TW412645B - A irradiation-sensitive composition using for color-filter - Google Patents

A irradiation-sensitive composition using for color-filter Download PDF

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Publication number
TW412645B
TW412645B TW088113132A TW88113132A TW412645B TW 412645 B TW412645 B TW 412645B TW 088113132 A TW088113132 A TW 088113132A TW 88113132 A TW88113132 A TW 88113132A TW 412645 B TW412645 B TW 412645B
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Taiwan
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meth
acid
acrylate
weight
radiation
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TW088113132A
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Chinese (zh)
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Shigeru Abe
Hiroaki Nemoto
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Jsr Corp
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
    • G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • G03F7/0397—Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition the macromolecular compound having an alicyclic moiety in a side chain

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials For Photolithography (AREA)
  • Optical Filters (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A irradiation-sensitive composition using for color-filter, which comprises (A) coloring agent; (B) at least one monomer was selected from dicarboxic acid mono (2-acryloyloxyic ester) and dicarboxic acid mono (2-methacryloyloxyic ester), and alkyl-solubable resins contain copolymers of mono-functional monomers which can be copolymerized with these said monomers; (C) multi-functional monomers; and (D) photo-polymerization initiators. These compositions also show excellent development effect while contain high pigemtns. In particular, it would not take place residues and pollutants on un-exposed parts of substrates and mask layers, and also impart patters with good adherence to substrates and mask layers.

Description

412645 A7 經濟部智慧財產局員工消費合作社印則衣 _B7_五、發明說明（1 ) 發月所龎技術範噓_ 本發明係關於顯像性等優良之濾色片用幅照敏感性組 成物。尤指使用透射性或反射性彩色液晶顯示裝置、彩 色收像管元件等形成瀘色片之滤色片用幅照敏感性組成 物。 罟知抟術 向來在製造使用幅照敏感性組成物之漶色片時.在基 板上或預先形成所需画型遮光層之基板上，塗佈幅照敏 感性組成物，乾燥後，對乾燥之塗膜於所需圖型照射放 射線（κ下稱「曝光」），加κ顯像.而得各色圖素。如 此製成的漶色片，在顯像之際，於未曝光部的基板上或 遮光層上，容易產生殘渣或污染，成為問題，其程度随 幅照敏感性組成物所含顔料濃度增加，而有顯著化的傾 向，因而難Μ達成充分的色濃度。 链明所薛解決的謀頚 本發明之目的，在於提供瀘色片用幅照敏感性組成物。 本發明另一目的，在於提供即使含高濃度顔料時也會 顯示良好顯像性之漶色片用幅照敏感性組成物，具體而 言，在於提供一種新穎瀘色Η用幅照敏感性組成物，於 未曝光部的基板上和遮光層上，顯像時不會發生殘渣和 污染，且賦予對基板和遮光層具有儍良接觸性之圖素。 本發明其他目的和優點由下列說明即苛明白。 解決課頴的丰段 按照本發明，本發明上述目的和優點是利用濾色片用 -3 - (請先閱讀背面之注意事項再填寫本頁) -------------------^ Ϊ 本紙張尺度適用中國國家標準（CNS)A4規格（210x297公釐） 412645 A7 ___B7_____ 五、發明說明（2) 幅照敏感性組成物達成，其特徵為，S括（A)著色劑， (B)含有選自二羧酸單（2 -丙烯酿氧乙-酯）和二梭酸單（2 -異丁烯醯氧乙酯）之至少一種單體，以及與此單體可共 聚合之其他單官能性單體的共聚物之溶性樹脂，（c) 多官能性單體，Μ及（D)光聚合引發 ® ° 茲詳述本發明如下。 (Α)著色劑 本發明著色劑對色調無特別限制，可視所得滅色片之 用途適當選擇，無論有機著色劑或無鳴著色劑均可° 前述有機著色劑具體例指染料、有’顔料、天然色素 等。而該無機著色劑具體例除無機顔科外，指有體質顔 科之稱的無機鹽等。漶色片要求高精细的發色和耐熱性 ，故本發明之著色劑係發色性高，且耐熱性高的著色劑 ，尤以耐熱分解性高的著色劑為佳，通常有機著色劑以 使用有機顔料最好。 前述有機顔料有例如在色度指數ί C.1.染料及色素學 家協會公司發行）中分類於顔料（Pi? n!eat)之化合物， 具體例有下列附註色度指數（C . I ·)號碼者。 C.I.黃色顔料83, C.I.黃色顔料]2& ，C_I_黃色顔料 138 ，C.I,黃色顔料139 ，C.I.黃色顔料150 ，C.I.黃 色顔料151 ，C.I.黃色顔料152 , C. ί*黃色顏料153 ， C.I.黃色顔料154 , C.I.黃色顔料，C.1*黃色顔料 156 ，C.I.黃色顔料166 ，C.I·黃色顔料168 ，C.I.黃 色顔料175 , C.I.黃色顔料185 ; -4- 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） 經濟部智慧財產局員工消費合作杜印製 4Ϊ^Γ45 Α7 _Β7_ 五、發明說明（3 ) C. I.紫色顔料19, C. I.紫色顔料23, C,I.紫色顔料29 ，C.I.紫色顏料32, C.I.紫色顔料36, C.I.紫色顔料38; C.I.紅色顔料177 , C.I.紅色顔料202 , C.I.紅色顔 料206 , C. I.釭色顔料207 , C. I.紅色顔料20δ , C.I. 紅色顔料20 9 , C.I.紅色顔料215 ，C.I.紅色顔料216 ,C.I.紅色顏料220 , C.I·紅色顔料224 , C.I.紅色顔 料226 , C.I.紅色顔料242 , C.I.紅色顔料243 . C.I. 紅色顔料245 , C.I.紅色顔料254 , C.I.紅色顏料255 ,C . I .紅色顔料2 6 4 . C . I .紅色顔料265 ; C.I.藍色顔料15, C.I.藍色顔料15:3, C.I.M色顔料 15:4, C.I.藍色顔料 15:6; (：.1.綠色顔料7,(：.1.綠色顔料36; C.I.黑色顔料1 , C.I.黑色顔料7 。 此等有機顔料可單獨或二種Μ上共用。 前述無機著色劑之具體例有氧化钛、硫酸鋇、碳酸鈣 、鋅粉、硫酸鉛、黃鉛、鋅黃、紅丹（紅色氧化_( I® )) 、鎘紅、群青、绀青、氯化鉻綠、鈷綠、琥珀、钛黑、 合成鐵黑、碳黑等。 此等無機著色劑可單獨或二種Μ上共用。 本發明中，前述各著色劑可視需要，Μ聚合物對其粒 子表面加Μ改質使用。對著色劑表面改質之聚合物，有 例如特開平8-259876號公報等所載聚合物，市售各種顔 料分散用聚合物或寡聚物。 另外，本發明中的著色劑可視需要和分散劑共用。 -5- I --------訂·-------- - t (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（2]〇x 297公釐） 412645 A7 _B7_五、發明說明（4 ) 此等分散劑有例如陽離子糸、陰離子系、非離子系、 兩性、矽嗣糸、氟糸等界面活性劑。 前述界面活性劑具體例有：聚氧化乙烯月桂醚、聚氧 化乙烯硬脂魅、聚氧化乙烯油艇等聚氧化乙烯烷基醚類 ;聚氧化乙烯辛基笨醚、聚氧化乙烯壬基苯_等聚氧化 乙烯烷基笨醚頬；聚乙二醇二月桂酸酯、聚乙二醇二硬 脂酸酯等聚乙二醇二酯類；山梨糖醇酐脂肪酸酯類；脂 肪酸改質聚酯類；叔胺改質聚胺酯類；聚乙烯亞胺類等 ,κ外有下列商品名：KP (信越化學工業公司製品）、 波利夫羅（共榮社化學公司製品）、冶夫托普（托克姆 產品公司製品）、美加夫阿庫（大日本油墨化學工業公 司製品）、夫羅納多（住友3M公司製品）、阿撒衣加多 、撒夫羅恩（以上旭玻璃公司製品）、迪衣斯帕-BYK (畢庫克密公司製品）、EFKA-46和47 (EFKA公司製品） 1利魯斯帕斯（哆内卩t公司製品）等。 此等界面活性劑可單獨或二種以上共同使用。 相對於著色劑100重量份，界面:活性劑的使用量M50 重量份Μ下為佳，而以〇〜30重量份更好。 (請先閱讀背面之注意事項再填寫本頁) 訂一---------線- 經濟部智慧財產局員工消費合作社印製 2 其 單少 酸)M 羧酯 二乙 自氧 選醯 有烯 含 ^~-,異 為 2 /IN 徵 特 之 旨 ai二 樹 和 性)ίι 溶酯 鹼乙 明氧 發醢 本烯 丙 單 酸 羧 其 之Ξ共 與 - r 體 單 性 能 官 單 厂 為 稱 體 單 此 下 Μ /V 體 單 物 聚 共 之 體 單 性 lit 官 單 的 合 聚 共 可 他412645 A7 Yinzeyi, a consumer cooperative of employees of the Bureau of Intellectual Property, Ministry of Economic Affairs_B7_V. Description of the invention (1) Technical specifications of the month of the month _ This invention relates to the radiation sensitivity of color filters with excellent image development and other components Thing. In particular, it is a radiation-sensitive composition for a color filter using a transmissive or reflective color liquid crystal display device, a color receiver tube element, or the like to form a ocher color filter. In the conventional method, when manufacturing a color film using a radiation-sensitive composition, the radiation-sensitive composition is coated on a substrate or a substrate on which a desired light-shielding layer is formed in advance, and dried. The coating film is irradiated with radiation in a desired pattern (hereinafter referred to as "exposure"), and κ is developed to obtain various color pixels. The thus produced ocher film is liable to cause residues or contamination on the substrate of the unexposed part or on the light-shielding layer during development, which becomes a problem, and the degree thereof increases with the concentration of the pigment contained in the radiation-sensitive composition. On the other hand, there is a tendency to make it remarkable, and it is difficult to achieve a sufficient color density. The objective of the present invention is to provide a radiation-sensitive composition for cyan dyes. Another object of the present invention is to provide a radiation-sensitive composition for ocher films that exhibits good developability even when containing a high concentration of pigment, and in particular, to provide a novel radiation-sensitive composition for ocher films Objects, on the substrate of the unexposed part and on the light-shielding layer, residues and contamination do not occur during development, and pixels having a silly contact with the substrate and the light-shielding layer are provided. Other objects and advantages of the present invention will be apparent from the following description. Solve the high-end segment of the lesson According to the present invention, the above-mentioned object and advantages of the present invention are the use of color filters -3-(Please read the precautions on the back before filling this page) ------------ ------- ^ Ϊ This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 mm) 412645 A7 ___B7_____ V. Description of the invention (2) Photosensitive composition is achieved, its characteristics are as follows: (A) a colorant, (B) containing at least one monomer selected from the group consisting of dicarboxylic acid mono (2-propenyloxyethyl-ester) and disuccinic acid mono (2-isobutylene ethoxyethyl), and Soluble resins of copolymers of other copolymerizable monofunctional monomers, (c) polyfunctional monomers, M and (D) photopolymerization initiation ° The invention is described in detail below. (A) Colorant The colorant of the present invention is not particularly limited in color tone, and may be appropriately selected depending on the use of the obtained color extinction sheet, regardless of organic colorant or non-sounding colorant. Specific examples of the organic colorant include dyes, pigments, Natural pigments, etc. Specific examples of the inorganic colorant include inorganic salts other than inorganic pigments. The ocher sheet requires high-precision color development and heat resistance. Therefore, the coloring agent of the present invention is a coloring agent with high color development and high heat resistance, especially a coloring agent with high thermal decomposition resistance. Generally, organic coloring agents are Organic pigments are best. The aforementioned organic pigments are, for example, compounds classified as pigments (Pi? N! Eat) in the chromaticity index ί C.1. Issued by the Association of Dyestuffs and Pigmentologists. Specific examples include the following chromaticity index (C.I. ) Numbers. CI yellow pigment 83, CI yellow pigment] 2 &, C_I_ yellow pigment 138, CI, yellow pigment 139, CI yellow pigment 150, CI yellow pigment 151, CI yellow pigment 152, C. Yellow pigment 153, CI yellow pigment 154, CI yellow pigment, C.1 * yellow pigment 156, CI yellow pigment 166, CI · yellow pigment 168, CI yellow pigment 175, CI yellow pigment 185; -4- This paper size applies to China National Standard (CNS) A4 specifications (210x 297 mm) Consumption cooperation by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 印 ^ Γ45 Α7 _Β7_ V. Description of the invention (3) CI purple pigment 19, CI purple pigment 23, C, I. Purple pigment 29, CI purple pigment 32, CI purple pigment 36, CI purple pigment 38; CI red pigment 177, CI red pigment 202, CI red pigment 206, CI ocher pigment 207, CI red pigment 20δ, CI red pigment 20 9, CI red pigment 215, CI Red pigment 216, CI red pigment 220, CI red pigment 224, CI red pigment 226, CI red pigment 242, CI red pigment 243. CI red pigment 245, CI red pigment 254, CI red pigment 255, C. I. Red pigment 2 6 4. C. I. Red pigment 265; CI blue pigment 15, CI blue pigment 15: 3, CIM pigment 15: 4, CI blue pigment 15: 6; ( : .1. Green pigment 7, (: .1. Green pigment 36; CI black pigment 1, CI black pigment 7. These organic pigments can be used alone or in combination of two kinds of M. Specific examples of the aforementioned inorganic colorants include titanium oxide , Barium sulfate, calcium carbonate, zinc powder, lead sulfate, yellow lead, zinc yellow, red dandelion (red oxide (I®)), cadmium red, ultramarine green, turquoise green, chromium chloride green, cobalt green, amber, titanium Black, synthetic iron black, carbon black, etc. These inorganic colorants can be used alone or in combination of two kinds of M. In the present invention, each of the aforementioned colorants can be modified by adding M to the surface of its particles. Polymers whose surface has been modified include, for example, polymers contained in Japanese Patent Application Laid-Open No. 8-259876, and various pigment dispersion polymers or oligomers are commercially available. In addition, the coloring agent in the present invention may be shared with the dispersing agent as required. -5- I -------- Order · ---------t (Please read the precautions on the back before filling this page) This paper is applicable National Standard (CNS) A4 specification (2) 0x 297 mm) 412645 A7 _B7_ V. Description of the invention (4) These dispersants include, for example, cationic gadolinium, anionic, nonionic, amphoteric, silicon gallium, fluorine界面 and other surfactants. Specific examples of the aforementioned surfactants include: polyoxyethylene lauryl ether, polyoxyethylene stearin, and polyoxyethylene alkyl ether such as polyoxyethylene alkyl ethers; polyoxyethylene octyl benzyl ether, and polyoxyethylene nonylbenzene. Polyethylene oxide alkyl stupid ethers; Polyethylene glycol diesters such as polyethylene glycol dilaurate, polyethylene glycol distearate; sorbitan fatty acid esters; fatty acid modified polyesters Tertiary amines modified polyurethanes; polyethyleneimines, etc., with the following trade names outside Kappa: KP (Shinyue Chemical Industry Co., Ltd.), Bolivro (Kyoeisha Chemical Co., Ltd.), Yefu Top (Tuo Kum Product Co., Ltd.), Megafaku (Product of Dainippon Ink Chemical Industry Co., Ltd.), Fronado (Product of Sumitomo 3M Co., Ltd.), Asagado, Safron (Product of Asahi Glass Co., Ltd.), Dyespar-BYK (products of Becocome), EFKA-46 and 47 (products of EFKA company), 1 Liluth Pass (products of Inachi Corporation), etc. These surfactants can be used alone or in combination of two or more. With respect to 100 parts by weight of the colorant, the use amount of the interface: active agent M50 is preferably 50 parts by weight M, and more preferably 0 to 30 parts by weight. (Please read the precautions on the back before filling this page) Order one --------- Line-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 Its mono- and less acid) M Carboxylate Diethyl Oxygen Selection There is ene containing ^ ~-, the difference is 2 / IN. The purpose of the ai two tree is harmonious) ίι the ester-soluble base ethoxylated benzoic acid benzoyl monocarboxylic acid carboxylic acid and its co-ordination-r-body single performance official single The factory is called the body monomer, and the M / V body monomer is co-sexual.

