TW202033093A - Clothes insect pest control composition, and clothes deodorizing method and clothes insect pest controlling and deodorizing method using said composition - Google Patents

Abstract

A clothing pest control composition is provided that has a pest prevention function and also can persistently deodorize unpleasant odors adhering to clothing. A clothing pest control composition containing a pest prevention component and a fragrance component, wherein the fragrance component has a deodorizing function for deodorizing unpleasant odors adhering to clothing, and the pest prevention component has a persistence function for causing the deodorizing function of the fragrance component to persist. The pest prevention component is empenthrin and/or profluthrin, and the fragrance component is a compound that: has no electron-conjugated part other than an electron-conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure; has a carbon number of 6-18; has a molecular weight of 98-270; has a carbon atom, a hydrogen atom, and an oxygen atom; and does not have a sulfur atom, a nitrogen atom, or a halogen atom.

Description

Clothing pest control composition, and clothing deodorization method using the composition, and clothing pest control and deodorization method

The present invention relates to a clothing pest control composition containing pest control components and fragrance components and a clothing deodorization method using the composition. Furthermore, the present invention relates to a method for preventing insects and deodorizing clothes by simultaneously performing insect-proof treatment and deodorizing treatment on clothes.

In order to protect fiber products from clothing pests, various clothing pest control products have been developed and have been put into practical use. For example, there is known a clothing pest control product that uses a fragrance component as an active ingredient instead of a pyrethroid-based pest control component having room temperature volatility (for example, refer to Patent Document 1).

The clothing pest control product of Patent Document 1 is made by keeping perfume ingredients such as acetate compounds and allyl ester compounds in a water-absorbing polymer. By maintaining the volatility of the active ingredients for a long time, it can kill wardrobes, drawers, closets, and clothing. The larvae of the clothing pests in the storage space such as the storage box exerts an excellent feeding suppression effect. [Prior Technical Literature] [Patent Literature]

[Patent Document 1] JP 2015-117231 A

[The problem to be solved by the invention]

Clothes often have daily odors such as sweat, elderly people, and cigarette odors when they are worn. Therefore, in terms of clothing management, except for the prevention of clothing pests, it is preferable to remove the bad odor attached to clothing. For example, because outerwear is often used day after day, and when it is taken out from a storage space such as a closet, the daily odor attached to the clothing the day before may cause discomfort. Therefore, it is desirable to continuously remove the odor during storage. .

The clothing pest control product of Patent Document 1 is expected to exhibit deodorizing functions by using fragrance components as effective ingredients. However, it focuses on the insect repellent function against clothing pests and selecting compounds as fragrance components. Regarding the removal of odors specific to clothing There is still room for discussion on odor function.

The present invention was completed in view of the above-mentioned problems, and aims to provide a clothing pest control composition that can exert its insect-proof function and can continuously remove bad odors attached to clothing, and a clothing deodorizing method using the composition. Furthermore, the present invention aims to provide an insect-proof and deodorant method for clothing that can simultaneously impart an insect-proof effect and a continuous deodorant effect to clothing with only one treatment. [Means to solve the problem]

The characteristic structure of the clothing pest control composition of the present invention for solving the above-mentioned problems is: A clothing pest control composition, which contains pest control components and fragrance components, wherein: The aforementioned fragrance ingredient has a deodorizing function to remove bad odors attached to clothing, The anti-insect ingredient has a continuous function of continuously maintaining the deodorizing function of the fragrance ingredient.

The clothing pest control composition of this composition is based on the inventors of the present invention. After preparing various clothing pest control compositions and repeating various tests, they have newly discovered that a specific pest control component has a continuous function of maintaining the deodorizing function of the fragrance component. A person who has reached completion. According to the clothing pest control composition of this structure, the fragrance component has a deodorizing function to remove the odor attached to the clothing material, and the pest control component has a continuous function to maintain the deodorizing function of the fragrance component, and can exert the effect of the pest control component on clothing pests. It has anti-insect function and can continuously remove bad odors attached to clothing while maintaining the deodorizing function produced by fragrance ingredients for a long time. Therefore, by pre-treating the clothing storage space of the clothing pest control composition of the present invention, the deodorizing function generated by the fragrance component can be continuously maintained during storage, and it is possible to prevent uncomfortable feeling when the clothing is taken out from the storage space.

In the clothing pest control composition of the present invention, preferably The aforementioned insect-proof ingredients are Yibining and/or profluthrin, The aforementioned fragrance ingredients do not have electronic conjugate parts other than those derived from benzene ring, benzoate structure or salicylate structure, carbon number is 6-18, molecular weight is 98-270, and it has carbon atoms , Hydrogen atom and oxygen atom, without sulfur atom, nitrogen atom and halogen atom compound.

