WO2020095809A1 - Clothing pest control composition, and method for deodorizing clothing and method for preventing pests in and deodorizing clothing using said composition - Google Patents

Clothing pest control composition, and method for deodorizing clothing and method for preventing pests in and deodorizing clothing using said composition Download PDF

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Publication number
WO2020095809A1
WO2020095809A1 PCT/JP2019/042763 JP2019042763W WO2020095809A1 WO 2020095809 A1 WO2020095809 A1 WO 2020095809A1 JP 2019042763 W JP2019042763 W JP 2019042763W WO 2020095809 A1 WO2020095809 A1 WO 2020095809A1
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Prior art keywords
clothing
pest control
control composition
component
deodorizing
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PCT/JP2019/042763
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French (fr)
Japanese (ja)
Inventor
友裕 田丸
鹿島　誠一
中山　幸治
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大日本除蟲菊株式会社
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Application filed by 大日本除蟲菊株式会社 filed Critical 大日本除蟲菊株式会社
Priority to JP2020556017A priority Critical patent/JP7109578B2/en
Publication of WO2020095809A1 publication Critical patent/WO2020095809A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/12—Apparatus, e.g. holders, therefor

Definitions

  • the present invention relates to a clothing pest control composition containing an insect repellent component and a fragrance component, and a method for deodorizing clothing using the composition. Furthermore, the present invention relates to a method for preventing and removing clothing insects by simultaneously performing insect repellent treatment and deodorant treatment on clothing.
  • the clothing pest control product of Patent Document 1 is one in which a fragrance component such as an acetic acid ester compound and an allyl ester compound is held in a water-absorbent polymer, and by maintaining volatility of the active ingredient for a long period of time, In the storage space such as the drawer, the closet, and the clothing storage box, the larva of the clothing pest can be killed, and an excellent feeding-inhibiting effect can be exhibited.
  • a fragrance component such as an acetic acid ester compound and an allyl ester compound
  • Clothes may have a daily odor such as sweat odor, aging odor, cigarette odor, etc. while wearing. Therefore, in the management of clothing, in addition to controlling the harmful insects of clothing, it is desired to eliminate the bad odor attached to the clothing. For example, since outer garments are often used every day, the living odor attached to clothes on the previous day may cause discomfort when taken out from the storage space such as a closet. It is desirable to be able to smell.
  • the clothing pest control product of Patent Document 1 is expected to have a deodorant function by using a fragrance component as an active ingredient, but a compound serving as a fragrance component has been selected with a focus on the insect control function against clothing pests, and is peculiar to clothing. There is room for consideration regarding the deodorizing function for bad odors.
  • the present invention has been made in view of the above problems, and a clothing pest control composition capable of deodorizing a malodor that adheres to clothes while performing an insect repellent function, and a clothing deodorant using the composition.
  • the purpose is to provide a method.
  • a further object of the present invention is to provide a method for controlling insect deodorant of clothing, which is capable of imparting insect control effect and continuous deodorant effect to clothing at one time.
  • a clothing pest control composition comprising an insect repellent component and a fragrance component,
  • the fragrance component has a deodorizing function of deodorizing a bad odor attached to clothing,
  • the insect repellent component has a sustaining function of sustaining the deodorizing function of the fragrance component.
  • the clothing pest control composition of the present configuration while preparing various clothing pest control composition and repeat various tests, a specific insect control component is a continuous function to maintain the deodorant function of the fragrance component. It was completed by newly discovering that it has.
  • the fragrance component has a deodorant function of deodorizing the bad odor attached to the garment
  • the insect repellent component has a continuous function of continuing the deodorant function of the fragrance component
  • the insect repellent component has an insect repellent function against clothing pests
  • the deodorant function of the fragrance component can be maintained for a long period of time to continuously eliminate the bad odor attached to the clothing. Therefore, by treating the clothing pest control composition of the present invention in the storage space of clothes, the deodorizing function of the fragrance component is maintained during storage, and discomfort occurs when the clothes are taken out from the storage space. Can be prevented.
  • the insect repellent component is empentrin, and / or profluthrin
  • the fragrance component does not have an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. It is preferable that the compound has a carbon atom, a hydrogen atom, and an oxygen atom and does not have a sulfur atom, a nitrogen atom, and a halogen atom.
  • the clothing pest control composition of the present configuration by combining the specific insect repellent component and the fragrance component, by the synergistic effect of the insect repellent component and the fragrance component, the deodorant function of the fragrance component is maintained for a long time.
  • the perfume ingredients are cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lilial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicyt. It is preferably at least one selected from the group consisting of rate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brushlate, and cyclopentadecanolide.
  • the clothing pest control composition of this constitution by containing the above-mentioned fragrance component, the synergistic effect of the mosquito repellent component and the fragrance component becomes large, and the sustainability of the deodorant function can be improved.
  • the content of the fragrance component is preferably 1 to 20% by mass.
  • the content of the fragrance component is in an appropriate range, for example, a carrier impregnated with the clothing pest control composition is installed in the storage space of clothes, and the storage space is placed in the storage space.
  • the clothes pest control composition is volatilized, the bad smell attached to the clothes can be masked by the aroma, and sufficient deodorant properties can be obtained.
  • the compounding ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is preferably 0.1 to 2.0 as a weight ratio.
  • the compounding ratio is in an appropriate range, while fully exerting the insect repellent function of the insect repellent component against clothing pests, a sufficient synergistic effect between the insect repellent component and the fragrance component is exerted. Therefore, the deodorizing function of the fragrance component can be maintained for a long period of time.
  • the characteristic configuration of the clothing deodorizing method according to the present invention for solving the above-mentioned problems A method for deodorizing clothing using the clothing pest control composition according to any one of the above, A carrier impregnated with the clothing pest control composition is placed in a clothing storage space, and the clothing pest control composition is volatilized from the carrier.
  • the clothing deodorizing method of the present configuration by volatilizing the clothing pest control composition according to any one of the above in the storage space, it is possible to obtain an insect repellent function by an insect repellent component, and an insect repellent component and a fragrance component. Due to the synergistic effect with, the deodorizing function of the fragrance component lasts for a long time. Therefore, by carrying out the clothing deodorizing method of the present invention, it is possible to prevent the deodorizing function of the fragrance component from being maintained during storage and prevent discomfort when taking out the clothing from the storage space.
  • the characteristic configuration of the clothing insect repellent method according to the present invention for solving the above-mentioned problems, A method of deodorizing clothing by performing insect repellent treatment and deodorant treatment on clothing at the same time, A storage step of storing the clothing to be treated in the storage space together with a clothing pest control composition containing an insect repellent component and a fragrance component, A volatilization step of volatilizing the clothing pest control composition in the storage space so that the clothing is provided with a sufficient insect-controlling effect and deodorizing effect, To include.
  • the clothing to be treated is stored in the storage space together with the clothing pest control composition containing the insect repellent component and the fragrance component, and further, the clothing has a sufficient insect repellent effect and deodorant.
  • the clothing pest control composition By volatilizing the clothing pest control composition in the storage space so that the effect is imparted, it is possible to impart the insect control effect and the persistent deodorizing effect to the clothing at the same time by a single treatment.
  • the clothing treated by the clothing insect repellent deodorizing method of the present invention the synergistic effect of the insect repellent component and the perfume component, the deodorant function of the perfume component is maintained for a long time, for example, like going out all day. Even in such a case, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
  • the clothing pest control composition of the present invention comprises a perfume component having a deodorant function of deodorizing a bad odor attached to clothing, and an insect repellent component having a persistent function of continuing the deodorant function of the perfume component in addition to the insect repellent function. contains.
  • insect repellent component which is one of the main components of the clothing pest control composition of the present invention
  • one having a sustaining function of sustaining the deodorizing function of the fragrance component is used.
  • Specific examples thereof include enpentrin, profluthrin, p-menthane-3,8-diol, and the like
  • the preferred insect repellent component is enpentrin and / or profluthrin.
  • empentryn and profluthrin which are preferable insect repellent components, will be described.
  • Empentrin and profluthrin are pyrethroid insect repellents that have volatility at room temperature, and are highly controllable against larvae of clothes worms, koga, beetle simian beetle, beetle simian beetle and spots, especially mosquito or larvae of carp. Have an effect.
  • empentrin and profluthrin have been conventionally used as insect repellents, the present inventors have prepared various kinds of clothing pest control compositions containing empentrin and profluthrin, and thus, It has been newly found that profluthrin has a sustaining function of sustaining the deodorizing function of a specific fragrance component described later.
  • the clothing pest control composition of the present invention by installing a carrier impregnated with the clothing pest control composition in the storage space of the clothing, while controlling the clothing pests by volatilizing the insect control component in the storage space, the storage. It is possible to maintain the deodorization of the bad odor attached to the clothes inside for a long period of time.
  • the content of the insect control component in the clothing pest control composition is preferably 10 to 80% by mass. Within such a range, by placing the carrier impregnated with the clothing pest control composition in the storage space, while exhibiting an insect-repellent effect against clothing pests, a synergistic effect with a specific fragrance component described later is obtained. It is possible to improve the durability of the deodorant function.
  • the content of the insect repellent component is less than 10% by mass, the insect repellent effect against clothing pests and the deodorant function due to the synergistic effect with the fragrance component may be insufficient in sustainability.
  • the content of the insect repellent component exceeds 80% by mass, the insect repellent component is blended in an amount exceeding the amount required to obtain the insect repellent effect required for practical use, which is economically disadvantageous.
  • a benzene ring, a benzoic acid ester structure, or an electron conjugated part other than an electron conjugated part derived from a salicylic acid ester structure is not contained, and carbon A compound having a number of 6 to 18, a molecular weight of 98 to 270, a carbon atom, a hydrogen atom, and an oxygen atom and no sulfur atom, nitrogen atom, or halogen atom is used.
  • Such a compound has an excellent deodorizing function of masking an offensive odor (sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor) attached to clothes with an aroma, and also serves as an insect repellent component in the present invention.
  • the deodorant function can be maintained for a long time due to the synergistic effect with the used empentorin and profluthrin.
  • Cis-3-hexenol represented by the following formula (hereinafter referred to as “compound A”), the following formula (2):
  • Ethyl linalool represented by the following formula (hereinafter referred to as “compound C”), the following formula (4):
  • Linalool represented by the following formula (hereinafter referred to as “compound D”), the following formula (5):
  • Geraniol represented by the following formula (hereinafter referred to as “compound E”), the following formula (6):
  • Compound K Benzyl benzoate represented by the following (hereinafter referred to as "Compound K”), the following formula (12):
  • Cis-3-hexenyl salicylate represented by the following (hereinafter referred to as “compound M”), the following formula (14):
  • a raspberry ketone (hereinafter, referred to as “compound P”) represented by the following formula (17):
  • a galaxolide represented by the following (hereinafter referred to as "compound Q"), the following formula (18):
  • compound S cyclopentadecanolide
  • the above compounds A to S may be used alone or in combination of two or more.
  • the content of the fragrance component is preferably 1 to 20% by mass.
  • a carrier impregnated with the clothing pest control composition of the present invention is installed in a storage space of clothes, or an aerosol containing the clothing pest control composition of the present invention is provided.
  • spraying sprayed products such as the above directly into the clothing storage space and volatilizing the clothing pest control composition in the storage space, masks the bad odor adhering to the clothing being stored and provides sufficient deodorant properties. Obtainable.
  • the deodorant property may be insufficient when the clothing pest control composition is volatilized in the storage space.
  • the content of the fragrance component exceeds 20% by mass, the clothing pest control composition tends to be sticky.
  • the compounding ratio (a / b) of the fragrance component (a) and the insect control component (b) is preferably adjusted to a weight ratio of 0.1 to 2.0.
  • the compounding ratio (a / b) is in such a range, the synergistic effect of the insect repellent component and the fragrance component becomes large, and the deodorizing function of the fragrance component continues for a long period of time.
  • the compounding ratio (a / b) is less than 0.1 and when the compounding ratio (a / b) exceeds 2.0, the synergistic effect of the insect repellent component and the fragrance component may not be sufficiently exhibited. There is.
  • the clothing pest control composition of the present invention may appropriately contain, in addition to the above components, a fungicide, an antibacterial agent, a bactericidal agent, an antioxidant, etc. for molds and fungi.
