TW201641200A - Method for arc-welding molten Zn plated steel plate, method for manufacturing welded member, and welded member, each excellent in appearance of welded part and in welding strength - Google Patents

Method for arc-welding molten Zn plated steel plate, method for manufacturing welded member, and welded member, each excellent in appearance of welded part and in welding strength Download PDF

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TW201641200A
TW201641200A TW105113582A TW105113582A TW201641200A TW 201641200 A TW201641200 A TW 201641200A TW 105113582 A TW105113582 A TW 105113582A TW 105113582 A TW105113582 A TW 105113582A TW 201641200 A TW201641200 A TW 201641200A
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molten
plated steel
steel sheet
based plated
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TWI685390B (en
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Kazuaki Hosomi
Tomokazu Nobutoki
Takefumi Nakako
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Nisshin Steel Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/09Arrangements or circuits for arc welding with pulsed current or voltage
    • B23K9/091Arrangements or circuits for arc welding with pulsed current or voltage characterised by the circuits
    • B23K9/093Arrangements or circuits for arc welding with pulsed current or voltage characterised by the circuits the frequency of the pulses produced being modulatable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/16Arc welding or cutting making use of shielding gas
    • B23K9/173Arc welding or cutting making use of shielding gas and of a consumable electrode
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/09Arrangements or circuits for arc welding with pulsed current or voltage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/23Arc welding or cutting taking account of the properties of the materials to be welded
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • C22C18/04Alloys based on zinc with aluminium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/18Sheet panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/34Coated articles, e.g. plated or painted; Surface treated articles

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Arc Welding In General (AREA)
  • Coating With Molten Metal (AREA)
  • Arc Welding Control (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

When melting Zn-based plated steel sheet by means of arc welding, the process is carried out using pulse current waveforms with averaged welding current of 100~350A, averaged welding voltage of 20~35V, and the pulse period of current waveform is 1~50ms, which is repeated with perform peak current and base current; and the plated layer of the melted Zn-based plated steel sheet is mainly composed of Zn, in addition to Al of 1.0 ~ 22.0% by mass, and the electroplating adhesion amount W is 15 ~ 250g/m2.

Description

具有優異的焊接部外觀與焊接強度之熔融Zn系電鍍鋼板的弧焊接方法、焊接組件的製造方法及焊接組件 Arc welding method of molten Zn-based plated steel sheet having excellent weld portion appearance and welding strength, manufacturing method of welding assembly, and welding assembly

本發明係關於減少濺鍍與氣孔的產生量,且具有優異的焊接部外觀與焊接強度之熔融Zn系電鍍鋼板的弧焊接方法、焊接組件的製造方法及焊接組件。 The present invention relates to an arc welding method, a method of manufacturing a welded component, and a welded component of a molten Zn-based plated steel sheet having an excellent weld portion appearance and weld strength, which are capable of reducing the amount of sputtering and pore generation.

熔融Zn系電鍍鋼板因為有良好的抗腐蝕性,所以使用於以建築組件或汽車組件為主的廣泛用途中。這當中,含有Al濃度為1質量%以上的熔融Zn-Al-Mg系電鍍鋼板因為於長期間保持優異的抗腐蝕性,作為取代傳統的熔融Zn電鍍鋼板之材料而言,需求持續增加。又,傳統的熔融Zn電鍍鋼板之電鍍層中的Al濃度通常為0.3質量%以下(參照JIS G3302)。 The molten Zn-based plated steel sheet is used in a wide range of applications mainly for building components or automobile components because of its good corrosion resistance. Among these, the molten Zn-Al-Mg-based plated steel sheet containing the Al concentration of 1% by mass or more has an excellent corrosion resistance over a long period of time, and the demand for the conventional molten Zn-plated steel sheet is continuously increased. Moreover, the Al concentration in the plating layer of the conventional molten Zn-plated steel sheet is usually 0.3% by mass or less (refer to JIS G3302).

將熔融Zn系電鍍鋼板使用於建築組件、汽車組件等情況下,多以弧焊接法來組合。但是,若弧銲接熔融Zn系電鍍鋼板,濺鍍及凹痕、氣孔(以下,只要沒有特別敘述的氣孔,則包含凹痕)的產生明顯,弧焊接性質變差。這是因為,Zn的沸點約906℃比Fe的熔點約1538℃低,所以於弧焊接時會產生Zn蒸氣,由於此Zn蒸氣使得弧變得不安定,而產生濺鍍。而且,在Zn蒸氣還未排出時,若熔融池凝固,則會產生氣孔。若濺鍍附著於電鍍面,不只焊接部外觀較差,而且因為此部分會變成腐蝕的起點,所以抗腐蝕性變差。另一方面,若氣孔的產生明顯,會有焊接強度變差的問題。 When a molten Zn-based plated steel sheet is used in a building component, an automobile component, or the like, it is often combined by an arc welding method. However, when the arc-welded Zn-based plated steel sheet is arc-welded, sputtering, dents, and pores (hereinafter, dents are included as long as pores are not particularly described) are generated, and the arc welding property is deteriorated. This is because Zn has a boiling point of about 906 ° C lower than the melting point of Fe of about 1538 ° C, so that Zn vapor is generated during arc welding, and the arc becomes unstable due to the Zn vapor, and sputtering occurs. Further, when the Zn vapor has not been discharged, if the molten pool is solidified, pores are generated. If the sputtering adheres to the plating surface, not only the appearance of the welded portion is poor, but also since this portion becomes a starting point of corrosion, the corrosion resistance is deteriorated. On the other hand, if the generation of the pores is conspicuous, there is a problem that the welding strength is deteriorated.

更具體而言,在要求長時間耐久性的組件中,雖然使用電鍍 附著量為120g/m2以上的厚單位面積重量之熔融Zn系電鍍鋼板,但因為厚單位面積重量於弧焊接時的Zn蒸氣量變多,濺鍍、氣孔的產生變得更顯著。 More specifically, in a module requiring long-term durability, a molten Zn-based plated steel sheet having a thickness per unit weight of 120 g/m 2 or more is used, but a thick basis weight is used for Zn during arc welding. As the amount of vapor increases, the generation of sputtering and pores becomes more remarkable.

作為抑制熔融Zn系電鍍鋼板的濺鍍、氣孔之方法而言,提出一種脈衝弧焊接法。根據脈衝弧焊接法,小粒化熔滴來使濺鍍被抑制。而且,藉由脈衝弧,攪拌熔融池的同時,下壓熔融池,使熔融池變薄,促進Zn蒸氣的脫離,從而使氣孔被抑制。 As a method of suppressing sputtering and pores of a molten Zn-based plated steel sheet, a pulse arc welding method has been proposed. According to the pulse arc welding method, small granulation droplets are used to suppress sputtering. Further, by the pulse arc, while stirring the molten pool, the molten pool is pressed down, the molten pool is thinned, and the detachment of Zn vapor is promoted, so that the pores are suppressed.