According to the clothing pest control composition of this structure, by combining the above-mentioned specific insect-preventing component and the fragrance component, the deodorizing function of the fragrance component can be continuously maintained for a long time by the synergistic effect of the insect-preventing component and the fragrance component.

In the clothing pest control composition of the present invention, The aforementioned fragrance ingredients are preferably selected from the group consisting of cis-3-hexenol, dihydrogeranyl alcohol, ethyl linalool, linalool, geraniol, tetrahydrogeranol, terpineol, phenethyl alcohol, Xinyang Jasmaldehyde, lily of the valley, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicylate, methyl dihydrojasmonate, agarinyl acetate, raspberry ketone, carol musk, At least one of the group consisting of ethylene glycol tridecanedioic acid and pentadecanolide.

According to the clothing pest control composition of the present structure, by containing the fragrance component, the synergistic effect of the pest control component and the fragrance component can be increased, and the sustainability of the deodorizing function can be improved.

In the clothing pest control composition of the present invention, The content of the aforementioned fragrance component is preferably 1 to 20% by mass.

According to the clothing pest control composition of this constitution, since the content of the fragrance component is in an appropriate range, for example, the carrier impregnated with the clothing pest control composition is placed in the storage space of the clothing, and the clothing pest control composition is stored in the storage space. When it volatilizes in the space, the fragrance can be used to mask the bad odor attached to the clothing to obtain sufficient deodorization.

In the clothing pest control composition of the present invention, The blending ratio (a/b) of the fragrance component (a) and the insect control component (b) is preferably 0.1 to 2.0 in terms of weight ratio.

According to the clothing pest control composition of this constitution, since the blending ratio is in an appropriate range, it can fully exert the anti-insect function of the anti-insect component against clothing pests, and can give full play to the combination of the anti-insect component and the fragrance component. By taking advantage of the effect, it can maintain the deodorizing function of the fragrance ingredients for a long time.

The characteristic structure of the clothing deodorizing method of the present invention for solving the above-mentioned problems is: It is a clothing deodorization method using any one of the foregoing clothing pest control compositions, wherein: The carrier impregnated with the clothing pest control composition is placed in the storage space of the clothing, and the clothing pest control composition is volatilized from the carrier.

According to the clothing deodorization method of this structure, by volatilizing the clothing pest control composition of any one of the foregoing items in the storage space, the insect-proof function produced by the insect-proof component can be obtained, and the insect-proof component and the fragrance component can be obtained The synergistic effect of this product keeps the deodorizing function produced by the fragrance ingredients for a long time. Therefore, by implementing the clothing deodorizing method of the present invention, the deodorizing function generated by the fragrance component can be continuously maintained during storage, and the uncomfortable feeling when the clothing is taken out from the storage space is prevented.

The characteristic structure of the method for preventing insects and deodorizing clothing of the present invention for solving the above-mentioned problems is that: It is a method for preventing insects and deodorizing clothes by simultaneously performing insect-proof and deodorizing treatments on clothes, which includes: The storing step is to store the clothing material of the treatment object and the clothing pest control composition containing insect-proof components and fragrance ingredients together in the storage space; and The volatilization step is to volatilize the clothing pest control composition in the storage space, so as to provide the clothing with a sufficient insect repellent effect and deodorant effect.

According to the clothing pest control and deodorization method of the present composition, the clothing pest control composition containing the pest control component and the fragrance component is jointly stored in the storage space, and the clothing pest control composition is further stored in the storage space. Internal volatilization, to give sufficient insect repellent and deodorant effects to the clothing, and can give clothing both an insect repellent effect and a continuous deodorant effect with only one treatment. Moreover, the clothing material treated by the method for preventing insects and deodorizing clothing of the present invention, due to the synergistic effect of insect-resistant ingredients and fragrance ingredients, can maintain the deodorizing function of fragrance ingredients for a long time, for example, even all day long. When going out, annoying pests will not come close, and can move comfortably for a long time without caring about the smell.

The clothing pest control composition and the clothing deodorizing method of the present invention will be described below. However, the present invention is not intended to be limited to the configuration described in the embodiment described below.

＜Clothing pest control composition＞ The clothing pest control composition of the present invention contains: a fragrance component, which has a deodorizing function to remove bad odors attached to clothing; and a pest control component, which has a continuous function of maintaining the deodorizing function of the fragrance component in addition to the pest control function .

