TW201440666A - Sweet taste and/or milky taste accelerator - Google Patents

Sweet taste and/or milky taste accelerator Download PDF

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TW201440666A
TW201440666A TW102140080A TW102140080A TW201440666A TW 201440666 A TW201440666 A TW 201440666A TW 102140080 A TW102140080 A TW 102140080A TW 102140080 A TW102140080 A TW 102140080A TW 201440666 A TW201440666 A TW 201440666A
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oil
sweetness
fat
milk flavor
hydrogenated
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TW102140080A
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TWI620510B (en
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Atsushi Shibutani
Mina Yoshimura
Minako Hiraoka
Miyuki MATSUSHIMA
Aki Teraminami
Takahiro Tokuchi
Hiroshi Muramatsu
Kaori Hiraoka
Hiroatsu Hagiri
Tsutomu Hanajiri
Masahiro Arai
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J Oil Mills Inc
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • A23D7/0056Spread compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/88Taste or flavour enhancing agents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Edible Oils And Fats (AREA)
  • Seasonings (AREA)
  • Confectionery (AREA)

Abstract

The present invention is directed to providing a sweet taste and/or milky taste accelerator so as to increase sweet taste and/or milky taste of the food and decrease the usage amount of other sweet taste and/or milky taste additives. The sweet taste and/or milky taste accelerator of the present invention is achieved by including partial-oxidized hydrogenated oil having POV values ranging from 25 to 300 as effective component. Furthermore, the trans-fatty acid content of the partial-oxidized hydrogenated oil preferably ranges from 5 to 75 wt% and the iodine value the partial-oxidized hydrogenated oil preferably ranges from 35 to 135.

Description

甜味及/或乳香味增強劑 Sweet and/or milk flavor enhancer

本發明係關於甜味及/或乳香味增強劑,更詳細係有關於上述增強劑係藉由強烈吸引共存於食品中的糖質或乳類脂肪之味覺,即可減少甜味、乳香味調味料等使用量。 The present invention relates to a sweetness and/or a milk flavor enhancer, and more particularly relates to the above-mentioned enhancer which can reduce the taste of sugar or milk fat which is coexistent in a food, thereby reducing sweetness and milky flavor. The amount of materials used.

隨著飲食生活之改變且代謝症候群或糖尿病之風險的增加,因此開發出越來越多低卡路里的食品。食品中的高卡路里成分,由於食材本身或添加物中的糖質或乳類脂肪,所以使用有低卡路里食材之食品或使用有無糖人工甜料、低脂防加工乳品等就很普及化。另外,來自天然之糖質或乳類脂肪之特有甜味、乳香味,其中一個主因係會提高食品之試口性。因此,即使在降低共存的味覺成分之含量之同時,也期盼可開發出強烈吸引味覺的味覺增強劑。 As dietary life changes and the risk of metabolic syndrome or diabetes increases, more and more low-calorie foods are developed. The high-calorie ingredients in foods are popularized by using foods with low-calorie ingredients or using sugar-free artificial sweets and low-fat anti-processed dairy products because of the sugar or milk fat in the food itself or in the additives. In addition, from the natural sugar or milk fat, the unique sweetness and milk flavor, one of the main factors will improve the mouth-testing of food. Therefore, even when the content of the coexisting taste component is lowered, it is expected that a taste enhancer which strongly attracts the taste can be developed.

有關如何將食材甜味、苦味、鮮味等味覺是否由人類味覺受體辨識而得,目前還在進行生理學研究當中,同時也朝向可刺激味覺受體之化合物或可辨別出物質之開發。被辨識出之化合物,係使用可增強共存於食品中之味覺成分效果的味覺增強劑。譬如,專利文獻1(日本專利特開2009-284859)所記載之飲食品之甜味增強劑及甜味增強方法是由長鏈多不飽和脂肪酸及/或其之酯體所構成。若藉由專利文獻1之記載,可將其添加於 食品中以增加飲食品之甜味。又,專利文獻2(日本專利特開2010-158210)所記載之添加奶香味或增強劑,係由12-甲基十三醛(12-Methyltridecanal)所構成。再者,專利文獻3(日本專利特開2003-000189)所記載的添加奶香味或其增強劑,其特徵為包含(Z)-6-Octenal有效成分所構成。若藉由專利文獻2及專利文獻3之記載,可藉由將此添加於食品中而讓乳品名賦予特有的甜甜奶油香味。 Regarding how to recognize the taste, such as sweetness, bitterness and umami taste, from human taste receptors, it is still undergoing physiological research, and is also directed towards the development of compounds that can stimulate taste receptors or discernible substances. The identified compound is a taste enhancer that enhances the effect of the taste component coexisting in the food. For example, the sweetness enhancer and the sweetness enhancement method of the food and beverage described in the patent document 1 (Japanese Patent Laid-Open Publication No. 2009-284859) are composed of a long-chain polyunsaturated fatty acid and/or an ester thereof. If it is described in Patent Document 1, it can be added to Food to increase the sweetness of food and beverage. Further, the milk flavor or enhancer described in Patent Document 2 (Japanese Patent Laid-Open Publication No. 2010-158210) is composed of 12-Methyltridecanal. Further, the added milk flavor or the enhancer thereof described in Patent Document 3 (Japanese Patent Laid-Open Publication No. 2003-000189) is characterized by comprising (Z)-6-Octenal active ingredient. According to the descriptions of Patent Document 2 and Patent Document 3, the dairy product name can be imparted with a unique sweet cream flavor by adding this to the food.

本發明者們,精心研討上述課題後,發現於一定比例之部分氧化氫化油脂中具有增加食材或添加物所具有的甜味及/或乳香味效果,因此得到發明。也就是說,本發明提供過氧化價為25~300之部分氧化氫化油脂作為有效成分之甜味及/或乳香味增強劑。於本說明書中所謂甜味增強劑係意味若組合食材中之甜味成分或甜料,會增進對因味覺受體所產生之甜味的辨識度發生作用之物質或組合物。所謂「乳香味」乃意味乳品特有的乳味或乳脂感。以下將「增強劑」稱之為甜味及/或乳香味增強劑,其中,甜味及/或乳香味簡稱為「甜味等」。 The present inventors have intensively studied the above problems and found that a certain proportion of the partially hydrogenated hydrogenated fats and oils have an effect of increasing the sweetness and/or the milky flavor of the foodstuff or the additive, and thus have been invented. That is, the present invention provides a sweetness and/or milk flavor enhancer which is a partial oxidation-hydrogenated fat or oil having a peroxidation price of 25 to 300 as an active ingredient. The term "sweetness enhancer" as used herein means a substance or composition which, when combined with a sweet ingredient or a sweetener in a foodstuff, enhances the recognition of the sweetness produced by the taste receptor. The so-called "milk flavor" means a milky or creamy taste unique to dairy products. Hereinafter, the "enhancer" is referred to as a sweetness and/or milk flavor enhancer, and the sweetness and/or milk flavor is simply referred to as "sweetness, etc."

上述的增強劑,其中部分氧化氫化油脂之反式脂肪酸(Trans-fatty acid)含量最佳為5~75重量%。 The above-mentioned reinforcing agent, wherein the partial oxidation-hydrogenated fat and oil has a trans-fatty acid content of preferably 5 to 75% by weight.

上述的增強劑,於部分氧化氫化油脂之所有構成脂肪酸中的C18:2反式型異構體含量最佳為5~60重量%。 The above-mentioned reinforcing agent preferably has a C18:2 trans isomer content of from 5 to 60% by weight in all constituent fatty acids of the partially oxidized hydrogenated fat.

上述的增強劑,部分氧化氫化油脂之碘價(iodine value)最佳者為35~135。 The above-mentioned enhancer, the partial iodine value of the partially oxidized hydrogenated fat is 35 to 135.

上述的增強劑,其中部分氧化氫化油脂最好含有0.003~10 重量%。 The above-mentioned reinforcing agent, wherein the partial oxidation hydrogenated fat preferably contains 0.003~10 weight%.

上述的增強劑,譬如由粉末油脂所構成。 The above reinforcing agent is composed, for example, of a powdered fat.

粉末油脂,進一步讓攪拌含有過氧化價為25~300之部分氧化氫化油脂、食用油脂、乳化劑、粉末化基材以及水的混合物而所得之乳膠且藉由粉末乾燥化而取得。 The powdery fat and oil are further obtained by stirring a latex obtained by mixing a partial oxidation-hydrogenated fat and oil having a peroxidation price of 25 to 300, an edible fat, an emulsifier, a powdered base material, and water, and drying the powder.