稱 下 W 物 聚 I I _ 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） 412645 經濟部智慧財產局員工消費合作社印製 五、發明說明（5 ) 單官能性單體（bl)中的二羧酸，有例如乙二酸、丙二 酸、丁二酸、戊二酸、己二酸等C2〜C20.更好是C2 〜C 1〇脂族二羧酸類；六氫酞酸、六氫異酞酸、六氫對 肽酸等C?〜C 24,更好是C8〜C!4脂環族二羧酸類；駄 酸、異酞酸、對酞酸等C8〜C24,更好是C8〜C14芳族 二羧酸類。 此等二羧酸當中，M C2〜（：8脂族二羧酸為佳，而Μ 丁二酸最好。 本發明中，單官能性單體（bl)可單體或二種以上共同 使用。 前述其他可共聚合之單官能性單體.Μ可與單官能性 單體（bl)共聚合，具有1個聚合性不飽和鐽為佳，不限 於可與單官能性單體（bl)共聚合，且所得共聚物（B1)為 鹼溶性者，尤Μ單官能性單體（bl) Μ外具有1 上羧 基的簞官能性單體（以下稱「單官能性單體（b2)」）， 與不具有羧基的共聚合性單官能性單體（以下單稱「單 官能性單體（b3)」），所組成單體混合物為佳。 單官能性簞體（b2)有例如丙烯酸、異丁烯酸、丁烯酸 、α-氯丙烯酸、肉桂酸等不飽和單羧酸類；馬來酸、 馬來酐、富馬酸、衣康酸、衣康酐、檸樣酸、撺康酐、 中康酸等不飽和二羧酸及其酐類；三價Μ上不飽和多元 羧酸及其酐類；ω-羧基聚己内酯單丙烯酸酯、ω-狻基 聚己内酯單異丁烯酸酯等。 此等單官能性單體（b2)可單獨或二種Μ上共同使用。 -7 - (請先閱讀背面之注意事項再填寫本頁) ----訂-----------線— 本紙張尺度適用中國國家標準（CNS)M規格（2〗〇χ 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 A? _B7_五、發明說明（6 ) 另外，具有羧基之其他軍官能性單體（b3)有例如： 苯乙烯、α-甲基笨乙烯、鄰乙烯基甲笨、間乙烯基 甲笨、對乙烯基甲笨、對氯苯乙烯、鄰甲氧基苯乙烯、 間甲氧基苯乙烯、對甲氧基笨乙烯、茚、郯乙烯基苄基 甲醚、間乙烯基苄基甲醚、對乙烯基苄基甲醚、鄰乙烯 基苄基縮水甘油醚、間乙烯基苄基縮水甘油醚、對乙烯 基苄基縮水甘油醚等芳族乙烯基化合物；丙烯酸甲酯、 異丁烯酸甲_、丙烯酸乙酿、異丁烯酸乙酯、丙烯酸正 丙酷、異丁稀酸正丙酯、丙稀酸異丙醋、異丁稀酸異丙 酯、丙烯酸正丁酯、異丁烯酸正丁酯、丙烯酸異丁醅、 異丁烯酸異丁酯、丙烯酸次丁醅、異丁烯酸次丁酯、丙 烯酸特丁酯、異丁烯酸特丁酯、2-羥乙基丙烯酸酯、2-羥乙基異丁烯酸酯、2-羥丙基丙烯酸酯、2-羥丙基異丁 烯酸酯、3-羥丙基丙烯酸酯、3-羥丙基異丁烯酸酯、2-羥丁基丙烯酸酯、2-羥丁基異丁烯酸_、3-羥丁基丙烯 酸酯、3 -羥丁基異丁烯酸酯、4 -羥丁基丙烯酸酯、4 -羥 丁基異丁烯酸酯、丙烯酸烯丙酯、異丁烯酸烯丙酯、丙 (請先閱讀背面之注意事項再填寫本頁) 環烯酸酸烯烯烯 酸丙烯烯丙丙丙 稀基丙丙酵醇醇 丁乙基醇二 二 二 異基乙二 乙丙丙 、 氧基乙三基二 酿甲氧二基氧基 己2-笨基氧甲氧 環、2-氧甲、甲 酸酯、甲、酯、 輝苯酯、酯酸酯 丙酸酸酯酸烯酸 、 烯烯酸烯丁烯 醋 丁丁稀 丁異丁 ί卞異異 丁異醇異 酸、基異醇二醇 烯酯乙基二乙二 丁 笨基乙乙三丙 異酸氧基二基基 、 烯甲氧基氧氧 酯丙2-笨氧甲甲 ί卞、 、2-甲、 、 酸酷酯、、酷酯 烯己酸酯酯酸酸The following W 物 聚 II _ This paper size applies to the Chinese National Standard (CNS) A4 (210x 297 mm) 412645 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (5) Monofunctional monomer (bl ), For example, C2 ~ C20, such as oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, etc., more preferably C2 ~ C 10 aliphatic dicarboxylic acids; hexahydrophthalic acid Acid, hexahydroisophthalic acid, hexahydropeptidic acid, etc. C? ~ C24, more preferably C8 ~ C! 4 alicyclic dicarboxylic acids; acetic acid, isophthalic acid, terephthalic acid, etc. C8 ~ C24, More preferred are C8 to C14 aromatic dicarboxylic acids. Among these dicarboxylic acids, M C2 ~ (: 8 aliphatic dicarboxylic acid is preferable, and M succinic acid is most preferable. In the present invention, the monofunctional monomer (bl) may be used alone or in combination of two or more kinds. The aforementioned other copolymerizable monofunctional monomers. M can be copolymerized with the monofunctional monomer (bl), preferably having one polymerizable unsaturated hydrazone, not limited to being compatible with the monofunctional monomer (bl) Copolymerization, and the obtained copolymer (B1) is alkali-soluble, especially a monofunctional monomer (bl), a fluorene functional monomer having a carboxyl group other than 1 (hereinafter referred to as "monofunctional monomer (b2)" ), And a copolymerizable monofunctional monomer having no carboxyl group (hereinafter referred to as "monofunctional monomer (b3)"), a monomer mixture is preferred. The monofunctional carbohydrate (b2) has, for example, acrylic acid , Methacrylic acid, butenoic acid, α-chloroacrylic acid, cinnamic acid and other unsaturated monocarboxylic acids; maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, citrate-like acid, panconic anhydride, Unsaturated dicarboxylic acids such as mesaconic acid and their anhydrides; unsaturated polycarboxylic acids and their anhydrides at trivalent M; ω-carboxy polycaprolactone monoacrylate, ω -Fluorenyl polycaprolactone monomethacrylate, etc. These monofunctional monomers (b2) can be used alone or in combination of two kinds of M. -7-(Please read the precautions on the back before filling this page)- --- Order ----------- Line — This paper size is applicable to China National Standard (CNS) M specification (2〗 〇χ297mm) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 412645 A _B7_ V. Explanation of the invention (6) In addition, other military functional monomers (b3) having a carboxyl group include, for example, styrene, α-methylbenzyl, o-vinylmethylbenzyl, m-vinylmethylbenzyl, Vinyl methylbenzyl, p-chlorostyrene, o-methoxystyrene, m-methoxystyrene, p-methoxybenzyl ethylene, indene, fluorene vinyl benzyl methyl ether, m-vinyl benzyl methyl ether, Aromatic vinyl compounds such as vinyl benzyl methyl ether, o-vinyl benzyl glycidyl ether, m-vinyl benzyl glycidyl ether, p-vinyl benzyl glycidyl ether; methyl acrylate, methyl methacrylate, acrylic acid Brewery, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isobutyl acrylate Isopropyl, n-butyl acrylate, n-butyl methacrylate, isobutyl methacrylate, isobutyl methacrylate, succinyl acrylate, butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, 2- Hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, 2 -Hydroxybutyl acrylate, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, Allyl acrylate, Allyl methacrylate, Propylene (Please read the notes on the back before filling out this page) Cycloalkenoic Acrylic Acrylic Acrylic Acrylic Propionyl Alcohol Butyl Alcohol 222 Isoethylene ethylene dipropylene propylene, oxyethylene triyl dimethyl methoxydiyloxyhexyl 2-benzyloxymethoxy ring, 2-oxomethyl, formate, formazan, ester, phenidyl ester, ester acid Ester Propionate, Ethylene Acrylic Acid, Ethylene Acrylic Acid Diethylenedibutylbenzylethylenetripropionateoxydiyl, dimethoxybenzyloxybenzyl 2-benzyloxybenzyl, 2,2-methyl, succinate, bisester Acid ester

It — —— — «ΙΓ11Ι — — — — 1 — llulllllllllllll-lli -t __ 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 a； _B7_五、發明說明（7 ) 酸酯、甲氧基二丙二酸異丁烯酸酯、異冰片i丙烯酸酷 、異冰片基異丁烯酸酯、二環戊二烯基丙烯酸酯、二環 戊二烯基異丁烯酸酯、2-羥基-3-苯氧基丙基丙烯酸酯 、2 -羥基-3 -苯氧基丙基異丁烯酸酯、丙三醇單丙烯酸 酷、丙三醇單異丁烯酸酯等不飽和羧酸酯類； 2-氨乙基丙烯酸酯、2-氨乙基異丁烯酸酯、2-二甲基 氨乙基丙烯酸酯、2-二甲基氨乙基異丁烯酸酯、2-氨丙 基丙烯酸酯、2 -氨丙基異丁烯酸酯、2 -二甲基氨丙基丙 烯酸醅、2-二甲基氨丙基異丁烯酸酯、3-氨丙基丙烯酸 酯、3-氨丙基異丁烯酸酿、3-二甲基氨丙基丙烯酸酯、 3 -二甲基氨丙基異丁烯酸酯等不飽和羧酸氨烷酯類； 丙烯酸縮水甘油_、異丁烯酸酯縮水甘油酯等不飽和 (請先閱讀背面之注意事項再填寫本頁) 烯 乙 酸 甲 笨 r 酯 烯 乙 酸 丁 ' 酯 烯 乙 ; 酸 類丙 醅、 油酯 甘烯 水乙 縮酸 酸乙 梭 丁 異 醚 油 甘 水 縮 基 丙 烯 r 醚 乙 基 ; 烯 類乙 醋、 烯醚 乙甲 酸基 羧烯 等乙 酯 0 和 飽、 不腈 等烯 醚丁 油異 甘、 水腈 縮烯 基丙 烯 α 類 氰 等 氰 二 叉 烯 乙 ' 腈 烯 丙 氯 胺 醯 和 包 不 等 胺0 烯 α 丁 、 異 胺基 醃乙 烯羥 ·* 1 ~~- 2 物異Ν-合、、 化胺胺 基醯醯 烯烯烯 乙丙丙 化 基 胺 醢 烯 丙 氯 乙 羥 類 亞 烯 醯 二 來 軛 馬 共 基；族 己類脂 環胺等 Ν-亞烯 、 醯二 胺和丁 亞飽氯 醯不、 來等烯 馬胺二 基醯間 笨來戊 Ν-馬異 和代、 胺取烯 亞被二 醯的丁 來類3- 7\ 3Λ 馬之 1’ 胺 本紙張尺度適用中國國家標準（CNS)A4規格（2】〇χ 297公釐） -訂il·------線— 412645 A7 經濟部智慧財產局員工消費合作社印*'1^ B7_五、發明說明（8 ) 類； 聚苯乙烯、聚丙烯酸甲酯、聚異丁烯酸甲酯、聚丙烯 酸正丁酯、聚異丁烯酸正丁酯、聚矽氧烷等在聚合物分 子鐽末端具有單丙烯醯基或單異丁烯醸基之巨分子單體 類等。 此等其他單官能性單體可單獨或二種以上共同使用。 共聚物（B1)特別K單官能性單體（bl),含有丙烯酸和 /或異丁烯酸* Μ及視情形含ω-羧基聚己内酯單丙 烯酸酯和/或w-羧基聚己内酯單異丁烯酸酯之單官能 性單體（b2), Μ及選自苯乙烯、丙烯酸甲酿、異丁烯酸 甲酯、2-羥乙基丙烯酸醅、2-羥乙基異丁烯酸酯、丙烯 酸苄酯、異丁烯酸苄酿、丙烯酸笨酯、異丁烯酸笨酿、 丙三醇單丙烯酸酯、丙三醇單異丁烯酸酯、Ν-笨基馬來 醯亞胺、聚笨乙烯巨分子單體、和聚異丁烯酸甲酯巨分 子單體之至少一種單體（b3)之共聚物（以下稱「鹼溶性 樹脂（I )」）為佳。 鹼溶性樹脂（I )具體例如下： (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯共聚物、 (甲基）丙烯酸/簞官能性單體（bl) /笨基（甲基）丙烯 酸酯共聚物等三聚物（Μ下稱「鹼溶性樹脂（I a)」）； (甲基）丙烯酸/單官能性單體（b 1) /苯乙烯/苄基 (甲基）丙烯酸酷共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/苯基 -1 0- (請先閱讀背面之注意事項再填寫本頁) 一訂il·------線- 本紙張尺度適用t國國家標準（CNS)A4規格（2]0 297公釐） 1 412645 A7 經濟部智慧財產局員工消費合作社印制私 _B7五、發明說明（9 ) (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/ N-苯基 馬來醯亞胺共聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 _苄基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯苯基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2 -羥乙基（甲基） 丙烯酸酯/节基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2 -羥乙基（甲基） 丙烯酸酯/苯基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯/笨基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸醑 /單官能性單體（bl) /苄基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯/丙二醇單（甲基）丙烯酸酿共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯/聚笨乙烯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯/聚異丁烯酸甲_巨分子單體共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯輩（甲基）丙烯酸酯 /單官能性單體（bl) /笨基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性簞體（bl) /苯基（甲基）丙烯 ~ 1 1 (請先閱讀背面之注意事項再填寫本頁) - _ .---------訂----------線！It — — — — «ΙΓ11Ι — — — — 1 — llulllllllllllllll-lli -t __ This paper size applies to China National Standard (CNS) A4 (210x 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 a; _B7_V. Description of the invention (7) Ester, methoxydimalonic acid methacrylate, isobornyl acrylic acid, isobornyl methacrylate, dicyclopentadienyl acrylate, dicyclopentadiene Methyl methacrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-hydroxy-3-phenoxypropyl methacrylate, glycerol monoacrylate, glycerol monomethacrylate, etc. Saturated carboxylic acid esters; 2-aminoethyl acrylate, 2-aminoethyl methacrylate, 2-dimethylaminoethyl acrylate, 2-dimethylaminoethyl methacrylate, 2-aminopropyl Acrylate, 2-aminopropyl methacrylate, 2-dimethylaminopropyl methacrylate, 2-dimethylaminopropyl methacrylate, 3-aminopropyl acrylate, 3-aminopropyl methacrylate Unsaturated carboxylic acids such as acid brewing, 3-dimethylaminopropyl acrylate, 3-dimethylaminopropyl methacrylate Alkyl esters; Acrylic glycidyl _, methacrylic acid glycidyl ester and other unsaturated (Please read the precautions on the back before filling in this page) Methyl acetoacetate r Ester butyl acetoacetate Ethyl acetate Ester Glycol Hydrogen Ethyl Acetate Isobutyl Isoether Oil Glycol Glycol Propyl Ether Ethyl; Ethyl Ethyl Acetate, Ethyl Ethyl Acetate Carboxy Carboxene Ethyl Ethyl Ethyl Acetate, Ethyl Acetate Carboxy Carboxy Carboxene, etc. Isocyanuric acid, nitrile alkenyl propylene α-type cyanide, and other cyanodialkylene ethylene 'nitrile allyl chloramine 醯 and unequal amines 0 olefin α butyl, isoamine pickled ethylene hydroxy · * 1 ~~-2 N-Amine, Amine, Amine, Alkenyl, Ethylene, Propyl, Amine, Allyl, Chloride, Ethylene, Diene Conjugate; N-alkylene, alicyclic amines, etc. Diamines and butylated chlorinated bis, lysedenylamine diyl, stilbenyl pentamidine, N-methylisobutadiene, amines and diamines, butadienes, butylated 3-7 \ 3Λ horse's 1 'amines This paper size is applicable to China National Standard (CNS) A4 specification (2) 〇χ 297 mm-order il · ------ line 412645 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs * '1 ^ B7_V. Description of invention (8) Category: polystyrene, polymethyl acrylate, polymethyl methacrylate, poly-n-butyl acrylate, polymethacrylic acid Macromolecular monomers such as n-butyl ester, polysiloxane, and the like having a monopropenyl group or a monoisobutylene group at the polymer molecule terminal. These other monofunctional monomers may be used alone or in combination of two or more. Copolymer (B1) is a special K monofunctional monomer (bl) containing acrylic acid and / or methacrylic acid * M and optionally ω-carboxyl-containing polycaprolactone monoacrylate and / or w-carboxyl polycaprolactone mono Monofunctional monomer (b2) of methacrylate, M and selected from styrene, methyl acrylate, methyl methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxyethyl methacrylate, benzyl acrylate, Benzyl methacrylate, stearic acid acrylate, stearic acid methacrylate, glycerol monoacrylate, glycerol monomethacrylate, N-benzyl maleimide, polyethylene macromonomer, and polyisobutylene A copolymer of at least one monomer (b3) of the methyl ester macromonomer (hereinafter referred to as "alkali-soluble resin (I)") is preferred. Specific examples of the alkali-soluble resin (I) are as follows: (meth) acrylic acid / monofunctional monomer (bl) / benzyl (meth) acrylate copolymer, (meth) acrylic acid / fluorene functional monomer (bl) Terpolymers such as / benzyl (meth) acrylate copolymers (hereinafter referred to as "alkali-soluble resin (I a)"); (meth) acrylic acid / monofunctional monomer (b 1) / styrene / benzyl (Meth) acrylic acid cool copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / phenyl-1 0- (Please read the precautions on the back before filling this page) Order il · ------ Line-This paper size is applicable to the national standard (CNS) A4 specification (2) 0 297 mm 1 412645 A7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs _B7 V. Description of the invention (9) (meth) acrylic acid ester copolymer, (meth) acrylic acid / monofunctional monomer (bl) / Styrene / N-phenylmaleimide copolymer, (meth) acrylic acid / monofunctional Monomer (bl) / (meth) acrylic acid-benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / (meth) acrylate benzene (Meth) acrylic acid ester copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (meth) acrylate / synthyl (meth) acrylate copolymer, (formyl) Group) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (meth) acrylate / phenyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / Benzyl (meth) acrylate / benzyl (meth) acrylate copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylic acid fluorene / monofunctional monomer (bl) / Benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / benzyl (meth) acrylate / propylene glycol mono (meth) acrylic acid copolymer, (meth) ) Acrylic acid / monofunctional monomer (bl) / benzyl (meth) acrylate / polyethylene macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / benzyl (formaldehyde) Base) acrylate / polymethacrylic acid_macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone (meth) acrylate / monoglyceride Functional monomer (bl) / benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional carbohydrate (bl) / phenyl (meth) acrylic acid ~ 1 1 (Please read the back Please fill in this page again for attention)-_ .--------- Order ---------- Online!