The insect control component, which is one of the main components of the clothing pest control composition of the present invention, uses a sustained function that has a deodorizing function that continuously maintains the fragrance component. Specifically, it can be exemplified by imidacin, profluthrin, p-menthane-3,8-diol, etc. The preferred insect-proof ingredient is imidacin and/or profluthrin. In addition, in the following description, an embodiment using the better insect-preventing ingredients of Ebenerin and Profluthrin is described. Yibining and profluthrin are pyrethroid insect-proof ingredients with room temperature volatility. For clothing pests such as clothing moths, bag-cloth moths, bonito, small bonito or silverfish, especially for The larvae of clothes moth or bag clothes moth have high control effect. In this way, Yibinin and perfluthrin have always been used as insect repellents; and the inventors of this case have newly discovered Yibinin after preparing various clothing pest control compositions containing Yibinin and perfluthrin. And profluthrin has a continuous function that continuously maintains the deodorizing function of the specific fragrance component described later. In the clothing pest control composition of the present invention, by arranging the carrier impregnated with the clothing pest control composition in the storage space of the clothing, the pest control component can be volatilized in the storage space to prevent and control clothing pests, while maintaining attachment to Removal of bad smell from clothes in storage. The content of the pest control component in the clothing pest control composition is preferably 10 to 80% by mass. If it is in this range, by placing the carrier impregnated with the clothing pest control composition in the storage space, the pest control effect on the clothing pest can be exerted, and the synergistic effect with the specific fragrance ingredients described later can be exerted, thereby enhancing Sustainability of deodorizing function. If the content of the anti-insect component is less than 10% by mass, the anti-insect effect on clothing pests or the deodorizing function due to the synergistic effect of the fragrance component may not be sufficient. When the content of the anti-insect component exceeds 80% by mass, the anti-insect component is blended in an amount that is practically necessary to obtain an anti-insect effect, which is economically disadvantageous.

The fragrance component, which is one of the main components of the clothing pest control composition of the present invention, uses an electronic conjugate part that does not have an electronic conjugate part derived from a benzene ring, a benzoate structure or a salicylate structure, and A compound with carbon number 6-18, molecular weight 98-270, carbon atom, hydrogen atom, and oxygen atom, and no sulfur atom, nitrogen atom, or halogen atom. This compound has an excellent deodorizing function that can mask the bad odors attached to clothing (sweat, middle-aged male body odor, elderly odor, smoke odor, and conditioning odor) by fragrance. The synergistic effect of Yibining and Profluthrin, which are used as insect control ingredients, can maintain its deodorizing function for a long time. As such compounds, the following formula (1) can be mentioned:

所示之順-3-己烯醇(下稱「化合物A」)、下述式(2)：

The shown cis-3-hexenol (hereinafter referred to as "Compound A"), the following formula (2):

所示之二氫香葉烯醇(下稱「化合物B」)、下述式(3)：

The dihydrogeranyl alcohol (hereinafter referred to as "compound B") shown in the following formula (3):

所示之乙基沉香醇(下稱「化合物C」)、下述式(4)：

The shown ethyl linalool (hereinafter referred to as "compound C"), the following formula (4):

所示之沉香醇(下稱「化合物D」)、下述式(5)：

The shown linalool (hereinafter referred to as "compound D"), the following formula (5):

所示之香葉醇(下稱「化合物E」)、下述式(6)：

The geraniol shown (hereinafter referred to as "compound E"), the following formula (6):

所示之四氫香葉醇(下稱「化合物F」)、下述式(7)：

The shown tetrahydrogeraniol (hereinafter referred to as "compound F"), the following formula (7):

所示之萜品醇(下稱「化合物G」)、下述式(8)：

The terpineol shown (hereinafter referred to as "compound G"), the following formula (8):

所示之苯乙醇(下稱「化合物H」)、下述式(9)：

The shown phenethyl alcohol (hereinafter referred to as "compound H"), the following formula (9):

所示之新洋茉莉醛(下稱「化合物I」)、下述式(10)：

Shown as Xinyang Jasminaldehyde (hereinafter referred to as "Compound I"), the following formula (10):

所示之鈴蘭醛(下稱「化合物J」)、下述式(11)：

The shown lily of the valley (hereinafter referred to as "compound J"), the following formula (11):

所示之苯甲酸苄酯(下稱「化合物K」)、下述式(12)：

The shown benzyl benzoate (hereinafter referred to as "compound K"), the following formula (12):

所示之水楊酸苄酯(下稱「化合物L」)、下述式(13)：

The shown benzyl salicylate (hereinafter referred to as "compound L"), the following formula (13):

所示之順-3-己烯基水楊酸酯(下稱「化合物M」)、下述式(14)：

The shown cis-3-hexenyl salicylate (hereinafter referred to as "compound M"), the following formula (14):

所示之二氫茉莉酸甲酯(下稱「化合物N」)、下述式(15)：

The shown methyl dihydrojasmonate (hereinafter referred to as "compound N"), the following formula (15):

所示之沉香基乙酸酯(下稱「化合物O」)、下述式(16)：

The shown agarinyl acetate (hereinafter referred to as "compound O"), the following formula (16):

所示之覆盆子酮(下稱「化合物P」)、下述式(17)：

The shown raspberry ketone (hereinafter referred to as "Compound P"), the following formula (17):

所示之佳樂麝香(下稱「化合物Q」)、下述式(18)：

The Jiale Musk (hereinafter referred to as "Compound Q") shown in the following formula (18):

所示之十三碳二酸乙二醇酯(下稱「化合物R」)、下述式(19)：

The shown glycol ester of tridecanedioic acid (hereinafter referred to as "compound R"), the following formula (19):

所示之十五碳內酯(下稱「化合物S」)等。

The 15-carbon lactone shown (hereinafter referred to as "compound S"), etc.