上述粉末之脂肪球直徑(中數粒徑)最佳者為0.2~2.0μm。 The fat cell diameter (median diameter) of the above powder is preferably 0.2 to 2.0 μm.

另外,本發明所提供之油脂組合物係含有上述的增強劑。 Further, the oil and fat composition provided by the present invention contains the above-mentioned reinforcing agent.

另外,本發明所提供之食品,係含有上述的增強劑或使用上述的增強劑且調理過的食物。 Further, the food provided by the present invention contains the above-mentioned reinforcing agent or a food which has been conditioned by using the above-mentioned reinforcing agent.

另外,本發明所提供之甜味及/或乳香味增強劑之製造方法,係添加過氧化價為25~300之部分氧化氫化油脂作為有效成分。 Further, in the method for producing a sweetness and/or milk flavor enhancer according to the present invention, a partially oxidized hydrogenated fat or oil having a peroxide price of 25 to 300 is added as an active ingredient.

另外,本發明所提供的調理食品之甜味及/或乳香味的增強方法,係將包含有過氧化價為25~300之部分氧化氫化油脂作為有效成份的甜味及/或乳香味增強劑添加於食材中且調理而成。 In addition, the method for enhancing the sweetness and/or milk flavor of the prepared food provided by the present invention comprises a sweet and/or milk flavor enhancer comprising a partial oxidation hydrogenated fat having a peroxide price of 25 to 300 as an active ingredient. It is added to the ingredients and conditioned.

上述甜味增強劑,最好是依食材之每糖度添加0.00002~200倍的部分氧化氫化油脂。所以,本發明所提供之調理食品之甜味增強方法,係將包含過氧化價為25~300之部分氧化氫化油脂作為有效成分的甜味增強劑添加於食材中,調理讓部分氧化氫化油脂成為食材每糖度之0.00002~200倍而成。 Preferably, the sweetness enhancer is added with 0.00002 to 200 times of a partially oxidized hydrogenated fat per sugar content of the foodstuff. Therefore, the method for enhancing the sweetness of the prepared food provided by the present invention is to add a sweetness enhancer containing a part of the oxidized hydrogenated fat having a peroxidation price of 25 to 300 as an active ingredient to the food, and conditioning the partial oxidation hydrogenated fat to become The ingredients are made from 0.00002 to 200 times per sugar.

添加本發明增強劑的食品或加工食品,可增加具有食材、甜味料等添加劑之甜味及/或乳香味。因此,若將本發明之增強劑用於食品之製造、加工或調理時,即可降低食材中添加甜味料等的添加量而可保持食 品甜味等。另外,可有效利用甜味等較低之食材。本發明之增強劑期待可作為添加劑,並用於譬如低卡路里食品、乳製品等方面。 The food or processed food to which the enhancer of the present invention is added can increase the sweetness and/or milk flavor of the additive such as the foodstuff, the sweetener and the like. Therefore, when the reinforcing agent of the present invention is used for the production, processing or conditioning of foods, the addition amount of sweeteners and the like added to the foodstuff can be reduced and the food can be kept. Sweetness and so on. In addition, it is possible to effectively utilize lower foods such as sweetness. The enhancer of the present invention is expected to be used as an additive and is used in, for example, low calorie foods, dairy products and the like.

以下,將詳細說明本發明之第一實施型態。本發明之增強劑,其有效成分為過氧化價(稱之POV)為一定範圍的部分氧化氫化油脂(以下稱之「部分氧化氫化脂」)。油脂的過氧化價可依據「財團法人 日本油化學會 基準油脂分析法2.5.2.1-1996」所記載的方法來量測。 Hereinafter, the first embodiment of the present invention will be described in detail. The reinforcing agent of the present invention has an active ingredient of a partially oxidized hydrogenated fat (hereinafter referred to as "partial oxidized hydrogenated fat") having a peroxidation value (referred to as POV). The peroxidation price of fats and oils can be measured by the method described in "The Japan Oil Chemical Society Benchmark Oil Analysis Method 2.5.2.1-1996".

部分氧化氫化脂之POV下限為25meq/kg,較佳為30meq/kg,最佳者為80meq/kg。若POV小於25meq/kg,於食材添加一定量時,有時較不易引出並強化食材或添加劑的甜味等。反之,POV上限為300meq/kg,較佳為280meq/kg而最佳者為200meq/kg。若POV高於300meq/kg,則有時會因為增強劑而聞到不舒服之臭味(以下稱之為「惡臭」)。 The POV lower limit of the partial oxidized hydrogenated fat is 25 meq/kg, preferably 30 meq/kg, and most preferably 80 meq/kg. When the POV is less than 25 meq/kg, when a certain amount is added to the foodstuff, it is sometimes difficult to extract and enhance the sweetness of the foodstuff or the additive. On the contrary, the upper limit of POV is 300 meq/kg, preferably 280 meq/kg and the best is 200 meq/kg. If the POV is higher than 300 meq/kg, an unpleasant odor (hereinafter referred to as "odor") may be caused by the reinforcing agent.

作為部分氧化氫化脂主要原料的部分氫化脂,通常係包含有從數個重量%至數十重量%之亞麻油酸(linoleic acid)或油酸(oleic acid)之順反異構體或位置異構體。氫化反應時會讓不飽和脂肪酸之雙鍵(double bond)從順式型(cis)往反式型(trans)作為異構化,反式脂肪酸為副產品,另外,雙鍵結合之位置所移動之位置異構體也為副產品。 As a main raw material of partial oxidation hydrogenated fat, a partially hydrogenated fat usually contains a cis-trans isomer or a positional difference of linoleic acid or oleic acid from several weight% to several tens% by weight. Structure. The hydrogenation reaction causes the double bond of the unsaturated fatty acid to be isomerized from the cis to the trans, and the trans fatty acid is a by-product, and the position of the double bond is moved. Positional isomers are also by-products.

一般部分氧化氫化脂之反式脂肪酸含量為5~75重量%,較佳為7~70重量%,最佳為45~70重量%。藉由以下範圍添加此部分氧化氫化脂之增強劑的反式脂肪酸含量,通常為0.00015~7.5重量%而較佳為0.005~3.3重量%。 The trans-fatty acid content of the partial partial oxidized hydrogenated fat is 5 to 75% by weight, preferably 7 to 70% by weight, most preferably 45 to 70% by weight. The trans fatty acid content of the partial oxidized hydrogenation enhancer added by the following range is usually 0.00015 to 7.5% by weight, preferably 0.005 to 3.3% by weight.

所謂反型異構體,係意味使用氣相液相層析(gas-liquid chromatography)法來分析部分氫化脂時,C18:1、C18:2及C18:3之反型異構體之總合。油脂之反式脂肪酸含量係以美國油化學會公定法(Ce1h-05)為基準而藉由氣相液相層析法來測定。 The so-called trans isomer means the total of the trans isomers of C18:1, C18:2 and C18:3 when the partial hydrogenated fat is analyzed by gas-liquid chromatography. . The trans fatty acid content of the oil and fat is determined by gas phase liquid chromatography on the basis of the American Society of Oil Chemistry (Ce1h-05).

於上述部分氧化氫化脂之所有構成脂肪酸中的C18:2反式型異構體含量較佳為5~60重量%,其次為8~50重量%,再來為15~45重量%,最佳者為30~45重量%。所謂C18:1反型異構體係當使用氣相液相層析法來分析試料時,就相當於出現於C18:0之峰值與C18:1順式型異構體之峰值間的所有峰值的脂肪酸總稱。另外,若C18:2反式型異構體低於5重量%,就無法獲得強化食材之甜味等的部分氧化氫化脂。反之,若C18:2反式型異構體含量超過60重量%,則有時會較難以製造。 The content of the C18:2 trans isomer in all the constituent fatty acids of the above partial oxidized hydrogenated fat is preferably from 5 to 60% by weight, followed by from 8 to 50% by weight, and further from 15 to 45% by weight, most preferably The amount is 30 to 45% by weight. The so-called C18:1 inverse isomerization system is equivalent to all peaks between the peak of C18:0 and the peak of C18:1 cis isomer when analyzed by gas phase liquid chromatography. A general term for fatty acids. Further, when the C18:2 trans isomer is less than 5% by weight, partial oxidation of hydrogenated fat which enhances the sweetness of the foodstuff or the like cannot be obtained. On the other hand, if the content of the C18:2 trans isomer exceeds 60% by weight, it may be difficult to manufacture.

