TW201738199A - 純化（甲基）丙烯酸酯之方法 - Google Patents
純化（甲基）丙烯酸酯之方法 Download PDFInfo
- Publication number
- TW201738199A TW201738199A TW106101041A TW106101041A TW201738199A TW 201738199 A TW201738199 A TW 201738199A TW 106101041 A TW106101041 A TW 106101041A TW 106101041 A TW106101041 A TW 106101041A TW 201738199 A TW201738199 A TW 201738199A
- Authority
- TW
- Taiwan
- Prior art keywords
- meth
- acrylate
- column
- purified
- dividing wall
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 43
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title description 9
- 238000000746 purification Methods 0.000 claims abstract description 29
- 150000002148 esters Chemical class 0.000 claims abstract description 23
- 239000011541 reaction mixture Substances 0.000 claims abstract description 16
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 29
- 239000003112 inhibitor Substances 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 21
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 18
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 18
- 238000005886 esterification reaction Methods 0.000 claims description 17
- 230000032050 esterification Effects 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 10
- 238000005192 partition Methods 0.000 claims description 10
- 230000006641 stabilisation Effects 0.000 claims description 9
- 238000011105 stabilization Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- -1 acrylic ester Chemical class 0.000 abstract description 7
- 238000011084 recovery Methods 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 19
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000012074 organic phase Substances 0.000 description 9
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000006227 byproduct Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000004821 distillation Methods 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000012264 purified product Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 241000183024 Populus tremula Species 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- QWQNFXDYOCUEER-UHFFFAOYSA-N 2,3-ditert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1C(C)(C)C QWQNFXDYOCUEER-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 229940093475 2-ethoxyethanol Drugs 0.000 description 1
- AODAQIOEZVDQLS-UHFFFAOYSA-N 3,4-ditert-butylbenzene-1,2-diol Chemical class CC(C)(C)C1=CC=C(O)C(O)=C1C(C)(C)C AODAQIOEZVDQLS-UHFFFAOYSA-N 0.000 description 1
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 1
- WNWJEWBQWOFWEF-UHFFFAOYSA-N C(=CC)OCCC(=O)O Chemical compound C(=CC)OCCC(=O)O WNWJEWBQWOFWEF-UHFFFAOYSA-N 0.000 description 1
- MTUCWZQRZVOEHM-UHFFFAOYSA-N C1(O)=CC=C(O)C=C1.S1C=CC=C1 Chemical compound C1(O)=CC=C(O)C=C1.S1C=CC=C1 MTUCWZQRZVOEHM-UHFFFAOYSA-N 0.000 description 1
- ZFDIRQKJPRINOQ-HWKANZROSA-N Ethyl crotonate Chemical compound CCOC(=O)\C=C\C ZFDIRQKJPRINOQ-HWKANZROSA-N 0.000 description 1
- 238000006845 Michael addition reaction Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- QYTDEUPAUMOIOP-UHFFFAOYSA-N TEMPO Chemical group CC1(C)CCCC(C)(C)N1[O] QYTDEUPAUMOIOP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- UHKJHMOIRYZSTH-UHFFFAOYSA-N ethyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OCC UHKJHMOIRYZSTH-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229960003505 mequinol Drugs 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- ZFDIRQKJPRINOQ-UHFFFAOYSA-N transbutenic acid ethyl ester Natural products CCOC(=O)C=CC ZFDIRQKJPRINOQ-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/141—Fractional distillation or use of a fractionation or rectification column where at least one distillation column contains at least one dividing wall
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0057—Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
- B01D5/006—Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with evaporation or distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1650469A FR3047004B1 (fr) | 2016-01-21 | 2016-01-21 | Procede de purification d'esters (meth)acryliques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201738199A true TW201738199A (zh) | 2017-11-01 |
