JP2024514968A - プロピレン系共重合体、その製造方法および使用、ならびに該プロピレン系共重合体を含有するポリプロピレン組成物 - Google Patents

プロピレン系共重合体、その製造方法および使用、ならびに該プロピレン系共重合体を含有するポリプロピレン組成物 Download PDF

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JP2024514968A
JP2024514968A JP2023565395A JP2023565395A JP2024514968A JP 2024514968 A JP2024514968 A JP 2024514968A JP 2023565395 A JP2023565395 A JP 2023565395A JP 2023565395 A JP2023565395 A JP 2023565395A JP 2024514968 A JP2024514968 A JP 2024514968A
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propylene
polypropylene
polymerization
comonomer
based copolymer
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JP2024514968A5 (enExample
Inventor
宋文波
方園園
韓書亮
金▲ザオ▼
王路生
呂静蘭
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Sinopec Beijing Research Institute of Chemical Industry
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Sinopec Beijing Research Institute of Chemical Industry
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Priority claimed from CN202110449881.5A external-priority patent/CN115232236B/zh
Priority claimed from CN202110449898.0A external-priority patent/CN115246967B/zh
Priority claimed from CN202110448666.3A external-priority patent/CN115232235B/zh
Application filed by Sinopec Beijing Research Institute of Chemical Industry filed Critical Sinopec Beijing Research Institute of Chemical Industry
Publication of JP2024514968A publication Critical patent/JP2024514968A/ja
Publication of JP2024514968A5 publication Critical patent/JP2024514968A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27—Amount of comonomer in wt% or mol%
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
JP2023565395A 2021-04-25 2022-04-21 プロピレン系共重合体、その製造方法および使用、ならびに該プロピレン系共重合体を含有するポリプロピレン組成物 Pending JP2024514968A (ja)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
CN202110449881.5A CN115232236B (zh) 2021-04-25 2021-04-25 一种丙烯基共聚物及其制备方法和应用和聚丙烯组合物
CN202110449881.5 2021-04-25
CN202110449898.0A CN115246967B (zh) 2021-04-25 2021-04-25 一种丙烯基组合物及应用和聚丙烯材料
CN202110448666.3 2021-04-25
CN202110448666.3A CN115232235B (zh) 2021-04-25 2021-04-25 一种烯烃聚合物的制造方法及烯烃聚合物
CN202110449898.0 2021-04-25
PCT/CN2022/088102 WO2022228260A1 (zh) 2021-04-25 2022-04-21 丙烯基共聚物、其制备方法和用途和包含其的聚丙烯组合物

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JP2024514968A true JP2024514968A (ja) 2024-04-03
JP2024514968A5 JP2024514968A5 (enExample) 2024-08-06

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JP2023565395A Pending JP2024514968A (ja) 2021-04-25 2022-04-21 プロピレン系共重合体、その製造方法および使用、ならびに該プロピレン系共重合体を含有するポリプロピレン組成物

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US (1) US20240218098A1 (enExample)
EP (1) EP4332132A4 (enExample)
JP (1) JP2024514968A (enExample)
KR (1) KR20230175305A (enExample)
CN (1) CN117321095A (enExample)
BR (1) BR112023022186A2 (enExample)
CA (1) CA3216518A1 (enExample)
TW (1) TW202309112A (enExample)
WO (1) WO2022228260A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116239716A (zh) * 2023-03-21 2023-06-09 广东新华粤石化集团股份公司 一种丙烯共聚物及其制备方法
CN119684499A (zh) * 2023-09-22 2025-03-25 国家能源投资集团有限责任公司 用于烯烃聚合过程的催化剂、丙烯聚合物及其生产方法

Citations (4)

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JP2008506018A (ja) * 2004-07-08 2008-02-28 エクソンモービル・ケミカル・パテンツ・インク 超臨界条件におけるポリマー製造
JP2011508009A (ja) * 2007-12-20 2011-03-10 エクソンモービル リサーチ アンド エンジニアリング カンパニー エチレンプロピレンコポリマーのためのバルク均一重合方法
JP2017531721A (ja) * 2014-10-27 2017-10-26 ボレアリス エージー 衝撃強さ／剛性バランスが改善され、粉体流動性が改善され、排出量が低減された収縮率が低い異相ポリプロピレン
WO2021011892A1 (en) * 2019-07-17 2021-01-21 Exxonmobil Chemical Patents Inc. High propylene content ep having low glass transition temperatures

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US5714554A (en) * 1992-09-08 1998-02-03 Rexene Corporation High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers
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JP2001064322A (ja) * 1999-06-24 2001-03-13 Idemitsu Petrochem Co Ltd プロピレン系重合体及びその成形体並びにプロピレン系重合体の製造方法
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JP2008506018A (ja) * 2004-07-08 2008-02-28 エクソンモービル・ケミカル・パテンツ・インク 超臨界条件におけるポリマー製造
JP2011508009A (ja) * 2007-12-20 2011-03-10 エクソンモービル リサーチ アンド エンジニアリング カンパニー エチレンプロピレンコポリマーのためのバルク均一重合方法
JP2017531721A (ja) * 2014-10-27 2017-10-26 ボレアリス エージー 衝撃強さ／剛性バランスが改善され、粉体流動性が改善され、排出量が低減された収縮率が低い異相ポリプロピレン
WO2021011892A1 (en) * 2019-07-17 2021-01-21 Exxonmobil Chemical Patents Inc. High propylene content ep having low glass transition temperatures

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BR112023022186A2 (pt) 2023-12-19
TW202309112A (zh) 2023-03-01
EP4332132A1 (en) 2024-03-06
US20240218098A1 (en) 2024-07-04
CN117321095A (zh) 2023-12-29
EP4332132A4 (en) 2025-08-20
KR20230175305A (ko) 2023-12-29
WO2022228260A1 (zh) 2022-11-03
CA3216518A1 (en) 2022-11-03

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