TW434422B - Color filter and radiation-sensitive composition useful in color filter - Google Patents

Color filter and radiation-sensitive composition useful in color filter Download PDF

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Publication number
TW434422B
TW434422B TW089106646A TW89106646A TW434422B TW 434422 B TW434422 B TW 434422B TW 089106646 A TW089106646 A TW 089106646A TW 89106646 A TW89106646 A TW 89106646A TW 434422 B TW434422 B TW 434422B
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TW
Taiwan
Prior art keywords
color filter
radiation
acid
weight
compound
Prior art date
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TW089106646A
Other languages
Chinese (zh)
Inventor
Koichi Sakurai
Hideyuki Kamii
Takahiro Sakai
Takeshi Watanabe
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Jsr Corp
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Publication of TW434422B publication Critical patent/TW434422B/en

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
    • G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials For Photolithography (AREA)
  • Optical Filters (AREA)

Abstract

The object of the present invention is to provide a reaiation-sensitive composition and a color filter produced by using said composition, wherein said composition comprises a photo-polymerization initiator containing a triazine compound. The pixels obtained from said comosition can form color filter which does not have residues adhered to a photomask and which exhibit high developability and excellent adhesion to both a substrate and a light shading layer. The radiation-sensitive composition of the present application comprises, as the essential components, (A) a colorant, (B) an alkali soluble resin, (C) a multi-functional monomer, (D) a photo-polymerization initiator containing a triazine compound and (E) an organic amino compound having one on more amino group(s) in a molecule. Color filter can be formed by pixels, which is produced by using this composition.

Description

,α4422^ Α7 經濟部智慧財產局員工消費合作杜印製 Β7五、發明説明Ο ) 〔發明之詳細說明〕 〔發明所屬之技術領域〕 本發明爲關於濾色器用感放射線性組成物及濾色器， 更詳言之，爲關於照射放射線時不會產生光罩附著物，且 顯像性等優良之穿透型或反射型彩色液晶顯示裝置、彩色 照像管元件等所用之瀘色器製造中有用的濾色器用感放射 線性組成物，及由該濾色器用感放射線性組成物所形成之 濾色器。 〔先前之技術〕 以往，已知使用著色感放射線性組成物製造濾色器時 ，於基板上或預先形成所欲圖型遮光層之基板上，將著色 感放射線性組成物塗佈並乾燥後，於乾燥塗膜上對所欲之 圖型形狀照射放射線（以下，稱爲「曝光」），並且顯像 ，則可取得各色畫素之形成方法（參照特開平 2 — 1 4 4 5 0 2號公報及特開平3 - 5 3 2 0 1號公報 )° 但是，依據此類方法所得之濾色器，於顯像時，於未 曝光部之基板上或遮光層上易產生殘渣和質地污染之情況 ，先前的著色感放射線性組成物，以刷淸洗除去此類殘渣 和質地污染等時，乃將畫素表面刮傷，產生缺乏圖型，並 成爲圖型不良之大原因。 又，於使用鹵甲基噚二唑系化合物和鹵甲基- s —三 (請先閱讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準（CNS ) A4規格（2!ΟX 297公釐）-4 · A7 —________B7___ 五、發明説明泛) -----------政-- (請先閱讀背面之注意事項再填寫本頁) 明^系化合物之濾色器用感放射線性組成物中，爲了抑制由 此些化合物所副生成之鹵化氫的影響，乃提案配合（二） 縮水甘油醚等具有環氧基之有機化合物、和環氧樹脂之技 術（參照特開平1 一 2 549 1 8號（特公平 8 - 9 5 2 3 8號）公報及特開平8 — 9 48 2 4號公報 )α 此些濾色器用感放射線性組成物，可製作電性、化學 安定性優良之濾色器，或者可抑制光罩附著物，但特別於 使用鹵甲基- s -三畊系化合物般之三畊系化合物時，於 抑制光罩附著物之點上仍未充分。 〔發明所欲解決之課題〕 於是，本發明之課題爲在於提供使用含三畊系化合物 之光聚合引發劑時，於曝光時不會產生光罩附著物，且顯 像性優良，可提供對於基板及遮光層之密合性亦優之畫素 的新穎濾色器用感放射線性組成物，及由該濾色器用感放 射線性組成物所形成之濾色器。 經濟部智慧財產局員工消費合作社印製 〔用以解決課題之手段〕 若根據本發明’則本發明之前述課題，第一可經由含 有（A )著色劑、（B )鹼可溶性樹脂、（C )多官能性 單體、（D)含三畊系化合物之光聚合引發劑、及（E) 於分子中具有一個以上胺基之有機胺基化合物爲其特徵之 濾色器用感放射線性組成物（以下，稱爲「第一發明」） 本紙張尺度適用中賴家標準（ CNS ) A4規格（210X297公釐)~~Γ7Τ ' 434422 ? Α7 __ Β7 經濟部智慧財產局員工消費合作社印製 五、發明說明（3 ) 而達成。 若根據本發明，則本發明之前述課題，第二可經由具 有由含有（A)著色劑、（B)鹼可溶性樹脂、（C)多 官能性單體、（D )含三畊系化合物之光聚合引發劑、及 (E)於分子中具有1個以上胺基之有機胺基化合物之濾 色器用感放射線性組成物所形成畫素爲其特徵之濾色器（ 以下，稱爲「第二發明」）而達成。 本發明所稱之「放射線」爲意指包含可見光線、紫外 線、遠紫外線、電子射線.X射線等。 以下，詳細說明本發明。 (A )著色劑 本發明之著色劑，其色調並無特別限定，可根據所得 濾色器之用途而適當選定，且可爲顏料、染料或天然色素 之任何一種。 因於濾色器中要求高精細呈色及耐熱性，故第一發明 之著色劑較佳爲呈色性高，且耐熱性高之著色劑，特別爲 耐熱分解性高之著色劑，通常使用顏料，特性爲使用有機 顏料。 前述之有機顏料’可列舉例如於色彩指數（C . I . ;The Society of Dyers and Co 丨 ourists 公司發行）中被分類 成顏料（Pigment )之化合物’具體而言’爲如下述被附以 色彩指數（C . Ϊ .)編號之化合物。 C. I .顏料黃83、C. I，顏料黃128、 * - - ·1-- ------1--!-严-------訂---I--I—線 <請先J»讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -6 _ 4344221 A7 B7 五、發明說明（4 ) C .I .顏料黃1 3 8、 C .] :.顏料黃1 3 9、 C .I .顏料黃1 5 0、 C .] :.顏料黃1 5 1、 C .I .顏料黃1 5 2、 C .] :.顏料黃1 5 3、 C .I .顏料黃1 5 4、 C . 1 :.顏料黃1 5 5、 C .I .顏料黃1 5 6、 C . 1 :.顏料黃1 6 6、 C .I .顏料黃、 1 6 8 C .] :.顔料黃1 7 5、 C .I .顏料黃1 8 5 ; C .1 .顏料橙7 1 、C I .顏料橙7 3 ; C .I ·顏料紫 19 、C I .顏料紫 2 3、 (請先Μ讀背面之注意事項再填寫本頁> 經濟部智慧財產局員工消費合作社印製 C . .I ，顏 料紫 2 9 C I • 顔 料 紫3 2 % C . .I 顏 料紫 3 6 、 C • I 顏 料 紫3 8 1 C I .顏 料紅 1 7 7 C - I .顏 料 紅 2 0 2、 C . .I .顏 料紅 2 0 6 、 C - I • 顏 料紅 2 0 7 , C , ,I .顏 料紅 2 0 8 > C I 顏 料紅 2 0 9、 C I •顏 料紅 2 1 5 C * I * 顏 料紅 2 1 6、 C . .I .顏 料紅 2 2 0 、 C • I • 顏 料紅 2 2 4、 C . ,I •顏 料紅 2 2 6 > C * I - 顏 料紅 2 4 2、 C . I .顏 料紅 2 4 3 C * I * 顏 料紅 2 4 5、 C , .I .顏 料紅 2 5 4 、 C I - 顏 料紅 2 5 5、 C I 顏 料紅 2 6 4 - C * I • 顏 料紅 2 6 5 ； C • I 顏 料 藍 1 5 ' C I • 顏料 藍 1 5:3、 C I ，顏 料藍 1 5 ; 4 ' C • I * 顏料 藍 1 5:6、 C . I .顏 料藍 6 0 1 C.I·顏料綠了、 C,I.顏料綠36: 本紙張尺度適用申國國家標準（CNS)A4規格（210 X 297公釐） -7- A7 B7 五、發明説明（5 ) C. I ·顏料棕23、C‘ I .顏料棕25 : C·I.顔料黑1、 C·I.顏料黑7。 又，此些有機顏料例如以硫酸再結晶法、溶劑洗淨法 、和其組合等予以精製則可使用。 前述有機顏料可單獨或混合使用二種以上。 又，無機顏料可列舉例如氧化鈦、硫酸鋇、碳酸鈣、 鋅白、硫酸锆、黃鉛、紅色氧化鐵（I I I )、鎘紅、群 青、紺青、氧化鉻綠、鈷綠、琥珀、鈦黑、合成鐵黑、炭 黑等。 此些無機顏料可單獨或混合使用二種以上。 於本發明中，前述各著色劑可依所欲，以聚合物將其 粒子表面予以改質供使用。將著色劑粒子表面改質之聚合 物可列舉例如特開平8 - 2 5 9 8 7 6號公報等中所記載 之聚合物，和市售之各種顏料分散用聚合物或低聚物等。 又，本發明之著色劑爲依所欲，與分散劑共同使用。 此類分散劑可列舉例如陽離子系、陰離子系、非離子 系、兩性、聚矽氧烷系、氟系等界面活性劑等。 前述界面活性劑之具體例可列舉聚氧乙烯月桂醚、聚 氧乙烯硬脂醚、聚氧乙烯油醚等之聚氧乙烯烷醚類；聚氧 乙烯正辛基苯醚、聚氧乙烯正壬基苯醚等之聚氧乙烯烷基 苯醚類；聚乙二醇二月桂酸酯、聚乙二醇二硬脂酸酯等之 聚乙二醇二酯類；山梨糖醇酐脂肪酸酯類、脂肪酸改質聚 酯類；三級胺改質聚胺基甲酸酯類、聚乙烯亞胺類等、及 以下商品名之KP (信越化學工業（株）製）、Polyflow 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公兹）_ A_ I---"-------^II (請先閱讀背面之注$項再填寫本頁) '、ΤΓ. 經濟部智慧財產局員X消費合作社印製 線— I-^---：--- 4 3 4 4 2 2 3 a? B7 經濟部智慧財產局員工消費合作社印製 五、發明説明) (共榮公司化學（株）製_)、F T 0 P C Tokem Products 公司製）、Megafac (大日本油墨化學工業（株）製）、 Florad (住友 3 Μ (株）製）、Asahi Guard、Surflone ( 以上，旭硝子（株）製）、Disperbyk ( BeakChemiJapan (株）製）、Soluspass ( Zeneka (株）製）等。 此些界面活性劑可單獨或混合使用二種以上。 界面活性劑之使用量，相對於著色劑1 0 0重量份， 通常爲以5 0重量份以下，較佳爲3 0重量份以下。 尙，本發明之感放射線性組成物中，前述顏料於除去 溶劑之全成分中所佔之比例可爲適當之比例，但期望爲 2 0〜5 0 %。組成物中之顏料比例可於此範圍內，依據 用途而採用適當之値，例如，於作爲筆記型電腦和電腦之 液晶監測器用，可爲2 0〜4 0 %，而於液晶電視用途中 則可爲35〜50%。 (B)鹼可溶性樹脂 本發明之鹼可溶性樹脂爲對於（A )著色劑，作用爲 粘合劑，且於製造濾色器時，若對於其顯像處理工程所用 之顯像液，特佳爲鹼性顯像液具有可溶性者，則無特別限 定，但以具有羧基之鹼可溶性樹脂爲佳，特別以具有1個 以上羧基之乙烯性不飽和單體（以下，單稱爲「含羧基之 不飽和單體」）與其他可共聚之乙烯性不飽和單體（以下 ，單稱爲「共聚性不飽和單體」）之共聚物（以下，單稱 爲「含羧基之共聚物」）爲佳。 I--.-------^ i (請先閱讀背面之注項再镇寫本頁) 、1Τ- 線-! 本紙張尺度適用中國國家標準（CNS ) Α4規格（2ΙΟΧ：297公釐） -9- 4344223 A7 經濟部智慧財產局員工消費合作社印製 B7___五、發明説明（7 ) 含羧基之不飽和單體可列舉例如 丙烯酸、甲基丙烯酸、巴豆酸、α -氯基丙烯酸、肉 桂酸等之不飽和單羧酸類； 順丁烯二酸、順丁烯二酸酐、反丁烯二酸、衣康酸、 衣康酸酐、檸康酸、檸康酸酐、中康酸等之不飽和二羧酸 或其酐類； 三價以上之不飽和多價羧酸或其酐類； 琥珀酸單（2 -丙烯醯氧乙基）酯、琥珀酸單（2 -甲基丙烯醯氧乙基）酯、苯二甲酸單（2 —丙烯醯氧乙基 )酯、苯二甲酸單（2 —甲基丙烯醯氧乙基）酯等之二價 以上之多價羧酸的單〔（甲基）丙烯醯氧烷基〕酯類； ω—羧基聚己內酯單丙烯酸酯、ω_羧基聚己內酯單 甲基丙烯酸酯等之於兩終端具有羧基和羥基之聚合物的單 (甲基）丙烯酸酯類等。 於此些含羧基之不飽和單體中，琥珀酸單（2 —丙烯 醯氧乙基）酯及苯二甲酸單（2_丙烯醯氧乙基）酯’分 別爲以Μ— 5300及Μ— 5400 (東亞合成（株）製 )之商品名市售。 前述之含羧基之不飽和單體可單獨或混合使用二種以 上。 又，共聚性不飽和單體可列舉例如 苯乙烯、α_甲基苯乙烯、鄰一乙烯基甲苯、間一乙 烯基甲苯、對一乙烯基甲苯、對一氯基苯乙烯、鄰一甲氧 基苯乙烯、間-甲氧基苯乙烯、對-甲氧基苯乙烯、鄰- I---.--[---疫------ITI-.-----0— II (請先聞讀背面之注意事項再填寫本頁) 本紙張又度適用中國國家標隼（CNS > Α4規格（210Χ297公釐} - 10- 經濟部智慧財產局員工消費合作社印製 434422:'-， A7 B7 _五、發明説明（8 ) 乙烯基苄基甲醚.間一乙烯基苄基甲醚、對一乙烯基苄基 甲醚、鄰一乙烯基苄基縮水甘油醚、間-乙烯基苄基縮水 甘油醚、對一乙烯基苄基縮水甘油醚等之芳香族乙烯基化 合物； 茚、1 一甲基茚等之茚類； 丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙 烯酸乙酯、丙烯酸正丙酯、甲基丙烯酸正丙酯、丙烯酸異 丙酯、甲基丙烯酸異丙酯、丙烯酸正丁酯、甲基丙烯酸正 丁酯、丙烯酸異丁酯、甲基丙烯酸異丁酯.丙烯酸第二丁 酯、甲基丙烯酸第二丁酯、丙烯酸第三丁酯、甲基丙烯酸 第三丁酯、丙烯酸2 —羥乙酯、甲基丙烯酸2 -羥乙酯、 丙烯酸2-羥丙酯、甲基丙烯酸2_羥丙酯、丙烯酸3_ 羥丙酯、甲基丙烯酸3-羥丙酯、丙烯酸2 -羥丁酯、甲 基丙烯酸2 -羥丁酯、丙烯酸3 -羥丁酯、甲基丙烯酸3 -羥丁酯、丙烯酸4 -羥丁酯、甲基丙烯酸4 一羥丁酯、 丙烯酸烯丙酯、甲基丙烯酸烯丙酯、丙烯酸苄酯、甲基丙 烯酸苄酯、丙烯酸環己酯、甲基丙烯酸環己酯、丙烯酸苯 酯、甲基丙烯酸苯酯、丙烯酸2 -甲氧基乙酯、甲基丙烯 酸2-甲氧基乙酯、丙烯酸2-苯氧基乙酯、甲基丙烯酸 2-苹氧基乙酯、丙烯酸甲氧基二甘醇酯、甲基丙烯酸甲 氧基二甘醇酯、丙烯酸甲氧基三甘醇酯、甲基丙烯酸甲氧 基三甘醇酯、丙烯酸甲氧基丙二醇酯、甲基丙烯酸甲氧基 丙二醇酯、丙烯酸甲氧基二丙二醇酯、甲基丙烯酸甲氧基 二丙二醇酯'丙烯酸異冰片酯' 甲基丙烯酸異冰片酯、丙 本紙張纽it财關家辟（CNS ) A4規格（21GX297公釐)~_ 1] _ ----J------裝-- (讀先聞讀背面之注意事項再填寫本頁) 訂, α4422 ^ Α7 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs for consumer cooperation Du B5. Description of the invention 0) [Detailed description of the invention] [Technical field to which the invention belongs] The present invention relates to a radiation-sensitive composition for color filters and color filtering More specifically, it is a color filter manufactured for a transmissive or reflective color liquid crystal display device, a color photo tube element, and the like that does not generate a mask attachment when irradiated with radiation and has excellent image development properties. A useful radiation-sensitive composition for a color filter, and a color filter formed from the radiation-sensitive composition for a color filter. [Previous Technology] Conventionally, when a color filter is manufactured using a colored radiation-sensitive composition, the colored radiation-sensitive composition is coated and dried on a substrate or a substrate on which a desired light-shielding layer is formed in advance. By irradiating a desired pattern shape with radiation (hereinafter, referred to as "exposure") on a dry coating film, and developing the image, a method for forming each color pixel can be obtained (see JP-A Hei 2 — 1 4 4 5 0 2 And Japanese Unexamined Patent Publication No. 3-5 3 2 0 1) ° However, when a color filter obtained by such a method is developed, residues and texture pollution are liable to occur on a substrate or a light-shielding layer of an unexposed portion during development. In some cases, when the previous color-sensitive radioactive composition was brushed to remove such residues and texture contamination, the surface of the pixel was scratched, resulting in a lack of pattern and a major cause of poor pattern. In addition, in the use of halomethyl oxadiazole-based compounds and halomethyl-s-tri (please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 specifications (2! ΟX 297 mm)-4 · A7 —________ B7___ V. Description of Invention Pan) ----------- Politics-(Please read the precautions on the back before filling out this page) The color of the ^ series compound In order to suppress the influence of hydrogen halide by-produced by these compounds in the radiation-sensitive composition for device, it is proposed to incorporate (ii) glycidyl ether and other organic compounds having epoxy groups, and epoxy resin technology (see special features) Kaihei 1-2 549 1 No. 8 (Junkai No. 8-9 5 2 3 8) and Hei. No. 8-9 48 2 4) α These color filters are radiation-sensitive compositions that can be used to produce electrical properties, A color filter with excellent chemical stability or suppression of mask attachments, but especially when using a three-till compound like a halomethyl-s-three-tillage compound, it has not yet been effective in suppressing mask attachments. full. [Problems to be Solved by the Invention] Accordingly, an object of the present invention is to provide a photopolymerization initiator containing a three-tillage compound, which does not generate a mask attachment at the time of exposure and has excellent image development properties. A novel radiation-sensitive composition for a color filter having excellent adhesion between the substrate and the light-shielding layer, and a color filter formed from the radiation-sensitive composition for a color filter. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [means for solving problems] According to the present invention, the aforementioned problems of the present invention can be achieved by first containing (A) a colorant, (B) an alkali-soluble resin, and (C ) A polyfunctional monomer, (D) a photopolymerization initiator containing a tri-tillage compound, and (E) a radiation-sensitive composition for color filters characterized by an organic amine compound having one or more amine groups in the molecule (Hereinafter referred to as "the first invention.") This paper size applies the China Lai Jia Standard (CNS) A4 specification (210X297 mm) ~~ 7T '43442? Α7 __ Β7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Invention Description (3). According to the present invention, the above-mentioned problem of the present invention is, secondly, possible by having a composition containing (A) a colorant, (B) an alkali-soluble resin, (C) a polyfunctional monomer, and (D) a tri-tillage compound. A photopolymerization initiator and (E) a color filter (hereinafter referred to as "the first") characterized by pixels formed by a radiation-sensitive composition for a color filter of an organic amine compound having one or more amine groups in the molecule Two inventions "). The term "radiation" as used in the present invention means to include visible rays, ultraviolet rays, extreme ultraviolet rays, electron rays, X-rays, and the like. Hereinafter, the present invention will be described in detail. (A) Coloring agent The coloring agent of the present invention is not particularly limited in color tone, can be appropriately selected according to the use of the obtained color filter, and can be any of a pigment, a dye, and a natural pigment. Since high color rendering and heat resistance are required in the color filter, the coloring agent of the first invention is preferably a coloring agent with high coloring property and high heat resistance, especially a coloring agent with high thermal decomposition resistance, and is generally used. Pigment, using organic pigments. Examples of the aforementioned organic pigments include, for example, a compound that is classified as a pigment in the color index (issued by the Society of Dyers and Co. Ourists). Specifically, the compound is colored as described below. Index (C.Ϊ.) numbered compounds. C. I. Pigment Yellow 83, C. I, Pigment Yellow 128, *--· 1-- ------ 1-!-Yan ------- Order --- I--I —Line & Please read the notes on the back of the page before filling in this page) The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -6 _ 4344221 A7 B7 V. Description of the invention (4) C.I.Pigment Yellow 1 3 8, C.] :. Pigment Yellow 1 39, C.I.Pigment Yellow 1 50, C.] :. Pigment Yellow 1 5 1, C.I.Pigment Yellow 1 5 2.C.] :. Pigment Yellow 1 5 3.C.I.Pigment Yellow 1 4 5.C. 1: .Pigment Yellow 1 5 5. C.I.Pigment Yellow 1 5 6.C. 1: .Pigment Yellow 1 6 6, C.I.Pigment Yellow, 16 8 C.] :. Pigment Yellow 1 7 5, C.I.Pigment Yellow 1 8 5; C.1.Pigment Orange 7 1, CI.Pigment Orange 7 3; C.I. Pigment Violet 19, CI. Pigment Violet 2 3. (Please read the precautions on the back before filling out this page> Printed by C..I, Pigment Violet 2 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 9 CI • Pigment Violet 3 2% C.. I Pigment Violet 3 6, C • I Pigment Violet 3 8 1 CI. Pigment Red 1 7 7 C-I. Pigment Red 2 0 2, C.. I. Pigment Red 2 0 6 、 C-I • Yan Pigment Red 2 0 7, C,, I. Pigment Red 2 0 8 > CI Pigment Red 2 0 9, CI • Pigment Red 2 1 5 C * I * Pigment Red 2 1 6, C.. I. Pigment Red 2 2 0, C • I • Pigment Red 2 2 4, C., I • Pigment Red 2 2 6 > C * I-Pigment Red 2 4 2, C. I. Pigment Red 2 4 3 C * I * Pigment Red 2 4 5, C, .I. Pigment Red 2 5 4, CI-Pigment Red 2 5 5, CI Pigment Red 2 6 4-C * I • Pigment Red 2 6 5; C • I Pigment Blue 1 5 'CI • Pigment Blue 1 5: 3, CI, Pigment Blue 1 5; 4 'C • I * Pigment Blue 1 5: 6, C. I. Pigment Blue 6 0 1 CI · Pigment Green, C, I. Pigment Green 36: This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -7- A7 B7 V. Description of the invention (5) C. I · Pigment Brown 23, C 'I. Pigment Brown 25: C · I. Pigment Black 1, C · I. Pigment Black 7. These organic pigments can be used, for example, by refining them with a sulfuric acid recrystallization method, a solvent washing method, or a combination thereof. The aforementioned organic pigments may be used alone or in combination of two or more. Examples of the inorganic pigment include titanium oxide, barium sulfate, calcium carbonate, zinc white, zirconium sulfate, yellow lead, red iron oxide (III), cadmium red, ultramarine blue, ultramarine blue, chrome oxide green, cobalt green, amber, and titanium black. , Synthetic iron black, carbon black, etc. These inorganic pigments can be used alone or in combination of two or more. In the present invention, each of the aforementioned colorants may be modified by a polymer to have a particle surface for use as desired. Examples of the polymer that has been modified on the surface of the colorant particles include polymers described in JP-A No. 8-2 5 9 8 7 and the like, and various commercially available polymers for dispersing pigments or oligomers. Moreover, the coloring agent of this invention is used together with a dispersing agent as desired. Examples of such dispersants include surfactants such as cationic, anionic, nonionic, amphoteric, polysiloxane, and fluorine-based surfactants. Specific examples of the aforementioned surfactant include polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether and the like; polyoxyethylene n-octylphenyl ether, and polyoxyethylene n-nonyl Polyoxyethylene alkyl phenyl ethers such as phenylene ether; polyethylene glycol diesters such as polyethylene glycol dilaurate, polyethylene glycol distearate; sorbitan fatty acid esters, Fatty acid modified polyesters; tertiary amine modified polyurethanes, polyethyleneimines, etc., and KP (manufactured by Shin-Etsu Chemical Industry Co., Ltd.) and Polyflow under the following trade names (CNS) A4 specification (210X297 kilometers) _ A_ I --- " ------- ^ II (Please read the note on the back before filling this page) ', ΤΓ. Member of Intellectual Property Bureau, Ministry of Economic Affairs X Consumer Cooperative Cooperative Printing Line — I-^ ---: --- 4 3 4 4 2 2 3 a? B7 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of Invention) (Gongrong Chemical Co., Ltd.) _), FT 0 PC Tokem Products), Megafac (manufactured by Dainippon Ink Chemical Industry Co., Ltd.), Florad (manufactured by Sumitomo 3M Co., Ltd.) , Asahi Guard, Surflone (above, manufactured by Asahi Glass Co., Ltd.), Disperbyk (made by BeakChemiJapan Co., Ltd.), Soluspass (made by Zeneka Co., Ltd.), etc. These surfactants can be used alone or in combination of two or more. The amount of the surfactant used is usually 50 parts by weight or less, and preferably 30 parts by weight or less, based on 100 parts by weight of the colorant. Alas, in the radiation-sensitive composition of the present invention, the proportion of the aforementioned pigment in the total component excluding the solvent may be an appropriate ratio, but it is desirable to be 20 to 50%. The pigment ratio in the composition can be within this range, and the appropriate ratio can be used depending on the application. For example, it can be 20% to 40% for liquid crystal monitors of notebook computers and computers. Can be 35 ~ 50%. (B) Alkali-soluble resin The alkali-soluble resin of the present invention is a (A) colorant that acts as a binder, and when manufacturing a color filter, it is particularly preferred for the developing solution used in its development treatment process. The alkali developing solution is not particularly limited if it is soluble, but an alkali-soluble resin having a carboxyl group is preferred, and an ethylenically unsaturated monomer having one or more carboxyl groups (hereinafter, simply referred to as a "carboxyl-containing Saturated monomer ") and a copolymerizable ethylenically unsaturated monomer (hereinafter, simply referred to as" copolymerizable unsaturated monomer ") (hereinafter, simply referred to as" carboxyl-containing copolymer ") is preferred . I --.------- ^ i (Please read the note on the back before writing this page), 1T- LINE-! This paper size is applicable to China National Standard (CNS) Α4 size (2ΙΟχ: 297) (%) -9- 4344223 A7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7___ V. Description of Invention (7) Examples of unsaturated monomers containing carboxyl groups include acrylic acid, methacrylic acid, crotonic acid, and α-chloroacrylic acid Unsaturated carboxylic acids such as cinnamic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, citraconic acid, citraconic anhydride, mesaconic acid, etc. Unsaturated dicarboxylic acids or their anhydrides; Unsaturated polyvalent carboxylic acids or their anhydrides; tris (2-propenyloxyethyl) succinate, mono (2-methacryl) oxy Ethyl) esters, mono (2-propenyloxyethyl) phthalate, mono (2-methacryloxyethyl) phthalate, and other monovalent polyvalent carboxylic acids [(( (Meth) acryloyloxyalkyl] esters; ω-carboxy polycaprolactone monoacrylate, ω_carboxy polycaprolactone monomethacrylate, etc. Mono (meth) acrylates having a carboxyl group and a hydroxyl group of the polymer. Among these carboxyl group-containing unsaturated monomers, mono (2-propenyloxyethyl) succinate and mono (2-propenyloxyethyl) phthalate are M-5300 and M- 5400 (manufactured by Toa Gosei Co., Ltd.) is commercially available. The aforementioned carboxyl group-containing unsaturated monomers may be used alone or in combination of two or more. Examples of the copolymerizable unsaturated monomer include styrene, α-methylstyrene, o-vinyl toluene, m-vinyl toluene, p-vinyl toluene, p-chlorostyrene, and o-methoxy Styrene, m-methoxystyrene, p-methoxystyrene, o-I ---.-- [--- epidemic ------ ITI -.----- 0— II (Please read the notes on the reverse side before filling out this page) This paper is again applicable to the Chinese national standard (CNS > Α4 size (210 × 297 mm)-10- Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economy 434422: '-, A7 B7 _V. Description of the invention (8) Vinyl benzyl methyl ether. M-vinyl benzyl methyl ether, p-vinyl benzyl methyl ether, o-vinyl benzyl glycidyl ether, m- Aromatic vinyl compounds such as vinyl benzyl glycidyl ether, p-vinyl benzyl glycidyl ether; indene such as indene, 1-methylindene; methyl acrylate, methyl methacrylate, ethyl acrylate , Ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, n-butyl acrylate , N-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate. Second butyl acrylate, second butyl methacrylate, third butyl acrylate, third butyl methacrylate, acrylic acid 2 —Hydroxyethyl, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, 2-hydroxybutyl acrylate Ester, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, allyl acrylate, methyl Allyl acrylate, benzyl acrylate, benzyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, phenyl acrylate, phenyl methacrylate, 2-methoxyethyl acrylate, methacrylic acid 2 -Methoxyethyl ester, 2-phenoxyethyl acrylate, 2-pentoxyethyl methacrylate, methoxydiethylene glycol acrylate, methoxydiethylene glycol methacrylate, methoxyacrylate Triethylene glycol ester, methoxytriethylene glycol methacrylate, methoxypropylene diacrylate Ester, methacrylic acid methacrylate, methacrylic acid methacrylate, methacrylic acid methacrylate 'isobornyl acrylate', isobornyl methacrylate, acrylic paper (CNS) A4 specification (21GX297mm) ~ _ 1] _ ---- J ------ install-(read the notes on the back and then fill in this page) Order