  • Antifungal agents, antibacterial agents, and bactericides include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolyl) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, triphorin, and 3 -Methyl-4-isopropylphenol, ortho-phenylphenol and the like can be mentioned.
  • the clothing pest control composition of the present invention is prepared by mixing the above-mentioned components in an appropriate weight ratio and further adding a solvent so that the concentration of each component is appropriate.
  • a solvent it is preferable to use normal paraffin hydrocarbon, isoparaffin hydrocarbon, lower alcohol having 2 to 3 carbon atoms, higher fatty acid ester having 16 to 20 carbon atoms, or the like.
  • a preferred product form of the clothing pest control composition of the present invention is a clothing pest control product in which a solid carrier impregnated with the clothing pest control composition is contained in a container such as a breathable case.
  • a solid carrier such as a breathable case.
  • a fibrous carrier pulp, linter, rayon, etc.
  • beads or foam made of cellulose or recycled cellulose inorganic porous carrier (silicate, silica, zeolite, etc.), sublimable carrier (trioxane, adamantane, etc.). Etc.) can be mentioned.
  • a fibrous carrier a mat-like or sheet-like one having a thickness of about 1 to 3 mm is preferable.
  • a spray product such as a hand spray or an aerosol
  • the aerosol product in which the clothing pest control composition of the present invention and the propellant are enclosed in an aerosol container equipped with a metering valve is convenient.
  • the propellant liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air or the like can be used.
  • Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air and the like can be mentioned.
  • Liquefied petroleum gas LPG
  • dimethyl ether DME
  • nitrogen gas carbon dioxide gas, nitrous oxide, compressed air and the like
  • Liquefied petroleum gas LPG
  • dimethyl ether DME
  • nitrogen gas carbon dioxide gas, nitrous oxide, compressed air and the like
  • a preferred embodiment of the clothing deodorizing method of the present invention is to install a carrier impregnated with the clothing pest control composition of the present invention in the storage space of the clothing, and volatilize the clothing pest control composition from the carrier, for example, It can be carried out using a solid carrier impregnated with the above-mentioned clothing pest control product.
  • Another aspect of the clothing deodorizing method of the present invention is to directly apply the clothing pest control composition of the present invention to the storage space of the clothing and volatilize it, and for example, it is carried out using the above-mentioned aerosol product. be able to.
  • the clothing pest control product when the clothing pest control product is a solid carrier, the solid carrier is installed in a clothing storage space such as a closet.
  • the clothes in storage are provided with an excellent insect control function and a continuous deodorizing function.
  • the clothing pest control product is an aerosol product, the clothing pest control composition is directly sprayed into the storage space for clothes such as a closet. Then, when the storage space is immediately closed, the pesticidal composition for clothing is volatilized and filled in the storage space, and the clothes in storage are provided with an excellent insect control function and a continuous deodorizing function.
  • the clothing deodorizing method of the present invention it is possible to deodorize the bad odor attached to the clothing being stored while controlling the clothing harmful insects in the storage space.
  • the clothing insect repellent method of the present invention includes a storage step of storing the clothing to be treated together with the clothing pest control composition containing an insect repellent component and a fragrance component in the storage space, and a sufficient insect repellent and deodorant effect on the clothing. And a volatilization step of volatilizing the clothing pest control composition in the storage space.
  • the clothing insect deodorizing method of the present invention has the same basic steps (operations) as those of the clothing deodorizing method described above, but in the volatilization step, the clothing is provided with a sufficient insect controlling effect and deodorizing effect.
  • the clothing pest control composition may be volatilized for one day or more with the storage space closed.
  • the clothing treated by the clothing insect deodorant method of the present invention has a synergistic effect of an insect repellent component and a fragrance component, which will be described later, because the deodorant function of the fragrance component continues for a long period of time, for example, going out all day. Even in such a case, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
  • the clothing pest control composition according to the present invention by combining the insect repellent component with a specific perfume ingredient, the synergistic effect of the insect repellent ingredient and the perfume ingredient allows the deodorant function of the perfume ingredient to be maintained for a long period of time. ..
  • the duration of the deodorant function varies depending on the combination of the insect repellent component and the fragrance component, the mixing ratio of both components, the use conditions of the clothing pest control composition, etc., but it is sufficient to maintain the deodorant function for about one day. Is possible. Therefore, if the clothing pest control composition is volatilized in the storage space according to the clothing deodorizing method of the present invention which is carried out using this clothing pest control composition, for example, when storing clothes for about 24 hours. The deodorizing function of the stored clothes is maintained, and it is possible to prevent discomfort from being caused by a bad smell attached to the clothes when the clothes are taken out from the storage space.
  • a clothing pest control composition (Examples 1 to 59) having the characteristic constitution of the present invention was prepared, and a deodorant function confirmation test was conducted. Was carried out.
  • clothing pest control compositions (Comparative Examples 1 to 56) not having the characteristic constitution of the present invention were prepared, and the same deodorant function confirmation test was carried out.
  • “g” is shown as a unit of weight, but it is possible to scale up at any magnification. That is, the unit “g” can be read as “part by weight”.
  • Examples 1 to 21 Compositions for controlling insect pests of clothing (Examples 1 to 21) were prepared according to the following Formulation 1 using Empentrin as an insect repellent component.
  • Compounds A to S were used as perfume ingredients in the clothing pest control compositions of Examples 1 to 19.
  • a mixed fragrance hereinafter, referred to as “prepared fragrance 1” in which equal amounts of the compounds B, H, L, N, and Q were mixed was used as a fragrance component.
  • a compounded fragrance hereinafter, referred to as “prepared fragrance 2” in which equal amounts of the compounds L, N, Q, ⁇ -damascon, and cashmere were mixed was used as a fragrance component. did.
  • Prescription 1 A total of 100 g was prepared by mixing 15 g (15% by mass) of the fragrance component, 70 g (70% by mass) of empentrin, and the balance (balance) of deotomisole as a solvent.
  • the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.21 as a weight ratio.
  • Examples 22 to 27 Compositions for controlling insect pests of clothing (Examples 22 to 27) were prepared according to the following Formulation 2 using Empentrin as an insect repellent component. In the clothing pest control compositions of Examples 22 to 27, Compounds B, H, L, N, Q and Formulated Fragrance 1 were used as the perfume ingredients.
  • Prescription 2 A total of 100 g was prepared by mixing 15 g (15% by mass) of the fragrance component, 30 g (30% by mass) of empentrine, and the balance (balance) of deotomizole as a solvent.
  • the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.50 as a weight ratio.
  • Clothing pest control compositions (Examples 28 to 32) were prepared according to the following Formulation 3 using Empentrin as an insect control component.
  • compounds B, H, L, N, and Q were used as perfume ingredients.
  • Prescription 3 A total of 100 g was prepared by mixing 15 g (15% by mass) of the fragrance component, 15 g (15% by mass) of empentrin, and the balance (balance) of deotomizole as a solvent.
  • the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 1.00 as a weight ratio.
  • Clothing pest control compositions (Examples 33 to 53) were prepared according to the following formulation 4 using profluthrin as an insect control component.
  • Compounds A to S, Formulated Perfume 1 and Formulated Perfume 2 were used as perfume ingredients.
  • Prescription 4 15 g (15% by mass) of the fragrance component, 35 g (35% by mass) of profluthrin, and the balance (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g.
  • the compounding ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.43 as a weight ratio.
  • Examples 54 to 59 Compositions for controlling insect pests of clothing (Examples 54 to 59) were prepared according to the following formulation 5 using profluthrin as an insect repellent component.
  • Compounds B, H, L, N and Q, and the prepared perfume 1 were used as perfume ingredients.
  • Prescription 5 15 g (15% by mass) of the fragrance component, 15 g (15% by mass) of profluthrin and the balance (balance) of deotomizole as a solvent were mixed to prepare a total amount of 100 g.
  • the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 1.00 as a weight ratio.
  • Compositions for controlling insect pests for clothing were prepared according to the following formulation 6 containing no insect repellent.
  • Compositions of Comparative Examples 1 to 21 compounds A to S, blended flavor 1 and blended flavor 2 were used as flavor components.
  • Prescription 6 15 g (0.5% by mass) of the fragrance component and the balance (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g.
  • a clothing pest control composition (Comparative Example 22) was prepared according to the following formulation 7 using empentryn as an insect control component.
  • the clothing pest control composition of Comparative Example 22 does not contain a fragrance component.
  • Prescription 7 70 g (70% by mass) of empentryn and deotomisole as a solvent were mixed in the balance (balance) to prepare a total amount of 100 g.
  • the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.00 as a weight ratio.
  • a clothing pest control composition (Comparative Example 23) was prepared according to the following formulation 8 using profluthrin as an insect control component.
  • the clothing pest control composition of Comparative Example 23 did not contain a fragrance component.
  • Prescription 8 35 g (35% by mass) of profluthrin and the balance (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g.
  • the compounding ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.00 as a weight ratio.
  • Composition 1 for controlling clothing pests was prepared according to Formulation 1 using Empentrin as an insect repellent component.
  • compounds having an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure were used as a perfume component.
  • the clothing pest control composition of Comparative Example 24 the following formula (20):
  • compound C2 ⁇ -ionone represented by (hereinafter, referred to as “compound C2”) was used as a perfume ingredient.
  • ⁇ -Damascone represented by (hereinafter referred to as “compound C3”) was used as a perfume ingredient.
  • Damasenone represented by the formula (hereinafter referred to as "compound C4") was used as a perfume ingredient.
  • Citral represented by (hereinafter, referred to as "compound C5") was used as a perfume ingredient.
  • the cinnamaldehyde represented by (hereinafter, referred to as "compound C6") was used as a perfume ingredient.
  • the calixol represented by (hereinafter referred to as "compound C7") was used as a perfume ingredient.
  • the cashew melanin (hereinafter, referred to as "compound C8") was used as a perfume ingredient.
  • Carvone represented by (hereinafter referred to as "compound C10") was used as a perfume ingredient.
  • Composition 6 for controlling clothing pests was prepared according to Formulation 6 containing no insect control component.
  • Composition 6 containing no insect control component In the clothing pest control compositions of Comparative Examples 46 to 56, compounds C1 to C11 having an electron conjugated portion other than the electron conjugated portion derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients.
  • Tables 1 and 2 show the formulations of the clothing pest control compositions of Examples 1 to 59 and Comparative Examples 1 to 56, and the fragrance components.
  • Deodorant function confirmation test A deodorant function confirmation test for sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor was conducted. As a test piece, the test solution of Examples 1 to 59 and Comparative Examples 1 to 56 dispensed in an amount of 15 mg was used. Regarding the sweat odor, a test filter paper having a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of ammonia water (manufactured by Nacalai Tesque, Inc.) in a spray vial to obtain a malodor treated sample.
  • an ethanol solution of ammonia water manufactured by Nacalai Tesque, Inc.
  • a test filter paper having a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of diacetyl (manufactured by Nacalai Tesque, Inc.) with a spray vial to obtain a malodor treated sample.
  • a test filter paper having a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of 2-nonenal (manufactured by Tokyo Kasei Kogyo Co., Ltd.) with a spray vial to obtain a malodor-treated sample.
  • a sample obtained by exposing tobacco smoke to a test filter paper having a diameter of 9 cm in a small enclosed space was used as a malodor-treated sample.
  • a test filter paper having a diameter of 9 cm in a small enclosed space was used as a malodor-treated sample.
  • beef tallow was burned in a small enclosed space, and the smoke was exposed to a test filter paper having a diameter of 9 cm to obtain a malodor-treated sample.
  • the malodor-treated sample was suspended in a stainless steel cylinder having a capacity of 13.5 L, and one hour after the malodor-treated sample was installed, the test sample was suspended in parallel with the malodor-treated sample.
  • the odor inside the stainless steel was evaluated 1 hour and 24 hours after the installation of the specimen.
  • the odor was evaluated by five testers according to the following five-level odor intensity display method, and the average score was obtained.
  • the average score of 0 or more and less than 2 was evaluated as ⁇ , 2 or more and less than 3 as ⁇ , and 3 or more and 4 or less as x. 0: Do not feel scent 1: Feel slightly 2: Feel weak 3: Feel clearly 4: Feel strongly
  • Tables 6 to 8 show the results of the deodorant function confirmation test for middle fat odor.
  • Tables 9 to 11 show the results of the deodorant function confirmation test for aging odor.
