TW353596B - Methods of attracting and combatting insects. - Google Patents
Methods of attracting and combatting insects. Download PDFInfo
- Publication number
- TW353596B TW353596B TW85103670A TW85103670A TW353596B TW 353596 B TW353596 B TW 353596B TW 85103670 A TW85103670 A TW 85103670A TW 85103670 A TW85103670 A TW 85103670A TW 353596 B TW353596 B TW 353596B
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- 241000238631 Hexapoda Species 0.000 title claims description 39
- 238000000034 method Methods 0.000 title claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 31
- 235000013305 food Nutrition 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 241000238657 Blattella germanica Species 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 102100022150 Lateral signaling target protein 2 homolog Human genes 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 101150026176 zfyve28 gene Proteins 0.000 claims 1
- 239000005667 attractant Substances 0.000 description 14
- 230000031902 chemoattractant activity Effects 0.000 description 13
- 239000004480 active ingredient Substances 0.000 description 9
- 230000000749 insecticidal effect Effects 0.000 description 9
- 239000002917 insecticide Substances 0.000 description 9
- 230000001276 controlling effect Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 241001674044 Blattodea Species 0.000 description 5
- 125000001188 haloalkyl group Chemical group 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 230000002079 cooperative effect Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- IQVNEKKDSLOHHK-FNCQTZNRSA-N (E,E)-hydramethylnon Chemical compound N1CC(C)(C)CNC1=NN=C(/C=C/C=1C=CC(=CC=1)C(F)(F)F)\C=C\C1=CC=C(C(F)(F)F)C=C1 IQVNEKKDSLOHHK-FNCQTZNRSA-N 0.000 description 2
- 241000238660 Blattidae Species 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 241000257303 Hymenoptera Species 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 230000002431 foraging effect Effects 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- 230000005180 public health Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- -1 (2,6-dichloro-4-trifluoromethyl) phenyl Chemical group 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000258241 Mantis Species 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 241000238675 Periplaneta americana Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001887 anti-feedant effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004438 haloalkoxy group Chemical group 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000003307 slaughter Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Food Science & Technology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(1 ) 本發明係關於在農作物成長之地點,尤其是栽培地農作 物,或爲了大眾健康原因,不希望有昆蟲之地點,吸引及 對抗昆蟲之方法。 