舉例來說,於專利文獻1,揭示一種脈衝弧焊接法,將焊線組成與脈衝電流波形的峰值電流、峰值時間、基極電流控制於適當範圍內,來抑制濺鍍、氣孔。 For example, Patent Document 1 discloses a pulse arc welding method in which the peak current, the peak time, and the base current of the wire composition and the pulse current waveform are controlled within an appropriate range to suppress sputtering and pores.

[先前技術文獻] [Previous Technical Literature]

[專利文獻] [Patent Literature]

【專利文獻1】日本國公開專利公報「特開平第9-206984號公報」 [Patent Document 1] Japanese Laid-Open Patent Publication No. 9-206984

但是,專利文獻1僅揭示每一面的電鍍附著量為45g/m2之薄單位面積重量熔融Zn電鍍鋼板的實施例,並未記載關於厚單位面積重量的熔融Zn系電鍍鋼板之濺鍍、氣孔的抑制方法。 However, Patent Document 1 only discloses an example of a thin unit area weight molten Zn plated steel sheet having a plating adhesion amount of 45 g/m 2 per surface, and does not describe sputtering or pores of a molten Zn-based plated steel sheet having a thick basis weight. The method of suppression.

而且,專利文獻1係將電鍍層中的Al濃度通常為0.3質量%以下的熔融Zn電鍍鋼板作為焊接對象。因為Al濃度會使電鍍層的熔點有所差異,所以電鍍層中的Al濃度於焊接時會影響電鍍層的表現。因此,不能將專利文獻1的技術就這樣應用於含有Al濃度為1質量%以上的熔融Zn系電鍍鋼板(舉例來說,熔融Zn-Al-Mg系電鍍鋼板)。 Further, in Patent Document 1, a molten Zn plated steel sheet having an Al concentration in the plating layer of usually 0.3% by mass or less is used as a welding target. Since the Al concentration causes a difference in the melting point of the plating layer, the Al concentration in the plating layer affects the performance of the plating layer during soldering. Therefore, the technique of Patent Document 1 cannot be applied to a molten Zn-based plated steel sheet (for example, a molten Zn-Al-Mg-based plated steel sheet) having an Al concentration of 1% by mass or more.

如上所述,雖然含有Al濃度為1質量%以上的熔融Zn系電鍍鋼板具有優異的抗腐蝕性,但於弧焊接時,會產生濺鍍、氣孔,而使焊接部外觀與焊接強度變差。本發明鑒於這樣的現況,其目的在於提供一種具有優異的焊接部外觀與焊接強度,且含有Al濃度為1質量%以上的熔融Zn系電鍍鋼板之弧焊接方法及焊接組件。 As described above, the molten Zn-based plated steel sheet containing the Al concentration of 1% by mass or more has excellent corrosion resistance. However, during arc welding, sputtering and pores are generated, and the appearance and weld strength of the welded portion are deteriorated. In view of the above circumstances, an object of the present invention is to provide an arc welding method and a welding assembly including a molten Zn-based plated steel sheet having an excellent weld portion appearance and weld strength and having an Al concentration of 1% by mass or more.

依據發明者們詳細的研究結果得知,對含有Al濃度為1質量%以上的熔融Zn系電鍍鋼鈑之弧焊接,使用脈衝弧焊接法,因為將平均焊接電流、平均焊接電壓、脈衝周期、電鍍層中的Al濃度、電鍍附著量控制於適當範圍內,所以能不損害焊接部外觀,並能抑制濺鍍與氣孔,藉此,完成本發明。 According to the detailed research results of the inventors, it is known that the arc welding of the molten Zn-based galvanized steel containing Al having a concentration of 1% by mass or more is performed by the pulse arc welding method because the average welding current, the average welding voltage, the pulse period, Since the Al concentration and the plating adhesion amount in the plating layer are controlled within an appropriate range, the present invention can be completed without impairing the appearance of the welded portion and suppressing sputtering and pores.

關於本發明之熔融Zn系電鍍鋼板的弧焊接方法,熔融Zn系電鍍鋼板的電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%,電鍍附著量W為15~250g/m2;並以平均焊接電流為100~350A,平均焊接電壓為20~35V,焊接電流的電流波形為在1~50ms的脈衝周期反復進行峰值電流與基極電流之脈衝電流波形,來進行弧焊接。 In the arc welding method of the molten Zn-based plated steel sheet according to the present invention, the composition of the plating layer of the molten Zn-based plated steel sheet is mainly composed of Zn, and contains Al: 1.0 to 22.0% by mass, and the plating adhesion amount W is 15 to 250 g/m. 2 ; and the average welding current is 100~350A, the average welding voltage is 20~35V, and the current waveform of the welding current is the pulse current waveform of the peak current and the base current repeatedly in the pulse period of 1~50ms for arc welding. .

根據本發明,能提供一種焊接組件,於熔融Zn系電鍍鋼板的弧焊接時,能抑制濺鍍與氣孔,並具有優異的焊接部外觀、焊接強度及抗腐蝕性。 According to the present invention, it is possible to provide a welded assembly capable of suppressing sputtering and pores during arc welding of a molten Zn-based plated steel sheet, and having excellent weld appearance, weld strength, and corrosion resistance.

1,1'‧‧‧熔融Zn系電鍍鋼板 1,1'‧‧‧Fused Zn plating plate

2‧‧‧焊線 2‧‧‧welding line

3‧‧‧熔融池 3‧‧‧melting pool

4‧‧‧脈衝弧 4‧‧‧ pulse arc

5‧‧‧熔滴 5‧‧‧fusion

6‧‧‧焊道 6‧‧‧weld

7‧‧‧區域 7‧‧‧Area

[圖1]係為顯示脈衝電流波形、脈衝電壓波形的示意圖。 FIG. 1 is a schematic view showing a pulse current waveform and a pulse voltage waveform.

[圖2]係為顯示脈衝弧焊接現象的示意圖。 [Fig. 2] is a schematic view showing a phenomenon of pulse arc welding.

[圖3]係為說明濺鍍附著數量的測定方法與氣孔占有率定義之圖。 Fig. 3 is a view for explaining a method of measuring the amount of sputter adhesion and a definition of pore occupancy.

[圖4]係為顯示本發明的電鍍層中之適當Al濃度下限值之圖。 Fig. 4 is a view showing a lower limit value of an appropriate Al concentration in the plating layer of the present invention.

[圖5]係為顯示添加元素影響Fe黏度之圖。 [Fig. 5] is a graph showing that an additive element affects the viscosity of Fe.

