JP7109578B2 - Clothing pest control composition, and clothing deodorizing method and clothing insect repellent and deodorizing method using the composition - Google Patents
Clothing pest control composition, and clothing deodorizing method and clothing insect repellent and deodorizing method using the composition Download PDFInfo
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- JP7109578B2 JP7109578B2 JP2020556017A JP2020556017A JP7109578B2 JP 7109578 B2 JP7109578 B2 JP 7109578B2 JP 2020556017 A JP2020556017 A JP 2020556017A JP 2020556017 A JP2020556017 A JP 2020556017A JP 7109578 B2 JP7109578 B2 JP 7109578B2
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- insect repellent
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
- A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/12—Apparatus, e.g. holders, therefor
Description
本発明は、防虫成分と香料成分とを含有する衣料害虫防除組成物、及び当該組成物を用いた衣料消臭方法に関する。さらに、本発明は、衣料に対して防虫処理と消臭処理とを同時に行う衣料防虫消臭方法に関する。 TECHNICAL FIELD The present invention relates to a clothing pest control composition containing an insect repellent component and a fragrance component, and a method for deodorizing clothing using the composition. Furthermore, the present invention relates to an insect repellent and deodorant method for clothing in which insect repellent treatment and deodorant treatment are simultaneously performed on clothing.
衣料害虫から繊維製品を保護するため、様々な衣料害虫防除製品が開発され、実用化されている。例えば、常温揮散性を有するピレスロイド系防虫成分に代えて、香料成分を有効成分とする衣料害虫防除製品が知られている（例えば、特許文献１を参照）。 Various clothing pest control products have been developed and put into practical use to protect textile products from clothing pests. For example, instead of a pyrethroid-based insect repellent component having room temperature volatility, there is known a clothing pest control product containing a fragrance component as an active ingredient (see, for example, Patent Document 1).
特許文献１の衣料害虫防除製品は、酢酸エステル化合物、アリルエステル化合物等の香料成分を吸水性ポリマーに保持させたものであり、長期に亘って有効成分の揮散性を維持することで、タンス、引き出し、クローゼット、衣料収納箱等の収納空間で衣料害虫の幼虫を致死させ、優れた摂食阻害効果を発揮することができる。 The clothing pest control product of Patent Document 1 is obtained by retaining perfume ingredients such as acetate ester compounds and allyl ester compounds in a water-absorbing polymer, and by maintaining the volatility of the active ingredients over a long period of time, It can kill larvae of clothing pests in storage spaces such as drawers, closets, clothing storage boxes, etc., and exhibit an excellent antifeeding effect.
衣類は、着用中に汗臭、加齢臭、タバコ臭等の生活臭が付着することがある。そのため、衣類の管理では、衣料害虫の防除に加えて、衣類に付着する悪臭を消臭することが望まれる。例えば、外衣等は、連日使用することが多いため、クローゼット等の収納空間から取り出す際に、前日に衣類に付着した生活臭が不快感をもたらす虞があり、収納中に悪臭を持続的に消臭できることが望まれる。 Clothing may be contaminated with daily odors such as sweat odor, aging odor, and cigarette odor while being worn. Therefore, in the management of clothes, it is desired to deodorize offensive odors adhering to clothes, in addition to controlling pests on clothes. For example, outer clothes are often used every day, so when taking them out of a storage space such as a closet, there is a risk that the daily odors that have adhered to the clothes the day before may cause discomfort. It is desired to be able to smell.
特許文献１の衣料害虫防除製品は、香料成分を有効成分としていることで消臭機能が期待されるが、衣料害虫に対する防虫機能を主眼として香料成分となる化合物が選択されており、衣類特有の悪臭に対する消臭機能については、検討の余地がある。 The clothing pest control product of Patent Document 1 is expected to have a deodorizing function because it contains a fragrance component as an active ingredient. There is room for further study on the deodorizing function against bad odors.
本発明は、上記問題点に鑑みてなされたものであり、防虫機能を果たすとともに衣類に付着する悪臭を持続的に消臭可能な衣料害虫防除組成物、及び当該組成物を用いた衣料消臭方法を提供することを目的とする。さらに、本発明は、一回の処理で衣料に防虫効果と持続的な消臭効果とを同時に付与可能な衣料防虫消臭方法を提供することを目的とする。 The present invention has been made in view of the above-mentioned problems, and provides a clothing pest control composition that functions as an insect repellent and is capable of continuously deodorizing offensive odors adhering to clothing, and clothing deodorization using the composition. The purpose is to provide a method. A further object of the present invention is to provide an insect repellent and deodorant method for clothing that can simultaneously impart an insect repellent effect and a sustained deodorant effect to clothing in a single treatment.
上記課題を解決するための本発明に係る衣料害虫防除組成物の特徴構成は、
防虫成分と香料成分とを含有する衣料害虫防除組成物であって、
前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有し、
前記防虫成分は、前記香料成分の消臭機能を持続させる持続機能を有することにある。The characteristic configuration of the clothing pest control composition according to the present invention for solving the above problems is
A clothing pest control composition containing an insect repellent component and a fragrance component,
The perfume component has a deodorant function to deodorize bad odors attached to clothes,
The insect repellent component has a function of sustaining the deodorizing function of the perfume component.
本構成の衣料害虫防除組成物は、本発明者らが、様々な衣料害虫防除組成物を調製して種々試験を繰り返す中で、特定の防虫成分が香料成分の消臭機能を持続させる持続機能を有することを新たに見出したことにより、完成するに至ったものである。本構成の衣料害虫防除組成物によれば、香料成分が衣料に付着した悪臭を消臭する消臭機能を有し、防虫成分が香料成分の消臭機能を持続させる持続機能を有することにより、防虫成分が衣料害虫に対する防虫機能を果たすととともに、香料成分による消臭機能を長期に亘って持続させて衣類に付着する悪臭を持続的に消臭することができる。そのため、本発明の衣料害虫防除組成物を衣類の収納空間に処理しておくことで、収納中に香料成分による消臭機能が持続し、収納空間から衣類を取り出す際に不快感が生じることを防ぐことができる。 The clothing pest control composition of this configuration has a sustained function that the specific insect repellent component maintains the deodorant function of the fragrance component while the present inventors have prepared various clothing pest control compositions and repeated various tests. It has been completed by newly discovering that it has According to the clothing pest control composition of this configuration, the fragrance component has a deodorizing function of deodorizing offensive odors adhering to clothing, and the insect repellent component has a sustaining function of sustaining the deodorizing function of the fragrance component, The insect repellent component fulfills an insect repellent function against clothing insect pests, and the deodorizing function of the fragrance component can be maintained over a long period of time to continuously deodorize odors adhering to clothing. Therefore, by treating the storage space of clothes with the pest control composition for clothes of the present invention, the deodorizing function of the perfume component is maintained during storage, and discomfort is caused when the clothes are taken out of the storage space. can be prevented.
本発明に係る衣料害虫防除組成物において、
前記防虫成分は、エンペントリン、及び／又はプロフルトリンであり、
前記香料成分は、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物であることが好ましい。In the clothing pest control composition according to the present invention,
The insect repellent component is empentrin and/or profluthrin,
The perfume component does not have an electron conjugated portion other than an electron conjugated portion derived from a benzene ring, a benzoate structure, or a salicylate structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. Compounds having carbon, hydrogen and oxygen atoms and no sulfur, nitrogen and halogen atoms are preferred.
