TW426664B - Industrial heterogeneously catalyzed gas-phase oxidation of propane to acrolein - Google Patents

Industrial heterogeneously catalyzed gas-phase oxidation of propane to acrolein Download PDF

Info

Publication number
TW426664B
TW426664B TW086107698A TW86107698A TW426664B TW 426664 B TW426664 B TW 426664B TW 086107698 A TW086107698 A TW 086107698A TW 86107698 A TW86107698 A TW 86107698A TW 426664 B TW426664 B TW 426664B
Authority
TW
Taiwan
Prior art keywords
patent application
item
propane
scope
gas mixture
Prior art date
Application number
TW086107698A
Other languages
English (en)
Chinese (zh)
Inventor
Andreas Tenten
Theo Proll
Hans-Peter Schildberg
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Application granted granted Critical
Publication of TW426664B publication Critical patent/TW426664B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW086107698A 1996-06-04 1997-06-04 Industrial heterogeneously catalyzed gas-phase oxidation of propane to acrolein TW426664B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19622331A DE19622331A1 (de) 1996-06-04 1996-06-04 Verfahren der heterogen katalysierten Gasphasenoxidation von Propan zu Acrolein

Publications (1)

Publication Number Publication Date
TW426664B true TW426664B (en) 2001-03-21

Family

ID=7796070

Family Applications (1)

Application Number Title Priority Date Filing Date
TW086107698A TW426664B (en) 1996-06-04 1997-06-04 Industrial heterogeneously catalyzed gas-phase oxidation of propane to acrolein

Country Status (12)

Country Link
US (1) US6252122B1 (ja)
EP (1) EP0912480B1 (ja)
JP (1) JP2000511548A (ja)
KR (1) KR20000016288A (ja)
CN (1) CN1221399A (ja)
AU (1) AU3168697A (ja)
CA (1) CA2257075A1 (ja)
CZ (1) CZ394498A3 (ja)
DE (2) DE19622331A1 (ja)
ID (1) ID17756A (ja)
TW (1) TW426664B (ja)
WO (1) WO1997046506A1 (ja)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6541664B1 (en) 1997-10-21 2003-04-01 Basf Aktiengesellschaft Method of heterogeneous catalyzed vapor-phase oxidation of propane to acrolein and/or acrylic acid
DE19837517A1 (de) 1998-08-19 2000-02-24 Basf Ag Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan
US6114278A (en) * 1998-11-16 2000-09-05 Saudi Basic Industries Corporation Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same
DE19910507A1 (de) * 1999-03-10 2000-09-14 Basf Ag Verfahren der heterogen katalysierten Gasphasenoxidation von Propan zu Acrolein und/oder Acrylsäure
JP4809532B2 (ja) * 1999-11-15 2011-11-09 サウディ ベーシック インダストリーズ コーポレイション プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法
DE10028582A1 (de) * 2000-06-14 2001-12-20 Basf Ag Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemischen aus Propan
KR100740728B1 (ko) 2000-06-14 2007-07-19 바스프 악티엔게젤샤프트 아크롤레인 및(또는) 아크릴산의 제조 방법
US6919472B2 (en) 2001-12-21 2005-07-19 Saudi Basic Industries Corporation Catalyst compositions for the selective conversion of alkanes to unsaturated carboxylic acids, methods of making and methods of using thereof
DE10232482A1 (de) 2002-07-17 2004-01-29 Basf Ag Verfahren zum sicheren Betreiben einer kontinuierlichen heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Verbindung
US7115776B2 (en) 2002-07-18 2006-10-03 Basf Aktiengesellschaft Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound
FR2844263B1 (fr) * 2002-09-10 2004-10-15 Atofina Procede de fabrication d'acide acrylique a partir de propane, en presence d'oxygene moleculaire
EP1411043A1 (en) * 2002-10-18 2004-04-21 Rohm And Haas Company Preparation of unsaturated carboxylic acids and unsaturated carboxylic acid esters from alkanes and/or alkenes
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
US7294734B2 (en) * 2003-05-02 2007-11-13 Velocys, Inc. Process for converting a hydrocarbon to an oxygenate or a nitrile
US7220390B2 (en) 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
US7589046B2 (en) * 2003-06-04 2009-09-15 Basf Aktiengesellschaft Thermal treatment of the precursor material of a catalytically active material
US7524792B2 (en) * 2003-06-04 2009-04-28 Basf Aktiengesellschaft Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu
KR100807972B1 (ko) 2005-08-10 2008-02-28 주식회사 엘지화학 아크릴산 선택성이 높은 복합 금속 산화물 촉매
DE102006000996A1 (de) 2006-01-05 2007-07-12 Basf Ag Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung
EP1734030A1 (de) 2006-01-18 2006-12-20 BASF Aktiengesellschaft Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung
EA200802034A1 (ru) * 2006-03-29 2009-02-27 Басф Се Способ получения пропена из пропана
KR101170177B1 (ko) 2006-04-18 2012-07-31 에스케이종합화학 주식회사 비스무스 몰리브데이트 촉매, 이의 제조방법 및 이를이용한 1,3-부타디엔의 제조방법
WO2008058918A1 (de) * 2006-11-15 2008-05-22 Basf Se Verfahren zum betreiben einer exothermen heterogen katalysierten partiellen gasphasenoxidation einer organischen ausgangsverbindung zu einer organischen zielverbindung
WO2010000720A2 (de) * 2008-07-02 2010-01-07 Basf Se Verfahren zur herstellung eines oxidischen geometrischen formkörpers
ES2387349T3 (es) 2008-07-21 2012-09-20 Basf Se Procedimiento para la obtención industrial de propeno
GB201011091D0 (en) * 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
US20140163291A1 (en) * 2012-12-06 2014-06-12 Basf Se Process for the Oxidative Dehydrogenation of N-Butenes to Butadiene
US9399606B2 (en) * 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
CN103041830A (zh) * 2012-12-26 2013-04-17 新兴能源科技有限公司 一种丙烯一步法氧化制丙烯酸催化剂的制备方法
EP3068753A1 (de) * 2013-11-11 2016-09-21 Basf Se Mechanisch stabiler hohlzylindrischer katalysatorformkörper zur gasphasenoxidation eines alkens zu einem ungesättigten aldehyd und/oder einer ungesättigten carbonsäure