I I I I I—I n J— n —1» --u n Γ— -- I I 經濟部智慧財產局員工消費合作社印製 434422 i A7 _____B7_ 五、發明説明（9 ) 烯酸二環戊二烯酯、甲基丙烯酸二環戊二烯酯、丙烯酸2 —羥基一 3 -苯氧基丙酯、甲基丙烯酸2 —羥基—3 -苯 氧基丙酯、單丙烯酸甘油酯、單甲基丙烯酸甘油酯等之不 飽和羧酸酯類； 丙烯酸2 -胺乙酯、甲基丙烯酸2 —胺乙酯、丙烯酸 2-二甲胺乙酯、甲基丙焼酸2-二甲胺乙酯、丙稀酸2 一胺丙酯、甲基丙烯酸2 —胺丙酯、丙烯酸2 _二甲胺丙 酯、甲基丙烯酸2-二甲胺丙酯、丙烯酸3_胺丙酯、甲 基丙烯酸3 -胺丙酯、丙烯酸3 -二甲胺丙酯、甲基丙烯 酸3 -二甲胺丙酯等之不飽和羧酸胺烷酯類； 丙烯酸縮水甘油酯、甲基丙烯酸縮水甘油酯等之不飽 和羧酸縮水甘油酯類； 醋酸乙烯酯、丙酸乙烯酯、丁酸乙烯酯、苯甲'酸乙烯 酯等之羧酸乙烯酯類； 乙烯基甲醚、乙烯基乙醚、烯丙基縮水甘油醚等之不 飽和醚類： 丙烯腈、甲基丙烯腈、氯基丙烯腈、氰化伸乙烯 等之氰化乙烯基化合物： 丙烯醯胺、甲基丙烯醯胺、α-氯基丙烯醯胺、Ν- 2-羥乙基丙烯醯胺、Ν—2-羥乙基甲基丙烯醯胺等之 不飽和醯胺類； 馬來醯亞胺、Ν_苯基馬來醯亞胺、Ν—環己基馬來 醯亞胺等之不飽和醯亞胺類； 1，3 -丁二烯、異戊二烯、氯戊二烯等之脂族共軛 本紙張尺度適用中國國家標準{ CNS ) Α4規格（2!0Χ 297公釐）~-12 - ' I--Κ---1Κ---^------訂--------線-I (請先閱讀背面之注意事項再填寫本頁) 434422'2 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（10 ) 二烯類； 聚苯乙烯、聚丙烯酸甲酯、聚甲基丙烯酸甲酯、聚丙 烯酸正丁酯、聚甲基丙烯酸正丁酯、聚矽氧烷等之於聚合 物分子鏈終端具有單丙烯醯基或單甲基丙烯醯基之微單體 類等。 此些共聚性不飽和單體可單獨或混合使用二種以上。 本發明之含羧基之共聚物較佳爲①以丙烯酸和/或甲 基丙烯酸作爲必須成分，且視情況，再含有琥珀酸單（2 -丙烯醯氧乙基）酯、琥珀酸單（2 —甲基丙烯醯氧乙基 )酯、ω-羧基聚己丙酯單丙烯酸酯及^-羧基聚己內酯 單甲基丙烯酸酯群中選出至少一種之含羧基不飽和單體成 分，和②苯乙Μ、丙烯酸2 —經乙酯、甲基丙烯酸2 —經 乙酯、丙烯酸烯丙酯、甲基丙烯酸烯丙酯、丙烯酸卡酯、 甲基丙烯酸苄酯、單丙烯酸甘油酯、單甲基丙烯酸甘油酯 、Ν -苯基馬來醯亞胺、聚苯乙烯微單體及聚甲基丙烯酸 甲酯微單體群中選出至少一種之共聚物（以下，稱爲「含 羧基之共聚物（I)」）爲佳。 含羧基共聚物（I )之具體例可列舉 (甲基）丙烯酸/(甲基）丙烯酸苄酯共聚物， (甲基）丙烯酸/(甲基）丙烯酸2—羥乙酯/(甲 基）丙烯酸苄酯共聚物’ (甲基）丙烯酸/(甲基）丙烯酸苄酯/聚苯乙烯微 單體共聚物， (甲基）丙烯酸/(甲基）丙烯酸苄酯/聚甲基丙烯 本紙張尺度適用中國國家標準（CNS ) Α4规格（210Χ297公羞)~~「13: I--Κ---1Κ---裝------訂--„------線丨 I (請先閲讀背面之注意Ϋ項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 434422 i ΑΊ _B7 ___五、發明説明（υ ) 酸甲酯微單體共聚物， (甲基）丙烯酸/(甲基）丙烯酸2 一經乙酯甲 基）丙烯酸苄酯/聚苯乙烯微單體共聚物’ (甲基）丙烯酸/苯乙烯/(甲基）丙烯酸卡酯/N 一苯基馬來醯亞胺共聚物， (甲基）丙烯酸/琥珀酸單〔2 -（甲基）丙嫌醯氧 乙基〕酯/苯乙烯/(甲基）丙烯酸苄酯基馬來 醯亞胺共聚物， (甲基）丙烯酸/琥珀酸單〔2 -（甲基）丙嫌醯氧 乙基/苯乙烯/(甲基）丙烯酸烯丙酯/N_苯基馬來酿 亞胺共聚物， (甲基）丙烯酸/苯乙烯/(甲基）丙烯酸苄酯/單 (甲基）丙烯酸甘油酯/N-苯基馬來醯亞胺共聚物’ (甲基）丙烯酸/ω —羧基聚己內酯單（甲基）丙烯 酸酯/苯乙烯/(甲基）丙烯酸苄酯/單（甲基）丙烯酸 甘油酯/Ν—苯基馬來醯亞胺共聚物等。 含羧基共聚物中之含羧基不飽和單體的共聚比例通常 爲5〜50重量％，較佳爲1 〇〜40重量％。此時’含 羧基不飽和單體之共聚比例爲未滿5重量％ ’則所得之感 放射線性組成物對於鹼性顯像液之溶解性有降低之傾向’ 另一方面，若超過5 0重量％，則對於鹼性顯像液之溶解 性變成過大，以鹼性顯像液予以顯像時’恐令畫素由基板 上脫落和令畫素表面的膜粗糙。 鹼可溶性樹脂以凝膠滲透層析（G P C、溶出溶劑： I---1.1-„----症------.訂——.-----千 — (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS) Α4規格（210Χ297公釐）-14- 4 3 4422 a? B7 經濟部智慧財產局員工消費合作社印製 五、發明説明〇2 ) 四氫呋喃）所測定之換算成聚苯乙烯之重量平均分子量（ 以下，稱爲「Mw」），較佳爲3，000〜 300，000，更佳爲 5，000 〜1〇〇，000。 經由使用具有此類特定Mw或Μ η之鹼可溶性樹脂， 則可取得顯像性優之感放射性組成物，藉此可形成具有淸 晰圖型邊緣之畫素，並且於顯像時，難於未曝光之基板上 及遮光層上發生殘渣、質地污染、殘膜等。 又，鹼可溶性樹脂之Mw與Μη之比（Mw/Mn ) 通常爲1〜5，較佳爲1〜4。 於本發明中，鹼可溶性樹脂可單獨或混合使用二種以 上。 本發明鹼可溶性樹脂之使用量相對於（A )著色劑 100重量份，通常以10〜1，000重量份，’較佳爲 2 0〜5 0 0重量份。此時，鹼可溶性樹脂之使用量爲未 滿1 0重量份，例如，則令鹼顯像性降低，且恐於未曝光 部之基板上或遮光層上發生質地污染和殘膜，另一方面* 若超過1，0 0 0重量份，則相對地令著色劑濃度降低， 故難以達成作爲薄膜的目的色濃度。 (C )多官能件單體 本發明之多官能性單體爲具有二個以上聚合性不飽和 鍵的單體。 多官能性單體可列舉例如 乙二醇、丙二醇等之伸烷基二元醇的二丙烯酸酯或二 ---^---.----¾-I (請先閱讀背面之注意事項再填寫本頁)IIIII—I n J— n —1 »--un Γ—-II Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economy 434422 i A7 _____B7_ V. Description of the invention (9) Dicyclopentadienyl acrylate, methyl Dicyclopentadienyl acrylate, 2-hydroxy-3 -phenoxypropyl acrylate, 2-hydroxy-3-phenoxypropyl methacrylate, glyceryl monoacrylate, glyceryl monomethacrylate, etc. Saturated carboxylic acid esters; 2-amine ethyl acrylate, 2-amine ethyl methacrylate, 2-dimethylamine ethyl acrylate, 2-dimethylamine ethyl methacrylate, 2-monoamine acrylate Propyl ester, 2-aminopropyl methacrylate, 2-dimethylaminopropyl acrylate, 2-dimethylaminopropyl methacrylate, 3-aminopropyl acrylate, 3-aminopropyl methacrylate, acrylic acid 3 -Unsaturated carboxylic acid amine alkyl esters such as dimethylamine propyl, 3-dimethylaminopropyl methacrylate, etc .; Unsaturated carboxylic acid glycidyl esters such as glycidyl acrylate, glycidyl methacrylate, etc .; Vinyl carboxylates such as vinyl acetate, vinyl propionate, vinyl butyrate, vinyl benzoate, etc .; ethylene Unsaturated ethers such as methyl ether, vinyl ether, allyl glycidyl ether, etc .: Acrylonitrile, methacrylonitrile, chloroacrylonitrile, vinyl cyanide and other vinyl compounds: acrylamide, methyl Unsaturated fluorene amines such as methacrylamide, α-chloroacrylamide, N-2-hydroxyethylacrylamide, N-2-hydroxyethylmethacrylamine; maleimide, Unsaturated fluorinimines such as N-phenyl maleimide, N-cyclohexyl maleimide, etc .; aliphatic copolymers of 1,3-butadiene, isoprene, chloroprene, etc. The paper size of the yoke is applicable to the Chinese National Standard {CNS) A4 specification (2! 0 × 297 mm) ~ -12-'I--Κ --- 1Κ --- ^ ------ Order ----- --- Line-I (Please read the precautions on the back before filling out this page) 434422'2 Printed by A7 B7, Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (10) Diene; polystyrene, poly Methyl acrylate, polymethyl methacrylate, poly-n-butyl acrylate, poly-n-butyl methacrylate, polysiloxane, etc. Micro single And so on. These copolymerizable unsaturated monomers can be used alone or in combination of two or more. The carboxyl group-containing copolymer of the present invention preferably includes ① acrylic acid and / or methacrylic acid as essential components, and optionally contains succinic acid mono (2-propenyloxyethyl) ester and succinic acid mono (2-- At least one carboxyl group-containing unsaturated monomer component selected from the group consisting of methacrylic acid ethyl ester, ω-carboxy polyhexyl monoacrylate, and ^ -carboxy polycaprolactone monomethacrylate group, and ② benzene BM, acrylic acid 2-ethyl ester, methacrylic acid 2-ethyl ester, allyl acrylate, allyl methacrylate, carbamate acrylate, benzyl methacrylate, glyceryl monoacrylate, monomethacrylic acid A copolymer of at least one selected from the group consisting of glyceride, N-phenylmaleimide, polystyrene micromonomers, and polymethylmethacrylate micromonomers (hereinafter, referred to as "carboxyl-containing copolymers (I ) ") Is better. Specific examples of the carboxyl group-containing copolymer (I) include (meth) acrylic acid / benzyl (meth) acrylate copolymer, (meth) acrylic acid / (meth) acrylic acid 2-hydroxyethyl ester / (meth) acrylic acid Benzyl ester copolymer '(meth) acrylic acid / benzyl (meth) acrylate / polystyrene micromonomer copolymer, (meth) acrylic acid / benzyl (meth) acrylate / polymethacrylic acid This paper is suitable for paper size China National Standard (CNS) Α4 specification (210 × 297 male shame) ~~ "13: I--Κ --- 1Κ --- installation ------ order-„ ------ line 丨 I ( Please read the note on the back before filling in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 434422 i ΑB _B7 ___ V. Description of the invention (υ) Methyl ester micromonomer copolymer, (meth) acrylic acid / (Meth) acrylic acid 2 methyl ethyl benzyl acrylate / polystyrene micromonomer copolymer '(meth) acrylic acid / styrene / (meth) acrylic acid carboxylate / N-phenylmaleic acid Imine copolymer, (meth) acrylic acid / succinic acid mono- [2- (meth) propanyloxyethyl] ester / styrene / benzyl maleate (meth) acrylate copolymer, (Meth) acrylic acid / succinic acid mono- [2- (meth) propanyloxyethyl / styrene / allyl (meth) acrylate / N-phenylmaleimide copolymer, (methyl ) Acrylic acid / styrene / benzyl (meth) acrylate / glyceryl (meth) acrylate / N-phenylmaleimide imide copolymer '(meth) acrylic acid / ω-carboxy polycaprolactone mono ( Meth) acrylate / styrene / benzyl (meth) acrylate / glyceryl mono (meth) acrylate / N-phenylmaleimide copolymer. The copolymerization ratio of the carboxyl group-containing unsaturated monomer in the carboxyl group-containing copolymer is usually 5 to 50% by weight, preferably 10 to 40% by weight. At this time, 'the copolymerization ratio of the carboxyl group-containing unsaturated monomer is less than 5% by weight', the solubility of the resulting radiation-sensitive composition to the alkaline developer tends to decrease 'On the other hand, if it exceeds 50% by weight %, The solubility of the alkaline developing solution becomes too large, and when developing with the alkaline developing solution, there is a fear that the pixels will fall off from the substrate and the film on the surface of the pixels will be rough. Alkali-soluble resins are analyzed by gel permeation chromatography (GPC, dissolution solvent: I --- 1.1-„---- Syndrome ------. Order ——.----- Thousands— (Please read the back first Note: Please fill in this page again.) This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297 mm) -14- 4 3 4422 a? B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. ) Tetrahydrofuran) The weight-average molecular weight (hereinafter referred to as "Mw") converted to polystyrene measured is preferably 3,000 to 300,000, more preferably 5,000 to 100,000. By using an alkali-soluble resin having such a specific Mw or M η, a radioactive composition having excellent imaging properties can be obtained, thereby forming pixels with a sharp pattern edge, and it is difficult to prevent the development of imaging Residues, texture contamination, residual film, etc. occur on the exposed substrate and on the light-shielding layer. The ratio of Mw to Mη (Mw / Mn) of the alkali-soluble resin is usually 1 to 5, preferably 1 to 4. In the present invention, the alkali-soluble resin may be used alone or in combination of two or more. The amount of the alkali-soluble resin used in the present invention is usually 100 to 1,000 parts by weight with respect to 100 parts by weight of the (A) colorant, and is preferably 20 to 500 parts by weight. At this time, the use amount of the alkali-soluble resin is less than 10 parts by weight. For example, the alkali developability is reduced, and there is a fear that texture pollution and residual film may occur on the substrate or the light-shielding layer of the unexposed portion. * If it exceeds 1,000 parts by weight, the concentration of the colorant is relatively reduced, and it is difficult to achieve the intended color concentration as a film. (C) Polyfunctional monomer The polyfunctional monomer of the present invention is a monomer having two or more polymerizable unsaturated bonds. Examples of polyfunctional monomers include diacrylates or di-alkylene glycols of diethylene glycols such as ethylene glycol and propylene glycol. Please read the notes on the back first. 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,1T 線- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨ΟΧ297公釐）-15- 經濟部智慧財產局員工消費合作社印t 434422 A7 _______B7__五、發明説明〇3 ) 甲基丙烯酸酯類； 聚乙二醇、聚丙二醇等之聚伸烷基二元醇的二丙烯酸 酯或二甲基丙烯酸酯類： 甘油、三羥甲基丙烷、季戊四醇、二季戊四醇等之三 價以上多元醇的聚丙烯酸酯或聚甲基丙烯酸酯和其二羧酸 改質物； 聚酯、環氧樹脂、聚胺基甲酸酯樹脂、醇酸樹脂、聚 矽氧烷樹脂、螺烷樹脂等之低丙烯酸酯或低甲基丙烯酸酯 類； 兩終端羥基聚- 1，3- 丁二烯，兩終端羥基聚異戊 二烯、丙終端羥基聚己丙酯等之兩終端羥基化聚合物的二 丙烯酸酯或二甲基丙烯酸酯類，和 磷酸三（2 -丙烯醯氧乙基）酯、磷酸三（2 —甲基 丙烯醯氧乙基）酯等。 此些多官能性單體中，較隹爲三價以上多元醇的聚丙 烯酸酯或聚甲基丙烯酸酯類和其二羧酸改質物，且具體而 言，爲三丙烯酸三羥甲基丙烷酯、三甲基丙烯酸三羥甲基 丙烷酯、三丙烯酸季戊四醇酯、三甲基丙烯酸季戊四醇酯 、四丙烯酸季戊四醇酯、四甲基丙烯酸季戊四醇醇、五丙 烯酸二季戊四醇酯、五甲基丙烯酸二季戊四醇酯、六丙烯 酸二季戊四醇酯、六甲基丙烯酸二季戊四醇酯、下述式（ -----1^--：-----裝------訂--^---;--線-. (請先閲讀背面之注項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）_ 16 - 經濟部智慧財產局員工消費合作杜印製 434422 Μ Α7 _______Β7 五、發明説明〇4 ) CH2 OCOCH二CH2 HOCOCH2 CH2 COOCH2 -C-CH2 OCOCH二CH2 ... (l) CH2 OCOCH二CH2 所示之化合物等爲佳，且特別以三丙烯酸三羥甲基丙烷酯 、三丙烯酸季戊四醇酯及六丙烯酸二季戊四醇酯爲畫素強 度高、畫素表面之平滑性優1且於未曝光部之基板上及遮 光層上難發生質地污染、殘膜等，故爲佳。 於本發明中，多官能性單體可單獨或混合使用二種以 上。 本發明多官能性單體之使用量相對於（B )鹼可溶性 樹脂1 0 0重量份，通常以5〜5 0 0重量份，較佳爲 2 0〜3 0 0重量份。此時，多官能性單體之使用量爲未 滿5重量份，則畫素強度和表面平滑性有降低之傾向，另 一方面，若超過5 0 0重量份，則例如令鹼顯像性降低， 於未曝光部之基板上或遮光層上易發生質地污染、殘膜等 0 又，於本發明中，視情況，亦可將前述多官能性單體 與單官能性單體倂用。 此類單官能性單體之例可列舉前述含羧基共聚物中所: 例示之含羧基不飽和單體、及光聚性不飽和單體和N-pg 烯醯基嗎啉、N —甲基丙烯醯基嗎啉、N -乙烯基吡略院 酮、N—乙烯基一ε_丁內酯等以外，及市售品M-5600 (商品名、東亞合成（株）製）等。 單官能性單體之使用比例，相對於多官能性單體與胃 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐）-17 - I-------Γ.---疲------訂--------線- {請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 4 Μ 4?，.. Α7 __Β7_五、發明説明〇5 ) 官能性單體之合計通常爲9 0重量％以下，較佳爲5 0重 量％以下。此時，單官能性單體之使用比例若超過9 0重 量％ ’則有令所得畫素之強度和表面平滑性降低之傾向。 (D )光聚合引發劑 本發明之光聚合引發劑爲含有三畊系化合物，可經由 可見光線、紫外線、遠紫外線、電子射線、X射線等之曝 光’而發生可引發前述（C )多官能性單體之活性種成分 □ 前述三畊系化合物之具體例可列舉 2，4，6 —三（三氯甲基）_5-三畊、 2 —甲基一 4，6-雙（三氯甲基）一s —三畊、 2 〔 2 —（5 —甲基呋喃一2 —基）乙烯基〕+— 4， 6 -雙（三氯甲基）—s —三畊、 2 -〔2 —(呋喃一 2 —基）乙烯基〕一4，6 -雙 (二氣甲基）—s —二哄、 2 —〔 2 —（4 一二乙胺基一2 —甲基苯基）乙烯基 〕一4 ’ 6 —雙（三氯甲基）_s —三啡、 2〔2— (3，4 —二甲氧基苯基）乙烯基〕一4， 6 -雙（三氯甲基）—s_三畊、 2 -（4 一甲氧基苯基）一4，6_雙（三氯甲基） 一 s —三畊 2— (4 —乙氧基苯乙烯基）一 4，6 —雙（三氯甲 基）—s —三畊、 本紙張尺度適用中國國家標準（CNS) Μ说格（2丨0X297公釐）-18- ----„----„---¾------ΐτ--1--：--ii- I (請先閱讀背面之注意事項再填寫本瓦) 434422 * ' A7 ______B7 五、發明説明) （4 —正丁氧基苯基）一4，6 -雙（三氯甲基 )一 s —三畊、 下述式（2 )所示之化合物（以下，稱爲「三畊系化 合物（2 )」）。 下述式（3 )所示之化合物（以下 (3 )」）。 稱爲「三畊系化合物 (請先閱讀背面之注意事項再填寫本頁) H3C0—— CH：Line 1T-This paper size applies to China National Standard (CNS) A4 specification (2 丨 〇297mm) -15-Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs t 434422 A7 _______B7__V. Description of the invention 〇3) Methacrylic acid Esters; diacrylates or dimethacrylates of polyalkylene glycols such as polyethylene glycol and polypropylene glycol: glycerol, trimethylolpropane, pentaerythritol, dipentaerythritol, etc. Polyacrylate or polymethacrylate and its dicarboxylic acid modified products; low acrylic acid of polyester, epoxy resin, polyurethane resin, alkyd resin, polysiloxane resin, spirane resin, etc. Esters or oligomethacrylates; two-terminal hydroxy poly-1,3-butadiene, two-terminal hydroxy polyisoprene, propylene-terminated hydroxy polyhexyl diacrylate, etc. Or dimethacrylates, and tris (2-propenyloxyethyl) phosphate, tris (2-methacryloxyethyl) phosphate, and the like. Among these polyfunctional monomers, polyacrylic acid esters or polymethacrylic acid esters of trivalent or higher polyhydric alcohols and dicarboxylic acid modified products thereof, and more specifically, trimethylolpropane triacrylate , Trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol pentaacrylate, dipentaerythritol pentamethacrylate, Dipentaerythritol hexaacrylate, dipentaerythritol hexamethacrylate, the following formula (----- 1 ^-: ------------------- order-^ ---;- LINE-. (Please read the note on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210X297 mm) _ 16-Intellectual Property Office of the Ministry of Economic Affairs, Consumer Consumption Du printed 434422 Μ Α7 _______B7 V. Description of the invention 〇4) CH2 OCOCH di CH2 HOCOCH2 CH2 COOCH2 -C-CH2 OCOCH di CH2 ... (l) The compounds shown by CH2 OCOCH di CH2 and the like are preferred, and especially trimethylolpropane triacrylate Esters, pentaerythritol triacrylate and hexaacrylic acid Pentaerythritol pixels high is strong, the surface smoothness of pixels and preferably 1 scumming, film remaining and the like on the substrate and the unexposed portions of the light-shielding layer is difficult to occur, it is better. In the present invention, two or more kinds of polyfunctional monomers may be used alone or in combination. The amount of the polyfunctional monomer of the present invention is 100 parts by weight with respect to the (B) alkali-soluble resin, usually 5 to 500 parts by weight, and preferably 20 to 300 parts by weight. At this time, if the used amount of the polyfunctional monomer is less than 5 parts by weight, the pixel strength and surface smoothness tend to decrease. On the other hand, if it exceeds 500 parts by weight, for example, alkali developability Reduced, texture pollution, residual film, etc. are easy to occur on the substrate of the unexposed part or on the light-shielding layer. In the present invention, the aforementioned polyfunctional monomer and monofunctional monomer may be used in combination as appropriate. Examples of such monofunctional monomers include the carboxyl group-containing copolymers mentioned above: Exemplary carboxyl group-containing unsaturated monomers, and photopolymerizable unsaturated monomers, N-pg alkenylmorpholine, N-methyl Other than acryl morpholine, N-vinylpyrrolidone, N-vinyl-ε-butyrolactone, etc., and commercially available product M-5600 (trade name, manufactured by Toa Sangyo Co., Ltd.), and the like. The proportion of the monofunctional monomer is relative to the size of the multifunctional monomer and the paper. The Chinese National Standard (CNS) A4 specification (210X 297 mm) -17-I ------- Γ.- --Tired ------ Order -------- Line- {Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy 4 Μ 4? .. Α7 __Β7_ V. Description of the Invention 05) The total amount of the functional monomers is usually 90% by weight or less, preferably 50% by weight or less. At this time, if the use ratio of the monofunctional monomer exceeds 90% by weight ', the strength and surface smoothness of the obtained pixels tend to decrease. (D) Photopolymerization Initiator The photopolymerization initiator of the present invention contains a compound of the Three Cultivation System, which can be triggered by exposure to visible light, ultraviolet, far ultraviolet, electron rays, X-rays, etc., and can trigger the aforementioned (C) polyfunctionality. Active species components of sexual monomers □ Specific examples of the aforementioned three-tillage compounds include 2,4,6-tris (trichloromethyl) _5-three-tillage, 2-methyl-1,6-bis (trichloromethane) Base) -s — three farms, 2 [2 — (5-methylfuran- 2 —yl) vinyl] + — 4, 6 -bis (trichloromethyl) —s — three farms, 2-[2 — (Furan-2-yl) vinyl] -4,6-bis (difluoromethyl) -s-dioxane, 2- [2- (4-diethylamino- 2-methylphenyl) vinyl ] 4 ′ 6 —bis (trichloromethyl) _s —triphine, 2 [2— (3,4-dimethoxyphenyl) vinyl] —4, 6 -bis (trichloromethyl) — s_Sangen, 2-(4-monomethoxyphenyl) -4,6_bis (trichloromethyl) -s —Sangen 2 -— (4-ethoxystyryl) —4,6 — Bis (trichloromethyl) -s-three-tillage, paper size Using the Chinese National Standard (CNS) M Grid (2 丨 0X297 mm) -18 ------------------------ ΐτ--1--: --ii -I (Please read the precautions on the back before filling in this tile) 434422 * 'A7 ______B7 V. Description of the invention) (4-n-butoxyphenyl)-4,6-bis (trichloromethyl) -s — Sangen, a compound represented by the following formula (2) (hereinafter referred to as "Sangen system compound (2)"). A compound represented by the following formula (3) (hereinafter (3) "). Called "Three-Cultural Compounds (Please read the precautions on the back before filling this page) H3C0—— CH:

