TW202031596A - 用於鋰離子電池之鋰過渡金屬氧化物之電漿處理 - Google Patents

用於鋰離子電池之鋰過渡金屬氧化物之電漿處理 Download PDF

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TW202031596A
TW202031596A TW108147074A TW108147074A TW202031596A TW 202031596 A TW202031596 A TW 202031596A TW 108147074 A TW108147074 A TW 108147074A TW 108147074 A TW108147074 A TW 108147074A TW 202031596 A TW202031596 A TW 202031596A
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nmc
lithium
powder
hours
raw material
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理查 Ｋ 荷曼
卡默爾 哈迪迪
葛雷格里 伍羅貝爾
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美商６Ｋ有限公司
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    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C—CHEMISTRY; METALLURGY
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    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C01G53/504—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C01G53/504—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5
    • C01G53/506—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5 with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.8, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.8
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    • H01M4/0469—Electroforming a self-supporting electrode; Electroforming of powdered electrode material
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
TW108147074A 2018-12-20 2019-12-20 用於鋰離子電池之鋰過渡金屬氧化物之電漿處理 TW202031596A (zh)

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US201862782845P 2018-12-20 2018-12-20
US201862782828P 2018-12-20 2018-12-20
US201862782982P 2018-12-20 2018-12-20
US62/782,845 2018-12-20
US62/782,828 2018-12-20
US62/782,982 2018-12-20