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3147084A (en) 1962-03-08 1964-09-01 Shell Oil Co Tubular catalytic reactor with cooler
BE759434A (fr) * 1969-11-25 1971-04-30 Power Gas Ltd Oxydation catalytique
CA939676A (en) * 1970-03-24 1974-01-08 David Naden Catalytic oxidation
JPS5129124B1 (ja) 1971-04-27 1976-08-24
US3893951A (en) 1973-02-22 1975-07-08 Standard Oil Co Catalysts for oxidation reactions
JPS5246208B2 (ja) 1973-03-22 1977-11-22
US4339355A (en) 1975-10-09 1982-07-13 Union Carbide Corporation Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal
DE2626887B2 (de) 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
AU529228B2 (en) 1977-07-13 1983-06-02 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalytic vapour phase oxidation
US4260822A (en) 1978-10-30 1981-04-07 Rohm And Haas Company Process for the production of unsaturated acids
DE2909671A1 (de) 1979-03-12 1980-10-02 Basf Ag Verfahren zur herstellung von schalenkatalysatoren
US4472314A (en) 1980-05-27 1984-09-18 Allied Corporation Bismuth-containing mixed oxides of perovskite structure in oxidation of acyclic hydrocarbons
US4302610A (en) 1980-05-27 1981-11-24 Allied Corporation Vanadium containing niobates and tantalates
DE3151805A1 (de) 1981-12-29 1983-07-07 Basf Ag, 6700 Ludwigshafen Verfahren zum regenerierenden aufarbeiten von geschaedigten oxidationskatalysatoren
DE3461782D1 (en) 1983-02-22 1987-02-05 Halcon Sd Group Inc Conversion of propane to acrylic acid
ES2028180T3 (es) 1987-06-05 1992-07-01 Nippon Shokubai Kagaku Kogyo Kabushiki Kaisha Catalizador para la oxidacion de acroleina y procedimiento para su preparacion.
JP2614089B2 (ja) * 1988-09-17 1997-05-28 三菱化学株式会社 アクロレインの製造方法
CA2029277A1 (en) 1989-11-06 1991-05-07 Tatsuya Kawajiri Method for production of acrylic acid
FR2700974B1 (fr) 1993-01-29 1995-04-28 Rhone Poulenc Chimie Composition de matière à base d'étain, catalyseurs à base de ces compositions de matière et leur utilisation pour la préparation d'acides carbocyliques insaturés.
DE4302991A1 (de) 1993-02-03 1994-08-04 Basf Ag Multimetalloxidmassen
DE4431949A1 (de) 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure
CN1035762C (zh) 1994-11-23 1997-09-03 大庆石油学院 丙烷均相氧化脱氢及丙烯氧化制取丙烯酸的方法及其装置