已知有許多具殺蟲活性之化合物,如在國際專利公告W0 87/03781 號,W0 93/06089號及W0 94/21606號,以及歐洲 專利公告 0295117,0403300,0385809,0679650,德國專 利公告19511269及美國專利5,232,940與5,236,938所述及之 殺蟲峨嗅。 與擾人昆蟲,尤其是被認爲棲息在私人或公共房屋或建 築物之昆蟲有關連之特殊問題係其困難達到及處理所有昆 蟲,且最希望的是具有一種能消除昆蟲種群之方法,尤其 是那些不易處理或就任何理由而言,仍維持未經處理之昆 蟲。 在消除或減少擾人昆蟲種群之一項額外障礙係這些昆蟲 通常能夠偵測殺蟲活性成分之存在,因此該成分就作爲昆 蟲的驅除劑或抗-進料劑。 直到現在,用以控制大群昆蟲之一般方法,尤其是那些 不易直接處理之方法,係利用含有殺蟲活性成分之餌之多 處理法或多取代法之計劃,或使引誘劑與殺蟲活性成分結 合0 本發明之一項目標係提供一種控制或對抗昆蟲之簡化及 有效之方法。 本發明之另一項目標係提供一種控制或對抗昆蟲之簡化 及有效之方法,其中使吸引成分(亦即引謗劑)贈給昆蟲。 -4- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ---------1,装------訂------^ (請先閱讀背面之注意事項再填寫本頁) 第85103670號專利申 中文説明書修正頁(87年1〇月
„.AV B7 經濟部中央標準局員工消費合作衽印製 修正 補充 五、發明説明(2 ) 1---^一-一s 本發明之一項尤其有用之目標係提供一種控制或對抗昆 蟲之簡化及有效方法,其中使引謗劑呈給昆蟲,該引誘劑 係同時具殺菌活性。 本發明因此係提供一種具有以下式子之化合物之新用 途,如昆蟲之引誘劑:
Rl3 (0'· 其中: 尺1是0>1或甲基; R2SS(0)nR3 ; R 3是烷基或鹵烷基; R 4係選自包括氫原子,闺原子,及可能是_ N R 5 r 6, -S(〇)mR7,烷基,卣烷基,-0R8,或- N = C(R9)(R10) 基; 及R·6係個別選自氫原子,烷基,自烷基,-C(〇)烷基, -S(0)rCF3 ’·或115及尺6 —起形成可穿插一個或多個雜原 子之二價基; R 7係選自烷基或鹵烷基; R s係選自燒基,鹵燒基或氫原子; -5- 本纸浪尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) (請先閱讀背面之注意事項再填寫本頁)
經濟部中央標準局員工消費合作社印製 1' 發明獅(7~7" ~~~—— 尺9係選自氫原子及炫> 基; R 1 0係選自苯基或視需要經—或多個羥基取代之雜芳基, =原子,-0-烷基,_S_烷基,氰基,或烷基或其化合物; 1 1及R i 2係個別選自鹵原子或氫原子; R13係選自鹵原子,鹵烷基,鹵烷氧基,_s(〇)qCF3, -s F 5 ; m ’ η,q,r係個別選自〇,1及2 ; X係選自氮元素及C - R丨2基; 其限制條件爲其中、是甲基,尺3是商燒基,RANH2, Ri 1 是Cl,R13 是CF3,而 X是N。 較佳之式I化合物群爲那些具備如下者: ;及/或 Κ·3是鹵烷基;及/或 R4是νη2 ;及/或 R 1 1與R 1 2係個別選自鹵素;及/或 R 1 3是自燒•基。 根據本發明尤佳使用者爲殺蟲劑5 _胺基_ 3 _氨基_ ^ _ (2,6-二氯-4-三氟曱基)苯基_4_三氟甲基亞磺醯吡唑。本 化合物在下文中’以化合物(A)命名。 在以上説明文中,烷基可以是含有1至6個碳之支鏈或直 鏈。鹵素可以是氟,氯,溴或碘,較佳係氟或氣。 作爲文中之式(I)化合物之製備可以根據上文所列舉之專 利文件所説明之任何方法,或在熟悉化學合成技藝的人所 能瞭解範圍内之其它方法進行。 本纸張尺度適用中國國家標準(CNS ) A4規格(2IOX297公整) -. f j衣 訂 ^ (請先閱讀背面之注意事項再填寫本頁j 五、發明説明(4 ) A7 B7 經濟部中央標準局員工消費合作社印製 在一方面’本發明因此提供一種吸引昆蟲之方法,該方 法包含供應有效引誘劑量之如上述定義之式(1)化合物给這 些昆蟲攝食。 在另一方面,本發明係提供一種吸引及殺害昆蟲之方法 ,其包含將作爲引誘劑及作爲殺蟲劑兩者皆有效之量的上 述定義之式(I)化合物,供應給這些昆蟲攝食。 根據本發明之更另一方面,係提供一種控制昆蟲,尤其 是能夠在公共或私人房屋或建築物或住宅行走或遊歷之昆 蟲’亦即能夠進入或棲息在房屋之昆蟲,之方法,其中如 前述定義之引誘劑且殺蟲有效量之式(I)化合物係如同在代 用食物或食品之中的食物般,提供或呈給需要被控制之昆 蟲,其可以緊密地定位。 本發明之方法尤其有利,因爲它提供更多可能性及很多 自由以取代該殺蟲活性成分D由於其引誘劑性質,該殺蟲 活性成分可以放置在任何地方,不止在昆蟲將會行走及進 食之特定適當方法。 本發明之一項較佳具體實例,係提供一種於在或接近食 物貯藏’製備’供食之地點或飲食區,控制昆蟲種群之方 法’該方法包含以代用食物源之方式,提供在作爲引謗劑 及作爲殺蟲劑皆有效之一數量之上述定義之式(丨)化合物給 該昆蟲。