t I tf Γ· I n I I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 41^645 A7 _B7_ 五、發明說明C1。） 酸酯/丙三醇（甲基）丙烯酸酯共聚物、 (請先閱讀背面之注意事項再填寫本頁) (甲基）丙烯酸/單官能性翬體（bl) /笨基（甲基）丙烯 酸酯/聚苯乙烯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯基（甲基）丙烯 酸酯/聚異丁烯酸酯巨分子單體共聚物等四聚物（以下 稱「鹼溶性樹脂（I a)」）。 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ (甲基） 丙烯酸甲酯/苄基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/ (甲基） 丙烯酸甲酯/苯基（甲基）丙烯酸醅共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ (甲基） 丙烯酸甲_/}^ -笨基馬來豳亞胺共聚物' (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苄基（甲基）丙烯酸_共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苯基（甲基）丙烯酸_共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/ 2-羥乙 基（甲基）丙烯酸酯/ N-笨基馬來醯亞胺共聚物、 經濟部智慧財產局員Η消費合作社印製 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/苄基 (甲基）丙烯酸酿/笨基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/ <y-羧基聚己內酯單（甲基）丙烯酸酯 /單官能性單體（bl) /笨乙烯/苄基（甲基）丙烯酸酯共 聚物、 (甲基）丙烯酸/單官能性簞體（bl) /笨乙烯/苄基 -12- 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） A7 412645 _B7_ 五、發明說明（11 ) (請先閱讀背面之注意事項再填寫本頁) (甲基）丙烯酸酯/丙三醇單（甲基）丙烯酸醋共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/苄基 (甲基）丙烯酸酯/聚苯乙烯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/苄基 (甲基）丙烯酸酯/聚異丁烯酸甲酯巨分子單體共聚物、 (甲基）丙烯酸/ ω-狻基聚己内酯單（甲基）丙烯酸_ /單官能性單體（bl) /笨乙烯/笨基（甲基）丙烯酸酯共 聚物、 (甲基）丙浠酸/單官能性單體（bl) /笨乙烯/苯基 (甲基）丙烯酸酯/丙三醇單（甲基）两烯酸酿共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/笨基 (甲基）丙烯酸酯/聚苯乙烯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/苯基 (甲基）丙烯酸酯/聚異丁烯酸甲酯巨分子單體共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯簞（甲基）丙烯酸酯 /單官能性單體（bl) /苯乙烯/ Ν-笨基馬來醯亞胺共聚 物、 經濟部智慧財產局員工消費合作社印製 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ N-笨基 馬來醯亞胺/丙三醇單（甲基）丙烯酸_共聚物、 (甲基）丙烯酸/單官能性單體（b 1 ) /笨乙烯/1苯基 馬來醯亞胺/聚苯乙烯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/ N-笨基 馬來醯亞胺/聚異丁烯酸甲酯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 -13- 本紙張尺度適用中國國家標準（CNS)A4規格（2〗〇χ 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 A7 _B7_五、發明說明（12 ) 酯/ 2-羥乙基（甲基）丙烯酸酯/苄基（甲基 > 丙烯酸酯共 聚物、 (甲碁）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯/ 2-羥乙基（甲基）丙烯酸酯/苯基（甲基）丙烯酸酯共 聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯/苄基（甲基）丙烯酸酯/笨基（甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸酯 /單官能性單體（bl)/ (甲基）丙烯酸甲醅/苄基（甲基） 丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯/苄基（甲基）丙烯酸酯/丙三醇（甲基）丙烯酸酯共聚 物、 (申基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯/苄基（甲基）丙烯酸酯/聚笨乙烯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯/苄基（甲基）丙烯酸酯/聚異丁烯酸甲酯巨分子單體 共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸酯 /單官能性單體（bl) / (甲基）丙烯酸甲酯/苄基（甲基） 丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酿/苯基（甲基）丙烯酸酯/丙三醇單（甲基）丙烯酸酯共 聚物、 -14- (請先閱讀背面之注意事項再填寫本頁) 訂-----------線— 本纸張尺度過用中國國家標準（CNSM4规格（210^ 297公釐） 412645 A7 B7 五、發明說明（13 經濟部智慧財產局員工消費合作社印製 (甲基）丙烯酸/單官能性單體（bl) / (甲基Ί丙烯酸甲 酯/苯基（甲基）丙烯酸酯/聚笨乙烯巨分子單體共聚物 (甲基）丙烯酸/單官能性單體（bl) / (甲基）丙烯酸甲 酯/苯基（甲基）丙烯酸酯/聚異丁烯酸甲酯巨分子單體 共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2-羥乙基（甲基） 丙烯酸酿/苄基（甲基）丙烯酸酯/苯基（甲基）丙烯酸酯 共聚物、 (甲基）丙烯酸/ 羧基聚己内酯單（甲基）丙烯酸酯 /單官能性單體（bl)/2 -羥乙基（甲基）丙烯酸酯/苄基 (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體Π>1)/2-羥乙基（甲基） 丙烯酸酿/苄基（甲基）丙烯酸酷/丙三醇單（甲基）丙烯 酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2-羥乙基（甲基） 丙烯酸_ /节基（甲基）丙烯酸酯/聚笨乙烯巨分子單體 共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2-羥乙基（甲基） 丙烯酸酯/芣基（甲基）丙烯酸酯/聚異丁烯酸甲醅巨分 子單體共聚物、 (甲基）丙烯酸/ ω-羧基聚己內酯單（甲基）丙烯酸_ /單官能性單體（bl)/2-羥乙基（甲基）丙烯酸酯/苯基 (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2-羥乙基（申基） -15 一 本纸張尺度適用中國國家標準（CNS)A4規格（2]ϋχ 297公1 ) -請 先 閱 讀 —背 之 注 意 秦 項 再 填 寫 頁 412645 A7 經濟部智慧財產局員工消費合作社印製 _B7_五、發明說明（u) 丙烯酸酯/苯基（甲基）丙烯酸酯/丙三醇（甲基）丙烯 酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2 -羥乙基（甲基） 丙烯酸酯/苄基（甲基）丙烯酸酯/聚苯乙烯巨分子單體 共聚物、 (甲基）丙烯酸/單官能性單體（bl)/2-羥乙基（甲基） 丙烯酸酯/苄基（甲基）丙烯酸酯/聚異丁烯酸甲醅巨分 子單體共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸酯 /單官能性單體（bl) /苄基（甲基）丙烯酸酯/苯基（甲 基）丙烯酸酷共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯/笨基（甲基）丙烯酸酯/丙三醇（甲基）丙烯酸酯-共聚物、 (甲基）丙烯酸/軍官能性單體（bl) /苄基（甲基）丙烯 酸酯/笨基（甲基）丙烯酸酯/聚笨乙烯巨分孑單體共聚 物、 (甲基）丙烯酸/單官能性單體（bl) /苄基（甲基）丙烯 酸酯/苯基（甲基）丙烯酸酯/聚異丁烯酸甲酯巨分子單 體共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸酯 /單官能性簞體（bl) /苄基（甲基）丙烯酸酯/丙三酵單 (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸酯 _ 1 6 — <請先閱讀背面之注意事項再填寫本頁) ---------訂.-----------線 — 本紙張尺度適用中國國家標準<CNS)A4规格（2]0 X 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 A7 _B7_五、發明說明（15 ) /單官能性單體（bl) /苄基（甲基）丙烯酸酯/聚笨乙稀 巨分子單體共聚物、 (甲基）丙烯酸/ 〇>-羧基聚己内酷單（甲基）丙烯酸_ /單官能性單體（bl) /苄基（甲基）丙烯酸酯/聚異丁稀 酸甲酯巨分子單體共聚物、 (甲基）丙烯酸/ ω -羧基聚己内酯單（甲基）丙烯酸酯 /單官能性單體（bl) /苯基（甲基）丙烯酸酯/丙三醇單 (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸_ /單官能性單體（bl) /苯基（甲基）丙烯酸酯/聚笨乙烯 巨分子單體共聚物、 (甲基）丙烯酸/ ω-羧基聚己内酯單（甲基）丙烯酸酯 /單官能性單體（bl) /苯基（甲基）丙烯酸酯/聚異丁烯 酸甲酯巨分子單體共聚物等五聚物（Μ下稱「鹼溶性樹 脂（Ic)」）； (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苄基（甲基）丙烯酸酯/丙三醇單 (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苄基（甲基）丙烯酸酯/ N-笨基馬來 醯亞胺共聚物、 (甲基）丙烯酸/單官能性輩體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苄基（甲基）丙烯酸酯/聚苯乙烯巨 分子單體共聚物、 -17- (請先閱讀背面之注意事項再填窝本頁) 訂 ^-------線！ 本紙張尺度適用中國®家標準（CNSM4規格⑵Ο X 297公釐） 經濟部智慧財產局員工消費合作社印利衣 412645 A7 _B7_五、發明說明（16 ) (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苄基（甲基）丙烯酸酯/聚異丁烯酸 甲酯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酷/苯基（甲基）丙烯酸酯/丙三醇單 (甲基）丙烯酸酯共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/ 2-羥乙 基（甲基）丙烯酸醅/笨基（甲基）丙烯酸酯/ N-苯基馬來 醯亞胺共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苯基（甲基）丙烯酸酯/聚笨乙烯巨 分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/ 2-羥乙 基（甲基）丙烯酸酯/苯基（甲基）丙烯酸酯/聚異丁烯酸 申酯巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/苄基 (甲基）丙烯酸酯/丙三醇單（甲基）丙烯酸酯/ N-笨基馬 來醢亞胺共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/苄基 (甲基）丙烯酸酷/丙三醇單（甲基）丙烯酸酯/聚苯乙烯 巨分子單體共聚物、 (甲基）丙烯酸/單官能性單體（bl) /苯乙烯/芣基 (甲基）丙烯酸酯/丙三醇單（甲基）丙烯酸酯/聚異丁烯 酸甲酯巨分子單體共聚物、 一 1 8 - 請先閱讀背面之注意事項再填寫本頁)t I tf Γ · I n I I The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 41 ^ 645 A7 _B7_ V. Description of the invention C1. ) Ester / glycerol (meth) acrylate copolymer, (Please read the notes on the back before filling this page) (meth) acrylic acid / monofunctional carbohydrate (bl) / benzyl (meth) Tetramerization of acrylate / polystyrene macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / phenyl (meth) acrylate / polymethacrylate macromonomer copolymer, etc. (Hereinafter referred to as "alkali-soluble resin (I a)"). (Meth) acrylic acid / monofunctional monomer (bl) / styrene / (meth) acrylic acid methyl ester / benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl ) / Styrene / (meth) acrylic acid methyl ester / phenyl (meth) acrylic acid fluorene copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / (meth) acrylic acid methacrylate // } ^-Benyl maleimide imine copolymer '(meth) acrylic acid / monofunctional monomer (bl) / styrene / 2-hydroxyethyl (meth) acrylate / benzyl (meth) acrylic acid _Copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / 2-hydroxyethyl (meth) acrylate / phenyl (meth) acrylic acid_copolymer, (meth) acrylic acid / Monofunctional monomer (bl) / Styrene / 2-Hydroxyethyl (meth) acrylate / N-Styryl maleimide / imine copolymer, Printed by Consumer Cooperatives, Member of Intellectual Property Bureau, Ministry of Economic Affairs ) Acrylic acid / monofunctional monomer (bl) / styrene / benzyl (meth) acrylic acid / benzyl (meth) acrylate copolymer, (meth) acrylic acid < y-carboxy polycaprolactone (Meth) acrylic acid ester / monofunctional monomer (bl) / Styrene / benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional carcass (bl) / Styrene / benzyl -12- This paper size is in accordance with China National Standard (CNS) A4 (210x 297 mm) A7 412645 _B7_ V. Description of the invention (11) (Please read the notes on the back before filling this page) (Meth) acrylate / Glycerol mono (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / benzyl (meth) acrylate / polystyrene macromonomer copolymer , (Meth) acrylic acid / monofunctional monomer (bl) / styrene / benzyl (meth) acrylate / polymethyl methacrylate macromonomer copolymer, (meth) acrylic acid / ω-fluorenyl Polycaprolactone mono (meth) acrylic acid // monofunctional monomer (bl) / Styrene / benzyl (meth) acrylate copolymer, (meth) propanoic acid / monofunctional monomer (bl ) / Styrene / Phenyl (meth) acrylate / Glycerol mono (meth) diene acid copolymer, (meth) acrylic acid / monofunctional monomer ( bl) / Styrene / Styryl (meth) acrylate / polystyrene macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / phenyl (meth) acrylic acid Ester / polymethacrylate macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone 己 (meth) acrylate / monofunctional monomer (bl) / styrene / N-benzyl Copolymer of maleimide, printed by (Meth) acrylic acid / monofunctional monomer (bl) / styrene / N-benzylmaleimide / glycerol Mono (meth) acrylic acid_copolymer, (meth) acrylic acid / monofunctional monomer (b 1) / Styrene / 1 phenylmaleimide / polystyrene macromonomer copolymer, (A Group) acrylic acid / monofunctional monomer (bl) / Styrene / N-benzylmaleimide / polymethylmethacrylate macromonomer copolymer, (meth) acrylic acid / monofunctional monomer ( bl) / (meth) acrylic acid-13- This paper size applies to China National Standard (CNS) A4 (2〗 〇χ297 mm) Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Print 412645 A7 _B7_ V. Description of the invention (12) Ester / 2-hydroxyethyl (meth) acrylate / benzyl (meth) acrylate copolymer, (formamidine) acrylic acid / monofunctional monomer (Bl) / methyl (meth) acrylate / 2-hydroxyethyl (meth) acrylate / phenyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / (Meth) acrylate / benzyl (meth) acrylate / benzyl (meth) acrylate copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate / mono Functional monomer (bl) / formyl (meth) acrylate / benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / (meth) acrylate / Benzyl (meth) acrylate / glycerol (meth) acrylate copolymer, (Shenyl) acrylic acid / monofunctional monomer (bl) / (meth) acrylate / benzyl (meth) Acrylate / polyethylene macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / methyl (meth) acrylate / benzyl (meth) propylene Ester / polymethylmethacrylate macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate / monofunctional monomer (bl) / (meth) acrylic acid Methyl ester / benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / (meth) acrylic acid methyl ester / phenyl (meth) acrylate / glycerol mono (Meth) acrylate copolymer, -14- (Please read the precautions on the back before filling this page) Order ----------- Line — This paper has been used in accordance with Chinese National Standards (CNSM4 Specifications (210 ^ 297 mm) 412645 A7 B7 V. Description of the invention (13 Printed by (meth) acrylic acid / monofunctional monomer (bl) / (methyl methacrylate) / Phenyl (meth) acrylate / polyethylene macromonomer copolymer (meth) acrylic acid / monofunctional monomer (bl) / methyl (meth) acrylate / phenyl (meth) acrylate / Polymethyl methacrylate macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (meth) acrylic acid / (Meth) acrylate / phenyl (meth) acrylate copolymer, (meth) acrylic acid / carboxy polycaprolactone mono (meth) acrylate / monofunctional monomer (bl) / 2-hydroxy Ethyl (meth) acrylate / benzyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer Π > 1) / 2-hydroxyethyl (meth) acrylic acid / benzyl (Meth) acrylic acid / glycerol mono (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (meth) acrylic acid (Meth) acrylate / polyethylene macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (meth) acrylate / fluorenyl (meth) acrylic acid Ester / polymethacrylic acid formamidine macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylic acid // monofunctional monomer (bl) / 2-hydroxyethyl ( Meth) acrylate / phenyl (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (shenyl) -15 One paper size applicable National Standard (CNS) A4 Specification (2) ϋχ 297 Male 1)-Please read it first-note Qin Xiang and then fill out page 412645 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs_B7_ V. Description of Invention (u) Acrylate / phenyl (meth) acrylate / glycerol (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2 -hydroxyethyl (meth) acrylate / Benzyl (meth) acrylate / polystyrene macromonomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / 2-hydroxyethyl (meth) acrylate / benzyl ( Methacrylic acid ester / polymethacrylic acid formamidine macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate / monofunctional monomer (bl) / benzyl (Meth) acrylic acid ester / phenyl (meth) acrylic acid copolymer, (meth) acrylic acid / monofunctional monomer (bl) / benzyl (meth) acrylate / benzyl (meth) acrylate / Glycerol (meth) acrylate-copolymer, (meth) acrylic acid / military functional monomer (bl) / benzyl (meth) Acrylate / Styryl (meth) acrylate / Polyethylene macro-tiller monomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / benzyl (meth) acrylate / phenyl ( (Meth) acrylate / polymethylmethacrylate macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate / monofunctional carbohydrate (bl) / benzyl (Meth) acrylate / glycerol mono (meth) acrylate copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate_ 1 6 — < Please read the back first Please pay attention to this page before filling in this page) --------- Order .----------- Line — This paper size is applicable to China National Standard < CNS) A4 Specification (2) 0 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 A7 _B7_ V. Description of the invention (15) / Monofunctional monomer (bl) / Benzyl (meth) acrylate / Polyethylene giant Monomer copolymer, (meth) acrylic acid / 〇 > -carboxy polycaprolactone mono (meth) acrylic acid // monofunctional monomer (bl) / benzyl (meth) acrylate / polyisobutyleneMethyl ester macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate / monofunctional monomer (bl) / phenyl (meth) acrylate / glycerin Alcohol mono (meth) acrylate copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylic acid // monofunctional monomer (bl) / phenyl (meth) acrylate / Polystyrene macromonomer copolymer, (meth) acrylic acid / ω-carboxy polycaprolactone mono (meth) acrylate / monofunctional monomer (bl) / phenyl (meth) acrylate / poly Pentamers such as methyl methacrylate macromonomer copolymer (hereinafter referred to as "alkali-soluble resin (Ic)"); (meth) acrylic acid / monofunctional monomer (bl) / styrene / 2-hydroxyethyl (Meth) acrylate / benzyl (meth) acrylate / glycerol mono (meth) acrylate copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / 2- Hydroxyethyl (meth) acrylate / benzyl (meth) acrylate / N-benzyl maleimide copolymer, (meth) acrylic acid / monofunctional precursor (bl) / phenethyl Ene / 2-hydroxyethyl (meth) acrylate / benzyl (meth) acrylate / polystyrene macromonomer copolymer, -17- (Please read the precautions on the back before filling this page) Order ^ ------- line! This paper size is in accordance with Chinese standards (CNSM4 specification ⑵〇 X 297 mm) Employees ’Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, India Liyi 412645 A7 _B7_ V. Description of the invention (16) (meth) acrylic acid / monofunctional monomer (Bl) / styrene / 2-hydroxyethyl (meth) acrylate / benzyl (meth) acrylate / polymethyl methacrylate macromonomer copolymer, (meth) acrylic acid / monofunctional mono (Bl) / styrene / 2-hydroxyethyl (meth) acrylate / phenyl (meth) acrylate / glycerol mono (meth) acrylate copolymer, (meth) acrylic acid / monofunctional Monomer (bl) / Styrene / 2-Hydroxyethyl (meth) acrylate / Styrene (meth) acrylate / N-phenylmaleimide copolymer, (meth) acrylic acid / mono Functional monomer (bl) / styrene / 2-hydroxyethyl (meth) acrylate / phenyl (meth) acrylate / polyethylene macromonomer copolymer, (meth) acrylic acid / monofunctional Monomer (bl) / styrene / 2-hydroxyethyl (meth) acrylate / phenyl (meth) acrylate / polymethacrylate Monomer copolymer, (meth) acrylic acid / monofunctional monomer (bl) / benzyl ethylene / benzyl (meth) acrylate / glycerol mono (meth) acrylate / N-benzyl malein Imine copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / benzyl (meth) acrylic acid / glycerol mono (meth) acrylate / polystyrene macromonomer Copolymer, (meth) acrylic acid / monofunctional monomer (bl) / styrene / fluorenyl (meth) acrylate / glycerol mono (meth) acrylate / polymethyl methacrylate macromonomer Copolymer, 1-18-Please read the notes on the back before filling this page)

