TW343962B - Process for hydrocyanation - Google Patents
Process for hydrocyanationInfo
- Publication number
- TW343962B TW343962B TW085101840A TW85101840A TW343962B TW 343962 B TW343962 B TW 343962B TW 085101840 A TW085101840 A TW 085101840A TW 85101840 A TW85101840 A TW 85101840A TW 343962 B TW343962 B TW 343962B
- Authority
- TW
- Taiwan
- Prior art keywords
- para
- meta
- formulae
- zero
- compound
- Prior art date
Links
- 238000005669 hydrocyanation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 abstract 2
- ISBHMJZRKAFTGE-ONEGZZNKSA-N (e)-pent-2-enenitrile Chemical compound CC\C=C\C#N ISBHMJZRKAFTGE-ONEGZZNKSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 150000002816 nickel compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
- C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/408,250 US5523453A (en) | 1995-03-22 | 1995-03-22 | Process for hydrocyanation |
Publications (1)
Publication Number | Publication Date |
---|---|
TW343962B true TW343962B (en) | 1998-11-01 |
Family
ID=23615497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW085101840A TW343962B (en) | 1995-03-22 | 1996-02-14 | Process for hydrocyanation |
Country Status (13)
Country | Link |
---|---|
US (1) | US5523453A (en, 2012) |
EP (1) | EP0815073B1 (en, 2012) |
JP (1) | JP2911608B2 (en, 2012) |
KR (1) | KR100270499B1 (en, 2012) |
CN (1) | CN1069310C (en, 2012) |
AT (1) | ATE203233T1 (en, 2012) |
BR (1) | BR9607982A (en, 2012) |
CA (1) | CA2214009C (en, 2012) |
DE (1) | DE69613968T2 (en, 2012) |
IN (1) | IN186815B (en, 2012) |
MY (1) | MY117595A (en, 2012) |
TW (1) | TW343962B (en, 2012) |
WO (1) | WO1996029303A1 (en, 2012) |
Families Citing this family (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1082946C (zh) * | 1993-11-23 | 2002-04-17 | 纳幕尔杜邦公司 | 用于单烯烃氢氰化的方法和催化剂组合物 |
US5693843A (en) * | 1995-12-22 | 1997-12-02 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles |
JP3441605B2 (ja) * | 1996-10-30 | 2003-09-02 | 高砂香料工業株式会社 | 新規光学活性ジホスフィン及び該化合物より得られる遷移金属錯体及び該錯体の存在下にて光学活性体を得る方法 |
US5710344A (en) * | 1996-11-08 | 1998-01-20 | E. I. Du Pont De Nemours And Company | Process to prepare a linear aldehyde |
DE19652273A1 (de) | 1996-12-16 | 1998-06-18 | Basf Ag | Monoolefinische C¶5¶-Mononitrile, Verfahren zu ihrer Herstellung und ihre Verwendung |
US5847191A (en) * | 1997-07-29 | 1998-12-08 | E. I. Du Pont De Nemours And Company | Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel |
DE19740180A1 (de) | 1997-09-12 | 1999-03-18 | Basf Ag | Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
DE19825212A1 (de) | 1998-06-05 | 1999-12-09 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
DE19827232A1 (de) | 1998-06-18 | 1999-12-23 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phosphinitliganden und Verfahren zur Hydroformylierung und Hydrocyanierung |
US6048996A (en) * | 1999-08-26 | 2000-04-11 | E. I. Du Pont De Nemours And Company | Insoluble promoters for nickel-catalyzed hydrocyanation of monoolefins |
US6365322B1 (en) | 1999-12-07 | 2002-04-02 | Clariant Finance (Bvi) Limited | Photoresist composition for deep UV radiation |
FR2803294B1 (fr) * | 1999-12-30 | 2002-02-15 | Rhodia Polyamide Intermediates | Procede d'hydrocyanation de composes organiques insatures |
US6437192B1 (en) | 2000-11-17 | 2002-08-20 | E. I. Du Pont De Nmeours And Company | Hydroformylation of conjugated dienes to alkenals using phosphonite ligands |
US6362354B1 (en) | 2000-11-17 | 2002-03-26 | E. I. Du Pont De Nemours And Company | Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same |
DE10136488A1 (de) * | 2001-07-27 | 2003-02-06 | Basf Ag | Ni(O) enthaltendes Katalysatorsystem |