(3) 訂 經濟部智慧財產局員工消費合作杜印製 等之具有鹵甲基之三哄系化合物。 此些三畊系化合物中，以2 —〔2 — (3，4 —二甲 氧基苯基）乙嫌基〕一 4，6雙（三氯甲基）一 s —三畊 、三啡系化合物（2 )、三畊系化合物（3 )等爲佳。 前述三畊系化合物可單獨或混合使用二種以上。 本發明三哄系化合物之使用量，相對於（C )多官能 性單體及視情況使用之單官能性單體之合計1 〇 〇重量份 ，通常爲以0·01〜40重量份，較佳爲1〜30重量 份，更佳爲1〜2 0重量份。此時，三d井系化合物之使用 量未滿0 . 0 1重量份，則曝光造成之硬化不足，恐難根 線丨—— -JH — - J— . 2 Η(3) Order the three-membered compounds with halomethyl groups such as Du Yinzhi, employee cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs. Among these three-tillage compounds, 2- [2- (3,4-dimethoxyphenyl) ethanoyl] -4,6bis (trichloromethyl) -s-three-tillage, three-morphine The compound (2) and the three-tillage compound (3) are preferred. The aforementioned three-tillage compounds can be used alone or in combination of two or more. The used amount of the triad compound of the present invention is generally 0.01 to 40 parts by weight relative to the total amount of (C) the polyfunctional monomer and the monofunctional monomer used as the case may be. It is preferably 1 to 30 parts by weight, and more preferably 1 to 20 parts by weight. At this time, if the amount of the three-d well system compound is less than 0.01 parts by weight, the hardening caused by exposure will be insufficient, which may make it difficult for the root line. 丨 —— -JH —-J—. 2 Η

c C 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐）-19- 經濟部智慧財產局員工消費合作社印製 4 34422^3 a? B7 五、發明説明（17 ) 據指定序列配置之畫素排列取得畫素圖型，另一方面，若 超過4 0重量份，則所形成之畫素於顯像時有易由基板上 脫落之傾向。 又，本發明中，光聚合引發劑之構成成分可倂用三畊 系化合物及其他之化合物（以下，稱爲「其他之光聚合引 發劑」）。 其他之光聚合引發劑可列舉例如乙醯苯系化合物、二 咪唑系化合物、苯偶因系化合物、二苯酮系化合物、α-二酮系化合物、多核醌系化合物、咕吨酮系化合物、重氮 系化合物等，且其中，以乙醯苯系化合物及二咪唑系化合 物群所選出之至少一種爲佳。 前述乙醯苯系化合物之具體例可列舉 2 -羥基一 2 -甲基一 1 一苯基丙烷—1 _酮、 2-甲基一 1—〔4_ (甲硫基）苯基〕一2 -嗎啉 丙酮—1、 2 -苄基—2 —二甲胺基一 1— (4 —嗎啉苯基）丁 酮一 1、 2 —羥基環己基苯基酮、 2 ’ 2 —二甲氧基一 1 ，2_聯苯基甲烷一1 一酮等 〇 此些乙醯苯系化合物中，特別以2 -苄基_ 2 -二甲 胺基—1— (4 —嗎啉苯基）丁酮一 1爲佳。 前述乙醯苯系化合物可單獨或混合使用二種以上。 於本發明中，乙醯苯系化合物與三哄系化合物倂用作 本纸浪尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐）_ 2〇 - I---L----^---奘------訂------·,--線- (請先閲讀背面之注意事項再填寫本頁) 434422 之 3 A7 B7 _ 五、發明説明（18 ) 爲光聚合引發劑之構成成分時的使用比例，相對於三哄系 化合物與乙醯苯系化合物之合計，通常爲9 0重量％以下 ，較佳爲3 0〜8 0重量％。此時，乙醯苯系化合物之使 用比例若超過9 0重量％，則所形成之畫素於顯像時有胃 由基板上脫落之傾向。 又，前述二咪唑系化合物之具體例可列舉2 ’ 2 >一 雙（2—氯苯基）—4，4 — ，5，5 / —四（4 一乙氧 羰苯基）—1，2，一二咪唑' 2，2 / —雙（2 -溴苯 基）一4，4 -，5，5 / —四（4 —乙氧羰苯基）一1 ，2 — -二咪唑、2，2 / —雙（2 -氯苯基）—4 ’ 4一，5，5^ —四苯基— 二咪唑、 —雙（2，4 —二氯苯基）一4，，5，5^ —四苯 基）-1，2 一—二咪唑、2，2一 —雙（2，4 + ’6 -三氯苯基）—4，4，，5，5 一 一四苯基—1，2' 一 唑 咪二 雙 基 苯 溴 4 4 5 4 經濟部智慧財產局員工消費合作社印製 基苯唑 苯溴咪 四二 二 唑 咪 ’ 較 -·» 4 中 ’ 其 4 2 雙 基 苯 四 基 苯 氯 三 基 彳基’基 雙苯 2 苯 I 四爲四 ' _ 物 一 2 \ 合' ， 5 化 5 0-3 ， 之 ， '5 佳 5 基 苯 氯二 - 4 唑 咪 雙 ί 1 基。基 、 雙 一苯唑苯唑 1 基溴咪氯咪 . 苯三二 一二 2 四一 一 2 一 1--Κ-------¾------訂--„-----千 (請先閱讀背面之注意事項存填寫本頁) 4 4 雙 基 苯 四 本紙乐尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐）_ 21 -c C This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -19- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 34422 ^ 3 a? B7 V. Description of the invention (17) According to the specified sequence The arranged pixel arrangement obtains a pixel pattern. On the other hand, if it exceeds 40 parts by weight, the formed pixel tends to fall off the substrate during development. Further, in the present invention, as a constituent component of the photopolymerization initiator, a three-farm-type compound and other compounds (hereinafter, referred to as "other photopolymerization initiators") can be used. Other photopolymerization initiators include, for example, acetophenone-based compounds, diimidazole-based compounds, benzoin-based compounds, benzophenone-based compounds, α-diketone-based compounds, polynuclear quinone-based compounds, glutanone-based compounds, Diazo-based compounds and the like, among them, at least one selected from the group of acetophenone-based compounds and diimidazole-based compounds is preferred. Specific examples of the aforementioned acetophenone-based compound include 2-hydroxy-1, 2-methyl-1, 1-phenylpropane-1-one, 2-methyl-1, [4- (methylthio) phenyl], 2- Morpholine acetone-1, 2-benzyl-2-dimethylamino-1- (4-morpholinyl) butanone-1, 2-hydroxycyclohexylphenyl ketone, 2 '2-dimethoxy Among these acetophenone compounds, 2-benzyl-2-dimethylamino-1- (4-morpholinylphenyl) butanone One is better. The acetophenone-based compound may be used alone or in combination of two or more. In the present invention, the acetophenone compound and the trioxane compound 倂 are used as the standard of this paper, and the Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applied. 2-0- I --- L --- -^ --- 奘 ------ Order ------ ·,-line- (Please read the notes on the back before filling out this page) 434422 3 A7 B7 _ V. Description of the invention (18 ) Is used as a constituent component of the photopolymerization initiator, and is usually 90% by weight or less, and preferably 30 to 80% by weight, relative to the total of the trioxane-based compound and the acetophenone-based compound. At this time, if the usage ratio of the acetophenone-based compound exceeds 90% by weight, the formed pixels tend to fall off the stomach from the substrate during development. In addition, specific examples of the aforementioned diimidazole-based compound include 2 '2 > bis (2-chlorophenyl) -4,4-,-5,5 / -tetrakis (4-ethoxycarbonylphenyl) -1, 2,1-diimidazole '2, 2 /-bis (2-bromophenyl)-4, 4-, 5, 5 /-tetra (4- ethoxycarbonylphenyl)-1, 2--diimidazole, 2 , 2 / -bis (2-chlorophenyl) -4 '4, mono, 5,5 ^ -tetraphenyl-diimidazole, -bis (2,4-dichlorophenyl) -4,5,5 ^ —Tetraphenyl) -1,2—diimidazole, 2,2—bis (2,4 + '6-trichlorophenyl) —4,4,, 5,5—tetraphenyl-1, 2 'Izobimidine didiphenylbenzene bromide 4 4 5 4 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Benzyl chloride triyl fluorenyl 'ylbisbenzene 2 benzene I four to four' _ 物 一 2 \ 合 ', 5 0-5, of which,' 5 Jia 5 phenyl chloro chloro-4 azole bis 1 base. Bis, benzophenazole, benzoxazole, 1-yl bromide, chloroimid, benzene, three-two, two, two, one, one, two, one, one--K ------- ¾ ------ order-„- --- Thousands (please read the precautions on the back and fill in this page first) 4 4 Biphenylbenzene four paper scales are applicable to China National Standard (CNS) A4 specifications (2 丨 0X297 mm) _ 21-