因此,較佳係提供有效引謗劑及殺蟲量之式(J )化 合物给在或接近一個其它食物以該建築物或住宅之正常用 途之實際結果之方式存在之地區之昆蟲。 式(I)之活性成分較佳係按本發明,以铸之型式使用,其 -7 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本買) 袈· 訂 丄 經濟部中央標準局員工消費合作社印製 3S3S93 Α7 ___ B7 五、發明説明(5 ) ' '— 可以是固體、液體或凝膠餌。該餌之製備方式,對於熟悉 本技藝的人,簡單明瞭。餌在前文列舉之專利文件中,已 有説明。由於文中之式(I)化合物可作爲引誘劑以及殺蟲劑 ,所以不需要添加引誘劑至式之活性成分及該載體或稀 釋劑以形成該_。 本發明之方法尤其適合作爲控制例如蟑螂,蟻或諸如此 類之昆蟲(尤其是那些屬於緋蠊科(Blatidae )或大蝶科 (Formacidae)之方法。本發明之一項較佳特徵爲在蟑螂之 出現有害公眾健康之地區,亦即在房屋或建築物中,處理 蟑螂’尤其有關所謂的美國蟑螂(periplaneta americana ), 以及其它璋螂如德國璋螂(Blatella germanica)之控制。 可以使用在本發明之實踐中之引謗劑組合物或餌可以以 不同量提供或呈給這些昆蟲。然而’通常,以每1〇〇平方 米約0.00001克至約20克之式(1)之活性成分,較佳係每1〇〇 m2約0.001克至約1克,供應這些含有呈適當型式之式 化合物之引謗劑組合物或餌是有利的。 使用在本發明之引誘劑組合物通常含有約〇 〇〇〇1至約 1 5% w/w之式(I)的活性成分’較佳係從約〇 〇1至約6% 。這些组合物可以呈固體之型式’例如塵粉或顆粒或可濕 粉末,或呈液體型式,如可乳化濃縮物或眞溶液。 該引誘劑組合物亦可以含有相容表面活性劑及/或载體 ,較佳係選自可以被昆蟲吃掉之成分。該載體本身可以是 固體或液體。 該式(I)化合物可以依順序或混合使用’尤其與另—種殺 -8 - 本紙張尺疳谪用中國國家標举(CNS ) A4親技f ή λ 、 ; , t衮 訂------{ - - (請先閱讀背面之注意事項再填寫本頁) •3咏9; 〜--〜五、發明説明(6 Ο A7 B7 經濟部中央標準局員工消費合作社印製 蟲劑混合使用,例如殺昆蟲劑,殺蟎劑或殺眞菌劑。 該引誘劑組合物可以經由簡單地混合這些成分而製成。 本發明經由以下範例説明,其不應該被認爲限定或限制 本發明。 範例 在1平万米固疋區域上之大圓圈中,使各種食物及兩種化 合物(A)之餌分佈在75厘米直徑之圓圈之周園。將同樣餌 碎片放置在該圓圈之直徑相反的點上。 釋放蟑螂成長(25隻雄性與25隻雌性),且在該實驗開始 幻2 4小時,k供隱藏處。所有試驗在紅外線照明下,於夜 間進行。各物種進行三次複製。在實驗室之照明關掉後一 小時,開始觀察。以10分鐘間隔,記錄於各位置正在覓食 的蜂螂之數目,時間爲120分鐘。 範例1 只使用化合物(A )作爲殺蟲劑。 該代用食物爲:2片咬的食物,2片咬的膠狀物及2小 水。 測量且累積增加至高3小時覓食時間之正在見食的德國 螂之數目。 62隻蟑螂往化合物(A),43隻往食物,25隻往膠狀物 2 2隻往水。 ' 範例2 只使用化合物(A)作爲殺蟲劑。 代用食物爲:2片咬的食物’ 2小瓶油及2小瓶水。 瓶 璋 及 (請先閲讀背面之注意事項再填寫本頁) 訂 .丄 -9- 衣紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ________* A7 -------B7 五、發明説明(7 ) — —---— 測量且累積增加至高3小時見食時間之正在見食的德國緯 螂之數目。 68隻璋螂往化合物(A),25隻往食物,23隻往油及丨斗隻 往水。 範例3 一種殺蟲餌含有化合物(A)而另一種含有殺滅能 (hydramethylnon) ° 該代用食物爲:2片咬的食物,2片咬的膠狀物、2小瓶 水及小片殺滅能(hydramethylnon)。 測量且累積增加至高3小時見食時間之正在見食的美國蟑 螂之數目。 3 5隻蟑螂往化合物(A)(實質上幾何、'绛有往另一種殺蟲劑) ,17隻往食物,15隻往膠狀物及18隻'往水。 雖然本發明已經根據各種較佳具體實例説明,熟練的技 士可瞭解’只要不違背其精神,皆可做各種修飾,取代, 省略及改變。因此,意欲只經由以下申請專利範圍,包括 其同義字,限制本發明之範圍。 f . - I------ - —1— - ^ -表 I—I 1— ......I II I: In ί - - (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 準 一標 一家 |國 一國 中 用 一適 尺 張 -紙 本 一格 規 A4
Claims (1)
- SMS級 第85 1 03 670號專利申請案 _ 中文申請專利範圍再修正本(87年丨丨4 _ ! D8 A8 t:' 87.11.27 六、申請專利範圍 1. 一種吸引昆蟲之方法,其包括提供有效量之如下式化 合物吸引該昆蟲:汉13 經濟部中央標準局員工消費合作社印製 (I)'- 其中: _:i RACN ; R2 是-S(0)nR3 ; R 3是齒烷基; R4 係 NH2 ; R 1 1及R 1 2係個別選自鹵原子; R 1 3係卣坑基; η係選自0,1及2 ; X係選C-R12基; 上面烷基部份具有丨至6個碳之支或直鏈。 2. 根據申凊專利範圍第1項之方法,其中式(丨)化合物 是5 -胺基-3-氰基-1-(2,6 -二氯-4-三氟甲基)苯基_ 4 -二氣甲基亞項g產基υ比嗅。 3. 根據申請專利範圍第1或2項之方法,其中昆蟲族鮮 位於公共或私人住宅區,公共或私人建築物,或公共 或私人住家。 