The above-mentioned compounds A to S can be used alone or in combination of multiple types. The content of the fragrance component is preferably 1 to 20% by mass. If the content of the fragrance component is in this range, for example, the carrier impregnated with the clothing pest control composition of the present invention is placed in the clothing storage space, or the clothing containing the clothing pest control composition of the present invention is directly sprayed When sprayed products such as aerosols volatilize the clothing pest control composition in the storage space, it can mask the bad odors of the clothing attached to the storage and obtain sufficient deodorizing properties. When the content of the fragrance component is less than 1% by mass, the deodorizing property when volatilizing the clothing pest control composition in the storage space may be insufficient. When the content of the fragrance component exceeds 20% by mass, the clothing pest control composition tends to become sticky.

In the clothing pest control composition of the present invention, the blending ratio (a/b) of the perfume component (a) and the insect control component (b) is preferably adjusted to 0.1-2.0 in terms of weight ratio. If the blending ratio (a/b) is in this range, the synergistic effect of the insect-proof component and the fragrance component can be increased, and the deodorizing function of the fragrance component can be maintained for a long time. When the blending ratio (a/b) is less than 0.1 and when the blending ratio (a/b) exceeds 2.0, the synergistic effect of the insect-proof component and the fragrance component may not be sufficiently exhibited.

In addition to the above-mentioned components, the clothing pest control composition of the present invention can also be suitably blended with antifungal agents, antibacterial agents, bactericides, antioxidants, etc. that target molds or fungi. Antifungal agents, antibacterial agents and fungicides include cypress alcohol, 2-mercaptobenzothiazole, 2-(4-thiazolyl)benzimidazole, 5-chloro-2-methyl-4-isothiazoline-3 -Ketone, Saifenin, 3-methyl-4-isopropylphenol, o-phenylphenol, etc.

The clothing pest control composition of the present invention blends the above-mentioned components at an appropriate weight ratio, and further adds a solvent to adjust the concentration of each component to an appropriate one. As the solvent, it is preferable to use normal alkane-based hydrocarbons, isoparaffin-based hydrocarbons, lower alcohols having 2 to 3 carbons, higher fatty acid esters having a total of 16 to 20 carbons, and the like.

＜Clothing pest control products＞ The preferred product form of the clothing pest control composition of the present invention is a clothing pest control product obtained by accommodating a solid carrier impregnated with the clothing pest control composition in a container such as a permeable shell. Examples of solid carriers include fibrous carriers (pulp, lint, rayon, etc.), beads and foams made of cellulose or regenerated cellulose, inorganic porous carriers (silicate, silica, zeolite, etc.), Sublimation carrier (trioxane, adamantane, etc.). When a fibrous carrier is used, it is preferably a cushion or sheet with a thickness of about 1 to 3 mm. In addition, as the product form of other clothing pest control compositions, spray products such as manual spray or aerosol can also be used. In particular, an aerosol product in which the clothing pest control composition of the present invention and a propellant are enclosed in an aerosol container with a quantitative injection valve is more convenient to use. As the propellant, liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen, carbon dioxide, nitric oxide, compressed air, etc. can be used.

＜How to deodorize clothing＞ A preferred aspect of the clothing deodorization method of the present invention is that the carrier impregnated with the clothing pest control composition of the present invention is arranged in the storage space of the clothing, and the clothing pest control composition is volatilized from the carrier. For example, impregnated with the above It is implemented as a solid carrier of clothing pest control products. In addition, another aspect of the clothing deodorization method of the present invention is to directly impart and volatilize the clothing pest control composition of the present invention to the storage space of the clothing, and it can be implemented using the above-mentioned aerosol product, for example. Specifically, when the clothing pest control product is a solid carrier, the solid carrier is installed in a closet or other clothing storage space. By making the clothing pest control composition of the present invention volatilize from the solid carrier provided in the storage space, the clothing in the storage can be provided with excellent insect control function and continuous deodorizing function. When the clothing pest control product is an aerosol product, the clothing pest control composition is sprayed directly into the storage space of the clothing such as a closet. After that, if the storage space is immediately closed, the clothing pest control composition will volatilize and spread throughout the storage space, which can provide excellent insect resistance and continuous deodorizing functions to the clothes in storage. In this way, according to the clothing deodorizing method of the present invention, clothing pests can be prevented in the storage space, and at the same time, the malodors of clothing attached to the storage can be removed.