43442U A7 經濟部智慧財產局員工消費合作社印製 B7 _五、發明説明〇9 ) 2 / —二咪唑’特佳之化合物爲2，2 雙（2 —氯苯 基）一4 ’ 4 ^ ’ 5，5 一一四苯基一1，2 二咪哩 、2，2 一-雙（2，4一二氯苯基）一4，4—，5, 5 ――四苯基一 1 ，2，一二咪唑。 此些二咪唑系化合物對於溶劑之溶解性優，不會產生 未溶解物、析出物等異物，且感度高，以較少之能量曝光 則可令硬化反應充分進行，且對比度高，於未曝光部不會 產生硬化反應，故曝光後之塗膜，可明確區分出對於顯像 液不溶之硬化部分，及對顯像液具有高溶解性之未硬化部 分，藉此，則可令無削切（undercut )之畫素圖型，形成 根據指定序列配置的高精細畫素排列。 前述二咪唑系化合物可單獨或混合使用二種以上。 於本發明中，二咪唑系化合物與三哄系化合物倂用作 爲光聚合引發劑之構成成分時的使用比例，相對於三畊系 化合物與二咪唑系化合物之合計，通常爲9 0重量％以下 ，較佳爲5〜8 0重量％。此時，二咪唑系化合物之使用 比例若超過9 0重量％ ’則所形成之畫素於顯像時有易由 基板上脫落之傾向。 -氫供給體— 於本發明中，使用二咪唑系化合物作爲光聚合引發劑 之構成成分時，由更佳改良感度方向而言，較佳爲倂用下 述之氫供給體。 此處所謂之「氫供給體」，爲指可對經由曝光而由二 本紙張尺度逋用中國國家揉準（CNS) A4規格（210X297公釐)~_ 〇〇 _ I---_----一---¾------ir——I----千 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 ______B7 五、發明説明泛0 ) 咪哩系化合物中發生的游離基’供給氫原子之化合物。 前述之氫供給體較佳爲下述所定義之硫醇系化合物， 下述所定義之胺系化合物等。 前述之硫醇系化合物爲以苯環或雜環作爲母核，且直 接結合該母核之氫硫基爲具有1個以上，較佳爲i〜3個 ’更佳爲1〜2個化合物（以下，稱爲「硫醇系氫供給體 」）所構成。 前述之胺系化合物爲以苯環或雜環作爲母核，且直接 結合該母核之胺基爲具有1個以上，較佳爲1〜3個，更 佳爲1〜2個化合物（以下，稱爲「胺系氫供給體」）所 構成。 尙，此些氫供給體亦可同時具有氫硫基及胺基。 以下》更具體說明此些氫供給體。 硫醇系氫供給體可分別具有1個以上之苯環或雜環， 又可具有苯環與雜環兩者，於具有2個以上此些環之情形 中，亦可形成縮合環或未形成亦可。 又，硫醇系供給體爲具有2個以上之氫硫基時，只要 至少一個游離之氫硫基爲殘存，其剩餘之1個以上之氫硫 基亦可經烷基、芳烷基或芳基所取代’更且只要至少一個 游離之氫硫基爲殘存’則可具有二個硫原子爲透過伸烷基 等二價有機基結合之構造單位，或具有二個硫原子爲以二 硫型式結合之構造單位。 更且，硫醇系氫供給體於氫硫基以外之處’亦可經羧 基、烷氧羰基、經取代烷氧羰基、苯氧羰基'經取代苯氧 本紙張尺度適用中國國家標準（CNS ) A4规格（210 X 297公釐）-23 - -------------------訂-------線- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 4344223 A7 ____B7_ 五、發明説明釦） 羰基、，腈基等而予以取代。 此類硫醇系氫供給體之具體例可列舉2 —氫硫基苯並 噻唑、2 -氫硫基苯並nfB坐、2 -氫硫基苯並咪唑、2, 5 -二氫硫基一 1 ’ 3，4 —噻二唑、2_氫硫基—2， 5-二甲胺基吡啶等。 此些硫醇系氫供給體中，以2—氫硫基苯並噻唑、2 一氫硫基苯並噚唑爲佳，且特別以〇： _氫硫基苯並噻唑爲 佳。 其次’胺系氫供給體可分別具有1個以上苯環或雜環 ’又可具有苯環與雜環兩者，於具有2個以上此些環之情 形中，亦可形成縮合環或未形成亦可。 又’胺系氫供給體其1個以上之胺基，亦可經烷基或 經取代烷基所取代，又於胺基以外之處，亦可經羧基、烷 氧羰基、經取代烷氧羰基、苯氧羰基、經取代苯氧羰基、 腈基等所取代。 此類胺系氫供給體之具體例可列舉4，4 — 一雙（二 甲胺基）二苯酮、4 ’ 4 — 一雙（二乙胺基）二苯酮、4 一二乙胺基乙醯苯、4 —二甲胺基丙醯苯、4 一二甲胺基 苯甲酸乙酯、4一二甲胺基苯甲酸異戊酯、4一二甲胺基 苯甲酸' 4一二甲胺基苄腈等。 此些胺系氫供給體中，以4，4 > 一雙（二甲胺基） 二苯酮' 4 ’ 4 — 一雙（二乙胺基）二苯酮爲佳，且特別 以4，4 雙（二乙胺基）二苯酮爲佳。 於本發明中，氫供給體可單獨或混合使用二種以上， 泰紙張尺度適用中國國家轉（CNS ) A4規格（210X W7公釐)24 - ^ n^— n n^I I n 線— '~ (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明位2 ) 但將一種以上之硫醇系氫供給體與一種以上之胺系氫供給 體組合使用，由所形成之畫素於顯像時難由基板上脫落， 和畫素強度及感度亦高之方面而言爲佳。 硫醇系氫供給體與胺系氫供給體之較佳組合的具體例 可列舉2 —氫硫基苯並噻唑/4，4 > —雙（二甲胺基） 二苯酮、2 —氫硫基苯並噻唑/4，4 >_雙（二乙胺基 )苯並噻唑、2_氫硫基苯並噚唑/4，4 > 一雙（二甲 胺基）二苯酮、2_氫硫基苯並nf唑/ 4，4 — 一雙（二 乙胺基）二苯酮等，更佳之組合爲2 -氫硫基苯並噻唑/ 4，4> 一雙（二乙胺基）二苯酮、2 —氫硫基苯並鳄唑 /4 ’ 4 > 一雙（二乙胺基）二苯酮，特佳之組合爲2 — 氫硫基苯並噻唑/4，4 < 一雙（二乙胺基）二苯酮。 硫醇系氫供給體與胺系氫供給體之組合中，硫醇系氫 供給體與胺系氫供給體之重量比通常爲1 : 1〜1 : 4， 較佳爲1 : 1〜1 : 3。 於本發明中’氫供給體與二咪唑系化合物倂用時之使 用量’相對於（C )多官能性單體與視情況所使用之多官 能性單體之合計100重量份，通常以〇 . 〇1〜40重 量份，較佳爲1〜3 0重量份，更佳爲1〜2 0重量份。 此時’氫供給體之使用量若未滿〇 〇 1重量份，則具有 令感度之改良效果降低之傾向，另一方面，若超過4 〇重 量份，則於顯像時所形成之畫素有易由基板上脫落之傾向 〇 此處，若例示本發明中（a )三畊系化合物與乙醯苯 本紙張尺度適用中國國家標準（CNS > Α4規格（210X297公釐） -25- I---^------€------、1T——r--^--千 ί·1 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 434422 ^ A7 __B7 五、發明説明鉍） 系化合物之組合，（b )三哄系化合物與二咪唑系化合物 之組合’ （C )三D井系化合物、乙醯苯系化合物及二咪哩 系化合物之組合，（d )三畊系化合物、二咪唑系化合物 、硫醇系氫供給體及胺系氫供給體之組合，（e )三哄系 化合物、乙醯苯系化合物、二咪唑系、硫醇系氫供給體及 胺系氫供給體之組合的特佳具體例，則可列舉下述物質。 前述（a )之特佳的組合爲 2 —〔2—（3，4_二甲氧基苯基）乙烯基〕—4 ，6 —雙（三氯甲基）一s —三畊/2 —苄基一 2 -二甲 胺基一 1— (4 —嗎啉苯基）丁酮—1、 三畊系化合物（2) /2 —苄基一2 —二甲胺基—丄 —(4_嗎啉苯基）丁酮一1、 三哄系化合物（3 ) /2—;基一2 —二甲胺基—工 一（4 —嗎啉苯基）丁酮一 1等。 前述（b)之特佳的組合爲 2 —〔 2— (3 ，4-二甲氧基苯基）乙烯基〕一 4 ，6 —雙（三氯甲基）—s —三畊/2，2 - —雙（2， 4 —二氯苯基）—4，4 ^ ’ 5，5，一四苯基一 1，2 ——二咪唑、 三哄系化合物（2)/2，2 雙（2，4_二氯 苯基）-4，4^ ，5，5，—四苯基一 1 ，2二咪 唑、 三哄系化合物（3)/2，2 > -雙（2，4 一二氯 I本基）—4’4 ’5，5 —四苯基—1，2 一 一二咪 本紙張尺度適用中國國家標率（CNS ) A4規格（210X29?公嫠）-26 - -T---1------^------,1T——r----千 — (請先閲讀背面之注意事項再填寫本頁} 434422 -5 A7 經濟部智慧財產局員工消費合作社印製 B7五、發明説明泛4 ) 唑等。又，於上述之組合中，將2，2 雙（2，4 二氯苯基）一 4，4' ，5，5^ —四苯基一 1，2^ — 二咪唑以2，2 - -雙（2 —氯苯基）一 4，4#，5， 5 ' _四苯基一 1，2 > —二咪哗代替之組合亦爲特佳使 用。 前述（c )之特佳組合爲 2 -〔 2— ( 3，4 —二甲氧基苯基）乙烯基〕一 4 ，6_雙（三氯甲基）一s —三畊/2 -苄基一2 —二甲 胺基一 1一（4 一嗎啉苯基）丁酮—1/2，2 > -雙（ 2 ’ 4 —二氯苯基）一4，4 — ，5，5 / —四苯基—1 ，2 二咪唑、三畊系化合物（2)/2_苄基—2 — 二甲胺基_1_ (4 一嗎啉苯基），丁酮一1/2，2 一 一雙（2，4-二氯苯基）一4，，5，5 一一四苯 基一 1，2 二咪唑、三畊系化合物（3) /2 —苄基 一 2 —二甲胺基_1一（4-嗎啉苯基），丁酮一1/2 ,2——雙（2，4 —二氯苯基）—4，4'，5，5 一 —四苯基_1 ，2 二咪唑等。又，於上述之組合中， 將 2，2'—雙（2，4 —二氯苯基）一4，，5， 5 > —四苯基一1，2 < —二咪唑以2，2 一一雙（2 — 氯苯基）—4，4，，5，5— - 四苯基—1，- 二 咪唑代替之組合亦爲特佳使用。 前述（d)之特佳組合爲 2 —〔2—（3 ，4_二甲氧基苯基）乙烯基〕—4 ，6 —雙（三氯甲基）—s—三畊/2，2 / _雙（2， (請先閲讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準（CNS ) Α4規格（2〗Ο X 297公釐）-27 - 經濟部智慧財產局員工消費合作社印製 43442 2 i a? ____B7_五、發明説明紅） 4 一二氯苯基）—4，4 / ，5，5 / —四苯基_1， 2 - -二咪唑—氫硫基苯並噻唑/4，4 — 一雙（二 乙胺基）二苯酮、三啡系化合物（2)/2，—雙（ 2，4 — 一 氯苯基）—4，4 -，5，5 — - 四苯基一 1 ，2 二咪唑/2 —氫硫基苯並噻唑/4，4 > 一雙（ 二乙胺基）二苯酮、三畊系化合物（3) /2，2 / -雙 (2，4 —二氯苯基）—4，4 -，5，5 四苯基— s 1，2 > -二咪唑/2 —氫硫基苯並噻唑/4，4 > —雙 (二乙胺基）二苯酮等。又，於上述之組合中，將2， 2 一雙（2 ’ 4 一二氯苯基）一4 ，4 一，5 ，5' — 四苯基一 1，2> —二咪唑以2，2> —雙（2 —氯苯基 )-4，4 — ，5 ’ 5四苯基-1 ，2 二咪唑代 替之組合亦爲特佳使用。 前述（e )之特佳組合爲 2 —〔2 — (3 ，4 —二甲氧基苯基）乙烯基〕一 4 ，6 —雙（三氯甲基）—s —三畊/2—苄基一 2 —二甲 胺基—1— (4—嗎琳苯基）丁爾—1/2，2 —雙（ 2 ，4 一二氯苯基）一4，，5，5 > —四苯基一1 ，2 / —二咪唑/2 -氫硫基苯並噻唑/4，4 —雙（二 乙胺基）二苯酮、 三畊系化合物（2) /2 —苄基一2 —二甲胺基一 1 一（4 一嗎啉苯基），丁酮—1/2，2 > -雙（2，4 一二氯苯基）-4，4’ ’ 5 ’ 5— -四苯基一 1，2 一 一二咪唑、/ 2 -氫硫基苯並噻唑/4，4 > 一雙（二乙 I----^---rp---€------tr——1-----乎 — (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）-28 - 4 3 442 2」 at B7 五、發明説明鉍） 胺基）二苯酮、 (請先鬩讀背面之注意事項再填寫本頁) 三畊系化合物（3) /2 -苄基一 2 —二甲胺基一 1 一（4 一嗎啉苯基），丁酮—1/2，2 〃 —雙（2，4 一二氣苯基）—4 ’ 4 ^ ’ 5，5 四苯基—1，2 一二咪唑/2 —氫硫基苯並噻唑/4，4 < 一雙（二乙胺 基）二苯酮等。又，於上述之組合中，將2，2 —雙（ 2，4 —二氯苯基）一4 , 4 — ，5，5 四苯基-1 ，2二咪唑以2，2 ――雙（2 —氯苯基）—4， 4 > ，5，5 > —四苯基—1 ，2 二咪唑代替之組合 亦爲特佳使用。 (E)有機胺基化合物 本發明之有機胺基化合物爲於分子中，具有1姻以上 胺基之有機胺基化合物（以下，稱爲「（ E )有機胺基化 合物」）〇 經濟部智慧財產局員工消費合作社印製 (E )有機胺化合物爲將曝光時，由濾色器用感放射 線性組成物中之光聚合引發劑中所含之三畊系化合物所發 生的活性游離基、和該活性游離基與感放射線性組成物中 之有機化合物反應副生成之揮發性酸性化合物（例如，鹵 化氫等）予以捕捉，防止光罩附著物的發生，並且達成令 形成畫素之基板與遮光層之密合性改良作用之成分。尙， 前述之胺系氫供給體本身亦具有此類作用，但因該胺系氫 供給體爲與（C)光聚合引發劑主成分之前述二咪唑系化 合物的交互作用而消耗，故該胺系氫供給體本身實際上並 本紙張尺度適用中國國家標準（CNS ) A4规格（2丨Ο X 297公釐）_ 29 - 經濟部智慧財產局員工消費合作社印製 43 44 2 2 i A7 A7 _____B7_五、發明説明切） 不顯示前述作用。 (E )有機胺基化合物以脂族胺或含苯基之胺爲佳。 前述脂族胺之例可列舉 正丙胺、異丙胺、正丁胺、異丁胺、第二丁胺、第三 丁胺、正戊胺、正己胺、正庚胺、正辛胺、正壬胺、正癸 胺、正十一胺、正十二胺、環己胺、鄰—甲基環己胺、間 -甲基環己胺、對一甲基環己基、鄰一乙基環己胺、間一 乙基環己胺、對一乙基環己胺等之單（環）烷胺類； 甲基乙胺、二乙胺、甲基正丙胺、乙基正丙胺、二正 丙胺、二異丙胺、二正丁胺、二異丁胺、二第二丁胺、二 第三丁胺、二正戊胺、二正己胺、甲基環己胺、乙基環己 胺、二環己胺等之二（環）烷胺類； 二甲基乙胺、甲基二乙胺、三乙胺、二甲基正丙胺、 二乙基正丙胺、甲基二正丙胺、乙基二正丙胺、三正丙胺 、三異丙胺、三正丁胺、三異丁胺、三第二丁胺、三第三 丁胺、三正戊胺、三正己胺、二甲基環己胺、二乙基環己 胺、甲基二環己胺、乙基二環己胺、三環乙胺等之三（環 )烷胺類； 2 —胺基乙醇、3 -胺基一 1一丙醇、1 一胺基—2 一丙醇、4 一胺基一 1 一丁醇、5 —胺基—1 一戊_、6 一胺基—1一己醇、4 一胺基—1—環己醇等之單（環） 烷醇胺類； 二乙醇胺、二正丙醇胺、二異丙醇胺、二正丁醇胺、 二異丁醇胺、二正戊醇胺、二正乙醇胺、二（4 —環己醇 -----^---r---¾------IT--r-----子 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS > A4规格（210X297公楚）-30- 經濟部智慧財產局員工消費合作社印製 森 3 4 4· 2 2 二： A7 B7____五、發明説明（28 ) )胺等之二（環）烷醇胺類； 三乙醇胺、三正丙醇胺、三異丙醇胺、三正丁醇胺、 三異丁醇胺、三正戊醇胺、三正己醇胺、三（4 -環己醇 )胺等之三（環）烷醇胺類； 3 -胺基-1，2—丙二醇、2 —胺基-1，3-丙 二醇' 4 一胺基—1，2_丁二醇' 4 —胺基—1 ’ 3 — 丁二醇、4 —胺基一 1，2 —環己二醇、4 —胺基—1， 3 —環己二醇、3 —二甲胺基—1，2 —丙二醇、3 —二 乙胺基一1，2 -丙二醇、2 -二甲胺基—1，3 -丙二 醇、2 —二乙胺基一 1，3 -丙二醇等之胺基（環）鏈烷 二醇類； 1-胺基環戊烷甲醇' 4 一胺基環戊烷甲醇、1 一胺 基環己烷甲醇、4 -胺基環己烷甲醇、4 —二甲胺基環戊 烷甲醇、4_二乙胺基環戊烷甲醇、4 —二甲胺基環己烷 甲醇、4-二乙胺基環己烷甲醇等之含胺基環鏈烷甲醇類 /3 —丙胺酸、2 -胺基丁酸，3 —胺基丁酸、4 一胺 基丁酸、2 —胺基異丁酸、3 —胺基異丁酸、2 -胺基戊 酸、5 -胺基戊酸、6 -胺基己酸、1 -胺基環丙烷羧酸 、1一胺基環己烷羧酸、4-胺基環己烷羧酸等之胺基羧 酸類等。 又，含苯基之胺可列舉例如，胺基直接結合至苯基之 化合物，胺基爲透過二價鍵結基結合至苯基之化合物等。 含苯基之胺之例可列舉 ----^---ί---#------,ιτ--：-----千 — {請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨Ο X 297公釐）_ 31 - ^ 34422¾ A7 B7 五、發明説明鉍） 苯胺、鄰一甲基苯胺'間一甲基苯胺、對—甲基苯胺 、對一乙基苯胺、對-正丙基苯胺'對-異丙基苯胺對 —正丁基苯胺、對一第三丁基苯胺、1 一萘胺、2 一萘胺 、N ’ N —二甲基苯胺、N，N —二乙基苯胺、對—甲基 一 N ’ N —二甲基苯胺等之芳香族胺類； 鄰-胺基苄醇、間一胺基苄醇、對-胺基苄醇、對— 二甲胺基苄醇、對-二乙胺基苄醇等之胺基苄醇類； 鄰一胺基苯酚、間-胺基苯酚、對—胺基苯酚、對一 二甲胺基苯酚、對-二乙胺基苯酚等之胺基苯酚類： 間-胺基苯甲酸、對-胺基苯甲酸、對一二甲胺基苯 甲酸、對一二乙胺基苯甲酸等之胺基苯甲酸（衍生物）類 等。 此些（E)有機胺基化合物中，由對於後述溶劑之溶 解性，防止未曝光部基板上或遮光層上質地污染和殘膜等 之觀點而言，則脂族胺以單（環）烷醇胺類及胺基（環） 鏈烷二醇類爲佳，且特別以2 —胺基乙醇、3 -胺基—1 一丙醇、5 —胺基—1一戊醇、3_胺基—1，2 —丙二 醇、2 —胺基—1 ’ 3 —丙二醇、4 一胺基—1 ’ 2 — 丁 二醇等爲佳。又，含苯基之胺以胺基苯酚類爲佳’且特別 以鄰-胺基苯酹、間-胺基苯酌、對一胺基苯紛等爲佳。 於本發明中，（E)有機胺基化合物可單獨或混合使 用二種以上》 本發明（E )有機胺基化合物之使用量’相對於感放 射線性組成物全體，通常以〇 〇 1〜1 5重量份’較佳 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇><297公釐）-32 - I----^--------裝------訂--^-----線- (請先鬩讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 434422^ A7 B7___ 五、發明説明細） 爲0 . 01〜10重量％。此時，有機胺基化合物（E) 之使用量未滿〇 . 〇 1重量％，則令光罩附著物之抑制效 果或所形成畫素對於基板和遮光層密合性的改良效果有降 低之傾向，另一方面，若超過1 5重量％，則反而令與已 形成畫素之基板的密合性有降低之傾向。 添加劑 本發明之瀘色器用感放射性組成物，視需要亦可含有 各種添加劑。 前述添加劑爲令濾色器用感放射性組成物，對於鹼性 顯像液之溶解特性更加改善，且令顯像後未溶解物的殘存 更加顯示抑制作用等，並且可列舉出有機酸等。 一有機酸一 前述有機酸，以分子中具有1個以上羧基且分子量爲 1 ’ 0 0 0以下之脂族羧酸或含苯基之羧酸爲佳。 前述脂族羧酸之例可列舉 經濟部智慧財產局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 甲酸、醋酸、丙酸、丁酸、戊酸、特戊酸、己酸、二 乙基醋酸、庚酸、辛酸等之脂族單羧酸類； 草酸、丙二酸、琥珀酸、戊二酸、己二酸、庚二酸、 辛二酸、壬二酸、癸二酸、巴西二酸、甲基丙二酸、乙基 丙二酸、二甲基丙二酸、甲基琥珀酸、四甲基琥珀酸、環 己院二羧酸、衣康酸、檸康酸、順丁烯二酸、反丁烯二酸 、中康酸等之脂族二羧酸類；丙三羧酸、丙烯一 1 ，3 — 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）-33 經濟部智慧財產局員工消費合作社印製 434422^ A7 __B7_五、發明説明⑸） 三羧酸、樟腦三酸等之脂族三羧酸類等。 又’前述含苯基之羧酸可列舉例如羧基爲直接結合苯 基之化合物、和羧基爲透過二價結合基而結合至苯基之化 合物等。 含苯基之羧酸例可列舉 苯甲酸、甲苯酸、枯茗酸、二甲基苯甲酸、来林酸等 之芳香族單羧酸類； 苯二甲酸、間苯二酸、對苯二酸等之芳香族二羧酸類 > 均苯四酸、均苯三酸、偏苯四酸、偏苯三酸等之三價 以上之芳香族聚羧酸類和 苯基醋酸、氫化阿托酸、氫化肉桂酸、苦杏仁酸、苯 基琥珀酸、阿托酸、肉桂酸、肉桂叉酸、枯基酸、傘形酸 等。 此些有機酸中，由鹼溶解性，對於後述溶劑之溶解性 ，防止未曝光部之基板上及遮光層上的質地污染和殘膜等 之觀點而言，則脂族羧酸以脂族二羧酸類爲佳，且特別以 丙二酸、己二酸、衣康酸、檸康酸、反丁烯二酸、中康酸 等爲佳。又，含苯基之羧酸以芳香族二羧酸爲佳，且特佳 爲苯二甲酸。 有機酸之使用量，相對於感放射性組成物全體，通常 爲1 5重量％以下，較佳爲1 0重量％以下。此時，有機 酸之使用量若超過1 5重量％，則對於形成畫素之基板的 密合性有降低之傾向。 I----^-------裝------訂——^----線- (請先闊讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標率（CNS ) A4規格（210X297公釐）_ 34 - 經濟部智慧財產局員工消費合作社印製 4^4422¾ A7 _B7__ 五、發明説明) 又，前述以外之添加劑，可列舉例如 銅鈦菁衍生物等之藍色顏料衍生物和黃色顏料衍生物 等之分散助劑； 玻璃、氧化鋁等之充塡劑； 聚乙烯醇、聚乙二醇單烷醚類、聚（丙烯酸氟烷酯） 類等之高分子化合物： 非離子系、陽離子系、陰離子系等之界面活性劑； 乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、乙烯基 三（2 -甲氧乙氧基）矽烷、N— (2 —胺乙基）—3 — 胺丙基甲基二甲氧基矽烷、N— (2 —胺乙基）一 3 -胺 丙基三甲氧基矽烷、3-胺丙基三乙氧基矽烷、3-縮水 甘油氧丙基三甲氧基矽烷、3-縮水甘油氧丙基甲基二甲 氧基矽烷、2 -（3，4 -環氧環己基）乙基三甲氧基矽 烷、3 —氯丙基甲基二甲氧基矽烷、3 -氯丙基三甲氧基 矽烷、3-甲基丙烯氧丙基三甲氧基矽烷、3—氫硫丙基 三甲氧基矽烷等之密合促進劑； 2，2 > —硫代雙（4 一甲基一 6 —第三丁基苯酚） 、2 ’ 6 -二一第三丁基苯酚等之抗氧化劑； 2 — (3 —第三丁基一5 —甲基一2 —羥苯基）一 5 -氯苯並三唑、烷氧基二苯酮類等之紫外線吸收劑； 聚丙烯酸鈉等之防凝集劑； 1 ’ 1 < —偶氮雙（環己烷一 1 一腈）、2-苯基偶 氮一 4 -甲氧基一 2，4 一二甲基戊腈等之熱游離基發生 劑； 本紙張尺度適用中國國家標隼（CNS ) A4規格（210X297公釐〉_ 35 - --------Γ—---€------il--------千 — (請先聞讀背面之注意事項再填寫本頁)43442U A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7 _V. Description of the invention 〇9) 2 /-Diimidazole 'especially good compound is 2, 2 bis (2-chlorophenyl)-4' 4 ^ '5, 5 one-tetraphenyl-1,2 dimi-mile, 2,2 one-bis (2,4-dichlorophenyl) -4, 4--5, 5-tetraphenyl-1,2, one Diimidazole. These diimidazole compounds have excellent solubility in solvents, do not generate foreign matter such as undissolved matter, precipitates, and have high sensitivity. Exposure with less energy can make the hardening reaction fully proceed, and the contrast is high. There is no hardening reaction at the part, so the coating film after exposure can clearly distinguish between the hardened part that is insoluble in the developer and the unhardened part that has high solubility in the developer. With this, no cutting is possible. The pixel pattern of (undercut) forms a high-resolution pixel arrangement configured according to a specified sequence. The diimidazole-based compound may be used alone or in combination of two or more. In the present invention, the use ratio of the diimidazole-based compound and the trioxazole-based compound 倂 as a constituent component of the photopolymerization initiator is usually 90% by weight or less relative to the total of the three-tillage compound and the diimidazole-based compound. It is preferably 5 to 80% by weight. At this time, if the use ratio of the diimidazole-based compound exceeds 90% by weight, the formed pixel tends to fall off the substrate during development. -Hydrogen donor- In the present invention, when a diimidazole-based compound is used as a constituent component of the photopolymerization initiator, it is preferable to use a hydrogen donor described below in order to improve the sensitivity direction. The so-called "hydrogen donor" here refers to the use of the Chinese National Standard (CNS) A4 specification (210X297 mm) from the two paper sizes by exposure ~ _ 〇〇_ I ---_-- -一 --- ¾ ------ ir——I ---- Thousands (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ______B7 V. Invention It is explained that the free radical 'supplying a hydrogen atom occurs in the milie compound. The hydrogen donor is preferably a thiol-based compound defined below, an amine-based compound defined below, and the like. The aforementioned thiol-based compound is a benzene ring or a heterocyclic ring as a mother core, and the hydrogen thio group directly bound to the mother core has one or more, preferably i ~ 3 ', more preferably 1 ~ 2 compounds ( Hereinafter, it is referred to as a "thiol-based hydrogen donor"). The aforementioned amine-based compound has a benzene ring or heterocyclic ring as the mother core, and the amine group directly bound to the mother core has one or more, preferably 1 to 3, more preferably 1 to 2 compounds (hereinafter, (Referred to as "amine-based hydrogen donor"). Alas, these hydrogen donors may have both a hydrogen sulfur group and an amine group. The following hereinafter describes these hydrogen donors in more detail. The thiol-based hydrogen donor may have at least one benzene ring or heterocyclic ring, and may have both a benzene ring and a heterocyclic ring. In the case of having two or more of these rings, a condensed ring or no ring may be formed. Yes. When the thiol-based donor has two or more hydrogen sulfide groups, as long as at least one free hydrogen sulfide group remains, the remaining one or more hydrogen sulfide groups may be alkyl, aralkyl, or aromatic. "And as long as at least one free hydrogen-sulfur group is residual", it may have two sulfur atoms as a structural unit bonded through a divalent organic group such as an alkylene group, or have two sulfur atoms as a disulfide type Combined construction unit. In addition, thiol-based hydrogen donors other than hydrogen thio groups can also be substituted with carboxyl, alkoxycarbonyl, substituted alkoxycarbonyl, and phenoxycarbonyl 'substituted phenoxy. This paper applies Chinese national standards (CNS) A4 specification (210 X 297 mm) -23-------------------- Order ------- Line- (Please read the precautions on the back before (Fill in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4344223 A7 ____B7_ V. Description of the invention Deduction) Carbonyl, nitrile, etc. are replaced. Specific examples of such thiol-based hydrogen donors include 2-hydrothiobenzothiazole, 2-hydrothiobenzonfB, 2-hydrothiobenzimidazole, and 2, 5-dihydrothio. 1 '3,4-thiadiazole, 2-hydrothio-2,5-dimethylaminopyridine, and the like. Among these thiol-based hydrogen donors, 2-hydrothiobenzothiazole and 2-monohydrothiobenzoxazole are preferred, and 0: _hydrothiobenzothiazole is particularly preferred. Next, the amine-based hydrogen donor may have more than one benzene ring or heterocyclic ring, respectively, and may have both a benzene ring and a heterocyclic ring. In the case of having two or more of these rings, a condensed ring or no ring may be formed. Yes. Also, an amine-based hydrogen donor may have more than one amine group, which may be substituted by an alkyl group or a substituted alkyl group. Besides the amine group, it may also be substituted by a carboxyl group, an alkoxycarbonyl group, or a substituted alkoxycarbonyl group. , Phenoxycarbonyl, substituted with substituted phenoxycarbonyl, nitrile and the like. Specific examples of such an amine-based hydrogen donor include 4,4-bis (dimethylamino) benzophenone, 4 '4-bis (diethylamino) benzophenone, and 4-diethylamine Ethylbenzene, 4-dimethylaminopropanbenzene, 4-dimethylaminobenzoate, 4-isodimethylaminobenzoate, 4-dimethylaminobenzoate '4-dimethyl Aminobenzonitrile and the like. Among these amine-based hydrogen donors, 4,4 > monobis (dimethylamino) benzophenone '4' 4-monobis (diethylamino) benzophenone, and particularly 4, 4 Bis (diethylamino) benzophenone is preferred. In the present invention, two or more hydrogen donors can be used alone or in combination. Thai paper size is applicable to China National Transfer (CNS) A4 specification (210X W7 mm) 24-^ n ^ — nn ^ II n line — '~ ( Please read the notes on the back before filling in this page) A7 B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of invention 2) However, more than one thiol-based hydrogen supplier and more than one amine-based hydrogen supply It is preferable that the formed pixels are difficult to fall off from the substrate during development, and the pixel strength and sensitivity are also high. Specific examples of a preferred combination of a thiol-based hydrogen donor and an amine-based hydrogen donor include 2-hydrothiobenzobenzothiazole / 4,4 > -bis (dimethylamino) benzophenone, 2-hydrogen Thiobenzothiazole / 4,4 > _bis (diethylamino) benzothiazole, 2-hydrothiobenzoxazole / 4,4 > bis (dimethylamino) benzophenone, 2-Hydroxythiobenzonfazole / 4,4-bis (diethylamino) benzophenone, etc., a better combination is 2-hydrothiobenzobenzothiazole / 4,4 > monobis (diethylamine) Group) benzophenone, 2-hydrothiobenzocrocodazole / 4 '4 > A bis (diethylamino) benzophenone, a particularly preferred combination is 2-hydrothiobenzothiazole / 4,4 & lt One bis (diethylamino) benzophenone. In the combination of a thiol-based hydrogen donor and an amine-based hydrogen donor, the weight ratio of the thiol-based hydrogen donor to the amine-based hydrogen donor is usually 1: 1 to 1-4, and preferably 1: 1 to 1: 1: 3. In the present invention, the "amount of use of the hydrogen donor and the diimidazole-based compound" is usually 100 parts by weight with respect to the total of (C) the polyfunctional monomer and the polyfunctional monomer used as the case may be. 