  • Tables 12 to 14 show the results of the deodorant function confirmation test for tobacco odor.
  • Tables 15 to 17 show the results of the deodorant function confirmation test for cooking odors.
  • the clothing pest control composition having the characteristic constitution of the present invention has the composition of Examples 1 to 32 containing enpentrin as an insect repellent and Examples 33 to 59 containing profluthrin as an insect repellent.
  • excellent deodorizing properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor were exhibited 24 hours after the installation of the test sample. From this, when the clothing pest control composition having the characteristic configuration of the present invention is volatilized in the storage space, the deodorizing function for the stored clothes continues for about 24 hours, and when the clothes are taken out from the storage space. It is considered possible to prevent the unpleasant sensation caused by the bad smell attached to the clothes.
  • the clothing pest control compositions of Comparative Examples 1 to 21 containing no insect repellent component are Examples 1 to 32 containing enpentrin as an insect repellent component and Examples 33 to 59 containing profluthrin as an insect repellent component. It contains the same fragrance ingredients, but feels an odor against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor even one hour after the installation of the sample. However, it did not show deodorant properties 24 hours after the installation of the test piece.
  • the clothing pest control composition of Comparative Example 22 contains enpentrin as an insect control component as in Examples 1 to 32, and the clothing pest control composition of Comparative Example 23 is similar to Examples 33 to 59. However, Comparative Examples 22 and 23 do not contain a fragrance component. The clothing pest control compositions of Comparative Examples 22 and 23 did not show deodorant properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor. From this, it was confirmed that the insect repellents, empentryn and profluthrin, alone do not have deodorant properties.
  • the insect repellent components empentryn and profluthrin, do not have deodorant properties by themselves, they are compared with the clothing pest control compositions of Comparative Examples 1 to 21 and only the insect repellent component is added to them. It is considered that the deodorizing function lasted for a long time in the clothing pest control compositions of Examples 1 to 59 because the insect repellent component has some synergistic effect with the specific flavor component defined in the present invention.
  • the deodorant function did not last for a long time even when it contained enpentrin as the insect repellent component (Comparative Examples 24-34) and when it contained profluthrin as the insect repellent component (Comparative Examples 35-45). It is considered that the synergistic effect between the insect repellent component and the fragrance component was not obtained because the specified specific fragrance component was not used.
  • the clothing pest control compositions (Examples 1 to 59) having the characteristic constitution of the present invention, by the combination of the specific insect repellent component and the specific perfume component, the synergistic effect of the insect repellent component and the perfume component. It was confirmed that the deodorizing function of the fragrance component lasted for a long time.
  • the clothing pest control composition and the clothing deodorizing method of the present invention are used for deodorizing a malodor adhering to clothing, and can be used for deodorizing a textile product. Furthermore, the clothing insect repellent and deodorant method of the present invention can be used for insect repellent and deodorant for textile products.

Abstract

A clothing pest control composition is provided that has a pest prevention function and also can persistently deodorize unpleasant odors adhering to clothing. A clothing pest control composition containing a pest prevention component and a fragrance component, wherein the fragrance component has a deodorizing function for deodorizing unpleasant odors adhering to clothing, and the pest prevention component has a persistence function for causing the deodorizing function of the fragrance component to persist. The pest prevention component is empenthrin and/or profluthrin, and the fragrance component is a compound that: has no electron-conjugated part other than an electron-conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure; has a carbon number of 6-18; has a molecular weight of 98-270; has a carbon atom, a hydrogen atom, and an oxygen atom; and does not have a sulfur atom, a nitrogen atom, or a halogen atom.

Description

衣料害虫防除組成物、並びに、当該組成物を用いた衣料消臭方法及び衣料防虫消臭方法Clothing pest control composition, and clothing deodorant method and clothing insect deodorant method using the composition
　本発明は、防虫成分と香料成分とを含有する衣料害虫防除組成物、及び当該組成物を用いた衣料消臭方法に関する。さらに、本発明は、衣料に対して防虫処理と消臭処理とを同時に行う衣料防虫消臭方法に関する。 The present invention relates to a clothing pest control composition containing an insect repellent component and a fragrance component, and a method for deodorizing clothing using the composition. Furthermore, the present invention relates to a method for preventing and removing clothing insects by simultaneously performing insect repellent treatment and deodorant treatment on clothing.
　衣料害虫から繊維製品を保護するため、様々な衣料害虫防除製品が開発され、実用化されている。例えば、常温揮散性を有するピレスロイド系防虫成分に代えて、香料成分を有効成分とする衣料害虫防除製品が知られている（例えば、特許文献１を参照）。 Various clothing pest control products have been developed and put into practical use in order to protect textile products from clothing pests. For example, there is known a clothing pest control product containing a fragrance component as an active ingredient in place of the pyrethroid insect control component having room temperature volatility (for example, see Patent Document 1).
　特許文献１の衣料害虫防除製品は、酢酸エステル化合物、アリルエステル化合物等の香料成分を吸水性ポリマーに保持させたものであり、長期に亘って有効成分の揮散性を維持することで、タンス、引き出し、クローゼット、衣料収納箱等の収納空間で衣料害虫の幼虫を致死させ、優れた摂食阻害効果を発揮することができる。 The clothing pest control product of Patent Document 1 is one in which a fragrance component such as an acetic acid ester compound and an allyl ester compound is held in a water-absorbent polymer, and by maintaining volatility of the active ingredient for a long period of time, In the storage space such as the drawer, the closet, and the clothing storage box, the larva of the clothing pest can be killed, and an excellent feeding-inhibiting effect can be exhibited.
特開２０１５－１１７２３１号公報JP, 2005-117231, A
　衣類は、着用中に汗臭、加齢臭、タバコ臭等の生活臭が付着することがある。そのため、衣類の管理では、衣料害虫の防除に加えて、衣類に付着する悪臭を消臭することが望まれる。例えば、外衣等は、連日使用することが多いため、クローゼット等の収納空間から取り出す際に、前日に衣類に付着した生活臭が不快感をもたらす虞があり、収納中に悪臭を持続的に消臭できることが望まれる。 Clothes may have a daily odor such as sweat odor, aging odor, cigarette odor, etc. while wearing. Therefore, in the management of clothing, in addition to controlling the harmful insects of clothing, it is desired to eliminate the bad odor attached to the clothing. For example, since outer garments are often used every day, the living odor attached to clothes on the previous day may cause discomfort when taken out from the storage space such as a closet. It is desirable to be able to smell.
　特許文献１の衣料害虫防除製品は、香料成分を有効成分としていることで消臭機能が期待されるが、衣料害虫に対する防虫機能を主眼として香料成分となる化合物が選択されており、衣類特有の悪臭に対する消臭機能については、検討の余地がある。 The clothing pest control product of Patent Document 1 is expected to have a deodorant function by using a fragrance component as an active ingredient, but a compound serving as a fragrance component has been selected with a focus on the insect control function against clothing pests, and is peculiar to clothing. There is room for consideration regarding the deodorizing function for bad odors.
　本発明は、上記問題点に鑑みてなされたものであり、防虫機能を果たすとともに衣類に付着する悪臭を持続的に消臭可能な衣料害虫防除組成物、及び当該組成物を用いた衣料消臭方法を提供することを目的とする。さらに、本発明は、一回の処理で衣料に防虫効果と持続的な消臭効果とを同時に付与可能な衣料防虫消臭方法を提供することを目的とする。 The present invention has been made in view of the above problems, and a clothing pest control composition capable of deodorizing a malodor that adheres to clothes while performing an insect repellent function, and a clothing deodorant using the composition. The purpose is to provide a method. A further object of the present invention is to provide a method for controlling insect deodorant of clothing, which is capable of imparting insect control effect and continuous deodorant effect to clothing at one time.
　上記課題を解決するための本発明に係る衣料害虫防除組成物の特徴構成は、
　防虫成分と香料成分とを含有する衣料害虫防除組成物であって、
　前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有し、
　前記防虫成分は、前記香料成分の消臭機能を持続させる持続機能を有することにある。 Characteristic composition of the clothing pest control composition according to the present invention for solving the above problems,
A clothing pest control composition comprising an insect repellent component and a fragrance component,
The fragrance component has a deodorizing function of deodorizing a bad odor attached to clothing,
The insect repellent component has a sustaining function of sustaining the deodorizing function of the fragrance component.
　本構成の衣料害虫防除組成物は、本発明者らが、様々な衣料害虫防除組成物を調製して種々試験を繰り返す中で、特定の防虫成分が香料成分の消臭機能を持続させる持続機能を有することを新たに見出したことにより、完成するに至ったものである。本構成の衣料害虫防除組成物によれば、香料成分が衣料に付着した悪臭を消臭する消臭機能を有し、防虫成分が香料成分の消臭機能を持続させる持続機能を有することにより、防虫成分が衣料害虫に対する防虫機能を果たすととともに、香料成分による消臭機能を長期に亘って持続させて衣類に付着する悪臭を持続的に消臭することができる。そのため、本発明の衣料害虫防除組成物を衣類の収納空間に処理しておくことで、収納中に香料成分による消臭機能が持続し、収納空間から衣類を取り出す際に不快感が生じることを防ぐことができる。 The clothing pest control composition of the present configuration, the present inventors, while preparing various clothing pest control composition and repeat various tests, a specific insect control component is a continuous function to maintain the deodorant function of the fragrance component. It was completed by newly discovering that it has. According to the clothing pest control composition of the present configuration, the fragrance component has a deodorant function of deodorizing the bad odor attached to the garment, and the insect repellent component has a continuous function of continuing the deodorant function of the fragrance component, While the insect repellent component has an insect repellent function against clothing pests, the deodorant function of the fragrance component can be maintained for a long period of time to continuously eliminate the bad odor attached to the clothing. Therefore, by treating the clothing pest control composition of the present invention in the storage space of clothes, the deodorizing function of the fragrance component is maintained during storage, and discomfort occurs when the clothes are taken out from the storage space. Can be prevented.
　本発明に係る衣料害虫防除組成物において、
　前記防虫成分は、エンペントリン、及び／又はプロフルトリンであり、
　前記香料成分は、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物であることが好ましい。 In the clothing pest control composition according to the present invention,
The insect repellent component is empentrin, and / or profluthrin,
The fragrance component does not have an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. It is preferable that the compound has a carbon atom, a hydrogen atom, and an oxygen atom and does not have a sulfur atom, a nitrogen atom, and a halogen atom.
　本構成の衣料害虫防除組成物によれば、上記の特定の防虫成分と香料成分とを組み合わせることによって、防虫成分と香料成分との相乗効果により、香料成分による消臭機能を長期に亘って持続させることができる。 According to the clothing pest control composition of the present configuration, by combining the specific insect repellent component and the fragrance component, by the synergistic effect of the insect repellent component and the fragrance component, the deodorant function of the fragrance component is maintained for a long time. Can be made
　本発明に係る衣料害虫防除組成物において、
　前記香料成分は、シス－３－ヘキセノール、ジヒドロミルセノール、エチルリナロール、リナロール 、ゲラニオール、テトラヒドロゲラニオール、テルピネオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、リナリルアセテート、ラズベリーケトン、ガラクソリド、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つであることが好ましい。 In the clothing pest control composition according to the present invention,
The perfume ingredients are cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lilial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicyt. It is preferably at least one selected from the group consisting of rate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brushlate, and cyclopentadecanolide.
　本構成の衣料害虫防除組成物によれば、上記の香料成分を含有することにより、防虫成分と香料成分との相乗効果が大きくなり、消臭機能の持続性を向上させることができる。 According to the clothing pest control composition of this constitution, by containing the above-mentioned fragrance component, the synergistic effect of the mosquito repellent component and the fragrance component becomes large, and the sustainability of the deodorant function can be improved.
　本発明に係る衣料害虫防除組成物において、
　前記香料成分の含有量が１～２０質量％であることが好ましい。 In the clothing pest control composition according to the present invention,
The content of the fragrance component is preferably 1 to 20% by mass.