FR2830530B1 (fr) * | 2001-10-08 | 2004-07-02 | Rhodia Polyamide Intermediates | Procede de transformation, d'une part, de composes a insaturation ethylenique en nitriles et, d'autre part, de nitriles branches en nitriles lineaires |
AR036636A1 (es) * | 2001-10-12 | 2004-09-22 | Basf Ag | Fosfonita i, su uso como ligando en complejos de metal de transicion, dichos complejos, procedimiento para la obtencion de estos ultimos, uso de complejos de metal transitorio como catalizador y procedimientos para la adicion de acido cianhidrico a un doble enlace olefinico y para la isomerizacion d |
DE10150286A1 (de) * | 2001-10-12 | 2003-04-17 | Basf Ag | Phosphinite |
DE10150285A1 (de) * | 2001-10-12 | 2003-04-17 | Basf Ag | Phosphonite |
US6660876B2 (en) | 2001-11-26 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
US6893996B2 (en) * | 2001-11-26 | 2005-05-17 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation |
AR038161A1 (es) * | 2002-01-24 | 2004-12-29 | Basf Ag | Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos |
US6906218B2 (en) | 2002-12-18 | 2005-06-14 | Invista North America S.A.R.L. | Cyclohexane derivatives and methods for their preparation |
FR2849027B1 (fr) * | 2002-12-23 | 2005-01-21 | Rhodia Polyamide Intermediates | Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques |
US6936171B2 (en) * | 2003-01-08 | 2005-08-30 | Invista North America S.A.R.L. | Process for catalyst recovery from hydrocyanation product mixtures |
US6897329B2 (en) * | 2003-01-14 | 2005-05-24 | Invista North America S.A.R.L. | Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation |
FR2850966B1 (fr) * | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
US6844289B2 (en) * | 2003-04-08 | 2005-01-18 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst |
FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
FR2854892B1 (fr) * | 2003-05-12 | 2005-06-24 | Rhodia Polyamide Intermediates | Procede de fabrication de dinitriles |
WO2005026106A1 (en) | 2003-09-11 | 2005-03-24 | Invista Technologies S.A R.L. | Process of hydrocyanation of unsaturated carboxylic acid derivatives |
US7385071B2 (en) * | 2003-10-28 | 2008-06-10 | Invista North America S.A.R.L. | Hydrocyanation of pentenenitriles and/or 2-methyl-3-butenenitrile using promoters obtained from the chlorination of titanium-rich ores |
DE10351003A1 (de) * | 2003-10-30 | 2005-05-25 | Basf Ag | Verfahren zur Herstellung von Nickel-Phosphorligand-Komplexen |
DE10350999A1 (de) * | 2003-10-30 | 2005-06-02 | Basf Ag | Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen |
DE10351000A1 (de) * | 2003-10-30 | 2005-06-09 | Basf Ag | Verfahren zur Herstellung von Nickel(O)-Phosphorligand-Komplexen |
DE10351002A1 (de) * | 2003-10-30 | 2005-05-25 | Basf Ag | Einsatz von azeotrop-getrockneten Nickel(II)-halogeniden |
US8119829B2 (en) * | 2004-09-08 | 2012-02-21 | Invista North America S.A.R.L. | Process of hydrocyanation of unsaturated carboxylic acid derivatives |
DE102004049339A1 (de) * | 2004-10-08 | 2006-04-13 | Basf Ag | Verfahren zur Reinigung von phosphorhaltigen Chelat-Liganden |
EP1948591A1 (en) * | 2005-10-18 | 2008-07-30 | INVISTA Technologies S.à.r.l. | Process of making 3-aminopentanenitrile |
BRPI0709313A2 (pt) * | 2006-03-17 | 2011-07-05 | Invista Tech Sarl | método de separação e método para a preparação de triorganofosfitos |
US7709674B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L | Hydrocyanation process with reduced yield losses |
US7919646B2 (en) | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
US7880028B2 (en) * | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
US7709673B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