於圖1顯示脈衝弧焊接方法中之電流波形及電壓波形的示意圖。脈衝弧焊接方法係為交互地反復進行峰值電流IP與基極電流IB的弧焊接方法,峰值電流IP設定於熔滴噴射過渡的臨界電流以上。峰值電流IP為臨界電流以上的情況中,依據電磁力的收縮效應,焊線前端的熔滴產生收縮,來小粒化熔滴,並在每脈衝周期進行有規律的熔滴過渡,使濺鍍被抑制。對此,峰值電流IP為臨界電流以下的情況中,因為熔滴過渡變得不規則,熔滴大大地成長,所以與熔融池短路而產生濺鍍。 FIG. 1 is a schematic diagram showing current waveforms and voltage waveforms in a pulse arc welding method. The pulse arc welding method is an arc welding method in which the peak current IP and the base current IB are alternately repeated, and the peak current IP is set above the critical current of the droplet injection transition. In the case where the peak current IP is above the critical current, according to the contraction effect of the electromagnetic force, the droplets at the front end of the wire are shrunk to granulate the droplets, and a regular droplet transfer is performed every pulse period to cause the sputtering to be performed. inhibition. On the other hand, in the case where the peak current IP is equal to or lower than the critical current, since the droplet transition becomes irregular and the droplet greatly grows, the molten pool is short-circuited to cause sputtering.

於圖2顯示脈衝弧焊接方法中焊接現象的示意圖。脈衝弧焊接中,因為小粒的熔滴5從焊線2噴射過渡至熔融池3,不會產生短路,使濺鍍被抑制。而且,因為藉由脈衝弧4下壓弧正下方的熔融池3,使其變薄,讓Zn蒸氣易於排出,從而使氣孔被抑制。 Fig. 2 shows a schematic view of the welding phenomenon in the pulse arc welding method. In the pulse arc welding, since the small droplets 5 are ejected from the bonding wire 2 to the molten pool 3, no short circuit occurs, and sputtering is suppressed. Further, since the molten pool 3 directly under the arc is pressed by the pulse arc 4 to be thinned, the Zn vapor is easily discharged, so that the pores are suppressed.

但是,若為電鍍附著量多的厚單位面積重量材料,因為Zn蒸氣的產生量變多,即使是脈衝弧焊接方法,Zn蒸氣不會從熔融池排出,並滯留於熔融池內,變得容易產生氣孔。而且,滯留於熔融池內的Zn蒸氣一口氣噴出而擾亂弧,變得容易產生濺鍍。於此,本發明中,將平均焊接電流、平均焊接電壓、脈衝周期控制於適當範圍內,同時藉由將電鍍附著量及電鍍層的Al濃度進行適當地管理,降低熔融池的黏性,促進Zn蒸氣的排出,來抑制濺鍍、氣孔。 However, in the case of a thick basis weight material having a large amount of plating adhesion, since the amount of Zn vapor generated is increased, even in the pulse arc welding method, Zn vapor is not discharged from the molten pool and stays in the molten pool, which is liable to occur. Stomata. Further, the Zn vapor remaining in the molten pool is ejected in one breath to disturb the arc, and sputtering is likely to occur. In the present invention, the average welding current, the average welding voltage, and the pulse period are controlled within an appropriate range, and the adhesion of the plating deposit and the Al concentration of the plating layer are appropriately managed to reduce the viscosity of the molten pool and promote The discharge of Zn vapor suppresses sputtering and pores.

將電鍍層的Mg濃度固定為3質量%,將Al濃度變化為1~22質量%,於實驗室製作每一單面的電鍍附著量為15~250g/m2的熔融Zn系電鍍鋼板樣品。又,樣品尺寸為板厚度3.2mm、寬度100mm、長度200mm。此樣品的搭接邊為30mm,以焊道長度L=180mm進行搭接填角焊。在此,將平均焊接電流在100~350A、平均焊接電壓在20~35V、脈衝周期在1~50ms的範圍進行適當設定,進行脈衝弧焊接,來製造熔融Zn系電鍍鋼板彼此接合的焊接組件。拍攝弧焊接部的X光線穿透照片,如圖3所示意,測定沿著焊道6的長邊方向之氣孔長度d1~di,求出其加總值Σdi(mm),從式(2)算出氣孔占有率Br。而且,藉由目視計算以圖3的虛線所示之焊道6為中心的寬度100mm、長度100mm之區域7的濺鍍附著數量。區域7係為以平行於焊道6的長邊方向且焊道6位於其中央的兩邊、以及垂直於焊道6的長邊方向之兩邊所圍成的每一邊長度為100mm之正方形區域。 The Mg concentration of the plating layer was fixed at 3% by mass, and the Al concentration was changed to 1 to 22% by mass. A sample of the molten Zn-based plated steel sheet having a plating adhesion amount of 15 to 250 g/m 2 per one surface was prepared in the laboratory. Further, the sample size was a plate thickness of 3.2 mm, a width of 100 mm, and a length of 200 mm. The lap joint of this sample was 30 mm, and the fillet fillet was welded with a bead length L = 180 mm. Here, the average welding current is set to 100 to 350 A, the average welding voltage is 20 to 35 V, and the pulse period is set to 1 to 50 ms, and pulse arc welding is performed to produce a welded joint in which molten Zn-based plated steel sheets are joined to each other. The X-ray penetrating photograph of the arc welding portion is photographed, as shown in Fig. 3, and the pore length d 1 ~ di along the long side direction of the bead 6 is measured, and the total value Σ di (mm) is obtained, and the formula (2) is obtained. ) Calculate the porosity occupancy Br. Further, the number of sputter adhesions in the region 7 having a width of 100 mm and a length of 100 mm centered on the bead 6 shown by the broken line in Fig. 3 was visually calculated. The region 7 is a square region having a length of 100 mm on each side surrounded by two sides of the bead 6 in the longitudinal direction of the bead 6 and the bead 6 at the center thereof and two sides perpendicular to the longitudinal direction of the bead 6.

Br=(Σdi/L)×100...(2)。 Br = (Σdi / L) × 100 (2).

於圖4顯示電鍍層中之Al濃度與電鍍附著量影響氣孔占有率Br、濺鍍附著數量的調查結果。根據建築用薄板焊接接合部設計-施工手冊(建築用薄板焊接接合部設計-施工手冊編集委員會),只要氣孔占有率Br為30%以下,焊接強度就不會有問題。而且,只要濺鍍附著數量為20個以下,濺鍍就不醒目,且對於抗腐蝕性的影響也較小。於此,圖4中,氣孔占有率為30%以下且濺鍍附著數量為20個以下繪製為○,不論是氣孔占有率超過30%或濺鍍附著量超過20個的情況則繪製為●。圖4中之四條直線圍成的區域內,氣孔占有率Br為30%以下且濺鍍附著數量為20個以下,故得知藉由適當管理電鍍附著量及Al濃度,能抑制濺鍍與氣孔。 Fig. 4 shows the results of investigations on the influence of the Al concentration and the plating adhesion amount in the plating layer on the pore occupancy ratio Br and the number of sputter adhesion. According to the design of the welded joints for construction sheets - the construction manual (the construction of the thin-plate welded joints for construction - the construction manual compilation committee), as long as the porosity of the pores is less than 30%, the welding strength is not problematic. Further, as long as the number of sputter adhesions is 20 or less, the sputtering is not conspicuous, and the influence on the corrosion resistance is small. Here, in FIG. 4, the porosity occupancy rate is 30% or less, and the number of sputtering adhesions is 20 or less, and is plotted as ○, and the case where the pore occupancy ratio exceeds 30% or the sputtering adhesion amount exceeds 20 is plotted as ●. In the region surrounded by the four straight lines in Fig. 4, the pore occupancy ratio Br is 30% or less and the number of sputtering adhesions is 20 or less. Therefore, it is known that sputtering and pores can be suppressed by appropriately managing the plating adhesion amount and the Al concentration. .

