂所形成。 層間絕緣層11、u上形成構成外層之第二配線圖案12、 12,第二配線圖案12、12連接於由層間絕緣層11 ' n面臨 外部之金屬凸塊9、9之端面,而與内層之第一配線圖案3、 J保持電性連接。 其··人,參照圖2說明以上之多層型印刷電路基板丨之製造 方法時,如圖2(A)所示,首先,在基板2形成第一配線圖案 -9 - 518924 A7 發明説明 J 3具體而5,係在基板2兩面貼設銅箔之銅箔疊層板 (例如東芝化學公司製TLC-W_551,基板厚度〇 2 銅 箔厚度1.8//m)先形成連接孔4 ,以使構成各面之第一配線 圖案3、3之銅箔間保持電性連接。此連接孔4例如係利用 NC(數值控制)鑽孔機(例如在日立製工公司製卯了 上裝設鑽頭)而形成直徑〇.25 mm之孔所構成。在設在含連 接孔4内面之基板2兩面之銅箔上,利用無電解式鍍銅等形 成鍍銅層(厚度18/zm),藉以在連接孔4内面也形成導電 層,使設於基板2兩面之銅箔間保持電性連接。其後,為使 基板2表面平坦化,將導電性或絕緣性膏6以永久填埋方式 充填於内面設有轴層之連接孔4。其後,機械的及化 學的處理(例如硫酸洗淨與刷子研磨)對銅箔上設有電鍍層之 ,板2上之導電層表面施行整面。接著,對完成表面^二之 導電層貼上感光性蝕刻抗蝕劑(例如旭化成製三福 AQ5044),並利用設置圖案膜之曝光裝置(歐姆公司製 HMW-55 1D曝光機)加以曝光。然後,利用1%無水碳酸納 對曝光後之導電層加以顯影,並以氯化鐵或氯化銅水溶液 加以㈣。其後’利用3%苛性鈉將導電層之乾膜剝離而形 成第一配線圖案3、3。 接著,如圖2(B)所示,在完成第一配線圖案3、3之圖案 化之基板2上形成薄膜絕緣層7、7。薄膜絕緣層7、7係利用 網版印刷法,將鹼性顯影型光阻材料 '適光用絕緣油墨等 絕緣材料(例如太陽油墨公司製psR-4〇〇〇)塗佈於完成第一 配線圖案3、3之圖案化之基板2上,謂。c施行%分鐘之 -10- --- 本紙浪尺度適用中國國家標準(CNS) A4規格(210 X 297公釐) 五、發明説明( 烘乾而成半硬化狀態。 接著,在薄膜絕緣層7、7形成使第一配線圖案3、3面臨 外4之連接孔8、8,連接孔8、8係利用照相钱刻法钱刻薄 膜絕緣層7、7所形成。其後,將形成連接孔8、8之薄膜絕 緣層7 ' 7置於16(TC下加熱6〇分鐘,使其完全硬化。此 時,如上所述,所形成之薄膜絕緣層7、7厚度在l//m〜3〇 /^之間^好的情況係在“瓜〜⑼㈣之間乂此係因為 薄膜絕緣層7、7之厚度小於1//〇1時,與第一配線圖案3、3 之密接性會變差,在施行此薄膜絕緣層7、7之表面改質之 際,薄膜絕緣層7、7有發生剝離之虞;又,薄膜絕緣層7、 7之厚度大於30 # m時,金屬導電層13、13對次一工序所形 成之連接孔8 ' 8内之第一配線圖案3、3之密接性,即電鐘 之搶接性會變差,且即使為形成第二配線圖案12、12而研 磨金屬導電層13、13之表面也不會使之平滑之故。 在此雖係以利用照相蝕刻法將連接孔8、8形成於薄膜絕 緣層7/ 7之例加以說明,但連接孔8、8也可改用鑽孔機或 雷射光加工方式加以形成。即,首先在形成第一配線圖案 J^之基板2上,利用熱硬化或熱可塑性之絕緣性油墨或薄 膜形成薄膜絕緣層7、7。例如將網版(T-3〇〇N、厚設 置於網版印刷裝置(New Long製印刷機LS-150),利用網版 印刷將熱硬化油墨(旭化學研究所製CR-15〇)印刷在形成第 一配線圖案3、3之基板2上,以形成薄膜絕緣層7、7。接 著’以開箱狀態將形成薄膜絕緣層7、7之基板2,置於16〇 C溫度下加熱60分鐘,藉以使薄膜絕緣層7、7硬化,然後Those formed on the thin film insulation layer; the step of forming the metal conductive layer, which is electroplated to turn the metal conductive sound; Λ ', the dimple slip is formed on the thin film insulation layer forming the connection hole; the step of forming the metal bumps uses the selectivity Remove the metal guide; the way of the layer 'forms the metal bumps protruding from the insulating layer; the interlayer insulation layer forming step is to form the interlayer insulating layer on the thin film insulating layer in a manner of surrounding the metal bumps; and A wiring pattern forming step in which another wiring pattern is formed on the interlayer insulating layer using a second plating process of the same kind as the first plating process. [Embodiments of the invention] Hereinafter, a multilayer printed circuit board to which the present invention is applied and a method of manufacturing the printed circuit board will be described with reference to the drawings. As shown in Fig. 1, a multilayer printed circuit board to which the present invention is applied has a substrate 2 which is an insulating substrate formed by impregnating glass fibers with an insulating resin such as epoxy resin. The first wiring patterns 3 and 3 constituting the inner layer are formed on both sides of the substrate 2 by etching copper foils attached to both sides of the substrate 2. In addition, a connection hole 4 is formed on the substrate 2 to allow the first wiring patterns 3 and 3 to be electrically connected. An electric ore layer 5 is provided in the connection hole 4 so that the first wiring pattern 3 ′ 3 can be electrically maintained. Sexual connection. The connection hole 4 is permanently filled with a conductive or insulating paste 6 in order to planarize the substrate 2. On both surfaces of the substrate 2, thin-film insulating layers 7, 7 are formed so as to cover the first wiring patterns 3, 3. The thin-film insulating layers 7 and 7 are formed using an insulating material such as an alkali-developing photoresist material and an insulating ink for light adaptation. The thickness of the thin-film insulating layer 7 ′ 7 is 1 / im˜30 // m. This is because when the thickness of the thin-film insulating layers 7, 7 is less than 1 V m, the adhesiveness with the first wiring patterns 3, 3 will be deteriorated. At -8-, this paper size applies the Chinese National Standard (CMS) A4 specification (210X297 (Issue) 518924 A7 ______B7 V. Description of the invention (6) When the surface modification of the thin film insulation layers 7, 7 is implemented, the thin film insulation layers 7, 7 may be peeled off; the thickness of the thin film insulation layers 7, 7 is greater than 3 〇 // m, the adhesion of the metal conductive layers 13, 13 to the first wiring patterns 3, 3 in the connection holes 8 '8 formed in the next process, that is, the adhesion of the plating will be poor, and even if it is formed, Polishing the surfaces of the metal conductive layers 13 and 13 of the second wiring patterns 12 and 12 does not smooth them. The thickness of the thin-film insulating layers 7 and 7 is more preferably 5 / zm to 20 / zm. Connection holes 8, 8 are formed in the first wiring patterns 3, 3 of the thin film insulation layers 7, 7. In the connection holes 8, 8, metal bumps 9, 9 are formed in a protruding manner from the thin film insulation layers 7, 7. In order to make contact with the first wiring patterns 3 and 3, the first wiring patterns 3 and 3 on the inner layer and the second wiring patterns of the outer layer are electrically connected. The metal bumps 9 and 9 are formed of ferrous chloride and cuprous chloride, for example. In addition, interlayer insulating layers 11, 11 are formed on the thin film insulating layers 7, 7 so as to surround the metal bumps 9, 9 so as to keep the first wiring patterns 3, 3 on the inner layer and the second wiring patterns on the outer layer insulated. Interlayer insulation layer 丨 i, 丨 丨 are made of thermosetting resins such as epoxy resins, phenolic resins, urea resins, or polyethers, polyethers, polyethers, polyphenylene ethers, polyimines, and polyfluorenes. Formed from a thermoplastic resin such as imine. The second wiring patterns 12, 12 constituting the outer layer are formed on the interlayer insulating layers 11, u. The second wiring patterns 12, 12 are connected to the end faces of the metal bumps 9, 9 facing the outside by the interlayer insulating layer 11'n, and communicate with the inner layer. The first wiring patterns 3 and J remain electrically connected. When the following describes the manufacturing method of the multilayer printed circuit board 丨 with reference to FIG. 2, as shown in FIG. 2 (A), first, a first wiring pattern is formed on the substrate 9-518924 A7 Invention Description J 3 Specifically, 5 is a copper foil laminated board (for example, TLC-W_551 manufactured by Toshiba Chemical Co., Ltd. with a substrate thickness of 0 and a copper foil thickness of 1.8 // m) on both sides of the substrate 2 to form a connection hole 4 to make the structure The copper foils of the first wiring patterns 3 and 3 on each side are electrically connected. This connection hole 4 is formed by, for example, an NC (numerical control) drilling machine (for example, a drill is manufactured by Hitachi Manufacturing Co., Ltd.) and a hole having a diameter of 0.25 mm is formed. A copper plating layer (thickness 18 / zm) is formed on the copper foil provided on both sides of the substrate 2 including the inner surface of the connection hole 4 by using electroless copper plating or the like, so that a conductive layer is also formed on the inner surface of the connection hole 4 and provided on the substrate. 2 The copper foils on both sides remain electrically connected. Thereafter, in order to flatten the surface of the substrate 2, a conductive or insulating paste 6 is permanently filled in the connection hole 4 provided with a shaft layer on the inner surface. Thereafter, mechanical and chemical treatments (such as sulfuric acid cleaning and brush grinding) are provided on the copper foil with a plating layer, and the entire surface of the conductive layer on the plate 2 is applied. Next, a photosensitive etching resist (for example, Mitaka AQ5044, manufactured by Asahi Kasei) is applied to the conductive layer on the second surface, and exposed using an exposure device (HMW-55 1D exposure machine, manufactured by Ohm Corporation) provided with a pattern film. Then, the exposed conductive layer was developed by using 1% anhydrous sodium carbonate, and then rubbed with ferric chloride or copper chloride aqueous solution. After that, the dry film of the conductive layer was peeled with 3% caustic soda to form the first wiring patterns 3, 3. Next, as shown in FIG. 2 (B), thin-film insulating layers 7, 7 are formed on the substrate 2 on which the first wiring patterns 3, 3 have been patterned. The thin-film insulating layers 7 and 7 are coated with an insulating material such as an alkali-developing photoresist material, a light-resistant insulating ink (for example, psR-4OO, manufactured by Sun Ink Co., Ltd.) using a screen printing method to complete the first wiring. Patterns 3 and 3 are patterned on the substrate 2. c Implementation of% minutes -10- --- This paper wave scale is applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 5. Description of the invention (Drying into a semi-hardened state. Next, the thin film insulation layer 7 7 and 7 form connection holes 8 and 8 with the first wiring patterns 3 and 3 facing outward 4. The connection holes 8 and 8 are formed by engraving thin-film insulating layers 7 and 7 with a photo money engraving method. Thereafter, connection holes will be formed. The thin film insulation layers 7 and 7 of 8 and 8 are heated at 16 ° C for 60 minutes to completely harden. At this time, as described above, the thickness of the thin film insulation layers 7 and 7 formed is 1 // m ~ 3 〇 / ^ ^ The good condition is between “melon and ⑼㈣”. This is because when the thickness of the thin-film insulating layers 7, 7 is less than 1 // 〇1, the adhesion with the first wiring patterns 3, 3 will change. Poor. When the surface modification of the thin film insulating layers 7 and 7 is implemented, the thin film insulating layers 7 and 7 may be peeled off. When the thickness of the thin film insulating layers 7 and 7 is greater than 30 # m, the metal conductive layer 13 And 13 pairs of the first wiring patterns 3, 3 in the connection holes 8 ′ 8 formed in the next process, the tightness of the electric clock will be worse, and even if the first The wiring patterns 12, 12 are not smoothed by polishing the surfaces of the metal conductive layers 13, 13. Although the connection holes 8, 8 are formed in the thin-film insulating layer 7/7 by using a photo-etching method, this is used as an example. Note, but the connection holes 8 and 8 can also be formed by drilling or laser processing. That is, firstly, on the substrate 2 on which the first wiring pattern J ^ is formed, a thermosetting or thermoplastic insulating ink or The thin film forms the thin film insulating layers 7, 7. For example, a screen printing plate (T-3 00N, thickly installed in a screen printing device (New Long printing press LS-150)), and a screen printing method is used to apply a thermosetting ink (Asahi Chemical CR-15 manufactured by the research institute) is printed on the substrate 2 on which the first wiring patterns 3 and 3 are formed to form the thin-film insulating layers 7, 7. Then, the substrate 2 on which the thin-film insulating layers 7, 7 are formed in an unboxed state, Heat at 60 ° C for 60 minutes to harden the thin film insulation layers 7, 7 and then