上述部分氧化氫化脂之所有構成脂肪酸中的C18:1反式型異構體含量對C18:2反式型異構體含量之重量比範圍較佳係在0.2~1.8。若超過此範圍,則有時會讓增強劑產生加熱惡臭味。 The weight ratio of the C18:1 trans isomer content to the C18:2 trans isomer content of all the constituent fatty acids of the above partial oxidized hydrogenated fat is preferably in the range of 0.2 to 1.8. If it exceeds this range, the reinforcing agent may be heated to produce a foul odor.

部分氧化氫化脂之碘價(IV)為較佳為35~135而最佳者為70~130。若IV太低於35則有時會無法發揮充分之效果。反之,若IV過大於135,於食材添加一定量時,有時較不易引出及強化食材或添加劑之甜味等。IV在日本油化學會中可藉由Wijs法來計算出來。另外,IV也可以簡單之近紅外分析法來求之,於J.Am.Oil Chem.Soc.76(6)693~9(1999)中也可獲得許多相關資料。於本實施例上係以近紅外分析法來計算出IV。 The partial oxyhydrogenated fat has an iodine value (IV) of preferably 35 to 135 and most preferably 70 to 130. If the IV is too low below 35, sometimes the full effect will not be achieved. On the other hand, if IV is more than 135, when a certain amount is added to the food, it is sometimes difficult to extract and enhance the sweetness of the food or the additive. IV can be calculated by the Wijs method in the Japanese Oil Chemistry Association. In addition, IV can also be obtained by simple near-infrared analysis method, in J. Am. Oil Chem. Soc. A lot of relevant information is also available in 76(6) 693~9 (1999). In the present embodiment, IV is calculated by near-infrared analysis.

部份氧化氫化脂,可藉由包括下述兩個步驟之製造方法而取得,亦即對油脂進行部分氫化,直到所有構成脂肪酸中的C18:2反式型異構 體含量較佳達到5~60重量%的步驟,以及對油脂進行氧化處理,直到過氧化價達到25~300meq/kg的步驟。 Partial oxidized hydrogenated fat can be obtained by a manufacturing process comprising the following two steps, that is, partial hydrogenation of the oil and fat until C18:2 trans isomerism in all constituent fatty acids The step of preferably having a body content of 5 to 60% by weight and the step of oxidizing the oil until the peroxide price reaches 25 to 300 meq/kg.

油脂之部分氫化處理及氧化處理之順序並非特別限定。較佳係對油脂進行部分氫化,直到所有構成脂肪酸中的C18:2反式型異構體含量較佳達到5~60重量%,然後,對所得之部分氫化脂進行氧化處理,直到過氧化價達到25~300meq/kg。 The order of the partial hydrogenation treatment and the oxidation treatment of the fats and oils is not particularly limited. Preferably, the oil is partially hydrogenated until the content of the C18:2 trans isomer in all of the constituent fatty acids is preferably from 5 to 60% by weight, and then the obtained partially hydrogenated fat is oxidized until the peroxidation price It reaches 25~300meq/kg.

因此,要取得上述部分氧化氫化脂最佳係將油脂進行部份氫化,然後再將所得之部分氫化脂進行氧化處理。也可以依照法則施加退色處理、脫臭處理等之精製步驟後再對部分氫化脂進行氧化處理。 Therefore, in order to obtain the above partial oxidation hydrogenated fat, the oil is partially hydrogenated, and then the obtained partially hydrogenated fat is subjected to oxidation treatment. It is also possible to apply a purification step such as a fading treatment or a deodorization treatment to the oxidative treatment of the partially hydrogenated fat.

部分氧化氫化脂及部分氫化脂主要成份之原料油脂,若為食用用途則無特別限制,但最佳者為食用植物油脂。食用植物油脂譬如可舉出如下:亞麻籽油(linseed oil)、大豆油、棕櫚油(palm oil)、胡桃油(walnut oil)、荏胡麻油(Egoma oil(紫蘇油))、油菜籽油(rapeseed oil)、玉米油(Corn oil)等。 The raw material fat of the main component of the partial hydrogenated fat and the partially hydrogenated fat is not particularly limited as long as it is used for food, but the best is edible vegetable fat. The edible vegetable oils are as follows: linseed oil, soybean oil, palm oil, walnut oil, eucalyptus oil (Egoma oil), rapeseed oil (rapeseed) Oil), corn oil, etc.

於原料油脂之構成脂肪酸中,α-次亞麻油酸(Alpha-linolenic acid)含量較佳為大於6重量%,其次為大於30重量%,最佳者為大於45重量%。不但可強化含有部分氧化氫化脂之增強劑效果,同時可輕微抑制調理品的惡臭。又,雖並無特定限制原料油脂之構成脂肪酸中之α-次亞麻油酸含量,但通常之食用油脂不會超過70重量%。 Among the constituent fatty acids of the raw material fats and oils, the content of α-linolenic acid is preferably more than 6% by weight, more preferably more than 30% by weight, and most preferably more than 45% by weight. It not only enhances the effect of the enhancer containing partial oxidized hydrogenated fat, but also slightly suppresses the malodor of the conditioning product. Further, although the α-linolenic acid content in the constituent fatty acids of the raw material fats and oils is not particularly limited, the usual edible fats and oils do not exceed 70% by weight.

α-次亞麻油酸含量較高之油脂有亞麻籽油、荏胡麻油(Egoma oil(紫蘇油))、及胡桃油(walnut oil)。其中尤其係亞麻籽油、荏胡麻油包含有50重量%之α-次亞麻油酸,故最好於原料油脂中包含此等之 一種或二種。 The oils having a high content of α-linolenic acid are linseed oil, eucalyptus oil (Egoma oil), and walnut oil. Among them, linseed oil and eucalyptus oil contain 50% by weight of α-linolenic acid, so it is preferable to include these in raw materials and fats. One or two.

原料油脂也可搭配上述1種或2種以上之油脂。對此等進行轉酯化(Transesterification)、分離等之油脂、甚至亦可為其混合物。 The raw material fats and oils may be used in combination with one or more of the above-mentioned fats and oils. These may be subjected to transesterification, separation, etc., or even a mixture thereof.

部分氫化脂可藉由常用方法之氫化反應製造出來。譬如於原料油脂之食用植物油脂中,添加對油0.01~0.3重量%的鎳觸媒等,且在溫度為120~220℃環境下以氫壓為0.01~0.3MPa的條件下進行氫化反應。 Partially hydrogenated fats can be produced by hydrogenation of a conventional method. For example, a nickel catalyst such as 0.01 to 0.3% by weight of an oil is added to the edible vegetable oil of the raw material oil, and the hydrogenation reaction is carried out under the conditions of a hydrogen pressure of 0.01 to 0.3 MPa at a temperature of 120 to 220 °C.

為了要取得具有較強之甜味等增強劑,可使用上述α-次亞麻油酸含量較高之原料油脂。譬如以下所示之選擇條件:較佳係以鎳觸媒(觸媒添加量0.05~0.3重量%)、反應溫度為170~210℃、氫壓為0.01~0.2MPa進行氫化反應。最佳者為於觸媒使用低活性之鎳觸媒(譬如已經於氫化反應中使用一次以上之觸媒或品名為SO650(堺化學工業股份有限公司製)),觸媒添加量為0.1~0.3重量%、反應溫度為190~210℃,氫壓為0.01~0.1MPa環境下來進行。 In order to obtain a reinforcing agent having a strong sweetness, the above-mentioned raw material fat having a high content of α-linolenic acid can be used. For example, the selection conditions are as follows: a hydrogenation reaction is preferably carried out by using a nickel catalyst (catalyst addition amount: 0.05 to 0.3% by weight), a reaction temperature of 170 to 210 ° C, and a hydrogen pressure of 0.01 to 0.2 MPa. The best one is to use a low-activity nickel catalyst for the catalyst (for example, if the catalyst has been used more than once in the hydrogenation reaction or the product name is SO650 (manufactured by Suga Chemical Industry Co., Ltd.)), the amount of catalyst added is 0.1~0.3. The weight %, the reaction temperature is 190 to 210 ° C, and the hydrogen pressure is 0.01 to 0.1 MPa.

