TW279184B - - Google Patents

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Publication number
TW279184B
TW279184B TW083111875A TW83111875A TW279184B TW 279184 B TW279184 B TW 279184B TW 083111875 A TW083111875 A TW 083111875A TW 83111875 A TW83111875 A TW 83111875A TW 279184 B TW279184 B TW 279184B
Authority
TW
Taiwan
Prior art keywords
carpet
acid
bath
weight
melt
Prior art date
Application number
TW083111875A
Other languages
English (en)
Original Assignee
Basf Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corp filed Critical Basf Corp
Application granted granted Critical
Publication of TW279184B publication Critical patent/TW279184B/zh

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/04—Pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/06—Dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/04—Processes in which the treating agent is applied in the form of a foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0065—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by the pile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • D06N7/0073—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing the back coating or pre-coat being applied as an aqueous dispersion or latex
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/041—Polyacrylic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/065—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/04—Foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/06—Melt
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0807—Coloured
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/147—Stainproof, stain repellent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23986—With coating, impregnation, or bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2041—Two or more non-extruded coatings or impregnations
    • Y10T442/2049—Each major face of the fabric has at least one coating or impregnation
    • Y10T442/2057—At least two coatings or impregnations of different chemical composition
    • Y10T442/2066—Different coatings or impregnations on opposite faces of the fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2549—Coating or impregnation is chemically inert or of stated nonreactance
    • Y10T442/2574—Acid or alkali resistant

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Carpets (AREA)
  • Coloring (AREA)
  • Artificial Filaments (AREA)
  • Automatic Embroidering For Embroidered Or Tufted Products (AREA)

Description

經濟部中央樣準局員工消費合作社印製 ^ ^ 〇134 A7 B7 五、發明説明（1 ) 發一明描沭 本發明係關於一種用於製造抗著色之熔融染色地毯之方 法，更特定而言，其係關s‘熔融染色尼龍共聚物地毯使用 聚甲基丙烯酸，聚甲基丙烯酸共聚物，聚甲基丙烯酸與磺 化芳香醛縮合產物之混合物，及在磺化芳香醛縮合產物存 在下的甲基丙烯酸之聚合或共聚合反應產物處理該地毯 抗著色熔融染地毯纖維藉由用著色保護劑處理尼龍而製 成。 美國專利號4 , 8 2 2 , 3 7 3揭示藉由用部份磺化之酚醛樹脂 與聚甲基丙烯酸，甲基丙烯酸之共聚物或甲基丙烯酸與甲 基丙烯酸共聚物之化學结合所處理之具抗酸性著色劑著色 之纖維聚_胺基材： 美國專利號4 , 9 4 0 , 7 5 7揭示藉由在磺化芳香醛縮合聚合 物之存在下聚合α -取代丙烯酸所製備之抗著色姐成物- 另一改進尼龍抗著色性5法為將尼龍與芳香族磺酸鹽或 其之鹼金屬鹽共聚合。 美國專利號3,846,507揭示藉由製作具特定笨磺單元之 聚合物，然後將其與正常聚醯胺摻合之產生_維化聚醯胺 與不具ί η ί t y之還原性酸忭染料。 美國專利號4 , 3 7 4 , 6 4 1揭示由水與可分散之聚合體，如 含磺酸化笨之聚醯胺及著色劑所製備而用於熱塑性材料著 色之顔色濃縮物。 美國專利號4 , 5 7 9 , 7 6 2揭示由Μ特定足量之芳香族磺酸 鹽單元修飾而改善酸性染料性質的尼龍6 6或尼龍6所製成 __________________~ 4 ~_ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） ---------批衣------11------# (請先閱讀背面之注意事項再填寫本頁) A7 -V9184 B7 五、發明説明（2 ) 之地毯。 美國專利號5, 108,684揭示藉由加入顔料入含0.25-4 . 0以重量計之芳香族磺酸鹽或鹼金臛鹽的尼龍共聚物而 產生抗著色顏料化之尼龍纖維。 K上所描述之抗著色纖維之缺點為，在以高p Η值之洗潔 劑處理後，Μ著色保護劑處理之纖維著色保護作用會幾乎 消失，而未Μ著色保護劑處理之磺酸化尼龍之著色保護作 用減低- 本發明之目的為提供在用高ρ Η值之洗潔劑處理後仍具高 著色保護性之抗著色熔融染色地毯之製作方法。 