Also Published As

Publication number Publication date
JP2000511548A (ja) 2000-09-05
ID17756A (id) 1998-01-22
US6252122B1 (en) 2001-06-26
CA2257075A1 (en) 1997-12-11
WO1997046506A1 (de) 1997-12-11
EP0912480A1 (de) 1999-05-06
DE19622331A1 (de) 1997-12-11
EP0912480B1 (de) 2001-09-19
CN1221399A (zh) 1999-06-30
DE59704681D1 (de) 2001-10-25
AU3168697A (en) 1998-01-05
CZ394498A3 (cs) 1999-09-15
KR20000016288A (ko) 2000-03-25

Similar Documents

Publication Publication Date Title
TW426664B (en) Industrial heterogeneously catalyzed gas-phase oxidation of propane to acrolein
US6395936B1 (en) Method for the catalytic gas phase oxidation of propene into acrolein
US6998504B1 (en) Method for the catalytic gas phase oxidation of propene into acrylic acid
US6403829B1 (en) Method for the catalytic gas phase oxidation of acrolein into acrylic acid
US6525217B1 (en) Method for the catalytic gas-phase oxidation of propene to acrylic acid
US6541664B1 (en) Method of heterogeneous catalyzed vapor-phase oxidation of propane to acrolein and/or acrylic acid
US6740779B1 (en) Method for carrying out the catalytic gas phase oxidation of propene to form acrylic acid
EP1424125B1 (en) Process for preparing an antimony based mixed metal oxide catalyst and catalyst obtained
US5446004A (en) Multimetal oxide compositions
US5017542A (en) Catalyst for the oxidation and ammonoxidation of α-, β-unsaturated hydrocarbons
TWI324993B (en) Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid
US20090030230A1 (en) Mixed oxide catalysts for the catalytic gas-phase oxidation of olefins and processes for producing them
JP2003528706A (ja) プロピレンの低温度選択的酸化用のモリブデン−バナジウム系触媒、その製造方法及び使用方法
JP2001025664A (ja) 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒およびこの触媒を用いた不飽和アルデヒドおよび不飽和カルボン酸の製造方法
JP3476307B2 (ja) 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の充填方法
TW299316B (ja)
ZA200508595B (en) Method for the heterogeneously catalysed partial gas phase oxidation of propene to form acrolein
US4410752A (en) Process for the oxydehydrogenation of ethane to ethylene
US20040192963A1 (en) Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid
JPS584691B2 (ja) メタクロレインの製造方法
EP0032618B1 (en) Oxidation and ammoxidation catalysts and their uses
TWI324148B (en) Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid
US4487850A (en) Catalysts for the oxidation and ammoxidation of olefins
EP2011780B1 (en) Process for producing methacrolein and/or methacrylic acid
KR101065089B1 (ko) 아크롤레인을 형성하기 위한 프로펜의 불균질 촉매화 부분기체상 산화 방법