一般而言,氧化處理係於溫度為50~200℃,較佳係在100~200℃、最佳者為在100~180℃之溫度下對油脂加熱即可。加熱時未必需要注入空氣,但要以一定之速度(譬如50~350轉/分)一邊攪拌,一邊注入定量(譬如0.2~1.0L/分)之空氣,即可在短時間內有效地氧化至既定之過氧化價。藉由短時間的氧化處理也可防止惡臭發生。又,通常氧化處理前之部分氫化油脂(進行提煉過)之過氧化價為0。 In general, the oxidation treatment is carried out at a temperature of 50 to 200 ° C, preferably at 100 to 200 ° C, and preferably at a temperature of 100 to 180 ° C for heating the grease. It is not necessary to inject air when heating, but it should be oxidized in a short time by injecting a certain amount of air (for example, 0.2 to 1.0 L/min) while stirring at a certain speed (for example, 50 to 350 rpm). The established peroxide price. Odor can also be prevented by a short-time oxidation treatment. Further, in general, the partial hydrogenated fats and oils (extracted) before the oxidation treatment have a peroxidation value of zero.

通常,於增強劑中也可添加原油以稀釋部分氧化氫化脂。原油若為食用油脂的話並非特別限定。原油的範例可舉出:棕櫚油(palm oil)、棕櫚核仁油(Palm Kernel Oil)、棕櫚硬脂油、椰子油、玉米油、棉花子油(cotton seed oil)、大豆油、油菜籽油(rapeseed oil)、米油、葵花籽油(sunflower oil)、紅花油(Safflower oil)、可可子油脂(cacao)等植物油脂、豬油等動物性油脂等。另外,也可使用上述的分離油(棕櫚油之中熔點部、棕櫚油之分離軟質油、棕櫚油之分別硬脂油等)、加工酯交換油等之油脂。另外,可使用1種或2種以上之此等之食用油脂。 Typically, crude oil may also be added to the enhancer to dilute the partially oxidized hydrogenated fat. The crude oil is not particularly limited as long as it is edible fat or oil. Examples of crude oils include: palm oil, palm kernel oil, palm stear oil, coconut oil, corn oil, cottonseed oil (cotton) Seed oil), soybean oil, rapeseed oil, rice oil, sunflower oil, Safflower oil, coca cola oil (cacao) and other vegetable oils, lard and other animal fats, etc. . Further, the above-mentioned separation oil (melting point in palm oil, separated soft oil of palm oil, and stearic oil of palm oil, etc.) may be used, and fats and oils such as transesterified oil may be processed. Further, one or two or more of these edible fats and oils can be used.

原油的範例可舉出:棕櫚油(palm oil)、棕櫚核仁油(Palm Kernel Oil)、棕櫚硬脂油、椰子油、玉米油、棉花子油(cotton seed oil)、大豆油、油菜籽油(rapeseed oil)、米油、葵花籽油(sunflower oil)、紅花油(Safflower oil)、可可子油脂(cacao)等植物油脂、豬油等動物性油脂等。另外,也可使用上述的分離油(棕櫚油之中熔點部、棕櫚油之分離軟質油、棕櫚油之分別硬脂油等)、加工酯交換油等之油脂。另外,可使用1種或2種以上之此等之食用油脂。 Examples of crude oil include: palm oil, palm kernel oil, palm stear oil, coconut oil, corn oil, cotton seed oil, soybean oil, rapeseed oil ( Rapeseed oil), rice oil, sunflower oil, Safflower oil, vegetable oils such as cacao oil, and animal fats such as lard. Further, the above-mentioned separation oil (melting point in palm oil, separated soft oil of palm oil, and stearic oil of palm oil, etc.) may be used, and fats and oils such as transesterified oil may be processed. Further, one or two or more of these edible fats and oils can be used.

本發明之增強劑可搭配廣泛用於食用油脂之添加劑。上述添加劑可舉例包含:卵磷脂(Lecithin)、甘油二酯(Diacylglycerol)、甘油脂肪酸酯(Glycerin fatty acid ester)、山梨糖醇酐脂肪酸酯(Sorbitan fatty acid ester)、丙二醇脂肪酸酯(Propylene glycol fatty acid ester)、蔗糖脂肪酸酯(Sucrose esters of fatty acids)、聚甘油脂肪酸酯(Polyglycerol esters of fatty acids)等乳化劑。糖類(Carbohydrate)、蛋白質(Protein)、肽(Peptide)等粉末化基材。酪蛋白(Casein)、酪蛋白酸鈉(Casein sodium)、酸酪蛋白(Acid casein)等穩定化劑。氫氧化鈉(Sodium hydroxide)等pH調整劑。玉米糖漿(Corn syrup)、部分氫化澱粉(Partial hydrogenation starch)、葡萄糖(Glucose)、果糖(Fructose)、麥芽糖(Maltose)、蔗糖(Sucrose)、寡糖(Oligosaccharide)、核糖 (Ribose)、海藻糖(Trehalose)、異麥芽糖(Isomaltose)、赤蘚醇(Erythritol)、麥芽糖醇(Maltitol)、木糖醇(Xylitol)、山梨糖醇(Sorbitol)、阿斯巴甜(Aspartame)、三氯蔗糖(Sucralose)等甜味;牛奶香精(Milk flavor)、奶油香精(Butter flavor)、乳酪香精(Cheese flavor)、優酪乳香精(Yogurt flavor)、咖啡香精(Coffee flavor)、紅茶香精(Tea flavor)、肉桂香精(Cinnamon flavor)、洋甘菊香精(Chamomile flavor)等香料類。留蘭香油(Spearmint oil)、丁香油(Clove oil)、胡椒薄荷油(Peppermint oil)等香味油。由乙醛(Acetaldehyde)、苯甲醛(Benzaldehyde)、丁醛(Butyraldehyde)、檸檬醛(Citral)、橙花醛(Neral)、癸醛(Decanal)、乙基香草醛(Ethyl vanillin)、香草醛(Vanillin)、丁醛(Butyraldehyde)、己醛(Hexanal)等乙醛(aldehyde)所構成之香味劑。香辛料;生育酚(Tocopherol)、維生素C棕櫚酸酯(Vitamin C Palmitate)、木酚素(Lignan)、谷維素(Oryzanol)等抗氧化劑。有機矽(Silicone)等消泡劑。輔酶Q(Coenzyme Q)等之生理活性物質等。 The enhancer of the present invention can be used in combination with additives widely used in edible oils and fats. The above additives may be exemplified by: lecithin, diacylglycerol, Glycerin fatty acid ester, sorbitan fatty acid ester, and propylene glycol fatty acid ester (Propylene). Emulsifiers such as glycol fatty acid esters, sucrose esters of fatty acids, and polyglycerol esters of fatty acids. A powdered substrate such as Carbohydrate, Protein, or Peptide. Stabilizers such as casein, casein sodium, and acid casein. A pH adjuster such as sodium hydroxide. Corn syrup, Partial hydrogenation starch, Glucose, Fructose, Maltose, Sucrose, Oligosaccharide, Ribose (Ribose), Trehalose, Isomaltose, Erythritol, Maltitol, Xylitol, Sorbitol, Aspartame Sweetness such as Sucralose; Milk flavor, Butter flavor, Cheese flavor, Yogurt flavor, Coffee flavor, Black tea flavor (Tea flavor), cinnamon flavor (Cinnamon flavor), chamomile flavor (Chamomile flavor) and other spices. Aroma oils such as Spearmint oil, Clove oil, and Peppermint oil. From acetaldehyde, Benzaldehyde, Butyraldehyde, Citral, Neral, Decanal, Ethyl vanillin, Vanillin Vanillin), a scent of acetaldehyde such as butyraldehyde or Hexanal. Spices; antioxidants such as Tocopherol, Vitamin C Palmitate, Lignan, Oryzanol. Defoamer such as Silicone. A physiologically active substance such as Coenzyme Q.

本發明之增強劑中的部分氧化氫化脂之含量,通常為0.003~10重量%,較佳係0.01~10重量%,最佳者為0.05~5重量%。 The content of the partial oxidized hydrogenated fat in the reinforcing agent of the present invention is usually 0.003 to 10% by weight, preferably 0.01 to 10% by weight, most preferably 0.05 to 5% by weight.

本發明之增強劑中的油脂部份(部分氧化氫化脂及原油之總合),通常為5~100重量%,較佳係20~100重量%。 The oil and fat portion (the total of the partial hydrogenated hydrogenated fat and the crude oil) in the reinforcing agent of the present invention is usually 5 to 100% by weight, preferably 20 to 100% by weight.