抗著色熔融染色地毯之製作完成本發明之目的，其包含 a )熔融混合磺酸鹽基與著色劑之聚醯胺共聚物而形成均句 共合物熔融物； b )旋纺該聚合體熔融物成纖維； c )蔟化該纖維成地毯；及 d )以選自由含聚甲基丙烯酸，聚甲基丙烯酸共聚物，甲基 丙烯酸與磺化芳香族醛縮合產物之混合物及在磺化芳香 醛縮合產物存在下之甲基丙烯酸聚合或共聚合反應產物 中之一棰化合物處理該纖維. 在抗著色熔融染地毯纖維製作法之（a >步驟中，將含磺 酸鹽基之聚_胺共聚物熔融化混合顔色來形成均勻共聚物 熔融物。適當之含磺酸鹽基之聚醯胺共聚物在聚醯胺單體 聚合時藉由加入磺化芳香雙羧酸或其鹼金靨鹽而形成。 --5 - 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨OX 297公釐） 批衣 Ί 線 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 279184 A7 B7五、發明説明（3 ) 經濟部中央標準局員工消費合作社印製 磺化芳香雙羧酸於、例如美國專利號3 . 8 4 6 , 5 0 7與 4 , 5 7 9 , 7 6 2中所描述，其内容Μ參考資料方式併入文中。 一適當之磺化芳香雙羧酸戍鹼金屬鹽為5 -磺化異鈦酸或納 、鉀或鋰鹽。Μ下為適當之聚_胺共聚物，如尼龍6 ，尼 龍6 / 6 ，尼龍6 / 9 ，尼龍6 / 1 0，尼龍6 / Τ， 尼龍6 / 1 2，尼 龍1 1，尼龍1 2及其共聚物或混合物 通當之聚醯胺亦可為 尼龍6或尼龍6 / 6之共聚物與藉由反應雙羧酸如對鈦酸， 異鈦酸，己二酸或皮脂酸與二胺類如6伸甲基二胺、甲基 二甲苯二胺，或1 , 4雙胺基甲基環丙烷而獲得。Μ聚己内 醯胺（尼龍6 )及聚己二酸己二醇酯（尼龍6 / 6 )較佳：最佳者 為尼龍6 。 對含磺酸鹽基聚藤胺共聚物之製備而言，部份之尼龍單 體Μ同莫耳鼉之例如5 -磺化異鈦酸取代。在尼龍6 / 6之情 況則部份之己二酸Κ同莫]ί量之5 -磺化異鈦酸取代。 對尼龍6而言，加入所欲量之5 -磺化異鈦酸至己内醯胺 中繼而進行共聚合反應。 尼龍共聚物較佳含有由0 . 2 5至4 »； Κ重量計之磺化芳香雙 酸_金屬鹽，如鋰、納或鉀鹽，以0 . 5至3 % Μ重量計較佳 ，而最佳為1至2 以重量計。 本發明方法之適當著色劃為具熱安定性及化學惰性與含 水溶性染料、有機溶劑吋溶性染料、聚合體可溶染料與顔 料。例如可由H i 1 t ο n D a ν i s購得商業名P e a c 〇丨i n e 〇之銅 鈦青藍；杜邦之Μ ο n a s t r a 1 Θ G r e e n G之銅鈦青綠； BASF之Paliofast^ LBDG-K之銅钛青Μ ;杜邦之 ---------t-------IT-----1.^ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） A7 B7五、發明説明（4 ) 經濟部中央標準局員工消費合作社印製 Μ ο n a s t r a 1 〇 G「e e n G G T 7 5卜D之乾粉綢鈦青綠顔料； B A S F 之 L u c ο n y 1 T M R e d 3 8 ? ; B A S F 之 N e 〇 z a p a η Y e 1 1 〇 w R ; Ciba Geigy^lFilaniid® Red 841» Pilamid^ Yellow 2 7 3 2；由 Hoechst之 Novoperm Θ Red B L ；由 BASF之 Paliogen*® Red K3580與 Sicotan® Yellow K20110 通常使用於尼龍共聚物2著色劑量為約0 . 00 1至約5 . 0 1« 以重量計Μ尼龍共聚物總重計之最，由約0 . 0 0 5至4 %較佳 根據相對聚合體之熔點 < 該熔混通常操作於擠型器中， 溫度為由約2 2 5 至4 0 0 r。著色劑可Μ純質型式加入尼 龍共聚物中或Κ由約5至約6 5 I Μ重量計之著色劑分批加 入同樣的或吊一尼龍中或Μ龍共聚物或其他聚合體中，以 由約2 0至約3 5 % Μ重量計較佳。 