　本構成の衣料害虫防除組成物によれば、香料成分の含有量が適切な範囲にあるため、例えば、衣料害虫防除組成物を含浸させた担体を衣類の収納空間に設置し、収納空間内に衣料害虫防除組成物を揮散させた場合に、衣類に付着する悪臭を芳香によってマスクして、十分な消臭性を得ることができる。 According to the clothing pest control composition of the present configuration, since the content of the fragrance component is in an appropriate range, for example, a carrier impregnated with the clothing pest control composition is installed in the storage space of clothes, and the storage space is placed in the storage space. When the clothes pest control composition is volatilized, the bad smell attached to the clothes can be masked by the aroma, and sufficient deodorant properties can be obtained.
　本発明に係る衣料害虫防除組成物において、
　前記香料成分（ａ）と前記防虫成分（ｂ）との配合比（ａ／ｂ）が、重量比として、０．１～２．０であることが好ましい。 In the clothing pest control composition according to the present invention,
The compounding ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is preferably 0.1 to 2.0 as a weight ratio.
　本構成の衣料害虫防除組成物によれば、配合比が適切な範囲にあるため、防虫成分による衣料害虫に対する防虫機能を十分に発揮しつつ、防虫成分と香料成分との相乗効果を十分に発揮することができ、香料成分による消臭機能を長期に亘って持続させることができる。 According to the clothing pest control composition of the present composition, since the compounding ratio is in an appropriate range, while fully exerting the insect repellent function of the insect repellent component against clothing pests, a sufficient synergistic effect between the insect repellent component and the fragrance component is exerted. Therefore, the deodorizing function of the fragrance component can be maintained for a long period of time.
　上記課題を解決するための本発明に係る衣料消臭方法の特徴構成は、
　前記の何れか一つに記載の衣料害虫防除組成物を用いた衣料消臭方法であって、
　前記衣料害虫防除組成物を含浸させた担体を衣料の収納空間に設置し、前記担体から前記衣料害虫防除組成物を揮散させることにある。 The characteristic configuration of the clothing deodorizing method according to the present invention for solving the above-mentioned problems,
A method for deodorizing clothing using the clothing pest control composition according to any one of the above,
A carrier impregnated with the clothing pest control composition is placed in a clothing storage space, and the clothing pest control composition is volatilized from the carrier.
　本構成の衣料消臭方法によれば、前記の何れか一つに記載の衣料害虫防除組成物を収納空間において揮散させることで、防虫成分による防虫機能が得られるととともに、防虫成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続する。そのため、本発明の衣料消臭方法を実施することで、収納中に香料成分による消臭機能が持続し、収納空間から衣類を取り出す際に不快感が生じることを防ぐことができる。 According to the clothing deodorizing method of the present configuration, by volatilizing the clothing pest control composition according to any one of the above in the storage space, it is possible to obtain an insect repellent function by an insect repellent component, and an insect repellent component and a fragrance component. Due to the synergistic effect with, the deodorizing function of the fragrance component lasts for a long time. Therefore, by carrying out the clothing deodorizing method of the present invention, it is possible to prevent the deodorizing function of the fragrance component from being maintained during storage and prevent discomfort when taking out the clothing from the storage space.
　上記課題を解決するための本発明に係る衣料防虫消臭方法の特徴構成は、
　衣料に対して防虫処理と消臭処理とを同時に行う衣料防虫消臭方法であって、
　収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納する収納工程と、
　前記衣料に十分な防虫効果及び消臭効果が付与されるように、前記収納空間内に前記衣料害虫防除組成物を揮散させる揮散工程と、
を包含することにある。 The characteristic configuration of the clothing insect repellent method according to the present invention for solving the above-mentioned problems,
A method of deodorizing clothing by performing insect repellent treatment and deodorant treatment on clothing at the same time,
A storage step of storing the clothing to be treated in the storage space together with a clothing pest control composition containing an insect repellent component and a fragrance component,
A volatilization step of volatilizing the clothing pest control composition in the storage space so that the clothing is provided with a sufficient insect-controlling effect and deodorizing effect,
To include.
　本構成の衣料防虫消臭方法によれば、収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納し、さらに、衣料に十分な防虫効果及び消臭効果が付与されるように、収納空間内に衣料害虫防除組成物を揮散させることで、一回の処理で衣料に防虫効果と持続的な消臭効果とを同時に付与することができる。そして、本発明の衣料防虫消臭方法によって処理された衣料は、防虫成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続するため、例えば、一日中外出するような場合であっても、不快な害虫が寄り付かず、かつ臭いも気にならずに長時間快適に活動することができる。 According to the clothing insect repellent deodorant method of the present configuration, the clothing to be treated is stored in the storage space together with the clothing pest control composition containing the insect repellent component and the fragrance component, and further, the clothing has a sufficient insect repellent effect and deodorant. By volatilizing the clothing pest control composition in the storage space so that the effect is imparted, it is possible to impart the insect control effect and the persistent deodorizing effect to the clothing at the same time by a single treatment. And, the clothing treated by the clothing insect repellent deodorizing method of the present invention, the synergistic effect of the insect repellent component and the perfume component, the deodorant function of the perfume component is maintained for a long time, for example, like going out all day. Even in such a case, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
　以下、本発明の衣料害虫防除組成物、及び衣料消臭方法について説明する。ただし、本発明は、以下に説明する実施形態に記載される構成に限定されることを意図しない。 The clothing pest control composition and the clothing deodorizing method of the present invention will be described below. However, the present invention is not intended to be limited to the configurations described in the embodiments described below.
＜衣料害虫防除組成物＞
　本発明の衣料害虫防除組成物は、衣料に付着した悪臭を消臭する消臭機能を有する香料成分と、防虫機能に加えて香料成分の消臭機能を持続させる持続機能を有する防虫成分とを含有する。 <Clothing pest control composition>
The clothing pest control composition of the present invention comprises a perfume component having a deodorant function of deodorizing a bad odor attached to clothing, and an insect repellent component having a persistent function of continuing the deodorant function of the perfume component in addition to the insect repellent function. contains.
　本発明の衣料害虫防除組成物の主成分の一つである防虫成分としては、香料成分の消臭機能を持続させる持続機能を有するものが使用される。具体的には、エンペントリン、プロフルトリン、及びｐ－メンタン－３，８－ジオール等が挙げられ、好ましい防虫成分は、エンペントリン、及び／又はプロフルトリンである。なお、以降の説明では、好ましい防虫成分であるエンペントリン、及びプロフルトリンを使用した実施形態について述べる。エンペントリン、及びプロフルトリンは、常温揮散性を有するピレスロイド系防虫成分であり、衣料害虫であるイガ、コイガ、ヒメカツオブシムシ、ヒメマルカツオブシムシやシミ類に対して、特にイガ、又はコイガの幼虫に対して高い防除効果を有する。このように、エンペントリン、及びプロフルトリンは、従来は防虫剤として使用されていたが、本発明者らが、エンペントリン、及びプロフルトリンを含有する様々な衣料害虫防除組成物を調製する中で、エンペントリン、及びプロフルトリンが、後述する特定の香料成分の消臭機能を持続させる持続機能を有することを新たに見出した。本発明の衣料害虫防除組成物は、衣料害虫防除組成物を含浸させた担持体を衣類の収納空間へ設置することで、収納空間内に防虫成分を揮散させて衣料害虫を防除しつつ、収納中の衣類に付着した悪臭の消臭を長期に亘って持続させることができる。衣料害虫防除組成物中の防虫成分の含有量は、１０～８０質量％であることが好ましい。このような範囲であれば、衣料害虫防除組成物を含浸させた担持体を収納空間内に設置することで、衣料害虫に対する防虫効果を発揮しつつ、後述する特定の香料成分との相乗効果を奏して、消臭機能の持続性を向上することができる。防虫成分の含有量が１０質量％未満である場合、衣料害虫に対する防虫効果や、香料成分との相乗効果による消臭機能の持続性が不十分となる虞がある。防虫成分の含有量が８０質量％を超える場合、実用上必要な防虫効果が得られる量を超えて防虫成分を配合することになり、経済的に不利である。 As the insect repellent component which is one of the main components of the clothing pest control composition of the present invention, one having a sustaining function of sustaining the deodorizing function of the fragrance component is used. Specific examples thereof include enpentrin, profluthrin, p-menthane-3,8-diol, and the like, and the preferred insect repellent component is enpentrin and / or profluthrin. In addition, in the following description, an embodiment using empentryn and profluthrin, which are preferable insect repellent components, will be described. Empentrin and profluthrin are pyrethroid insect repellents that have volatility at room temperature, and are highly controllable against larvae of clothes worms, koga, beetle simian beetle, beetle simian beetle and spots, especially mosquito or larvae of carp. Have an effect. As described above, although empentrin and profluthrin have been conventionally used as insect repellents, the present inventors have prepared various kinds of clothing pest control compositions containing empentrin and profluthrin, and thus, It has been newly found that profluthrin has a sustaining function of sustaining the deodorizing function of a specific fragrance component described later. The clothing pest control composition of the present invention, by installing a carrier impregnated with the clothing pest control composition in the storage space of the clothing, while controlling the clothing pests by volatilizing the insect control component in the storage space, the storage. It is possible to maintain the deodorization of the bad odor attached to the clothes inside for a long period of time. The content of the insect control component in the clothing pest control composition is preferably 10 to 80% by mass. Within such a range, by placing the carrier impregnated with the clothing pest control composition in the storage space, while exhibiting an insect-repellent effect against clothing pests, a synergistic effect with a specific fragrance component described later is obtained. It is possible to improve the durability of the deodorant function. When the content of the insect repellent component is less than 10% by mass, the insect repellent effect against clothing pests and the deodorant function due to the synergistic effect with the fragrance component may be insufficient in sustainability. When the content of the insect repellent component exceeds 80% by mass, the insect repellent component is blended in an amount exceeding the amount required to obtain the insect repellent effect required for practical use, which is economically disadvantageous.