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H 1' I —- I ί 1 I 本紙張尺度適用中國國家標準（CNS)A4規格（2]0 U97公釐） 412645 A7 B7 五、發明說明（17: 經濟部智慧財產局員工消費合作社印製 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/苯基 (甲基）丙烯酸酿/丙三醇單（甲基）丙烯酸酯/ N-苯基馬 來醢亞胺共聚物、 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/苯基 (甲基）丙烯酸醋/丙三醇單（甲基）丙烯酸酯/聚苯乙烯 巨分子單體共聚物、或 (甲基）丙烯酸/單官能性單體（bl) /笨乙烯/笨基 (甲基）丙烯酸酯/丙三醇單（甲基）丙烯酸酯/聚異丁烯 酸甲酯巨分子單體共聚物等六聚物下稱「鹼溶性樹 脂（I d)」）等。 本發明前述鹼溶性樹脂（I a)、鹼溶性樹脂（I b)、鹼 溶性樹脂（I c)和鹼溶性樹脂（I d)當中，其構成成份之 單官能性單體（bl), Μ 丁二酸單（2 -丙烯醯氧乙酯）和/ 或丁二酸單（2 -異丁烯醯氧乙酯）之樹脂最好。 共聚物（Β1)中的單官能性單體（b 1)共聚合比例，Μ 5 〜35重量S：為佳，而Μ 1〇〜25重量％更好。此時，單官 能性單體（bl)之共聚合比例在5重量$以下時，未曝光 部基板上或遮光層上有發生殘渣、污染之處，另方面， 超過35重童S；時，利用鹼顯像液顯像之際，所形成圖素 有容易從基板脫落的傾向。 另外，共聚物（B1)係由單官能性單體（bl)與單官能性 單體（b2)及其他不飽和單體共聚時，單官能性單體（b2) 之共聚合比例，以5〜50重量％為佳，而K 10〜40重量！I： 更好，其他不飽和單體之共聚合比例，K15〜90重量％ -19- 本紙張尺度適用中國國家標準（CNS)A4規格（2]〇χ 297公釐） -請 先 閱 讀 —背 面 之 注 意 $ 項 再 填 寫 本 頁 訂 線 經濟部智慧財產局員工消費合作社印製 412645 A7 _B7_五、發明說明（18 ) 為佳，而以35〜80重量！S更好。此時，單官能性單體 U2)之共聚合比例在5重量％ Μ下時，所得幅照敏感性 姐成物對鹼顯像液之溶解性有降低傾向，另方面若超過 50重量％ ，利用鹼顯像液顯像時，所形成圖素有從基板 脫落或圖素表面容易變粗糙的傾向。含單官能性單體 (b 2 )和單官能性單體（b 1)共同在前述特定共聚合比例之 共聚物（B1),對鹼顯像液具有優良溶解性，使用該共聚 物為黏合劑之幅照敏感性組成物，利用鹼顯像液顧像後 ,極少殘存未溶解物，在未曝光部的基板上或遮光層上 ,很難發生殘渣、污染等，而該組成物所得圖素，不會 過剩溶解於鹼顯像液，對基板具有優異接觸性，無從基 板脫落之虞。 前述共聚物（B1)可單獨或二種K上共同使用。 本發明可視情形，於該共聚物（B1)併用其他鹼溶性樹 脂0 前述其他鹼溶性樹脂有例如：具有羧基、酚系羥基等 酸性官能基之樹脂。 此類其他鹼溶性樹睢Μ具有羧基的樹脂為佳。更好的 共聚物（Β1)例為單官能性單體（b2)與前述單官能性單體 之共聚物，尤K丙烯酸和/或異丁烯酸之外，視情況另 含有ω-羧基聚己内酯單丙烯酸酯和/或ω-羧基聚己内 酯單異丁烯酸酯之單官能性單體（b2),與選自笨乙烯、 丙烯酸甲酯、異丁烯酸甲酷、2 -羥乙基丙烯酸酯、2 -羥 乙基異丁烯酸酯、丙烯酸烯丙酯、異丁烯酸丙酯、苄基 — 20- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中1國家標準（CNS)A4规格（210x 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 A7 _R7_五、發明說明（19 ) 丙烯酸_、苄基異丁烯酸酯、丙三醇單丙烯i酯、丙三 醇異丁烯酸酯、N -笨基馬來醯胺、聚笨乙烯巨分子單體 和聚異丁烯酸甲酯巨分子單體等至少一種化合物之共聚 物（以下稱「鹼溶性樹脂U )」）為佳。 鹼溶性樹脂（I )具體例有： (甲基）丙烯酸/ (甲基）丙烯酸甲酯共聚物、 (甲基）丙烯酸/(甲基）丙烯酸苄酯共聚物、 (甲基）丙烯酸/(甲基）丙烯酸甲酯/聚苯乙烯巨分子 單體共聚物、 (甲基）丙烯酸/(甲基）丙烯酸甲酯/聚異丁烯酸甲酯 巨分子單體共聚物、 (甲基）丙烯酸/(甲基）丙烯酸苄酯/聚苯乙烯巨分子 單體共聚物、 (甲基）丙烯酸/(甲基）丙烯酸苄酯/聚異丁烯酸甲酯 巨分子單體共聚物、 (甲基）丙烯酸/ 2-羥乙基（甲基）丙烯酸甲酿/(甲基） 丙烯酸苄酯共聚物、 (甲基）丙烯酸/ 2-羥乙基（甲基）丙烯酸甲酯/(甲基） 丙烯酸苄酯/聚笨乙烯巨分子單體共聚物、 (甲基）丙烯酸/ 2-羥乙基（甲基）丙烯酸甲酯/(甲基） 丙烯酸苄酯/聚異丁烯酸甲酯巨分子單體共聚物、 (甲基）丙烯酸/笨乙烯/異丁烯酸苄酯/ N-笨基醯亞 胺共聚物、 (甲基）丙烯酸/ ω-羧基聚己內酯單（甲基）丙烯酸酯 -21 - (請_先閱讀1面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（2W X 297公釐） 412645 A7 經濟部智慧財產局員工消費合作社印制衣 B7_五、發明說明（2〇 ) /(甲基）丙烯酸烯丙酯/ N-苯基醯亞胺共聚物、 (甲基）丙烯酸/苯乙烯/異丁烯酸苄酯/丙三醇（甲 基）丙烯酸酯/ H-笨基馬來醢亞胺共聚物等。 此等鹼溶性樹脂（I )可單獨或二種K上併用。 前述其他鹼溶性樹脂使用時之該樹脂使用量，相對於 鹼溶性樹脂合計量Μ 5 0重量ίΚ Μ下為佳，而以3 0重量S： Μ下更好。此時，其他鹼溶性樹脂使用量超出50重量％ 時，未曝光部基板上或遮光層上有容易發生殘渣、污染 等之傾向。 本發明鹼溶性樹脂令共聚物（Β1)為必要戊份，構成該 鹼溶性樹脂的各成份經凝膠滲透層析法（GPC ,溶提溶 劑為四氫呋喃）所得，換算聚笨乙烯重量平均分子量 (Μ下簡稱「重量平均分子量」）Κ3,000〜300,000為 佳，而Μ 5,000〜100,000尤佳。使用具有如此特定重量 平均分子量之鹼溶性樹脂，可得顯像性優良的幅照敏感 性组成物，因而可形成具有明銳圖邊的圖素，同時顯像 時，在未曝光部的基板上或遮光層上很難發生殘渣、污 染、殘膜等。本發明中鹸溶性樹脂的使用量，相對於 (Α)著色劑100重量份，Μ 10〜：！，000重量份為佳，而 Κ20〜500重量份更好。此時，鹼溶性樹脂使用量在1〇 重量份Μ下時，有例如鹼顯像性降低，未曝光部基板上 或遮光層上發生殘渣、污染之虞，另方面，超過1,000 重星份時，相對地著色劑濃度會降低，因薄膜有時難以 達成所要標的之色濃度。 -22- (請先閱讀背面之注意事項再填窝本頁) 本紙張尺度適用令國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 a； _B7_五 '發明說明（21 ) (C )多官能件匿體 J . 本發明中之多官能性單體，係具有聚合性不飽和鍵二 個Μ上之單體，其例有： 乙二醇、丙二醇等烷二醇之二丙烯酸酷或二異丁烯酸 酯類； 聚乙二醇、聚丙二酵等聚烷二醇之二丙烯酸酯或二異 丁烯酸酷類； 丙三醇、三羥甲基丙烷、季戊四醇、二季戊四醇等三 元Μ上的多元醇之聚丙烯酸酯或聚異丁烯酸酯類，或其 二羧酸改質物； 聚酯、環氧樹脂、氨基甲酸乙醋樹脂、醇酸樹脂、矽 嗣樹脂、螺烷樹脂等寡丙烯酸酯或寡異丁烯酸酯類； 兩末端羥基聚-1,3 -丁二烯、兩末端羥基聚異戊間二 烯、兩末端羥基聚己内酯等兩末端羥基化聚合物之二丙 烯酸酯或二異丁烯酸酯類，或 三（2-丙烯醢氧乙基）磷酸酯、三（2-異丁醯氣乙基） 磷酸酯等。 此等多官能性單體當中，三元Κ上的多元醇之聚丙烯 酸酯或聚異丁烯酸酯類，Κ其二羧酸改質物為佳。具體 例有：三羥甲基丙烷三丙烯酸酯、三羥甲基丙烷三異丁 烯酸酯、季戊四醇三丙烯酸酯、季戊四醇三異丁烯酸酯 、季戊四醇四丙烯酸酯、季戊四醇四異丁烯酸酯、二季 戊四醇五丙烯酸酯、二季戊四醇五異丁烯酸酯、二季戊 四醇六丙烯酸酯、二季戊四醇六異丁烯酸酯，Κ下式0) -23- (-if先閱讀'f面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） 412645 A7 經濟部智慧財產局員工消費合作社印製 B7五、發明說明（22 ) 所示化合物等為佳。尤其是以三羥甲基丙烷三丙烯酸酷 、季戊四醇三丙烯酸酯和二季戊四醇六丙烯酸酯為佳， 因其圖素強度高，圖素表面的平滑性優，且未曝光部的 基板上或遮光層上，難Μ發生污染、殘膜等。 CHj OOCCH=CH2 HOOCCH2 CH2 COOCH—C — CH2 OOCCH=CH2 ···〇) CH2 oocch=ch2 前述多官能性單體可單獨或二種K上併用。 另外，在本發明中可視情形，與該多官能性單體併用 單官能性單體。 此等單官能性單體之具體例，除就共聚物（B1)所舉例 單官能性單體（b2)或前述其他單官能性單體之外，憑有 市售品M-5400, M-5600 (商品名，東亞合成公司製品） 等。 此等單官能性單體可單獨或二種Μ上併用。 前述單官能性單體使用比例，相對於多官能性單體和 單官能性單體之合量，Μ 90重童％ Κ下為佳，而Μ0〜 50重童S；更好。此時，單官能性單體使用比例超過90重 量％時，所得圖素的強度或表面平滑性有不足之虜。 本發明中多官能性單體和單官能性單體之合計使用量 ，相對於（Β )鹸溶性樹脂1 0 〇重量份，Μ 5〜5 0 0重量份 為佳，而以20〜300重量份更好。在此情況下，前述使 用量不超過5重量份時，圖素強度和表面平滑性有降低 傾向，另方面超過500重量份時，例如鹼顯像性降低時 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（2〗0^297公釐） 412645 A7 --_B7_ 五、發明說明（23 ) ，在未曝光部的基板上或遮光層上，有容易_生污染、 殘膜等的傾向。 (m 光聚合引锻割 本發明中的光聚合引發劑，指會因可見光線、紫外線 、遠紫外線、電子線、X射線等的曝光而分解，或键破 裂、Μ自由基、陽離子、陰離子等開始發生前述（C)多 官能性單體聚合之活性種的化合物。 此等光聚合引發劑除具有Μ下式（2)、式（3)或式⑷所示 為主幹之至少一種骨架構造的二眯唑糸化合物之外，尚 有苯偶姻糸化合物、乙醯笨系化合物、二苯甲_系化合 物、〇[-二_糸化合物、多核醒糸化合物、咕噸_系化 合物、三嗪糸化合物、磷系化合物等。 (請先閱讀.背面之注意事項再填寫本頁) ..訂Γ-I ^ OJ-pllllllll — III (Γ (IIII Γ —-111! H 1 'I —- I ί 1 I This paper size applies to China National Standard (CNS) A4 specifications (2) 0 U97 mm) 412645 A7 B7 V. Description of the invention (17: Printed by (meth) acrylic acid / monofunctional monomer (bl) / Styrene / phenyl (meth) acrylic acid / glycerol mono (A) Base) acrylate / N-phenylmaleimide copolymer, (meth) acrylic acid / monofunctional monomer (bl) / Styrene / phenyl (meth) acrylate / glycerol mono (methyl) Base) acrylate / polystyrene macromonomer copolymer, or (meth) acrylic acid / monofunctional monomer (bl) / Styrene / Styryl (meth) acrylate / Glycerol mono (methyl) ) Hexamers such as acrylate / polymethacrylate macromonomer copolymers are hereinafter referred to as "alkali-soluble resins (I d)"), etc. The aforementioned alkali-soluble resins (I a) and alkali-soluble resins (I b ), Alkali-soluble resin (I c) and alkali-soluble resin (I d), the monofunctional monomer (bl), Μ succinate mono (2-propenyloxyethyl) And / or succinic acid mono (2-isobutylene ethoxylate) resin is the best. The copolymerization ratio of the monofunctional monomer (b 1) in the copolymer (B1), M 5 to 35 weight S: better M is more preferably 10 to 25% by weight. At this time, when the copolymerization ratio of the monofunctional monomer (bl) is less than 5% by weight, residues and contamination occur on the substrate of the unexposed portion or on the light-shielding layer. On the other hand, when it exceeds 35 weights S, when the image is developed using an alkali developer, the formed pixels tend to fall off from the substrate. In addition, the copolymer (B1) is composed of a monofunctional monomer (bl When copolymerizing with the monofunctional monomer (b2) and other unsaturated monomers, the copolymerization ratio of the monofunctional monomer (b2) is preferably 5 to 50% by weight, and K 10 to 40% by weight! I: Better, the proportion of copolymerization of other unsaturated monomers, K15 ~ 90% by weight -19- This paper size applies to China National Standard (CNS) A4 specifications (2) 〇χ 297 mm)-Please read first-Note on the back $ Item, fill in this page and print the line Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 A7 _B7_ V. Description of the Invention (18) It is better, but 35 ~ 80 weight! S is even better. At this time, when the copolymerization ratio of the monofunctional monomer U2) is at 5% by weight Μ, the obtained radiation sensitivity of the product to the alkali imaging solution Solubility tends to decrease. On the other hand, if it exceeds 50% by weight, the developed pixel tends to fall off the substrate or the surface of the pixel tends to become rough when developed with an alkali developer. Monofunctional monomers (b 2 ) And the monofunctional monomer (b 1) together with the copolymer (B1) in the aforementioned specific copolymerization ratio, has excellent solubility in an alkali imaging solution, and uses the copolymer as a radiation-sensitive composition for an adhesive, After dissolving the image with an alkali imaging solution, there is very little undissolved matter remaining. On the substrate or the light-shielding layer of the unexposed part, residues and pollution are difficult to occur, and the pixel obtained by the composition will not be excessively dissolved in the alkali solution. The image liquid has excellent contact with the substrate, and there is no risk of falling off the substrate. The aforementioned copolymer (B1) can be used alone or in combination of two kinds. In the present invention, depending on the situation, other copolymers of alkali-soluble resin are used in the copolymer (B1). The other alkali-soluble resins include resins having acidic functional groups such as carboxyl group and phenolic hydroxyl group. Such other alkali-soluble resins having a carboxyl group are preferred. Examples of better copolymers (B1) are copolymers of the monofunctional monomer (b2) and the aforementioned monofunctional monomer, especially K acrylic acid and / or methacrylic acid, and optionally contain ω-carboxy polycaprolactone Monofunctional monomer (b2) of ester monoacrylate and / or ω-carboxy polycaprolactone monomethacrylate, and selected from the group consisting of styrene, methyl acrylate, methyl methacrylate, 2-hydroxyethyl acrylate , 2 -Hydroxyethyl methacrylate, allyl acrylate, propyl methacrylate, benzyl — 20- (Please read the precautions on the back before filling this page) This paper is applicable to China National Standard (CNS) A4 Specifications (210x 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 A7 _R7_ V. Description of the invention (19) Acrylic acid, benzyl methacrylate, glycerol monopropene ester, glycerol methacrylate A copolymer of at least one compound such as an ester, N-benzylmaleimide, a polybenzyl macromonomer, and a polymethacrylate macromonomer (hereinafter referred to as "alkali-soluble resin U") is preferred. Specific examples of the alkali-soluble resin (I) include (meth) acrylic acid / (meth) methacrylate copolymer, (meth) acrylic acid / (meth) acrylic acid benzyl copolymer, (meth) acrylic acid / (formaldehyde) Based) methyl acrylate / polystyrene macromonomer copolymer, (meth) acrylic acid / methyl (meth) acrylate / polymethyl methacrylate macromonomer copolymer, (meth) acrylic acid / (methyl Based) benzyl acrylate / polystyrene macromonomer copolymer, (meth) acrylic acid / benzyl (meth) acrylate / polymethyl methacrylate macromonomer copolymer, (meth) acrylic acid / 2- Copolymer of methyl hydroxyethyl (meth) acrylate / benzyl (meth) acrylate, (meth) acrylic acid / methyl 2-hydroxyethyl (meth) acrylate / benzyl (meth) acrylate / polybenzyl Ethylene macromonomer copolymer, (meth) acrylic acid / 2-hydroxyethyl (meth) acrylate / (meth) benzyl acrylate / polymethacrylate macromonomer copolymer, (methyl ) Acrylic acid / Styrene / Benzene methacrylate / N-benzylimine copolymer, (meth) acrylic acid / ω-carboxy polyhexylene Ester Mono (meth) acrylate 21-(Please _ read the precautions on 1 side before filling out this page) This paper size applies to China National Standard (CNS) A4 (2W X 297 mm) 412645 A7 Wisdom of the Ministry of Economic Affairs Printed clothing B7 of the Consumer Cooperative of the Property Bureau. V. Description of the invention (20) / (meth) acrylic acid allyl / N-phenylphosphonium imine copolymer, (meth) acrylic acid / styrene / benzyl methacrylate Ester / glycerol (meth) acrylate / H-benzylmaleimide copolymer. These alkali-soluble resins (I) can be used alone or in combination of two kinds. The amount of the resin used when the other alkali-soluble resins are used is better than the total amount of the alkali-soluble resins at M 50 weight, and more preferably at 30 weight S: M. At this time, when the amount of the other alkali-soluble resin used exceeds 50% by weight, residues, contamination, etc. tend to occur on the substrate of the unexposed portion or on the light-shielding layer. The alkali-soluble resin of the present invention makes the copolymer (B1) an essential amount, and each component constituting the alkali-soluble resin is obtained by gel permeation chromatography (GPC, extraction solvent is tetrahydrofuran), and the weight average molecular weight of polyethylene is converted ( Hereinafter referred to as "weight average molecular weight") K3,000 to 300,000 is preferred, and 5,000 to 100,000 is particularly preferred. By using an alkali-soluble resin having such a specific weight-average molecular weight, a radiation-sensitive composition having excellent developability can be obtained, and thus a pixel having a sharp pattern edge can be formed. At the same time, when developing, on a substrate of an unexposed portion or Residues, contamination, and residual films are unlikely to occur on the light-shielding layer. The usage-amount of the water-soluble resin in this invention is M 10 ~: with respect to 100 weight part of (A) colorants. It is preferably 10,000 parts by weight, and κ 20 to 500 parts by weight is more preferable. At this time, when the amount of the alkali-soluble resin used is 10 parts by weight, there is a possibility that, for example, alkali developability is lowered, and residues and contamination may occur on the substrate of the unexposed portion or on the light-shielding layer. Relatively, the concentration of the colorant will decrease, and it is sometimes difficult for the film to achieve the desired color concentration. -22- (Please read the precautions on the back before filling in this page) This paper size is applicable to the national standard (CNS) A4 (210 X 297 mm) of the country. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 a; _B7_ Five 'Description of the Invention (21) (C) Polyfunctional body J. The polyfunctional monomer in the present invention is a monomer having two polymerizable unsaturated bonds on M, examples of which include: Diacrylates or dimethacrylates of alkanediols such as alcohols and propylene glycol; Diacrylates or dimethacrylates of polyalkanediols such as polyethylene glycol and polymalonase; glycerol, trimethylol Propane, pentaerythritol, dipentaerythritol and other polyhydric alcohols such as polyacrylates or polymethacrylates, or their dicarboxylic acid modifications; polyesters, epoxy resins, urethane resins, alkyd resins, Oligoacrylates or oligomethacrylic acid esters such as silicone resins and spiro resins; two terminal hydroxyl poly-1,3-butadiene, two terminal hydroxyl polyisoprene, two terminal hydroxyl polycaprolactone, etc. Diacrylate or dimethacrylate of terminal hydroxylated polymer , Or tris (2-acryloyl oxyethyl Dukes) phosphate, tris (2-isobutoxy acyl gas ethyl) phosphate. Among these polyfunctional monomers, polyacrylic acid esters or polymethacrylic acid esters of polyhydric alcohols on trivalent K are preferred, and K is a dicarboxylic acid modified product. Specific examples are: trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol pentaacrylate , Dipentaerythritol pentamethacrylate, dipentaerythritol hexaacrylate, dipentaerythritol hexamethacrylate, K below formula 0) -23- (-if read the precautions on the f side before filling out this page) This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) 412645 A7 The B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the compounds shown in the description of invention (22) are preferred. In particular, trimethylolpropane triacrylate, pentaerythritol triacrylate, and dipentaerythritol hexaacrylate are preferred. Because of its high pixel strength, the smoothness of the pixel surface is excellent, and on the substrate or light-shielding layer of the unexposed portion On the other hand, it is difficult to cause contamination, residual film, and the like. CHj OOCCH = CH2 HOOCCH2 CH2 COOCH—C — CH2 OOCCH = CH2 ··· 〇) CH2 oocch = ch2 The aforementioned multifunctional monomers can be used alone or in combination of two kinds of K. In the present invention, a monofunctional monomer may be used in combination with the polyfunctional monomer as the case may be. Specific examples of these monofunctional monomers include commercially available products M-5400, M-, in addition to the monofunctional monomer (b2) exemplified for the copolymer (B1) or the aforementioned other monofunctional monomers. 5600 (trade name, manufactured by Toa Kosei), etc. These monofunctional monomers may be used singly or in combination of two kinds. The use ratio of the aforementioned monofunctional monomer is better than M90% by weight and K0% by weight relative to the total amount of the polyfunctional monomer and the monofunctional monomer, and M0 to 50% by weight; more preferably. In this case, when the use ratio of the monofunctional monomer exceeds 90% by weight, the strength or surface smoothness of the obtained pixel is insufficient. The total amount of the polyfunctional monomer and the monofunctional monomer used in the present invention is preferably 5 to 500 parts by weight, and 20 to 300 parts by weight relative to 100 parts by weight of the (B) osmotic resin. Serving is better. In this case, when the amount used is not more than 5 parts by weight, the pixel strength and surface smoothness tend to decrease. On the other hand, when the amount exceeds 500 parts by weight, such as when the alkali developability is reduced (please read the precautions on the back first) (Fill in this page) This paper size is in accordance with Chinese National Standard (CNS) A4 specification (2〗 0 ^ 297 mm) 412645 A7 --_ B7_ V. Description of the invention (23) on the substrate of the unexposed part or on the light-shielding layer, There is a tendency to easily cause pollution, residual film, and the like. (m Photopolymerization) The photopolymerization initiator in the present invention refers to decomposition due to exposure to visible light, ultraviolet, far ultraviolet, electron rays, X-rays, or bond breakage, M radicals, cations, anions, etc. Compounds of the above-mentioned active species of (C) polyfunctional monomer polymerization start. These photopolymerization initiators have at least one backbone structure represented by the following formula (2), formula (3) or formula ⑷. In addition to dioxazonium compounds, there are benzoin compounds, acetophenone compounds, dibenzoyl compounds, 〇 [-di_fluorene compounds, polynuclear compounds, gluten compounds, and triazines Europium compounds, phosphorus compounds, etc. (Please read. Note on the back before filling out this page) .. Order Γ