該均勻聚合體熔融物可由旋纺機旋約為纖維，或Μ二種 不同方式煸纺：在-二步驟之方法中，旋妨該纖維，以修 飾劑處理及綳成一包編紗 在下一步驟中較佳抽絲與嫌構該編絲成為_塊連續之長 絲締捲物（B C卩）而適於簇化成地毯' 更佳之技術為包含結 合該擠製或已旋坊之纖維成為編絲，再抽拉，織構和纏繞 成-·包，所有程序均以一步驟完成。該製作B C F之單步驟 法可參考如旋-抽-織之業中。 為製作地毯之尼龍纖維通常具之Γ尼爾（丁尼爾即9 0 0 0 公尺長之單絲克重）在3至7 5單丁尼爾/長絲（d p f )。對地毯 纖維更佳之範圍為1 5至2 5 d p f。 (請先閱讀背面之注意事項再填寫本頁) -裝- 、-° 線 --7 ~- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 經濟部中央標隼局員工消費合作社印製 A7 B7 五、發明説明（5 ) 由此處之BC F編絲可經過許多技藝中熟知之方法加工： 本發明之纖維於步驟（C )中簇化成内裡而形成地毯。 對遮蓋樓板應用之地毯製作而言，BCF編絲常簇化成柔 軟的初級内裡。初級内裡一般選自由含傳統麻織纖維，編 織聚丙烯，孅維質不織市及尼龍，聚酯及聚丙烯不織布 未襯裡之地毯於步驟（d )中Μ聚甲基丙烯酸，聚甲基丙稀 酸共聚物，聚甲基丙烯酸與磺化芳香醛縮合產物混合物或 在磺化芳香醛縮合產物存rt:下之甲基丙烯酸聚合反應產物 處理。 聚甲基丙烯酸共聚物由甲基丙烯酸與一或多共單體之共 聚合反應形成，其描述於美國專利號4 , 8 2 2 , 3 7 3中。 較佳之共單髑包括單或多烯未飽和酸，酯，酐及醯胺如 丙烯酸，順丁烯二酸，順丁烯二酸酐，反丁烯二酸，該酸 之C，-至C : 8 -烷基或環烷基酯類，羥基烷基丙烯酸酯與甲 基丙烯酸酯，丙烯醯胺及甲基丙烯醯胺 較佳者為丙烯酸，甲基内烯酸酯，乙基丙烯酸酯，2 -羥 基乙基甲基内烯酸酯及二跸基丙基甲基丙烯酸酯 磺化芳香醛縮合產物於例如美國專利號4 , 9 40，7 5 7中所 描述： 適當之化合物為醛類與4 , 4 ·二羥基二笨基SS或笨基4磺 酸之醛縮合產物。 適當之化合物亦可為由在磺化芳香醛縮合產物存在下之 甲基丙烯酸與一或多共單體之聚合或共聚合反應產物： 未襯裡之地毯可用任何Μ巳處理法於步驟（d )中著色保 -二- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 批衣 訂 务 (請先閱讀背面之注意事項再填寫本頁) 第831U87 5號專利申請案 年脩ιΕ頁（8 4年9月）A7 B7 五、發明説明（ 經濟部中央橾生局員工消費合作杜印裝 謁劑之水溶液處理。較佳之處理法為提淨處理，連續處理 及發泡處理。未襯裡之地毯κ發泡方法連合乳膠襯底法用 著色保譁劑處理較佳，其描述於下。 在提淨處埋法中，該地毯通常在水溶液浴中處理，其地 毯：浴重最比為約1 : 5至約1 : 1 0 0 ，K約1 : 1 0至約1 : 5 0處 理約5至40分鐘較佳*較佳者為在pH值約1.5至約6.0處 理约15至約20分鐘，較佳在溫度約40至約90t：下pH值約 2 . 0至約3 . 0，較佳在溫度約7 0至約8 5 C而浴中著色保護劑 濟度在約0.1至約10.0¾地毯重，Μ約0.2至約3.0¾重較佳。 將該地毯由浴中移開，提煉及乾烽於約 50至約120 °C之烘 箱中。 在連鑛處理法中，未襯裡之地毯通常K滾輪如 F I e X n i ρΘ於浴中襯裡，其中地毯之處理於地毯：浴重量 比由約1 : 1約1 : 5 ，以約1 : 2至約1 : 3較佳。襯浴中之著色 保護劑濃度由约0.1至約10.0¾地毯重，以約0.2至約3.0¾ 較佳及P Η值約〗.5至6 . 0，以約'2 . 0至3 . 0較佳。 然後將地毯送人蒸氣產生器中較佳，其中之溫度為80至 100 C，Κ95ξ100Τ：持縝 0.5 至 6.0 分鐘較佳，1.0 至 3.0 分鐘較佳。 在發泡處理法中，該地毯較佳送入發泡器中，發泡成分 為著色保護劑具Μ下空氣：液體比為10:1至80:1，Κ由 40:1至60:1應用於該地毯表面而具足夠之力量在濕吸收由 5至60%F穿透該地毯蔟之底部較佳，又Κ濕吸收由10至 3 0 W p Η侑由2 · 0至6 · 0地毯重為基準較佳，p H值Μ 2.0至 I ·^參 訂 I (請先閱請背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210公蝽） 83. 