本構成の衣料害虫防除組成物によれば、上記の特定の防虫成分と香料成分とを組み合わせることによって、防虫成分と香料成分との相乗効果により、香料成分による消臭機能を長期に亘って持続させることができる。 According to the clothing pest control composition of this configuration, by combining the specific insect repellent component and the fragrance component, the synergistic effect of the insect repellent component and the fragrance component allows the deodorizing function of the fragrance component to be maintained for a long period of time. can be made
本発明に係る衣料害虫防除組成物において、
前記香料成分は、シス－３－ヘキセノール、ジヒドロミルセノール、エチルリナロール、リナロール 、ゲラニオール、テトラヒドロゲラニオール、テルピネオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、リナリルアセテート、ラズベリーケトン、ガラクソリド、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つであることが好ましい。In the clothing pest control composition according to the present invention,
The perfume ingredients include cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lyrial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicylate. preferably at least one selected from the group consisting of laxate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brassylate, and cyclopentadecanolide.
本構成の衣料害虫防除組成物によれば、上記の香料成分を含有することにより、防虫成分と香料成分との相乗効果が大きくなり、消臭機能の持続性を向上させることができる。 According to the clothing insect pest control composition of this configuration, the synergistic effect between the insect repellent component and the fragrance component can be enhanced by containing the above perfume component, and the sustainability of the deodorizing function can be improved.
本発明に係る衣料害虫防除組成物において、
前記香料成分の含有量が１～２０質量％であることが好ましい。In the clothing pest control composition according to the present invention,
It is preferable that the content of the perfume component is 1 to 20% by mass.
本構成の衣料害虫防除組成物によれば、香料成分の含有量が適切な範囲にあるため、例えば、衣料害虫防除組成物を含浸させた担体を衣類の収納空間に設置し、収納空間内に衣料害虫防除組成物を揮散させた場合に、衣類に付着する悪臭を芳香によってマスクして、十分な消臭性を得ることができる。 According to the clothing pest control composition of this configuration, since the content of the fragrance component is within an appropriate range, for example, the carrier impregnated with the clothing pest control composition is placed in the storage space of the clothing, and the carrier is placed in the storage space. When the clothing pest control composition is volatilized, it is possible to mask offensive odors adhering to clothing with the fragrance and obtain sufficient deodorizing properties.
本発明に係る衣料害虫防除組成物において、
前記香料成分（ａ）と前記防虫成分（ｂ）との配合比（ａ／ｂ）が、重量比として、０．１～２．０であることが好ましい。In the clothing pest control composition according to the present invention,
The blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is preferably 0.1 to 2.0 as a weight ratio.
本構成の衣料害虫防除組成物によれば、配合比が適切な範囲にあるため、防虫成分による衣料害虫に対する防虫機能を十分に発揮しつつ、防虫成分と香料成分との相乗効果を十分に発揮することができ、香料成分による消臭機能を長期に亘って持続させることができる。 According to the clothing pest control composition of this configuration, since the compounding ratio is within an appropriate range, the insect repellent component sufficiently exerts the insect repellent function against clothing pests, while sufficiently exhibiting the synergistic effect of the insect repellent component and the fragrance component. It is possible to maintain the deodorizing function of the perfume component for a long period of time.
上記課題を解決するための本発明に係る衣料消臭方法の特徴構成は、
前記の何れか一つに記載の衣料害虫防除組成物を用いた衣料消臭方法であって、
前記衣料害虫防除組成物を含浸させた担体を衣料の収納空間に設置し、前記担体から前記衣料害虫防除組成物を揮散させることにある。The characteristic configuration of the clothes deodorizing method according to the present invention for solving the above problems is as follows:
A method for deodorizing clothing using the clothing pest control composition according to any one of the above,
The carrier impregnated with the pest-controlling composition for clothing is placed in a storage space for clothing, and the pest-controlling composition for clothing is volatilized from the carrier.
本構成の衣料消臭方法によれば、前記の何れか一つに記載の衣料害虫防除組成物を収納空間において揮散させることで、防虫成分による防虫機能が得られるととともに、防虫成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続する。そのため、本発明の衣料消臭方法を実施することで、収納中に香料成分による消臭機能が持続し、収納空間から衣類を取り出す際に不快感が生じることを防ぐことができる。 According to the clothes deodorizing method of this configuration, by volatilizing the clothing pest control composition according to any one of the above in the storage space, an insect repellent function is obtained by the insect repellent component, and the insect repellent component and the fragrance component are obtained. Due to the synergistic effect with, the deodorizing function of the perfume ingredient lasts for a long time. Therefore, by carrying out the clothes deodorizing method of the present invention, the deodorizing function of the perfume component can be maintained during storage, and discomfort can be prevented when taking out the clothes from the storage space.
上記課題を解決するための本発明に係る衣料防虫消臭方法の特徴構成は、
衣料に対して防虫処理と消臭処理とを同時に行う衣料防虫消臭方法であって、
収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納する収納工程と、
前記衣料に十分な防虫効果及び消臭効果が付与されるように、前記収納空間内に前記衣料害虫防除組成物を揮散させる揮散工程と、
を包含することにある。The characteristic configuration of the clothing insect repellent deodorant method according to the present invention for solving the above problems is as follows:
A clothing insect repellent and deodorant method for performing insect repellent treatment and deodorant treatment on clothing at the same time,
a storage step of storing the clothing to be treated in the storage space together with the clothing pest control composition containing an insect repellent component and a fragrance component;
a volatilization step of volatilizing the clothing pest control composition in the storage space so as to impart sufficient insect repellent effect and deodorant effect to the clothing;
to include
本構成の衣料防虫消臭方法によれば、収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納し、さらに、衣料に十分な防虫効果及び消臭効果が付与されるように、収納空間内に衣料害虫防除組成物を揮散させることで、一回の処理で衣料に防虫効果と持続的な消臭効果とを同時に付与することができる。そして、本発明の衣料防虫消臭方法によって処理された衣料は、防虫成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続するため、例えば、一日中外出するような場合であっても、不快な害虫が寄り付かず、かつ臭いも気にならずに長時間快適に活動することができる。 According to the clothing insect repellent and deodorant method of this configuration, the clothing to be treated is stored in the storage space together with the clothing pest control composition containing the insect repellent component and the fragrance component, and furthermore, the clothing has sufficient insect repellent effect and deodorant. By volatilizing the clothing pest control composition in the storage space so that the effect is imparted, the insect repellent effect and the continuous deodorant effect can be imparted to the clothing at the same time with a single treatment. In addition, the clothes treated by the insect repellent and deodorizing method for clothes of the present invention maintain the deodorizing function of the perfume component for a long period of time due to the synergistic effect of the insect repellent component and the perfume component. Even in such a case, it is possible to comfortably work for a long time without being disturbed by unpleasant pests and without worrying about odors.
以下、本発明の衣料害虫防除組成物、及び衣料消臭方法について説明する。ただし、本発明は、以下に説明する実施形態に記載される構成に限定されることを意図しない。 The pest control composition for clothing and the deodorizing method for clothing of the present invention are described below. However, the present invention is not intended to be limited to the configurations described in the embodiments described below.
＜衣料害虫防除組成物＞
本発明の衣料害虫防除組成物は、衣料に付着した悪臭を消臭する消臭機能を有する香料成分と、防虫機能に加えて香料成分の消臭機能を持続させる持続機能を有する防虫成分とを含有する。<Clothing pest control composition>
The clothing pest control composition of the present invention comprises a fragrance component having a deodorizing function of deodorizing offensive odors adhering to clothing, and an insect repellent component having a sustaining function of maintaining the deodorizing function of the fragrance component in addition to the insect repellent function. contains.