在硬化之薄膜絕緣層7、7之特定位置,利用雷射開孔裝置 (日立比亞美卡尼克斯公司製LC0-1A21),以使第一配線圖 案3、3面臨外部方式形成連接孔8、8。 其次,對薄膜絕緣層7、7_表面施行表面改質,以改善與 _人工序所形成之金屬導電層之密接性。此表面改質係利 用下列方式進行:利用德絲麥處理裝置等,將形成薄膜絕 緣層7、7之基板2浸潰在N_甲基代吡咯烷酮、過錳酸 鈉、硫酸胲中,經各工序後,再經過水洗、烘乾而完成改 質處理。此外,此表面改質也可利用過錳酸鉀、重鉻酸 卸、重鉻酸鈉、濃硫酸等之氧化劑 '氫氧化納、氫氧化钾 等驗性劑、N,N-二曱替卸醯胺、二甲亞石風等有機溶劑、 電漿處理、紫外線照射處理等加以完成。 其次,如圖2(C)所示,在表面改質後之薄膜絕緣層7、7 上形成用於形成金屬凸塊9、9之金屬導電層13、13。此金 屬導電層13、13為確保與銅箔所形成之第一配線圖案3、3 之拴接性強度,利用無電解式鐘銅等形成6〇“111程度之厚 度。又’金屬導電層13、13除銅以外,也可使用鎳、|呂、 金'銀等之導電材料。 其次’如圖2(D)所示,金屬導電層13、13利用除去其特 定區域而形成由薄膜絕緣層7、7突出之金屬凸塊9、9。金 屬凸塊9、9之形成係利用下列方式:即,利用硫酸、鹽 酸、有機酸等化學性研磨或擦洗、刮削、刷洗等物理性研 磨,研磨金屬導電層13、13,整理金屬凸塊9、9表面之 後,在金屬導電層13、13上形成抗蝕劑層,利用蝕刻選擇 -12- 本紙浪尺度適用中國國家標準(CNS) Λ4規格(210X 297公釐) A7 B7At a specific position of the hardened thin film insulating layers 7, 7, a laser hole device (LC0-1A21 manufactured by Hitachi Bikanex Corporation) is used to form the connection holes 8 so that the first wiring patterns 3 and 3 face the outside. ,8. Secondly, surface modification is performed on the surface of the thin-film insulating layers 7 and 7 to improve the adhesion with the metal conductive layer formed by the human process. This surface modification is performed in the following manner: The substrate 2 forming the thin-film insulating layers 7 and 7 is immersed in N_methylpyrrolidone, sodium permanganate, and thallium sulfate by using a Desmac treatment device and the like. After the process, it is washed and dried to complete the modification process. In addition, this surface modification can also use oxidizing agents such as potassium permanganate, dichromate, sodium dichromate, concentrated sulfuric acid, such as sodium hydroxide, potassium hydroxide and other test agents, N, N-dioxine, etc. Organic solvents such as osmamine and dimethylphosphine, plasma treatment, and ultraviolet irradiation treatment are completed. Next, as shown in FIG. 2 (C), metal conductive layers 13, 13 for forming metal bumps 9, 9 are formed on the thin-film insulating layers 7, 7 after surface modification. The metal conductive layers 13 and 13 are formed to a thickness of 60 to 111 by using electroless bell copper or the like in order to ensure the strength of the connection between the first wiring patterns 3 and 3 formed with the copper foil. In addition to copper, conductive materials such as nickel, copper, and silver can also be used. Next, as shown in FIG. 2 (D), the metal conductive layers 13, 13 are formed by removing a specific region to form a thin-film insulating layer. 7, 7 protruding metal bumps 9, 9. The formation of the metal bumps 9, 9 is achieved by the following methods: that is, using chemical polishing such as sulfuric acid, hydrochloric acid, organic acid, or physical polishing such as scrubbing, scraping, brushing, etc. Metal conductive layers 13,13, after finishing the surface of metal bumps 9,9, a resist layer is formed on metal conductive layers 13,13, and the selection is made by etching -12- This paper applies the Chinese National Standard (CNS) Λ4 specification ( 210X 297 mm) A7 B7