　本発明の衣料害虫防除組成物の主成分の一つである香料成分としては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物が使用される。このような化合物は、衣類に付着した悪臭（汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭）を芳香によってマスクする優れた消臭機能を有するとともに、本発明において防虫成分として使用されるエンペントリン、及びプロフルトリンとの相乗効果により、その消臭機能を長時間に亘って持続させることができる。このような化合物としては、下記式（１）： As the perfume component which is one of the main components of the clothing pest control composition of the present invention, a benzene ring, a benzoic acid ester structure, or an electron conjugated part other than an electron conjugated part derived from a salicylic acid ester structure is not contained, and carbon A compound having a number of 6 to 18, a molecular weight of 98 to 270, a carbon atom, a hydrogen atom, and an oxygen atom and no sulfur atom, nitrogen atom, or halogen atom is used. Such a compound has an excellent deodorizing function of masking an offensive odor (sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor) attached to clothes with an aroma, and also serves as an insect repellent component in the present invention. The deodorant function can be maintained for a long time due to the synergistic effect with the used empentorin and profluthrin. As such a compound, the following formula (1):
Figure JPOXMLDOC01-appb-C000001
 で示されるシス－３－ヘキセノール（以下、「化合物Ａ」と称する。）、下記式（２）：
Figure JPOXMLDOC01-appb-C000001
 Cis-3-hexenol represented by the following formula (hereinafter referred to as “compound A”), the following formula (2):
Figure JPOXMLDOC01-appb-C000002
 で示されるジヒドロミルセノール（以下、「化合物Ｂ」と称する。）、下記式（３）：
Figure JPOXMLDOC01-appb-C000002
 Dihydromyrcenol represented by the following formula (hereinafter referred to as “compound B”), the following formula (3):
Figure JPOXMLDOC01-appb-C000003
 で示されるエチルリナロール（以下、「化合物Ｃ」と称する。）、下記式（４）：
Figure JPOXMLDOC01-appb-C000003
 Ethyl linalool represented by the following formula (hereinafter referred to as “compound C”), the following formula (4):
Figure JPOXMLDOC01-appb-C000004
 で示されるリナロール（以下、「化合物Ｄ」と称する。）、下記式（５）：
Figure JPOXMLDOC01-appb-C000004
 Linalool represented by the following formula (hereinafter referred to as “compound D”), the following formula (5):
Figure JPOXMLDOC01-appb-C000005
 で示されるゲラニオール（以下、「化合物Ｅ」と称する。）、下記式（６）：
Figure JPOXMLDOC01-appb-C000005
 Geraniol represented by the following formula (hereinafter referred to as “compound E”), the following formula (6):
Figure JPOXMLDOC01-appb-C000006
 で示されるテトラヒドロゲラニオール（以下、「化合物Ｆ」と称する。）、下記式（７）：
Figure JPOXMLDOC01-appb-C000006
 Tetrahydrogeraniol represented by (hereinafter referred to as “Compound F”), the following formula (7):
Figure JPOXMLDOC01-appb-C000007
 で示されるテルピネオール（以下、「化合物Ｇ」と称する。）、下記式（８）：
Figure JPOXMLDOC01-appb-C000007
 Terpineol represented by the following formula (hereinafter referred to as “compound G”), the following formula (8):
Figure JPOXMLDOC01-appb-C000008
 で示されるフェニルエチルアルコール（以下、「化合物Ｈ」と称する。）、下記式（９）：
Figure JPOXMLDOC01-appb-C000008
 Phenylethyl alcohol represented by (hereinafter, referred to as "Compound H"), the following formula (9):
Figure JPOXMLDOC01-appb-C000009
 で示されるヘリオナール（以下、「化合物Ｉ」と称する。）、下記式（１０）：
Figure JPOXMLDOC01-appb-C000009
 Helional represented by the following (hereinafter referred to as “Compound I”), the following formula (10):
Figure JPOXMLDOC01-appb-C000010
 で示されるリリアール（以下、「化合物Ｊ」と称する。）、下記式（１１）：
Figure JPOXMLDOC01-appb-C000010
 Lilyal represented by the following formula (hereinafter referred to as “compound J”), the following formula (11):
Figure JPOXMLDOC01-appb-C000011
 で示される安息香酸ベンジル（以下、「化合物Ｋ」と称する。）、下記式（１２）：
Figure JPOXMLDOC01-appb-C000011
 Benzyl benzoate represented by the following (hereinafter referred to as "Compound K"), the following formula (12):
Figure JPOXMLDOC01-appb-C000012
 で示されるサリチル酸ベンジル（以下、「化合物Ｌ」と称する。）、下記式（１３）：
Figure JPOXMLDOC01-appb-C000012
 Benzyl salicylate (hereinafter referred to as “compound L”) represented by the following formula (13):
Figure JPOXMLDOC01-appb-C000013
 で示されるシス－３－ヘキセニルサリチレート（以下、「化合物Ｍ」と称する。）、下記式（１４）：
Figure JPOXMLDOC01-appb-C000013
 Cis-3-hexenyl salicylate represented by the following (hereinafter referred to as “compound M”), the following formula (14):
Figure JPOXMLDOC01-appb-C000014
 で示されるジヒドロジャスモン酸メチル（以下、「化合物Ｎ」と称する。）、下記式（１５）：
Figure JPOXMLDOC01-appb-C000014
 Methyl dihydrojasmonate represented by (hereinafter referred to as “compound N”), the following formula (15):
Figure JPOXMLDOC01-appb-C000015
 で示されるリナリルアセテート（以下、「化合物Ｏ」と称する。）、下記式（１６）：
Figure JPOXMLDOC01-appb-C000015
 Linalyl acetate represented by the following formula (hereinafter referred to as “compound O”), the following formula (16):
Figure JPOXMLDOC01-appb-C000016
 で示されるラズベリーケトン（以下、「化合物Ｐ」と称する。）、下記式（１７）：
Figure JPOXMLDOC01-appb-C000016
 A raspberry ketone (hereinafter, referred to as “compound P”) represented by the following formula (17):
Figure JPOXMLDOC01-appb-C000017
 で示されるガラクソリド（以下、「化合物Ｑ」と称する。）、下記式（１８）：
Figure JPOXMLDOC01-appb-C000017
 A galaxolide represented by the following (hereinafter referred to as "compound Q"), the following formula (18):
Figure JPOXMLDOC01-appb-C000018
 で示されるエチレンブラシレート（以下、「化合物Ｒ」と称する。）、下記式（１９）：
Figure JPOXMLDOC01-appb-C000018
 An ethylene brushlate represented by (hereinafter referred to as “compound R”), the following formula (19):
Figure JPOXMLDOC01-appb-C000019
 で示されるシクロペンタデカノリド（以下、「化合物Ｓ」と称する。）等が挙げられる。
Figure JPOXMLDOC01-appb-C000019
 And cyclopentadecanolide (hereinafter referred to as "compound S").
　上記の化合物Ａ～Ｓは、単独で使用してもよいし、複数種を組み合わせて使用してもよい。香料成分の含有量は、１～２０質量％が好ましい。香料成分の含有量がこのような範囲であれば、例えば、本発明の衣料害虫防除組成物を含浸させた担体を衣類の収納空間に設置し、或いは本発明の衣料害虫防除組成物を含むエアゾール等の噴射製品を衣類の収納空間内に直接噴射し、収納空間内に衣料害虫防除組成物を揮散させた場合に、収容中の衣類に付着した悪臭をマスクして、十分な消臭性を得ることができる。香料成分の含有量が１質量％未満である場合、収納空間内に衣料害虫防除組成物を揮散させた場合の消臭性が不足する虞がある。香料成分の含有量が２０質量％を超える場合、衣料害虫防除組成物がべたつき易くなる。 The above compounds A to S may be used alone or in combination of two or more. The content of the fragrance component is preferably 1 to 20% by mass. When the content of the fragrance component is in such a range, for example, a carrier impregnated with the clothing pest control composition of the present invention is installed in a storage space of clothes, or an aerosol containing the clothing pest control composition of the present invention is provided. When spraying sprayed products such as the above directly into the clothing storage space and volatilizing the clothing pest control composition in the storage space, masks the bad odor adhering to the clothing being stored and provides sufficient deodorant properties. Obtainable. When the content of the fragrance component is less than 1% by mass, the deodorant property may be insufficient when the clothing pest control composition is volatilized in the storage space. When the content of the fragrance component exceeds 20% by mass, the clothing pest control composition tends to be sticky.
　本発明の衣料害虫防除組成物において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．１～２．０に調整することが好ましい。配合比（ａ／ｂ）がこのような範囲であれば、防虫成分と香料成分との相乗効果が大きくなり、香料成分による消臭機能が長期に亘って持続する。配合比（ａ／ｂ）が０．１未満である場合、及び配合比（ａ／ｂ）が２．０を超える場合、防虫成分と香料成分との相乗効果を十分に発揮することができない虞がある。 In the clothing pest control composition of the present invention, the compounding ratio (a / b) of the fragrance component (a) and the insect control component (b) is preferably adjusted to a weight ratio of 0.1 to 2.0. When the compounding ratio (a / b) is in such a range, the synergistic effect of the insect repellent component and the fragrance component becomes large, and the deodorizing function of the fragrance component continues for a long period of time. When the compounding ratio (a / b) is less than 0.1 and when the compounding ratio (a / b) exceeds 2.0, the synergistic effect of the insect repellent component and the fragrance component may not be sufficiently exhibited. There is.
　本発明の衣料害虫防除組成物は、上記成分に加え、カビ類や菌類等を対象とした防カビ剤、抗菌剤、殺菌剤、酸化防止剤等を適宜配合することもできる。防カビ剤、抗菌剤、及び殺菌剤としては、ヒノキチオール、２－メルカプトベンゾチアゾール、２－（４－チアゾリル）ベンツイミダゾール、５－クロロ－２－メチル－４－イソチアゾリン－３－オン、トリホリン、３－メチル－４－イソプロピルフェノール、オルト－フェニルフェノール等が挙げられる。 The clothing pest control composition of the present invention may appropriately contain, in addition to the above components, a fungicide, an antibacterial agent, a bactericidal agent, an antioxidant, etc. for molds and fungi. Antifungal agents, antibacterial agents, and bactericides include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolyl) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, triphorin, and 3 -Methyl-4-isopropylphenol, ortho-phenylphenol and the like can be mentioned.
　本発明の衣料害虫防除組成物は、上掲の各成分を適切な重量比で配合し、さらに溶剤を添加して各成分の濃度が適切となるように調整される。溶剤としては、ノルマルパラフィン系炭化水素、イソパラフィン系炭化水素、炭素数が２～３の低級アルコール、炭素数の総数が１６～２０の高級脂肪酸エステル等の使用が好ましい。 The clothing pest control composition of the present invention is prepared by mixing the above-mentioned components in an appropriate weight ratio and further adding a solvent so that the concentration of each component is appropriate. As the solvent, it is preferable to use normal paraffin hydrocarbon, isoparaffin hydrocarbon, lower alcohol having 2 to 3 carbon atoms, higher fatty acid ester having 16 to 20 carbon atoms, or the like.
＜衣料害虫防除製品＞
　本発明の衣料害虫防除組成物の好ましい製品形態は、衣料害虫防除組成物を含浸させた固形担体を、通気性ケース等の容器に収容した衣料害虫防除製品である。固形担体としては、繊維質担体（パルプ、リンター、レーヨン等）、セルロール又は再生セルロール製のビーズ及び発泡体、無機多孔質担体（ケイ酸塩、シリカ、ゼオライト等）、昇華性担体（トリオキサン、アダマンタン等）が挙げられる。繊維質担体を使用する場合、厚さ１～３ｍｍ程度のマット状又はシート状のものが好ましい。また、別の衣料害虫防除組成物の製品形態として、ハンドスプレーやエアゾール等の噴射製品を採用することも可能である。特に、定量噴射バルブを備えたエアゾール容器に本発明の衣料害虫防除組成物と噴射剤とを封入したエアゾール製品が使い勝手が良い。噴射剤としては、液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等を使用することができる。液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等が挙げられる。液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等が挙げられる。液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等が挙げられる。 <Clothing pest control products>
A preferred product form of the clothing pest control composition of the present invention is a clothing pest control product in which a solid carrier impregnated with the clothing pest control composition is contained in a container such as a breathable case. As the solid carrier, a fibrous carrier (pulp, linter, rayon, etc.), beads or foam made of cellulose or recycled cellulose, inorganic porous carrier (silicate, silica, zeolite, etc.), sublimable carrier (trioxane, adamantane, etc.). Etc.) can be mentioned. When a fibrous carrier is used, a mat-like or sheet-like one having a thickness of about 1 to 3 mm is preferable. Further, as another product form of the clothing pest control composition, a spray product such as a hand spray or an aerosol can be adopted. In particular, the aerosol product in which the clothing pest control composition of the present invention and the propellant are enclosed in an aerosol container equipped with a metering valve is convenient. As the propellant, liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air or the like can be used. Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air and the like can be mentioned. Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air and the like can be mentioned. Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air and the like can be mentioned.
＜衣料消臭方法＞
　本発明の衣料消臭方法の好ましい態様は、本発明の衣料害虫防除組成物を含浸させた担体を衣料の収納空間に設置し、担体から衣料害虫防除組成物を揮散させるものであり、例えば、上述の衣料害虫防除製品を含浸させた固形担体を用いて実施することができる。また、本発明の衣料消臭方法の別の態様は、本発明の衣料害虫防除組成物を衣料の収納空間に直接付与して揮散させるものであり、例えば、上述のエアゾール製品を用いて実施することができる。具体的には、衣料害虫防除製品が固形担体である場合、この固形担体をクローゼット等の衣類の収納空間に設置する。収容空間内に設置した固形担体から本発明の衣料害虫防除組成物が揮散することで、収容中の衣類には優れた防虫機能、及び持続的な消臭機能が付与される。衣料害虫防除製品がエアゾール製品である場合、クローゼット等の衣類の収納空間内に衣料害虫防除組成物を直接噴射する。その後、直ちに収納空間を閉鎖すると、衣料害虫防除組成物が収容空間内に揮散して充満し、収容中の衣類には優れた防虫機能、及び持続的な消臭機能が付与される。このように、本発明の衣料消臭方法によれば、収容空間において衣料害虫を防除しつつ、収容中の衣類に付着した悪臭を消臭することができる。 <Clothing deodorizing method>
A preferred embodiment of the clothing deodorizing method of the present invention is to install a carrier impregnated with the clothing pest control composition of the present invention in the storage space of the clothing, and volatilize the clothing pest control composition from the carrier, for example, It can be carried out using a solid carrier impregnated with the above-mentioned clothing pest control product. Another aspect of the clothing deodorizing method of the present invention is to directly apply the clothing pest control composition of the present invention to the storage space of the clothing and volatilize it, and for example, it is carried out using the above-mentioned aerosol product. be able to. Specifically, when the clothing pest control product is a solid carrier, the solid carrier is installed in a clothing storage space such as a closet. By volatilizing the clothes pest control composition of the present invention from the solid carrier placed in the storage space, the clothes in storage are provided with an excellent insect control function and a continuous deodorizing function. When the clothing pest control product is an aerosol product, the clothing pest control composition is directly sprayed into the storage space for clothes such as a closet. Then, when the storage space is immediately closed, the pesticidal composition for clothing is volatilized and filled in the storage space, and the clothes in storage are provided with an excellent insect control function and a continuous deodorizing function. As described above, according to the clothing deodorizing method of the present invention, it is possible to deodorize the bad odor attached to the clothing being stored while controlling the clothing harmful insects in the storage space.