本發明之增強劑之型態可為液體狀、乳膠(油中水(W/O)形或水中油(O/W)、固態(粉末、顆粒、薄片狀、塊狀等)。本發明之增強劑較佳係由粉末油脂所構成。 The type of the enhancer of the present invention may be liquid, latex (water in oil (W/O) or oil in water (O/W), solid (powder, granule, flake, block, etc.). The reinforcing agent is preferably composed of powdered fats and oils.

上述之粉末或顆粒之粒子直徑通常為0.3~3mm,較佳為0.5~2m。另外,薄片狀之厚度通常為0.2~3mm,較佳為0.5~2mm。 The particle diameter of the above powder or granule is usually from 0.3 to 3 mm, preferably from 0.5 to 2 m. Further, the thickness of the sheet is usually 0.2 to 3 mm, preferably 0.5 to 2 mm.

上述粉末油脂之脂肪球直徑(中數粒徑)通常為0.2~2.0μm,較佳為0.3~1.8μm。 The fat ball diameter (median diameter) of the above powdered fat is usually 0.2 to 2.0 μm, preferably 0.3 to 1.8 μm.

本發明之增強劑可因應型態並藉由適當方法加以調製。譬如由液體狀或固態油脂所組成之增強劑,可藉由適當之原油及添加劑一起混合而得之部分氧化氫化脂。藉由選擇原油而可調整為液體狀或固態。 The enhancer of the present invention can be prepared according to the type and by an appropriate method. For example, a reinforcing agent composed of a liquid or solid oil, a partial oxidized hydrogenated fat obtained by mixing together a suitable crude oil and an additive. It can be adjusted to liquid or solid by selecting crude oil.

由乳膠所構成之增強劑係以乳化機器來攪拌部分氧化氫化脂、食用油脂(原油)、乳化劑、含其他添加劑及水的混合物而得之。通常乳膠之油脂部份為10~90重量%。 The reinforcing agent composed of latex is obtained by emulsification machine for stirring a mixture of partial hydrogen peroxide, edible fat (crude oil), emulsifier, other additives and water. Usually, the fat portion of the latex is 10 to 90% by weight.

成分為粉末或顆粒油脂之增強劑,可進一步以攪拌混合含有部分氧化氫化脂、食用油脂(原油)、乳化劑、粉末化基材及水的混合物所得之乳膠,再對乳膠進行乾燥粉末化而得之。譬如有乳膠之噴霧乾燥、凍結粉碎等。 The component is a reinforcing agent for powder or granular oil, and the latex obtained by mixing a mixture of partial hydrogenated hydrogenated fat, edible fat (crude oil), emulsifier, powdered substrate and water may be further stirred and dried, and the latex is dried and powdered. Get it. For example, spray drying of latex, freezing and crushing, etc.

另外,本發明所提供之食品,係含有增強劑之食品(以下稱之調理食品)或使用上述的增強劑而調理之食品(以下稱之加工食品)。 Further, the food provided by the present invention is a food containing a reinforcing agent (hereinafter referred to as a prepared food) or a food (hereinafter referred to as a processed food) which is conditioned by using the above-mentioned reinforcing agent.

上述加工食品之具體例可舉出:調味預拌粉(Flour mix)(天婦羅粉(Tempura flour)、炸雞粉(Fried flour)、大阪燒粉(Okonomiyaki flour)、韓式煎餅粉(Jijimi flour)、蛋糕粉(Baking mixes)、鬆餅粉(Pancake mixes)、甜甜圈預拌粉(Donut mixes)、調製奶粉(Powdered milk)、乳清粉(Whey powder)等)、炒麵糊(Roux)(咖哩(Curry)、燉煮調料(Stew)、牛肉燴料(Hashed beef)等)、即食調理包(Instant food)(泡麵(Instant noodles)、即食沖泡湯(Instant soup)、即食味噌湯(instant miso soup)、速溶咖啡(Instant Coffee)、速溶可可亞(Instant cocoa)等)、真空食品(Retort pouch)(咖哩(Curry)、燉煮調料 (Stew)、義大利麵醬(Pasta sauces)、真空即食湯(Soup)等)、冷藏、冷凍食品(甜甜圈(Donut)、薯條(French fries)、炸雞(Fried chicken)、可樂餅(Korokke)、炸肉餅(Menchi-katsu)、炸豬排(Tonkatsu)、炸魚(Fried fish)、魷魚圈(Fried squid)、洋蔥圈(Onion rings)、焗烤飯(Gratin)、披薩(Pizza)、炒飯(Fried rice)、印度抓飯(Pilaf)、烏龍麵(Udon)、拉麵(Ramen)、包子(Pork buns)、餃子(Dumpling)等)、加工肉品名(火腿(Ham)、培根(Bacon)、香腸(Sausage)、漢堡肉(Hamburger)、叉燒肉(Char siu)、調味肉(Seasoned meat)、烤牛肉(Roast beef)、牛排(Steak)等)、水產加工食品(魚肉香腸(Fish sausage)、魚板(Kamaboko)、明太子(Mentaiko)、蔥花鮪魚(Scallion tuna)、鹽漬魚(Shiokara)、蝦醬(Shrimp paste)等)、調味料(味噌(Miso)、醬料(Sauce)、番茄醬(Tomato sauce)、鮮醬油(Seasoning sauce)、美乃滋(Mayonnaise)、調味汁(Dressing)、和風醬(Vinegar)、風味油(Oil sauce)、中華料理調味料(Chinese food sauce)、雞湯塊(Chicken stock cube)、高湯(Broth)、火鍋高湯(Pot soup)等)、糕餅、麵包類(洋芋片(Potato chip)、巧克力(Chocolate)、餅乾(Cookie)、蛋糕(Cake)、餡餅(Pie)、比司吉(Biscuit)、蘇打餅(Cracker)、軟糖(Gummy)、口香糖(Chewing gum)、牛軋糖(Nougat)、太妃糖(Toffee)、焦糖(Caramel)、糖果(Candy)、麵包(Bread)、丹麥麵包(Danish)等)、糕點材料(巧克力抹醬(Chocolate spread)、披覆巧克力(Chocolate coating)、杏仁豆腐粉(Almond pudding mix)、布丁粉(Pudding mix)、果凍粉(Jelly mix)之類的甜點混合粉(Dessert mix)等)、乳品名(牛奶(Milk)、優酪乳(Yogurt)、奶油(Butter)、鮮奶油(Cream)、加工乳酪(Processed cheese)、起司(Cheese)等)、乳類替代品(人造奶油(Margarine)、起酥油(Shortening)、食用塗抹脂肪(Fat spread)、奶油粉(Creaming powder)、 淡奶油(Coffee cream)、發泡鮮奶油(Whip cream)等)、冷甜點(冰淇淋(Ice cream)、果凍(Jelly)、布丁(Pudding))等。 Specific examples of the processed foods include Flour mix (Tempura flour, Fried flour, Okonomiyaki flour, and Korean pancake powder). ), Baking mixes, Pancake mixes, Donut mixes, Powdered milk, Whey powder, etc., Roux (Curry, Stew, Hashed beef, etc.), Instant food (Instant noodles, Instant soup, instant miso soup) (instant miso soup), Instant Coffee, Instant cocoa, etc., Retort pouch (Curry), stew seasoning (Stew), Pasta sauces, Soups, etc., chilled, frozen foods (Donuts, French fries, Fried chicken, cola cakes) (Korokke), Menchi-katsu, Tonkatsu, Fried fish, Fried squid, Onion rings, Gratin, Pizza ), Fried rice, Pilaf, Udon, Ramen, Pork buns, Dumpling, etc., processed meat name (Ham, bacon) (Bacon), Sausage, Hamburger, Char siu, Seasoned meat, Roast beef, Steak, etc., aquaculture processed food (fish sausage) Fish sausage), fish plate (Kamaboko), Mentaiko, Scallion tuna, Shiokara, Shrimp paste, etc., seasoning (Miso), sauce (Sauce) ), Tomato sauce, Seasoning sauce, Mayonnaise, Dressing, Vinegar, Oil sauce, Chinese cuisine Chinese food sauce, Chicken stock cube, Broth, Pot soup, etc., pastry, bread (Potato chip, chocolate, biscuit (Cookie) ), Cake, Pie, Biscuit, Cracker, Gummy, Chewing gum, Nougat, Toffee ), Caramel, Candy, Bread, Danish, etc., pastry materials (Chocolate spread, Chocolate coating, almond tofu powder (Almond) Pudding mix), Pudding mix, Dessert mix, Jelly mix, etc., Dairy name (Milk, Yogurt, Butter, Butter) Cream, Processed Cheese, Cheese, etc., Dairy Substitutes (Margarine, Shortening, Fat Spread, Creaming (Creaming) Powder), Coffee cream, Whip cream, etc., cold dessert (Ice cream, Jelly, Pudding), and the like.