本発明の衣料害虫防除組成物の主成分の一つである防虫成分としては、香料成分の消臭機能を持続させる持続機能を有するものが使用される。具体的には、エンペントリン、プロフルトリン、及びｐ－メンタン－３，８－ジオール等が挙げられ、好ましい防虫成分は、エンペントリン、及び／又はプロフルトリンである。なお、以降の説明では、好ましい防虫成分であるエンペントリン、及びプロフルトリンを使用した実施形態について述べる。エンペントリン、及びプロフルトリンは、常温揮散性を有するピレスロイド系防虫成分であり、衣料害虫であるイガ、コイガ、ヒメカツオブシムシ、ヒメマルカツオブシムシやシミ類に対して、特にイガ、又はコイガの幼虫に対して高い防除効果を有する。このように、エンペントリン、及びプロフルトリンは、従来は防虫剤として使用されていたが、本発明者らが、エンペントリン、及びプロフルトリンを含有する様々な衣料害虫防除組成物を調製する中で、エンペントリン、及びプロフルトリンが、後述する特定の香料成分の消臭機能を持続させる持続機能を有することを新たに見出した。本発明の衣料害虫防除組成物は、衣料害虫防除組成物を含浸させた担持体を衣類の収納空間へ設置することで、収納空間内に防虫成分を揮散させて衣料害虫を防除しつつ、収納中の衣類に付着した悪臭の消臭を長期に亘って持続させることができる。衣料害虫防除組成物中の防虫成分の含有量は、１０～８０質量％であることが好ましい。このような範囲であれば、衣料害虫防除組成物を含浸させた担持体を収納空間内に設置することで、衣料害虫に対する防虫効果を発揮しつつ、後述する特定の香料成分との相乗効果を奏して、消臭機能の持続性を向上することができる。防虫成分の含有量が１０質量％未満である場合、衣料害虫に対する防虫効果や、香料成分との相乗効果による消臭機能の持続性が不十分となる虞がある。防虫成分の含有量が８０質量％を超える場合、実用上必要な防虫効果が得られる量を超えて防虫成分を配合することになり、経済的に不利である。 As the insect repellent component, which is one of the main components of the pest control composition for clothing of the present invention, one having a sustaining function of sustaining the deodorizing function of the perfume component is used. Specific examples include empenthrin, profluthrin, p-menthane-3,8-diol, etc. Empenthrin and/or profluthrin are preferred insect repellent ingredients. In the following description, an embodiment using empentrin and profluthrin, which are preferred insect repellent ingredients, will be described. Empentrin and profluthrin are pyrethroid-based insect repellent components that evaporate at room temperature, and are highly effective against clothing pests such as burrs, Japanese squirrel moths, scaly beetles, scaly beetles, and stains, especially against squirrel larvae or scorpion moth larvae. have an effect. Thus, empentrin and profluthrin have traditionally been used as insect repellents, but in preparing various clothing pest control compositions containing empentrin and profluthrin, the present inventors found that empentrin and profluthrin It was newly discovered that profluthrin has a sustaining function that sustains the deodorant function of a specific perfume ingredient described later. The pest control composition for clothing of the present invention can be stored while preventing pests from clothing by volatilizing the insect repellent component in the storage space of the clothing by placing the carrier impregnated with the pest control composition for clothing in the storage space of the clothing. It is possible to maintain the deodorization of bad odors adhering to clothes inside for a long period of time. The content of the insect repellent component in the clothing pest control composition is preferably 10 to 80% by mass. Within such a range, by installing the support impregnated with the clothing pest control composition in the storage space, the synergistic effect with the specific fragrance component described later can be achieved while exhibiting the insect repellent effect against clothing pests. As a result, the durability of the deodorizing function can be improved. If the content of the insect repellent component is less than 10% by mass, there is a possibility that the insect repellent effect against clothing pests and the sustainability of the deodorant function due to the synergistic effect with the perfume component may be insufficient. If the content of the insect repellent component exceeds 80% by mass, the amount of the insect repellent component exceeds the practically necessary insect repellent effect, which is economically disadvantageous.
本発明の衣料害虫防除組成物の主成分の一つである香料成分としては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物が使用される。このような化合物は、衣類に付着した悪臭（汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭）を芳香によってマスクする優れた消臭機能を有するとともに、本発明において防虫成分として使用されるエンペントリン、及びプロフルトリンとの相乗効果により、その消臭機能を長時間に亘って持続させることができる。このような化合物としては、下記式（１）： The perfume component, which is one of the main components of the clothing pest control composition of the present invention, does not have an electronic conjugated moiety other than an electron conjugated moiety derived from a benzene ring, a benzoate structure, or a salicylate structure, and has a carbon A compound having a number of 6 to 18, a molecular weight of 98 to 270, having carbon, hydrogen and oxygen atoms and no sulfur, nitrogen and halogen atoms is used. Such a compound has an excellent deodorizing function of masking bad odors (sweat odor, middle-aged oily odor, aging odor, cigarette odor, and cooking odor) adhering to clothes with fragrance, and is used as an insect repellent component in the present invention. Due to the synergistic effect of empentrin and profluthrin used, the deodorizing function can be maintained for a long time. Such compounds include the following formula (1):
上記の化合物Ａ～Ｓは、単独で使用してもよいし、複数種を組み合わせて使用してもよい。香料成分の含有量は、１～２０質量％が好ましい。香料成分の含有量がこのような範囲であれば、例えば、本発明の衣料害虫防除組成物を含浸させた担体を衣類の収納空間に設置し、或いは本発明の衣料害虫防除組成物を含むエアゾール等の噴射製品を衣類の収納空間内に直接噴射し、収納空間内に衣料害虫防除組成物を揮散させた場合に、収容中の衣類に付着した悪臭をマスクして、十分な消臭性を得ることができる。香料成分の含有量が１質量％未満である場合、収納空間内に衣料害虫防除組成物を揮散させた場合の消臭性が不足する虞がある。香料成分の含有量が２０質量％を超える場合、衣料害虫防除組成物がべたつき易くなる。 The above compounds A to S may be used alone, or may be used in combination. The content of the perfume component is preferably 1 to 20% by mass. If the content of the perfume component is within such a range, for example, a carrier impregnated with the clothing pest control composition of the present invention is placed in the storage space of clothing, or an aerosol containing the clothing pest control composition of the present invention is used. When the spray product such as is directly sprayed into the clothing storage space and the clothing pest control composition is volatilized in the storage space, the bad odor attached to the clothing during storage is masked and sufficient deodorization is achieved. Obtainable. If the content of the perfume component is less than 1% by mass, the deodorizing property may be insufficient when the pest control composition for clothing is volatilized in the storage space. If the content of the perfume component exceeds 20% by mass, the pest control composition for clothing tends to be sticky.