518924 五、發明説明( 性除去金屬導電層13、13所形成。此時,薄膜絕緣層7、7 具有作為形成金屬凸塊9、9之際之蝕刻阻擋層之機能。具 體而言’係利用厚30 /z m之乾膜(日合莫頓公司製NIT_ 230) ’作為蝕刻抗蝕劑,在研磨後,利用疊片機將此乾膜 貼合於金屬導電層13、13,接著,利用曝光裝置(小野測器 公司製NT-800)加以曝光,然後由金屬導電層13、13將乾 膜剝離而形成金屬凸塊9、9。 又’姓刻抗钱劑也可利用將抗钱刻油墨,以網版印刷方 式印在金屬導電層13、13上,或利用電解沉積蝕刻抗蝕劑 之電泳塗裝法(ED 法;electrophoretic deposition method)加以形成。又,蝕刻時應兼顧金屬導電層13、13 之材料與蝕刻抗蝕劑雙方之需要,選擇最適當之方法。例 如,金屬導電層13、13使用氯化亞鐵或氯化亞銅時,蝕刻 抗蝕劑之除去係利用強鹼溶劑等化學藥品或刷洗研磨等物 理性研磨方式加以除去。 其次,如圖2(E)所示,在薄膜絕緣層7、7上形成層間絕 緣層11、11,以便使内層之第一配線圖案3、3與外層之第 二配線圖案12、12保持電性絕緣。層間絕緣層丨〗、丨丨係由 環氧樹脂、三聚氰胺樹脂、紛酿樹脂、脲酸:樹脂等熱硬化 性樹脂或聚醚、聚醚酮、聚醚硬、聚苯撐醚、聚醯亞胺、 聚酿二亞胺等熱可塑性樹脂所形成,且形成與金屬凸塊9、 9等高或略高之高度。又,層間絕緣層η、11係利用疊片裝 置(名機公司製品)’對乾膜施行真空疊片所形成。另外,層 間絕緣層11、11也可利用簾流塗佈法塗佈上述材料,或利 -13- 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐)518924 V. Description of the invention (formed by removing metallic conductive layers 13, 13 at this time. At this time, the thin-film insulating layers 7, 7 have a function as an etching stopper when metal bumps 9, 9 are formed. Specifically, it is used A dry film with a thickness of 30 / zm (NIT_230 manufactured by Nippon Morton Co., Ltd.) 'as an etching resist, and after lapping, this dry film was bonded to the metal conductive layers 13 and 13 by a laminator, and then exposed by exposure Device (NT-800 manufactured by Ono Detector Co., Ltd.), and then the metal conductive layers 13, 13 are used to peel off the dry film to form metal bumps 9, 9. Also, the anti-money engraving agent can also be used. , Printed on the metal conductive layers 13 and 13 by screen printing, or formed by using an electrophoretic deposition method (ED method) of an electrolytic deposition etching resist. Also, the metal conductive layer 13 should be taken into consideration during etching. The materials and materials used for etching resists are the most appropriate method. For example, when ferrous chloride or cuprous chloride is used for metal conductive layers 13, 13, the etching resist is removed by using a strong alkaline solvent. And other chemicals or scrubbing The physical polishing method is used to remove it. Next, as shown in FIG. 2 (E), interlayer insulating layers 11, 11 are formed on the thin film insulating layers 7, 7 so that the first wiring patterns 3, 3 on the inner layer and the second wiring patterns 3 on the outer layer are formed. The wiring patterns 12, 12 are electrically insulated. The interlayer insulation layer is made of epoxy resin, melamine resin, brewed resin, uric acid: resin or other thermosetting resin or polyether, polyetherketone, or polyether. It is formed by thermoplastic resins such as hard, polyphenylene ether, polyimide, and polyimide, and it has a height equal to or slightly higher than the metal bumps 9, 9, and the interlayer insulation layers η, 11 are It is formed by using a lamination device (product of Mingji Co., Ltd.) to perform vacuum lamination on the dry film. In addition, the interlayer insulation layers 11, 11 can also be coated with the above materials by curtain flow coating, or -13- this paper size Applicable to China National Standard (CNS) A4 (210 X 297 mm)