3. 10,000 經濟部中央標準局員工消費合作杜印製 A7 B7 五、發明説明（7 ) 4 . 0較佳 '對發泡形成而言浴中之著色保護劑之澹度由為 0 . 1至1 0 . 0 $重量比，Μ 0 . 2至3 . 0 $較佳。然後該地毯於溫 度由1 0 0至1 2 Ο Γ之烘箱中乾燥‘- 在所有之三個處理法中•為了要降低著色保護劑之Ρ Η值 ，於浴中可加入有機或無機酸如對甲笨磺酸，磷酸，磺酸 ，胺磺酸等* Μ胺磺酸較佳。 在所有之Ξ':個處理法中之著色保護劑最終濃度為由〇 . 1 至約5 ϋ;重量比，以地毯重為基準，其最佳為0 . 2至3 %。 然後初级襯裡通常塗佈J: 一適當之乳膠材料如傳統的笨 乙烯-Γ二烯乳膠，氯化亞乙烯聚合體或氯化乙烯-氯化 亞乙烯共聚物。通常用填料如碳酸鈣來降低乳膠成本。通 常最後步驟為2级襯裡，通常其為麻織纖維或如聚丙烯之 編織合成物- 較佳為使用編織聚丙烯初级襯裡，傳統之笨乙烯-丁二 烯（S Β )乳膠及麻織纖維或編織聚丙烯為二鈒襯裡：S Β乳膠 中可包含碳酸鈣填料及/或一或多之列於上之水合材料： 該地毯應用於覆蓋地板 例] 將尼龍6與磺化鈦酸之鋪鹽共聚物，其含0 . 1 4 $硫及相 對黏度U V ) 2 . 5 5 (在2 5 Γ下Μ重量計1无溶液於9 0 %甲酸中> 與0.0 01«肽青綠，0.00U鈦青Μ ，0.004¾碳黑及0.2¾二 氧化钛於傳統之旋纺器中，2 6 5 t、f融旋纺而得到淡灰色 蔭而產生11 1 5 丁尼爾5 8長絲陽離子可染編絲。該編絲具胺 基含量（A E G ) 1 1 m e g ./公斤：> Μ同法形成尼龍6編絲 -1 A - 本紙張尺度適用中國國家標率（CNS ) A4規格（210X 297公釐） ----------批衣------ir-----1 ^ (請先閲讀背面之注意事項再填寫本頁) A7 7D184 B7 五、發明説明（8 ) (請先閱讀背面之注意事項再填寫本頁) (in t r a m 丨 d B ®，B A S F A G ,德國，R V = 2 . 7 )旋纺，其具 A E G 3 6 m e g / 公斤。 將陽離子可染編絲與ιΕ常酸可染編絲編成各別管來模擬 地毯。由每一編織管之4個5 0克樣本記錄為樣本1 - 4且分 別Μ 2 0 ·· 1浴比率藉由Μ下之提淨處埋法處理： 樣__立_丄 未處理。 樣本2 正常酸可染和陽離子可染樣本藉由下列步驟Μ個別同 量浴來處埋、 製備2個冷的浴1升： 0 . 2 5克/升 V e r s e n e 〇 (伸乙基：二胺四醋酸，二納鹽， 蝥隔劑），Mali inckrodt Specialty Chemicals Γ ο, ί η A a r ί s, Κ Υ 0 . 5 0克/升 Ν Β - 5 7 L C (在磺化芳香醛縮合產物存在下甲基 丙烯酸之聚合或共聚合反應產物）B A S F Corporation, Par sippany, NJ胺碌酸至 pH 值 2 . 0 - 經濟部中央標準局員工消費合作社印製 樣本進入每·浴中，加熱至8 5 t並於8 5 t F持續】5分鐘 後冷卻。 樣本從浴中移除，萃取尨於Η 0 =Γ之烘箱中乾燥。 然後樣本在1 4 0 °C下熱處理1分鐘來模擬乳膠襯裡乾燥 之溫度c 樣本3 --4· 1 ~- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（9 ) 止.常酸可染及陽離子可染樣本藉由下列步驟Μ個別同量 浴處理。 製備二個冷浴〗升。 0 . 2 5克/升 V e r s e n e Θ (伸乙基二胺四醋酸，二納鹽，
II隔劑）· Mallinekrodt specialty Chemicals in Paris, K Y 0 . 5 0克/升 N 5 0丨丨（由：：羥基二笨基W及醛之反應而得 之磺化芳香縮合產物）於B A S F F i b e r Products k1 & 丨）at Enka, Nc 實驗室製備 胺磺酸至P H值2 . 0 樣本進入每一浴中，加熱至8 5 t及持績1 5分鐘後冷卻「 然後樣本在1 4 0 V下熱處理1分鐘來横擬乳膠襯裡乾燥 之溫度。