即,如圖4所示,將平均焊接電流在100~350A、平均焊接電壓在20~35V、脈衝周期在1~50ms的範圍進行適當設定,進行脈衝弧焊接 具有含有Al濃度為1~22質量%的電鍍層且每一單面的電鍍附著量為15~250g/m2之熔融Zn系電鍍鋼板,能抑制濺鍍與氣孔。 That is, as shown in FIG. 4, the average welding current is set to 100 to 350 A, the average welding voltage is 20 to 35 V, and the pulse period is set to 1 to 50 ms, and pulse arc welding is performed to have an Al concentration of 1 to 22 mass. A molten Zn-based plated steel sheet having a plating layer of 15 to 250 g/m 2 per 100% of the plating layer can suppress sputtering and pores.

又,於圖4中,在電鍍層中的Al濃度CAl(質量%)與電鍍附著量W(g/m2)滿足CAl<0.0085W+0.87的範圍之情況下,雖然顯示不論是氣孔占有率超過30%或濺鍍附著量超過20個,但藉由將平均焊接電流、平均焊接電壓、脈衝周期以外的脈衝弧焊接條件適當調整,能抑制氣孔占有率為30%以下且濺鍍附著數量為20個以下。即,電鍍附著量為15~250g/m2時,為了抑制氣孔占有率30%為以下且濺鍍附著數量為20個以下,在CAl<0.0085W+0.87的範圍,除了平均焊接電流、平均焊接電壓、脈衝周期,還必須調整這些以外的焊接速度、遮蔽氣體組成,在0.0085W+0.87≦CAl的範圍,只要調整平均焊接電流、平均焊接電壓、脈衝周期。因此,為了抑制氣孔占有率為30%以下且濺鍍附著數量為20個以下,較佳係在0.0085W+0.87≦CAl的範圍。 Further, in Fig. 4, in the case where the Al concentration C Al (% by mass) and the plating adhesion amount W (g/m 2 ) in the plating layer satisfy the range of C Al < 0.0085 + 0.87, although it is shown that the pores are When the occupancy rate exceeds 30% or the amount of sputter deposition exceeds 20, the average welding current, the average welding voltage, and the pulse arc welding conditions other than the pulse period are appropriately adjusted, thereby suppressing the porosity of 30% or less and sputtering adhesion. The number is less than 20. In other words, when the plating adhesion amount is 15 to 250 g/m 2 , in order to suppress the porosity occupancy rate of 30% or less and the number of sputtering adhesions to 20 or less, in the range of C Al <0.0085 W + 0.87, in addition to the average welding current and average. For the welding voltage and pulse period, it is necessary to adjust the welding speed and shielding gas composition other than these. In the range of 0.0085 + 0.87 ≦ C Al , the average welding current, the average welding voltage, and the pulse period are adjusted. Therefore, in order to suppress the porosity occupation ratio of 30% or less and the number of sputter adhesions to 20 or less, it is preferably in the range of 0.0085 W + 0.87 ≦ C Al .

以下詳細敘述本發明的脈衝弧焊接條件。 The pulse arc welding conditions of the present invention are described in detail below.

〔平均焊接電流〕 [average welding current]

本發明中,如圖1所示的電流波形係為反復進行峰值電流與基極電流之脈衝波形,平均焊接電流IA較佳為100~350A的範圍。本發明中,平均焊接電流IA如下式(3)。 In the present invention, the current waveform shown in Fig. 1 is a pulse waveform in which the peak current and the base current are repeated, and the average welding current IA is preferably in the range of 100 to 350 Å. In the present invention, the average welding current IA is as shown in the following formula (3).

IA=((IP×TIP)+(IB×TIB))/(TIP+TIB)...(3) IA=((IP×TIP)+(IB×TIB))/(TIP+TIB)...(3)

其中, among them,

IP:峰值電流(A) IP: peak current (A)

IB:基極電流(A) IB: base current (A)

TIP:峰值電流期間(ms) TIP: peak current period (ms)

TIB:基極電流期間(ms) TIB: base current period (ms)

平均焊接電流低於100A時,因熱量輸入不足,熔融池的溫度下降,黏度變高,Zn蒸氣變得難排出,於熔融池內殘存Zn蒸氣,而產生氣孔。焊接電流與焊線的供給量連接後,若將焊接電流變大至需求以上,因為熔滴粗大化,與熔融池短路而產生濺鍍,所以焊接電流較佳為350A以下。 When the average welding current is less than 100 A, the heat input is insufficient, the temperature of the molten pool is lowered, the viscosity is increased, the Zn vapor is difficult to be discharged, and Zn vapor remains in the molten pool to cause pores. When the welding current is connected to the supply amount of the bonding wire, if the welding current is increased to a demand or higher, since the droplet is coarsened and the molten pool is short-circuited to cause sputtering, the welding current is preferably 350 A or less.

〔平均焊接電壓〕 [average welding voltage]

本發明中,平均焊接電壓EA較佳為20~35V的範圍。本發明中,平均焊接電壓EA如下式(4)。 In the present invention, the average welding voltage EA is preferably in the range of 20 to 35V. In the present invention, the average welding voltage EA is as shown in the following formula (4).

EA=((EP×TEP)+(EB×TEB))/(TEP+TEB)...(4) EA=((EP×TEP)+(EB×TEB))/(TEP+TEB)...(4)

其中, among them,

EP:峰值電壓(V) EP: peak voltage (V)

EB:基極電壓(V) EB: base voltage (V)

TEP:峰值電壓期間(ms) TEP: peak voltage period (ms)

TEB:基極電壓期間(ms) TEB: base voltage period (ms)

平均焊接電壓EA低於20V時,弧長變短,熔滴與熔融池短路而產生濺鍍。若平均焊接電壓超過35V,因熱量輸入過多,會產生燒穿。 When the average welding voltage EA is lower than 20 V, the arc length becomes short, and the droplets are short-circuited with the molten pool to cause sputtering. If the average welding voltage exceeds 35V, burn-through will occur due to excessive heat input.

〔脈衝周期〕 [pulse period]

脈衝周期PF為1~50ms的範圍。低於1ms時,熔滴過渡變得不安定,產生濺鍍。另一方面,若超過50ms,不會產生弧的期間變得過長,熔融池的下壓效果變弱,Zn蒸氣變得難排出,而會產生濺鍍、氣孔。 The pulse period PF is in the range of 1 to 50 ms. Below 1 ms, the droplet transition becomes unstable and sputtering occurs. On the other hand, if it exceeds 50 ms, the period in which the arc does not occur becomes too long, the effect of the pressing of the molten pool becomes weak, and the Zn vapor becomes difficult to be discharged, and sputtering and pores are generated.