裝 訂Binding

線 A7 ------— __B7 三、發明説明(~— 用網版印刷法印刷上述材料等方法加以形成。 其後,研磨層間絕緣層U'u表面,以施行金屬凸塊9、 9之頭部顯路與平滑化處理。此時,係利用研削力較大之皮 帶砂磨、刮削研磨等物理性研磨方式。在此,因上述薄膜 利用此研磨,使金屬凸塊9、9之端面及連續於此端面之層 間絕緣層U、η表面保持平滑,且在形成第二配線圖案 12、12時,可防止像以往一般在連接孔8、8上及其周緣部 形成凹部。 然後,對已經平滑化之層間絕緣層丨丨、u表面施行粗糙 化處理’以提高在此所形成之第二配線圖案12、12之密接 性。具體而言,此粗糙化處理係利用水平德絲麥處理裝置 等’將層間絕緣層11、11浸潰在N-甲基代-2-啦錢g同、過 猛§文鈉H胲巾而完成,然後將此層間絕緣層u、^水 洗後烘乾。又,此粗糙化處理也可利用過錳酸鉀、重鉻酸 鈉、濃硫酸等之氧化劑、氫氧化鈉、氫氧化鉀等鹼性劑、 N-甲基代-2-咄咯烷酮、N,二甲替鉀醯胺、二曱亞颯、 二°比咯烷酮等有機溶劑等加以施行。 其後,如上述圖1所示,在層間絕緣層11、11上形成第二 配線圖案12、12。具體而言,係在層間絕緣層11、11上, 形成至少具有形成於精細圖案之第二配線圖案12、12時不 會斷線程度之厚度,例如3〇//m以下之鍍銅層,在此係利 用無電解式鍍銅等形成18/zm之鍍銅層。此係因為厚度大 於3 0/zm時,對精細圖案之形成較為不利之故。其後,以 用中_ 家標準 -14- 518924Line A7 -------- __B7 Third, the description of the invention (~-Formed by screen printing method to print the above materials and other methods. After that, the surface of the interlayer insulation layer U'u was polished to implement metal bumps 9, 9 The head is exposed and smoothed. At this time, a physical grinding method such as belt sanding and scraping grinding with a large grinding force is used. Here, the above-mentioned film uses this grinding to make the metal bumps 9, 9 The end surface and the surfaces of the interlayer insulation layers U and η continuous to this end surface are kept smooth, and when the second wiring patterns 12, 12 are formed, it is possible to prevent the formation of recesses on the connection holes 8, 8 and their peripheral portions as in the past. Roughening the surface of the interlayer insulating layer 丨 丨 u that has been smoothed to improve the adhesion of the second wiring patterns 12, 12 formed here. Specifically, this roughening treatment uses horizontal Desma Processing device, etc. 'The interlayer insulation layers 11 and 11 are impregnated with N-methyl-2--2- alkane, the same and too fierce § Wen Na H towel, and then the interlayer insulation layers u and ^ are washed with water and dried. Dry, and this roughening treatment can also use potassium permanganate, dichromic acid Oxidants such as sodium and concentrated sulfuric acid, alkaline agents such as sodium hydroxide and potassium hydroxide, N-methyl-2-pyrrolidone, N, dimethylformamidine, diamidine, dioxin Organic solvents such as rolidone are applied. Thereafter, as shown in FIG. 1 described above, the second wiring patterns 12 and 12 are formed on the interlayer insulating layers 11 and 11. Specifically, they are formed on the interlayer insulating layers 11 and 11. The thickness of at least the second wiring pattern 12, 12 formed in the fine pattern will not be disconnected, for example, a copper plating layer of 30 // m or less. Here, an electroless copper plating is used to form 18 / zm copper plating layer. This is because the thickness is more than 30 / zm, which is disadvantageous for the formation of fine patterns. After that, it is recommended to use the standard _ house standard -14-518924