揉——iLA 正常酸可染及陽離子可染樣本賴由T列步驟Μ個別同量 浴處理 製備冷浴 ().2 5毫克/升 V e r s e n e ® (伸乙基二胺四醋酸，二納鹽， II 隔劑），M a Π i n c k r 〇 d 1, s p e c i a i t y Chemicals C i) . in Paris, K Y 5.7¾ ( M地毯編絲重為準H 7 . 4 :固體P M A A (聚甲基 丙烯酸）胺磺酸p H值至2 . 0 樣本進入每一浴中，加熱至8 5 t並於8 5 P下持續】5分鐘 --·1，，2 二- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X2517公釐） 裝 訂 線 (請先閱讀背面之注意事項再填寫本頁) -79184 A7 B7 五、發明説明（10) 後冷卻。 樣本移出浴中’於110 t烘箱中提取及乾煉。 然後樣本在140 C下加熱處理1分鐘來横擬乳膠襯裡乾 埭之溫度。 在處理後，每一處理管中之樣本暴露於Bane-cieee^^ 潔劑，Bane-C丨ene Corporati〇n。依據製造廠商指示製備 之IndianapolisM實驗室中下列步嫌具pH值1〇.〇。 由處理樣本卜4號之編管樣本於10:；1浴比率之
Corporation中個別處理。在室溫下處理Indianapolis 30分鐘，然後用家用洗衣機之旋轉循環離心及在室溫下 於網幕中空氣乾堍〗6小時。 當樣本乾燥後，由每一處理樣本得來之未洗潔與已洙潔 之樣本Μ下列程序測試其抗紅色染性。 經濟部中央標準局員工消費合作社印製 C請先閱讀背面之注意事項存填寫本萸)
用 Sauer’s Red FoodG Color (Colour Index Food Red 17 or FD&C Red 40) » C.F. Sauer Company in Richmond, VA.於室溫下Ml〇:l浴比率處理該樣本5分鐘 。Sauer’s Red Food 之濃度為 2.5 克 / 升之 Sauer’s Red Pood Color，其用檸樣酸調整pH值至2.8 ，相等於FD&C
Red 40之澹度。 所附之表1顯示了在洗潔相對於未處理之陽離子樣本與 正常酸可染樣本後之處理過陽離子可染樣本對抗紅染色性 的改善ϋ -1 3 ~ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -79184 Α7 Β7 五、發明説明（11 ) 表 1 樣本丨S t e a i rt 編號4處理 1 i 朱 1 未 編 絲 正 常 抗紅染測試f B a n e - C 1 e n e洗潔 ί 1劑加抗紅染測試* 31.3 30.0 陽離子 4.4 4.3 ! 2 丨 Ν Β - 5 7 L C ιΐ- 常 0.6 Π . 5 2 Ν Β - 5 7 L C: 陽離子 1.6 0.7 3 Ν 5 0 Η —E 常 7 . 3 11.4 N 5 0 H 陽離T- μ-- 4 P M A A tl. 常 0.9 9.3 4 PMA A 陽離子 0.4 0 . 6 i A C S Δ E c i t k A B 值 A k c i f :l·. A B值愈低 w抗染性愈佳 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 例2 由每洌1之每-同樣編W中取4個超過5 0克樣本編號為 5 - 8巨以以I、之模擬連續處理法於實驗室中處理 在室溫下2 . 5 : 1浴比率熗杯中個別處埋每一樣本，縫 由浸潰和壓交換輪流進行ί ΐ.至其均勻潤濕處埋液 然後樣 本由燒杯中移開及在實驗室Kusters® 蒸氣產生器中於 9 9 t ’丨、'蒸汽化1分鐘、蒸氣化後•離心樣本儘可能移去水 份及於1 1 0 Γ下烘箱乾燥 然後在1 4 () Γ下處理來模擬乳 膠襯裡乾燥之溫度-處理浴如下： 樣H. -~ 1 4 ~- 本紙張尺度適用中國國家標準（CNS > Α4規格（210Χ 297公釐） 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（12 ) 未處埋|