〔焊接速度〕 [welding speed]

本發明中的焊接速度並未特別限制。依據熔融Zn系電鍍鋼板的板厚度適當選擇。 The welding speed in the present invention is not particularly limited. It is appropriately selected depending on the thickness of the plate of the molten Zn-based plated steel sheet.

〔遮蔽氣體〕 [masking gas]

脈衝弧焊接法中,為了熔滴噴射過渡,使用Ar-CO2混合氣體。在本發明 中的遮蔽氣體也是使用Ar-CO2混合氣體。Ar-30體積%CO2氣體或Ar-20體積%CO2氣體、或者是CO2濃度更低的Ar-5體積%CO2氣體等因為濺鍍抑制效果大,所以較適合。 In the pulse arc welding method, an Ar-CO 2 mixed gas is used for the droplet ejection transition. The shielding gas in the present invention is also an Ar-CO 2 mixed gas. Ar-30 vol% CO 2 gas or Ar-20 vol% CO 2 gas or Ar-5 vol% CO 2 gas having a lower CO 2 concentration is preferable because the sputtering suppression effect is large.

〔熔融Zn系電鍍鋼板〕 [Fused Zn-based plated steel sheet]

關於本發明的熔融Zn系電鍍鋼板,電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%,電鍍附著量W為15~250g/m2In the molten Zn-based plated steel sheet according to the present invention, the composition of the plating layer is mainly composed of Zn, and contains Al: 1.0 to 22.0% by mass, and the plating adhesion amount W is 15 to 250 g/m 2 .

而且,電鍍附著量W與電鍍層中的Al濃度CAl較佳係滿足以下式(1)的關係。 Further, it is preferable that the plating adhesion amount W and the Al concentration C Al in the plating layer satisfy the relationship of the following formula (1).

0.0085W+0.87≦CAl≦22...(1) 0.0085W+0.87≦C Al ≦22...(1)

其中, among them,

W:電鍍附著量(g/m2) W: plating adhesion amount (g/m 2 )

CAl:電鍍層中的Al濃度(質量%)。 C Al : Al concentration (% by mass) in the plating layer.

該熔融Zn系電鍍鋼板的電鍍層能更含有由Mg:0.05~10.0質量%、Ti:0.002~0.10質量%、B:0.001~0.05質量%、Si:0~2.0質量%、Fe:0~2.5質量%所組成的群組中之至少一者。 The plating layer of the molten Zn-based plated steel sheet may further contain Mg: 0.05 to 10.0% by mass, Ti: 0.002 to 0.10% by mass, B: 0.001 to 0.05% by mass, Si: 0 to 2.0% by mass, and Fe: 0 to 2.5. At least one of the groups consisting of % of mass.

雖然熔融電鍍的方法並未特別限制,一般而言,使用線上退火型的熔融電鍍設備,對成本有利。電鍍層組成係為大致反映熔融電鍍浴組成的物。以下,說明關於電鍍層的成分元素。電鍍層成分元素的「%」除非特別聲明,係指「質量%」。 Although the method of the melt plating is not particularly limited, in general, the use of an in-line annealing type molten plating apparatus is advantageous in terms of cost. The composition of the plating layer is a substance that substantially reflects the composition of the molten plating bath. Hereinafter, the constituent elements of the plating layer will be described. "%" of the plating component elements means "% by mass" unless otherwise stated.

Al對電鍍鋼板的抗腐蝕性有提升的效果,而且,電鍍浴中,會抑制Mg氧化物系渣的產生。再者,如圖5所示,Al以微量添加,有降低Fe的黏度之效果,於弧焊接時,電鍍層中的Al進入熔融池,降低熔融池的黏度,促進Zn蒸氣的排出,來抑制濺鍍、氣孔。為了使這些作用充分發揮,必須確保1.0%以上的Al含有量,較佳係確保4.0%以上的Al含有量。另一方面,若 Al含有量變多,於電鍍層的底部變得容易生成脆的Fe-Al合金層,Fe-Al合金層的過度生成是導致電鍍密合性下降的主要原因。基於種種檢討的結果,Al含有量較佳為22.0%以下,即使是管理在15.0%以下或甚至於10.0%以下也可以。 Al has an effect of improving the corrosion resistance of the plated steel sheet, and in the plating bath, generation of Mg oxide slag is suppressed. Further, as shown in FIG. 5, Al is added in a small amount to reduce the viscosity of Fe. During arc welding, Al in the plating layer enters the molten pool, lowers the viscosity of the molten pool, and promotes the discharge of Zn vapor to suppress Sputtering, pores. In order to fully exert these effects, it is necessary to ensure an Al content of 1.0% or more, and it is preferable to ensure an Al content of 4.0% or more. On the other hand, if The Al content is increased, and a brittle Fe-Al alloy layer is easily formed at the bottom of the plating layer, and excessive formation of the Fe-Al alloy layer is a cause of a decrease in plating adhesion. Based on the results of various reviews, the Al content is preferably 22.0% or less, and may be managed at 15.0% or less or even 10.0% or less.

Mg於電鍍層表面使腐蝕生成物均勻地生成,呈現出明顯提高電鍍鋼板的抗腐蝕性之作用。Mg含有量為0.05%以上較有效果,Mg含有量為1.0%以上效果更佳。另一方面,若電鍍浴中的Mg含有量變多,變得容易產生Mg氧化物系渣,因為是導致電鍍層的品質下降之主要原因,所以Mg含有量應為10.0%以下的範圍。而且,Mg的沸點約1091℃,比Fe的熔點更低,與Zn一樣,於弧焊接時蒸發,因為認為是導致濺鍍、氣孔的原因,所以希望Mg含有量為10.0%以下。 Mg uniformly forms a corrosion product on the surface of the plating layer, and exhibits a remarkable effect of improving the corrosion resistance of the plated steel sheet. It is more effective to have a Mg content of 0.05% or more, and a Mg content of 1.0% or more is more effective. On the other hand, when the Mg content in the plating bath is increased, the Mg oxide-based slag is likely to be generated, and the quality of the plating layer is lowered. Therefore, the Mg content should be in the range of 10.0% or less. Further, Mg has a boiling point of about 1091 ° C and is lower than the melting point of Fe. Like Zn, it evaporates during arc welding. Since it is considered to cause sputtering and pores, the Mg content is desirably 10.0% or less.