＜衣料防虫消臭方法＞
　本発明の衣料防虫消臭方法は、収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納する収納工程と、衣料に十分な防虫効果及び消臭効果が付与されるように、収納空間内に衣料害虫防除組成物を揮散させる揮散工程とを実行するものである。本発明の衣料防虫消臭方法は、基本的な工程（操作）は上述の衣料消臭方法と同様であるが、揮散工程において、衣料に十分な防虫効果及び消臭効果が付与されるように、例えば、収納空間を閉鎖した状態で衣料害虫防除組成物を一日以上揮散させればよい。その際、例えば、衣料のうち特に臭いが気になる箇所（例えば、脇下、首回り、脚周辺部など）を裏返しにするなどして露出させることで、念入りに揮散処理を行うことで、衣料に効果的な防虫効果と持続的な消臭効果とを同時に付与することができる。このように、本発明の衣料防虫消臭方法を実施すれば、一回の処理で衣料に防虫効果と持続的な消臭効果とを同時に付与することができる。そして、本発明の衣料防虫消臭方法によって処理された衣料は、後述する防虫成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続するため、例えば、一日中外出するような場合であっても、不快な害虫が寄り付かず、かつ臭いも気にならずに長時間快適に活動することができる。 <Clothing insect deodorant method>
The clothing insect repellent method of the present invention includes a storage step of storing the clothing to be treated together with the clothing pest control composition containing an insect repellent component and a fragrance component in the storage space, and a sufficient insect repellent and deodorant effect on the clothing. And a volatilization step of volatilizing the clothing pest control composition in the storage space. The clothing insect deodorizing method of the present invention has the same basic steps (operations) as those of the clothing deodorizing method described above, but in the volatilization step, the clothing is provided with a sufficient insect controlling effect and deodorizing effect. For example, the clothing pest control composition may be volatilized for one day or more with the storage space closed. At that time, for example, by exposing the places where the odor is particularly worrisome (for example, armpits, neck, legs and the like) by turning them upside down, carefully performing the volatilization treatment, It is possible to impart an effective insect repellent effect and a persistent deodorant effect to clothing at the same time. Thus, by carrying out the method of deodorizing clothing and insects of the present invention, it is possible to impart the insecticidal effect and the persistent deodorant effect to clothing at the same time by a single treatment. The clothing treated by the clothing insect deodorant method of the present invention has a synergistic effect of an insect repellent component and a fragrance component, which will be described later, because the deodorant function of the fragrance component continues for a long period of time, for example, going out all day. Even in such a case, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
　本発明に係る衣料害虫防除組成物は、防虫成分に特定の香料成分を組み合わせることによって、防虫成分と香料成分との相乗効果により、香料成分による消臭機能を長期に亘って持続させることができる。消臭機能の持続期間は、防虫成分と香料成分との組み合わせ、両成分の配合割合、衣料害虫防除組成物の使用条件等により異なるが、おおよそ一日程度、消臭機能を持続させることは十分に可能である。このため、この衣料害虫防除組成物を用いて実行される本発明の衣料消臭方法に従って、衣料害虫防除組成物を収納空間内に揮散させれば、例えば、２４時間程度衣類を収納する場合に、収納中の衣類に対する消臭機能が持続し、収納空間から衣類を取り出す際に衣類に付着した悪臭により不快感が生じることを防ぐことができる。 The clothing pest control composition according to the present invention, by combining the insect repellent component with a specific perfume ingredient, the synergistic effect of the insect repellent ingredient and the perfume ingredient allows the deodorant function of the perfume ingredient to be maintained for a long period of time. .. The duration of the deodorant function varies depending on the combination of the insect repellent component and the fragrance component, the mixing ratio of both components, the use conditions of the clothing pest control composition, etc., but it is sufficient to maintain the deodorant function for about one day. Is possible. Therefore, if the clothing pest control composition is volatilized in the storage space according to the clothing deodorizing method of the present invention which is carried out using this clothing pest control composition, for example, when storing clothes for about 24 hours. The deodorizing function of the stored clothes is maintained, and it is possible to prevent discomfort from being caused by a bad smell attached to the clothes when the clothes are taken out from the storage space.
　本発明の衣料害虫防除組成物について、消臭機能の持続性を確認するため、本発明の特徴構成を備えた衣料害虫防除組成物（実施例１～５９）を準備し、消臭機能確認試験を実施した。また、比較のため、本発明の特徴構成を備えていない衣料害虫防除組成物（比較例１～５６）を準備し、同様の消臭機能確認試験を実施した。なお、実施例１～５９、及び比較例１～５６では重量の単位として「ｇ」が示されているが、任意の倍率でスケールアップが可能である。すなわち、単位「ｇ」は、「重量部」と読み替えることができる。 Regarding the clothing pest control composition of the present invention, in order to confirm the durability of the deodorant function, a clothing pest control composition (Examples 1 to 59) having the characteristic constitution of the present invention was prepared, and a deodorant function confirmation test was conducted. Was carried out. For comparison, clothing pest control compositions (Comparative Examples 1 to 56) not having the characteristic constitution of the present invention were prepared, and the same deodorant function confirmation test was carried out. In addition, in Examples 1 to 59 and Comparative Examples 1 to 56, “g” is shown as a unit of weight, but it is possible to scale up at any magnification. That is, the unit “g” can be read as “part by weight”.
＜実施例１～２１＞
　防虫成分としてエンペントリンを使用する下記の処方１により、衣料害虫防除組成物（実施例１～２１）を調製した。実施例１～１９の衣料害虫防除組成物においては、化合物Ａ～Ｓを香料成分として使用した。実施例２０の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、及びＱを等量ずつ混合した調合香料（以下、「調合香料１」と称する。）を香料成分として使用した。実施例２１の衣料害虫防除組成物においては、化合物Ｌ、Ｎ、Ｑ、β－ダマスコン、及びカシュメランを等量ずつ混合した調合香料（以下、「調合香料２」と称する。）を香料成分として使用した。 <Examples 1 to 21>
Compositions for controlling insect pests of clothing (Examples 1 to 21) were prepared according to the following Formulation 1 using Empentrin as an insect repellent component. Compounds A to S were used as perfume ingredients in the clothing pest control compositions of Examples 1 to 19. In the clothing pest control composition of Example 20, a mixed fragrance (hereinafter, referred to as “prepared fragrance 1”) in which equal amounts of the compounds B, H, L, N, and Q were mixed was used as a fragrance component. In the clothing pest control composition of Example 21, a compounded fragrance (hereinafter, referred to as “prepared fragrance 2”) in which equal amounts of the compounds L, N, Q, β-damascon, and cashmere were mixed was used as a fragrance component. did.
　処方１：
　香料成分を１５ｇ（１５質量％）、エンペントリンを７０ｇ（７０質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方１において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．２１である。 Prescription 1:
A total of 100 g was prepared by mixing 15 g (15% by mass) of the fragrance component, 70 g (70% by mass) of empentrin, and the balance (balance) of deotomisole as a solvent. In Formulation 1, the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.21 as a weight ratio.
＜実施例２２～２７＞
　防虫成分としてエンペントリンを使用する下記の処方２により、衣料害虫防除組成物（実施例２２～２７）を調製した。実施例２２～２７の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、Ｑ、及び調合香料１を香料成分として使用した。 <Examples 22 to 27>
Compositions for controlling insect pests of clothing (Examples 22 to 27) were prepared according to the following Formulation 2 using Empentrin as an insect repellent component. In the clothing pest control compositions of Examples 22 to 27, Compounds B, H, L, N, Q and Formulated Fragrance 1 were used as the perfume ingredients.
　処方２：
　香料成分を１５ｇ（１５質量％）、エンペントリンを３０ｇ（３０質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方２において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．５０である。 Prescription 2:
A total of 100 g was prepared by mixing 15 g (15% by mass) of the fragrance component, 30 g (30% by mass) of empentrine, and the balance (balance) of deotomizole as a solvent. In Formulation 2, the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.50 as a weight ratio.
＜実施例２８～３２＞
　防虫成分としてエンペントリンを使用する下記の処方３により、衣料害虫防除組成物（実施例２８～３２）を調製した。実施例２８～３２の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、及びＱを香料成分として使用した。 <Examples 28 to 32>
Clothing pest control compositions (Examples 28 to 32) were prepared according to the following Formulation 3 using Empentrin as an insect control component. In the clothing pest control compositions of Examples 28 to 32, compounds B, H, L, N, and Q were used as perfume ingredients.
　処方３：
　香料成分を１５ｇ（１５質量％）、エンペントリンを１５ｇ（１５質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方３において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、１．００である。 Prescription 3:
A total of 100 g was prepared by mixing 15 g (15% by mass) of the fragrance component, 15 g (15% by mass) of empentrin, and the balance (balance) of deotomizole as a solvent. In Formulation 3, the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 1.00 as a weight ratio.
＜実施例３３～５３＞
　防虫成分としてプロフルトリンを使用する下記の処方４により、衣料害虫防除組成物（実施例３３～５３）を調製した。実施例３３～５３の衣料害虫防除組成物においては、化合物Ａ～Ｓ、調合香料１、及び調合香料２を香料成分として使用した。 <Examples 33 to 53>
Clothing pest control compositions (Examples 33 to 53) were prepared according to the following formulation 4 using profluthrin as an insect control component. In the clothing pest control compositions of Examples 33 to 53, Compounds A to S, Formulated Perfume 1 and Formulated Perfume 2 were used as perfume ingredients.
　処方４：
　香料成分を１５ｇ（１５質量％）、プロフルトリンを３５ｇ（３５質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方４において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．４３である。 Prescription 4:
15 g (15% by mass) of the fragrance component, 35 g (35% by mass) of profluthrin, and the balance (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In formulation 4, the compounding ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.43 as a weight ratio.
＜実施例５４～５９＞
　防虫成分としてプロフルトリンを使用する下記の処方５により、衣料害虫防除組成物（実施例５４～５９）を調製した。実施例５４～５９の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、Ｑ、及び調合香料１を香料成分として使用した。 <Examples 54 to 59>
Compositions for controlling insect pests of clothing (Examples 54 to 59) were prepared according to the following formulation 5 using profluthrin as an insect repellent component. In the clothing pest control compositions of Examples 54 to 59, Compounds B, H, L, N and Q, and the prepared perfume 1 were used as perfume ingredients.
　処方５：
　香料成分を１５ｇ（１５質量％）、プロフルトリンを１５ｇ（１５質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方５において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、１．００である。 Prescription 5:
15 g (15% by mass) of the fragrance component, 15 g (15% by mass) of profluthrin and the balance (balance) of deotomizole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 5, the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 1.00 as a weight ratio.
＜比較例１～２１＞
　防虫成分を配合しない下記の処方６により、衣料害虫防除組成物（比較例１～２１）を調製した。比較例１～２１の衣料害虫防除組成物においては、化合物Ａ～Ｓ、調合香料１、及び調合香料２を香料成分として使用した。 <Comparative Examples 1 to 21>
Compositions for controlling insect pests for clothing (Comparative Examples 1 to 21) were prepared according to the following formulation 6 containing no insect repellent. In the clothing pest control compositions of Comparative Examples 1 to 21, compounds A to S, blended flavor 1 and blended flavor 2 were used as flavor components.
　処方６：
　香料成分を１５ｇ（０．５質量％）、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。 Prescription 6:
15 g (0.5% by mass) of the fragrance component and the balance (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g.
＜比較例２２＞
　防虫成分としてエンペントリンを使用する下記の処方７により、衣料害虫防除組成物（比較例２２）を調製した。比較例２２の衣料害虫防除組成物においては、香料成分を配合していない。 <Comparative Example 22>
A clothing pest control composition (Comparative Example 22) was prepared according to the following formulation 7 using empentryn as an insect control component. The clothing pest control composition of Comparative Example 22 does not contain a fragrance component.