＜Methods to prevent insects and deodorize clothing＞ The clothing pest control and deodorization method of the present invention executes: the storage step, which is to store the clothing material of the processing object and the clothing pest control composition containing the pest control component and the fragrance component in the storage space; and the volatilization step to make the clothing pests The anti-removal composition volatilizes in the storage space to impart sufficient insect repellent and deodorizing effects to the clothing. The basic steps (operations) of the clothing material deodorization method of the present invention are the same as the above-mentioned clothing material deodorization method. In the volatilization step, in order to impart sufficient insect control and deodorization effects to the clothing, for example, as long as the It is sufficient to volatilize the clothing pest control composition for more than one day in the state of the storage space. At this time, for example, by turning over the parts of the clothing that are particularly odorous (such as underarms, around the neck, around the feet, etc.) to expose them and carefully perform volatilization treatment, the clothing can be effectively protected at the same time. Insect effect and continuous deodorizing effect. In this way, as long as the method for preventing insects and deodorizing clothing materials of the present invention is implemented, only one treatment can impart insect-repellent effects and sustained deodorizing effects to clothing materials at the same time. Moreover, the clothing material treated by the method for preventing insects and deodorizing clothing of the present invention has the synergistic effect of the insect-preventing ingredient and the fragrance ingredient described later, since the deodorizing function produced by the fragrance ingredient can be continuously maintained for a long time, for example, even if one When going out all day, annoying pests will not come close, and you can move comfortably for a long time without caring about the smell.

The clothing pest control composition of the present invention can maintain the deodorizing function of the fragrance component for a long time by combining the specific fragrance component with the pest control component, and through the synergistic effect of the pest control component and the fragrance component. The duration of the deodorizing function depends on the combination of the insect-preventing component and the fragrance component, the blending ratio of the two components, the use conditions of the clothing pest-repellent composition, etc., and the deodorizing function can be fully maintained for about one day. Therefore, as long as the clothing deodorization method of the present invention implemented using the clothing pest control composition is used to make the clothing pest control composition volatilize in the storage space, for example, when the clothing is stored for about 24 hours, it can continue to maintain The deodorizing function of the clothing can prevent uncomfortable odors attached to the clothing when the clothing is taken out from the storage space. [Example]

In order to confirm the sustainability of the deodorizing function of the clothing pest control composition of the present invention, a clothing pest control composition (Examples 1 to 59) having the characteristic structure of the present invention was prepared, and the deodorizing function confirmation test was carried out. In addition, for comparison, a clothing pest control composition (Comparative Examples 1 to 56) that does not have the characteristic structure of the present invention was prepared, and the same deodorizing function confirmation test was performed. In addition, in Examples 1 to 59 and Comparative Examples 1 to 56, "g" is shown as the unit of weight, but it can be scaled up at any magnification. That is, the unit "g" can be changed to "parts by weight".

<Examples 1-21> The clothing pest control composition (Examples 1 to 21) was prepared according to the following formula 1 using Yibining as an insect control component. In the clothing pest control composition of Examples 1-19, compounds A to S were used as fragrance components. In the clothing pest control composition of Example 20, a blended fragrance (hereinafter referred to as "blended fragrance 1") obtained by mixing compounds B, H, L, N, and Q in equal amounts was used as a fragrance component. In the clothing pest control composition of Example 21, a blended perfume (hereinafter referred to as "blended perfume 2") obtained by mixing the compounds L, N, Q, β-turkone and cashmeran in equal amounts was used as Spice ingredients.

Recipe 1: 15 g (15% by mass) of perfume ingredients, 70 g (70% by mass) of Ebinin, and Deotomisol as the remaining components of the solvent (for balance) were mixed to prepare a total of 100 g. In the formulation 1, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 0.21 in terms of weight ratio.

<Examples 22~27> The clothing pest control composition (Examples 22 to 27) was prepared according to the following formula 2 using Ebinin as an insect control component. In the clothing pest control composition of Examples 22 to 27, compounds B, H, L, N, Q and the blended fragrance 1 were used as fragrance components.

Formulation 2: 15 g (15% by mass) of fragrance components, 30 g (30% by mass) of Ebinin, and Deotomisol as the remaining components of the solvent (for balance) were mixed to prepare a total of 100 g. In Formula 2, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 0.50 in terms of weight ratio.

＜Example 28~32＞ The clothing pest control composition (Examples 28 to 32) was prepared according to the following formula 3 using Yibining as the insect control component. In the clothing pest control composition of Examples 28 to 32, compounds B, H, L, N, and Q were used as fragrance components.

Recipe 3: 15 g (15% by mass) of fragrance ingredients, 15 g (15% by mass) of Ebinin, and Deotomisol as the remaining components of the solvent (for balance) were mixed to prepare a total of 100 g. In formula 3, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 1.00 in terms of weight ratio.