若於熔融電鍍浴中含有Ti,因為抑制了導致電鍍層外觀與抗腐蝕性變差的Zn11Mg2系相之生成、成長,所以效果較佳。Ti添加量低於0.002%時,抑制效果不充分,若超過0.1%,於電鍍時造成Ti-Al系的析出物之生成、成長,從而成為引起電鍍層表面之外觀不良的主要原因。因此,本發明中,Ti添加量限定於0.002~0.1%。 When Ti is contained in the molten electroplating bath, the formation and growth of the Zn 11 Mg 2 -based phase which deteriorates the appearance of the plating layer and the corrosion resistance are suppressed, so that the effect is preferable. When the amount of addition of Ti is less than 0.002%, the effect of suppressing is insufficient. When the amount is more than 0.1%, the formation and growth of precipitates of Ti-Al type are caused during plating, which causes a defect in the appearance of the surface of the plating layer. Therefore, in the present invention, the amount of Ti added is limited to 0.002 to 0.1%.

B也與Ti相同,具有抑制Zn11Mg2系相之生成、成長的效果。有B的情況下,添加量為0.001%以上較有效果。但是,若B也過度添加,因為造成Ti-B或Al-B系的析出物,引起電鍍層表面的外觀不良,所以B較佳為0.05%以下的範圍。 B is also the same as Ti, and has an effect of suppressing the formation and growth of the Zn 11 Mg 2 -based phase. In the case of B, the addition amount is 0.001% or more. However, if B is excessively added, since Ti-B or Al-B-based precipitates are caused, the appearance of the surface of the plating layer is poor, so B is preferably in the range of 0.05% or less.

若於熔融電鍍浴中含有Si,抑制了於電鍍基板表面與電鍍層的界面生成的Fe-Al合金層之過度成長,就提升熔融Zn-Al-Mg系電鍍鋼板的加工性而言,是有利的。因此,因應必要,能含有Si。於此情況下,Si含有量為0.005%以上較有效果。但是,因為含有過度的Si是增多熔融電鍍浴中的 渣量之主要原因,所要Si含有量較佳為2.0%以下。 When Si is contained in the molten electroplating bath, excessive growth of the Fe-Al alloy layer formed at the interface between the surface of the plated substrate and the plating layer is suppressed, and it is advantageous in terms of improving the workability of the molten Zn-Al-Mg-based plated steel sheet. of. Therefore, Si can be contained as necessary. In this case, it is effective to have a Si content of 0.005% or more. However, because it contains excessive Si, it is added to the molten electroplating bath. The main reason for the amount of slag is that the Si content is preferably 2.0% or less.

於熔融電鍍浴中,因為鋼板被浸漬、通過的關係,Fe容易混入。若於Zn-Al-Mg系電鍍層中混入Fe,因為會降低抗腐蝕性,Fe含有量較佳為2.5%以下。 In the molten electroplating bath, Fe is easily mixed because of the relationship between the impregnation and passage of the steel sheet. When Fe is mixed in the Zn-Al-Mg-based plating layer, the Fe content is preferably 2.5% or less because the corrosion resistance is lowered.

〔電鍍附著量〕 [Electroplating adhesion]

若熔融Zn-Al-Mg系電鍍鋼板的電鍍附著量不多,不利於長時間保持電鍍面的抗腐蝕性及犧牲性防蝕作用。基於種種檢討的結果,每一單面的電鍍附著量為15g/m2以上較有效果。另一方面,若電鍍附著量超過250g/m2,因為Zn蒸氣的產生量變得過多,即使是本發明,也變得難以抑制濺鍍、氣孔,所以上限為250g/m2If the amount of plating adhesion of the molten Zn-Al-Mg-based plated steel sheet is small, it is disadvantageous for maintaining the corrosion resistance and the sacrificial anti-corrosion effect of the plating surface for a long time. Based on the results of various reviews, it is effective to have a plating adhesion amount of 15 g/m 2 or more per one side. On the other hand, when the plating adhesion amount exceeds 250 g/m 2 , the amount of Zn vapor generated is too large, and even in the present invention, it is difficult to suppress sputtering and pores, so the upper limit is 250 g/m 2 .

〔氣孔占有率、濺鍍附著數量〕 [Pore occupancy, number of sputter adhesions]

根據建築用薄板焊接接合部設計-施工手冊(建築用薄板焊接接合部設計-施工手冊編集委員會),只要從如圖3所示意之氣孔長度的加總值Σdi(mm)之測定值藉由下式(2)所算出的氣孔占有率Br為30%以下,焊接強度就不會有問題。本發明的焊接組件在氣孔占有率Br為30%以下,具有優異的焊接強度。 According to the design of the welded joints for construction sheets - the construction manual (the construction of the thin-plate welded joints for construction - the construction manual compilation committee), as long as the measured value of the total value of the pores Σdi (mm) is as shown in Fig. 3 The porosity occupancy ratio Br calculated by the formula (2) is 30% or less, and the welding strength is not problematic. The welded component of the present invention has an air hole occupancy ratio Br of 30% or less and has excellent welding strength.

Br=(Σdi/L)×100...(2) Br=(Σdi/L)×100...(2)

Σdi:氣孔長度的加總值(mm) Σdi: total value of pore length (mm)

L:焊道長度(mm)。 L: weld bead length (mm).

以圖3的虛線所示,只要以焊道為中心寬度100mm、長度100mm的區域7之濺鍍附著數量為20個以下,濺鍍就不醒目,且對於抗腐蝕性的影響也較小。本發明的焊接組件在濺鍍附著數量為20個以下,具有優異的焊接部外觀與抗腐蝕性。 As shown by the broken line in Fig. 3, as long as the number of sputter adhesions in the region 7 having a width of 100 mm and a length of 100 mm as the center of the bead is 20 or less, the sputtering is not conspicuous, and the influence on the corrosion resistance is small. The welded component of the present invention has an adhesion amount of 20 or less, and has an excellent weld appearance and corrosion resistance.

如上所述,關於本實施形態之熔融Zn系電鍍鋼板的弧焊接 方法,熔融Zn系電鍍鋼板的電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%,電鍍附著量W為15~250g/m2;並以平均焊接電流為100~350A,平均焊接電壓為20~35V,焊接電流的電流波形為在1~50ms的脈衝周期反復進行峰值電流與基極電流之脈衝電流波形,來進行弧焊接。 As described above, in the arc welding method of the molten Zn-based plated steel sheet according to the present embodiment, the composition of the plating layer of the molten Zn-based plated steel sheet contains Zn as a main component and contains Al: 1.0 to 22.0% by mass, and the plating adhesion amount W is 15~250g/m 2 ; and the average welding current is 100~350A, the average welding voltage is 20~35V, and the current waveform of the welding current is the pulse current waveform of the peak current and the base current repeatedly in the pulse period of 1~50ms. , to perform arc welding.

而且,關於本實施形態之熔融Zn系電鍍鋼板的弧焊接方法,該熔融Zn系電鍍鋼板的電鍍附著量W(g/m2)與電鍍層中的Al濃度CAl(質量%)較佳係滿足以下式(1)的關係。 Further, in the arc welding method of the molten Zn-based plated steel sheet according to the present embodiment, the plating adhesion amount W (g/m 2 ) of the molten Zn-based plated steel sheet and the Al concentration C Al (% by mass) in the plating layer are preferably The relationship of the following formula (1) is satisfied.