五、發明説明( A7 B7V. Description of the invention (A7 B7

120°C〜200°C之溫度,對設有鍍銅層之基板2施行1〇分鐘 〜120分鐘之熱處理,以提高鍍銅層與層間絕緣層丨丨、又i 之岔接性。此係因為不滿12 0及1 0分鐘時,無法提高密接 性,大於200。(:及120分鐘時,基板2本身會被氧化,而降 低基板2之可靠性之故。At a temperature of 120 ° C to 200 ° C, a heat treatment is performed on the substrate 2 provided with a copper plating layer for 10 minutes to 120 minutes to improve the bifurcation between the copper plating layer and the interlayer insulation layer. This is because when the time is less than 120 or 10 minutes, the adhesion cannot be improved, and it is more than 200. (: At 120 minutes, the substrate 2 itself will be oxidized, which reduces the reliability of the substrate 2.

裝 其次,利用水平德絲麥處理裝置等,將加熱處理後之鍍 銅層浸潰在N-甲基代-2-吡咯烷酮、過錳酸鈉、硫酸胲中, 以施行德絲麥處理,接著施行水洗。其後,鐘銅層在曝光 顯影之後,被姓刻而形成第二配線圖案丨2、12。 在經過以上處理後之印刷電路基板丨上,再於形成第二配 線圖案12、12之表面形成抗焊層(太陽油墨公司製p^ 4000系列),然後施行第二配線圖案12、12之預導通處理 而形成Ni/Au(鎳/金)層。Next, the heat-treated copper-plated layer was immersed in N-methyl-2-pyrrolidone, sodium permanganate, and thallium sulfate using a horizontal Desmarck treatment device, etc. Wash with water. Thereafter, the bell copper layer is engraved by the last name after exposure and development to form the second wiring patterns 2 and 12. On the printed circuit board after the above treatment, a solder resist layer (p ^ 4000 series made by Sun Ink Co., Ltd.) is formed on the surface on which the second wiring patterns 12, 12 are formed, and then the second wiring patterns 12, 12 are pre-planned. The Ni / Au (nickel / gold) layer is formed by the conduction process.

線 以上之多層型印刷電路基板1係在形成第一配線圖案33 後,形成薄膜絕緣層7、7,在此薄膜絕緣層7、7形成連接 孔8、8後,形成金屬導電層丨3、13,並以薄膜絕緣層7、7 作為钱刻阻擋層而蝕刻金屬導電層13、13 ,藉以形成金屬 凸塊9、9,因此,可形成直接連接於第一配線圖案3、3之 金屬凸塊9、9,而提高連接可靠性。亦即可提高第一配線 圖案3、3與金屬凸塊9、9之密接性,故可達成連接孔8、8 之小直徑化,即可縮小金屬凸塊9、9之直徑。 又,因形成金屬凸塊9、9之電鍍處理與形成第二配線圖 案1 2 ' 12之電鍍處理係採個別施行之方式,故可使第二配 線圖案12、12之膜厚變薄,達成第二配線圖案I〕、I〕之細 -15-The multilayer printed circuit board 1 above the line is formed with the first wiring pattern 33, and then formed with thin film insulation layers 7, 7, and after the connection holes 8, 8 are formed in the thin film insulation layers 7, 7, a metal conductive layer is formed. 13, and the thin film insulating layers 7, 7 are used as the etch-resistant barrier layer to etch the metal conductive layers 13, 13 to form metal bumps 9, 9; therefore, metal bumps directly connected to the first wiring patterns 3, 3 can be formed. Blocks 9, 9 improve connection reliability. That is, the adhesion between the first wiring patterns 3, 3 and the metal bumps 9, 9 can be improved, so that the diameter of the connection holes 8, 8 can be reduced, and the diameters of the metal bumps 9, 9 can be reduced. In addition, since the plating process for forming the metal bumps 9, 9 and the plating process for forming the second wiring pattern 12'12 are performed separately, the film thickness of the second wiring patterns 12, 12 can be reduced to achieve Fineness of the second wiring pattern I], I] -15-

518924 A7 B7 五、發明説明( 線化’同時使金屬凸塊9、9之週邊也變得平坦。 由於用於形成金屬凸塊9、9之金屬導電層13、13與用於 形成第二配線圖案12、12之鍍銅層係施行同種電鍍處理, 故可使用同一電鍍裝置,同時在蝕刻之際,也可使用相同 之餘刻液,因此可謀求製造工序之簡單化。 又’為形成金屬凸塊9、9而施行姓刻之際,由於係形成518924 A7 B7 V. Description of the Invention (Linearization) At the same time, the perimeters of the metal bumps 9, 9 also become flat. Because the metal conductive layers 13, 13 used to form the metal bumps 9, 9 and used to form the second wiring The copper plating layers of the patterns 12 and 12 are subjected to the same kind of electroplating treatment, so the same electroplating device can be used, and at the same time, the same etching solution can be used during etching, so that the manufacturing process can be simplified. When the bumps 9 and 9 are used for the last name engraving,