<Examples 33~53> The clothing pest control composition (Examples 33 to 53) was prepared according to the following formula 4 using profluthrin as an insect control component. In the clothing pest control composition of Examples 33 to 53, compounds A to S, blended fragrance 1 and blended fragrance 2 were used as fragrance components.

Recipe 4: 15 g (15% by mass) of fragrance ingredients, 35 g (35% by mass) of profluthrin, and Deotomisol as the remaining components of the solvent (for balance) were mixed to prepare a total of 100 g. In formula 4, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 0.43 in terms of weight ratio.

<Examples 54~59> The clothing pest control composition (Examples 54 to 59) was prepared according to the following formula 5 using profluthrin as an insect control component. In the clothing pest control composition of Examples 54 to 59, compounds B, H, L, N, Q and blended fragrance 1 were used as fragrance components.

Formula 5: 15 g (15% by mass) of fragrance ingredients, 15 g (15% by mass) of perfluthrin, and Deotomisol as the remaining components of the solvent (for balance) were mixed to prepare a total of 100 g. In formula 5, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 1.00 in terms of weight ratio.

＜Comparative Examples 1-21＞ The clothing pest control composition (Comparative Examples 1 to 21) was prepared according to the following formula 6 in which no insect control component was blended. In the clothing pest control composition of Comparative Examples 1 to 21, compounds A to S, blended fragrance 1 and blended fragrance 2 were used as fragrance components.

Formulation 6: 15 g (0.5% by mass) of fragrance ingredients and Deotomisol as the remaining components of the solvent (for balance) were mixed to prepare a total of 100 g.

<Comparative Example 22> The clothing pest control composition was prepared according to the following formula 7 using Ebinin as an insect-proof component (Comparative Example 22). In the clothing pest control composition of Comparative Example 22, fragrance components were not blended.

Formulation 7: Mix 70 g (70% by mass) of Ebinin and Deotomisol as the remaining component of the solvent (for balance) to prepare a total of 100 g. In Formula 7, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 0.00 in terms of weight ratio.

<Comparative Example 23> According to the following formula 8 using profluthrin as an insect control component, a clothing pest control composition (Comparative Example 23) was prepared. In the clothing pest control composition of Comparative Example 23, fragrance components were not blended.

Formulation 8: 35 g (35% by mass) of profluthrin and Deotomisol as the remainder of the solvent (for balance) were mixed to prepare a total of 100 g. In Formula 8, the blending ratio (a/b) of the fragrance component (a) and the insect-proof component (b) was 0.00 in terms of weight ratio.

＜Comparative Examples 24~34＞ According to the formula 1 using Yibining as the insect-preventing ingredient, the clothing pest control composition (Comparative Examples 24 to 34) was prepared. In the clothing pest control composition of Comparative Examples 24 to 34, a compound having an electronic conjugate part derived from a benzene ring, a benzoate structure, or a salicylate structure was used as a fragrance component. Specifically, in the clothing pest control composition of Comparative Example 24, the following formula (20) was used:

所示之香豆素(下稱「化合物C1」)作為香料成分。

The indicated coumarin (hereinafter referred to as "compound C1") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 25, the following formula (21) was used:

所示之β-紫羅蘭酮(下稱「化合物C2」)作為香料成分。

The shown β-ionone (hereinafter referred to as "compound C2") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 26, the following formula (22) was used:

所示之β-突厥酮(下稱「化合物C3」)作為香料成分。

The indicated β-turketone (hereinafter referred to as "compound C3") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 27, the following formula (23) was used:

所示之大馬仙酮(下稱「化合物C4」)作為香料成分。

The indicated damasinone (hereinafter referred to as "compound C4") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 28, the following formula (24) was used:

所示之檸檬醛(下稱「化合物C5」)作為香料成分。

Citral (hereinafter referred to as "compound C5") shown as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 29, the following formula (25) was used:

所示之肉桂醛(下稱「化合物C6」)作為香料成分。

The cinnamaldehyde shown (hereinafter referred to as "compound C6") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 30, the following formula (26) was used:

所示之乙基-2-甲基-6-戊基-4-氧基-2-環己烯羧酸酯(Calixole)(下稱「化合物C7」)作為香料成分。

The indicated ethyl-2-methyl-6-pentyl-4-oxy-2-cyclohexene carboxylate (Calixole) (hereinafter referred to as "compound C7") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 31, the following formula (27) was used:

所示之開司米木麝香(下稱「化合物C8」)作為香料成分。

The cashmere musk (hereinafter referred to as "compound C8") shown as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 32, the following formula (28) was used:

所示之麥芽酚(下稱「化合物C9」)作為香料成分。

The indicated maltol (hereinafter referred to as "compound C9") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 33, the following formula (29) was used:

所示之香芹酮(下稱「化合物C10」)作為香料成分。

The indicated carvone (hereinafter referred to as "compound C10") is used as a fragrance ingredient.