本発明の衣料害虫防除組成物において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．１～２．０に調整することが好ましい。配合比（ａ／ｂ）がこのような範囲であれば、防虫成分と香料成分との相乗効果が大きくなり、香料成分による消臭機能が長期に亘って持続する。配合比（ａ／ｂ）が０．１未満である場合、及び配合比（ａ／ｂ）が２．０を超える場合、防虫成分と香料成分との相乗効果を十分に発揮することができない虞がある。 In the clothing pest control composition of the present invention, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is preferably adjusted to 0.1 to 2.0 as a weight ratio. If the compounding ratio (a/b) is within such a range, the synergistic effect of the insect repellent component and the perfume component is enhanced, and the deodorizing function of the perfume component is maintained over a long period of time. When the compounding ratio (a/b) is less than 0.1 and when the compounding ratio (a/b) exceeds 2.0, there is a possibility that the synergistic effect of the insect repellent component and the fragrance component cannot be sufficiently exhibited. There is
本発明の衣料害虫防除組成物は、上記成分に加え、カビ類や菌類等を対象とした防カビ剤、抗菌剤、殺菌剤、酸化防止剤等を適宜配合することもできる。防カビ剤、抗菌剤、及び殺菌剤としては、ヒノキチオール、２－メルカプトベンゾチアゾール、２－（４－チアゾリル）ベンツイミダゾール、５－クロロ－２－メチル－４－イソチアゾリン－３－オン、トリホリン、３－メチル－４－イソプロピルフェノール、オルト－フェニルフェノール等が挙げられる。 In addition to the above components, the clothing pest control composition of the present invention can also contain, as appropriate, antifungal agents, antibacterial agents, bactericides, antioxidants, and the like, which target molds and fungi. Antifungal agents, antibacterial agents, and fungicides include hinokitiol, 2-mercaptobenzothiazole, 2-(4-thiazolyl)benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, trifoline, 3 -methyl-4-isopropylphenol, ortho-phenylphenol and the like.
本発明の衣料害虫防除組成物は、上掲の各成分を適切な重量比で配合し、さらに溶剤を添加して各成分の濃度が適切となるように調整される。溶剤としては、ノルマルパラフィン系炭化水素、イソパラフィン系炭化水素、炭素数が２～３の低級アルコール、炭素数の総数が１６～２０の高級脂肪酸エステル等の使用が好ましい。 The pest control composition for clothing of the present invention is prepared by blending each of the above components in an appropriate weight ratio, and further adding a solvent to adjust the concentration of each component to an appropriate level. As the solvent, it is preferable to use normal paraffinic hydrocarbons, isoparaffinic hydrocarbons, lower alcohols having 2 to 3 carbon atoms, higher fatty acid esters having 16 to 20 carbon atoms in total, and the like.
＜衣料害虫防除製品＞
本発明の衣料害虫防除組成物の好ましい製品形態は、衣料害虫防除組成物を含浸させた固形担体を、通気性ケース等の容器に収容した衣料害虫防除製品である。固形担体としては、繊維質担体（パルプ、リンター、レーヨン等）、セルロール又は再生セルロール製のビーズ及び発泡体、無機多孔質担体（ケイ酸塩、シリカ、ゼオライト等）、昇華性担体（トリオキサン、アダマンタン等）が挙げられる。繊維質担体を使用する場合、厚さ１～３ｍｍ程度のマット状又はシート状のものが好ましい。また、別の衣料害虫防除組成物の製品形態として、ハンドスプレーやエアゾール等の噴射製品を採用することも可能である。特に、定量噴射バルブを備えたエアゾール容器に本発明の衣料害虫防除組成物と噴射剤とを封入したエアゾール製品が使い勝手が良い。噴射剤としては、液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等を使用することができる。液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等が挙げられる。液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等が挙げられる。液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素、圧縮空気等が挙げられる。<Clothing pest control products>
A preferred product form of the clothing pest control composition of the present invention is a clothing pest control product in which a solid carrier impregnated with the clothing pest control composition is housed in a container such as a breathable case. Examples of solid carriers include fibrous carriers (pulp, linter, rayon, etc.), beads and foams made of cellulose or regenerated cellulose, inorganic porous carriers (silicate, silica, zeolite, etc.), sublimable carriers (trioxane, adamantane, etc.). etc.). When a fibrous carrier is used, a mat-like or sheet-like carrier having a thickness of about 1 to 3 mm is preferable. In addition, as another product form of the pest control composition for clothing, it is also possible to adopt a spray product such as a hand spray or an aerosol. In particular, an aerosol product in which the clothing pest control composition of the present invention and a propellant are sealed in an aerosol container equipped with a metered injection valve is convenient to use. As the propellant, liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air and the like can be used. Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air, and the like. Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air, and the like. Liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide, compressed air, and the like.
＜衣料消臭方法＞
本発明の衣料消臭方法の好ましい態様は、本発明の衣料害虫防除組成物を含浸させた担体を衣料の収納空間に設置し、担体から衣料害虫防除組成物を揮散させるものであり、例えば、上述の衣料害虫防除製品を含浸させた固形担体を用いて実施することができる。また、本発明の衣料消臭方法の別の態様は、本発明の衣料害虫防除組成物を衣料の収納空間に直接付与して揮散させるものであり、例えば、上述のエアゾール製品を用いて実施することができる。具体的には、衣料害虫防除製品が固形担体である場合、この固形担体をクローゼット等の衣類の収納空間に設置する。収容空間内に設置した固形担体から本発明の衣料害虫防除組成物が揮散することで、収容中の衣類には優れた防虫機能、及び持続的な消臭機能が付与される。衣料害虫防除製品がエアゾール製品である場合、クローゼット等の衣類の収納空間内に衣料害虫防除組成物を直接噴射する。その後、直ちに収納空間を閉鎖すると、衣料害虫防除組成物が収容空間内に揮散して充満し、収容中の衣類には優れた防虫機能、及び持続的な消臭機能が付与される。このように、本発明の衣料消臭方法によれば、収容空間において衣料害虫を防除しつつ、収容中の衣類に付着した悪臭を消臭することができる。<Clothing deodorant method>
A preferred embodiment of the method for deodorizing clothes of the present invention is to install a carrier impregnated with the pest control composition for clothes of the present invention in a storage space of clothes, and volatilize the pest control composition for clothes from the carrier. It can be carried out using a solid carrier impregnated with the textile pest control product described above. In another aspect of the method for deodorizing clothes of the present invention, the pest control composition for clothes of the present invention is applied directly to the storage space of clothes and volatilized, for example, using the above-mentioned aerosol product. be able to. Specifically, when the clothing pest control product is a solid carrier, the solid carrier is placed in a clothing storage space such as a closet. The volatilization of the pest control composition for clothing of the present invention from the solid carrier placed in the accommodation space imparts excellent insect repellency and long-lasting deodorizing function to the clothes being accommodated. When the clothing pest control product is an aerosol product, the clothing pest control composition is sprayed directly into the clothing storage space, such as a closet. Immediately after that, when the storage space is closed, the pest control composition for clothing volatilizes and fills the storage space, thereby imparting an excellent insect repellent function and a continuous deodorizing function to the stored clothing. As described above, according to the clothes deodorizing method of the present invention, it is possible to deodorize bad odors adhering to the clothes being accommodated while controlling the clothes pests in the accommodation space.