樣主iL 0 . 2 5克/_升 V e r s e n e ^ (伸乙基二胺四醋酸，二納鹽， 蟹隔劑），M a H i it (' k r 〇 d t s p e c ί a j t y Chemicals ί: o . in Paris, K Y 4 . 0克/升 N B - 5 7 L C (在磺化芳香醛縮合產物存在F甲基 丙烯酸之聚台或共聚合反應產物）B A S F Corporation Parsippany, N J 胺磺酸至p H值2 . 0 瘇立.1 0.25 V e r s e n e 〇 (伸乙基二胺四醋酸，二納鹽， 蝥隔劑），M a i 1 ί n c k r 〇 d t s p e c* ί a 1 t y Chemicals ( o. in Paris, K Y 4.0 N 5 0 H (由.：羥二笨基®及醛之反應而得之 磺化芳香縮合產物）KBASFFiber .Products R 8·. D at Enka NC 實驗室製備。 胺磺酸至p Η值2 . 0 樣――本1 0 · 2 5克/汗 V e r s e n e Θ (伸乙基二胺四醏酸，二納鹽， 蟹隔劑），M a I 1 i n c k r 〇 d t S p e c i a 1 t, y C h e m ί c a Is (' o , i η P a r i s * K Y 4 · 0 克 / 升 P M A A (在 B A S F F ί b e r P r o d u c t s R & ί ) 3 t: E n k a , N C實驗室由甲基丙烯酸用過硫酸銨當 起始劑所製備之聚甲基丙烯酸） 本紙張尺度適用中國國家標準（CNS〉A4規格（210X297公釐） --------丨^------.玎----- (請先閱讀背面之注意事項再填寫本頁) A7五、發明説明（13 ) 胺磺酸至p Η值2 . 0。 在處理後，樣本5 - 8暴露於B a n e - C 1 e n e ®洗潔劑中以同 例1之方法測試其抗紅色性。 所附之表11顯示3在洗潔相對於未處理之陽離子樣本與 Ε常酸可染樣本之處理過陽離f可染樣本抗紅染色性之改 表 2 善。 1樣本 編號 抗 染 處 理 編 絲 抗紅染測試 .T, B a n e - C 1 e n e 洗潔 劑加抗紅染測試ί 5 朱 正 常 30.2 27.7 5 末 陽離子 6.6 5.0 6 N B - 5 7 1, C 正 常 3.6 17.8 6 N B - 5 7 L C 陽離子 1.4 1,2 7 N 5 0 Η 正 常 19.9 2 1』 7 Ν 5 0 Η 陽離子 4.2 1.9 8 丨 PMAA 正 常 3.9 17.3 8 ； PMAA 陽離子 0.8 0.9 ’-1’· |\ L S A E 1 E L A B 值 --------丨^------、玎------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 Δ ET E 1. A B值愈小則抗染性愈佳 例3 由每一例1中同樣之編管取2個超過50克樣本編號為9 與1 0於實驗室中藉襯/乾處理法模擬發泡下如下： 在個別浴中沾濕該管，在沾濕後，在已決定之滾壓下立 刻由實驗襯底器襯底而具1 0 0 濕吸收。然後在1] 0 1C 烘箱 16-- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐〉 ^0184 A7 B7 五 '發明説明（l4 ) 中乾**該管，然後在140 c下處理1分鐘來模擬乾嫌乳膠 襯裡溫度。 浴之處理如下： 樣太9 未處理 樣本10 0,25克/升 Versene❼（伸乙基二胺四酷酸，二納鹽， 整隔劑），Mallinckrodt specialty Chemicals Co. in Paris, K Y 9.9克/升 NB-57LC(在磺化芳香醛縮合產物存在下，甲 基丙烯酸之聚合或共聚合反應產物）BASF Corporation 胺磺酸至pH值2.0。 