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨0X297公« ) SS3S06 六、申請專利範圍經濟部中央標準局員工消費合作社印製 4. 根據申請專利範圍第lst2項之方法,其巾昆蟲族群 能夠進入或棲息在公共或私人住宅區,公共或私人建 築’或公共或私人住家中。 5. 根據申請專利範圍第丨或2項之方法,其中昆蟲族群 位於或接近食物貯藏,製備,供應或飲食區之地點。 6. 根據申請專利範圍第1或2項之方法,其中該式(1)化 合物係以餌之型式使用,其可以是固體,液體或凝膠 7. 根據申請專利範圍第〗或2項之方法,其中該昆蟲屬 於緋蠊科(Blatidae)或大蠊科(Formacidae)。 8·根據申請專利範圍第丨或2項之方法,其中該昆蟲是 美國蜂螂(PeriPlanipa americana)或德國蟑螂(Biatella germanica)。 9·根據申請專利範圍第丨或2項之方法,其中該式(1)化 合物所給予量為每1〇〇平方米〇 〇〇〇〇1克至2〇克。 10.根據申請專利範圍第1或2項之方法,其中該式(1)化 合物所給予量為每1〇〇米2〇〇〇1克至1克。 Π·根據申請專利範圍第1或2項之方法,其中該式(I)化 合物所給予量為0.0001至15% w/w。 12.根據申請專利範圍第1或2項之方法,其中該式(I)化 '物所給予量為〇 〇丨至6% w/w。 根據申請專利範圍第1或2項之方法,其中該式(I)化 合物與表面活性劑或載體混合或掺合。 14·根據_請專利範圍第I或2項之方法,其中該式(〖)化 σ物與另一種殺有害生物劑混合或摻合。I; Γΐ 二請先閱讀背面之注意事項再填寫本頁) 訂 旅丨·
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HU (1) | HU220276B (zh) |
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FR2735950B1 (fr) * | 1995-06-29 | 1997-08-01 | Rhone Poulenc Agrochimie | Compositions insecticides a base d'un derive de phenylpyrazole pour lutter notamment contre les fourmis |
JPH0987111A (ja) * | 1995-09-27 | 1997-03-31 | Sumitomo Chem Co Ltd | 害虫駆除用毒餌剤 |
FR2745470B1 (fr) * | 1996-03-04 | 1998-04-10 | Rhone Poulenc Agrochimie | Pyrazoles aphicides |
DE69722930T2 (de) * | 1996-04-29 | 2004-05-06 | Syngenta Participations Ag | Pestizide zusammensetzungen |
HU228626B1 (en) * | 1996-07-23 | 2013-04-29 | Merial Ltd | Process and composition for the antiparasitic treatment of the surroundings of animals |
US6998131B2 (en) * | 1996-09-19 | 2006-02-14 | Merial Limited | Spot-on formulations for combating parasites |
US6426333B1 (en) | 1996-09-19 | 2002-07-30 | Merial | Spot-on formulations for combating parasites |
WO1999017613A1 (en) * | 1997-10-07 | 1999-04-15 | Rhone-Poulenc Agro | Methode of insect control |
BR9705278A (pt) * | 1997-10-15 | 1999-05-25 | Rhone Poulenc Agrochimie | Composição método para controlar formigas cortadas de folha e produto comercial |
CN1102023C (zh) * | 1998-07-08 | 2003-02-26 | 安万特杭州作物科学有限公司 | 氟虫腈复配农药 |
CN1204123C (zh) * | 2002-07-30 | 2005-06-01 | 王正权 | N-苯基吡唑衍生物杀虫剂 |
CN102246778A (zh) * | 2011-05-18 | 2011-11-23 | 海利尔药业集团股份有限公司 | 一种增效的杀虫组合物及其应用 |
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JPS63218604A (ja) * | 1987-03-06 | 1988-09-12 | Yuukou Yakuhin Kogyo Kk | 害虫駆除用毒餌剤 |
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DE19511269A1 (de) * | 1994-03-30 | 1995-10-05 | Ciba Geigy Ag | Pyrazole |
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1996