0.0085W+0.87≦CAl≦22...(1) 0.0085W+0.87≦C Al ≦22...(1)

而且,關於本實施形態之熔融Zn系電鍍鋼板的弧焊接方法,該熔融Zn系電鍍鋼板的電鍍層能更含有由Mg:0.05~10.0質量%、Ti:0.002~0.10質量%、B:0.001~0.05質量%、Si:0~2.0質量%、Fe:0~2.5質量%所組成的群組中之至少一者。 Further, in the arc welding method of the molten Zn-based plated steel sheet according to the present embodiment, the plating layer of the molten Zn-based plated steel sheet may further contain Mg: 0.05 to 10.0% by mass, Ti: 0.002 to 0.10% by mass, and B: 0.001%. At least one of a group consisting of 0.05% by mass, Si: 0 to 2.0% by mass, and Fe: 0 to 2.5% by mass.

再者,關於本實施形態之熔融Zn系電鍍鋼板的弧焊接方法,係進行弧焊接,使得下式(2)所示的氣孔占有率Br成為30%以下,且以焊道為中心長度100mm、寬度100mm的區域之濺鍍附著數量成為20個以下。 In the arc welding method of the molten Zn-based plated steel sheet according to the present embodiment, arc welding is performed so that the pore occupancy ratio Br represented by the following formula (2) is 30% or less, and the weld bead is centered at a length of 100 mm. The number of sputter adhesions in a region having a width of 100 mm is 20 or less.

Br=(Σdi/L)×100...(2) Br=(Σdi/L)×100...(2)

其中, among them,

di:為觀察第i個的氣孔之長度 Di: to observe the length of the i-th pore

L:為焊道長度。 L: is the length of the weld bead.

而且,關於本實施形態之焊接組件的製造方法,電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%的熔融Zn系電鍍鋼板彼此藉由弧焊接來接合;該熔融Zn系電鍍鋼板的每一單面之附著量W為15~250g/m2;並以平均焊接電流為100~350A,平均焊接電壓為20~35V,焊接電流的電流波形為在1~50ms的脈衝周期反復進行峰值電流與基極電流之 脈衝電流波形,來對該熔融Zn系電鍍鋼板彼此進行弧焊接。 Further, in the method for producing a welded component according to the present embodiment, the composition of the plating layer is mainly composed of Zn, and the molten Zn-based plated steel sheet containing Al: 1.0 to 22.0% by mass is joined by arc welding; The adhesion amount W of each single side of the plated steel plate is 15~250g/m 2 ; and the average welding current is 100~350A, the average welding voltage is 20~35V, and the current waveform of the welding current is pulse period of 1~50ms. The pulse current waveforms of the peak current and the base current are repeatedly performed to arc-weld the molten Zn-based plated steel sheets.

而且,關於本實施形態之本發明的焊接組件,係將電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%的熔融Zn系電鍍鋼板彼此焊接而成,該熔融Zn系電鍍鋼板的每一單面之附著量W為15~250g/m2,氣孔含有率Br為30%以內;且以焊道為中心長度100mm、寬度100mm的區域之濺鍍附著數量為20個以下,具有優異的焊接部外觀與抗腐蝕性。 In the welding module of the present invention, the composition of the plating layer is mainly composed of Zn, and the molten Zn-based plated steel sheets containing Al: 1.0 to 22.0% by mass are welded to each other, and the molten Zn-based plating is performed. The adhesion amount W of each single side of the steel sheet is 15 to 250 g/m 2 , and the pore content Br is 30% or less; and the number of sputtering adhesions in the region having a bead center of 100 mm and a width of 100 mm is 20 or less. Excellent weld appearance and corrosion resistance.

【實施例】 [Examples]

將板厚度3.2mm、板寬度1000mm的冷軋鋼帶做為電鍍基板,將此輸送於熔融電鍍產線,來製造熔融Zn-Al-Mg系電鍍鋼板。 A cold-rolled steel strip having a thickness of 3.2 mm and a width of 1000 mm was used as a plating substrate, and this was transported to a melt-plating line to produce a molten Zn-Al-Mg-based plated steel sheet.

從上述電鍍鋼板切出寬度100mm、長度200mm的樣品,以搭接填角焊接頭進行脈衝弧焊接。焊線係使用JIS Z3312 YGW12,焊接速度為0.4m/min、焊珠長度為180mm、搭接邊為30mm。其他的焊接條件如表1,2所示。脈衝弧焊接後,拍攝X光線穿透照片,以前述的方法測定氣孔占有率Br。而且,藉由目視測定濺鍍附著數量。 A sample having a width of 100 mm and a length of 200 mm was cut out from the above-mentioned plated steel sheet, and pulsed arc welding was performed by overlapping the fillet welded joint. The welding line used JIS Z3312 YGW12, the welding speed was 0.4 m/min, the bead length was 180 mm, and the lap joint was 30 mm. Other welding conditions are shown in Tables 1 and 2. After the pulse arc welding, X-rays were taken through the photograph, and the porosity occupancy Br was measured by the aforementioned method. Moreover, the amount of sputter adhesion was measured by visual inspection.

於表1中,顯示本發明之脈衝弧焊接的實施例。而且,於表2中,顯示電鍍層中的Al濃度CAl(質量%)與電鍍附著量W(g/m2)為CAl<0.0085W+0.87的範圍之參考例,並顯示電鍍層中的Al濃度在本發明的條件範圍外進行脈衝弧焊接的比較例。 In Table 1, an embodiment of the pulsed arc welding of the present invention is shown. Further, in Table 2, a reference example in which the Al concentration C Al (% by mass) and the plating adhesion amount W (g/m 2 ) in the plating layer are in the range of C Al < 0.0085 W + 0.87 is shown, and is shown in the plating layer. A comparative example in which the Al concentration was subjected to pulse arc welding outside the range of the conditions of the present invention.

如表1的No.1~30所示,在脈衝弧焊接條件、電鍍層中的Al濃度為本發明的範圍內之實施例中,氣孔占有率為30%以下,濺鍍附著數量為20以下。由本實施例可知,依據本發明,能得到具有優異的焊接部外觀、 抗腐蝕性及焊接強度之熔融Zn-Al-Mg系電鍍鋼鈑弧焊接組件。 As shown in Nos. 1 to 30 of Table 1, in the examples in which the pulse arc welding conditions and the Al concentration in the plating layer are within the range of the present invention, the porosity occupancy rate is 30% or less, and the sputtering adhesion amount is 20 or less. . According to the present embodiment, according to the present invention, it is possible to obtain an excellent appearance of a welded portion, A Zn-Al-Mg-based galvanized steel 钣-arc welding assembly with corrosion resistance and weld strength.