　処方７：
　エンペントリンを７０ｇ（７０質量％）、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方７において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．００である。 Prescription 7:
70 g (70% by mass) of empentryn and deotomisole as a solvent were mixed in the balance (balance) to prepare a total amount of 100 g. In the formulation 7, the mixing ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.00 as a weight ratio.
＜比較例２３＞
　防虫成分としてプロフルトリンを使用する下記の処方８により、衣料害虫防除組成物（比較例２３）を調製した。比較例２３の衣料害虫防除組成物においては、香料成分を配合していない。 <Comparative Example 23>
A clothing pest control composition (Comparative Example 23) was prepared according to the following formulation 8 using profluthrin as an insect control component. The clothing pest control composition of Comparative Example 23 did not contain a fragrance component.
　処方８：
　プロフルトリンを３５ｇ（３５質量％）、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方８において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．００である。 Prescription 8:
35 g (35% by mass) of profluthrin and the balance (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In the formulation 8, the compounding ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.00 as a weight ratio.
＜比較例２４～３４＞
　防虫成分としてエンペントリンを使用する処方１により、衣料害虫防除組成物（比較例２４～３４）を調製した。比較例２４～３４の衣料害虫防除組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物を香料成分として使用した。具体的には、比較例２４の衣料害虫防除組成物においては、下記式（２０）： <Comparative Examples 24 to 34>
Composition 1 for controlling clothing pests (Comparative Examples 24 to 34) was prepared according to Formulation 1 using Empentrin as an insect repellent component. In the clothing pest control compositions of Comparative Examples 24 to 34, compounds having an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure were used as a perfume component. Specifically, in the clothing pest control composition of Comparative Example 24, the following formula (20):
Figure JPOXMLDOC01-appb-C000020
 で示されるクマリン（以下、「化合物Ｃ１」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000020
 Coumarin (hereinafter, referred to as "compound C1") represented by the formula (1) was used as a perfume ingredient.
　比較例２５の衣料害虫防除組成物においては、下記式（２１）： In the clothing pest control composition of Comparative Example 25, the following formula (21):
Figure JPOXMLDOC01-appb-C000021
 で示されるβ-ヨノン（以下、「化合物Ｃ２」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000021
 Β-ionone represented by (hereinafter, referred to as “compound C2”) was used as a perfume ingredient.
　比較例２６の衣料害虫防除組成物においては、下記式（２２）： In the clothing pest control composition of Comparative Example 26, the following formula (22):
Figure JPOXMLDOC01-appb-C000022
 で示されるβ-ダマスコン（以下、「化合物Ｃ３」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000022
 Β-Damascone represented by (hereinafter referred to as “compound C3”) was used as a perfume ingredient.
　比較例２７の衣料害虫防除組成物においては、下記式（２３）： In the clothing pest control composition of Comparative Example 27, the following formula (23):
Figure JPOXMLDOC01-appb-C000023
 で示されるダマセノン（以下、「化合物Ｃ４」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000023
 Damasenone represented by the formula (hereinafter referred to as "compound C4") was used as a perfume ingredient.
　比較例２８の衣料害虫防除組成物においては、下記式（２４）： In the clothing pest control composition of Comparative Example 28, the following formula (24):
Figure JPOXMLDOC01-appb-C000024
 で示されるシトラール（以下、「化合物Ｃ５」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000024
 Citral represented by (hereinafter, referred to as "compound C5") was used as a perfume ingredient.
　比較例２９の衣料害虫防除組成物においては、下記式（２５）： In the clothing pest control composition of Comparative Example 29, the following formula (25):
Figure JPOXMLDOC01-appb-C000025
 で示されるシンナムアルデヒド（以下、「化合物Ｃ６」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000025
 The cinnamaldehyde represented by (hereinafter, referred to as "compound C6") was used as a perfume ingredient.
　比較例３０の衣料害虫防除組成物においては、下記式（２６）： In the clothing pest control composition of Comparative Example 30, the following formula (26):
Figure JPOXMLDOC01-appb-C000026
 で示されるカリクソール（以下、「化合物Ｃ７」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000026
 The calixol represented by (hereinafter referred to as "compound C7") was used as a perfume ingredient.
　比較例３１の衣料害虫防除組成物においては、下記式（２７）： In the clothing pest control composition of Comparative Example 31, the following formula (27):
Figure JPOXMLDOC01-appb-C000027
 で示されるカシュメラン（以下、「化合物Ｃ８」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000027
 The cashew melanin (hereinafter, referred to as "compound C8") was used as a perfume ingredient.
　比較例３２の衣料害虫防除組成物においては、下記式（２８）： In the clothing pest control composition of Comparative Example 32, the following formula (28):
Figure JPOXMLDOC01-appb-C000028
 で示されるマルトール（以下、「化合物Ｃ９」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000028
 Maltol represented by (hereinafter, referred to as "compound C9") was used as a perfume ingredient.
　比較例３３の衣料害虫防除組成物においては、下記式（２９）： In the clothing pest control composition of Comparative Example 33, the following formula (29):
Figure JPOXMLDOC01-appb-C000029
 で示されるカルボン（以下、「化合物Ｃ１０」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000029
 Carvone represented by (hereinafter referred to as "compound C10") was used as a perfume ingredient.
　比較例３４の衣料害虫防除組成物においては、下記式（３０）： In the clothing pest control composition of Comparative Example 34, the following formula (30):
Figure JPOXMLDOC01-appb-C000030
 で示されるファルネセン（以下、「化合物Ｃ１１」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000030
 Farnesene represented by (hereinafter referred to as "compound C11") was used as a perfume ingredient.
＜比較例３５～４５＞
　防虫成分としてプロフルトリンを使用する処方４により、衣料害虫防除組成物（比較例３５～４５）を調製した。比較例３５～４５の衣料害虫防除組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物Ｃ１～Ｃ１１を香料成分として使用した。 <Comparative Examples 35 to 45>
Formulation 4 using profluthrin as an insect repellent composition was used to prepare clothing pest control compositions (Comparative Examples 35 to 45). In the clothing pest control compositions of Comparative Examples 35 to 45, compounds C1 to C11 having an electron conjugated part other than the electron conjugated part derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients.
＜比較例４６～５６＞
　防虫成分を配合しない処方６により、衣料害虫防除組成物（比較例４６～５６）を調製した。比較例４６～５６の衣料害虫防除組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物Ｃ１～Ｃ１１を香料成分として使用した。 <Comparative Examples 46 to 56>
Composition 6 for controlling clothing pests (Comparative Examples 46 to 56) was prepared according to Formulation 6 containing no insect control component. In the clothing pest control compositions of Comparative Examples 46 to 56, compounds C1 to C11 having an electron conjugated portion other than the electron conjugated portion derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients.
　実施例１～５９、及び比較例１～５６の衣料害虫防除組成物の処方、及び香料成分を表１、２に示す。 Tables 1 and 2 show the formulations of the clothing pest control compositions of Examples 1 to 59 and Comparative Examples 1 to 56, and the fragrance components.
Figure JPOXMLDOC01-appb-T000031
Figure JPOXMLDOC01-appb-T000031
Figure JPOXMLDOC01-appb-T000032
Figure JPOXMLDOC01-appb-T000032
［消臭機能確認試験］
　汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭に対する消臭機能確認試験を実施した。供試体として、実施例１～５９、及び比較例１～５６の試験溶液を１５ｍｇ分注したものを用いた。汗臭については、直径９ｃｍの試験濾紙に、アンモニア水（ナカライテスク株式会社製）のエタノール溶液をスプレーバイアルにて適量噴霧したものを悪臭処理サンプルとした。ミドル脂臭については、直径９ｃｍの試験濾紙に、ジアセチル（ナカライテスク株式会社製）のエタノール溶液をスプレーバイアルにて適量噴霧したものを悪臭処理サンプルとした。加齢臭については、直径９ｃｍの試験濾紙に、２－ノネナール（東京化成工業株式会社製）のエタノール溶液をスプレーバイアルにて適量噴霧したものを悪臭処理サンプルとした。タバコ臭については、密閉小空間でタバコの煙を直径９ｃｍの試験濾紙に暴露処理したものを悪臭処理サンプルとした。調理臭については、密閉小空間で牛脂を燃やして、その煙を直径９ｃｍの試験濾紙に暴露処理したものを悪臭処理サンプルとした。 [Deodorant function confirmation test]
A deodorant function confirmation test for sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor was conducted. As a test piece, the test solution of Examples 1 to 59 and Comparative Examples 1 to 56 dispensed in an amount of 15 mg was used. Regarding the sweat odor, a test filter paper having a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of ammonia water (manufactured by Nacalai Tesque, Inc.) in a spray vial to obtain a malodor treated sample. Regarding the middle fat odor, a test filter paper having a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of diacetyl (manufactured by Nacalai Tesque, Inc.) with a spray vial to obtain a malodor treated sample. Regarding the aging odor, a test filter paper having a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of 2-nonenal (manufactured by Tokyo Kasei Kogyo Co., Ltd.) with a spray vial to obtain a malodor-treated sample. Regarding the tobacco odor, a sample obtained by exposing tobacco smoke to a test filter paper having a diameter of 9 cm in a small enclosed space was used as a malodor-treated sample. Regarding the cooking odor, beef tallow was burned in a small enclosed space, and the smoke was exposed to a test filter paper having a diameter of 9 cm to obtain a malodor-treated sample.
　消臭機能確認試験では、容量１３．５Ｌのステンレス製の円筒内に悪臭処理サンプルを吊るし、悪臭処理サンプル設置から１時間経過後に、悪臭処理サンプルに並べて供試体を吊るした。供試体の設置から１時間後、及び２４時間後に、ステンレス製の内の臭気を評価した。臭気の評価は以下の５段階臭気強度表示法で５人のテスターにより評価し、平均点を求めた。平均点０以上２未満を○、２以上３未満を△、３以上４以下を×とした。
　　０：香りを感じない
　　１：かすかに感じる
　　２：弱く感じる
　　３：明らかに感じる
　　４：強く感じる In the deodorant function confirmation test, the malodor-treated sample was suspended in a stainless steel cylinder having a capacity of 13.5 L, and one hour after the malodor-treated sample was installed, the test sample was suspended in parallel with the malodor-treated sample. The odor inside the stainless steel was evaluated 1 hour and 24 hours after the installation of the specimen. The odor was evaluated by five testers according to the following five-level odor intensity display method, and the average score was obtained. The average score of 0 or more and less than 2 was evaluated as ◯, 2 or more and less than 3 as Δ, and 3 or more and 4 or less as x.
0: Do not feel scent 1: Feel slightly 2: Feel weak 3: Feel clearly 4: Feel strongly
　汗臭に対する消臭機能確認試験の結果を表３～５に示す。 The results of the deodorant function confirmation test for sweat odor are shown in Tables 3-5.
Figure JPOXMLDOC01-appb-T000033
Figure JPOXMLDOC01-appb-T000033
Figure JPOXMLDOC01-appb-T000034
Figure JPOXMLDOC01-appb-T000034
Figure JPOXMLDOC01-appb-T000035
Figure JPOXMLDOC01-appb-T000035
　ミドル脂臭に対する消臭機能確認試験の結果を表６～８に示す。 Tables 6 to 8 show the results of the deodorant function confirmation test for middle fat odor.
Figure JPOXMLDOC01-appb-T000036
Figure JPOXMLDOC01-appb-T000036
Figure JPOXMLDOC01-appb-T000037
Figure JPOXMLDOC01-appb-T000037
Figure JPOXMLDOC01-appb-T000038
Figure JPOXMLDOC01-appb-T000038
　加齢臭に対する消臭機能確認試験の結果を表９～１１に示す。 Tables 9 to 11 show the results of the deodorant function confirmation test for aging odor.
Figure JPOXMLDOC01-appb-T000039
Figure JPOXMLDOC01-appb-T000039
Figure JPOXMLDOC01-appb-T000040
Figure JPOXMLDOC01-appb-T000040
Figure JPOXMLDOC01-appb-T000041
Figure JPOXMLDOC01-appb-T000041
　タバコ臭に対する消臭機能確認試験の結果を表１２～１４に示す。 Tables 12 to 14 show the results of the deodorant function confirmation test for tobacco odor.