上述加工食品,除了添加本發明之增強劑以外,也可藉由一般方法且配合使用之食材或其型態而加以製造。 The processed food may be produced by a general method in combination with the edible material of the present invention or a form thereof, in addition to the reinforcing agent of the present invention.

增強劑譬如可添加在食材內或表面、麵糊液內、蛋麵糊內、鹽醃漬液內、調味醃漬液內等。另外,增強劑可添加在煎炒用油或煮飯用油。 The reinforcing agent can be added, for example, in the food or on the surface, in the batter, in the egg batter, in the salt pickling liquid, in the seasoning pickling liquid, and the like. Further, the reinforcing agent may be added to the frying oil or the cooking oil.

添加在食品加工內之增強劑的添加劑,通常部分氧化氫化脂之含量為0.003~10重量%,較佳為0.0008~5重量%,最佳者為0.008~3重量%,特別好為0.008~1重量%。 The additive for adding the reinforcing agent in the food processing usually has a content of partially oxidized hydrogenated fat of 0.003 to 10% by weight, preferably 0.0008 to 5% by weight, most preferably 0.008 to 3% by weight, particularly preferably 0.008 to 1%. weight%.

上述加工食品,除了添加本發明之增強劑外,無需使用素材或特別條件且藉由普通方法即可製造出來。 The above processed foods can be produced without using materials or special conditions and by ordinary methods, except for the addition of the reinforcing agent of the present invention.

上述調理食品之具體例子可舉出調理上述加工食品所得之小菜、油炸食品、非油炸食品、乳品名、清涼飲料、糕點類等。 Specific examples of the above-mentioned prepared foods include side dishes, fried foods, non-fried foods, dairy names, refreshing drinks, and cakes obtained by conditioning the processed foods.

上述調理食品,除了使用本發明之增強劑而調理或製造外,無需使用之素材或特別條件且藉由普通方法即可調理或製造出來。 The above-mentioned prepared foods can be conditioned or manufactured without using the materials or special conditions and by ordinary methods, except for conditioning or manufacturing using the reinforcing agent of the present invention.

【實施例】 [Examples]

以下,將基於實施例來進一步詳細說明本發明。又,以下之實施例並非限定本發明。 Hereinafter, the present invention will be described in further detail based on examples. Further, the following examples are not intended to limit the invention.

【調製範例1~12】 [Modulation Examples 1~12]

調製出用於實施例之部分氧化氫化脂及用於比較例之部分氫化脂及氧化油脂。 The partial oxidized hydrogenated fat used in the examples and the partially hydrogenated fat and oxidized fat used in the comparative examples were prepared.

1.準備原料油脂準備以下三種之原料油脂。 1. Preparation of raw materials and fats The following three kinds of raw materials and fats are prepared.

亞麻籽油:日本J-OIL-MILLS股份有限公司製,碘價(iodine value)為186.7及α-次亞麻油酸含量為55.3%。 Flaxseed oil: manufactured by J-OIL-MILLS Co., Ltd., Japan, having an iodine value of 186.7 and an α-linolenic acid content of 55.3%.

大豆油:日本J-OIL-MILLS股份有限公司製,碘價為130及α-次亞麻油酸含量為7.2%。 Soybean oil: manufactured by Japan J-OIL-MILLS Co., Ltd., having an iodine value of 130 and an α-linolenic acid content of 7.2%.

棕櫚油:日本J-OIL-MILLS股份有限公司製,碘價為52.9及α-次亞麻油酸含量為0%。 Palm oil: manufactured by Japan J-OIL-MILLS Co., Ltd., having an iodine value of 52.9 and an α-linolenic acid content of 0%.

2.部分氫化處理 2. Partial hydrogenation treatment

利用以下條件且以部分氫化來處理上述之原料油脂達到所要之碘價。 The above-mentioned raw material fats and oils were treated by partial hydrogenation using the following conditions to achieve the desired iodine value.

觸媒 品名SO-650(鎳含量為14重量%,日本堺化學工業股份有限公司) Catalyst name SO-650 (nickel content 14% by weight, Nippon Chemical Industry Co., Ltd.)

觸媒添加量0.13% Catalyst added 0.13%

反應溫度200℃ Reaction temperature 200 ° C

氫壓0.05MPa Hydrogen pressure 0.05MPa

攪拌速度700轉/分 Stirring speed 700 rpm

3.部分氧化氫化之處理 3. Partial oxidation and hydrogenation treatment

利用以下步驟來氧化處理於上述2)得之部分氫化脂。首先,將250g部分氫化脂放入500mL不鏽鋼燒杯然後再將此浸入到油溫為110℃之油槽內。一邊注入空氣一邊加熱攪拌,強制氧化直到表1所示之所要的過氧化價為止。 The partial hydrogenated fat obtained in the above 2) was oxidized by the following procedure. First, 250 g of partially hydrogenated fat was placed in a 500 mL stainless steel beaker and then immersed in an oil bath having an oil temperature of 110 °C. The mixture was heated and stirred while injecting air, and was forcibly oxidized until the desired peroxide price shown in Table 1.

另外,也要準備大豆油之氧化油及極度硬化氫化棕櫚油(日本J-OIL-MILLS股份有限公司製)。 In addition, oxidized oil of soybean oil and extremely hardened hydrogenated palm oil (manufactured by J-OIL-MILLS Co., Ltd., Japan) are also prepared.

4.組成分析 4. Composition analysis

以下列步驟進行各油脂之分析。 The analysis of each grease was carried out in the following procedure.

4.1碘價 4.1 Iodine price

使用近紅外線分析儀(品名:近紅外線分析儀,型號:Model5000、日本NIRECO股份有限公司製造)來測定於1~3所得到之油脂碘價。結果如表1所示。 The iodine value of the fat obtained in 1 to 3 was measured using a near-infrared analyzer (product name: near-infrared analyzer, model: Model 5000, manufactured by NIRECO Co., Ltd., Japan). The results are shown in Table 1.

4.2過氧化價 4.2 Peroxidation price

上述過氧化價係依據「財團法人日本油化學會 基準油脂分析法2.5.2.1-1996」之記載方法而測定之。結果如表1所示。 The above-mentioned peroxidation price is measured in accordance with the method described in "The Japanese Oil Chemist's Standard Oil Analysis Method 2.5.2.1-1996". The results are shown in Table 1.

4.3反式脂肪酸含量 4.3 trans fatty acid content

藉由三氟化硼甲醇法將上述油脂進行脂肪酸甲基酯(fatty acid methyl ester)後,再以氣相層析(gas chromatography:GC)法來分析脂肪酸組成。 The fatty acid was subjected to fatty acid methyl ester by a boron trifluoride methanol method, and then the fatty acid composition was analyzed by gas chromatography (GC).

以下為表示GC測定條件 The following is the GC measurement conditions.

‧GC裝置 品名GC2010(島津製作所製造) ‧GC device Product name GC2010 (made by Shimadzu Corporation)

‧圓柱筒SP-2560(100m×0.25mm×0.2μm)(SUPELCO公司製) ‧ Cylindrical cylinder SP-2560 (100m × 0.25mm × 0.2μm) (manufactured by SUPELCO)

‧注入口溫度250℃ ‧Injection temperature 250 °C

‧載氣 氦氣(29.1ml/min) ‧ Carrier gas Helium (29.1ml/min)

‧稀釋比例(split ratio)25:1 ‧Dilution ratio 25:1

‧圓柱筒溫度180℃55min→(8℃/min)→220℃ 50min ‧Cylinder temperature 180°C55min→(8°C/min)→220°C 50min

‧檢測器 氫焰離子偵測器(Flame Ionization Detector)260℃ ‧Detector Flame Ionization Detector 260°C

將所得之GC色彩層析譜與「Journal of oleo science Vol.50, No.5(2001),339-352」之第5圖所示的峰值號碼1~7、13~27及30~33所示之脂肪酸進行對照,其次,從相當於以下之峰值面積計算出反式脂肪酸含量、C18:1反式型異構體(t18:1)、C18:2反式型異構體(t18:2)含量。結果如表1所示。 The resulting GC color chromatogram and "Journal of oleo science Vol.50, The fatty acids shown in the peak numbers 1 to 7, 13 to 27, and 30 to 33 shown in Fig. 5 of No. 5 (2001), 339-352, were compared, and the inverse was calculated from the peak area corresponding to the following. Fatty acid content, C18:1 trans isomer (t18:1), C18:2 trans isomer (t18:2) content. The results are shown in Table 1.