〇1 ~ 40 parts by weight, preferably 1 ~ 30 parts by weight, more preferably 1 ~ 20 parts by weight. At this time, if the used amount of the hydrogen donor is less than 0.001 parts by weight, there is a tendency that the improvement effect of sensitivity is reduced. On the other hand, if it exceeds 40 parts by weight, pixels formed during development are developed. There is a tendency to be easily peeled off the substrate. Here, if the (a) three-cultivation compound and acetophenone in the present invention are exemplified, the Chinese paper standard (CNS > A4 specification (210X297 mm)) is applied. -25- I --- ^ ------ € ------, 1T——r-^-Thousands · 1 (Please read the notes on the back before filling out this page) Employees of the Bureau of Intellectual Property, Ministry of Economic Affairs Printed by the Consumer Cooperative 434422 ^ A7 __B7 V. Description of the Invention Bismuth) -based compounds, (b) Triad-based compounds and diimidazole-based compounds' (C) Triple-D well-based compounds, acetophenone-based compounds, and two A combination of mili-based compounds, (d) a combination of a three-cooked compound, a diimidazole-based compound, a thiol-based hydrogen donor, and an amine-based hydrogen donor, (e) a triad-based compound, an acetophenone-based compound, Particularly preferred examples of combinations of imidazole-based, thiol-based hydrogen donors, and amine-based hydrogen donors are listed below. Take the following substances. The particularly preferred combination of the aforementioned (a) is 2- [2- (3,4-dimethoxyphenyl) vinyl] -4,6-bis (trichloromethyl) -s-Sangen / 2- Benzyl- 2 -dimethylamino- 1-(4-morpholinylphenyl) butanone-1-Cultivated compounds (2) / 2-benzyl-2-dimethylamino-fluorene-(4_ Morpholine phenyl) methyl ethyl ketone-1, triazine compound (3) / 2-; group dimethyl 2-dimethylamino-gongyi (4-morpholine phenyl) methyl ethyl ketone-1 and so on. A particularly preferred combination of the aforementioned (b) is 2- [2- (3,4-dimethoxyphenyl) vinyl] -4,6-bis (trichloromethyl) -s-Sangen / 2, 2-—bis (2,4-dichlorophenyl) -4,4 ^ '5,5, tetraphenyl-1,2 —diimidazole, triazine compound (2) / 2,2 bis ( 2,4_dichlorophenyl) -4,4 ^, 5,5,5-tetraphenyl-1,2diimidazole, triazine compound (3) / 2,2 > -bis (2,4 a Dichloro I base) — 4'4 '5,5 —tetraphenyl — 1, 2 1 and 2 paper This paper size is applicable to China National Standards (CNS) A4 specifications (210X29? Gong) -26--T --- 1 ------ ^ ------, 1T——r ---- Thousands— (Please read the notes on the back before filling out this page} 434422 -5 A7 Intellectual Property Bureau, Ministry of Economic Affairs Employee Consumer Cooperative printed B7 V. Invention Description Pan 4) azole etc. In addition, in the above combination, 2,2 bis (2,4 dichlorophenyl) -4,4 ', 5,5 ^ -tetraphenyl-1,2 ^ -diimidazole is 2,2-- The combination of bis (2-chlorophenyl) -4,4 #, 5,5'_tetraphenyl-1,2 > -dimidol is also particularly preferred. A particularly preferred combination of the aforementioned (c) is 2- [2- (3,4-dimethoxyphenyl) vinyl] -4,6_bis (trichloromethyl) -s-trigon / 2-benzyl -2-dimethylamino-1-(4-morpholinophenyl) butanone-1/2, 2 >-bis (2 '4-dichlorophenyl)-4, 4-, 5, 5 / —Tetraphenyl-1, 2 diimidazole, triploid compound (2) / 2_benzyl-2 — dimethylamino_1_ (4-monomorpholinephenyl), methyl ethyl ketone 1/2, 2 One bis (2,4-dichlorophenyl) one 4,4,5,5 One one tetraphenyl one 1,2 diimidazole, three farming compounds (3) / 2 -benzyl one 2-dimethylamine Yl_1- (4-morpholinephenyl), methyl ethyl ketone 1 / 2,2-bis (2,4-dichlorophenyl) -4,4 ', 5,5-tetraphenyl_1 , 2 diimidazole and so on. In the above combination, 2,2'-bis (2,4-dichlorophenyl) -4,5,5 > -tetraphenyl-1,2 < -diimidazole is 2, The combination of 2-one-bis (2-chlorophenyl) -4,4,5,5,5-tetraphenyl-1, -diimidazole is also particularly preferred. A particularly preferred combination of the aforementioned (d) is 2- [2- (3,4-dimethoxyphenyl) vinyl] -4,6-bis (trichloromethyl) -s-Sangen / 2,2 / _Double (2, (Please read the notes on the back before filling in this page) This paper size applies to China National Standard (CNS) Α4 specifications (2) 〇 X 297 mm -27-Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the consumer cooperatives 43442 2 ia? ____B7_ V. Description of the invention red) 4 -dichlorophenyl) -4,4 /, 5,5 / -tetraphenyl_1, 2--diimidazole -hydrothiobenzene Benzothiazole / 4,4 — bis (diethylamino) benzophenone, triphinoid compound (2) / 2, —bis (2,4 —monochlorophenyl) —4,4-, 5,5 —-Tetraphenyl-1,2 diimidazole / 2 —hydrothiobenzothiazole / 4,4 > Monobis (diethylamino) benzophenone, Tri-Cultural Compound (3) / 2, 2 / -Bis (2,4-dichlorophenyl) -4,4-, 5,5 tetraphenyl — s 1,2 > -diimidazole / 2 —hydrothiobenzothiazole / 4,4 > — Bis (diethylamino) benzophenone and the like. Moreover, in the above combination, 2, 2-bis (2 '4-dichlorophenyl)-4, 4-5, 5, 5'-tetraphenyl-1,2, >-diimidazole 2,2 > —Bis (2-chlorophenyl) -4,4—, 5′5tetraphenyl-1,2 diimidazole instead of the combination is also particularly preferred. A particularly preferred combination of the aforementioned (e) is 2- [2- (3,4-dimethoxyphenyl) vinyl] -4,6-bis (trichloromethyl) -s-trigon / 2-benzyl 2-dimethylamino-1— (4-morpholinyl) butan—1 / 2,2-bis (2,4-dichlorophenyl) —4,5,5 > —tetra Phenyl-1,2, -diimidazole / 2-hydrothiobenzothiazole / 4,4-bis (diethylamino) benzophenone, Tricotyl compound (2) / 2-benzyl-1 2- Dimethylamino-1 1- (4-morpholinophenyl), methyl ethyl ketone—1 / 2,2 > -bis (2,4-dichlorophenyl) -4,4 '' 5 '5- -tetra Phenyl-1,2-diimidazole, / 2-hydrothiobenzothiazole / 4,4 > bis (diethyl I ---- ^ --- rp --- € ----- -tr——1 ----- Hu— (Please read the notes on the back before filling out this page) This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) -28-4 3 442 2 " at B7 V. Description of the invention Bismuth) Amine) Benzophenone, (Please read the precautions on the reverse side before filling out this page) Sancang compound (3) / 2-benzyl-2-dimethylamino-1 One 4-monomorpholine phenyl), methyl ethyl ketone—1 / 2,2 〃—bis (2,4-difluorophenyl) -4 '4 ^' 5,5 tetraphenyl-1,2-diimidazole / 2 —Hydroxythiobenzothiazole / 4,4 < Monobis (diethylamino) benzophenone and the like. In addition, in the above combination, 2,2-bis (2,4-dichlorophenyl) -1,4,4-, 5,5 tetraphenyl-1,2diimidazole is 2,2-bis ( 2-chlorophenyl) -4,4 >, 5,5 > -tetraphenyl-1,2 diimidazole in combination is also particularly preferred. (E) Organic amine compound The organic amine compound of the present invention is an organic amine compound having at least one amine group in the molecule (hereinafter, referred to as "(E) organic amine compound"). Intellectual property of the Ministry of Economic Affairs The (E) organic amine compound printed by the Bureau ’s Consumer Cooperative is the active free radical generated by the three farming compounds contained in the photopolymerization initiator in the radiation-sensitive composition of the color filter at the time of exposure, and the activity Volatile acidic compounds (for example, hydrogen halides, etc.) that are formed as a by-product of the reaction of free radicals with organic compounds in the radiation-sensitive composition are captured to prevent the occurrence of mask attachments, and achieve the formation of pixel substrates and light shielding layers Ingredients for improving adhesion. Alas, the aforementioned amine-based hydrogen donor itself also has such effects, but the amine-based hydrogen donor is consumed due to the interaction with the aforementioned diimidazole-based compound of the main component of the (C) photopolymerization initiator, so the amine The hydrogen donor itself is actually in accordance with the Chinese National Standard (CNS) A4 specification (2 丨 〇 X 297 mm) for this paper size. _ 29-Printed by the Intellectual Property Bureau Employee Consumer Cooperatives of the Ministry of Economic Affairs 43 44 2 2 i A7 A7 _____B7 _Fifth, the description of the invention cut) does not show the aforementioned effect. (E) The organic amine-based compound is preferably an aliphatic amine or a phenyl-containing amine. Examples of the aliphatic amine include n-propylamine, isopropylamine, n-butylamine, isobutylamine, second butylamine, third butylamine, n-pentylamine, n-hexylamine, n-heptylamine, n-octylamine, and n-nonylamine. , N-decylamine, n-undecylamine, n-dodecylamine, cyclohexylamine, o-methylcyclohexylamine, m-methylcyclohexylamine, p-methylcyclohexyl, o-ethylcyclohexylamine, Mono (cyclo) alkylamines such as m-ethylcyclohexylamine, p-ethylcyclohexylamine; methylethylamine, diethylamine, methyl-n-propylamine, ethyl-n-propylamine, di-n-propylamine, diiso Propylamine, di-n-butylamine, diisobutylamine, second-second butylamine, second-third butylamine, di-n-pentylamine, di-n-hexylamine, methylcyclohexylamine, ethylcyclohexylamine, dicyclohexylamine, etc. Bis (cyclo) alkylamines; dimethylethylamine, methyldiethylamine, triethylamine, dimethyl-n-propylamine, diethyl-n-propylamine, methyl-di-n-propylamine, ethyl-di-n-propylamine, tris N-propylamine, triisopropylamine, tri-n-butylamine, triisobutylamine, tri-second butylamine, tri-third butylamine, tri-n-pentylamine, tri-n-hexylamine, dimethylcyclohexylamine, diethylcyclohexyl Amine, methyldicyclohexylamine, ethyl Tri (cyclo) alkylamines such as cyclohexylamine, tricycloethylamine, etc .; 2-aminoethanol, 3-amino-1-propanol, 1-amino-2 propanol, 4-amino-1 Mono (cyclo) alkanolamines such as monobutanol, 5-amino-1, 1-pentyl, 6-amino-1, 1-hexanol, 4-monoamino-1, 1-cyclohexanol; diethanolamine, di-n-propyl Alcoholamine, diisopropanolamine, di-n-butanolamine, diisobutanolamine, di-n-pentanolamine, di-n-ethanolamine, bis (4-cyclohexanol ----- ^ --- r-- -¾ ------ IT--r ----- child (Please read the notes on the back before filling this page) This paper size applies to Chinese national standards (CNS > A4 specification (210X297))- 30- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 3 4 4 · 2 2 Two: A7 B7____ V. Invention Description (28)) amines and other bis (cyclo) alkanolamines; triethanolamine, tri-n-propyl Tris (cyclo) alkanolamines such as alcoholamine, triisopropanolamine, tri-n-butanolamine, triisobutanolamine, tri-n-pentanolamine, tri-n-hexanolamine, tris (4-cyclohexanol) amine, etc. Class; 3-amino-1,2-propanediol, 2-amino-1,3-propanediol '4 monoamino-1,2-butane Diol'4-amino-1'3-butanediol, 4-amino-1,2-cyclohexanediol, 4-amino-1,3-cyclohexanediol, 3-dimethylamine —Amine groups such as —1,2-propanediol, 3-diethylamino-1,2-propanediol, 2-dimethylamino-1,3-propanediol, 2-diethylamino-1,3-propanediol ( Ring) alkanediols; 1-aminocyclopentanemethanol '4 monoaminocyclopentanemethanol, 1 monoaminocyclohexanemethanol, 4-aminocyclohexanemethanol, 4-dimethylamine Amine-containing cycloalkanes such as cyclopentanemethanol, 4-diethylaminocyclopentanemethanol, 4-dimethylaminocyclohexanemethanol, 4-diethylaminocyclohexanemethanol / 3 — Alanine, 2-aminobutyric acid, 3-aminobutyric acid, 4-monoaminobutyric acid, 2-aminoisobutyric acid, 3-aminoisobutyric acid, 2-aminovaleric acid, 5-amine Aminocarboxylic acids such as valproic acid, 6-aminohexanoic acid, 1-aminocyclopropanecarboxylic acid, 1-aminocyclohexanecarboxylic acid, 4-aminocyclohexanecarboxylic acid, and the like. Examples of the phenyl-containing amine include a compound in which an amine group is directly bonded to a phenyl group, and an amine group is a compound in which a phenyl group is bonded to a phenyl group through a divalent bonding group. Examples of phenyl-containing amines can be listed ---- ^ --- ί --- # ------, ιτ-: ----- thousand — {Please read the notes on the back before filling (This page) The paper size is in accordance with Chinese National Standard (CNS) A4 specification (2 丨 〇 X 297 mm) _ 31-^ 34422¾ A7 B7 V. Description of the invention Bisaniline, o-methylaniline 'm-methylaniline , P-methylaniline, p-ethylaniline, p-n-propylaniline 'p-isopropylaniline p-n-butylaniline, p-tributylaniline, 1-naphthylamine, 2-naphthylamine Aromatic amines such as N, N-dimethylaniline, N, N-diethylaniline, p-methyl-N'N-dimethylaniline; o-aminobenzyl alcohol, m-amine Amino benzyl alcohols such as benzyl alcohol, p-aminobenzyl alcohol, p-dimethylaminobenzyl alcohol, p-diethylaminobenzyl alcohol, etc .; o-aminophenol, m-aminophenol, p-amine Aminophenols such as p-dimethylaminophenol, p-dimethylaminophenol, p-diethylaminophenol, etc .: m-aminobenzoic acid, p-aminobenzoic acid, p-dimethylaminobenzoic acid, p-one Aminobenzoic acid (derivatives) such as diethylaminobenzoic acid Wait. Among these (E) organic amine-based compounds, from the viewpoint of the solubility of the solvent to be described later, and the prevention of texture contamination and residual film on the substrate of the unexposed portion or the light-shielding layer, the aliphatic amine is mono (cyclo) alkane Alcohol amines and amine (cyclic) alkanediols are preferred, and especially 2-aminoethanol, 3-amino-1 monopropanol, 5-amino-1 monopentanol, 3-amino -1,2-propanediol, 2-amino-1'3-propanediol, 4-monoamino-1'2-butanediol and the like are preferred. Further, phenyl-containing amines are preferably aminophenols, and particularly, o-aminophenylhydrazone, m-aminophenylbenzene, and p-aminophenylbenzene are preferred. In the present invention, the (E) organic amine-based compound may be used alone or in combination of two or more kinds. The amount of the (E) organic amine-based compound used in the present invention is generally 0.001 to 1 with respect to the entire radiation-sensitive composition. 5 parts by weight 'Better' This paper is sized according to Chinese National Standard (CNS) A4 (21〇 > < 297 mm) -32-I ---- ^ -------- pack --- --- Order-^ ----- line- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 434422 ^ A7 B7___ 5. Details of the invention) 0 01 ~ 10% by weight. At this time, if the amount of the organic amine compound (E) is less than 0.01% by weight, the suppression effect of the mask attachment or the improvement effect of the formed pixels on the adhesion between the substrate and the light-shielding layer is reduced. On the other hand, if it exceeds 15% by weight, the adhesion to the substrate on which the pixels have been formed tends to decrease. Additives The radiation-sensitive composition for a tinsel of the present invention may contain various additives as necessary. The additive is a radioactive composition for color filters, which further improves the dissolution characteristics of the alkaline developing solution, and further exhibits an inhibitory effect on the residue of undissolved matter after development, and organic acids and the like are mentioned. One organic acid The aforementioned organic acid is preferably an aliphatic carboxylic acid or a phenyl-containing carboxylic acid having one or more carboxyl groups in the molecule and having a molecular weight of 1 '00 or less. Examples of the aforementioned aliphatic carboxylic acids can be printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) Formic acid, acetic acid, propionic acid, butyric acid, valeric acid, pivalic acid, Aliphatic monocarboxylic acids such as acids, diethylacetic acid, heptanoic acid, caprylic acid; oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid Acid, glutaric acid, methylmalonic acid, ethylmalonic acid, dimethylmalonic acid, methylsuccinic acid, tetramethylsuccinic acid, cyclohexane dicarboxylic acid, itaconic acid, citraconic acid , Maleic acid, fumaric acid, mesaconic acid, etc .; aliphatic dicarboxylic acids; glycerin, propylene-1, 3 — This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -33 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 434422 ^ A7 __B7_ V. Description of the Invention ⑸) Tricarboxylic acids, camphor tricarboxylic acids and other aliphatic tricarboxylic acids. Examples of the phenyl-containing carboxylic acid include a compound in which a carboxyl group is directly bonded to a phenyl group, and a compound in which a carboxyl group is bonded to a phenyl group through a divalent bonding group. Examples of carboxylic acids containing phenyl include aromatic monocarboxylic acids such as benzoic acid, toluic acid, humic acid, dimethylbenzoic acid, and lylinic acid; phthalic acid, isophthalic acid, terephthalic acid, and the like Aromatic dicarboxylic acids > Trivalent or higher aromatic polycarboxylic acids, such as pyromellitic acid, trimesic acid, trimellitic acid, trimellitic acid, etc., and phenylacetic acid, hydrogenated atropic acid, hydrogenated cinnamon Acid, bitter almond acid, phenylsuccinic acid, atropic acid, cinnamic acid, cinnamic acid, cumyl acid, umbellic acid and the like. Among these organic acids, from the viewpoint of alkali solubility and the solubility of solvents to be described later, to prevent texture contamination and residual film on the substrate of the unexposed portion and the light-shielding layer, the aliphatic carboxylic acid is an aliphatic dicarboxylic acid. Carboxylic acids are preferred, and malonic acid, adipic acid, itaconic acid, citraconic acid, fumaric acid, mesaconic acid and the like are particularly preferred. The phenyl-containing carboxylic acid is preferably an aromatic dicarboxylic acid, and particularly preferably phthalic acid. The amount of the organic acid used is usually 15% by weight or less, and preferably 10% by weight or less, based on the entire radioactive composition. In this case, if the amount of the organic acid used exceeds 15% by weight, the adhesiveness of the substrate on which the pixels are formed tends to decrease. I ---- ^ ------- install ------ order-^ ---- line- (please read the precautions on the back first and then fill out this page) This paper size is applicable to China Standard rate (CNS) A4 specification (210X297 mm) _ 34-Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 4 ^ 4422¾ A7 _B7__ V. Description of the invention) In addition, additives other than the foregoing include copper-titanium-cyanine derivatives Dispersing additives such as blue pigment derivatives and yellow pigment derivatives; fillers for glass and alumina; polyvinyl alcohol, polyethylene glycol monoalkyl ethers, poly (fluoroalkyl acrylates), etc. Polymer compounds: non-ionic, cationic, anionic surfactants, etc .; vinyltrimethoxysilane, vinyltriethoxysilane, vinyltri (2-methoxyethoxy) silane, N — (2-aminoethyl) -3—aminopropylmethyldimethoxysilane, N— (2-aminoethyl) —3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxy Silane, 3-glycidyloxypropyltrimethoxysilane, 3-glycidyloxypropylmethyldimethoxysilane, 2- (3,4-epoxycyclohexane ) Ethyltrimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-hydrothiopropyl Adhesion promoters such as trimethoxysilane; 2,2 > -Thiobis (4-methyl-6-tert-butylphenol), 2 '6-di-tert-butylphenol and other antioxidants ; 2— (3-Third-butyl-5—methyl-2—hydroxyphenyl) —5-chlorobenzotriazole, alkoxybenzophenone and other ultraviolet absorbers; Agglutinating agent; 1 '1 < —Thermal radicals of azobis (cyclohexane-1 1nitrile), 2-phenylazo-4—methoxy-2,4-dimethylvaleronitrile, etc. occur Agent; this paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) _ 35--------- Γ —-- € ------ il ------ -千 — (Please read the notes on the back before filling in this page)