In the clothing pest control composition of Comparative Example 34, the following formula (30) was used:

所示之法呢烯(下稱「化合物C11」)作為香料成分。

The farnesene shown (hereinafter referred to as "compound C11") is used as a fragrance ingredient.

＜Comparative Examples 35~45＞ According to formula 4 using profluthrin as an insect-preventing component, a clothing pest control composition (Comparative Examples 35 to 45) was prepared. In the clothing pest control composition of Comparative Examples 35 to 45, compounds C1 to C11 having electronic conjugate parts other than those derived from benzene ring, benzoate structure or salicylate structure were used as fragrances ingredient.

＜Comparative Examples 46~56＞ According to the formula 6 which did not mix the insect-proof component, the clothing insect pest control composition (Comparative Examples 46 to 56) was prepared. In the clothing pest control composition of Comparative Examples 46 to 56, compounds C1 to C11 having electronic conjugated parts other than those derived from benzene ring, benzoate structure or salicylate structure were used as fragrances ingredient.

The formulations and fragrance components of the clothing pest control compositions of Examples 1 to 59 and Comparative Examples 1 to 56 are shown in Tables 1 and 2.

[Deodorization function confirmation test] We are here to carry out tests to confirm the deodorizing function of sweat odor, body odor of middle-aged men, elderly odor, smoke odor, and conditioning odor. As the test sample, 15 mg of the test solutions of Examples 1 to 59 and Comparative Examples 1 to 56 were used. For sweat odor, an appropriate amount of ethanol solution of ammonia water (manufactured by Nacalai Tesque Co., Ltd.) was sprayed on a test filter paper with a diameter of 9 cm in a spray glass bottle and used as a odor treatment sample. For the body odor of middle-aged men, a test filter paper with a diameter of 9 cm was sprayed with an ethanol solution of polyacetal (manufactured by Nacalai Tesque Co., Ltd.) in a spray glass bottle and used as a malodor treatment sample. For the odor of the elderly, an appropriate amount of 2-nonenal (manufactured by Tokyo Chemical Industry Co., Ltd.) ethanol solution was sprayed on a test filter paper with a diameter of 9 cm in a spray glass bottle as a malodor treatment sample. Regarding the odor of smoke, a test filter paper with a diameter of 9 cm was exposed to cigarette smoke in a closed small space and treated as a malodor treatment sample. Regarding odor conditioning, the tallow is burned in a small confined space, and a test filter paper with a diameter of 9 cm is exposed to the smoke and treated as a odor treatment sample.

In the deodorization function confirmation test, the malodorous treatment sample was suspended in a stainless steel cylinder with a capacity of 13.5L. One hour after the malodorous treatment sample was installed, the malodorous treatment sample was arranged and the test sample was suspended. After 1 hour and 24 hours after setting the test sample, the odor in the stainless steel cylinder was evaluated. The evaluation of odor is based on the following five-level odor intensity representation method, and 5 testers are invited to evaluate and obtain the average score. Those with an average score of 0 or more and less than 2 are rated as ○, those with 2 or more and less than 3 are rated as △, and those with 3 or more and 4 or less are rated as x. 0: No fragrance 1: Smell very weakly 2: Smell faintly 3: Obviously smell 4: Strong smell

Tables 3 to 5 show the results of the confirmation test for the deodorizing function of sweat.

Tables 6 to 8 show the results of the deodorizing function confirmation test on the body odor of middle-aged men.

The results of the deodorizing function confirmation test for the elderly odor are shown in Tables 9-11.

Tables 12-14 show the results of the deodorizing function confirmation test for smoke odor.

Tables 15-17 show the results of the deodorizing function confirmation test for the conditioning odor.

As a result of the deodorant function confirmation test, the clothing pest control composition with the characteristic structure of the present invention, Examples 1 to 32 containing Ebiphene as the insect repellent ingredient and Examples 33 to containing perfluthrin as the insect repellent ingredient 59. For sweat odor, middle-aged male body odor, elderly odor, cigarette odor, and conditioning odor, it showed excellent deodorization after setting the test sample to 24 hours. From this study, it was determined that by volatilizing the clothing pest control composition with the characteristics of the present invention in the storage space, the deodorizing function of the clothing in the storage can be maintained for about 24 hours, and the clothing can be prevented from being taken out of the storage space. The stench attached to clothing at times causes discomfort.

On the other hand, the clothing pest control compositions of Comparative Examples 1 to 21 that did not contain insect repellent ingredients were compared with Examples 1 to 32 that contained Ebenin as the insect repellent ingredient, and implementations containing perfluthrin as the insect repellent ingredient Examples 33 to 59 contain the same perfume ingredients, but for sweat, middle-aged male body odor, elderly odor, cigarette odor and conditioning odor, the odor can still be smelled after setting the test sample to 1 hour. The sample did not show deodorization after 24 hours.