-線' 經濟部智慧財產局員工消費合作社印*'1^ 前述二咪唑糸化合物具體例有：2,2’-雙（2-氯笨基）-4,4\5,5’-四（4-乙氧基碳醯笨基）-1,2二眯哇、2,2’ -雙（2-溴笨基）-4, 4',5,5〜四（4 -乙氧基碳醢笨基）-1, 2二咪唑、2,2’-雙（2,4-二氯笨基）-4,4，，5,5’-四苯 基-1,2' -二眯唑、2,2、雙（2,4,6 -三氯笨基）-4,4',5, 本紙張尺度適用中國國家標準（CNS)A4規格⑵(U297公釐） A7 412645 B7__ 五、發明說明（24) (請先閱讀背面之注意事項再填寫本頁) 5、四苯基-1,2' -二睬唑、2.2’ -雙（2,4 -二溴笨基）-4, 4，，5,5'-四笨基-1,2’ -二眯唑、和 2,2’-雙（2 ,4,6 -三溴 笨基）-4,4’，5,5、四苯基-1,2‘-二眯唑等。 前述二眯唑糸化合物對溶劑之溶解性優，不會產生未 溶解物、析出物等異物，且敏感度高，K很少能量曝光 即可充分進行硬化反應，對比高，因未曝光部不發生硬 化反應，故曝光後的塗膜，明確分成對顔像液不溶性之 硬化部份，和對顯像液具有高度溶解性的未硬化部份， 因此，無底割的圖素圖型可形成按預定排列配置之高精 细圖素行列。 另外，前述苯偶姻系化合物具體例有•苯偶姻、笨偶 絪甲醚、苯偶姻乙醚、苯偶姻異丙醚、笨偶姻異丁醚、 2-笨甲醯笨甲酸甲酯等。 經濟部智慧財產局員工消費合作社印製 前述乙醯苯糸化合物具體例有：2,2-二甲氧基-2-笨 基乙醢苯、2-羥基-2-甲基-1-笨基丙-1-酮、1-U-異丙 基笨基）-2-羥基-2-甲基丙-卜嗣、4-(2-羥基乙氧基）苯 基- (2-羥基-2-丙基）甲·、2, 2-二甲氧基乙醯苯、2,2-二乙氧基乙醯笨、2-甲基- (4-甲基硫代苯基）-2-嗎啉-1 -丙卜_、2-苄基-2-二甲基氨基-1-U-嗎啉並苯基)丁-1 -酮、1-羥基環己基笨基甲_、2,2 -二甲氧基-1,2 -二苯 基乙-1-酮等。 前述二笨甲_系化合物具體例有：4,4'-雙（二甲基氨 基）二笨甲酮、4,4' -雙（二乙基氨基）二苯甲_等。 前述ct-二酮糸化合物之具體例，有二乙醯、二笨甲 -26- 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） 412645 A7 經濟部智慧財產局員Η消費合作社印則衣 _E7_五、發明說明（25 ) 醯、甲基苯甲酿基甲酸酯等。 < ' 前述多核匿糸化合物具體例有饈醍、2 -乙基蒽酲、2-特丁基憩醍、1 , 4-萘醇等。 前述咕噸系化合物具體例有阽啼·酮、喀噸_、 2 - 氯喀噸嗣等。 前逑三嗪糸化合物具體例有1,3,5-三（三氯甲基）-5-三嗪、1,3-雙（三氯甲基）-5-(2氯苯基）~s-三嗪、1,3-雙（三氯甲基）-5-(4氯苯基）-s-三嗪、1,3-雙（三氯甲 基）-5-(2，-甲氧基笨基）-s-三嗪、1,3-雙（三氯甲基）-5 -U'-甲氧基苯基）-s-三嗪、2-(2’-呋喃基乙叉）-4,6-雙（三氯甲基）-s-三嗪、2-(f-甲氧基笨乙烯基）-4,6-雙（三氯甲基）-s-三嗦、2-(3’，4’-二甲氧基笨乙烯基）-4,6-雙（三氯甲基）-s-三嗪、2-U’-甲氧基萘基）-4,6-雙（三氯甲基）-s -三嗪、2-(2'-溴-4、甲基赛基）-4,6-雙（三氯甲基）-s-三嗪、2-(2'_硫代苯基乙叉）-4,6-雙 (兰氯甲基）-s-三嗪等。 前述磷化合物有卵磷脂等，以及商品名為IRGANOX 1700,和δ19(Μ上為汽巴特殊化學公司製品）。 此等光聚合引發劑可單獨或二種Μ上併用。 本發明中光聚合引發劑使用量，相對於（C )多官能性 輩體和視情形所用單官能性單體合計1 〇 〇重量份，Μ 0.01〜200重量份為佳，1〜120重量份更好，而以1〜100 重量份最佳。此時，光聚合引發劑使用量在〇.〇1重量份 以下時，因暘光使硬化不充分，很難獲得圖素圖型按預 _ 2 7 — (讀先閱讀背面之.注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)AO見格⑵0x 297公釐） 412645 A7 B7 經濟部智慧財產局員Η消費合作社印製 五、發明說明（6 ) 定排列配置的圖素行列，另方面超過2 0 Q重量份時，形 成的圖素在顯像時容易從基板脱落，旦在未曝光部的基 板上或遮光層上容易産生污染、殘膜等。 再者，在本發明中，前述光聚合引發劑可視需要併用 增感劑、硬化促進劑或高分子交聯、増烕劑一種以上。 本發明中的光聚合引發劑，特別可用二眯唑糸化合物 與乙醯苯糸化合物和/或二苯甲酮糸化合物之組合物， 則形成之圖素在顯像時很難從基板脱落，有利於圖素強 度和感度高。 本發明中，光聚合引發劑的二眯唑条化合物與其他成 份併用時，其他成份的使用比例以佔光聚合引發劑全體 的δ Q重量3!以下為佳。 於此，本發明中特佳光聚合引發劑以其構成成份的組 合表示，具體例如下： 2,2夂雙（2-氣苯基）-4,4',5,5’-四（4-乙氣基磺醯苯 基}-1，2'-二咪唑/ 4, 4'-雙（二乙氛基）二苯甲酮、 2,2、雙（2-氛苯基）-4,4'，5,5'-四（4-乙氣基磺 醯苯基）-1, 2'-二眯唑/ 4, 4'-雙（二乙氨基）二苯甲_/ 2-苄基-2-二甲氨基-1-(4-嗎啉並苯基）丁-卜_、 2y -雙（2 -氛苯基）-4,4八5,5’ -四（4 -乙氣基碩醯苯 基二咪唑/ 4,1-雙（二乙氨基）二苯甲酮/ 1-羥基環己基苯基甲酮、 2 ,2'-雙（2,4-二氣苯基）-4,4', 5,5' -四苯基-1,2、二 眯唑/ 4,4夂雙（二乙氛基）二苯甲酮、 -2 8 - (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 412645 A7 B7 五、發明說明（27 2,2、雙（2,4-二氯笨基卜4,4’，5,S’-四苯基-1,2’-二 眯唑/ 4, 4’-雙（二乙氨基）二笨甲苄基-2 -二甲氨 基-1-(4 -嗎啉並笨基）丁 -1-酮、 2,2'-雙（2,4-二溴苯基）-4, 4’，5,5’-四苯基-1,2’-二 咪唑/ 4,4’-雙（二乙氨基）二苯甲_/2-苄基-2-二甲氨 基-1-(4-嗎啉並笨基）丁-卜酮、 2, 2’-雙（2, 二溴笨基）-4,4，，5,5，-四苯基-1,2'-二 -請 先 閱 讀 背 之 注 經濟部智慧財產局員工消費合作社印製 眯唑/ 4 , 4 ’ 基甲酮。 添加酬 本發明滤 種添加劑。 前述添加 照敏感性組 存有未溶解 此等有機 基的羧酸為 前述脂族 甲酸、乙 乙基乙酸、 乙二酸、 、辛二酸、 、乙基丙二 二酸、環己 '雙（二乙氨基）二笨甲_/1-羥基瓌己基苯 色片用幅照敏感性組成物.可視需要含有各 劑可資一提者為有機酸，可改善濾色片用幅 成物，對鹼顯像液之溶解性，又因顯像後殘 物，而顯示抑制作用。 酸以分子量在1.000 K下的脂族羧酸或含笨 佳。 羧酸之具體例有： 酸、丙酸、丁酸、戊酸、特戊酸、己酸、二 庚酸、辛酸等單羧酸類； 丙二酸、丁二酸、戊二酸、己二酸、庚二酸 壬二酸、癸二酸、十三烷二酸、甲基丙二酸 酸、二甲基丙二酸、甲基丁二酸、四甲基丁 二酸、衣康酸、檸康酸、馬來酸、富馬酸、 -29- 本紙張尺度通用中國國家標準（CNS)A4規格（210^ 297公釐） 項 再 填 本 頁 412645 A7 經濟部智慧財產局員工消費合作社印製 B7_五、發明說明（28 ) 中康酸等二羧酸類； 丙三羧酸、丙烯三羧酸、樟腦三酸等三羧酸類等。 另，前述含笨基羧酸有羧基直接速接於苯基的芳族接 酸，或羧基藉碳鏈結合於苯基之羧酸等，具體例有笨甲 酸、笨乙酸、枯酸、半采酸、采林酸等芳族單羧酸類； 酞酸、異酞酸、對酤酸等芳族三羧酸類； 笨偏三酸、笨均三酸、笨偏四酸、笨均四酸等三元μ 上的芳族聚狻酸類，或 笨基乙酸、氫化眄托酸、氫化肉桂酸、扁桃酸、笨基 丁二酸、阿托酸、肉桂酸、肉桂叉酸、香豆酸、激形酸 等。 此等有機酸當中Μ丙二酸、己二酸、衣康酸、檸檬酸 、富馬酸、中康酸、酞酸等脂族二羧酸類和芳族二羧酸 類為佳，基於鹼溶性，下述對溶劑之溶解性，在未曝光 部基板上或遮光層上可防污染或殘膜。 該有機酸可單獨或二種以上併用。 有機酸使用量相對於幅照敏感性組成物全體而言，Μ 10重量5Κ Κ下為佳，而Μ 5重量$以下更好，尤Ml重 量无以下最好，此時，若有機酸用量超過10重量,對 所形成圖素基板之接觸性有降低之虡。 另外，前述有機酸以外的添加劑具體例有： 酞花青銅衍生物等青色顔料衍生物或黃色顔料衍生物 等分散肋劑； 玻璃、氧化鋁等填料； (請先間讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（2]0 X 297公釐） 412645 A7 β7 五、發明說明（29-Line 'Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs *' 1 ^ Specific examples of the aforementioned diimidazolium compounds are: 2,2'-bis (2-chlorobenzyl) -4,4 \ 5,5'-tetra ( 4-Ethoxycarbylbenzyl) -1,2 dioxin, 2,2'-bis (2-bromobenzyl) -4, 4 ', 5,5 ~ tetra (4-ethoxycarbinyl) (Benzyl) -1,2 diimidazole, 2,2'-bis (2,4-dichlorobenzyl) -4,4,5,5'-tetraphenyl-1,2'-dioxazole, 2,2, double (2,4,6 -trichlorobenzyl) -4,4 ', 5, This paper size is applicable to China National Standard (CNS) A4 specifications (U297 mm) A7 412645 B7__ 5. Description of the invention (24) (Please read the notes on the back before filling this page) 5. Tetraphenyl-1,2'-dioxazole, 2.2'-bis (2,4-dibromobenzyl) -4, 4, , 5,5'-tetrabenzyl-1,2'-dioxazole, and 2,2'-bis (2,4,6-tribromobenzyl) -4,4 ', 5,5, tetrabenzene -1,2'-dioxazole and the like. The aforementioned oxazolyl compound has excellent solubility in solvents, does not generate foreign matters such as undissolved matter and precipitates, and has high sensitivity. K hardly reacts sufficiently with little energy exposure. The contrast is high because the unexposed part is not A hardening reaction occurs, so the coating film after exposure is clearly divided into a hardened part that is insoluble in the image solution and an unhardened part that is highly soluble in the developing solution. Therefore, a pixel pattern without undercut can be formed High-resolution pixels arranged in a predetermined arrangement. In addition, specific examples of the aforementioned benzoin-based compounds include benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, and 2-benzyl methyl benzoate. Wait. Specific examples of the aforementioned acetophenone compounds printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs are: 2,2-dimethoxy-2-benzylacetophenone, 2-hydroxy-2-methyl-1-benzyl Propan-1-one, 1-U-isopropylbenzyl) -2-hydroxy-2-methylpropane-butanone, 4- (2-hydroxyethoxy) phenyl- (2-hydroxy-2- (Propyl) methyl ·, 2,2-dimethoxyacetanilide, 2,2-diethoxyacetamidine, 2-methyl- (4-methylthiophenyl) -2-morpholine -1 -propanyl, 2-benzyl-2-dimethylamino-1-U-morpholinophenyl) butan-1-one, 1-hydroxycyclohexylbenzylmethyl, 2,2-di Methoxy-1,2-diphenylethyl-1-one and the like. Specific examples of the dibenzyl-based compound include 4,4'-bis (dimethylamino) dibenzone, 4,4'-bis (diethylamino) dibenzo- and the like. Specific examples of the aforementioned ct-diketone hydrazone compounds are diethyl hydrazone and dibenzyl -26. This paper is sized to the Chinese National Standard (CNS) A4 (210x 297 mm) 412645 A7, member of the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperative Yin Zeyi _E7_ V. Description of the Invention (25) Pyrene, methyl benzoate, etc. < 'Specific examples of the aforementioned polynuclear concealed compound include fluorene, 2-ethylanthracene, 2-tert-butylphosphonium, 1,4-naphthol, and the like. Specific examples of the above-mentioned glutathione-based compound include cyprotonone, ketene, 2-chloro ketene, and the like. Specific examples of pro-triazine compounds include 1,3,5-tris (trichloromethyl) -5-triazine and 1,3-bis (trichloromethyl) -5- (2chlorophenyl) ~ s -Triazine, 1,3-bis (trichloromethyl) -5- (4chlorophenyl) -s-triazine, 1,3-bis (trichloromethyl) -5- (2, -methoxy Methylbenzyl) -s-triazine, 1,3-bis (trichloromethyl) -5 -U'-methoxyphenyl) -s-triazine, 2- (2'-furylethylidene) -4,6-bis (trichloromethyl) -s-triazine, 2- (f-methoxybenzylvinyl) -4,6-bis (trichloromethyl) -s-triamidine, 2- (3 ', 4'-dimethoxybenzylvinyl) -4,6-bis (trichloromethyl) -s-triazine, 2-U'-methoxynaphthyl) -4,6-bis (Trichloromethyl) -s-triazine, 2- (2'-bromo-4, methylsialyl) -4,6-bis (trichloromethyl) -s-triazine, 2- (2 ' _Thiophenylethylidene) -4,6-bis (bluechloromethyl) -s-triazine and the like. The aforementioned phosphorus compounds include lecithin and the like, as well as the trade names IRGANOX 1700, and δ19 (the product of Ciba Specialty Chemicals Co., Ltd.). These photopolymerization initiators can be used singly or in combination of two kinds. The amount of the photopolymerization initiator used in the present invention is 100 parts by weight with respect to the total amount of the (C) polyfunctional precursor and the monofunctional monomer used as appropriate, preferably 0.01 to 200 parts by weight, and 1 to 120 parts by weight. Even more preferred is 1 to 100 parts by weight. At this time, when the photopolymerization initiator is used in an amount of less than 0.01 parts by weight, the hardening is not sufficient due to calendering, and it is difficult to obtain the pixel pattern. (This page) Applicable to Chinese National Standards (CNS) AO (see 0x297 mm) on this paper scale. 412645 A7 B7 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperative. 5. Description of the invention (6) Pixels in a fixed arrangement. When it exceeds 20 Q parts by weight, the formed pixels easily fall off from the substrate during development, and contamination and residual film are easily generated on the substrate or the light-shielding layer of the unexposed portion. In the present invention, the photopolymerization initiator may be used in combination with one or more sensitizers, hardening accelerators, or polymer crosslinkers and tinctures, if necessary. The photopolymerization initiator in the present invention may be a combination of a oxazolidine compound and an acetophenone compound and / or a benzophenone hydrazone compound. The formed pixel is difficult to fall off from the substrate during development. Conducive to high pixel intensity and sensitivity. In the present invention, when the oxazole compound of the photopolymerization initiator is used in combination with other components, the use ratio of the other components is preferably δQ weight of 3! Or less with respect to the entire photopolymerization initiator. Here, the particularly preferred photopolymerization initiator in the present invention is represented by a combination of its constituent components, and the specific examples are as follows: 2,2 夂 bis (2-gasphenyl) -4,4 ', 5,5'-tetra (4 -Ethylsulfenylphenyl} -1,2'-diimidazole / 4, 4'-bis (diethylamino) benzophenone, 2,2, bis (2-aminophenyl) -4, 4 ', 5,5'-tetrakis (4-ethylaminosulfonylphenyl) -1, 2'-dioxazole / 4, 4'-bis (diethylamino) dibenzoyl / 2-benzyl -2-Dimethylamino-1- (4-morpholinophenyl) butyl-bu-, 2y-bis (2-aminophenyl) -4,4,8,5,5'-tetrakis (4-ethylamino) Sulfonyl phenyldiimidazole / 4,1-bis (diethylamino) benzophenone / 1-hydroxycyclohexylphenylmethanone, 2, 2'-bis (2,4-diphenylphenyl) -4 , 4 ', 5,5' -tetraphenyl-1,2, dioxazole / 4,4 夂 bis (diethylamino) benzophenone, -2 8-(Please read the precautions on the back before (Fill in this page) The paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 412645 A7 B7 V. Description of the invention (27 2,2, double (2,4-dichlorobenzyl 4,4) ', 5, S'-Tetraphenyl-1,2'-dioxazole / 4, 4'-bis (diethylamino) dibenzylbenzyl-2 -dimethylamino-1 -(4 -morpholinobenzyl) butan-1-one, 2,2'-bis (2,4-dibromophenyl) -4, 4 ', 5,5'-tetraphenyl-1,2 '-Diimidazole / 4,4'-bis (diethylamino) dibenzoyl / 2-benzyl-2-dimethylamino-1- (4-morpholinobenzyl) butanone, 2, 2'-Bis (2, dibromobenzyl) -4,4,5,5, -tetraphenyl-1,2'-di-Please read the note below printed by the Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Oxazole / 4, 4 'methyl ketone. Add the filter seed additive of the present invention. The carboxylic acid in which these organic groups are not dissolved according to the aforementioned sensitivity group is the aforementioned aliphatic formic acid, ethyl ethyl acetate, and oxalic acid. ,, Suberic acid,, Ethylmalonate, Cyclohexane 'bis (diethylamino) dibenzyl-1 / 1-hydroxy 基 hexylbenzene color film, radiation sensitive composition. Each agent can be included as needed The first mention is organic acid, which can improve the color filter web, its solubility in alkali developing solution, and its inhibitory effect due to the residual after development. The acid is aliphatic with molecular weight of 1.000 K Specific examples of carboxylic acids include: acid, propionic acid, butyric acid, valeric acid, pivalic acid, Monocarboxylic acids such as acids, diheptanoic acid, caprylic acid; malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, azelaic acid, sebacic acid, tridecanedioic acid, methylmalonic acid Acid, dimethylmalonic acid, methylsuccinic acid, tetramethylsuccinic acid, itaconic acid, citraconic acid, maleic acid, fumaric acid, -29- This paper is in accordance with the Chinese National Standard (CNS) ) A4 specification (210 ^ 297 mm) Refill this page 412645 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs B7_V. Description of the invention (28) Dicarboxylic acids such as mesaconic acid; glycerine, propylene Tricarboxylic acids such as tricarboxylic acids and camphor tricarboxylic acids. In addition, the aforementioned benzyl-containing carboxylic acid has a carboxyl group directly connected to an aromatic acid that is directly connected to a phenyl group, or a carboxylic acid having a carboxyl group bonded to a phenyl group through a carbon chain. Aromatic monocarboxylic acids, such as acids, talin, etc .; Aromatic tricarboxylic acids, such as phthalic acid, isophthalic acid, and p-orthocarboxylic acid; Aromatic polyfluoric acids on yuan μ, or benzylacetic acid, hydrogenated tropic acid, hydrogenated cinnamic acid, mandelic acid, benzyl succinic acid, attoric acid, cinnamic acid, cinnamic acid, coumaric acid, agonist Acid etc. Among these organic acids, aliphatic dicarboxylic acids and aromatic dicarboxylic acids such as M malonic acid, adipic acid, itaconic acid, citric acid, fumaric acid, mesaconic acid, and phthalic acid are preferred. Based on alkali solubility, The following solubility in solvents prevents contamination or residual film on the substrate of the unexposed area or on the light-shielding layer. These organic acids may be used alone or in combination of two or more. The amount of organic acid used is relative to the entire radiation-sensitive composition. It is better for M 10 to weigh 5K, and M 5 to be less than $ 5, especially M1 is not to be better than weight. At this time, if the amount of organic acid exceeds 10 weight, the contact with the formed pixel substrate is reduced. In addition, specific examples of additives other than the aforementioned organic acids include: cyan pigment derivatives such as phthalocyanine bronze derivatives or dispersing rib agents such as yellow pigment derivatives; fillers such as glass and alumina; (please read the precautions on the back before filling in (This page) The paper size applies to the Chinese National Standard (CNS) A4 specification (2) 0 X 297 mm. 412645 A7 β7 V. Description of the invention (29