434422tJ A7 B7 五、發明説明鉍） 下述式（4 )所示之化合物、 0. H2C\ /CH2 ... (4)/ \ C2H5 CH2 -0Η 下述式（5 )所示之化合物、 \h; C(H5'CH2 -o-ch2 —{^>—ch2 一0—C々/C2H5 / ；ch2 ...(5) I------^----裝-I (請先閱讀背面之注意事項再填寫本頁) 訂 等之氧雜環丁烷系化合物等 經濟部智慧財產局員4消費合作社印製 溶劑 本發明之濾色器用感放射線性組成物爲以（A )著色 劑、（B )鹼可溶性樹脂、（C )多官能單體、（D )含 三啡系化合物之光聚合引發劑、及（E )有機胺基化合物 作爲必須成分，且視需要可含有前述添加劑成分，較佳配 合溶劑調製成液狀組成物。 前述溶劑只要可將構成感放射線性組成物之（A )〜 (E )成分及添加劑成分予以分散或溶解，且不與此些成 一線丨！ 本紙浪尺度適用中囷國家標準（CNS ) A4規格（210 X 297公釐）-30 - A7 B7 4344 2 2 五、發明説明（34 ) 分反應，並具有適度之揮發性者，則可適當選擇使用。 此類溶劑可列舉例如 乙二醇單甲醇、乙二醇單乙醚、乙二醇單正丙醚、乙 二醇單正丁醚、二甘醇單甲醚、二甘醇單乙醚、二甘醇單 正丙醚、二甘醇單正丁醚、三甘醇單甲醚、三甘醇單乙醚 、丙二醇單甲醚、丙二醇單乙醚、丙二醇單正丙醚、丙二 醇單丁醚、二丙二醇單甲醚、二丙二醇單乙醚、二丙二醇 單正丙醚、二丙二醇單正丁醚.三丙二醇單甲醚、.三丙二 醇單乙醚等之（聚）伸烷基二元醇單烷醚類； 乙二醇單甲醚醋酸酯、乙二醇單乙醚醋酸酯、二甘醇 單甲醚醋酸酯、二甘醇單乙醚醋酸酯、丙二醇單甲醚醋酸 酯、丙二醇單乙醚醋酸酯等之（聚）伸烷基二元醇單烷醚 醋酸酯類；二甘醇二甲醚、二甘醇甲基乙醚、二甘醇二乙 醚、四氫呋喃等之其他醚類； 甲基乙基嗣、環乙酮、2_庚酮、3-庚酮等之酮類 2-羥基丙酸甲酯、2-羥基丙酸乙酯等之乳酸烷酯 類； 2—羥基一2—甲基丙酸乙酯、3—甲氧基丙酸甲酯 、3—甲氧基丙酸乙酯、3—乙氧基丙酸甲酯、3—乙氧 基丙酸乙酯、乙氧基醋酸乙酯、羥基醋酸乙酯、2 -羥基 _3—甲基丁酸甲酯、3-甲基一3—甲氧基丁基醋酸酯 、3 —甲基一 3 —甲氧基丁基丙酸酯、醋酸乙酯、醋酸正 丙酯、醋酸異丙酯、醋酸正丁酯、醋酸異丁酯、甲酸正戊 本紙張尺度適用中國國家梯準（CNS ) A4規格（210X297公釐）_ 37 - Ί------„----装-----—^--r-----線 — (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 A7 __B7 五、發明説明（35 ) 酯、醋酸異戊酯 '丙酸正丁酯、丁酸乙酯、丁酸正丙酯、 丁酸異丙酯、丁酸正丁酯 '丙酮酸甲酯、丙酮酸乙酯、丙 酮酸正丙酯、乙醯醋酸甲酯、乙醯醋酸、乙酯、2一氧基 丁酸乙酯等之其他酯類： -甲苯、二甲苯等之芳香族烴類； N-甲基吡咯烷酮、N，N —二甲基甲醯胺、n，N -二甲基乙醯胺等之醯胺類等。 此些溶劑中’由溶解性、顏料分散性、塗佈性等觀點 而言，則以丙二醇單甲醇、乙二醇單甲醚醋酸酯、丙二醇 、單甲醚醋酸酯、丙二醇單乙醇醋酸酯、二甘醇二甲醚、 二甘醇甲基乙醚、環己環、2 —庚酮、3 -庚酮、2_羥 基丙酸乙酯、3—甲氧基丙酸乙酯、3—乙氧基丙酸甲酯 、3 —乙氧基丙酸乙酯、3 —甲基一 3 —甲氧基丁基丙酸 酯、醋酸正丁酯、醋酸異丁酯、甲酸正戊酯、醋酸異戊酯 、丙酸正丁酯、丁酸乙酯、丁酸異丙酯、丁酸正丁酯、丙 酮酸乙酯等爲佳。 前述溶劑可單獨或混合使用二種以上。 更且，前述溶劑亦可併用苄基乙醚、二正己醚、丙酮 基丙酮、異佛爾酮、乙酸、癸酸、1一辛醇、1一壬醇、 苄醇、醋酸苄酯、苯甲酸乙酯、草酸二乙酯、順丁烯二酸 二乙酯、r-丁丙酯、碳酸乙烯酯、碳酸丙烯酯、乙二醇 單苯醚醋酸酯等之高沸點溶劑。 前述高沸點溶劑可單獨或混合使用二種以上。 溶劑之使用量並無特別特定，但由所得感放射線性組 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）_ 38 - I----TL----效------1T--r-----線丨 I (請先閱讀背面之注意事項再填寫本頁) 434422 經濟部智慧財產局8工消費合作社印製 Α7 Β7五、發明説明（3ό ) 成物之塗佈性，安定性等觀點而言，則期望除去液狀組成 物溶劑之各成分合計濃度較佳爲5〜5 0重量％，更佳爲 1 0〜40重量％之份量。 濾色器之形成方法 其次’說明關於使用第一發明之濾色器用感放射線性 組成物，形成第二發明濾色器之方法。 首先，於基板之表面上，視需要，以區隔畫素形成部 分地形成遮光層，並於此基板上，例如將分散紅色顏料之 感放射線性組成物的液狀組成物予以塗佈後，進行預烘烤 令溶劑蒸發，形成塗膜。其次，將此塗膜透過光罩物進行 曝光後，使用鹼性顯像液予以顯像，並溶解除去塗膜的末 曝光部，其後經由後烘烤，則可形成紅色之畫素圖型爲以 指定序列配置之畫素排列。 其次，使用分散綠色或藍色顏料之各感放射線性組成 物的液狀組成物 '同前述處理，進行各液狀組成物之塗佈 、預烘烤、曝光、顯像及後烘烤，於同一基板上依序形成 綠色之畫素排列及藍色之畫素排列，則可取得於基板上配 置紅色、綠色及藍色三原色畫素排列的濾色器。 形成濾色器時所使用之基板，可列舉例如玻璃、聚矽 氧烷、聚碳酸酯、聚酯、芳香族聚醯胺、聚醯胺亞胺、聚 醯亞胺等。對於此些基板，視所需’亦可施行以矽烷偶合 劑等之藥品處理、電漿處理、離子電鍍、濺鍍、氣相反應 法、真空澱積等之適當的前處理。 本紙張尺度適用中國國家標準（CMS ) A4^i格（210X297公釐)-39- (請先閲讀背面之注意事項再填寫本頁) -裝 訂 線— ！ 434422 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(37 ) 將感放射線性組成物的液狀組成物於基板上塗佈時， 可採用迴轉塗佈、流涎塗佈、輥塗佈法等之適當的塗佈法 0 塗佈厚度於乾燥後之膜厚，通常爲〇 . 1〜l〇#m ，較佳爲0 · 2〜8 . 0#m，更佳爲〇 . 2〜6 . 0 U m 。 製作濾色器時所使用之放射線，可使用例如可見光線 、紫外線、遠紫外線、電子射線、X射線等，且以波長爲 1 9 0〜4 5 0 nm範圍之放射線爲佳。 放射線之曝光量較佳爲1〜1，OOOmJ/cm2左 右。 又，前述之鹼性顯像液例如以碳酸鈉、氫氧化鈉、氫 氧化鉀、氫氧化四甲基銨、膽鹼、1，8-二吖雙環一〔 5.4.0〕— 7 -十一碳烯、1，5 —二吖雙環-〔 4 . 3 . 0〕一 5 -壬烯等之水溶液爲佳。 於前述之鹼性顯像液中，亦可適量添加例如甲醇、乙 醇等之水溶性有機溶劑和界面活性劑等。尙，鹼性顯像後 通常爲予以水洗。 顯像處理法可應用淋洗顯像法、噴霧顯像法、浸漬顯 像法、漿葉（裝入液體）顯像法等，且顯像條件以常溫下 5〜3 0 0秒爲佳。 如此所形成之第二發明濾色器，例如極有用於穿透型 或反射型彩色液晶顯示裝置、彩色照像管元件、彩色感應 器等。 本紙張尺度適用中國國家梯準（CNS ) A4規格（210X297公釐）-40 - I----^------装------Ϊ7--Γ-----線I (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 434422 ^ A7 _____B7五、發明説明（38 ) 〔發明之實施形態〕 第一發明之濾色器用感放射線性組成物爲以（A )著 色劑、（B )鹼可溶性樹脂、（C )多官能單體、（D ) 含三畊系化合物之光聚合引發劑、及（E )有機胺基化合 物作爲必須成分，但若具體例示較佳之組成物，則爲下述 (i )〜（v )。 (i )含有（B)鹼可溶性樹脂爲含羧基共聚物（I )之濾色器用感放射線性組成物。 (i i )如前述（i )之濾色器用感放射線性組成物 ，其中（C )多官能性單體爲由三丙烯酸三羥甲基丙烷酯 、三丙烯酸季戊四醇酯及六丙烯酸二季戊四醇酯群中選出 至少一種。 (i i i )如前述（i )或（i i )之濾色器用感放 射線性組成物，其中（D )光聚合引發劑爲再含有至少一 種選自己乙醯苯系化合物及二咪唑系化合物。 (i v )如前述（i )、 （ i i )或（i i i )之濾 色器用感放射線性組成物，其中（E )有機胺基化合物爲 由單（環）烷醇胺類、胺基（環）烷二醇類及胺基苯酚類 群中選出至少一種，且再佳爲含有由2-胺基乙醇、3-胺基一 1一丙醇、5_胺基—1 一戊醇、3 —胺基_1， 2 —丙二_、2_胺基—1，3 -丙一醇、4 —胺基—1 ，2 —丁二醇、鄰一胺基苯酚、間一胺基苯酚及對-胺基 苯酚群中選出至少一種。 (V )如前述（i )、 （ i i )、 （ i i i )或 I---------¾------訂-------線~ (請先閲讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準（CNS ) A4规格（21〇Χ 297公釐）-4卜 經濟部智慧財產局員工消費合作社印製 4 3 4 4 2 彡缝 A7五、發明説明鉍） (v i )之濾色器用感放射線性組成物，其中（A)著色 劑爲含有機顏料。 又 > 第二發明之較佳的濾色器爲 (vi)具有由前述（i)、 （ii)、 （iii) 、（i v)或（V)之濾色器用感放射線性組成物所形成 之畫素的濾色器。 以下，列舉實施例更具體說明本發明之實施形態，但 >本發明並不被限定於下述實施例。 〔實施例〕 實施例1 將作爲（A )著色劑之C . I .顏料紅1 7 7和 C . I .顏料紅224之65/35 (重量比）混合物 8 0重量份，作爲（B )鹼可溶性樹脂之甲基丙烯酸/苯 乙烯/甲基丙烯酸苄酯/單甲基丙烯酸甘油酯/N—苯基 馬來醯亞胺共聚物（共聚重量比=1 5/1 5/3 5/ 10/25，Mw=30，〇〇〇、Mn=l〇，〇〇◦ )7 0重量份，作爲（C )多官能性單體之六丙烯酸二季 ____ -——....... 戊四醇酯8 0重量份，作爲（D)光聚合引發劑之三哄系 一—、'wr:: 化合物（2 ) 9重量份，作爲（E )有機胺基化合物之2 -胺基乙醇2重量份，及作爲溶劑之丙二醇單甲醚醋酸醋 及環己酮之9 5/ 5 (重量比）混合物1，000重量份 混合，調製感放射線性組成物的液狀組成物（R 1 )。 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）~~-42- " (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 4 3 44 2 2^ A7 _B7_五、發明説明紕） <濾色器之形成> 將液狀組成物（R 1 )，於表面形成防止鈉離子溶出 之S i 〇2膜之蘇打玻璃基板表面上，使用旋塗器予以塗佈 後，於8 0°C之乾淨烤爐內進行1 0分鐘預烘烤，形成膜 厚1·8ym之塗膜。 其次，將此基板於室溫中冷却後，使用高壓水銀燈， 透過光覃物，對塗膜以含有365nm、 405nm及 4 3 6 nm各波長之紫外線，以5 Om J/cm2之曝光量 予以曝光。其後，將此基板於2 3 °C之0 . 0 4重量％氫 氧化鉀水溶液中浸漬1分鐘，顯像。其後，將基板以超純 水洗淨、風乾後，於2 0 〇°C之乾淨烤爐內進行3 0分鐘 後烘烤，於基板上形成紅色條狀之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 將液狀組成物（R1)，於表面形成防止鈉離子溶出 之S i 0 2膜之1 5公分X 1 5公分大小之蘇打玻璃基板表 面上，使用旋塗器予以塗佈後，於8 0°C之乾淨烤爐內進 行1 0分鐘預烘烤，製作形成膜厚1 . 8 /2 m塗膜之塗佈 基板（1 )。另外，沿著前述蘇打玻璃基板單側表面之外 周部，貼上寬度5mm，厚度4 3 之兩面粘接膠帶（ 商品名IC Tape Red、ITSUMI & 1C (株）製），製作對向 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）_ 43 - —7 Γ---焚------訂--J'--,--線-f (請先閣讀背面之注意事項再填寫本頁) 434422麵 A7 經濟部智慧財產局員工消費合作杜印製 B7五、發明説明⑷） 基板（1 )。 將塗佈基板（1 )與對向基板（1 )，以塗佈基板（ 1 )之塗膜面爲內側地，以前述兩面粘接膠帶予以貼合後 ，通過對向基板（1)，以150mJ/cm2之曝光量進 行曝光，一邊僅交換塗佈基板（1 ) 一邊重覆此操作1 0 回。其後，取出對向基板（1 )並且使用投光器進行觀察 時，於此對向基板（1 )上並未察見附著物。 實施例2 將作爲（A)著色劑之C . I ·顏料紅177和 C.I.顏料黃83之80/20(重量比）混合物65 重量份，作爲（B )鹼可溶性樹脂之甲基丙烯酸/苯乙烯 /甲基丙烯酸苄酯/N -苯基馬來醯亞胺共聚物（共聚重 量比=20/18 . 8/30/31 · 2，Mw = 45 ，000，Mn = 18 ·〇00) 60 重量份，作爲 (C )多官能性單體之六丙烯酸二季戊四醇酯9 0重量份 ，作爲（D )光聚合引發劑之三畊系化合物（3 ) 5重量 份，2 —苄基—2_二甲胺基-1— (4 —嗎啉苯基）丁 酮一 1以20重量份，2，2 < -雙（2 ’ 4-二氯苯基 )4，，5，5 四苯基一1 ，2 / -二咪唑 5 重 量份，及作爲氫供給體之氫硫基苯並噻唑2.5重量 份和4，4>_雙（二乙胺基）二苯酮5重量份，作爲（ Ε )有機胺基化合物之3 _胺基一 1 一丙醇5重量份，及 作爲溶劑之丙二醇單甲醚醋酸酯1 ’ 〇〇〇重量份混合， 本^張尺度逋用中國國家標隼（CNS ) Α4規格（210'〆297公釐)~「44- '~" (請先閱讀背面之注意事項再填寫本頁) .裝 訂 線I ! 4 3442 2 ^ A7 __ B7五、發明説明) 調製感放射線性組成物的液狀組成物（R 2 )。 其次，除了使用液狀組成物（R 2 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成紅色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時*於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（R2)代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（2 )及對向基 板（2)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（2 )上並未察見附著物 (請先閲讀背面之注意事項再填寫本育) 經濟部智慧財產局員工消費合作社印製 實施例3 將作爲（A)著色劑之C.I.顏料紅254和 c · I .顏料黃139之75/25 (重量比）混合物 7 5重量份，作爲（B )鹼可溶性樹脂之甲基丙烯酸/ω 一羧基聚丁丙酯單丙烯酸酸/苯乙烯/甲基丙烯酸苄酯/ 單甲基丙烯酸甘油酯/Ν —苯基馬來醯亞胺共聚物（共聚 重量比=15/10/11.3/35/10/187 ，Mw=40，000，Μη = 20 . 000) 75 重量 份，作爲（C )多官能性單體之六丙烯酸二季戊四醇酯 本紙張尺度適用中國國家標準（CNS ) Α4規格（2] 0 X 297公羞）-45- 經濟部智慧財產局員工消費合作社印製 434422建 A7 ____B7_ _五、發明説明（43 ) 7 5重量份，作爲（D )光聚合引發劑之三畊系化合物（ 2) 8重量份，苄基_2 —二甲胺基一 1 一（4 一嗎 啉苯基）丁酮一 1以10重量份，2，2 — -雙（2，4 —一氯本基）4，4 ，5，5 一一四苯基一 1，2 - 二咪唑3重量份，及作爲氫供給體之α -氫硫基苯並噻唑 1 · 5重量份和4，4 -—雙（二乙胺基）二苯酮5重量 份’作爲（Ε )有機胺基化合物之對一胺基苯酚1 0重量 份’及作爲溶劑之丙二醇單甲醚醋酸酯1 ，〇〇〇重量份 混合，調製感放射線性組成物的液狀組成物（R3)。 其次，除了使用液狀組成物（R 3 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成紅色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（R 3 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（3 )及對向基 板（3)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（3 )上並未察見附著物 —Γ---------裝------訂-------線— [ (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨0 X 297公釐）-46 - 經濟部智慧財產苟員工消費合作社印製 434422^ A7 _B7_五、發明説明W ) 實施例4 將作爲（A)著色劑之C‘ I ，顏料綠3 6和 C.I.顏料黃150之70/30 (重量比）混合物 9 0重量份，作爲（B )鹼可溶性樹脂之甲基丙稀酸/苯 乙烯/甲基丙烯酸苄酯/單甲基丙烯酸甘油酯/N _苯基 馬來醯亞胺共聚物（共聚重量比二1 5/1 5/3 5/ 10/25 -Mw=35 - 〇〇〇 'Mn-17 500 )6 0重量份，作爲（C )多官能性單體之六丙烯酸二季 戊四醇酯9 0重量份，作爲（D )光聚合引發劑之三畊系 化合物（2)10重量份及2-苄基一2_二甲胺基一1 一（4 一嗎啉苯基）丁酮一 1以1 5重量份，作爲（E) 有機胺基化合物之5-胺基一1-戊醇7. 5重量份’及 作爲溶劑之3 -乙氧基丙烯酸乙酯1 ’ 〇〇〇重量份混合 ，調製感放射線性組成物的液狀組成物（G1)。 其次，除了使用液狀組成物（G 1 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成綠色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（G 1 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（4 )及對向基 . n^i —ml ^^^1 ^^^1 - - I ϋ - - *一#>n^r- ^^^1 1^1^1 ^^1 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）_ 47 - A7 ^34422^ __ B7_ 五、發明説明細） 板（4)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（4 )上並未察見附著物434422tJ A7 B7 V. Description of the invention Bismuth) The compound represented by the following formula (4), 0. H2C \ / CH2 ... (4) / \ C2H5 CH2 -0Η The compound represented by the following formula (5), \ h; C (H5'CH2 -o-ch2 — {^ > —ch2 a 0—C々 / C2H5 /; ch2 ... (5) I ------ ^ ---- 装 -I ( Please read the notes on the back before filling this page.) Ordered oxetane-based compounds, etc. Member of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 Consumption cooperatives Printed solvents The radiation-sensitive composition for color filters of the present invention is (A) A colorant, (B) an alkali-soluble resin, (C) a polyfunctional monomer, (D) a photopolymerization initiator containing a trimorphine compound, and (E) an organic amine-based compound as essential components, and may contain the foregoing as necessary The additive component is preferably mixed with a solvent to prepare a liquid composition. As long as the solvent can disperse or dissolve the components (A) to (E) and additive components constituting the radiation-sensitive composition, and do not form a line with these 丨The scale of this paper is applicable to the China National Standard (CNS) A4 specification (210 X 297 mm) -30-A7 B7 4344 2 2 V. Description of the invention (34) Those with moderate volatility can be appropriately selected for use. Examples of such solvents include ethylene glycol monomethanol, ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether, ethylene glycol mono-n-butyl ether, and diethylene glycol. Monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, diethylene glycol mono-n-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monoethyl ether N-propyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-n-butyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether, etc. (poly) Alkylene glycol monoalkane ethers; ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate (Poly) alkylene glycol monoalkyl ether acetates such as esters, propylene glycol monoethyl ether acetate, and other ethers such as diglyme, diethylene glycol methyl ether, diethylene glycol diethyl ether, and tetrahydrofuran Ketones; methyl ethyl hydrazone, cycloethyl ketone, 2-heptanone, 3-heptanone and other ketones 2-hydroxy Alkyl lactates such as methyl propionate, ethyl 2-hydroxypropionate, etc .; 2-hydroxy-2-methyl propionate, 3-methoxy propionate methyl, 3-methoxy propionate ethyl Esters, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl ethoxyacetate, ethyl glycolate, 2-hydroxy-3-methylbutyrate, 3-methyl Methyl 3-methoxybutyl acetate, 3-methyl 3-methoxybutyl propionate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate Ester and n-ammonium formic acid paper standards are applicable to China National Standard (CNS) A4 (210X297 mm) _ 37-Ί ------ „---- Installation ------- ^-r- ---- Line — (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Ministry of Economic Affairs Intellectual Property Bureau Printed by A7 __B7 V. Invention Description (35) Ester, Isoamyl acetate 'n-butyl propionate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate' methylpyruvate, ethyl pyruvate, n-propyl pyruvate, Acetyl methyl acetate, ethyl acetate , Ethyl ester, ethyl 2-monooxybutyrate, etc .:-aromatic hydrocarbons such as toluene and xylene; N-methylpyrrolidone, N, N -dimethylformamide, n, N -Amidines such as dimethylacetamide. Among these solvents, from the viewpoints of solubility, pigment dispersibility, and coatability, propylene glycol monomethanol, ethylene glycol monomethyl ether acetate, propylene glycol, monomethyl ether acetate, propylene glycol monoethanol acetate, Diethylene glycol dimethyl ether, diethylene glycol methyl ether, cyclohexyl ring, 2-heptanone, 3-heptanone, ethyl 2-hydroxypropionate, ethyl 3-methoxypropionate, 3-ethoxy Methyl propionate, ethyl 3-ethoxypropionate, 3-methyl-3-methoxybutyl propionate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate Esters, n-butyl propionate, ethyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl pyruvate and the like are preferred. These solvents may be used alone or in combination of two or more. Furthermore, the aforementioned solvents may be used in combination with benzyl ether, di-n-hexyl ether, acetone acetone, isophorone, acetic acid, capric acid, 1-octanol, 1-nonanol, benzyl alcohol, benzyl acetate, and ethyl benzoate. Ester, diethyl oxalate, diethyl maleate, r-butyl propyl, ethylene carbonate, propylene carbonate, ethylene glycol monophenyl ether acetate and other high boiling point solvents. The aforementioned high boiling point solvents may be used alone or in combination of two or more. The amount of solvent used is not particularly specific, but the paper size obtained from the radiation-sensitive group of paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 38-I ---- TL ---- Effect --- --- 1T--r ----- line 丨 I (Please read the notes on the back before filling this page) 434422 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs 8 Industrial Consumer Cooperative Α7 Β7 V. Description of the invention (3) From the viewpoints of coating properties, stability, and the like, it is desirable that the total concentration of each component excluding the solvent of the liquid composition is 5 to 50% by weight, and more preferably 10 to 40% by weight. Method for forming color filter Next, a method for forming the color filter of the second invention by using the radiation-sensitive composition for a color filter of the first invention will be described. First, on the surface of the substrate, if necessary, a light-shielding layer is partially formed by segmenting pixels, and on this substrate, for example, a liquid composition in which a radiation-sensitive composition in which a red pigment is dispersed is applied, Pre-baking is performed to evaporate the solvent to form a coating film. Next, after this coating film is exposed through a photomask, it is developed using an alkaline developer, and the unexposed part of the coating film is dissolved and removed. After that, a red pixel pattern can be formed by post-baking. Arranges pixels in a specified sequence. Next, using the liquid composition of each radiation-sensitive composition in which green or blue pigments are dispersed, the coating, pre-baking, exposure, development, and post-baking of each liquid composition are performed in the same manner as described above. By sequentially forming a green pixel arrangement and a blue pixel arrangement on the same substrate, a color filter in which the three primary color pixel arrangements of red, green and blue are arranged on the substrate can be obtained. Examples of the substrate used in forming the color filter include glass, polysiloxane, polycarbonate, polyester, aromatic polyimide, polyimide, polyimide, and the like. For these substrates, appropriate pretreatments such as chemical treatment with a silane coupling agent, plasma treatment, ion plating, sputtering, vapor phase reaction method, vacuum deposition, etc. may be performed as needed. This paper size applies the Chinese National Standard (CMS) A4 ^ i (210X297 mm) -39- (Please read the precautions on the back before filling this page)-Binding Line —! 434422 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (37) When the liquid composition of the radiation-sensitive composition is coated on the substrate, spin coating, drool coating, roll coating can be used. Appropriate coating method such as cloth method 0 Coating thickness after film thickness after drying, usually 0.1 ~ 10 # m, preferably 0 · 2 ~ 8. 0 # m, more preferably 0.2 ~ 6.0 Um. The radiation used in making the color filter may be, for example, visible rays, ultraviolet rays, far ultraviolet rays, electron rays, X-rays, and the like, and the radiation rays having a wavelength ranging from 190 to 450 nm are preferred. The amount of radiation exposure is preferably about 10,000 mJ / cm2. In addition, the aforementioned basic developing solution includes, for example, sodium carbonate, sodium hydroxide, potassium hydroxide, tetramethylammonium hydroxide, choline, 1,8-diazinebicyclic one [5.4.0]-7-11 Carbene, 1,5-diazinebicyclo- [4.3.0] -5-nonene and the like are preferred in aqueous solution. To the aforementioned basic developing solution, a suitable amount of a water-soluble organic solvent such as methanol, ethanol, and a surfactant may be added. Alas, it is usually washed with water after alkaline development. As the development method, leaching development method, spray development method, immersion development method, paddle leaf (filled with liquid) development method can be applied, and the development conditions are preferably 5 to 300 seconds at normal temperature. The color filter of the second invention thus formed is extremely useful for, for example, a transmissive or reflective color liquid crystal display device, a color picture tube element, a color sensor, and the like. This paper size is applicable to China National Standard Ladder Standard (CNS) A4 (210X297 mm) -40-I ---- ^ ------ installation ------ Ϊ7--Γ ----- line I (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 434422 ^ A7 _____B7 V. Description of the Invention (38) [Implementation Mode of the Invention] The first invention's color filter radiation The sexual composition requires (A) a coloring agent, (B) an alkali-soluble resin, (C) a polyfunctional monomer, (D) a photopolymerization initiator containing a tri-tillage compound, and (E) an organic amine-based compound as essential Components, but if a preferable composition is specifically exemplified, it is the following (i) to (v). (i) A radiation-sensitive composition for a color filter containing (B) an alkali-soluble resin as a carboxyl-containing copolymer (I). (ii) The radiation-sensitive composition for color filters as described in (i) above, wherein (C) the polyfunctional monomer is selected from the group consisting of trimethylolpropane triacrylate, pentaerythritol triacrylate, and dipentaerythritol hexaacrylate Pick at least one. (i i i) The radiation-sensitive composition for a color filter as described in (i) or (i i) above, wherein (D) the photopolymerization initiator further contains at least one selected from an acetophenone-based compound and a diimidazole-based compound. (iv) The radiation-sensitive composition for a color filter as described in (i), (ii), or (iii) above, wherein (E) the organic amine-based compound is composed of mono (cyclo) alkanolamines and amine (ring) At least one selected from the group of alkanediols and aminophenols, and further preferably contains 2-aminoethanol, 3-amine-1propanol, 5-amino-1pentyl alcohol, 3-amino group _1,2-propanediol, 2-amino-1,3-propanol, 4-amino-1,2-butanediol, o-aminophenol, m-aminophenol and p-amine At least one kind of phenol group is selected. (V) As mentioned in (i), (ii), (iii) or I --------- ¾ ------ Order ------- line ~ (Please read the Note: Please fill in this page again) This paper size applies Chinese National Standard (CNS) A4 specification (21〇 × 297 mm) -4 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 4 3 4 4 2 Quilted A7 5 2. Description of the Invention The radiation-sensitive composition for color filters of bismuth) (vi), wherein (A) the colorant is an organic pigment. Also, a preferred color filter of the second invention is (vi) having a radiation-sensitive composition for the color filter of (i), (ii), (iii), (iv) or (V). Pixel filters. Hereinafter, embodiments will be described more specifically with examples, but the present invention is not limited to the following examples. [Examples] In Example 1, 80 parts by weight of a 65/35 (weight ratio) mixture of C.I.Pigment Red 1 7 and C.I.Pigment Red 224 as (A) colorants were used as (B). Methacrylic acid / styrene / benzyl methacrylate / glyceryl monomethacrylate / N-phenylmaleimide imide copolymer (copolymerization weight ratio = 1 5/1 5/3 5/10 / 25, Mw = 30, 00, Mn = 10, 00), 70 parts by weight, as the (C) polyfunctional monomer of the sixth acrylic acid second quarter ____ -----....... 80 parts by weight of pentaerythritol ester, as the third part of (D) photopolymerization initiator, 9 parts by weight of 'wr :: compound (2), as 2-aminoethanol of (E) organic amine compound 2 parts by weight and 1,000 parts by weight of a mixture of propylene glycol monomethyl ether acetate and cyclohexanone 9 5/5 (weight ratio) to prepare a liquid composition (R 1) of a radiation-sensitive composition . This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ~~ -42- " (Please read the precautions on the back before filling this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives 4 3 44 2 2 ^ A7 _B7_ V. Description of the invention 纰) < Formation of color filter > A liquid glass composition (R 1) was formed on the surface of a soda glass substrate having a Si 〇2 film that prevents sodium ions from leaching out. After coating with a spin coater, pre-bake in a clean oven at 80 ° C for 10 minutes to form a coating film with a thickness of 1.8 μm. Next, after the substrate was cooled at room temperature, a high-pressure mercury lamp was used to transmit light to the coating film, and the coating film was exposed to ultraviolet light at a wavelength of 365 nm, 405 nm, and 4 3 6 nm with an exposure amount of 5 Om J / cm2. . Thereafter, this substrate was immersed in a 0.4% by weight potassium hydroxide aqueous solution at 2 ° C for 1 minute, and developed. Thereafter, the substrate was washed with ultrapure water, air-dried, and then baked in a clean oven at 200 ° C for 30 minutes, and a red strip-shaped color filter was formed on the substrate. When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of photomask attachments > A liquid composition (R1) was formed on the surface of a surface of a soda glass substrate having a size of S i 0 2 to prevent the dissolution of sodium ions. After the applicator was coated, it was pre-baked in a clean oven at 80 ° C for 10 minutes to produce a coated substrate (1) to form a coating film with a thickness of 1.8 / 2 m. In addition, a double-sided adhesive tape (trade name: IC Tape Red, ITSUMI & 1C, Inc.) with a width of 5 mm and a thickness of 4 3 was attached along the outer periphery of the one-side surface of the soda glass substrate to produce a facing paper. Zhang scale is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) _ 43-—7 Γ --- burning --- order --J '-,-line-f (please read first) Note on the back, please fill out this page again) 434422 side A7 Consumer Cooperation of Intellectual Property Bureau of Ministry of Economic Affairs Du printed B7 5. Description of invention 发明) Substrate (1). After the coated substrate (1) and the counter substrate (1) are coated with the coating film surface of the coated substrate (1) as the inner side, the aforementioned two-sided adhesive tapes are adhered, and then the counter substrate (1) is used to Expose at an exposure of 150mJ / cm2, repeat this operation 10 times while exchanging only the coated substrate (1). Thereafter, when the counter substrate (1) was taken out and observed using a light projector, no attachment was observed on the counter substrate (1). Example 2 65 parts by weight of an 80/20 (weight ratio) mixture of C.I. Pigment Red 177 and CI Pigment Yellow 83 as (A) colorant was used as (B) methacrylic acid / styrene as an alkali-soluble resin. / Benzyl methacrylate / N-phenylmaleimide copolymer (copolymerization weight ratio = 20/18. 8/30/31 · 2, Mw = 45,000, Mn = 18 · 00) 60 weight 90 parts by weight of dipentaerythritol hexaacrylate as a (C) polyfunctional monomer, and 5 parts by weight of a three-cult compound (3) as a (D) photopolymerization initiator, 2-benzyl-2-di Methylamino-1- (4-morpholinylphenyl) butanone-1 in 20 parts by weight of 2,2 < -bis (2'4-dichlorophenyl) 4,5,5 tetraphenyl-1 5 parts by weight of 1, 2 /-diimidazole, 2.5 parts by weight of hydrogenthiobenzothiazole as a hydrogen donor, and 5 parts by weight of 4,4 > -bis (diethylamino) benzophenone as (E) 5 parts by weight of 3-amine-1 propanol and 1 part by weight of propylene glycol monomethyl ether acetate as a solvent are used in the organic amine compound, and the Chinese standard (CNS) is used for this standard. Α4 Specification (210'〆297 (%) ~ 「44- '~ " (Please read the notes on the back before filling in this page). Gutter I! 4 3442 2 ^ A7 __ B7 V. Description of the invention) Modulate the liquid composition of the radiation-sensitive composition Next, except that the liquid composition (R 2) is used instead of the liquid composition (R 1), the same treatment as in Example 1 is performed to form a red stripe-shaped color filter on the substrate. Using an optical microscope When observing the obtained color filter, no residue and texture contamination were observed on the substrate of the unexposed portion, and the adhesion with the obtained pixel substrate was also excellent. ≪ Evaluation of mask attachments > A coating composition (R2) was used in place of the liquid composition (R1) in the same manner as in Example 1, and a coated substrate (2) and a counter substrate (2) were produced, and a photomask attachment was evaluated. As a result, No attachments were found on the removed opposing substrate (2) (please read the precautions on the back before filling in this education). Example 3 printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs will be used as (A) CI Pigment Red 254 and c · I. Pigment Yellow 139 75/25 (weight ratio) mixture 7 5 Quantities, (B) Alkali-soluble resins of methacrylic acid / ω monocarboxy polybutyl acrylate monoacrylic acid / styrene / benzyl methacrylate / glyceryl monomethacrylate / N-phenylmaleate Amine copolymer (copolymerization weight ratio = 15/10 / 11.3 / 35/10/187, Mw = 40,000, Mn = 20. 000) 75 parts by weight, as (C) a polyfunctional monomer, dipentaerythritol hexaacrylate The paper size of the ester applies to the Chinese National Standard (CNS) A4 specification (2) 0 X 297 public shame) -45- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 434422 A7 ____B7_ _V. Description of the invention (43) 7 5 Weight Parts, 8 parts by weight of the three-cooked compound (2) as the (D) photopolymerization initiator, and 10 parts by weight of benzyl-2-dimethylamino-1,1- (4-morpholinephenyl) butanone-1 3 parts by weight of 2,2,2-bis (2,4-monochlorobenzyl) 4,4,5,5-tetraphenyl-1,2-diimidazole, and α-hydrosulfide as a hydrogen donor 1.5 parts by weight of benzothiazole and 5 parts by weight of 4,4-bis (diethylamino) benzophenone 'as p-aminophenol of (E) organic amino compound 10 weight ', And propylene glycol monomethyl ether acetate solvent of 1 part by weight 〇〇〇 mixed liquid composition (R3) modulated radiation-sensitive composition. Next, except that the liquid composition (R 3) was used instead of the liquid composition (R 1), the same treatment as in Example 1 was performed to form a red stripe-shaped color filter on the substrate. When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of mask attachments > A coating substrate (3) and a counter substrate (3) were prepared in the same manner as in Example 1 except that the liquid composition (R3) was used instead of the liquid composition (R1). ), And evaluation of the mask attachment was performed. As a result, no attached matter was observed on the removed opposing substrate (3) —Γ --------- installation ------ order ------- line— [(Please Please read the notes on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 specification (2 丨 0 X 297 mm) -46-Printed by the Intellectual Property of the Ministry of Economic Affairs and the Consumer Cooperatives 434422 ^ A7 _B7_ V. Description of the invention W) Example 4 90 (30) by weight of a 70/30 (weight ratio) mixture of C 'I, Pigment Green 36 and CI Pigment Yellow 150 (A) as a coloring agent, as (B) alkali-soluble Resin's methacrylic acid / styrene / benzyl methacrylate / glyceryl monomethacrylate / N-phenylmaleimide imide copolymer (copolymerization weight ratio 2 1 5/1 5/3 5/10 / 25 -Mw = 35-〇〇〇'Mn-17 500) 60 parts by weight, as (C) 90 parts by weight of dipentaerythritol hexaacrylate as a polyfunctional monomer, as (D) a photopolymerization initiator 10 parts by weight of the three-tillage compound (2) and 2-benzyl-2-dimethylamino-1 1- (4-morpholinephenyl) butanone-1 1 to 15 parts by weight as (E) an organic amine group 5-amino-l-pentanol 7.5 parts by weight of the compound 'and 1'000 parts by weight of ethyl 3-ethoxyacrylate was mixed as a solvent to prepare a liquid composition (G1) of a radiation-sensitive composition. Next, except that the liquid composition (G 1) was used instead of the liquid composition (R 1), the same process as in Example 1 was performed to form a green stripe-shaped color filter on the substrate. When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of mask attachments > Except that the liquid composition (G 1) was used in place of the liquid composition (R 1), the same treatment as in Example 1 was performed to produce a coated substrate (4) and an opposing substrate. n ^ i --ml ^^^ 1 ^^^ 1--I ϋ--* 一 # > n ^ r- ^^^ 1 1 ^ 1 ^ 1 ^^ 1 (Please read the notes on the back before filling in this (Page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297mm) _ 47-A7 ^ 34422 ^ __ B7_ V. Detailed description of the invention) Plate (4), and evaluation of the attachment of the mask. As a result, no adhered matter was observed on the removed opposing substrate (4).