US8906334B2 (en) | 2007-05-14 | 2014-12-09 | Invista North America S.A R.L. | High efficiency reactor and process |
EP2164587B1 (en) * | 2007-06-13 | 2018-04-04 | INVISTA Textiles (U.K.) Limited | Process for improving adiponitrile quality |
EP2229354B1 (en) * | 2008-01-15 | 2013-03-20 | Invista Technologies S.à.r.l. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
EP2229353B1 (en) * | 2008-01-15 | 2018-01-03 | INVISTA Textiles (U.K.) Limited | Hydrocyanation of pentenenitriles |
US20090240068A1 (en) * | 2008-03-19 | 2009-09-24 | Invista North America S.A.R.L. | Methods of making cyclododecatriene and methods of making laurolactone |
JP5619753B2 (ja) * | 2008-10-14 | 2014-11-05 | インヴィスタテクノロジーズ エスアエルエル | 2−第二級−アルキル−4,5−ジ−(直鎖−アルキル)フェノール類を製造する方法 |
US8338636B2 (en) * | 2009-08-07 | 2012-12-25 | Invista North America S.A R.L. | Hydrogenation and esterification to form diesters |
EP2512673B1 (en) | 2009-12-18 | 2016-09-28 | Invista Technologies S.à.r.l. | Nickel metal compositions and nickel complexes derived from basic nickel carbonates |
CN103080120B (zh) * | 2010-09-07 | 2016-06-01 | 因温斯特技术公司 | 制备镍磷配体配合物 |
FR2980792B1 (fr) * | 2011-09-30 | 2013-09-06 | Rhodia Operations | Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique |
US9133223B2 (en) | 2011-12-21 | 2015-09-15 | Invista North America S.A.R.L. | Extraction solvent control for reducing stable emulsions |
US9133226B2 (en) | 2011-12-21 | 2015-09-15 | Invista North America S.A.R.L. | Extraction solvent control for reducing stable emulsions |
US9011691B2 (en) | 2011-12-21 | 2015-04-21 | Invista North America S.A.R.L. | Extraction solvent control for reducing stable emulsions |
CN103547349B (zh) | 2011-12-21 | 2016-03-16 | 因温斯特北美公司 | 用于减少稳定乳液的萃取溶剂控制 |
EP3160907B1 (en) | 2014-06-27 | 2019-11-20 | INVISTA Textiles (U.K.) Limited | Enhanced extraction of impurities from mixture comprising nitriles |
WO2015200630A1 (en) | 2014-06-27 | 2015-12-30 | Invista North America S.A R.L. | Integrated process for nitrile manufacture with enhanced liquid-liquid extraction |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3496215A (en) * | 1965-11-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins using selected nickel phosphite catalysts |
GB1112539A (en) * | 1965-11-26 | 1968-05-08 | Du Pont | Preparation of organic nitriles |
US3496217A (en) * | 1967-05-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins |
US3558688A (en) * | 1967-10-26 | 1971-01-26 | Du Pont | Preparation of allylic nitriles from allylic esters and hcn in the presence of zero-valent nickel catalysts |
NL7002580A (en, 2012) * | 1969-03-03 | 1970-09-07 | ||
US3655723A (en) * | 1969-10-31 | 1972-04-11 | Du Pont | Hydrocyanation of olefins |
US3631191A (en) * | 1970-04-08 | 1971-12-28 | Du Pont | Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes |
US3766237A (en) * | 1972-01-25 | 1973-10-16 | Du Pont | Hydrocyanation of olefins |
US3846461A (en) * | 1972-10-25 | 1974-11-05 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
US3847959A (en) * | 1972-10-25 | 1974-11-12 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
US3903120A (en) * | 1973-06-19 | 1975-09-02 | Du Pont | Preparation of zerovalent nickel complexes from elemental nickel |
US4774353A (en) * | 1986-06-05 | 1988-09-27 | E. I. Du Pont De Nemours And Company | Triorganotin catalyst promoters for hydrocyanation |
US4874884A (en) * | 1988-03-31 | 1989-10-17 | E. I. Du Pont De Nemours And Company | Promoter synergism in pentenenitrile hydrocyanation |
US5360938A (en) * | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
US5175335A (en) * | 1991-11-12 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Enantioselective hydrocyanation of aromatic vinyl compounds |
-
1995