經濟部智慧財產局員工消費合作社印^J 聚乙烯醇、聚乙二醇單烷基醚類、聚（氟院^基诗烯酸 酯）類等高分子化合物； 2 -氨基乙酵類胺類； 非離子系、陽離子糸、陰離子系等界面活性劑； 乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、乙烯基 三（2 -甲氧基乙氧基）矽烷、N-(2 -氨乙基）-3 -氨丙基甲 基二甲氧基矽烷、N-(2-氨乙基）-3-氨丙基三甲氧基矽 烷、3 -氨丙棊三乙氧基矽烷、3-縮水甘油氧丙基三甲氧 基矽烷、3 -締水甘油氧丙基甲基二甲氧基矽烷、2-(3,4 -環氧環己基）乙基三甲氧基矽烷、3-氯丙基甲基二甲氧 基矽烷、3 -氯丙基三甲氧基矽烷、3 -異丁烯醯氧丙基三 甲氧基矽烷、3 -氮硫基丙基三甲氧基矽烷等接觸促進劑 2,2-硫代雙（4 -甲基-6 -特丁基酚）、2,6 -二特丁基酚 等抗氧化劑； 2-(3-特丁基-5 -甲基-2-羥苯基）-5-氯苯並三唑、烷 氧基二苯甲豳類等紫外線吸收劑； 聚丙烯酸鈉等凝集防止劑； 環氧化合物、蜜胺化合物、雙壘氮化物等熱交聯劑等 溶劑 本發明濾色片用幅照敏感性組成物，Μ前述（A)〜（D) 成分為必要成份，必要時可含前述添加劑成份，惟以混 配溶劑調製成液狀組成物為佳。 前逑溶劑只要可將構成幅照敏感性組成物之U)〜（D ) 成份或添加劑成份分散或溶解，而且與此等成份不會反 -31- 本紙張尺度適用中固國家標準（CNS)A4規格（21〇χ 297公f ) J青 先 53 •讀 背 面 之 注 意 事 項 再 填 本 頁 訂 線Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, J. Polyvinyl alcohol, polyethylene glycol monoalkyl ethers, poly (fluorinated sylveshenyl esters) and other polymer compounds; 2-aminoethyl fermented amines ; Non-ionic, cationic pyrene, anionic surfactants; vinyltrimethoxysilane, vinyltriethoxysilane, vinyltri (2-methoxyethoxy) silane, N- (2- Aminoethyl) -3 -aminopropylmethyldimethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3 -Glycidoxypropyltrimethoxysilane, 3-Glycidoxypropylmethyldimethoxysilane, 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-chloropropane Contact accelerators such as methylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-isobutylene, oxypropyltrimethoxysilane, and 3-nitrothiopropyltrimethoxysilane Antioxidants such as thiobis (4-methyl-6-tert-butylphenol), 2,6-ditert-butylphenol; 2- (3-tert-butyl-5-methyl-2-hydroxyphenyl) -5-Chlorobenzotriazole, alkoxy dibenzophenazines, etc. External line absorbent; Aggregation inhibitor such as sodium polyacrylate; Solvents such as epoxy compounds, melamine compounds, double barrier nitrides and other thermal crosslinking agents The radiation-sensitive composition for color filters of the present invention, M (A) ~ (D) The component is an essential component, and the aforementioned additive component may be contained if necessary, but it is better to prepare a liquid composition by mixing solvents. As long as the front solvent can disperse or dissolve the U) ~ (D) components or additive components that make up the radiation-sensitive composition, and these components will not reflect -31- This paper applies the China National Solid Standard (CNS) A4 specifications (21〇χ 297 Male f) J Qingxian 53 • Read the precautions on the back and fill in the page to set the thread

^12645五、發明說明（3G A7 B7 經濟部智慧財產局員工消費合作社印制^ 應，並具有適度揮發性者.不特別限制，均可適當選用 此等溶劑具體例有： 乙二醇軍甲醚、乙二醇單乙醚、乙二醇正丙醚、乙二 醇單正丁醚、二乙二醇單甲醚、二乙二醇單乙醚、二乙 二醇單正丙醚、二乙二醇單正丁醚、三乙二酵單甲醚、 三乙二酵單乙醚、丙二醇單甲醚、丙二醇單乙醚、丙二 醇單正丙醚、丙二醇單正丁醚、二丙二醇單甲醚、二丙 二醇單乙瞇、二丙二醇單正丙醚、二丙二醇單正丁醚、 三丙二醇單甲醚、三丙二醇單乙醚等（聚）烷二醇單烷醚 類； 乙二醇單甲醚乙酸酯、乙二醇單乙醚乙酸_、二乙二 醇單甲醚乙酸酯、二乙二醇單乙_乙酸酯、丙二醇單甲 醚乙酸酯*丙二醇單乙醚乙酸酯等（聚）烷二醇烷醚乙酸酯 類； 二乙二醇二甲醚、二乙二醇甲乙醚、二乙二醇二乙醚 、四氫呋喃等其他醚類； 丁酮、環己酮、2-庚酮、3-庚_等_類； 2-羥基丙酸甲酯、2-羥基丙酸乙酯等乳酸烷酯類； 2-羥基-2-甲基丙酸乙酯、3-甲氧基丙酸甲酯、3-甲 氧基丙酸乙酯、2-乙氣基丙酸甲酯、3 -乙氧基丙酸乙酯 、乙氧基乙酸乙酯、羥基乙酸乙酯、2-羥基-2-甲基丁 酸甲酯、3-甲基-3-甲氧基丁基乙酸酯、3-甲基-3-甲氧 基丁基丙酸酯、乙酸乙酯、乙酸正丙酯、乙酸異丙酯、 乙酸正丁酯、乙酸異丁酯、甲酸正戊酯、乙酸異戊酯、 -32- {請先閱讀背面之注意事項再填寫本頁)^ 12645 V. Description of the invention (3G A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ should be suitable for those with moderate volatility. These solvents can be appropriately selected without specific restrictions. Specific examples are: Ether, ethylene glycol monoethyl ether, ethylene glycol n-propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, diethylene glycol Mono-n-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol mono (Poly) alkanediol monoalkane ethers such as ethylene glycol, dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-n-butyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether; ethylene glycol monomethyl ether acetate, ethyl ether (Poly) alkanediols such as glycol monoethyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate *, propylene glycol monoethyl ether acetate, and the like Alkyl ether acetates; Diethylene glycol dimethyl ether, diethylene glycol methyl ether, diethylene glycol diethyl ether Other ethers such as tetrahydrofuran; methyl ethyl ketone, cyclohexanone, 2-heptanone, 3-heptyl, etc .; alkyl lactates such as methyl 2-hydroxypropionate, ethyl 2-hydroxypropionate; 2-hydroxy Ethyl-2-methylpropionate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 2-ethoxypropionate, ethyl 3-ethoxypropionate, Ethyl ethoxylate, ethyl hydroxyacetate, methyl 2-hydroxy-2-methylbutanoate, 3-methyl-3-methoxybutyl acetate, 3-methyl-3-methoxy Butylpropionate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, -32- {Please read the back (Please fill in this page again)