在處理後，樣本9與1()暴露於Bane-Clene®洗潔劑及以 同例1之法測試抗紅染性。 所附表i顯示了在洗潔相對於未處理之陽離子樣本與正 常酸可染樣本後之處理過陽離子可染樣本對抗紅染色性的 改善。 裝 訂 系 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作杜印製 表 3 樣本 钃號 抗 染 處 理 編 絲 抗魟染澜試 必· Bane-Clene洗潔 劑 9 未 正 常 33.2 33.9 9 N B - 5 7 L C 陽離子 5.3 5.2 10 未 正 常 2.2 16.5 10 NB-57LC 陽離子 1.6 4.4 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐〉 Μ 2701S4 Β7 五、發明説明（15 ) A S Δ Ε ί: I E L. A E(值 Δ t c: ί E i. A B值愈小彳几染性愈佳ϋ --------—I------ir-------.^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -二 4-8·二- 本紙張尺度適用中國國家標準（CNS > Α4規格（210X29*7公釐）

Claims (1)

  1. 79184 Α8 Β8 C8 D8 cl 六、申請專利範圍 1. 一種製作抗著色之熔融染色地毯之方法，其係包含 a) 熔融混含磺酸基之聚醢胺共聚物，與具熱安定性及化 學惰性含水溶性染料、有機溶劑可溶性染料、聚合體可 溶染料與顔料等著色劑而形成均匀聚合物熔融物； b) 旋坊該聚合物熔融物成纖維； C)於背襯簇化該纖維Μ形成地毯及； d)以選自聚甲基丙烯酸、甲基丙烯酸共聚物、聚甲基丙 烯酸與磺化芳香醛縮合產物之混合物、及在磺化芳香 醛縮合產物存在下之甲基丙烯酸聚合或共聚合反應產 物之化合物處理該地毯； 在提淨處理法中* Μ水溶液浴處理該地毯，其地毯： 浴重量比為約1:5至約1:100 ，並持續一段約5至40分 鐘之時間，其pH值為約1.5至約6.0 ，溫度約40至約 90C，而浴中著色保護劑澹度在約0. 1至約10. 0¾地毯重 ;將該地毯由浴中移開，提煉及乾燥於約50至約120TC 之烘箱中； 在連續處理法中，以滾輪於浴中襯墊該未襯裡之地毯 ，其中地毯之處理於地毯：浴重量比由約1:1約1:5 . 襯浴中之著色保護劑瀠度由約0.1至約10.0¾地毯重， pH值為約1.5至6.0; 經濟部中央標準局員工消费合作社印繁 (請先閱讀背面之注意事項再填寫本頁) 然後將地毯送入蒸氣產生器中，其中之溫度為80至 100 1C，持續0 . 5至6 . 0分鐘； 在發泡處理法中，將該地毯通過發泡器中，並使用一 種作為著色保護劑之發泡成分於該地毯表面，其具空氣 -1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A8 279184 ll D8 六、申請專利範圍. :液體比為10:1至80:1，使具足夠之力量κ濕吸收率5 至60¾滲透至該地毯簇之底部，而pH值由2. 0至6. 〇地毯 重；其中，浴中之著色保護劑之濃度由為0.1至1〇.〇重 量龙；然後將該地毯置於溫度由100至1201C之烘箱中乾 烽。 2. 根據申請專利範圍第1項之方法，其中含磺酸基之聚_ 胺共聚物可藉由磺化芳香二羧酸或其鹸金饜鹽與聚醯胺 形成單體共聚合而形成。 3. 根據申請專利範圃之第1項或第2項之方法，其中之磺 化芳香二羧酸或其鹼金屬馥選自5 -磺化異钛酸與其納鹽 ，鉀鹽及鋰鹽中。 4 · 根據申請專利範圍第1或2項之方法，係特徵於獲得一 種抗著色之熔融染色地毯。 V却先閲讀背s之注意事項再填寫本頁) 、1T 經濟部中央標準局貝工消费合作杜印製 本紙張尺度適用中國國家標準（CNS )八4说格（210X297公嫠）
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