薄膜絕緣層7 ' 7作為蝕刻阻擋層,因此,可減少金屬導電 層、13之蝕刻量,且提高蝕刻之精確度,結果可形成精 細圖案。 又’測定以上述方式所形成之多層型印刷電路基板1之第 一配線圖案3、3與第二配線圖案12、12間之導體電阻之結 不’發現其值為0.4Q,顯示可獲得良好之導通特性。 又,對此多層型印刷電路基板丨共“片反覆施行遽熱遽冷 處理,依照JIS(日本工業標準)C 50之規定施行20次循環之 熱衝擊試驗,以調查第二配線圖案12、12之剝離狀態等特 性之結果,證實第一配線圖案3、3與第二配線圖案12、12 間之導體電阻值為0.6 Ω,效果相當良好。 另外,依知、圖3所示方式製造以往型式之多層型印刷電路 基板,然後將其與應用本發明所形成之多層型印刷電路基 板1之精細圖案作比較。為製造以往型式之多層型印刷電路 基板21,如圖3(A)所示,首先,在基板22形成第一配線圖 案23、23 ’此第一配線圖案23、23係利用與形成在上述基 板2之第一配線圖案3、3同樣方式所形成。此時,在基板22 形成有内面設電鍍之連接孔32,以便使設於基板㈣ -16- 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐) 518924The thin-film insulating layer 7'7 serves as an etching stopper. Therefore, the amount of etching of the metal conductive layer and 13 can be reduced, and the accuracy of the etching can be improved. As a result, a fine pattern can be formed. Also, "measure the junction resistance between the first wiring patterns 3, 3 and the second wiring patterns 12, 12 of the multilayer printed circuit board 1 formed in the above manner, and find that the value is 0.4Q, which shows that good results can be obtained. Its conduction characteristics. In addition, this multilayer printed circuit board was subjected to a “hot and cold” treatment repeatedly, and a thermal shock test was performed 20 times in accordance with the JIS (Japanese Industrial Standard) C 50 to investigate the second wiring pattern 12, 12 As a result of characteristics such as peeling state, it was confirmed that the conductor resistance value between the first wiring patterns 3 and 3 and the second wiring patterns 12 and 12 was 0.6 Ω, and the effect was quite good. The multilayer printed circuit board is then compared with the fine pattern of the multilayer printed circuit board 1 formed by applying the present invention. In order to manufacture a conventional multilayer printed circuit board 21, as shown in FIG. 3 (A), first, The first wiring patterns 23 and 23 are formed on the substrate 22. The first wiring patterns 23 and 23 are formed in the same manner as the first wiring patterns 3 and 3 formed on the substrate 2. At this time, the substrate 22 is formed with The inner surface is provided with plated connection holes 32 so as to be provided on the substrate ㈣ -16- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 518924