--------訂1^------I I 本紙張尺度適用中國國家標準（C'NS)A·!規格（2】0 X 297公釐） ^12645 A7 B7_ 五、發明說明（31 ) 丙酸正丁酯、丁酸乙酯、丁酸正丙酯、丁酸真丙li旨、丁 酸正丁酿、丙酮酸甲酯、丙酮酸乙酯、丙酮酸正丙酯、 乙醯乙酸甲酯、乙醢乙酸乙酯、2-氧代丁酸乙酯等酯類； 甲苯、二甲苯等芳族烴類； N -甲基吡咯烷_、Ν,Ν -二甲基甲醯胺、Ν,Ν -二甲基乙 醯胺等醯胺類等。 此等溶劑當中，就溶解性、顏料分散性、塗佈性等而 言，以乙二醇單甲醚乙酸酯、丙二醇單甲醚、丙二醇單 甲醚乙酸酯、丙二醇單乙醚乙酸酯、二乙二酵二甲醚、 二乙二醇甲乙醚、環己酮、2-庚_、3-庚酮、2-羥基丙 酸乙酯、3 -甲氧丙酸乙酯、3 -乙氧基丙酸甲酯、3 -乙氧 丙酸乙酯、3 -甲基-3 -甲氧基丁基丙酸酯、乙酸正丁酯 、乙酸異丁酯、甲酸正戊酯、乙酸異戊酯、丙酸正丁酯 、丁酸乙酯、丁酸異丙酯、丁酸正丁酯、丙賑酸乙酯等 為佳。前述溶劑可單獨或二種Μ上併用。 再者，前述溶劑遨可併用苄基乙醚、環己醚、丙_基 丙_、異佛爾酮、己酸、辛酸、1-辛醇、1-壬醇、苄醇 、乙酸苄酯、笨甲酸乙酯、乙二酸二乙酯、馬來酸二乙 酷、7 _丁內酯、碳酸乙烯、碳酸丙烯、乙二醇單苯醚 乙酸酯等髙沸點溶劑。 此等高沸點溶劑當中Μ 7 - 丁内酯等為佳。 前逑高沸點溶劑可單獨或二種K上併用。溶劑使用量 雖無特別限制，但就所得幅照敏感性組成物的塗佈性， 安定性觀點言，除該姐成物溶劑>i外的各成份合計濃度 本纸張尺度遇用中國國家標準（CNS)A‘l規格（2〗〇χ 297公釐） ! Ί- — ---1*~| 訂·-------*線 (請，先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工涓費合作社印製 412645 A7 B7 五、發明說明（32 經濟部智慧財產局員工消費合作社印製 ，K 5〜50重量％為佳，而Μ 10〜40重量％更好。 濾色Η的形成方法 其次，說明使用本發明滤色片用幅照敏感性組成物， 形成濾色Η之方法。 首先，在基板表面上可視需要形成遮光層，與形成圖 素的郜份區別，在此基板上，塗佈例如分散有紅色顔料 之幅照敏感性姐成物之液狀組成物後，進行預烤.將溶 劑蒸發，形成塗膜。其次，對此塗膜藉經光罩曝光放射 線後，使用鹼顯像液顯像，溶除塗膜之未曝光部，然後 利用餘烤，形成紅色圖素圖型按預定排列配置之圖素行 列。 然後，使用分散綠色或藍色顔料的幅照敏感性組成物 之液狀組成物，和前述同樣進行各液狀组成物的塗佈、 預烤、暍光和顯像，然後進行餘烤，在同一基板上依次 形成綠色圖素行列和藍色圖素行列，而得紅、綠、藍三 原色的圖素行列配置在基板上的滤色Η。 形成濾色Η之際使用之基板，有例玻璃、矽_、聚碳 酸鹽、聚酯、芳族醢胺、聚族醯胺醯亞胺、聚醯亞胺等 。此等基板可視需要利用矽烷偶合劑等實施藥品處理、 電漿處理、離子鍍著、噴鍍、氣相反應法、真空蒸普等 適當前處理。 在基板上塗佈幅照敏感性組成物的液狀組成物之際， 可採用旋塗、流塗、輥塗等適當塗法。 塗佈厚度以乾煉後的膜厚0.1〜10微米為佳，0.2〜 -34- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -請 先 閱.讀 背 δ 之 注 意 事 項 再 填 本 頁 412645 A7 經濟部智慧財產局員工消費合作社印製 B7_五、發明說明（33 ) 5.0微米更好，而K 0.2〜3.0微米最佳。 “' 液色片製作之際所用放射線，可用例如可見光線、紫 外線、a紫外線、電子線、X射線等。其中μ波長19〇 〜450nm範圍的放射線為佳。 放射線照射能量以1〜1 , 0 〇 0毫焦耳/平方公分為佳。 前述鹼顯像液Μ例如碳酸納、氬氧化納、氫氧化鉀、四 甲基氫氧化銨、可林、1，δ -二吖雙環[5,4.0]-7-十一碳 烯、1,5 -二吖雙環[4.3.0)-5 -壬烯等水溶液為佳。 前述鹼顯像液可適量添加例如甲醇、乙醇等水溶性有 機溶劑或界面活性劑等。 顯像處理法可適用淋灑顯像法、唄灑顯像法、浸泡顯 像法、授動顯像法等。顯像條件Μ常溫5〜3 0 0秒為佳。 鹼顯像後，通常要經水洗。 如此彤成的滤色片極為有用於例如透射型或反射型彩 色液晶顯示裝置、彩色收像管元件、彩色察覺器等。 茲Κ實施例具體說明本發明實施形態如下，惟本發明 不限於下述實施例。 m齓1 取（A)著色劑C.I.紅色顔料177計120重量份，（B) 鹼溶性樹脂即異丁烯酸/ 丁二酸單（2 -丙烯醯氧乙酯）/ 笨乙烯/異丁烯酸苄酯/丙三醇單異丁烯酸酯/ N-笨基 馬來醮亞胺共聚物（共聚合重量比為15.0/10.0/11. 2' /35.0/10.0/18.8,重量平均分子量20,000)計60重 量份，（C)多官能性單體之二季戊四醇六丙烯酸酯計40 -35- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210x297公f ) 412645 A7 經濟部智慧財產局員工消費合作社印製 B7五、發明說明（34 ) 重量份，（D)光聚合引發劑，即2,2’-雙（2,4-二氯笨基） -4,4', 5, 5’-四苯基-1,2、二咪唑10重量份、4,4’-雙 (二乙氨基）二苯甲酮10重量份、2 -苄基-2-二甲氨基-1-U -嗎W並笨基）丁 -1-_50重量份，Μ及溶劑3 -乙氧基 丙酸乙酿1 0 0 0重量份，加以混合，調製成幅照敏感性之 液狀組成物W。液狀組成物⑴的顔料湄度約為全固體份 之43重童。 濾ft Μ之形成 取液狀組成物⑴在表面形成防止納離子溶出的s i 〇 2 膜之納坡璃基板表面，使用旋塗法塗佈後，在δ〇υ進行 預烤10分鐘，形成膜厚2.0微米的塗膜。 然後，將基板冷卻到室溫，使用高壓水銀燈，藉光罩 ，對塗膜Μ各含波長365微米、405微米和436微米的紫 外線，Μ100毫焦耳/平方公分暍光量曝光。接著，此 基板在23它的0.04重量％氫氧化鉀水溶液中浸泡1分鐘 ，顯像後，用超純水洗淨，風乾。然後，在230t!乾淨 爐内餘烤30分鐘，在基板上形成紅色條狀漶色片。 所得濾色Η利用光學顯微鏡觀察時，未曝光部的基板 上未見顯像殘渣，另使用投光器觀察時，未曝光部的基 板上並無污染。再者，此濾色片的未曝光部的基板表面 ,以含乙醇的投雷西（商品名，東麗公司製品的透鏡清 洗劑）擦拭10次，投雷西未見沾染紅色。而且，此濾色 片的圖素與基板的接觸性良好。 啻施例.2 -36- (請先閱讀背面之注意事項再填寫本頁) ί : 訂·· 線- 本紙張尺度適用中國國家標準（CNS)A4規格（2]〇χ 297公釐） 412645 A7 經濟部智慧財產局員工消費合作社印製 _B7_五、發明說明（35 ) 取U)著色劑C.i.紅色顏料177計120重4份\ (B) 鹼溶性樹脂即異丁烯酸/ 丁二酸單（2 -丙烯醯氧乙酯）/ 苯乙烯/ 2-羥乙基異丁烯酸酯/異丁烯酸苄酯/ N-笨基 馬來醯亞胺共聚物（共聚合重量比為15. 0/10.0/11.2 /10.0/35.0/18.8,重量平均分子量25,000)計60重 量份，（C)多官能性單體之二季戊四醇六丙烯酸酯計40 望量份，（D)光聚合引發劑，即2,2’-雙（2, 4-二氯笨基） -4,4’，5,5'-四苯基-1,2、二咪唑10重量份、4,4’-雙 (二乙氨基）二苯甲_1〇重量份、2 -苄基-2 -二甲氨基-1-(4-嗎啉並苯基）丁 -1-酮50重量份，Μ及溶劑3-乙氧基 丙酸乙酯1000重量份，加以混合，調製成幅照敏感性之 液狀組成物（2)。液狀組成物（2)的顔料濃度約為全固體份 之43重量S!。 濾色Η之形成 除液狀組成物⑴改用液狀姐成物⑵外，和實施例1同 漾，形成紅色條狀濾色片。 所得漶色片利用光學顯微鏡観察時，未曝光部的基板 上未見顯像殘渣，另使用投光器観察時，未曝光部的基 板上並無污染。再者，此溏色Η的未瞜光部的基板表面 ,Μ含乙醇的投雷西擦拭1 0次，投雷西未見沾染紅色。 而且，此濾色片的圖素與基板的接觸性良好。 皙施例3 取U )著色劑C · I .綠色顔料3 6計1〗0重量份，（Β )鹼 溶性樹脂即異丁烯酸/ 丁二酸單（2 -丙烯醯氧乙酯）/異 -37- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210x297公釐） 經濟部智慧財產局員工消費合作社印製 412645 A7 _B7_五、發明說明（36 ) 丁烯酸酯/丙三醇單異丁烯酸酯共聚物（共聚合重量比 為 15.0 / 10.0 / 60.0 / 15,0,重量平均分子量 30,000) 計6 0重量份，（C )多官能性單體之二季戊四醇六丙烯酸 酯計40重量份，（D)光聚合引發劑，即2, 2’-雙（2, 4-二 氯笨基）-4,4',5,5'-四苯基-1,2'-二眯唑10重量份、4, 4’-雙（二乙氨基）二苯甲酿110重量份、2 -苄基_2-二甲氨 基-1-(4-嗎啉並苯基）丁 -1-嗣50重量份，W及溶劑丙二 醇單甲醚乙酸酯1000重量份，加以混合，調製成幅照敏 感性之液狀組成物（3)。液狀組成物（3)的顔料湄度約為全 固體份之4 1重量％ 。 灌_色H_之龙 除液狀組成物⑴改·用液狀組成物（3)外，和實施例I同 樣，形成綠色條狀據色片。 所得濾色Η利用光學顯微鏡觀察時，未暘光部的基板 上未見顯像殘渣，另使用投光器觀察時，未暘光部的基 板上並無污染。再者，此濾色片的未曝光部的基板表面 ,Μ含乙醇的投雷西擦拭1 0次，投雷西未見沾染綠色。 而且，此滤色片的圖素與基板的接觸性良好。 背胞例4 取（/〇著色劑（：.1.藍色顏料15:6計100重量份，（8) 鹼溶性樹脂即異丁烯酸/ 丁二酸單（2 -丙烯醢氧乙酯）/ 笨乙烯/ 2-羥乙基異丁烯酸酯/異丁烯酸苄酷/ Ν-苯基 馬來醯亞胺共聚物（共聚合重量比為15.0/10.0/11.2 /10.0/35.0/18.8,重量平均分子量35,000)計60重 -3 8 - (請先閱讀，背面之注意事項再填寫本頁) 本紙張尺度適用中國0家標準（CNS)/VU見格（210 x 297公釐） 經濟部智慧財產局員工消費合作社印製 412645 a7 _B7_五、發明說明（37 ) 量份，（C )多官能性單體之二季戊四醇六丙烯酸扁計4 0 重量份，（D)光聚合引發劑，即2,2’-雙（2,4-二氯苯基） -4,4’，5,5·-四苯基-1,2、二咪唑10重量份、4,4'-雙 (二乙氨基）二笨甲嗣10重量份、2 -苄基-2 -二甲氨基-1-(4-嗎啉並苯基）丁 -卜酮50重量份，Μ及溶劑3-乙氧基 丙酸乙酯1 0 0 0重量份，加以混合，調製成幅照敏感性之 液狀組成物⑷。液狀組成物⑷的顔料濃度約為全固體份 之38重量35 。 逋色Η :>形成 除液狀姐成物⑴改用液狀組成物⑷外，和實施例1同 樣，形成藍色條狀涟色片。 所得漶色片利用光學顯微鏡觀察時，未曝光部的基板 上未見顯像殘渣，另使用投光器觀察時，未暍光部的基 板上並無污染。再者，此滤色片的未曝光部的基板表面 ,Κ含乙醇的投雷西擦拭1 0次，投雷西未見沾染藍色。 而且，此濾色片的圖素與基板的接觸性良好。i±-M ΜΛ 除實施例1的（B)鹼溶性樹脂60重量份，改用異丁烯 酸/ 2-羥乙基異丁烯酸酯/異丁烯酸苄共聚物（共聚合 比例為15/15/70,重量平均分子量28000) 60重量份 外，餘和實施例1同樣，調製成幅照敏感性組成物之液 狀組成物，在基板上形成紅色條狀逋色片。 所得漶色片用光學顯微鏡觀察，未曝光部的基板上顯 示殘渣，另用投光器観察，在未暍光部的基板上出琨污 -39- (請，先閱讀^面之注意事項再填寫本頁) --訂I--------線！ 本紙張尺度適用中國國家標準（CNS)/M規格（2〗0 X 297公釐） 經濟部智慧財產局員工消費合作社印5衣 412645五、發明說明（38 ) 染。再者，此濾色μ的未曝光部基板表面，κ含乙醇的 投雷西擦拭1 0次，投雷西沾染紅色。 發明效果 如上所述，本發明滤色Η用幅照敏感性驵成物，含高 濃度顏料時，顯示優良顯像性，顯像時在未曝光部的基 板上和遮光層上不產生殘渣和污染，且可賦予對基板和 遮光層之接觸性良好的優良圖素。 因此，本發明漶色片用幅照敏感性組成物，在電子工 業範鹉中，極適用於製造從彩色液晶顯示裝置用滹色片 起之各種滤色片。 ------------r--------,--訂·---------線 (請先閱讀背面之注意事項再填寫本頁) * -40- 本紙張尺度適用中國國家標準（CNS)/VI規格（210x297公釐）-------- Order 1 ^ ------ II This paper size applies Chinese National Standard (C'NS) A ·! Specification (2) 0 X 297 mm) ^ 12645 A7 B7_ V. Invention Note (31) n-butyl propionate, ethyl butyrate, n-propyl butyrate, n-butyl butyrate, n-butyl butyrate, methyl pyruvate, ethyl pyruvate, n-propyl pyruvate, Esters such as methyl ethyl acetate, ethyl ethyl acetate, ethyl 2-oxobutanoate; aromatic hydrocarbons such as toluene and xylene; N-methylpyrrolidine_, Ν, Ν -dimethylformamide Amidoamines, such as amidine, N, N-dimethylacetamide, etc. Among these solvents, ethylene glycol monomethyl ether acetate, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, and propylene glycol monoethyl ether acetate are used in terms of solubility, pigment dispersibility, and coating properties. , Diethylene glycol dimethyl ether, diethylene glycol methyl ether, cyclohexanone, 2-heptanone, 3-heptanone, ethyl 2-hydroxypropionate, ethyl 3-methoxypropionate, 3-ethyl Methyloxypropionate, ethyl 3-ethoxypropionate, 3-methyl-3 -methoxybutylpropionate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate Esters, n-butyl propionate, ethyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl propionate and the like are preferred. The aforementioned solvents may be used singly or in combination. In addition, the aforementioned solvents may be used in combination with benzyl ether, cyclohexyl ether, propyl propyl propyl, isophorone, hexanoic acid, caprylic acid, 1-octanol, 1-nonanol, benzyl alcohol, benzyl acetate, and benzene Solvents with boiling points such as ethyl formate, diethyl oxalate, diethylene glycol maleate, 7-butyrolactone, ethylene carbonate, propylene carbonate, and ethylene glycol monophenyl ether acetate. Among these high boiling point solvents, M 7 -butyrolactone and the like are preferred. Former high boiling point solvents can be used alone or in combination of two K. Although the amount of the solvent used is not particularly limited, in terms of the applicability and stability of the obtained radiation-sensitive composition, the total concentration of each component except the sister solvent > i is in compliance with the Chinese standard on this paper scale. Standard (CNS) A'l specification (2〗 〇297 297 mm)! Ί- — --- 1 * ~ | Order · ------- * line (please read the notes on the back before filling This page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the cooperative 412645 A7 B7 V. Invention description (32 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by K 5-50% by weight, and M 10-40% by weight The method for forming the color filter is as follows. The method of forming the color filter using the radiation-sensitive composition of the color filter of the present invention will be described. First, a light-shielding layer may be formed on the surface of the substrate as needed, and The difference is different. On this substrate, for example, a liquid composition in which a red pigment is dispersed is coated with a liquid composition, and then pre-baked. The solvent is evaporated to form a coating film. Second, the coating film is borrowed. After exposing the radiation through the photomask, use an alkali imaging solution to develop the image to dissolve the coating film. The exposure section then uses the residual baking to form a red pixel pattern arranged in a predetermined arrangement. Then, the liquid composition of the radiation-sensitive composition in which the green or blue pigment is dispersed is used, and each is performed in the same manner as described above. The liquid composition is coated, pre-baked, calendered, and developed, and then subjected to post-baking to form green pixel rows and blue pixel rows in sequence on the same substrate to obtain pixels of three primary colors of red, green, and blue. Color filters arranged on the substrate in rows and columns. Examples of substrates used when forming color filters include glass, silicon, polycarbonate, polyester, aromatic ammonium, polyamine, imine, and polyimide. Amines, etc. These substrates can be appropriately pretreated with silane coupling agents, such as pharmaceutical treatment, plasma treatment, ion plating, thermal spraying, gas phase reaction method, vacuum distillation, etc. as required. Coating radiation sensitivity on substrates For the liquid composition of the composition, appropriate coating methods such as spin coating, flow coating, and roll coating may be used. The coating thickness is preferably a dry film thickness of 0.1 to 10 microns, and 0.2 to -34. Applicable to China National Standard (CNS) A4 (210 X 297 mm)-Please read it first. Please read the notes of δ before filling in this page 412645 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7_V. Invention Description (33) 5.0 micron is better, and K 0.2 ~ 3.0 Micron is the best. "'The radiation used in the production of liquid color film can be, for example, visible light, ultraviolet rays, a ultraviolet rays, electron rays, X-rays, etc. Among them, radiation with a wavelength in the range of 19 to 450 nm is preferred. The radiation irradiation energy is 1 10,000 millijoules per square centimeter is preferred. The aforementioned alkali developing solution M is, for example, sodium carbonate, sodium argon oxide, potassium hydroxide, tetramethylammonium hydroxide, collin, 1, δ-diazine bicyclic ring [ 5,4.0] -7-undecene, 1,5-diazine bicyclic [4.3.0) -5-nonene and other aqueous solutions are preferred. The alkali developing solution may be added with a suitable amount of a water-soluble organic solvent such as methanol or ethanol, a surfactant, or the like. The imaging treatment method can be applied to the shower imaging method, the sprinkle imaging method, the immersion imaging method, and the perfusion imaging method. The development condition M is preferably 5 to 300 seconds at room temperature. After alkali development, it is usually washed with water. Such a color filter is extremely useful for, for example, a transmissive or reflective color liquid crystal display device, a color picture tube element, a color sensor, and the like. The embodiments are specifically described as follows, but the present invention is not limited to the following embodiments. m 齓 1 Take (A) 120 parts by weight of CI Red Pigment 177, (B) Alkali-soluble resin, namely methacrylic acid / succinic acid mono (2-propenyloxyethyl) / benzyl ethylene / benzyl methacrylate / 60 parts by weight of glycerol monomethacrylate / N-benzylmaleimide copolymer (copolymerization weight ratio is 15.0 / 10.0 / 11. 2 '/ 35.0 / 10.0 / 18.8, weight average molecular weight 20,000), (C) Dipentaerythritol hexaacrylate meter of polyfunctional monomers 40 -35- (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210x297 male f) 412645 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7 V. Description of the invention (34) parts by weight, (D) Photopolymerization initiator, namely 2,2'-bis (2,4-dichlorobenzyl) -4, 4 ', 5, 5'-tetraphenyl-1,2, 10 parts by weight of diimidazole, 10 parts by weight of 4,4'-bis (diethylamino) benzophenone, 2-benzyl-2-dimethyl Amino-1-U-?-W-benzyl) Butan-1-_50 parts by weight, M and 100 parts by weight of 3-ethoxypropionic acid ethyl alcohol, and mixed to prepare a radiation sensitive liquid状 组合 物 W。 Composition W. The liquid composition ⑴ has a pigmentation degree of about 43 weight children. The formation of the filter ft Μ takes the liquid composition. The surface of the Napo glass substrate is formed on the surface to prevent the dissolution of sodium ions. After coating by spin coating, pre-baking at δ〇υ for 10 minutes to form a film. 2.0 micron thick coating film. Then, the substrate was cooled to room temperature, and a high-pressure mercury lamp was used to expose the coating film M to ultraviolet light having a wavelength of 365 micrometers, 405 micrometers, and 436 micrometers at a light intensity of 100 millijoules per square centimeter. Next, the substrate was immersed in a 0.04% by weight potassium hydroxide aqueous solution for 23 minutes, and after development, it was washed with ultrapure water and air-dried. Then, bake in a 230t! Clean oven for 30 minutes to form a red bar-shaped ochre sheet on the substrate. When the obtained color filter was observed with an optical microscope, no development residue was found on the substrate of the unexposed portion, and when the observation was performed using a light projector, the substrate of the unexposed portion was not contaminated. Furthermore, the surface of the substrate of the unexposed portion of the color filter was wiped 10 times with ethanol-containing thixo (trade name, lens cleaner manufactured by Toray Corporation), and thixi did not stain red. In addition, the pixels of this color filter have good contact with the substrate.啻 例 .2 -36- (Please read the precautions on the back before filling in this page) ί: Order · Line-This paper size is applicable to China National Standard (CNS) A4 (2) 〇χ 297 mm 412645 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs_B7_ V. Description of the invention (35) Take U) Colorant Ci Red Pigment 177 120 120 weight 4 parts (B) Alkali-soluble resin, namely methacrylic acid / succinic acid mono (2-propenyloxyethyl) / styrene / 2-hydroxyethyl methacrylate / benzyl methacrylate / N-benzyl maleimide copolymer (copolymerization weight ratio is 15. 0 / 10.0 / 11.2 /10.0/35.0/18.8, weight average molecular weight 25,000) 60 parts by weight, (C) 40 parts by weight of dipentaerythritol hexaacrylate of the polyfunctional monomer, (D) photopolymerization initiator, namely 2,2 '-Bis (2, 4-dichlorobenzyl) -4,4', 5,5'-tetraphenyl-1,2, diimidazole 10 parts by weight, 4,4'-bis (diethylamino) di 10 parts by weight of benzyl, 50 parts by weight of 2-benzyl-2 -dimethylamino-1- (4-morpholinophenyl) but-1-one, M and ethyl 3-ethoxypropionate 1000 parts by weight of the ester are mixed to prepare a radiation-sensitive liquid composition (2). The pigment concentration of the liquid composition (2) was about 43% by weight of solids! Formation of Color Filters Except that the liquid composition was changed to a liquid composition, the same process as in Example 1 was used to form a red stripe color filter. When the obtained black-colored film was inspected with an optical microscope, no development residue was observed on the substrate of the unexposed portion, and when the light projector was inspected, the substrate of the unexposed portion was not contaminated. Furthermore, the surface of the substrate of the uncoated part of this black tincture was wiped 10 times with Methylacetate containing ethanol, and no red staining was observed with Methylacetone. In addition, the pixels of this color filter have good contact with the substrate. Example 3 Take U) Colorant C · I. Green pigment 36 6 1 1 0 parts by weight, (B) alkali-soluble resin, namely methacrylic acid / succinic acid mono (2-propenyloxyethyl) / iso- 37- (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210x297 mm). Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 A7 _B7_ V. Description of the invention (36) Butyrate / glycerol monomethacrylate copolymer (copolymerization weight ratio is 15.0 / 10.0 / 60.0 / 15,0, weight average molecular weight 30,000) 60 parts by weight, (C) polyfunctionality 40 parts by weight of the monomer dipentaerythritol hexaacrylate, (D) a photopolymerization initiator, that is, 2, 2'-bis (2, 4-dichlorobenzyl) -4,4 ', 5,5'-tetrakis 10 parts by weight of phenyl-1,2'-bisoxazole, 110 parts by weight of 4, 4'-bis (diethylamino) dibenzophenone, 2-benzyl_2-dimethylamino-1- (4- 50 parts by weight of morpholinophenyl) but-1-fluorene, and 1,000 parts by weight of propylene glycol monomethyl ether acetate as a solvent were mixed to prepare a radiation-sensitive liquid composition (3). The pigment composition of the liquid composition (3) is about 41% by weight based on the total solid content. Irrigation_color_H_dragon A green strip-shaped color chip was formed in the same manner as in Example I except that the liquid composition was changed to the liquid composition (3). When the obtained color filter was observed with an optical microscope, no development residue was observed on the substrate of the unreflected portion, and when observed using a light projector, the substrate of the unreflected portion was not contaminated. Furthermore, the surface of the substrate of the unexposed portion of the color filter was wiped 10 times with Methylacetate containing ethanol, and no green stain was observed with Methylacetone. In addition, the pixels of this color filter have good contact with the substrate. Back cell example 4 Take (/ 〇 colorant (: .1. Blue pigment 15: 6 based on 100 parts by weight, (8) alkali-soluble resin, namely methacrylic acid / succinic acid mono (2-propenyloxyethyl) / Styrene / 2-hydroxyethyl methacrylate / benzyl methacrylate / N-phenylmaleimide copolymer (copolymerization weight ratio is 15.0 / 10.0 / 11.2 / 10.0 / 35.0 / 18.8, weight average molecular weight 35,000 ) Total 60 weights-3 8-(Please read first, please fill in the notes on the back before filling this page) This paper size applies to China 0 Standards (CNS) / VU Seeg (210 x 297 mm) Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the consumer cooperative 412645 a7 _B7_ V. Description of the invention (37) parts by weight, (C) 40 parts by weight of dipentaerythritol hexaacrylic acid, a polyfunctional monomer, (D) photopolymerization initiator, ie 2,2 '-Bis (2,4-dichlorophenyl) -4,4', 5,5 · -tetraphenyl-1,2, 10 parts by weight of diimidazole, 4,4'-bis (diethylamino) di 10 parts by weight of benzamidine, 50 parts by weight of 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) butan-butanone, M and ethyl 3-ethoxypropionate 1 0 0 0 parts by weight, mixed to prepare a liquid composition with radiation sensitivity Material ⑷. Liquid composition ⑷ has a pigment concentration of about 38% by weight of the total solids. 35 逋 Color Η: > The same as Example 1 except that the liquid 成 is changed to a liquid ⑷. A blue stripe-shaped ripple film was formed. When the obtained ocher film was observed with an optical microscope, no development residue was observed on the substrate of the unexposed portion, and when observed using a light projector, there was no contamination on the substrate of the unexposed portion. On the surface of the substrate of the unexposed part of the color filter, K-containing ethanol was wiped 10 times, and Ricci was not stained with blue. In addition, the pixels of the color filter had good contact with the substrate. i ± -M ΜΛ In addition to 60 parts by weight of the (B) alkali-soluble resin of Example 1, the methacrylic acid / 2-hydroxyethylmethacrylic acid ester / methacrylic acid benzyl copolymer was used instead (the copolymerization ratio was 15/15/70, The weight average molecular weight is 28000), except that it is 60 parts by weight, the liquid composition of the radiation sensitive composition is prepared in the same manner as in Example 1 to form a red stripe-colored ocher sheet on the substrate. The obtained ocher sheet is observed with an optical microscope. Residues are displayed on the substrate of the unexposed area. -39- (Please read the precautions on the ^ side before filling out this page) --Order I -------- line! This paper size applies to China National Standard (CNS) / Specification M (2) 0 X 297 mm) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 412645 V. Invention Description (38) Dyeing. Furthermore, the surface of the substrate of the unexposed portion of this color filter μ, κ contains ethanol. Casting Rethy wiped 10 times, casting Rethy stained red. ADVANTAGEOUS EFFECTS OF THE INVENTION As described above, the radiation-sensitized product of the color filter according to the present invention exhibits excellent developability when containing a high concentration of pigment, and does not generate residues on the substrate of the unexposed portion and the light-shielding layer during development. Contamination, and can provide excellent pixels with good contact with the substrate and the light-shielding layer. Therefore, the radiation-sensitive composition for a cyan dye of the present invention is very suitable for manufacturing various color filters from the cyan dye for a color liquid crystal display device in the electronics industry. ------------ r --------,-Order · --------- line (Please read the precautions on the back before filling this page) * -40- This paper size applies to China National Standard (CNS) / VI specifications (210x297 mm)