Family
ID=55542938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW106101041A TW201738199A (zh) | 2016-01-21 | 2017-01-12 | 純化（甲基）丙烯酸酯之方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10508074B2 (https=) |
| EP (1) | EP3405450A1 (https=) |
| JP (1) | JP2019504078A (https=) |
| KR (1) | KR102647454B1 (https=) |
| CN (1) | CN108473412A (https=) |
| BR (1) | BR112018013060B1 (https=) |
| FR (1) | FR3047004B1 (https=) |
| TW (1) | TW201738199A (https=) |
| WO (1) | WO2017125657A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7337692B2 (ja) | 2016-12-21 | 2023-09-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 蒸留により対応する粗製アルキルアクリレートから純粋な２－エチルヘキシルアクリレートまたは純粋な２－プロピルヘプチルアクリレートを取得する方法 |
| BR112019011294B1 (pt) | 2016-12-21 | 2022-10-18 | Basf Se | Processo para isolar acrilato de butila puro de acrilato de butila bruto |
| EP3558922B1 (de) | 2016-12-21 | 2020-10-14 | Basf Se | Verfahren zur destillativen gewinnung von rein-tert-butyl(meth)acrylat aus roh-tert-butyl(meth)acrylat |
| FR3083233B1 (fr) | 2018-06-27 | 2020-05-29 | Arkema France | Procede de purification d'acrylates legers. |
| FR3091871B1 (fr) * | 2019-01-22 | 2020-12-18 | Arkema France | Procede de purification d’esters (meth)acryliques a l’aide d’une colonne a partition |
| CN113574047A (zh) * | 2019-04-16 | 2021-10-29 | 罗门哈斯公司 | 由丙烯酸和甲醇进行的酸催化的丙烯酸甲酯合成 |
| EP3956285B1 (en) * | 2019-04-16 | 2023-04-26 | Rohm and Haas Company | Acid catalyzed synthesis of methyl acrylate from acrylic acid and methanol |
| CN112552174B (zh) * | 2020-12-23 | 2023-04-11 | 江门谦信化工发展有限公司 | 一种精馏乙酸酯的装置及方法 |
| CN114011341B (zh) * | 2021-11-15 | 2024-12-06 | 丹东明珠特种树脂有限公司 | 催化精馏塔和深脱除异丁烯之高纯度mtbe制备系统 |
| WO2025131961A1 (en) * | 2023-12-21 | 2025-06-26 | Basf Se | Device and process for manufacture of (meth)acrylates |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6299345A (ja) * | 1985-10-24 | 1987-05-08 | Nippon Kayaku Co Ltd | アクリル酸エステル又はメタクリル酸エステルの回収法 |
| JP3999926B2 (ja) * | 2000-05-12 | 2007-10-31 | 三菱レイヨン株式会社 | メタクリル酸エステルの精製方法 |
| JP3672818B2 (ja) * | 2000-12-26 | 2005-07-20 | 三菱レイヨン株式会社 | （メタ）アクリル酸エステルの精製方法 |
| JP4733275B2 (ja) * | 2001-01-10 | 2011-07-27 | 三菱レイヨン株式会社 | （メタ）アクリル酸エステルの精製方法 |
| JP2005239564A (ja) * | 2004-02-24 | 2005-09-08 | Mitsubishi Rayon Co Ltd | （メタ）アクリル酸エステルの製造方法 |
| JP2007045803A (ja) * | 2005-08-12 | 2007-02-22 | Asahi Kasei Chemicals Corp | 精製されたメタクリル酸メチルを得る方法 |
| CN101367720A (zh) * | 2008-09-18 | 2009-02-18 | 中国石油大学(华东) | 一种隔壁共沸精馏塔提纯丙烯酸的工艺方法及装置 |
| WO2012071158A1 (en) * | 2010-11-22 | 2012-05-31 | Rohm And Haas Company | Acrylate production process |
| KR101496488B1 (ko) * | 2010-12-29 | 2015-02-26 | 주식회사 엘지화학 | 고순도 2-에틸헥실-아크릴레이트 생산을 위한 분리벽형 증류탑 및 이를 이용한 제조방법 |
-
2016
- 2016-01-21 FR FR1650469A patent/FR3047004B1/fr active Active
-
2017
- 2017-01-03 US US16/068,974 patent/US10508074B2/en active Active
- 2017-01-03 EP EP17702671.3A patent/EP3405450A1/fr not_active Withdrawn
- 2017-01-03 CN CN201780007542.3A patent/CN108473412A/zh active Pending
- 2017-01-03 JP JP2018538078A patent/JP2019504078A/ja active Pending
- 2017-01-03 WO PCT/FR2017/050005 patent/WO2017125657A1/fr not_active Ceased
- 2017-01-03 BR BR112018013060-5A patent/BR112018013060B1/pt active IP Right Grant
- 2017-01-03 KR KR1020187022465A patent/KR102647454B1/ko active Active
- 2017-01-12 TW TW106101041A patent/TW201738199A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20190016665A1 (en) | 2019-01-17 |
| EP3405450A1 (fr) | 2018-11-28 |
| JP2019504078A (ja) | 2019-02-14 |
| US10508074B2 (en) | 2019-12-17 |
| CN108473412A (zh) | 2018-08-31 |
| FR3047004B1 (fr) | 2019-08-09 |
| BR112018013060B1 (pt) | 2022-02-15 |
| FR3047004A1 (fr) | 2017-07-28 |
| KR20180108644A (ko) | 2018-10-04 |
| WO2017125657A1 (fr) | 2017-07-27 |
| BR112018013060A2 (pt) | 2018-12-11 |
| KR102647454B1 (ko) | 2024-03-13 |
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