＜衣料防虫消臭方法＞
本発明の衣料防虫消臭方法は、収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫防除組成物とともに収納する収納工程と、衣料に十分な防虫効果及び消臭効果が付与されるように、収納空間内に衣料害虫防除組成物を揮散させる揮散工程とを実行するものである。本発明の衣料防虫消臭方法は、基本的な工程（操作）は上述の衣料消臭方法と同様であるが、揮散工程において、衣料に十分な防虫効果及び消臭効果が付与されるように、例えば、収納空間を閉鎖した状態で衣料害虫防除組成物を一日以上揮散させればよい。その際、例えば、衣料のうち特に臭いが気になる箇所（例えば、脇下、首回り、脚周辺部など）を裏返しにするなどして露出させることで、念入りに揮散処理を行うことで、衣料に効果的な防虫効果と持続的な消臭効果とを同時に付与することができる。このように、本発明の衣料防虫消臭方法を実施すれば、一回の処理で衣料に防虫効果と持続的な消臭効果とを同時に付与することができる。そして、本発明の衣料防虫消臭方法によって処理された衣料は、後述する防虫成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続するため、例えば、一日中外出するような場合であっても、不快な害虫が寄り付かず、かつ臭いも気にならずに長時間快適に活動することができる。<Clothing insect repellent deodorizing method>
The insect repellent and deodorant method for clothing of the present invention includes a storage step of storing the clothing to be treated in a storage space together with a clothing pest control composition containing an insect repellent component and a fragrance component, and a sufficient insect repellent effect and deodorant effect on the clothing. and a volatilization step of volatilizing the clothing pest control composition in the storage space so that the is imparted. The basic steps (operations) of the clothing insect repellent and deodorizing method of the present invention are the same as those of the clothing deodorizing method described above, but in the volatilization step, the clothing is provided with sufficient insect repellent and deodorizing effects. For example, the clothing pest control composition may be volatilized for one day or longer with the storage space closed. At that time, for example, the part of the clothing where the smell is particularly worrisome (for example, the armpit, neck, leg area, etc.) is turned inside out to expose it, and by carefully volatilizing it, An effective insect repellent effect and a sustained deodorizing effect can be imparted to clothing at the same time. As described above, by carrying out the insect repellent and deodorizing method for clothes of the present invention, it is possible to simultaneously impart an insect repellent effect and a continuous deodorant effect to the clothes in a single treatment. In addition, the clothes treated by the insect repellent and deodorizing method for clothes of the present invention maintain the deodorizing function of the perfume component for a long period of time due to the synergistic effect of the insect repellent component and the perfume component, which will be described later. Even in such a case, it is possible to comfortably work for a long time without being disturbed by unpleasant pests and odors.
本発明に係る衣料害虫防除組成物は、防虫成分に特定の香料成分を組み合わせることによって、防虫成分と香料成分との相乗効果により、香料成分による消臭機能を長期に亘って持続させることができる。消臭機能の持続期間は、防虫成分と香料成分との組み合わせ、両成分の配合割合、衣料害虫防除組成物の使用条件等により異なるが、おおよそ一日程度、消臭機能を持続させることは十分に可能である。このため、この衣料害虫防除組成物を用いて実行される本発明の衣料消臭方法に従って、衣料害虫防除組成物を収納空間内に揮散させれば、例えば、２４時間程度衣類を収納する場合に、収納中の衣類に対する消臭機能が持続し、収納空間から衣類を取り出す際に衣類に付着した悪臭により不快感が生じることを防ぐことができる。 The pest control composition for clothing according to the present invention can maintain the deodorizing function of the fragrance component for a long period of time by combining the insect repellent component with the specific fragrance component due to the synergistic effect of the insect repellent component and the fragrance component. . The duration of the deodorizing function varies depending on the combination of the insect repellent component and the fragrance component, the mixing ratio of both components, the usage conditions of the clothing pest control composition, etc., but it is sufficient to maintain the deodorizing function for about one day. is possible. Therefore, if the clothing pest control composition is volatilized in the storage space according to the clothing deodorization method of the present invention that is carried out using this clothing pest control composition, for example, when the clothing is stored for about 24 hours. , the deodorizing function for the clothes being stored is maintained, and when the clothes are taken out from the storage space, it is possible to prevent unpleasant feeling due to the foul odor adhering to the clothes.
本発明の衣料害虫防除組成物について、消臭機能の持続性を確認するため、本発明の特徴構成を備えた衣料害虫防除組成物（実施例１～５９）を準備し、消臭機能確認試験を実施した。また、比較のため、本発明の特徴構成を備えていない衣料害虫防除組成物（比較例１～５６）を準備し、同様の消臭機能確認試験を実施した。なお、実施例１～５９、及び比較例１～５６では重量の単位として「ｇ」が示されているが、任意の倍率でスケールアップが可能である。すなわち、単位「ｇ」は、「重量部」と読み替えることができる。 In order to confirm the durability of the deodorizing function of the clothing pest control composition of the present invention, clothing pest control compositions (Examples 1 to 59) having the characteristic configuration of the present invention were prepared, and the deodorant function confirmation test was performed. carried out. In addition, for comparison, clothing pest control compositions (Comparative Examples 1 to 56) not having the features of the present invention were prepared, and similar deodorizing function confirmation tests were conducted. In Examples 1 to 59 and Comparative Examples 1 to 56, "g" is shown as the unit of weight, but scale-up is possible at any scale. That is, the unit "g" can be read as "parts by weight".
＜実施例１～２１＞
防虫成分としてエンペントリンを使用する下記の処方１により、衣料害虫防除組成物（実施例１～２１）を調製した。実施例１～１９の衣料害虫防除組成物においては、化合物Ａ～Ｓを香料成分として使用した。実施例２０の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、及びＱを等量ずつ混合した調合香料（以下、「調合香料１」と称する。）を香料成分として使用した。実施例２１の衣料害虫防除組成物においては、化合物Ｌ、Ｎ、Ｑ、β－ダマスコン、及びカシュメランを等量ずつ混合した調合香料（以下、「調合香料２」と称する。）を香料成分として使用した。<Examples 1 to 21>
Clothing pest control compositions (Examples 1-21) were prepared according to Formulation 1 below using empentrin as an insect repellent ingredient. In the clothing pest control compositions of Examples 1-19, compounds AS were used as perfume ingredients. In the clothing pest control composition of Example 20, a blended fragrance obtained by mixing equal amounts of compounds B, H, L, N, and Q (hereinafter referred to as “mixed fragrance 1”) was used as a fragrance component. In the clothing pest control composition of Example 21, a compounded fragrance (hereinafter referred to as "compounded fragrance 2") in which equal amounts of compounds L, N, Q, β-damascone and cashmeran were mixed was used as a fragrance component. did.
処方１：
香料成分を１５ｇ（１５質量％）、エンペントリンを７０ｇ（７０質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方１において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．２１である。Formula 1:
15 g (15% by mass) of a perfume component, 70 g (70% by mass) of empentrin, and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 1, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 0.21 as a weight ratio.
＜実施例２２～２７＞
防虫成分としてエンペントリンを使用する下記の処方２により、衣料害虫防除組成物（実施例２２～２７）を調製した。実施例２２～２７の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、Ｑ、及び調合香料１を香料成分として使用した。<Examples 22 to 27>
Clothing pest control compositions (Examples 22-27) were prepared according to Formulation 2 below using empentrin as the repellent ingredient. In the clothing pest control compositions of Examples 22-27, Compounds B, H, L, N, Q, and Formulated Perfume 1 were used as perfume ingredients.
処方２：
香料成分を１５ｇ（１５質量％）、エンペントリンを３０ｇ（３０質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方２において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．５０である。Formula 2:
15 g (15% by mass) of a perfume component, 30 g (30% by mass) of empentrin, and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 2, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 0.50 as a weight ratio.