Claims (1)

412645 A8 B8 C8 DB 修正 * 1- Λ- 申請專利範圍 第88113132號r濾色片用幅照敏感性組成物」專利案 U9年6月2日修正） 六申請專利範圍： 1. 一種濾色片用幅照敏感性組成物，其特徴爲，包括（A) 著色劑，（B)含有選自二羧酸單（2 -丙烯醢氧乙酯）和 二羧酸單（2 -異丁烯醯氧乙酯）之1種或2種以上單體 以及可與此單髖共聚合之其他單官能性單體的共聚物 構成之鹸溶性樹脂，（C )多官能性單體，以及（D )光聚 合引發劑，其中相對於著色劑（A)100重量份，其係含 鹼溶性榭脂<B) 10〜1 000重量份：其中鹼溶性樹脂<B) 每100重量份，其係含有多官能性單體（C)20〜300重 量份，光聚合引發劑（D)0.01〜20重量份》 2. 如申請專利範圍第1項之濾色片用幅照敏感性組成物 *其中二羧酸單<2-丙烯醯氧乙酯）和二羧酸單<2·異 丁烯醃氧乙酯）之二羧酸，係C2〜C2。脂族二羧酸、C7 〜C24脂環族二羧酸，或C8〜C24芳族二羧酸* 3 .如申請專利範圍第2項之濾色片用幅照敏感性組成物 ，其中該二羧酸爲C2〜C8脂族二羧酸。 4.如申請專利範圍第3項之濾色片用幅照敏感性組成物 ，其中該脂族二羧酸爲丁二酸。 5 .如申請專利範圍第1項之濾色片用幅照敏感性組成物 ，其中該其他單官能性單體係在分子內具有羧基之單 體，由選自不飽和單羧酸、不飽和二羧酸、不飽和二 本紙伕尺度適用申國國家梯準（CNS ) A4規格（210X2?7公釐） --- C#-先閲«*背面之注$項再填寫本頁) 訂 r' 經濟部智慧財產局員工消費合作社印製 412645 A8 B8 C8 DB 修正 * 1- Λ- 申請專利範圍 第88113132號r濾色片用幅照敏感性組成物」專利案 U9年6月2日修正） 六申請專利範圍： 1. 一種濾色片用幅照敏感性組成物，其特徴爲，包括（A) 著色劑，（B)含有選自二羧酸單（2 -丙烯醢氧乙酯）和 二羧酸單（2 -異丁烯醯氧乙酯）之1種或2種以上單體 以及可與此單髖共聚合之其他單官能性單體的共聚物 構成之鹸溶性樹脂，（C )多官能性單體，以及（D )光聚 合引發劑，其中相對於著色劑（A)100重量份，其係含 鹼溶性榭脂<B) 10〜1 000重量份：其中鹼溶性樹脂<B) 每100重量份，其係含有多官能性單體（C)20〜300重 量份，光聚合引發劑（D)0.01〜20重量份》 2. 如申請專利範圍第1項之濾色片用幅照敏感性組成物 *其中二羧酸單<2-丙烯醯氧乙酯）和二羧酸單<2·異 丁烯醃氧乙酯）之二羧酸，係C2〜C2。脂族二羧酸、C7 〜C24脂環族二羧酸，或C8〜C24芳族二羧酸* 3 .如申請專利範圍第2項之濾色片用幅照敏感性組成物 ，其中該二羧酸爲C2〜C8脂族二羧酸。 4.如申請專利範圍第3項之濾色片用幅照敏感性組成物 ，其中該脂族二羧酸爲丁二酸。 5 .如申請專利範圍第1項之濾色片用幅照敏感性組成物 ，其中該其他單官能性單體係在分子內具有羧基之單 體，由選自不飽和單羧酸、不飽和二羧酸、不飽和二 本紙伕尺度適用申國國家梯準（CNS ) A4規格（210X2?7公釐） --- C#-先閲«*背面之注$項再填寫本頁) 訂 r' 經濟部智慧財產局員工消費合作社印製 4 A8 BS C8 D8 六、申請專利範圍 ----------- (#先聞步背面之注-w'項再填寫本I) 羧酐、三元以上之多元不飽和羧酸，三元以上之多元 不飽和羧酐，ω -羧基聚己內酯單丙烯酸酯，和ω -羧 基聚己內酯單異丁烯酸酯選出1種或2種以上化合物 所構成。 6. 如申請專利範圍第1項之濾色片用幅照敏感性組成物 ，其中該其他單官能性單體係不飽和單羧酸，而不飽 和單羧酸爲丙烯酸或異丁烯酸* 7, 如申請專利範圍第1項之撼色片用幅照敏感性組成物 ，其中該其他單官能性單體係分子內具有羧基之單體 ，而不飽和羧酸酯或不飽和醯亞胺。 Λ, ! 經濟部智慧財產局員工消費合作社印製 8 .如申請專利範圍第1項之濾色片用幅照敏感性組成物 ，其中該不飽和羧酸酯係丙烯酸苄酯或異丁烯酸苄酯 ，而不飽和醯胺爲Μ_取代馬來醢亞胺·1 9.如申請專利範圍第1項之濾色片用幅照敏感性組成物 ，其中多官能性單體係選自三理甲基丙烷三丙烯酸酯 ，三羥甲基丙烷三異丁烯酸酯、季戊四醇三丙烯酸酯 、季戊四醇三異丁烯酸酯、季戊四醇四丙烯酸酯、季 季戊四醇四異丁烯酸酯、二季戊四醇五丙烯酸酯、二 季戊四醇五異丁烯酸酯'二季戊四醇六丙烯酸酯'二 季戊四醇六異丁烯酸酯，以及下式0)所示化合物之1 種或2種以上化合物： CH, OOCCH=CH2 | HOOCCH2 CHj COOCH2 —C— CH2 OOCCH=CHj …(1) CH2 OOCCH*CHj 本紙張尺度速用中國圃家標準（CNS)Α4規格（210X297公釐）412645 A8 B8 C8 DB Amendment * 1- Λ- Application for Patent Range No. 88113132 Radiation Sensitive Composition for Color Filters "Patent Case U.S. June 9, 2009 Amendment) Six patent applications: 1. A color filter A radiation-sensitive composition comprising (A) a colorant, and (B) containing a compound selected from the group consisting of dicarboxylic acid mono (2-propenyloxyethyl) and dicarboxylic acid mono (2-isobutenefluoroxyethyl) (Ester) one or two or more monomers and a copolymer made of a copolymer of other monofunctional monomers copolymerizable with this monohip, (C) a polyfunctional monomer, and (D) photopolymerization Initiator, which is based on 100 parts by weight of colorant (A), which contains alkali-soluble resin < B) 10 to 1,000 parts by weight: where 100 parts by weight of alkali-soluble resin < B) contains more 20 to 300 parts by weight of functional monomer (C), 0.01 to 20 parts by weight of photopolymerization initiator (D) The dicarboxylic acids of acid mono < 2-propenyloxyethyl) and dicarboxylic acid mono < 2 · isobutene pickled oxyethyl) are C2 to C2. Aliphatic dicarboxylic acid, C7 ~ C24 cycloaliphatic dicarboxylic acid, or C8 ~ C24 aromatic dicarboxylic acid * 3. For example, the radiation-sensitive composition for a color filter of the second patent application range, wherein the two The carboxylic acids are C2 ~ C8 aliphatic dicarboxylic acids. 4. The radiation-sensitive composition for a color filter as claimed in claim 3, wherein the aliphatic dicarboxylic acid is succinic acid. 5. The radiation-sensitive composition for a color filter according to item 1 of the patent application scope, wherein the other monofunctional monosystem has a monomer having a carboxyl group in the molecule, and is selected from unsaturated monocarboxylic acids, unsaturated The dicarboxylic acid and unsaturated dibasic paper are applicable to the China National Standard (CNS) A4 specification (210X2? 7mm) --- C # -Please read the “$” on the back of the page before filling in this page) Order r ' Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 412645 A8 B8 C8 DB Amendment * 1- Λ- Patent application scope No. 88113132 Radiation-sensitive composition for color filters" Patent Case U.S. Amended June 2, 2009) 6 Patent application scope: 1. A radiation-sensitive composition for color filters, which specifically comprises (A) a colorant, (B) contains a compound selected from the group consisting of dicarboxylic acid mono (2-propenyloxyethyl) and di Soluble resin consisting of a copolymer of one or more monomers of carboxylic acid mono (2-isobutylene ethoxylate) and other monofunctional monomers that can be copolymerized with this monohip, (C) polyfunctional Monomers, and (D) photopolymerization initiators, which are based on 100 parts by weight of the colorant (A). Alkali-soluble resin < B) 10 ~ 1,000 parts by weight: Among which, the alkali-soluble resin < B) contains 100-300 parts by weight of polyfunctional monomer (C) per 100 parts by weight, and the photopolymerization initiator ( D) 0.01 to 20 parts by weight "2. For example, the radiation-sensitive composition for color filters of the first scope of the application for patent * * dicarboxylic acid mono < 2-acrylic acid oxyethyl) and dicarboxylic acid mono <; 2 · isobutene pickled oxyethyl), a dicarboxylic acid, C2 ~ C2. Aliphatic dicarboxylic acid, C7 ~ C24 cycloaliphatic dicarboxylic acid, or C8 ~ C24 aromatic dicarboxylic acid * 3. For example, the radiation-sensitive composition for a color filter of the second patent application range, wherein the two The carboxylic acids are C2 ~ C8 aliphatic dicarboxylic acids. 4. The radiation-sensitive composition for a color filter as claimed in claim 3, wherein the aliphatic dicarboxylic acid is succinic acid. 5. The radiation-sensitive composition for a color filter according to item 1 of the patent application scope, wherein the other monofunctional monosystem has a monomer having a carboxyl group in the molecule, and is selected from unsaturated monocarboxylic acids, unsaturated The dicarboxylic acid and unsaturated dibasic paper are applicable to the China National Standard (CNS) A4 specification (210X2? 7mm) --- C # -Please read the “$” on the back of the page before filling in this page) Order r ' Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 A8 BS C8 D8 VI. Scope of patent application ----------- (#Xianwen step Note on the back -w 'item, then fill in this I) Carboxylic anhydride One or two polyunsaturated carboxylic acids, three or more polyunsaturated carboxylic anhydrides, ω-carboxy polycaprolactone monoacrylate, and ω-carboxy polycaprolactone monomethacrylate are selected. Consists of the above compounds. 6. The radiation-sensitive composition for a color filter, such as the item 1 in the scope of patent application, wherein the other monofunctional mono-system unsaturated monocarboxylic acid is unsaturated acrylic acid or methacrylic acid * 7, For example, the radiation-sensitive composition for color shock films of the first patent application range, wherein the other monofunctional single-system monomer having a carboxyl group in the molecule is an unsaturated carboxylic acid ester or an unsaturated sulfonimide. Λ,! Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 8. If the radiation sensitive composition for color filters of the first scope of the patent application, the unsaturated carboxylic acid ester is benzyl acrylate or benzyl methacrylate The unsaturated unsaturated amine is M_ substituted maleimide. 1 9. The radiation-sensitive composition for a color filter as described in the first item of the patent application scope, wherein the multifunctional single system is selected from trimethyl Propane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol pentaacrylate, dipentaerythritol pentamethacrylate Ester 'Dipentaerythritol hexaacrylate' Dipentaerythritol hexamethacrylate and one or more compounds of the compound represented by the following formula 0): CH, OOCCH = CH2 | HOOCCH2 CHj COOCH2 —C— CH2 OOCCH = CHj… ( 1) CH2 OOCCH * CHj This paper is a Chinese standard (CNS) A4 (210X297 mm)
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JP5523642B1 (en) * 2013-07-26 2014-06-18 太陽インキ製造株式会社 Photocurable composition for producing printed wiring board, cured product thereof and printed wiring board
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