面之第-配線圖案23、23間保持電性連接,並在此種連接 孔32中充填導電性或絕緣性之膏33。 其次,在形成第一配線圖案23、23之基板22,如圖3(B) 所示宜層一附樹脂之銅箔(塗樹脂銅箔RCC ·· resin coated C0pper,住友貝克萊特ApL-4〇〇i)。即在設有第 一配線圖案23、23之基板22上,形成層間絕緣層24、24, 在層間絕緣層24、24上疊層一銅羯25、25。 "人如圖3(c)所示’利用蝕刻除去銅箔25、25,接 者:在層間絕緣層24、24上之特定位置,利用雷射開孔裝 置形成使第一配線圖案23、23面臨外部之連接孔%、%。 其次,對形成連接孔26、26之層間絕緣層24、24施行德絲 麥處理,以除去表面之樹脂殘潰。 其次,如圖3(D)所示,在層間絕緣層24、24上,利用無 電解式鑛銅等形成厚度18_之鍍銅層27、27。此鑛銅層 27、27係用於構成外層之第二配線圖案之層,除了被形成 在層間絕緣層24、24表面以外,也被形成於連接孔26、26 之内面,而與第一配線圖案23、23保持電性連接。其後, 如圖3(E)所示,在内面設有鍍銅層27、27之連接孔%、26 中充填填孔用油墨28、28(旭化學研究所製FP-R12〇),並 在溫度12(TC下烘乾100分鐘,接著,在18〇t下加熱3〇分 鐘使其硬化。 其次’如圖3(F)所示,在鍍銅層27、27卫,利用無電解 式鍍銅形成鍍銅層29、29,接著,對鍍銅層27、29施行曝 光、顯影、蝕刻而形成第二配線圖案3〇、3〇。此第二配線 -17- 本紙ί艮尺度適用中國國冬標準(CNS) A4規格(210 X 297公發) 518924 A7 B7 五、發明説明(15 ) 圖案30、30係由鍍銅層27、29疊層所形成,其厚度為36/2 m ° 在上述應用本發明之多層型印刷電路基板1中,可將第二 配線圖案12、12之圖案寬/圖案間之空間寬形成50 // m/5〇 ,相對地,圖3所示之多層型印刷電路基板21雖可將圖 案寬/圖案間之空間寬形成70 // m/70 # m,但如將厚度減薄 至50//m/50"m時,第二配線圖案30、30便會斷線。此係 因為第二配線圖案30、30係由二層之鍍銅層27、29所構 成,其36/zm之厚度比厚度18//m之多層型印刷電路基板1 之第二配線圖案12、12更厚之故。如此,應用本發明之多 層型印刷電路基板1與比較例之印刷電路基板21相比,可形 成更小之圖案寬及更薄更細線化之配線圖案。 以上係以設有二層導電層之印刷電路基板丨為例加以說 明,但本發明並不限定於此導電層之數。 【發明之功效】 本發明由於在將配線圖案形成於基板後,形成薄膜絕緣 層,在薄膜絕緣層形成連接孔後,形成金屬導電層,並以 薄膜絕緣層作為蝕刻阻擋層而蝕刻金屬導電層,藉以形成 金屬凸塊,故可形成與基板上之配線圖案直接性連接之金 屬凸塊,提高連接之可靠性。即,因可提高基板上之配線 圖案與金屬凸塊之密接性,故可增進連接孔之小直徑化, 即達成金屬凸塊之小直徑化。 又’用於形成金屬凸塊之第一電鍍處理與用於形成層間 絕緣層上之配線圖案之第二電鍍處理係分別進行,故可減 -18- 本紙張尺度適用中國國家標準(CNS) A4規格(21^?297公發) --;-- 518924 A7 B7 五、發明説明(16 少外層之配線圖案之膜厚,增進層間絕緣層上之配線圖案 之細線化’同時使金屬凸塊之周邊也能保持平坦,因此, 可在安定之狀態下安裝電子零件。 形成金屬凸塊之金屬導電層與形成層間絕緣層上之配線 圖案之電鍍層因係施行同種電鍍處理,故可使用同一電鍍 裝置,同時在蝕刻之際,也可使用相同蝕刻液,因此,可 謀求裝置之簡單化,同時提高密接性。 另外’在施行用於形成金屬凸塊之姓刻之際,形成薄膜 絕緣層作為蝕刻阻擋層,因此,可減少金屬導電層之蝕刻 量’提高蝕刻精確度,結果即可形成精細圖案。 【圖式之簡單說明】 圖1係應用本發明之多層型印刷電路基板之剖面圖。 圖2(A)〜(E)係圖1所示之印刷電路基板之製造工序之說 明圖。 圖3 (A)〜(F)係作為比較例之多層型印刷電路基板之製造 工序之說明圖。 圖4(A)〜(G)係以往之印刷電路基板之製造工序之說明 圖。 【元件符號之說明】 1多層型印刷電路基板、2基板、3第一配線圖案、 4連接孔、5電鍍層、6膏、7薄膜絕緣層、8連 接孔、9 金屬凸塊、11 層間絕緣層、12 第二配線圖 案' 13 金屬導電層 -19- 本紙張尺度適用中國國家標準((:]^3) a4規格(21〇x 297公釐)Electrical connection is maintained between the first-wiring patterns 23 and 23, and a conductive or insulating paste 33 is filled in this connection hole 32. Next, on the substrate 22 on which the first wiring patterns 23 and 23 are formed, as shown in FIG. 3 (B), a copper foil with resin (resin-coated copper foil RCC ·· resin coated Copper), and Sumitomo Beklett ApL-4. 〇i). That is, on the substrate 22 provided with the first wiring patterns 23, 23, interlayer insulating layers 24, 24 are formed, and copper cymbals 25, 25 are laminated on the interlayer insulating layers 24, 24. " Person as shown in FIG. 3 (c), 'the copper foils 25 and 25 are removed by etching, and then: at a specific position on the interlayer insulation layers 24 and 24, the first wiring pattern 23, 23%,% facing external connection holes. Next, the interlayer insulation layers 24, 24 forming the connection holes 26, 26 are treated with Dessma to remove the resin residue on the surface. Next, as shown in FIG. 3 (D), on the interlayer insulating layers 24 and 24, copper-plated layers 27 and 27 having a thickness of 18 mm are formed using non-electrolytic mineral copper or the like. This mineral copper layer 27, 27 is a layer for forming the second wiring pattern of the outer layer. In addition to being formed on the surface of the interlayer insulating layers 24, 24, it is also formed on the inner surface of the connection holes 26, 26, and is connected to the first wiring. The patterns 23 and 23 remain electrically connected. Thereafter, as shown in FIG. 3 (E), the connection holes%, 26 of the copper plating layers 27, 27 are provided on the inner surface, and the hole filling inks 28, 28 (FP-R12, manufactured by Asahi Chemical Research Institute) are filled, and Bake at a temperature of 12 ° C for 100 minutes, and then heat for 30 minutes at 180 ° C to harden it. Next, as shown in FIG. 3 (F), the copper plating layers 27 and 27 are electroless. Copper plating is performed to form copper plating layers 29 and 29, and then the copper plating layers 27 and 29 are exposed, developed, and etched to form second wiring patterns 30 and 30. This second wiring -17- this paper is suitable for China National Winter Standard (CNS) A4 specification (210 X 297) 518924 A7 B7 V. Description of the invention (15) The patterns 30 and 30 are formed by laminating copper layers 27 and 29, and the thickness is 36/2 m ° In the multilayer printed circuit board 1 to which the present invention is applied, the pattern width of the second wiring patterns 12 and the space width between the patterns can be formed to 50 // m / 5. In contrast, the multilayer shown in FIG. 3 Type printed circuit board 21 can form a pattern width / space between patterns of 70 // m / 70 # m, but if the thickness is reduced to 50 // m / 50 " m, the second wiring pattern 30, 30 Will break This is because the second wiring pattern 30 and 30 are composed of two copper plating layers 27 and 29, and the thickness of 36 / zm is greater than the thickness of 18 // m of the multilayer wiring circuit board 1 of the second wiring pattern. 12, 12 is thicker. In this way, compared with the printed circuit board 21 of the comparative example, the multilayer printed circuit board 1 to which the present invention is applied can form a wiring pattern having a smaller pattern width and a thinner and thinner wiring pattern. A printed circuit board provided with two conductive layers is described as an example, but the present invention is not limited to the number of the conductive layers. [Effects of the Invention] The present invention forms a thin film insulation after forming a wiring pattern on a substrate. Layer, after forming the connection hole in the thin-film insulating layer, a metal conductive layer is formed, and the metal conductive layer is etched with the thin-film insulating layer as an etch stop layer to form a metal bump, so it can form a direct connection with the wiring pattern on the substrate Metal bumps improve the reliability of the connection. That is, because the closeness between the wiring pattern on the substrate and the metal bumps can be improved, the diameter of the connection hole can be reduced, that is, the small diameter of the metal bumps can be achieved. The first plating process for forming metal bumps and the second plating process for forming wiring patterns on interlayer insulation layers are performed separately, so it can be reduced by -18- This paper size applies to Chinese National Standards (CNS) A4 specifications (21 ^? 297 issued)-;-518924 A7 B7 V. Description of the invention (16 The thickness of the wiring pattern of the outer layer is less, and the thinning of the wiring pattern on the interlayer insulation layer is improved, and the metal bumps are made at the same time The periphery can also be kept flat, so electronic components can be mounted in a stable state. Since the metal conductive layer forming the metal bumps and the plating layer forming the wiring pattern on the interlayer insulating layer are subjected to the same plating treatment, the same plating device can be used, and at the same time, the same etching solution can also be used during etching. Simplicity of the device is required while improving the adhesion. In addition, when the last engraving for forming metal bumps is carried out, a thin film insulating layer is formed as an etching stopper layer. Therefore, the amount of etching of the metal conductive layer can be reduced ', and the accuracy of etching can be improved. As a result, a fine pattern can be formed. [Brief description of the drawings] FIG. 1 is a cross-sectional view of a multilayer printed circuit board to which the present invention is applied. 2 (A) to (E) are explanatory diagrams of the manufacturing process of the printed circuit board shown in FIG. Figs. 3 (A) to (F) are explanatory diagrams of a manufacturing process of a multilayer printed circuit board as a comparative example. Figs. 4 (A) to (G) are explanatory diagrams of a manufacturing process of a conventional printed circuit board. [Explanation of component symbols] 1 multilayer printed circuit board, 2 substrates, 3 first wiring patterns, 4 connection holes, 5 plating layers, 6 pastes, 7 thin film insulation layers, 8 connection holes, 9 metal bumps, 11 interlayer insulation Layer, 12 second wiring pattern '13 metal conductive layer-19- This paper size applies to Chinese national standard ((:] ^ 3) a4 size (21〇x 297 mm)