Q 實施例5 將作爲（A)著色劑之C. I _顏料綠36和 C. I .顏料黃138之75/25 (重量比）混合物 8 〇重量份，作爲（b )鹼可溶性樹脂之甲基丙烯酸/琥 珀酸單（2 _丙烯醯氧乙基）酯/苯乙烯/甲基丙烯酸； 酯/N -苯基馬來醯亞胺共聚物（共聚重量比二1 5/ 10/18 · 8/25/31 . 2 ’Mw 二 15，000 ，Mn = 6，000) 65重量份’作爲（C)多官能性 單體之六丙烯酸二季戊四醇酯8 0重量份’作爲（D)光 聚合引發劑之三畊系化合物（3) 10重量份，2，2一 —雙（2，4 一二氯苯基）4 ’’4： / ，5，5 / _四苯基 —1 ，2 / —二咪唑6重量份，及作爲氫供給體之氫 硫基苯並噻唑3重量份和4，4 / 一雙（二乙胺基）二苯 酮6重量份，作爲（Ε )有機胺基化合物之3 -胺基1 ’ 2 -丙二醇2重量份，及作爲溶劑之3 -乙氧基丙酸乙酯 1，0 0 0重量份混合，調製感放射線性組成物的液狀組 成物（G 2 )。 其次，除了使用液狀組成物（G 2 )代替液狀組成物 (R 1 )以外，同實施例1處理’於基板上形成綠色條狀 之濾色器。 本紙張尺度適用中國國家標準（CNS ) Α4規格（21 〇 X撕公釐）-48 - J Γ 楚------訂--Λ--,--線— I {請先聞讀背面之注意事項再填寫本頁) 經濟部智慧財產局Κ工消費合作社印製 4 3 4422 ί Α7 Α7 Β7 五、發明説明（½ ) 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（G 2 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（5 )及對向基 板（5)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（5 )上並未察見附著物 實施例6 將作爲（A )著色劑之C . I .顏料綠7和C · I . 顏料黃8 3之6 5 / 3 5 (重量比）混合物6 0重量份， 作爲（Β)鹼可溶性樹脂之甲基丙烯酸/琥珀酸單（2 -丙烯醯氧乙基）酯/苯乙烯/甲基丙烯酸苄基/Ν_苯基 馬來醯亞胺共聚物（共聚重量比=15/10/18.8 /25/31 · 2，Mw=24，000，Μη = 10 · 000) 75重量份，作爲（C)多官能性單體之 六丙烯酸二季戊四醇酯7 5重量份，作爲（D)光聚合引 發劑之三畊系化合物（3) 12重量份，作爲（E)有機 胺基化合物之2 -胺基乙醇5重量份’及作爲溶劑之3 -乙氧基丙酸乙酯及環己酮9 0/1 0 (重量比）混合物 1，0 0 0重量份混合，調製感放射線性組成物的液狀組 本紙張尺度適用中國國家標率（CNS)A4規格（210X297公釐）-49- J---^---L---裝 (請先閲讀背面之注意事項再填寫本頁) 玎 線 經濟部智慧財產局員工消費合作社印製 434422^ A7 B7 五、發明説明（47 ) 成物（G 3 )。 其次*除了使用液狀組成物（G 3 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成綠色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（G 3 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（6 )及對向基 板（6)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（6 )上並未察見附著物 實施例7 將作爲（A)著色劑之C. I ·顏料綠254和 C. I .顏料黃139之75/25 (重量比）混合物 1 1 0重量份，作爲（B )鹼可溶性樹脂之甲基丙烯酸/ 苯乙烯/甲基丙烯酸苄酯/單甲基丙烯酸甘油酯/N -苯 基馬來醯亞胺共聚物（共聚重量比=1 5/1 5/3 5/ 10/25 jMw=30 ' 000 'Μη — 10 . 000 )6 0重量份，作爲（C )多官能性單體之六丙烯酸二季 戊四醇酯9 0重量份，作爲（D )光聚合引發劑之三畊系 本紙張尺度適用中國國家標準（CNS ) A4規格（2IOX297公釐）_ g〇 _ J Γ 裝------钉-----T--線— I (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局W工消費合作社印製 經濟部智慧財產局員工消費合作社印製 434422 i A7 B7 五、發明説明細） 化合物（2 ) 1 5重量份，作爲（E )有機胺基化合物之 2 —胺基乙醇5重量份 > 及作爲溶劑之丙二醇單甲醚醋酸 醋及環己酮9 5/ 5 (重量比）混合物1，000重量份 混合，調製感放射線性組成物的液狀組成物（R 4 )。 其次，除了使用液狀組成物（R 4 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成紅色條狀 之濾、色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（R 4 )代替液狀組成物_( R 1 )以外，同實施例1處理，製作塗佈基板（7 )及對向基 板（7)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（7 )上並未察見附著物 實施例8 將作爲（A)著色劑之C.I.顏料綠36和 C . I .顔料黃150之70/30 (重量比）混合物 1 2 0重量份’作爲（B )鹼可溶性樹脂之甲基两儲酸/ 羧基聚丁內酯單丙烯酸酯/苯乙烯/甲基丙烯酸苄酯 /單甲基丙儲酸甘油醋/Ν —苯基馬來醜亞胺共聚物（共 J----------肢-------订--------線一I (請先閲讀背面之注意事項再填寫本I) 本紙掁尺度適用中國國家標準（CNS ) Α4规格（210 X 297公羞> -51 - 434422 A7 B7 五、發明説明（49 ) 聚重量比=15/10/11.3/35/10/18· 7 ’Mw=40，000，Mn = 20 . 000) 60 重 量份’作爲（C )多官能性單體之六丙烯酸二季戊四醇酯 9 0重量份，作爲（D )光聚合引發劑之三畊系化合物（ 2) 20重量份，作爲（E)有機胺基化合物之2-胺基 乙醇1 0重量份，及作爲溶劑之丙二醇單甲醚醋酸醋及環 己酮之9 5/ 5 (重量比）混合物1，0 0 0重量份混合 ，調製感放射線性組成物的液狀組成物（G 4 )。 其次，除了使用液狀組成物（G 4 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成綠色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（G 4 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（8 )及對向基 板（8)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（8 )上並未察見附著物 實施例9 除了使用60重量份之C . I .顏料藍15 : 6，代 本紙張尺度逋用中國國家標準（CNS > A4規格（210x297公釐）-52 - J.----------ti (請先閱讀背面之注意事項再填寫本頁) 訂 線— I. 經濟部智慧財產局員工消費合作社印製 4 3 4 2 id A7 B7 五、發明説明¢50 ) (請先閲讀背面之注意事項再填寫本頁) 替C. I .顏料綠36和C. I .顏料黃150之70/ 3 0 (重量比）混合物1 2 0重量份作爲（A )著色劑以 外，同實施例8處理，取得感放射線性組成物的液狀組成 物（B 1 )。 其次，除了使用液狀組成物（B 1 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成藍色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（B 1 )代替液狀組成物（R 1 )以外，同實施例1處理 > 製作塗佈基板（9 )及對向基 板（9)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（9 )上並未察見附著物 經濟部智慧財產局員工消費合作社印製 實施例1 ◦ 除了使用120重量份之C.I.顏料藍15:6作 爲（A )著色劑以外，同實施例9處理，調製感放射線性 組成物的液狀組成物（B 2 )。 其次，除了使用液狀組成物（B 2 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成藍色條狀 本紙張尺度通用中國國家標準（CNS ) A4規格（210X297公釐）_ 53 - 經濟部智慧財產局員工消費合作社印製 _B7_ 五、發明説明（51 ) 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上並未察見殘渣及質地污染，且與所得畫素基板之密 合性亦優良。 <光罩附著物之評價> 除了使用液狀組成物（B 2 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（1 〇 )及對向 基板（10)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（1 0 )上並未察見附著 物。 比較例1 除了未添加（E)有機胺基化合物5_胺基- 1 -戊 醇以外，同實施例4處理，調製感放射線性組成物的液狀 組成物（g 1 )。其次，除了使用液狀組成物（g 1 )代 替液狀組成物（R 1 )以外，同實施例1處理，於基板上 形成綠色條狀之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上察見乳白色之質地污染。 <光罩附著物之評價> 除了使用液狀組成物（g 1 )代替液狀組成物（R 1 )以外 > 同實施例1處理，製作塗佈基板（7 )及對向基 本紙張尺度適用中國國家標準（CNS ) Α4规格（210 X 297公釐）_ 54 - J.------„---^------ΐτ--Γ.--,--千 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 43 44 2 22 at ___B7__ 五、發明説明（52 ) 板（7) ’並且實施光罩附著物之評價。 其結果，於取出之對向基板（.7 )上察見白色之附著 物。 比較例2 除了添加5份之脂環式環氧樹脂Celloxide 202 1 p (商 品名’ Dicel化學工業（株）製），代替（E )有機胺基化 合物5 -胺基- 1戊醇以外，同實施例4處理，調製感放 射線性組成物的液狀組成物（g 2 )。 其次，除了使用液狀組成物（g 2 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成綠色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上察見乳白色之質地污染。 <光罩附著物之評價> 除了使用液狀組成物（g 2 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（8 )及對向基 板（8)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（8 )上察見白色之附著 物。 比較例3 除了添加5份之多官能脂環式環氧樹脂Epolide GT401 本紙張尺度適用中國國家標準（CNS >A4規格（210X297公釐）-55 - J. ----裝------訂-----J--線— I (請先閱讀背面之注意事項再填寫本頁) 43^422 Α7 Β7 五、發明説明fo ) (請先閲讀背面之注意事項再填寫本頁) (商品名，D1Cel化學工業（株）製），代替（E )有機胺 基化合物5_胺基- 1 _戊醇以外，同實施例4處理，調 製感放射線性組成物的液狀組成物（g3)。 其次，除了使用液狀組成物（g 3 )代替液狀組成物 (R 1 )以外，同實施例1處理，於基板上形成紅色條狀 之濾色器。 使用光學顯微鏡觀察所得之濾色器時，於未曝光部之 基板上察見乳白色之質地污染。 <光罩附著物之評價> 除了使用液狀組成物（g 3 )代替液狀組成物（R 1 )以外，同實施例1處理，製作塗佈基板（9 )及對向基 板（9)，並且實施光罩附著物之評價。 其結果，於取出之對向基板（9 )上察見白色之附著 物。 〔發明之效果〕 經濟部智慧財產局員工消費合作社印製 第一發明之濾色器用感放射線性組成物爲經由含有（ E )有機胺基化合物，而捕捉光聚合引發劑所含之三畊系 化合物中發生或副生成的活性游離基和揮發性酸性化合物 (例如，鹵化氫等），故不僅可防止曝光時光罩附著物的 發生且顯像性優，於未曝光部之基板上不會發生殘渣及質 地污染，且可提供對於基板及遮光層之密合性亦優之畫素 本紙張尺度適用中國國家標準（CNS) A4規格（2丨0X297公釐）-56-Q Example 5 80 parts by weight of a 75/25 (weight ratio) mixture of C. I_Pigment Green 36 and C. I. Pigment Yellow 138 as (A) colorants was used as (a) the base of the alkali-soluble resin. Acrylic acid / succinic acid mono (2-propenyloxyethyl) ester / styrene / methacrylic acid; ester / N-phenylmaleimide imide copolymer (copolymerization weight ratio 2 5 / 10/18 · 8 / 25/31. 2 'Mw di 15,000, Mn = 6,000) 65 parts by weight' 80 parts by weight of dipentaerythritol hexaacrylate as (C) polyfunctional monomer 'as (D) photopolymerization initiation 10 parts by weight of the three farming compound (3), 2,2-a-bis (2,4-dichlorophenyl) 4 '' 4: /, 5, 5 / _tetraphenyl-1, 2 /- 6 parts by weight of diimidazole and 3 parts by weight of hydrogenthiobenzothiazole as a hydrogen donor and 6 parts by weight of 4,4 / monobis (diethylamino) benzophenone as (E) organic amine compounds 2 parts by weight of 3-amino 1'2-propanediol, and 1,000 parts by weight of ethyl 3-ethoxypropionate as a solvent were mixed to prepare a liquid composition (G 2) of a radiation-sensitive composition . Next, except that the liquid composition (G 2) was used instead of the liquid composition (R 1), the same process as in Example 1 was used to form a green stripe-shaped color filter on the substrate. The size of this paper is applicable to China National Standard (CNS) Α4 size (21 〇X tear mm) -48-J Γ Chu ------ Order --Λ-, ---- Line — I {Please read the back first Please pay attention to this page, please fill in this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, KK Industrial Cooperative, 4 3 4422 ί Α7 Α7 Β7 V. Description of the invention (½) When using the optical microscope to observe the obtained color filter, the substrate on the unexposed part No residue and texture pollution were observed on the surface, and the adhesion with the obtained pixel substrate was also excellent. < Evaluation of mask attachments > A coating substrate (5) and a counter substrate (5) were prepared in the same manner as in Example 1 except that the liquid composition (G 2) was used instead of the liquid composition (R 1). ), And evaluation of the mask attachment was performed. As a result, no attached matter was observed on the removed counter substrate (5). Example 6 C. I. Pigment Green 7 and C · I. Pigment Yellow 8 3 of 6 which will be (A) colorants 5 / 3 5 (weight ratio) 60 parts by weight of the mixture as a (B) alkali-soluble resin of methacrylic acid / succinic acid mono (2-propenyloxyethyl) ester / styrene / benzyl methacrylate / N_benzene 75% by weight as a (C) polyfunctional monomer (copolymerization weight ratio = 15/10 / 18.8 / 25/31 · 2, Mw = 24,000, Mη = 10 · 000) 7 5 parts by weight of dipentaerythritol acrylate, (D) 12 parts by weight of the three-cult compound (3) as a photopolymerization initiator, and (E) 5 parts by weight of 2-aminoethanol as the organic amine compound; and As a solvent, 3-ethoxypropionic acid ethyl ester and cyclohexanone 9 0/1 0 (weight ratio) mixture of 1, 0 0 0 parts by weight are mixed to prepare a liquid composition of a radiation-sensitive composition. This paper is applicable to China. National Standard Rate (CNS) A4 Specification (210X297 mm) -49- J --- ^ --- L --- installation (please read the precautions on the back before filling this page) Staff of the Bureau of Intellectual Property, Ministry of Economic Affairs Eliminate 434422 ^ A7 B7 co printed V. invention is described in (47) into a product (G 3). Secondly, except that the liquid composition (G 3) is used instead of the liquid composition (R 1), the same treatment as in Example 1 is performed to form a green stripe-shaped color filter on the substrate. When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of mask attachments > A coating substrate (6) and a counter substrate (6) were prepared in the same manner as in Example 1 except that the liquid composition (G3) was used instead of the liquid composition (R1). ), And evaluation of the mask attachment was performed. As a result, no attached matter was observed on the counter substrate (6) taken out. Example 7 C. I. Pigment Green 254 and C. I. Pigment Yellow 139 75/25 (A) colorants ( (Weight ratio) 1 10 parts by weight of the mixture as (B) an alkali-soluble resin of methacrylic acid / styrene / benzyl methacrylate / glyceryl monomethacrylate / N-phenylmaleimide copolymer ( Copolymerization weight ratio = 1 5/1 5/3 5 / 10/25 jMw = 30 '000' Μη — 10. 000) 60 parts by weight, as (C) a difunctional pentaerythritol hexaacrylate 9 0 Parts by weight, as the (D) photopolymerization initiator of the Three Cultivation System. This paper is sized according to the Chinese National Standard (CNS) A4 (2IOX297 mm) _ g〇_ J Γ Packing ----- Nail ---- -T--line — I (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by W Industrial Consumer Cooperatives Printed by the Ministry of Economic Affairs ’Intellectual Property Bureau, printed by employee consumer cooperatives 434422 i A7 B7 5. Details of the invention ) Compound (2) 15 parts by weight, (E) 5 parts by weight of 2-aminoethanol as organic amine compound > and propylene glycol monomethyl ether acetic acid as solvent Vinegar and cyclohexanone 9 5/5 (weight ratio) 1,000 parts by weight of the mixture were mixed to prepare a liquid composition (R 4) of the radiation-sensitive composition. Next, except that the liquid composition (R 4) was used instead of the liquid composition (R 1), the same treatment as in Example 1 was performed to form a red stripe filter and color filter on the substrate. When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of mask attachments > Except that the liquid composition (R 4) was used instead of the liquid composition (R 1), the same treatment as in Example 1 was performed to prepare a coated substrate (7) and a counter substrate ( 7), and evaluation of the mask attachment is performed. As a result, no attached matter was observed on the removed counter substrate (7). Example 8 CI Pigment Green 36 and C.I. Pigment Yellow 150 as (A) colorants 70/30 (weight ratio) Mixture 1 2 0 parts by weight 'as (B) an alkali-soluble resin of methyl bisacid / carboxy polybutyrolactone monoacrylate / styrene / benzyl methacrylate / monomethylpropionic acid glycerol vinegar / N — Phenylmaleimine copolymer (total J ---------- limb ------- order -------- line one I (Please read the precautions on the back first Fill in this again I) The paper size of the paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 male shame) -51-434422 A7 B7 V. Description of the invention (49) Poly-weight ratio = 15/10 / 11.3 / 35 / 10/18 · 7 'Mw = 40,000, Mn = 220,000) 60 parts by weight' 90 parts by weight of dipentaerythritol hexaacrylate as (C) polyfunctional monomer, as (D) photopolymerization initiator 20 parts by weight of the three-cult compound (2), 10 parts by weight of 2-aminoethanol as (E) organic amine compound, and 9/5 of propylene glycol monomethyl ether acetate and cyclohexanone as solvent (Weight ratio) mixture 1, 0 0 0 weight Mix to prepare the liquid composition (G 4) of the radiation-sensitive composition. Next, except that the liquid composition (G 4) is used instead of the liquid composition (R 1), the same treatment as in Example 1 is performed on the substrate. A green stripe-shaped color filter is formed. When the obtained color filter is observed with an optical microscope, no residue or texture contamination is observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate is also excellent. ≪ Evaluation of photomask attachments> Except that the liquid composition (G 4) was used instead of the liquid composition (R 1), the same treatment as in Example 1 was performed to prepare a coated substrate (8) and a counter substrate (8). As a result, the attachment of the photomask was evaluated. As a result, no attachment was observed on the counter substrate (8) taken out. Example 9 Except the use of 60 parts by weight of C.I. Pigment Blue 15: 6, Substitute Paper size adopts Chinese national standard (CNS > A4 size (210x297 mm) -52-J .---------- ti (Please read the precautions on the back before filling this page). I. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 3 4 2 id A7 B7 V. Description of invention ¢ 50) (Please Read the notes on the reverse side and fill in this page) Replace C. I. Pigment Green 36 and C. I. Pigment Yellow 150 with 70/30 (weight ratio) mixture 1 2 0 parts by weight as (A) colorant, the same In Example 8, the liquid composition (B 1) of the radiation-sensitive composition was obtained. Next, except that the liquid composition (B 1) was used instead of the liquid composition (R 1), the same process as in Example 1 was performed to form a blue stripe-shaped color filter on the substrate. When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of mask attachments > The same processing as in Example 1 was performed except that the liquid composition (B 1) was used instead of the liquid composition (R 1). > Production of a coated substrate (9) and a counter substrate ( 9), and evaluation of the mask attachment is performed. As a result, the attached substrate (9) was taken out and the attached matter was printed in Example 1 by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. ◦ Except that 120 parts by weight of CI Pigment Blue 15: 6 was used for (A) coloring. Other than the agent, the liquid composition (B 2) of the radiation-sensitive composition was prepared in the same manner as in Example 9. Secondly, except that the liquid composition (B 2) was used instead of the liquid composition (R 1), the same treatment as in Example 1 was used to form a blue stripe on the substrate. The paper has a common Chinese national standard (CNS) A4 specification ( 210X297 mm) _ 53-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs _B7_ V. Color filter for invention description (51). When the obtained color filter was observed using an optical microscope, residues and texture contamination were not observed on the substrate of the unexposed portion, and the adhesion to the obtained pixel substrate was also excellent. < Evaluation of mask attachments > Except that the liquid composition (B 2) was used instead of the liquid composition (R 1), the same treatment as in Example 1 was performed to prepare a coated substrate (100) and a counter substrate ( 10), and evaluation of the mask attachment was performed. As a result, no adhered matter was observed on the removed opposing substrate (1 0). Comparative Example 1 A liquid composition (g 1) of a radiation-sensitive composition was prepared in the same manner as in Example 4 except that the (E) organic amine compound 5-amino-1 -pentyl alcohol was not added. Next, except that the liquid composition (g 1) was used in place of the liquid composition (R 1), the same treatment as in Example 1 was performed to form a green strip-shaped color filter on the substrate. When the obtained color filter was observed using an optical microscope, a milky texture was observed on the substrate of the unexposed portion. < Evaluation of mask attachments > Except that the liquid composition (g 1) was used instead of the liquid composition (R 1) > The same treatment as in Example 1 was performed to produce a coated substrate (7) and a base paper facing the substrate. The scale is applicable to China National Standard (CNS) Α4 specification (210 X 297 mm) _ 54-J .------ „--- ^ ------ ΐτ--Γ .--,-1000 (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 43 44 2 22 at ___B7__ V. Description of the Invention (52) Plate (7) 'and evaluate the attachment of the mask. As a result, a white deposit was observed on the counter substrate (.7) that was taken out. Comparative Example 2 In addition to adding 5 parts of an alicyclic epoxy resin Celloxide 202 1 p (trade name 'Dicel Chemical Industry Co., Ltd.) ), Instead of (E) organic amine compound 5-amino-1pentyl alcohol, the same treatment as in Example 4 was performed to prepare a liquid composition (g 2) of the radiation-sensitive composition. Next, except that the liquid composition was used (G 2) Instead of the liquid composition (R 1), the same treatment as in Example 1 was performed to form a green stripe-shaped color filter on the substrate. Using an optical display When the obtained color filter was observed under a microscope, a milky-white texture was observed on the substrate of the unexposed portion. ≪ Evaluation of the mask attachment > In addition to using a liquid composition (g 2) instead of the liquid composition (R 1) Except for the same treatment as in Example 1, a coated substrate (8) and a counter substrate (8) were produced, and evaluation of the mask attachment was performed. As a result, a white color was observed on the counter substrate (8) taken out Comparative Example 3 In addition to adding 5 parts of multifunctional alicyclic epoxy resin Epolide GT401, the paper size is applicable to Chinese national standards (CNS > A4 specification (210X297 mm) -55-J. ---- pack ------ Order ----- J--line — I (Please read the notes on the back before filling this page) 43 ^ 422 Α7 Β7 V. Description of the invention fo) (Please read the notes on the back first Fill in this page again) (trade name, manufactured by D1Cel Chemical Industry Co., Ltd.), instead of (E) organic amine compound 5-amino-1 -pentyl alcohol, treated in the same manner as in Example 4 to prepare a radiation-sensitive composition Liquid composition (g3) Secondly, except that the liquid composition (g 3) is used instead of the liquid composition (R 1), the same procedure is performed. In Example 1, a red stripe-shaped color filter was formed on the substrate. When the obtained color filter was observed with an optical microscope, a milky white texture was observed on the substrate in the unexposed portion. ≪ Evaluation of mask attachment > Except that the liquid composition (g 3) is used instead of the liquid composition (R 1), the same treatment as in Example 1 is performed to produce a coated substrate (9) and a counter substrate (9), and a mask attachment is implemented. Evaluation. As a result, a white deposit was observed on the counter substrate (9) that was taken out. [Effects of Invention] The first radiation-sensitive composition for color filters printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs was to capture the three farming systems contained in the photopolymerization initiator by containing (E) organic amine compounds Active free radicals and volatile acidic compounds (for example, hydrogen halides) that occur or are by-produced in the compound, not only can prevent the occurrence of mask attachments during exposure and have excellent imaging properties, but will not occur on the substrate in the unexposed area Residue and texture pollution, and can provide pixels with excellent adhesion to the substrate and light-shielding layer. The paper size is applicable to China National Standard (CNS) A4 specifications (2 丨 0X297 mm) -56-

