TW202309112A - 丙烯基共聚物、其製備方法和用途和包含其的聚丙烯組合物 - Google Patents

丙烯基共聚物、其製備方法和用途和包含其的聚丙烯組合物 Download PDF

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TW202309112A
TW202309112A TW111115322A TW111115322A TW202309112A TW 202309112 A TW202309112 A TW 202309112A TW 111115322 A TW111115322 A TW 111115322A TW 111115322 A TW111115322 A TW 111115322A TW 202309112 A TW202309112 A TW 202309112A
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Taiwan
Prior art keywords
propylene
based copolymer
polymerization
polypropylene
catalyst
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TW111115322A
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English (en)
Chinese (zh)
Inventor
宋文波
方園園
韓書亮
金釗
王路生
呂靜蘭
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大陸商中國石油化工科技開發有限公司
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Priority claimed from CN202110449881.5A external-priority patent/CN115232236B/zh
Priority claimed from CN202110449898.0A external-priority patent/CN115246967B/zh
Priority claimed from CN202110448666.3A external-priority patent/CN115232235B/zh
Application filed by 大陸商中國石油化工科技開發有限公司 filed Critical 大陸商中國石油化工科技開發有限公司
Publication of TW202309112A publication Critical patent/TW202309112A/zh

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27Amount of comonomer in wt% or mol%
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
TW111115322A 2021-04-25 2022-04-21 丙烯基共聚物、其製備方法和用途和包含其的聚丙烯組合物 TW202309112A (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
CN202110449881.5A CN115232236B (zh) 2021-04-25 2021-04-25 一种丙烯基共聚物及其制备方法和应用和聚丙烯组合物
CN202110449881.5 2021-04-25
CN202110449898.0A CN115246967B (zh) 2021-04-25 2021-04-25 一种丙烯基组合物及应用和聚丙烯材料
CN202110448666.3 2021-04-25
CN202110448666.3A CN115232235B (zh) 2021-04-25 2021-04-25 一种烯烃聚合物的制造方法及烯烃聚合物
CN202110449898.0 2021-04-25

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Publication Number Publication Date
TW202309112A true TW202309112A (zh) 2023-03-01

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TW111115322A TW202309112A (zh) 2021-04-25 2022-04-21 丙烯基共聚物、其製備方法和用途和包含其的聚丙烯組合物

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Country Link
US (1) US20240218098A1 (enExample)
EP (1) EP4332132A4 (enExample)
JP (1) JP2024514968A (enExample)
KR (1) KR20230175305A (enExample)
CN (1) CN117321095A (enExample)
BR (1) BR112023022186A2 (enExample)
CA (1) CA3216518A1 (enExample)
TW (1) TW202309112A (enExample)
WO (1) WO2022228260A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116239716A (zh) * 2023-03-21 2023-06-09 广东新华粤石化集团股份公司 一种丙烯共聚物及其制备方法
CN119684499A (zh) * 2023-09-22 2025-03-25 国家能源投资集团有限责任公司 用于烯烃聚合过程的催化剂、丙烯聚合物及其生产方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
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EP0582194B1 (de) 1992-08-03 1998-05-06 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5714554A (en) * 1992-09-08 1998-02-03 Rexene Corporation High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US6525157B2 (en) 1997-08-12 2003-02-25 Exxonmobile Chemical Patents Inc. Propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
ES2182494T3 (es) 1998-03-11 2003-03-01 Dow Chemical Co Procedimiento integrado para la preparacion de complejos de dienos.
JP2001064322A (ja) * 1999-06-24 2001-03-13 Idemitsu Petrochem Co Ltd プロピレン系重合体及びその成形体並びにプロピレン系重合体の製造方法
KR100374154B1 (ko) 2000-06-24 2003-02-26 장학선 전원신호 및 데이터신호를 송수신하기 위한 시스템
JP2004527617A (ja) 2001-04-12 2004-09-09 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンコポリマー
US7700707B2 (en) * 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US8618219B2 (en) * 2002-10-15 2013-12-31 Exxonmobil Chemical Patents Inc. Propylene copolymers for adhesive applications
KR20070039930A (ko) * 2004-07-08 2007-04-13 엑손모빌 케미칼 패턴츠 인코포레이티드 초임계 조건에서 중합체의 제조방법
DE602007009851D1 (de) * 2007-11-30 2010-11-25 Borealis Tech Oy Random-Propylencopolymer mit hohem Comonomergehalt
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CN114423838B (zh) * 2019-07-17 2023-11-24 埃克森美孚化学专利公司 包含丙烯-乙烯(-二烯)共聚物的压敏粘合剂
KR20220139378A (ko) * 2020-02-11 2022-10-14 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법

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Publication number Publication date
BR112023022186A2 (pt) 2023-12-19
EP4332132A1 (en) 2024-03-06
US20240218098A1 (en) 2024-07-04
CN117321095A (zh) 2023-12-29
EP4332132A4 (en) 2025-08-20
JP2024514968A (ja) 2024-04-03
KR20230175305A (ko) 2023-12-29
WO2022228260A1 (zh) 2022-11-03
CA3216518A1 (en) 2022-11-03

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