反式脂肪酸:第5圖中所示的峰值號碼1~7、13~27及30~33所示之脂肪酸 Trans fatty acids: fatty acids shown in peaks 1 to 7, 13 to 27 and 30 to 33 shown in Figure 5

C18:1反式型異構體(t18:1):第5圖所示的峰值號碼1~7所示之脂肪酸 C18:1 trans isomer (t18:1): fatty acid shown by peak number 1 to 7 shown in Fig. 5

C18:2反式型異構體(t18:2):第5圖所示的峰值號碼13~27所示之脂肪酸 C18:2 trans isomer (t18:2): fatty acid shown by peak number 13~27 shown in Fig. 5

於以下之實施例中,若無特別記載情況下,部分氧化氫化亞麻籽油係使用IV為113。 In the following examples, the partially oxidized hydrogenated linseed oil was used at a ratio of 113 unless otherwise specified.

【實施例1~2】<玉米奶油湯(1)> [Examples 1 to 2] <Corn Cream Soup (1)>

於市面上販賣之玉米奶油湯(品名:CUP soup cone cream味之素股份有限公司,依循品名之調理方法所調製時之糖度(%)為9.1%),係添加(每糖分為0.0011倍)表2所示之0.01重量%之原料油脂(與IV及POV不同之油脂)。以下列基準來評價無試吃調理品之玉米奶油湯的甜味、乳香味及惡臭。表2為表示調理品之官能評價結果。又,糖度(%)係以Atago公司製「Pocket糖度計PAL-J」作為BRIX值所測定值,利用以下同樣條件來測定。另外,搭配砂糖等時之添加糖分之值,大約等同上述糖度值。另外,食材之每一糖度,其部分氧化氫化油脂的添加量(倍數)係對食材的部分氧化氫化油脂之添加量(%)除以糖度(%)所得之值。 Corn cream soup sold in the market (name: CUP soup cone cream Ajinomoto Co., Ltd., the sugar content (%) when prepared according to the conditioning method of the product name is 9.1%), added (0.0011 times per sugar) 2% by weight of raw material fats and oils (different oils different from IV and POV). The sweetness, milky aroma and malodor of the corn cream soup without the taste-testing conditioner were evaluated on the following basis. Table 2 shows the results of the sensory evaluation of the conditioning product. In addition, the sugar content (%) was measured by the "Pocket Brix meter PAL-J" manufactured by Atago Co., Ltd. as a BRIX value, and was measured under the same conditions as below. In addition, the value of the added sugar when used in combination with sugar or the like is approximately equivalent to the above sugar value. In addition, the amount (multiple) of the partial oxidation-hydrogenated oil and fat added to each sugar content of the foodstuff is the value obtained by dividing the addition amount (%) of the partial oxidation-hydrogenated oil and fat of the foodstuff by the sugar content (%).

各種味覺之評價基準,如以下所示。 The evaluation criteria for various tastes are as follows.

<甜味> <sweet taste>

4‧相較於對照下感覺有非常強烈 4‧ Compared with the control, it feels very strong

3‧相較於對照下有強烈感覺 3‧ has a strong feeling compared to the control

2‧相較於對照下有稍強之感覺 2‧Slightly stronger than the control

1‧相等於對照或相較於對照下感覺較弱 1‧ is equivalent to the control or feels weaker than the control

<乳香味> <milk flavor>

4‧相較於對照下感覺有非常強烈 4‧ Compared with the control, it feels very strong

3‧相較於對照下有強烈感覺 3‧ has a strong feeling compared to the control

2‧相較於對照下稍微有強烈感覺 2‧ slightly stronger than the control

1‧相等於對照或相較於對照下感覺較弱 1‧ is equivalent to the control or feels weaker than the control

<惡臭> <bad smell>

4‧完全毫無感覺 4‧ No feeling at all

3‧稍微有感覺 3‧Slightly feel

2‧少量有感覺 2‧ a small amount of feeling

1‧強烈感覺 1‧ Strong feeling

於表2中,使用氧化大豆油(比較例1)或部分氫化大豆油(比較例2)之調理食品之甜味及乳香味,係與使用對照之大豆油的調理品相同或感覺稍微強烈之程度。另外,使用部分氧化氫化脂調理品(實施例1)之甜味及乳香味,相較於部分氧化下顯著增加了。即使從大豆油(實施例1)改變至亞麻籽油(實施例2)也可讓部分氧化氫化脂之原料油脂獲得相同效果。因此,本發明之增強劑並不需藉由原料油脂本身性質即可具有甜味及或乳香味增強效果。 In Table 2, the sweetness and milk flavor of the conditioned food using oxidized soybean oil (Comparative Example 1) or partially hydrogenated soybean oil (Comparative Example 2) were the same as or slightly stronger than the conditioning oil using the comparative soybean oil. degree. In addition, the sweetness and milky aroma of the partially oxidized hydrogenated fat conditioning product (Example 1) were significantly increased compared to partial oxidation. Even if it was changed from soybean oil (Example 1) to linseed oil (Example 2), the raw fat of the partial oxidized hydrogenated fat obtained the same effect. Therefore, the reinforcing agent of the present invention does not need to have a sweet taste or a milk flavor enhancing effect by the nature of the raw material fat itself.

【實施例3~5】(POV之改變) [Examples 3 to 5] (change of POV)

於實施例2中,除了使用表3所記載之POV值不同的部分氧化氫化亞麻籽油外,以同樣於實施例2之步驟,調製調理品且進行評價。結果如表3所示。 In the same manner as in Example 2 except that the partially oxidized hydrogenated linseed oil having different POV values described in Table 3 was used, the conditioning product was prepared and evaluated. The results are shown in Table 3.

由上述表3可看出本發明之增強劑,部分氧化氫化脂之POV於30~280範圍內具有效果。若POV120以上,即可於食品中強烈呈現出甜味及乳香味。另外,若POV280以上,則於食品中產生若干之惡臭。 It can be seen from the above Table 3 that the enhancer of the present invention has a POV of a partial oxidation hydrogenated fat having an effect in the range of 30 to 280. If the POV is 120 or more, the sweetness and milky aroma can be strongly exhibited in the food. Further, if the POV is 280 or more, some malodor is generated in the food.

【實施例6~11】<玉米奶油湯(2)> [Examples 6 to 11] <Corn Cream Soup (2)>

於實施例4中,除了將部分氫化亞麻籽油之添加量改變成如表4所示之量外,其他係以同樣於實施例4之步驟進行評價。其結果如表4所示。 In Example 4, the evaluation was carried out in the same manner as in Example 4 except that the amount of the partially hydrogenated linseed oil was changed to the amount shown in Table 4. The results are shown in Table 4.

從表4可知,本發明之增強劑(部分氧化氫化脂)含量為0.005重量%以上且呈現出增強效果。另外,利用食材之每糖度添加0.0005~0.11倍之部分氧化氫化脂,即可獲得甜味增強效果且0.001倍其效果更佳顯著。 As is clear from Table 4, the content of the reinforcing agent (partial hydrogenated hydrogenated fat) of the present invention is 0.005% by weight or more and exhibits a reinforcing effect. In addition, by adding 0.0005 to 0.11 times of the partial oxidation of hydrogen peroxide per sugar content of the foodstuff, a sweetness-enhancing effect can be obtained, and 0.001 times of the effect is more remarkable.

【實施例12~15】<玉米奶油湯(3)> [Examples 12 to 15] <Corn Cream Soup (3)>

於實施例1中,除了將添加之油脂改變成表5所示之IV及反式脂肪酸含量之不同的油脂外,其他皆以等同實施例1相同步驟調製調理品且加以評價。結果如表5所示。 In the first embodiment, the conditioning product was prepared and evaluated in the same manner as in Example 1 except that the added fat was changed to the oil having different IV and trans fatty acid contents shown in Table 5. The results are shown in Table 5.