Claims (1)

「叫I V 正先 f/捕 0 2 2 d Λ· A8SSD8 六、申請專利範圍 第89 1 06646號專利申請案 中文申請專利範圍修正本 (請先閲讀背面之注意事項再填寫本頁) 民國89年12月修正 1 . 一種濾色器用感放射線性組成物，其特徵爲含有 (A )著色劑、（B )鹼可溶性樹脂、（C )多官能性單 體、（D )含三畊系化合物之光聚合引發劑、及（E )於 分子中具有1個胺基之有機胺基化合物，其中（E )成分 之有機胺基化合物爲由單烷醇胺類、單環烷醇胺類、胺基 鏈烷二醇類、胺基環鏈烷二醇類、及胺基苯酣類群中選出 至少一種。 2 .如申請專利範圍第1項記載之濾色器用感放射線 性組成物，其中（D )光聚合引發劑爲再含有由乙醯苯系 化合物及二咪唑系化合物群中選出至少一種。 3 .如申請專利範圍第1項記載之濾色器用感放射線 性組成物，其中組成物中之除去溶劑之全部成分中的顏料 比例爲2 0〜5 0重量％。 經濟部智慧財產局貝工消費合作杜印製 4 . 一種濾色器，其特徵爲具有如申請專利範圍第1 〜3項中任一項記載之濾色器用感放射線性組成物所形成 之畫素。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 公 告 修正丨補充 ，年1. 申請曰期 89年 4月10日 案 號 89106646 類 別 (以上各襴由本局填註） Α4 C4 434422 || |專利説明書(修正頁) 中文 濾色器用感放射線性組成物及濂色器 發明 名稱 英文 Color filter and radiation-sensitive composition useful in color filter 姓 名 ί行廣 幸英孝 樓神坂 (1)0(3) .¾¾部智隻財是砀員工>/]費合作社印製 (1)日本 (2)日本 (3) 日本 發明， 二、齡A 國 籍 (1) 曰本國東京都中央區築地二丁目一一番二四號 J S R股份有限公司内 住、居所 ¢2) 曰本國東京都中央區築地二丁目一一番二四Μ J S R股份有限公司内 (3) 日本國東京都中央區築地二丁目一一番二四號 J S R股份有限公司内 姓 名 (名稱） (1) J S R睽份有限公司 >工吖工77—瓜株式会社 國 籍 (1) 日本 (1} 日本國東京都中央區築地二丁目一一番二四號 三' 申請人 住、居所 (事務所） 代表人 姓 名 ⑴ 松本榮一 裝 訂 本紙張尺度適用中國國家標準（CNS ) A4^t格（2丨0X29?公釐）"Called IV is the first f / catch 0 2 2 d Λ · A8SSD8 VI. Patent Application No. 89 1 06646 Patent Application Chinese Patent Application Amendment (Please read the precautions on the back before filling this page) Republic of China 89 Correction for December 1. A radiation-sensitive composition for a color filter, characterized in that it contains (A) a colorant, (B) an alkali-soluble resin, (C) a polyfunctional monomer, and (D) a compound containing a tri-tillage compound Photopolymerization initiators and (E) organic amine compounds having one amine group in the molecule, of which the organic amine compounds of component (E) are monoalkanolamines, monocycloalkanolamines, amine groups At least one selected from the group of alkanediols, aminocycloalkanediols, and aminophenylhydrazones. 2. The radiation-sensitive composition for a color filter according to item 1 of the scope of patent application, wherein (D) The photopolymerization initiator further contains at least one selected from the group of acetophenone-based compounds and diimidazole-based compounds. 3. The radiation-sensitive composition for a color filter according to item 1 of the patent application scope, wherein the composition is removed Pigments in all solvents The proportion is from 20 to 50% by weight. 4. Printed by the Shellfish Consumer Cooperative Department of the Intellectual Property Bureau of the Ministry of Economic Affairs. 4. A color filter having a color filter as described in any one of claims 1 to 3 of the scope of patent application. Pixels formed by the radiation-sensitive composition used in the device. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). Amendments to the notice are added. 1. The application date is April 10, 89. 89106646 Category (the above are filled in by the Bureau) Α4 C4 434422 || | Patent Specification (Revised Page) Chinese Color Filter and Radiation Inventive Composition Name English Color filter and radiation-sensitive composition useful in color filter Name 行行 广 幸 英 孝 楼 神 坂 (1) 0 (3). ¾¾Ministry's Wealth is an employee > /] Printed by Cooperative Cooperative (1) Japan (2) Japan (3) Japan Invention, Age A Nationality (1) JSR Co., Ltd., Tsukiji II-Chome 112, Chuo-ku, Tokyo, Japan JSR Co., Ltd.2) JSR Share, Tsukiji-II Chome, Chuo-ku 112, Tokyo, Japan Within the company (3) Name (Name) of JSR Co., Ltd., Tsukiji II-chome 112-112, Chuo-ku, Tokyo, Japan (1) JSR Co., Ltd. > Gonggong 77-Guar Co., Ltd. Nationality (1 ) Japan (1) Tsukiji II-chome No. 112, No. 24, No. 3 No. 3, Tsukiji, Chuo-ku, Tokyo, Japan Applicant's residence, domicile (office) Representative name ⑴ Matsumoto Eiichi binding This paper size applies Chinese National Standard (CNS) A4 ^ T cells (2 丨 0X29? mm) 修正蝻充 申請日期 89 年 4月10曰 案 號 89106646 類 則 (以上各欄由本局填註） A4 C4 Μ專利説明書 中 文 發明 名稱 英 文 边渡遙毅 姓 名 國 籍 W)曰本 裝 發明 册 人 m 日本國東京都中央區築地二丁目一一番二四號 J S R股份有限公司内 住、居所 訂 姓 名 (名稱） 國 籍 三' 申請人 住、居所 (事務所） 代表人 姓 名 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 「叫I V 正先 f/捕 0 2 2 d Λ· A8SSD8 六、申請專利範圍 第89 1 06646號專利申請案 中文申請專利範圍修正本 (請先閲讀背面之注意事項再填寫本頁) 民國89年12月修正 1 . 一種濾色器用感放射線性組成物，其特徵爲含有 (A )著色劑、（B )鹼可溶性樹脂、（C )多官能性單 體、（D )含三畊系化合物之光聚合引發劑、及（E )於 分子中具有1個胺基之有機胺基化合物，其中（E )成分 之有機胺基化合物爲由單烷醇胺類、單環烷醇胺類、胺基 鏈烷二醇類、胺基環鏈烷二醇類、及胺基苯酣類群中選出 至少一種。 2 .如申請專利範圍第1項記載之濾色器用感放射線 性組成物，其中（D )光聚合引發劑爲再含有由乙醯苯系 化合物及二咪唑系化合物群中選出至少一種。 3 .如申請專利範圍第1項記載之濾色器用感放射線 性組成物，其中組成物中之除去溶劑之全部成分中的顏料 比例爲2 0〜5 0重量％。 經濟部智慧財產局貝工消費合作杜印製 4 . 一種濾色器，其特徵爲具有如申請專利範圍第1 〜3項中任一項記載之濾色器用感放射線性組成物所形成 之畫素。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）Amend the application date of April 10, 89, case number 89106646 (the above columns are filled out by the Bureau) A4 C4 Μ Patent specification Chinese invention name English Biandu Yaoyi Name Nationality W) Inventor of booklet m JSR Co., Ltd., Tsukiji II, Chubu, Chuo-ku, Tokyo, Japan. Name of residence and residence (name) Nationality 3 'Applicant's residence and residence (office) Name of representative This paper applies Chinese national standards (CNS) A4 specification (210X297 mm) "Called IV positive f / capture 0 2 2 d Λ · A8SSD8 VI. Application for Patent Scope No. 89 1 06646 Chinese Patent Application Amendment (Please read the back Note: Please fill in this page again.) Rev. Dec. 89 of the Republic of China 1. A radiation-sensitive composition for color filters, characterized by containing (A) colorant, (B) alkali-soluble resin, (C) polyfunctional monomer (D) a photopolymerization initiator containing a tri-tillage compound, and (E) an organic amine compound having one amine group in the molecule, of which (E) The organic amine-based compound is at least one selected from the group of monoalkanolamines, monocycloalkanolamines, aminoalkanediols, aminocycloalkanediols, and aminophenylhydrazones. 2. Such as The radiation-sensitive composition for color filters according to item 1 of the scope of the patent application, wherein (D) the photopolymerization initiator further contains at least one selected from the group of acetophenone-based compounds and diimidazole-based compounds. The radiation-sensitive composition for color filters described in the first item of the scope, wherein the proportion of the pigment in all the components excluding the solvent in the composition is 20 to 50% by weight. Printed by Shellfisher Consumer Cooperation, Intellectual Property Bureau, Ministry of Economic Affairs 4. A color filter having pixels formed by the radiation-sensitive composition for a color filter as described in any one of claims 1 to 3 of the scope of patent application. This paper size is applicable to Chinese National Standards (CNS) A4 size (210 X 297 mm)
TW089106646A 1999-04-27 2000-04-10 Color filter and radiation-sensitive composition useful in color filter TW434422B (en)

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JP2002372779A (en) * 2001-06-15 2002-12-26 Toray Ind Inc Resist for color filter and method for producing color filter
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