- 1995-03-22 US US08/408,250 patent/US5523453A/en not_active Expired - Lifetime
-
1996
- 1996-02-05 IN IN206CA1996 patent/IN186815B/en unknown
- 1996-02-14 TW TW085101840A patent/TW343962B/zh not_active IP Right Cessation
- 1996-03-07 AT AT96908520T patent/ATE203233T1/de not_active IP Right Cessation
- 1996-03-07 WO PCT/US1996/002551 patent/WO1996029303A1/en active IP Right Grant
- 1996-03-07 BR BR9607982A patent/BR9607982A/pt not_active Application Discontinuation
- 1996-03-07 EP EP96908520A patent/EP0815073B1/en not_active Expired - Lifetime
- 1996-03-07 DE DE69613968T patent/DE69613968T2/de not_active Expired - Lifetime
- 1996-03-07 KR KR1019970706561A patent/KR100270499B1/ko not_active Expired - Lifetime
- 1996-03-07 CA CA002214009A patent/CA2214009C/en not_active Expired - Lifetime
- 1996-03-07 JP JP8528423A patent/JP2911608B2/ja not_active Expired - Lifetime
- 1996-03-07 CN CN96192673A patent/CN1069310C/zh not_active Expired - Lifetime
- 1996-03-16 MY MYPI96000977A patent/MY117595A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CA2214009C (en) | 2004-02-24 |
DE69613968T2 (de) | 2002-04-04 |
EP0815073B1 (en) | 2001-07-18 |
CN1179147A (zh) | 1998-04-15 |
WO1996029303A1 (en) | 1996-09-26 |
KR19980703158A (ko) | 1998-10-15 |
ATE203233T1 (de) | 2001-08-15 |
IN186815B (en, 2012) | 2001-11-17 |
MY117595A (en) | 2004-07-31 |
CN1069310C (zh) | 2001-08-08 |
JP2911608B2 (ja) | 1999-06-23 |
CA2214009A1 (en) | 1996-09-26 |
US5523453A (en) | 1996-06-04 |
JPH10505101A (ja) | 1998-05-19 |
BR9607982A (pt) | 1998-06-23 |
EP0815073A1 (en) | 1998-01-07 |
KR100270499B1 (ko) | 2000-11-01 |
DE69613968D1 (de) | 2001-08-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW343962B (en) | Process for hydrocyanation | |
TW360633B (en) | Improved process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles | |
MY112815A (en) | Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor | |
MY124170A (en) | Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor | |
ATE169902T1 (de) | Verfahren und katalysator-zusammensetzungen für die anlagerung von cyanwassenstoff an monoolefine | |
MY120453A (en) | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenesnitriles. | |
MY125853A (en) | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles | |
KR840003236A (ko) | 올레핀의 시안화 수소화 | |
DE50012997D1 (en) | Phosphite | |
NO944153L (no) | Fremgangsmåte for hydrocyanering av nitril | |
UA66806C2 (uk) | Спосіб одержання глюфозинату, проміжні продукти та спосіб одержання проміжних продуктів | |
AU2003300584A8 (en) | Method for synthesis of compounds comprising nitrile functions from ethylenically unsaturated compounds | |
KR880006166A (ko) | 할로겐화 아연 촉진제를 사용하는 연속 하이드로 시안화 반응법 | |
WO2008008930A3 (en) | Hydrocyanation process with reduced yield losses | |
GB9713739D0 (en) | Thyroid receptor ligands | |
CA2291640A1 (en) | Improved hydrocyanation process | |
KR830009004A (ko) | 올레핀의 하이드로시안화 방법 | |
KR970707079A (ko) | 비공액 2-알킬-3-모노알켄니트릴의 촉매화 기상 이성질화(catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles) | |
KR890014461A (ko) | 펜텐 니트릴의 하이드로시안화 시의 상승작용 촉진제 | |
DE69918093D1 (de) | Hydrocyanierung von olefinen und isomerisierung von nichtkonjugierten 2-alkyl-3-monoalken- nitrilen | |
MY139556A (en) | Catalyzed vapor-phase hydrocyanation of diolefinic compounds | |
EP0889027A4 (en) | METHOD FOR PRODUCING UNSATURATED NITRILE | |
MY119330A (en) | Manufacturing process for 6-aminocapronitrile | |
US5087723A (en) | Hydrocyanation of conjugated 2-alkenoates | |
TW353659B (en) | Process for the manufacture of alkylimidazolidone (meth)-acrylates |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Annulment or lapse of patent due to non-payment of fees |