Claims (1)

518924 8 8 8 8 A B c D 六、申請專利範圍 1. 一種多層型印刷電路基板,其特徵係在於包含: 基板,其係形成配線圖案者; 薄膜絕緣層,其係以覆蓋配線圖案之方式形成於上述 基板上者; 層間絕緣層,其係設於上述薄膜絕緣層上者; 金屬凸塊,其係被上述薄膜絕緣層與上述層間絕緣層 所包圍而由上述薄膜絕緣層突出,並設於上述配線圖案 上者;及 配線圖案,其係設於上述層間絕緣層上,並連接於上 述金屬凸塊者。 2. 如申請專利範圍第1項之多層型印刷電路基板,其中上述 薄膜絕緣層厚度為l#m〜30//m者。 3 . —種多層型印刷電路基板之製造方法,其特徵係在於包 含·· 配線圖案形成步驟,其係將配線圖案形成於基板者; 薄膜絕緣層形成步驟,其係以覆蓋上述配線圖案方 式,將薄膜絕緣層形成於設有上述配線圖案之基板上 者; 連接孔形成步驟,其係以使上述配線圖案面臨外部方 式,將連接孔形成於上述薄膜絕緣層者; 金屬導電層形成步驟,其係利用第一電鍍處理,將金 屬導電層形成於形成有上述連接孔之薄膜絕緣層上者; 金屬凸塊形成步驟,其係利用選擇性除去上述金屬導 電層方式,形成由上述薄膜絕緣層突出之金屬凸塊者; -20- 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公埜)518924 8 8 8 8 AB c D 6. Application scope 1. A multi-layer printed circuit board, which is characterized by comprising: a substrate, which forms a wiring pattern; and a thin film insulation layer, which is formed to cover the wiring pattern. On the substrate; interlayer insulation layer provided on the thin film insulation layer; metal bumps surrounded by the thin film insulation layer and the interlayer insulation layer and protruding from the thin film insulation layer and provided on the The above wiring pattern; and the wiring pattern provided on the interlayer insulating layer and connected to the metal bump. 2. The multilayer printed circuit board as described in the first item of the patent application, wherein the thickness of the above-mentioned thin film insulating layer is l # m ~ 30 // m. 3. A method for manufacturing a multilayer printed circuit board, which is characterized by including a wiring pattern forming step for forming a wiring pattern on a substrate; a thin-film insulating layer forming step for covering the wiring pattern; A thin film insulating layer is formed on a substrate provided with the above-mentioned wiring pattern; a connection hole forming step includes forming the connection hole in the thin film insulating layer so that the wiring pattern faces the outside; a metal conductive layer forming step, The first electroplating process is used to form a metal conductive layer on the thin film insulating layer on which the above-mentioned connection hole is formed; the metal bump forming step is to form a protrusion from the thin film insulating layer by selectively removing the metal conductive layer. Those with metal bumps; -20- This paper size applies to China National Standard (CNS) A4 (210 X 297 public field) 4. 層間絕緣層形成步驟,其係以包圍上述金屬凸塊方 式’將層間絕緣層形成於上述薄膜絕緣層上者;及 另配4·圖案形成步驟,其係利用與上述第一電鑛處 理同種之第二電鐘處理,將另—配線圖案形成於上述層 間絕緣層上者。 士申明專利範圍第3項之多層型印刷電路基板之製造方 法其中除去上述金屬導電層時,上述薄膜絕緣層係被 使用作為光罩者。 如申明專利範圍第3項之多層型印刷電路基板之製造方 法,其中上述連接孔係以照相蝕刻、鑽孔或雷射光中任 一種方法形成於上述薄膜絕緣層者。 如申請專利範圍第3項之多層型印刷電路基板之製造方 法’其中在將上述金屬導電層形成於上述薄膜絕緣層之 前’包含一表面改質步驟,其係用以施行上述薄膜絕緣 層之表面改質者。 如申請專利範圍第6項之多層型印刷電路基板之製造方 法’其中上述薄膜絕緣層之表面改質係利用氧化劑處 理、鹼性劑處理、有機溶劑處理、電漿處理、紫外線照 射處理中至少一種以上所進行者。 -21 - 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐) 裝 #4. The step of forming an interlayer insulating layer is one in which the interlayer insulating layer is formed on the thin film insulating layer in a manner of surrounding the above-mentioned metal bumps; and an additional 4. pattern forming step is performed by using the same process as the first electric ore treatment. The second electric clock of the same kind is processed by forming another wiring pattern on the interlayer insulating layer. In the method for manufacturing a multilayer printed circuit board according to Patent Claim 3, in which the above-mentioned thin film insulating layer is used as a photomask when the above-mentioned metal conductive layer is removed. For example, a method for manufacturing a multilayer printed circuit board according to claim 3, wherein the above-mentioned connection holes are formed in the above-mentioned thin-film insulating layer by any one of photoetching, drilling, or laser light. For example, the method for manufacturing a multilayer printed circuit board according to item 3 of the patent application 'wherein the above-mentioned metal conductive layer is formed before the above-mentioned thin-film insulating layer' includes a surface modification step for performing the surface of the above-mentioned thin-film insulating layer Reformer. For example, the method for manufacturing a multilayer printed circuit board according to item 6 of the patent application, wherein the surface modification of the thin-film insulating layer is at least one of oxidant treatment, alkaline treatment, organic solvent treatment, plasma treatment, and ultraviolet irradiation treatment. What has been done above. -21-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)
TW91104208A 2001-03-14 2002-03-07 Multi-layer printed wiring board and manufacturing method therefor TW518924B (en)

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Publication number Priority date Publication date Assignee Title
TWI428068B (en) * 2011-06-27 2014-02-21 Zhen Ding Technology Co Ltd Printed circuit board and method for manufacturing same
TWI683604B (en) * 2016-12-23 2020-01-21 德商德國艾托特克公司 Method of forming a solderable solder deposit on a contact pad and printed circuit board exposing on an activated contact pad a solderable solder deposit
US11032914B2 (en) 2016-12-23 2021-06-08 Atotech Deutschland Gmbh Method of forming a solderable solder deposit on a contact pad

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