The clothing pest control composition system of Comparative Example 22 contains Yibining as an insect-preventing component in the same way as Examples 1 to 32, and the clothing pest control composition system of Comparative Example 23 contains profluthrin in the same manner as Examples 33 to 59 Ester was used as an insect-proof ingredient, but Comparative Examples 22 and 23 did not contain a fragrance ingredient. The clothing pest control compositions of Comparative Examples 22 and 23 showed no deodorizing properties against sweat odor, middle-aged male body odor, elderly odor, smoke odor, and conditioning odor. From this, it was confirmed that the insect-preventing ingredients Ebenin and Profluthrin did not have deodorizing properties. Although Yibining and profluthrin, which are insect-proof ingredients alone, do not have deodorizing properties, compared with the clothing pest control composition of Comparative Examples 1 to 21, only these insect-proof ingredients are mixed in the implementation The reason why the clothing pest control composition of Examples 1 to 59 can maintain the deodorizing function for a long time is judged because the insect control component and the specific fragrance component specified in the present invention exert some synergistic effects.

In addition, Comparative Examples 24 to 56 using compounds having electronic conjugated parts other than those derived from benzene ring, benzoate structure or salicylate structure as perfume ingredients, for sweaty, middle-aged men Body odor, old man odor, smoke odor and conditioning odor can still be smelled after setting the test sample for 1 hour, and it does not show deodorization after setting the test sample for 24 hours. When it contains Yibining as an insect-proof ingredient (Comparative Examples 24-34) and when it contains Profluthrin as an insect-proof ingredient (Comparative Examples 35-45), the reason why the deodorant function cannot be maintained for a long time is determined. The specific fragrance component specified in the present invention is not used, and the synergistic effect of the insect-proof component and the fragrance component cannot be obtained.

From the above results, it is confirmed that the clothing pest control composition (Examples 1 to 59) having the characteristics of the present invention can be obtained by combining specific insect repellent ingredients and specific fragrance ingredients. It has a synergistic effect and maintains the deodorizing function of the fragrance ingredients for a long time. [Industrial availability]

The clothing pest control composition and the clothing deodorizing method of the present invention are used to remove bad odors attached to clothing and can be used for deodorizing fiber products. Furthermore, the insect-proof and deodorant method for clothing of the present invention can be used to prevent insects and deodorize fiber products.

Claims (7)

A clothing pest control composition, which contains pest control components and fragrance components, wherein: The aforementioned fragrance ingredient has a deodorizing function to remove bad odors attached to clothing, The anti-insect ingredient has a continuous function of continuously maintaining the deodorizing function of the fragrance ingredient. For example, the clothing pest control composition of claim 1, wherein the aforementioned insect-preventing ingredients are Yibining and/or profluthrin, The aforementioned fragrance ingredients do not have electronic conjugate parts other than those derived from benzene ring, benzoate structure or salicylate structure, carbon number is 6-18, molecular weight is 98-270, and it has carbon atoms , Hydrogen atom and oxygen atom, without sulfur atom, nitrogen atom and halogen atom compound. For example, the clothing pest control composition of claim 1 or 2, wherein the aforementioned fragrance ingredients are selected from the group consisting of cis-3-hexenol, dihydrogeranol, ethyl linalool, linalool, geraniol, and tetrahydrogen Leaf alcohol, terpineol, phenethyl alcohol, new jasmonal, lily of the valley, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicylate, methyl dihydrojasmonate, agarwood At least one of the group consisting of acetate, raspberry ketone, carol musk, ethylene glycol tridecanedioate, and pentadecanolide. Such as the clothing pest control composition of claim 1 or 2, wherein the content of the aforementioned fragrance ingredient is 1-20% by mass. Such as the clothing pest control composition of claim 1 or 2, wherein the blending ratio (a/b) of the aforementioned fragrance ingredient (a) and the aforementioned insect-proof ingredient (b) is 0.1 to 2.0 by weight. A method for deodorizing clothing, which uses the clothing pest control composition according to any one of Claims 1 to 5, wherein: The carrier impregnated with the clothing pest control composition is placed in the storage space of the clothing, and the clothing pest control composition is volatilized from the carrier. An anti-insect and deodorant method for clothing, which is to simultaneously perform anti-insect treatment and deodorization treatment on clothing, which includes: The storing step is to store the clothing material of the treatment object and the clothing pest control composition containing insect-proof components and fragrance ingredients together in the storage space; and The volatilization step is to volatilize the clothing pest control composition in the storage space, so as to provide the clothing with a sufficient insect repellent effect and deodorant effect.