＜実施例２８～３２＞
防虫成分としてエンペントリンを使用する下記の処方３により、衣料害虫防除組成物（実施例２８～３２）を調製した。実施例２８～３２の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、及びＱを香料成分として使用した。<Examples 28 to 32>
Clothing pest control compositions (Examples 28-32) were prepared according to Formulation 3 below using empentrin as an insect repellent ingredient. In the clothing pest control compositions of Examples 28-32, compounds B, H, L, N, and Q were used as perfume ingredients.
処方３：
香料成分を１５ｇ（１５質量％）、エンペントリンを１５ｇ（１５質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方３において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、１．００である。Formula 3:
15 g (15% by mass) of the perfume component, 15 g (15% by mass) of empentrin, and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 3, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 1.00 as a weight ratio.
＜実施例３３～５３＞
防虫成分としてプロフルトリンを使用する下記の処方４により、衣料害虫防除組成物（実施例３３～５３）を調製した。実施例３３～５３の衣料害虫防除組成物においては、化合物Ａ～Ｓ、調合香料１、及び調合香料２を香料成分として使用した。<Examples 33 to 53>
Clothing pest control compositions (Examples 33-53) were prepared according to Formulation 4 below using profluthrin as the repellent ingredient. In the clothing pest control compositions of Examples 33-53, Compounds AS, Fragrance Formula 1, and Perfume Formula 2 were used as perfume ingredients.
処方４：
香料成分を１５ｇ（１５質量％）、プロフルトリンを３５ｇ（３５質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方４において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．４３である。Formula 4:
15 g (15% by mass) of a perfume component, 35 g (35% by mass) of profluthrin, and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 4, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 0.43 as a weight ratio.
＜実施例５４～５９＞
防虫成分としてプロフルトリンを使用する下記の処方５により、衣料害虫防除組成物（実施例５４～５９）を調製した。実施例５４～５９の衣料害虫防除組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、Ｑ、及び調合香料１を香料成分として使用した。<Examples 54 to 59>
Clothing pest control compositions (Examples 54-59) were prepared according to Formulation 5 below using profluthrin as the repellent ingredient. In the clothing pest control compositions of Examples 54-59, Compounds B, H, L, N, Q, and Formulated Perfume 1 were used as perfume ingredients.
処方５：
香料成分を１５ｇ（１５質量％）、プロフルトリンを１５ｇ（１５質量％）、並びに、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方５において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、１．００である。Formula 5:
15 g (15% by mass) of a perfume component, 15 g (15% by mass) of profluthrin, and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 5, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 1.00 as a weight ratio.
＜比較例１～２１＞
防虫成分を配合しない下記の処方６により、衣料害虫防除組成物（比較例１～２１）を調製した。比較例１～２１の衣料害虫防除組成物においては、化合物Ａ～Ｓ、調合香料１、及び調合香料２を香料成分として使用した。<Comparative Examples 1 to 21>
Clothing pest control compositions (Comparative Examples 1 to 21) were prepared according to the following Formulation 6 containing no insect repellent component. In the clothing pest control compositions of Comparative Examples 1 to 21, compounds A to S, blended fragrance 1, and blended fragrance 2 were used as fragrance ingredients.
処方６：
香料成分を１５ｇ（０．５質量％）、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。Formula 6:
15 g (0.5% by mass) of a perfume component and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g.
＜比較例２２＞
防虫成分としてエンペントリンを使用する下記の処方７により、衣料害虫防除組成物（比較例２２）を調製した。比較例２２の衣料害虫防除組成物においては、香料成分を配合していない。<Comparative Example 22>
A clothing pest control composition (Comparative Example 22) was prepared according to Formulation 7 below using empentrin as an insect repellent ingredient. In the clothing pest control composition of Comparative Example 22, no fragrance component was blended.
処方７：
エンペントリンを７０ｇ（７０質量％）、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方７において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．００である。Formula 7:
70 g (70% by mass) of empentrin and the balance of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 7, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 0.00 as a weight ratio.
＜比較例２３＞
防虫成分としてプロフルトリンを使用する下記の処方８により、衣料害虫防除組成物（比較例２３）を調製した。比較例２３の衣料害虫防除組成物においては、香料成分を配合していない。<Comparative Example 23>
A clothing pest control composition (Comparative Example 23) was prepared according to Formulation 8 below using profluthrin as an insect repellent ingredient. In the clothing pest control composition of Comparative Example 23, no fragrance component was blended.
処方８：
プロフルトリンを３５ｇ（３５質量％）、溶剤としてデオトミゾールを残分（バランス）混合し、全量１００ｇに調製した。処方８において、香料成分（ａ）と防虫成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．００である。Formula 8:
35 g (35% by mass) of profluthrin and the remainder (balance) of deotomisole as a solvent were mixed to prepare a total amount of 100 g. In Formulation 8, the blending ratio (a/b) of the fragrance component (a) and the insect repellent component (b) is 0.00 as a weight ratio.
＜比較例２４～３４＞
防虫成分としてエンペントリンを使用する処方１により、衣料害虫防除組成物（比較例２４～３４）を調製した。比較例２４～３４の衣料害虫防除組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物を香料成分として使用した。具体的には、比較例２４の衣料害虫防除組成物においては、下記式（２０）：<Comparative Examples 24 to 34>
Clothing pest control compositions (Comparative Examples 24-34) were prepared according to Formulation 1 using empentrin as the repellent ingredient. In the clothing pest control compositions of Comparative Examples 24 to 34, a compound having an electronic conjugated moiety other than an electronic conjugated moiety derived from a benzene ring, a benzoate structure, or a salicylate structure was used as a fragrance component. Specifically, in the clothing pest control composition of Comparative Example 24, the following formula (20):
比較例２５の衣料害虫防除組成物においては、下記式（２１）： In the clothing pest control composition of Comparative Example 25, the following formula (21):
比較例２６の衣料害虫防除組成物においては、下記式（２２）： In the clothing pest control composition of Comparative Example 26, the following formula (22):
比較例２７の衣料害虫防除組成物においては、下記式（２３）： In the clothing pest control composition of Comparative Example 27, the following formula (23):
比較例２８の衣料害虫防除組成物においては、下記式（２４）： In the clothing pest control composition of Comparative Example 28, the following formula (24):
比較例２９の衣料害虫防除組成物においては、下記式（２５）： In the clothing pest control composition of Comparative Example 29, the following formula (25):
比較例３０の衣料害虫防除組成物においては、下記式（２６）： In the clothing pest control composition of Comparative Example 30, the following formula (26):
比較例３１の衣料害虫防除組成物においては、下記式（２７）： In the clothing pest control composition of Comparative Example 31, the following formula (27):
比較例３２の衣料害虫防除組成物においては、下記式（２８）： In the clothing pest control composition of Comparative Example 32, the following formula (28):
比較例３３の衣料害虫防除組成物においては、下記式（２９）： In the clothing pest control composition of Comparative Example 33, the following formula (29):
比較例３４の衣料害虫防除組成物においては、下記式（３０）： In the clothing pest control composition of Comparative Example 34, the following formula (30):
＜比較例３５～４５＞
防虫成分としてプロフルトリンを使用する処方４により、衣料害虫防除組成物（比較例３５～４５）を調製した。比較例３５～４５の衣料害虫防除組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物Ｃ１～Ｃ１１を香料成分として使用した。<Comparative Examples 35 to 45>
Clothing pest control compositions (Comparative Examples 35-45) were prepared according to Formulation 4 using profluthrin as the repellent ingredient. In the clothing pest control compositions of Comparative Examples 35 to 45, compounds C1 to C11 having an electronic conjugated moiety other than an electron conjugated moiety derived from a benzene ring, a benzoate structure, or a salicylate structure were used as perfume ingredients.