- 1996-03-27 HU HU9801631A patent/HU220276B/hu unknown
- 1996-03-27 TW TW85103670A patent/TW353596B/zh not_active IP Right Cessation
- 1996-03-27 PT PT96909130T patent/PT820228E/pt unknown
- 1996-03-27 SI SI9630173T patent/SI0820228T1/xx unknown
- 1996-03-27 BR BRPI9604945-6A patent/BR9604945B1/pt not_active IP Right Cessation
- 1996-03-27 JP JP53067696A patent/JP3681397B2/ja not_active Expired - Lifetime
- 1996-03-27 WO PCT/EP1996/001334 patent/WO1996032014A1/en not_active Application Discontinuation
- 1996-03-27 ZA ZA962447A patent/ZA962447B/xx unknown
- 1996-03-27 CZ CZ19973186A patent/CZ288743B6/cs not_active IP Right Cessation
- 1996-03-27 ES ES96909130T patent/ES2146876T3/es not_active Expired - Lifetime
- 1996-03-27 DK DK96909130T patent/DK0820228T3/da active
- 1996-03-27 DE DE69608555T patent/DE69608555T2/de not_active Expired - Lifetime
- 1996-03-27 UA UA97115389A patent/UA48176C2/uk unknown
- 1996-03-27 CN CN96193165A patent/CN1118235C/zh not_active Expired - Lifetime
- 1996-03-27 CA CA002217205A patent/CA2217205C/en not_active Expired - Lifetime
- 1996-03-27 AU AU52742/96A patent/AU709630B2/en not_active Expired
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- 1996-03-27 SK SK1362-97A patent/SK282657B6/sk not_active IP Right Cessation
- 1996-03-27 EA EA199700304A patent/EA000996B1/ru not_active IP Right Cessation
- 1996-03-27 KR KR1019970707192A patent/KR100428230B1/ko active
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- 1996-03-27 EP EP96909130A patent/EP0820228B1/en not_active Expired - Lifetime
- 1996-03-27 KR KR1019970707192A patent/KR19980703792A/ko not_active IP Right Cessation
- 1996-03-27 TR TR97/01143T patent/TR199701143T1/xx unknown
- 1996-03-27 AP APAP/P/1997/001110A patent/AP759A/en active
- 1996-03-27 PL PL96322851A patent/PL187699B1/pl unknown
- 1996-03-27 AT AT96909130T patent/ATE193183T1/de active
- 1996-04-08 PH PH52836A patent/PH11996052836B1/en unknown
- 1996-04-09 MY MYPI96001337A patent/MY112965A/en unknown
- 1996-04-10 CO CO96017129A patent/CO4650118A1/es unknown
- 1996-04-10 AR AR33611296A patent/AR001588A1/es active IP Right Grant
- 1996-10-10 US US08/731,132 patent/US5700460A/en not_active Expired - Lifetime
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1997
- 1997-10-10 OA OA70101A patent/OA10523A/en unknown
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2000
- 2000-05-25 GR GR990402499T patent/GR3033229T3/el unknown
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