Figure JPOXMLDOC01-appb-T000042
Figure JPOXMLDOC01-appb-T000042
Figure JPOXMLDOC01-appb-T000043
Figure JPOXMLDOC01-appb-T000043
Figure JPOXMLDOC01-appb-T000044
Figure JPOXMLDOC01-appb-T000044
　調理臭に対する消臭機能確認試験の結果を表１５～１７に示す。 Tables 15 to 17 show the results of the deodorant function confirmation test for cooking odors.
Figure JPOXMLDOC01-appb-T000045
Figure JPOXMLDOC01-appb-T000045
Figure JPOXMLDOC01-appb-T000046
Figure JPOXMLDOC01-appb-T000046
Figure JPOXMLDOC01-appb-T000047
Figure JPOXMLDOC01-appb-T000047
　消臭機能確認試験の結果、本発明の特徴構成を備えた衣料害虫防除組成物は、防虫成分としてエンペントリンを含有する実施例１～３２、及び防虫成分としてプロフルトリンを含有する実施例３３～５９の何れであっても、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭に対して、供試体の設置から２４時間後も優れた消臭性を示した。このことから、本発明の特徴構成を備えた衣料害虫防除組成物を、収納空間内に揮散させることで、収納中の衣類に対する消臭機能が２４時間程度持続し、収納空間から衣類を取り出す際に衣類に付着した悪臭により不快感が生じることを防ぐことができると考えられる。 As a result of the deodorant function confirmation test, the clothing pest control composition having the characteristic constitution of the present invention has the composition of Examples 1 to 32 containing enpentrin as an insect repellent and Examples 33 to 59 containing profluthrin as an insect repellent. In any case, excellent deodorizing properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor were exhibited 24 hours after the installation of the test sample. From this, when the clothing pest control composition having the characteristic configuration of the present invention is volatilized in the storage space, the deodorizing function for the stored clothes continues for about 24 hours, and when the clothes are taken out from the storage space. It is considered possible to prevent the unpleasant sensation caused by the bad smell attached to the clothes.
　一方、防虫成分を含有していない比較例１～２１の衣料害虫防除組成物は、防虫成分としてエンペントリンを含有する実施例１～３２、及び防虫成分としてプロフルトリンを含有する実施例３３～５９と、同一の香料成分を含有しているが、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても、供試体の設置から１時間後であっても臭気が感じられ、供試体の設置から２４時間後には消臭性を示さなかった。 On the other hand, the clothing pest control compositions of Comparative Examples 1 to 21 containing no insect repellent component are Examples 1 to 32 containing enpentrin as an insect repellent component and Examples 33 to 59 containing profluthrin as an insect repellent component. It contains the same fragrance ingredients, but feels an odor against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor even one hour after the installation of the sample. However, it did not show deodorant properties 24 hours after the installation of the test piece.
　比較例２２の衣料害虫防除組成物は、実施例１～３２と同様に防虫成分としてエンペントリンを含有しており、比較例２３の衣料害虫防除組成物は、実施例３３～５９と同様に防虫成分としてプロフルトリンを含有しているが、比較例２２及び２３は何れも香料成分を含有していない。このような比較例２２及び２３の衣料害虫防除組成物は、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても消臭性を示さなかった。このことから、防虫成分であるエンペントリン、及びプロフルトリンは単独では消臭性を有していないことが確認された。防虫成分であるエンペントリン、及びプロフルトリンが単独では消臭性を有していないにもかかわらず、比較例１～２１の衣料害虫防除組成物と比較して、これらに防虫成分を配合しただけの実施例１～５９の衣料害虫防除組成物において消臭機能が長時間持続したのは、防虫成分が本発明において規定する特定の香料成分と何らかの相乗効果を奏するためと考えられる。 The clothing pest control composition of Comparative Example 22 contains enpentrin as an insect control component as in Examples 1 to 32, and the clothing pest control composition of Comparative Example 23 is similar to Examples 33 to 59. However, Comparative Examples 22 and 23 do not contain a fragrance component. The clothing pest control compositions of Comparative Examples 22 and 23 did not show deodorant properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor. From this, it was confirmed that the insect repellents, empentryn and profluthrin, alone do not have deodorant properties. Despite the fact that the insect repellent components, empentryn and profluthrin, do not have deodorant properties by themselves, they are compared with the clothing pest control compositions of Comparative Examples 1 to 21 and only the insect repellent component is added to them. It is considered that the deodorizing function lasted for a long time in the clothing pest control compositions of Examples 1 to 59 because the insect repellent component has some synergistic effect with the specific flavor component defined in the present invention.
　また、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物を香料成分として使用した比較例２４～５６は、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても、供試体の設置から１時間後であっても臭気が感じられ、供試体の設置から２４時間後には消臭性を示さなかった。防虫成分としてエンペントリンを含有する場合（比較例２４～３４）、及び防虫成分としてプロフルトリンを含有する場合（比較例３５～４５）でも、消臭機能が長時間持続しなかったのは、本発明において規定する特定の香料成分を使用していないために、防虫成分と香料成分との相乗効果が得られなかったためと考えられる。 Further, Comparative Examples 24 to 56 in which a compound having an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure was used as a perfume component, were sweat odor, middle fat odor, and aging. With respect to all odors, tobacco odors, and cooking odors, an odor was felt even one hour after the installation of the test piece, and no deodorant property was exhibited 24 hours after the installation of the test piece. In the present invention, the deodorant function did not last for a long time even when it contained enpentrin as the insect repellent component (Comparative Examples 24-34) and when it contained profluthrin as the insect repellent component (Comparative Examples 35-45). It is considered that the synergistic effect between the insect repellent component and the fragrance component was not obtained because the specified specific fragrance component was not used.
　以上の結果から、本発明の特徴構成を備えた衣料害虫防除組成物（実施例１～５９）は、特定の防虫成分と特定の香料成分との組み合わせにより、防虫成分と香料成分との相乗効果が得られ、香料成分による消臭機能が長時間に亘って持続することが確認された。 From the above results, the clothing pest control compositions (Examples 1 to 59) having the characteristic constitution of the present invention, by the combination of the specific insect repellent component and the specific perfume component, the synergistic effect of the insect repellent component and the perfume component. It was confirmed that the deodorizing function of the fragrance component lasted for a long time.
　本発明の衣料害虫防除組成物、及び衣料消臭方法は、衣類に付着した悪臭を消臭するために使用されるものであり、繊維製品の消臭に利用可能である。さらに、本発明の衣料防虫消臭方法は、繊維製品に対する防虫及び消臭に利用可能である。 The clothing pest control composition and the clothing deodorizing method of the present invention are used for deodorizing a malodor adhering to clothing, and can be used for deodorizing a textile product. Furthermore, the clothing insect repellent and deodorant method of the present invention can be used for insect repellent and deodorant for textile products.

Claims (7)

  1. 　防虫成分と香料成分とを含有する衣料害虫防除組成物であって、
    　前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有し、
    　前記防虫成分は、前記香料成分の消臭機能を持続させる持続機能を有する衣料害虫防除組成物。     A clothing pest control composition comprising an insect repellent component and a fragrance component,
    The fragrance component has a deodorizing function of deodorizing a bad odor attached to clothing,
    The insect repellent composition is a clothes pest control composition having a sustaining function of sustaining the deodorizing function of the flavor component.
  2. 　前記防虫成分は、エンペントリン、及び／又はプロフルトリンであり、
    　前記香料成分は、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物である請求項１に記載の衣料害虫防除組成物。     The insect repellent component is empentrin, and / or profluthrin,
    The fragrance component does not have an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. The clothing pest control composition according to claim 1, which is a compound having a carbon atom, a hydrogen atom, and an oxygen atom and not having a sulfur atom, a nitrogen atom, and a halogen atom.
  3. 　前記香料成分は、シス－３－ヘキセノール、ジヒドロミルセノール、エチルリナロール、リナロール、ゲラニオール、テトラヒドロゲラニオール、テルピネオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、リナリルアセテート、ラズベリーケトン、ガラクソリド、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つである請求項１又は２に記載の衣料害虫防除組成物。 The perfume ingredients are cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lilial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicyt. Rate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brushlate, and at least one selected from the group consisting of cyclopentadecanolide, The clothing pest control composition according to claim 1 or 2.
  4. 　前記香料成分の含有量が１～２０質量％である請求項１～３の何れか一項に記載の衣料害虫防除組成物。 The clothing pest control composition according to any one of claims 1 to 3, wherein the content of the fragrance component is 1 to 20% by mass.
  5. 　前記香料成分（ａ）と前記防虫成分（ｂ）との配合比（ａ／ｂ）が、重量比として、０．１～２．０である請求項１～４の何れか一項に記載の衣料害虫防除組成物。 5. The blending ratio (a / b) of the fragrance component (a) and the insect repellent component (b) is 0.1 to 2.0 in terms of weight ratio, according to any one of claims 1 to 4. Clothing pest control composition.
  6. 　請求項１～５の何れか一項に記載の衣料害虫防除組成物を用いた衣料消臭方法であって、
    　前記衣料害虫防除組成物を含浸させた担体を衣料の収納空間に設置し、前記担体から前記衣料害虫防除組成物を揮散させる衣料消臭方法。     A method for deodorizing clothing, which comprises using the composition for controlling insect pests of clothing according to any one of claims 1 to 5,
    A clothing deodorizing method, wherein a carrier impregnated with the clothing pest control composition is placed in a clothing storage space, and the clothing pest control composition is volatilized from the carrier.
  7. 　衣料に対して防虫処理と消臭処理とを同時に行う衣料防虫消臭方法であって、
    　収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納する収納工程と、
    　前記衣料に十分な防虫効果及び消臭効果が付与されるように、前記収納空間内に前記衣料害虫防除組成物を揮散させる揮散工程と、
    を包含する衣料防虫消臭方法。     A method of deodorizing clothing by performing insect repellent treatment and deodorant treatment on clothing at the same time,
    A storage step of storing the clothing to be treated in the storage space together with a clothing pest control composition containing an insect repellent component and a fragrance component,
    A volatilization step of volatilizing the clothing pest control composition in the storage space so that the clothing is provided with a sufficient insect-controlling effect and deodorizing effect,
    A method for deodorizing clothing and insects including.
PCT/JP2019/042763 2018-11-06 2019-10-31 Clothing pest control composition, and method for deodorizing clothing and method for preventing pests in and deodorizing clothing using said composition WO2020095809A1 (en)

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Publication number Priority date Publication date Assignee Title
JPH107511A (en) * 1996-04-22 1998-01-13 Dainippon Jochugiku Co Ltd Insect-proofing/mildew-proofing agent
JPH11209207A (en) * 1998-01-27 1999-08-03 Fumakilla Ltd Insecticidal deodorant agent for clothes
JP2001095906A (en) * 1999-09-30 2001-04-10 Kao Corp Deodorizer for spray
JP2007031605A (en) * 2005-07-28 2007-02-08 Kao Corp Perfume composition
JP3168739U (en) * 2011-01-24 2011-06-30 株式会社ゼックフィールド Antibacterial, insect repellent and deodorant for terpene fir tree essential oil components in containers with fog generator
JP2013014574A (en) * 2011-06-07 2013-01-24 Dainippon Jochugiku Co Ltd Insect repellent for clothing
JP2015105245A (en) * 2013-11-29 2015-06-08 白元アース株式会社 Insect-repelling deodorizer

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH107511A (en) * 1996-04-22 1998-01-13 Dainippon Jochugiku Co Ltd Insect-proofing/mildew-proofing agent
JPH11209207A (en) * 1998-01-27 1999-08-03 Fumakilla Ltd Insecticidal deodorant agent for clothes
JP2001095906A (en) * 1999-09-30 2001-04-10 Kao Corp Deodorizer for spray
JP2007031605A (en) * 2005-07-28 2007-02-08 Kao Corp Perfume composition
JP3168739U (en) * 2011-01-24 2011-06-30 株式会社ゼックフィールド Antibacterial, insect repellent and deodorant for terpene fir tree essential oil components in containers with fog generator
JP2013014574A (en) * 2011-06-07 2013-01-24 Dainippon Jochugiku Co Ltd Insect repellent for clothing
JP2015105245A (en) * 2013-11-29 2015-06-08 白元アース株式会社 Insect-repelling deodorizer

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