＜比較例４６～５６＞
防虫成分を配合しない処方６により、衣料害虫防除組成物（比較例４６～５６）を調製した。比較例４６～５６の衣料害虫防除組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物Ｃ１～Ｃ１１を香料成分として使用した。<Comparative Examples 46 to 56>
Clothing pest control compositions (Comparative Examples 46 to 56) were prepared according to Formulation 6 containing no insect repellent component. In the clothing pest control compositions of Comparative Examples 46 to 56, compounds C1 to C11 having an electronic conjugated moiety other than an electron conjugated moiety derived from a benzene ring, a benzoate structure, or a salicylate structure were used as perfume ingredients.
実施例１～５９、及び比較例１～５６の衣料害虫防除組成物の処方、及び香料成分を表１、２に示す。 Tables 1 and 2 show the formulations and perfume ingredients of the clothing pest control compositions of Examples 1-59 and Comparative Examples 1-56.
［消臭機能確認試験］
汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭に対する消臭機能確認試験を実施した。供試体として、実施例１～５９、及び比較例１～５６の試験溶液を１５ｍｇ分注したものを用いた。汗臭については、直径９ｃｍの試験濾紙に、アンモニア水（ナカライテスク株式会社製）のエタノール溶液をスプレーバイアルにて適量噴霧したものを悪臭処理サンプルとした。ミドル脂臭については、直径９ｃｍの試験濾紙に、ジアセチル（ナカライテスク株式会社製）のエタノール溶液をスプレーバイアルにて適量噴霧したものを悪臭処理サンプルとした。加齢臭については、直径９ｃｍの試験濾紙に、２－ノネナール（東京化成工業株式会社製）のエタノール溶液をスプレーバイアルにて適量噴霧したものを悪臭処理サンプルとした。タバコ臭については、密閉小空間でタバコの煙を直径９ｃｍの試験濾紙に暴露処理したものを悪臭処理サンプルとした。調理臭については、密閉小空間で牛脂を燃やして、その煙を直径９ｃｍの試験濾紙に暴露処理したものを悪臭処理サンプルとした。[Deodorant function confirmation test]
A deodorizing function confirmation test was carried out for sweat odor, middle-aged oily odor, aging odor, cigarette odor, and cooking odor. As specimens, 15 mg of the test solutions of Examples 1 to 59 and Comparative Examples 1 to 56 were dispensed and used. For sweat odor, a test filter paper with a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of ammonia water (manufactured by Nacalai Tesque Co., Ltd.) using a spray vial to prepare a malodor-treated sample. For middle-aged oily odor, a test filter paper with a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of diacetyl (manufactured by Nacalai Tesque Co., Ltd.) using a spray vial to prepare a malodor-treated sample. As for age-related odor, a test filter paper with a diameter of 9 cm was sprayed with an appropriate amount of an ethanol solution of 2-nonenal (manufactured by Tokyo Kasei Kogyo Co., Ltd.) using a spray vial to prepare a malodor-treated sample. As for the tobacco odor, a test filter paper with a diameter of 9 cm was exposed to tobacco smoke in a closed small space to obtain a malodor treated sample. For the cooking odor, beef tallow was burned in a closed small space, and the fumes were exposed to a test filter paper with a diameter of 9 cm, which was used as a malodor-treated sample.
消臭機能確認試験では、容量１３．５Ｌのステンレス製の円筒内に悪臭処理サンプルを吊るし、悪臭処理サンプル設置から１時間経過後に、悪臭処理サンプルに並べて供試体を吊るした。供試体の設置から１時間後、及び２４時間後に、ステンレス製の内の臭気を評価した。臭気の評価は以下の５段階臭気強度表示法で５人のテスターにより評価し、平均点を求めた。平均点０以上２未満を○、２以上３未満を△、３以上４以下を×とした。
０：香りを感じない
１：かすかに感じる
２：弱く感じる
３：明らかに感じる
４：強く感じるIn the deodorizing function confirmation test, the malodor treatment sample was hung in a stainless steel cylinder with a capacity of 13.5 L, and after 1 hour from the installation of the malodor treatment sample, the specimen was hung side by side with the malodor treatment sample. One hour and 24 hours after installation of the test piece, the odor inside the stainless steel was evaluated. The odor was evaluated by five testers according to the following five-level odor intensity display method, and the average score was obtained. An average score of 0 or more and less than 2 was rated as ◯, an average score of 2 or more and less than 3 as Δ, and an average score of 3 or more and 4 or less as x.
0: No scent 1: Slightly sensed 2: Weakly sensed 3: Clearly sensed 4: Strongly sensed
汗臭に対する消臭機能確認試験の結果を表３～５に示す。 Tables 3 to 5 show the results of the deodorizing function confirmation test against sweat odor.
ミドル脂臭に対する消臭機能確認試験の結果を表６～８に示す。 Tables 6 to 8 show the results of the deodorizing function confirmation test for middle-aged oily odor.
加齢臭に対する消臭機能確認試験の結果を表９～１１に示す。 Tables 9 to 11 show the results of the deodorizing function confirmation test against aging odor.
タバコ臭に対する消臭機能確認試験の結果を表１２～１４に示す。 Tables 12 to 14 show the results of the deodorizing function confirmation test against tobacco odor.
調理臭に対する消臭機能確認試験の結果を表１５～１７に示す。 Tables 15 to 17 show the results of the deodorizing function confirmation test for cooking odors.
消臭機能確認試験の結果、本発明の特徴構成を備えた衣料害虫防除組成物は、防虫成分としてエンペントリンを含有する実施例１～３２、及び防虫成分としてプロフルトリンを含有する実施例３３～５９の何れであっても、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭に対して、供試体の設置から２４時間後も優れた消臭性を示した。このことから、本発明の特徴構成を備えた衣料害虫防除組成物を、収納空間内に揮散させることで、収納中の衣類に対する消臭機能が２４時間程度持続し、収納空間から衣類を取り出す際に衣類に付着した悪臭により不快感が生じることを防ぐことができると考えられる。 As a result of the deodorizing function confirmation test, the clothing pest control composition having the characteristic configuration of the present invention was obtained from Examples 1 to 32 containing empentrin as an insect repellent component and Examples 33 to 59 containing profluthrin as an insect repellent component. In any case, excellent deodorizing properties were exhibited even after 24 hours from the installation of the test piece against sweaty odor, middle-aged oily odor, aged odor, cigarette odor, and cooking odor. From this, it can be seen that by volatilizing the clothing pest control composition having the characteristic configuration of the present invention in the storage space, the deodorizing function for the stored clothing lasts for about 24 hours, and when the clothing is taken out from the storage space. It is thought that it is possible to prevent the discomfort caused by the bad smell adhering to the clothes.
一方、防虫成分を含有していない比較例１～２１の衣料害虫防除組成物は、防虫成分としてエンペントリンを含有する実施例１～３２、及び防虫成分としてプロフルトリンを含有する実施例３３～５９と、同一の香料成分を含有しているが、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても、供試体の設置から１時間後であっても臭気が感じられ、供試体の設置から２４時間後には消臭性を示さなかった。 On the other hand, the clothing pest control compositions of Comparative Examples 1 to 21 containing no insect repellent component were Examples 1 to 32 containing empentrin as an insect repellent component, Examples 33 to 59 containing profluthrin as an insect repellent component, Although the same perfume ingredients are contained, the odor of sweat, middle-aged oily odor, aging odor, tobacco odor, and cooking odor is felt even one hour after the test piece is installed. 24 hours after installation of the test piece, it did not exhibit deodorant properties.