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US (1) US20200203706A1 (cg-RX-API-DMAC7.html)
EP (1) EP3897963A4 (cg-RX-API-DMAC7.html)
JP (1) JP2022514676A (cg-RX-API-DMAC7.html)
KR (1) KR20210102427A (cg-RX-API-DMAC7.html)
CN (1) CN113423497A (cg-RX-API-DMAC7.html)
AU (1) AU2019405960A1 (cg-RX-API-DMAC7.html)
CA (1) CA3122582A1 (cg-RX-API-DMAC7.html)
TW (1) TW202031596A (cg-RX-API-DMAC7.html)
WO (1) WO2020132343A1 (cg-RX-API-DMAC7.html)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10987735B2 (en) 2015-12-16 2021-04-27 6K Inc. Spheroidal titanium metallic powders with custom microstructures
PL3389862T3 (pl) 2015-12-16 2024-03-04 6K Inc. Sferoidalne metale podlegające odwodornieniu oraz cząstki stopów metali
US10639712B2 (en) 2018-06-19 2020-05-05 Amastan Technologies Inc. Process for producing spheroidized powder from feedstock materials
CN112436115B (zh) * 2018-12-29 2021-12-28 宁德时代新能源科技股份有限公司 正极活性材料、正极极片及电化学储能装置
CN110233259B (zh) 2018-12-29 2021-02-09 宁德时代新能源科技股份有限公司 正极活性材料、正极极片及电化学储能装置
SG11202111578UA (en) 2019-04-30 2021-11-29 6K Inc Lithium lanthanum zirconium oxide (llzo) powder
JP7699057B2 (ja) 2019-04-30 2025-06-26 シックスケー インコーポレイテッド 機械的に合金化された粉末原料
WO2020226978A1 (en) * 2019-05-09 2020-11-12 A123 Systems Llc Methods and systems for dry surface doping of cathode materials
CN112786949B (zh) * 2019-11-06 2022-06-07 宁德时代新能源科技股份有限公司 二次电池及含有该二次电池的电池模组、电池包、装置
KR20220100861A (ko) 2019-11-18 2022-07-18 6케이 인크. 구형 분말을 위한 고유한 공급원료 및 제조 방법
US11590568B2 (en) 2019-12-19 2023-02-28 6K Inc. Process for producing spheroidized powder from feedstock materials
US12469838B2 (en) 2020-05-03 2025-11-11 Sparkz Inc. Systems and methods involving use of nitrogen-containing plasma to treat lithium iron phosphate cathodes
WO2021225998A1 (en) * 2020-05-03 2021-11-11 Venkatraman Prabhakar Systems and methods of fabricating a lithium ion cell
CN116034496A (zh) 2020-06-25 2023-04-28 6K有限公司 微观复合合金结构
CA3186082A1 (en) 2020-09-24 2022-03-31 6K Inc. Systems, devices, and methods for starting plasma
CA3196653A1 (en) 2020-10-30 2022-05-05 Sunil Bhalchandra BADWE Systems and methods for synthesis of spheroidized metal powders
AU2022206483A1 (en) * 2021-01-11 2023-08-31 6K Inc. Methods and systems for reclamation of li-ion cathode materials using microwave plasma processing
WO2022159401A1 (en) * 2021-01-19 2022-07-28 6K Inc. Single crystal cathode materials using microwave plasma processing
EP4313449A1 (en) 2021-03-31 2024-02-07 6K Inc. Systems and methods for additive manufacturing of metal nitride ceramics
WO2022269429A1 (en) * 2021-06-25 2022-12-29 Advanced Potash Technologies, Ltd. Multi-step methods of making a high temperature multi-phase material and related materials, compositions and methods of use
WO2023072737A1 (en) * 2021-10-25 2023-05-04 Umicore Method for preparing a precursor material for a li-containing cathode active material
CN116868371A (zh) * 2021-12-24 2023-10-10 宁德时代新能源科技股份有限公司 一种尖晶石型含镍锰锂复合氧化物、其制备方法及含有其的二次电池和用电装置
US12261023B2 (en) 2022-05-23 2025-03-25 6K Inc. Microwave plasma apparatus and methods for processing materials using an interior liner
US12040162B2 (en) 2022-06-09 2024-07-16 6K Inc. Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows
CN115394976B (zh) * 2022-08-04 2026-03-10 广东邦普循环科技有限公司 一种正极材料的制备方法及其应用
WO2024044498A1 (en) 2022-08-25 2024-02-29 6K Inc. Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (pip)
JP2025537460A (ja) * 2022-10-28 2025-11-18 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア カチオン無秩序岩塩酸化物および酸化フッ化物カソードに対する固体マイクロ波経路
US12195338B2 (en) 2022-12-15 2025-01-14 6K Inc. Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production
CN117558896A (zh) * 2023-11-27 2024-02-13 深圳市德方纳米科技股份有限公司 掺杂的磷酸盐系复合正极材料及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US838072A (en) * 1905-04-19 1906-12-11 Benner Mfg Company Baby-jumper.
JPH10172564A (ja) * 1996-12-04 1998-06-26 Mitsubishi Electric Corp 活物質及びその製造方法並びにその活物質を用いたリチウムイオン二次電池
JP2007238402A (ja) * 2006-03-10 2007-09-20 Chugai Ro Co Ltd 粉体製造装置および粉体製造方法
TWI491091B (zh) * 2009-08-24 2015-07-01 Applied Materials Inc 藉由熱噴塗原位沉積電池活性鋰材料
US20130032753A1 (en) * 2010-02-23 2013-02-07 Manabu Yamamoto Positive electrode active substance precursor particles, positive electrode active substance particles and non-aqueous electrolyte secondary battery
US9899674B2 (en) * 2013-02-28 2018-02-20 Nissan Motor Co., Ltd. Positive electrode active substance, positive electrode material, positive electrode, and non-aqueous electrolyte secondary battery
EP3474978B1 (en) * 2016-06-23 2021-10-13 6K Inc. Lithium ion battery materials

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EP3897963A1 (en) 2021-10-27
KR20210102427A (ko) 2021-08-19
US20200203706A1 (en) 2020-06-25
JP2022514676A (ja) 2022-02-14
CN113423497A (zh) 2021-09-21
AU2019405960A1 (en) 2021-06-24
CA3122582A1 (en) 2020-06-25
EP3897963A4 (en) 2022-09-14

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