如表2的No.31~34所示,在電鍍層中的Al濃度CAl(質量%)與電鍍附著量W(g/m2)為CAl<0.0085W+0.87的範圍之參考例中,發現濺鍍及氣孔的產生。但是,在滿足CAl<0.0085W+0.87的範圍中,藉由適當調整平均焊接電流、平均焊接電壓、脈衝周期以外的脈衝弧焊接條件,能抑制氣孔占有率為30%以下,且濺鍍附著數量為20個以下。 As shown in Nos. 31 to 34 of Table 2, in the reference example in which the Al concentration C Al (% by mass) and the plating adhesion amount W (g/m 2 ) in the plating layer are in the range of C Al < 0.0085 + 0.87 Found sputter and pores. However, in the range where C Al <0.0085W+0.87 is satisfied, by appropriately adjusting the average welding current, the average welding voltage, and the pulse arc welding conditions other than the pulse period, the porosity occupancy can be suppressed to 30% or less, and the sputtering adhesion can be suppressed. The number is less than 20.

相對地,在No.35~39的平均焊接電流、平均焊接電壓、脈衝周期為本發明的範圍外之比較例中,明顯產生濺鍍、氣孔。而且,在No.40的電鍍附著量超過本發明的範圍之比較例中,也明顯產生濺鍍、氣孔。 In contrast, in the comparative examples in which the average welding current, the average welding voltage, and the pulse period of No. 35 to 39 were out of the range of the present invention, sputtering and pores were remarkably generated. Further, in the comparative example in which the plating adhesion amount of No. 40 exceeded the range of the present invention, sputtering and pores were also apparent.

Claims (6)

一種熔融Zn系電鍍鋼板的弧焊接方法,係為將電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%的熔融Zn系電鍍鋼板,彼此接合之熔融Zn系電鍍鋼板的弧焊接方法,包含:該熔融Zn系電鍍鋼板的每一單面之附著量W為15~250g/m2;且以平均焊接電流為100~350A,平均焊接電壓為20~35V,焊接電流的電流波形為在1~50ms的脈衝周期反復進行峰值電流與基極電流之脈衝電流波形,來進行弧焊接。 An arc welding method for a molten Zn-based plated steel sheet is an arc of a molten Zn-based plated steel sheet in which a composition of a plating layer is mainly composed of Zn and a molten Zn-based plated steel sheet of Al: 1.0 to 22.0% by mass is bonded to each other. The welding method comprises: the adhesion amount W of each one side of the molten Zn-based plated steel plate is 15 to 250 g/m 2 ; and the average welding current is 100 to 350 A, and the average welding voltage is 20 to 35 V, and the current of the welding current The waveform is a pulse current waveform in which a peak current and a base current are repeatedly performed in a pulse period of 1 to 50 ms to perform arc welding. 如請求項1所述之熔融Zn系電鍍鋼板的弧焊接方法,該熔融Zn系電鍍鋼板的電鍍附著量W(g/m2)與電鍍層中的Al濃度CAl(質量%)滿足以下式(1)的關係:0.0085W+0.87≦CAl≦22...(1)。 The arc welding method of the molten Zn-based plated steel sheet according to claim 1, wherein the plating adhesion amount W (g/m 2 ) of the molten Zn-based plated steel sheet and the Al concentration C Al (% by mass) in the plating layer satisfy the following formula Relationship of (1): 0.0085 W + 0.87 ≦ C Al ≦ 22 (1). 如請求項1或2所述之熔融Zn系電鍍鋼板的弧焊接方法,該熔融Zn系電鍍鋼板的電鍍層之組成更含有由Mg:0.05~10.0質量%、Ti:0.002~0.10質量%、B:0.001~0.05質量%、Si:0~2.0質量%、Fe:0~2.5質量%所組成的群組中之至少一者。 The arc welding method of the molten Zn-based plated steel sheet according to claim 1 or 2, wherein the composition of the plating layer of the molten Zn-based plated steel sheet further contains Mg: 0.05 to 10.0% by mass, Ti: 0.002 to 0.10% by mass, B At least one of the group consisting of 0.001 to 0.05% by mass, Si: 0 to 2.0% by mass, and Fe: 0 to 2.5% by mass. 如請求項1或2所述之熔融Zn系電鍍鋼板的弧焊接方法,進行弧焊接,使得以下式(2)所示的氣孔占有率Br成為30%以下;且使以焊道為中心長度100mm、寬度100mm的區域之濺鍍附著數量成為20個以下;Br=(Σdi/L)×100...(2);其中,di:為觀察第i個的氣孔之長度; L:為焊道長度。 The arc welding method of the molten Zn-based plated steel sheet according to claim 1 or 2 is subjected to arc welding so that the pore occupancy ratio Br represented by the following formula (2) is 30% or less; and the length of the weld bead is 100 mm. The number of sputter adhesions in the region of 100 mm in width is 20 or less; Br = (Σdi / L) × 100 (2); wherein di: is the length of the i-th pore; L: is the length of the weld bead. 一種焊接組件的製造方法,係為將電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%的熔融Zn系電鍍鋼板,彼此藉由弧焊接來接合之焊接組件的製造方法,包含:該熔融Zn系電鍍鋼板的每一單面之附著量W為15~250g/m2;且以平均焊接電流為100~350A,平均焊接電壓為20~35V,焊接電流的電流波形在1~50ms的脈衝周期反復進行峰值電流與基極電流之脈衝電流波形,來對該熔融Zn系電鍍鋼板彼此進行弧焊接。 A method for producing a welded component is a method of manufacturing a welded component in which a composition of a plating layer is mainly composed of Zn and a molten Zn-based plated steel sheet of Al: 1.0 to 22.0% by mass is bonded to each other by arc welding. The method comprises the following: the adhesion amount W of each one surface of the molten Zn-based plated steel plate is 15 to 250 g/m 2 ; and the average welding current is 100 to 350 A, the average welding voltage is 20 to 35 V, and the current waveform of the welding current is 1 The pulse current waveform of the peak current and the base current is repeated in a pulse period of ~50 ms to arc-weld the molten Zn-based plated steel sheets. 一種熔融Zn系電鍍鋼板的焊接組件,係為將電鍍層之組成以Zn為主成分,且含有Al:1.0~22.0質量%的熔融Zn系電鍍鋼板,彼此焊接而成之焊接組件,包含:該熔融Zn系電鍍鋼板的每一單面之附著量W為15~250g/m2;下式(2)所示的氣孔占有率Br為30%以下;且以焊道為中心長度100mm、寬度100mm的區域之濺鍍附著數量為20個以下;Br=(Σdi/L)×100...(2);其中,di:為觀察第i個的氣孔之長度;L:為焊道長度。 A welded component of a molten Zn-based plated steel sheet is a welded component obtained by welding a molten Zn-based plated steel sheet having a composition of a plating layer of Zn as a main component and containing Al: 1.0 to 22.0% by mass, comprising: The adhesion amount W of each one surface of the molten Zn-based plated steel sheet is 15 to 250 g/m 2 ; the porosity of Br of the following formula (2) is 30% or less; and the length of the weld bead is 100 mm and the width is 100 mm. The number of sputter adhesions in the region is 20 or less; Br = (Σdi / L) × 100 (2); wherein di: is the length of the i-th pore; and L: is the length of the bead.
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