比較例２２の衣料害虫防除組成物は、実施例１～３２と同様に防虫成分としてエンペントリンを含有しており、比較例２３の衣料害虫防除組成物は、実施例３３～５９と同様に防虫成分としてプロフルトリンを含有しているが、比較例２２及び２３は何れも香料成分を含有していない。このような比較例２２及び２３の衣料害虫防除組成物は、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても消臭性を示さなかった。このことから、防虫成分であるエンペントリン、及びプロフルトリンは単独では消臭性を有していないことが確認された。防虫成分であるエンペントリン、及びプロフルトリンが単独では消臭性を有していないにもかかわらず、比較例１～２１の衣料害虫防除組成物と比較して、これらに防虫成分を配合しただけの実施例１～５９の衣料害虫防除組成物において消臭機能が長時間持続したのは、防虫成分が本発明において規定する特定の香料成分と何らかの相乗効果を奏するためと考えられる。 The clothing pest control composition of Comparative Example 22 contains empentrin as an insect repellent component in the same manner as in Examples 1 to 32, and the clothing pest control composition of Comparative Example 23 contains an insect repellent component in the same manner as in Examples 33 to 59. However, Comparative Examples 22 and 23 do not contain perfume ingredients. Such clothing pest control compositions of Comparative Examples 22 and 23 did not exhibit deodorizing properties against sweaty odor, middle-aged oily odor, aged odor, tobacco odor, and cooking odor. From this, it was confirmed that empentrin and profluthrin, which are insect repellent ingredients, do not have deodorizing properties by themselves. Although empentrin and profluthrin, which are insect repellent ingredients, do not have deodorizing properties by themselves, compared with the clothing pest control compositions of Comparative Examples 1 to 21, the implementation of only blending these with insect repellent ingredients. The long-lasting deodorant function of the clothing pest control compositions of Examples 1 to 59 is considered to be due to the fact that the insect repellent component has some synergistic effect with the specific perfume component defined in the present invention.
また、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物を香料成分として使用した比較例２４～５６は、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても、供試体の設置から１時間後であっても臭気が感じられ、供試体の設置から２４時間後には消臭性を示さなかった。防虫成分としてエンペントリンを含有する場合（比較例２４～３４）、及び防虫成分としてプロフルトリンを含有する場合（比較例３５～４５）でも、消臭機能が長時間持続しなかったのは、本発明において規定する特定の香料成分を使用していないために、防虫成分と香料成分との相乗効果が得られなかったためと考えられる。 In addition, Comparative Examples 24 to 56 using compounds having electronic conjugated moieties other than the electronic conjugated moieties derived from a benzene ring, benzoate structure, or salicylic acid ester structure as perfume ingredients had sweat odor, middle-aged oily odor, and aging. With respect to any of odors, cigarette odors, and cooking odors, odors were felt even 1 hour after installation of the test piece, and no deodorizing effect was exhibited 24 hours after installation of the test piece. Even when empentrin was contained as an insect repellent component (Comparative Examples 24 to 34) and when profluthrin was contained as an insect repellent component (Comparative Examples 35 to 45), the deodorant function did not last for a long time. It is considered that the synergistic effect of the insect repellent component and the fragrance component was not obtained because the specified specific fragrance component was not used.
以上の結果から、本発明の特徴構成を備えた衣料害虫防除組成物（実施例１～５９）は、特定の防虫成分と特定の香料成分との組み合わせにより、防虫成分と香料成分との相乗効果が得られ、香料成分による消臭機能が長時間に亘って持続することが確認された。 From the above results, the clothing pest control compositions (Examples 1 to 59) having the characteristic configuration of the present invention have a synergistic effect of the insect repellent component and the fragrance component by combining the specific insect repellent component and the specific fragrance component. was obtained, and it was confirmed that the deodorizing function of the perfume component lasts for a long time.
本発明の衣料害虫防除組成物、及び衣料消臭方法は、衣類に付着した悪臭を消臭するために使用されるものであり、繊維製品の消臭に利用可能である。さらに、本発明の衣料防虫消臭方法は、繊維製品に対する防虫及び消臭に利用可能である。 The pest control composition for clothing and the deodorizing method for clothing of the present invention are used for deodorizing offensive odors adhering to clothing, and can be used for deodorizing textile products. Furthermore, the method for insect repellent and deodorant for clothing of the present invention can be used for insect repellent and deodorant for textile products.
Claims (5)
前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有する、エチルリナロール、テトラヒドロゲラニオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、ラズベリーケトン、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つであり、
前記防虫成分は、前記香料成分の消臭機能を持続させる持続機能を有する、エンペントリン、及び／又はプロフルトリンである衣料害虫用防除組成物。 A clothing pest control composition containing an insect repellent component and a fragrance component,
The perfume ingredients include ethyl linalool, tetrahydrogeraniol, phenylethyl alcohol, helional, lyrial, benzyl benzoate, benzyl salicylate, and cis-3-hexenyl salicylate, which have a deodorizing function of deodorizing offensive odors adhering to clothing. , methyl dihydrojasmonate, raspberry ketone, ethylene brassylate, and at least one selected from the group consisting of cyclopentadecanolide,
The pest control composition for clothing, wherein the insect repellent component is empentrin and/or profluthrin, which has a function of sustaining the deodorizing function of the perfume component.
前記衣料害虫用防除組成物を含浸させた担体を衣料の収納空間に設置し、前記担体から前記衣料害虫用防除組成物を揮散させる衣料消臭方法。 A method for deodorizing clothes using the composition for controlling pests on clothes according to any one of claims 1 to 3 ,
A method for deodorizing clothes, comprising placing a carrier impregnated with the composition for controlling pests on clothes in a storage space of clothes, and volatilizing the composition for controlling pests on clothes from the carrier.
収納空間内に処理対象の衣料を防虫成分と香料成分とを含有する衣料害虫用防除組成物とともに収納する収納工程と、
前記衣料に十分な防虫効果及び消臭効果が付与されるように、前記収納空間内に前記衣料害虫用防除組成物を揮散させる揮散工程と、
を包含し、
前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有する、エチルリナロール、テトラヒドロゲラニオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、ラズベリーケトン、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つであり、
前記防虫成分は、前記香料成分の消臭機能を持続させる持続機能を有する、エンペントリン、及び／又はプロフルトリンである衣料防虫消臭方法。
A clothing insect repellent and deodorant method for performing insect repellent treatment and deodorant treatment on clothing at the same time,
a storage step of storing the clothing to be treated in the storage space together with the clothing pest control composition containing an insect repellent component and a fragrance component;
a volatilization step of volatilizing the clothing pest control composition in the storage space so as to impart a sufficient insect repellent effect and deodorant effect to the clothing;
encompasses
The perfume ingredients include ethyl linalool, tetrahydrogeraniol, phenylethyl alcohol, helional, lyrial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicylate, which have a deodorizing function of deodorizing bad odors attached to clothes. at least one selected from the group consisting of methyl dihydrojasmonate, raspberry ketone, ethylene brassylate, and cyclopentadecanolide;
The insect repellent and deodorant method for clothes , wherein the insect repellent component is empentrin and/or profluthrin, which has a sustaining function of sustaining the deodorizing function of the perfume component .
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