由上述表5可知,本發明之增強劑,在部分氧化氫化脂之反式脂肪酸含量為7.3重量%時具有效果。若反式脂肪酸含量為57重量%以上則增強效果高,當t18:2含量為37.2重量%以上時,其效果特別好。 As apparent from the above Table 5, the reinforcing agent of the present invention has an effect when the trans-fatty acid content of the partial oxidized hydrogenated fat is 7.3% by weight. When the trans fatty acid content is 57% by weight or more, the reinforcing effect is high, and when the content of t18:2 is 37.2% by weight or more, the effect is particularly good.

【實施例16~17】<砂糖水> [Examples 16 to 17] <Sucrose Water>

將砂糖溶解成10重量%之水(砂糖水),且於砂糖水中添加表6所記載之0.005重量%的油脂(每糖分為0.0005倍)並加以評價。結果如表6所示。 The granulated sugar was dissolved in 10% by weight of water (sucrose water), and 0.005 wt% of the oil and fat (compared to 0.0005 times per sugar) described in Table 6 was added to the granulated sugar and evaluated. The results are shown in Table 6.

由上述表6可知,即使將砂糖水添加進氧化大豆油中也無法獲得甜味增強效果。另外,部分氧化氫化油脂不需藉由氫化油脂之原料即可獲得甜味之增強效果。另外,部分氧化氫化脂本身不具有乳香味。 As is apparent from the above Table 6, even if sucrose water was added to the oxidized soybean oil, the sweetness enhancing effect could not be obtained. In addition, the partial oxidation-hydrogenated fats and oils do not require the raw material of the hydrogenated fats and oils to obtain a sweetness enhancing effect. In addition, the partial oxidized hydrogenated fat itself does not have a milky aroma.

【實施例18~21】<植物性脂肪用發泡鮮奶油(Whip cream)> [Examples 18 to 21] <Whip cream for vegetable fat>

於一般市面上所販賣之發泡鮮奶油(品名:Sujahta Whip(植物性脂肪用))、日本MEIRAKU股份有限公司製)添加精白砂糖(caster sugar)且在藉由一般方法調製出之發泡鮮奶油(添加糖度:10重量%、比重:3.9g/ml、商品溫度:9.3℃)中,添加如表7所記載之油脂而加以評價。結果如表7所示。 Foamed fresh whipped cream (product name: Sujahta Whip (for vegetable fat)), which is sold in the market, is added with caster sugar and is foamed fresh by a general method. In the cream (added sugar content: 10% by weight, specific gravity: 3.9 g/ml, and commercial temperature: 9.3 ° C), the oil and fat described in Table 7 was added and evaluated. The results are shown in Table 7.

由上述表7可知,添加由部分氧化氫化脂所構成之本發明增強劑0.01重量%以上的植物性脂肪用於發泡鮮奶油時,相較於對照之大豆油可獲得顯著的增強效果。另外,增強劑至少於每糖度添加0.001~0.1倍的部分氧化氫化亞麻籽油,可獲得甜味之增強效果。 As is apparent from the above Table 7, when the vegetable fat of 0.01% by weight or more of the reinforcing agent of the present invention composed of the partially oxidized hydrogenated fat was used for the foaming fresh cream, a remarkable reinforcing effect was obtained as compared with the soybean oil of the control. In addition, the reinforcing agent is added at least 0.001 to 0.1 times of the partially oxidized hydrogenated linseed oil per sugar degree to obtain a sweetness enhancing effect.

【實施例22~25】<乳製品發泡鮮奶油> [Examples 22 to 25] <dairy foaming cream>

於一般市面上所販賣之鮮奶油(品名:嚴選北海道純生鮮奶油(乳製品)、日本高梨乳業股份有限公司製)上添加精白砂糖,且在藉由一般方法調製出之發泡鮮奶油(添加糖分:20重量%、比重:4.7g/ml、商品溫度:6.4℃)中,添加如表8所記載之油脂而加以評價。結果如表8所示。 Adding white granulated sugar to the whipped cream (product name: carefully selected Hokkaido pure whipped cream (dairy product), manufactured by Japan Takari Dairy Co., Ltd.) on the market, and foaming fresh cream prepared by a general method ( In the case of adding sugar: 20% by weight, specific gravity: 4.7 g/ml, and commercial temperature: 6.4 ° C), the oil and fat described in Table 8 was added and evaluated. The results are shown in Table 8.

由上述表8可知,添加由部分氧化氫化脂所構成之本發明增強劑0.01重量%以上的發泡鮮奶油,相較於對照之大豆油可獲得顯著的增強效果。另外,增強劑利用至少於每糖分添加0.0005~0.05倍的部分氧化氫化脂,可獲得甜味之增強效果。再者,相較於表7之結果,本發明之增強劑,發泡原料不需藉由植物性脂肪或乳製品且也無關添加糖分量,即可獲得良好的增強效果。 As is apparent from the above Table 8, the addition of the foamed fresh cream of 0.01% by weight or more of the reinforcing agent of the present invention composed of the partially oxidized hydrogenated fat can obtain a remarkable reinforcing effect as compared with the comparative soybean oil. Further, the enhancer can obtain a sweetness enhancing effect by adding at least 0.0005 to 0.05 times of the partial oxidized hydrogenated fat per sugar. Further, as compared with the results of Table 7, the reinforcing agent of the present invention, the foaming raw material does not need to be added with a vegetable fat or a dairy product, and irrespective of the addition of the sugar component, a good reinforcing effect can be obtained.

【實施例26】<味噌> [Example 26] <Miso>

於一般市面上所販賣之味噌(品名:放入混合MARUKOME的味噌湯、日本MARUKOME股份有限公司製、糖度41.9%)20g且添加0.2g之油脂(每糖度添加0.0002倍)或0.2g之菜籽油,其中0.2g油脂係於菜籽油中溶解1重量%之部份氫化亞麻籽油(POV為170),再加以試吃進而評價甜味及鹹味。結果如表9所示。 20g of miso (name: miso soup mixed with MARUKOME, made by MARUKOME Co., Ltd., sugar degree 41.9%) and added with 0.2g of oil (0.0002 times per sugar) or 0.2g of rapeseed The oil, in which 0.2 g of oil was dissolved in rapeseed oil, dissolved 1% by weight of partially hydrogenated linseed oil (POV of 170), and then tasted to evaluate sweet and salty taste. The results are shown in Table 9.

<鹹度> <salty>

4‧相較於對照下感覺非常強烈 4‧It feels very strong compared to the control

3‧相較於對照下有強烈感覺 3‧ has a strong feeling compared to the control

2‧相較於對照下稍微有強烈感覺 2‧ slightly stronger than the control

1‧相等於對照或相較於對照下感覺較弱 1‧ is equivalent to the control or feels weaker than the control

由上述表9可知,添加有本發明增強劑的味增之甜味及鹹味,相較於對照之菜籽油可獲得顯著的增強效果。 As apparent from the above Table 9, the sweetness and the salty taste of the flavor added with the reinforcing agent of the present invention were remarkably enhanced as compared with the rapeseed oil of the control.

【實施例27】<番茄醬> [Example 27] <Ketchup>

於一般市面上所販賣之番茄醬(品名:成熟番茄之披薩醬、日本KOGOME股份有限公司製、糖度17.2%)20g上,對添加0.2g之油脂(每糖度添加0.0006倍)或0.2g之菜籽油所得之番茄醬的甜味,其中0.2g油脂係於菜籽油中溶解1重量%之部份氫化亞麻籽油(POV為170)而進行評價。結果如表10所示。 Adding 0.2g of fat (0.0006 times per sugar) or 0.2g of vegetables to 20g of ketchup (name: ripe tomato pizza sauce, Japanese KOGOME Co., Ltd., sugar content: 17.2%) sold in the market. The sweetness of the ketchup obtained from the seed oil, wherein 0.2 g of the oil was evaluated by dissolving 1% by weight of partially hydrogenated linseed oil (POV of 170) in the rapeseed oil. The results are shown in Table 10.

由上述表10可知,添加有本發明增強劑的番茄醬之甜味,相較於對照之菜籽油可有意義增強。另外,於添加增強劑之番茄醬,具有銳利的酸味及圓潤的口感。 As can be seen from the above Table 10, the sweetness of the ketchup to which the enhancer of the present invention was added was significantly enhanced as compared with the control rapeseed oil. In addition, the ketchup added with the enhancer has a sharp sour taste and a rounded mouthfeel.

【實施例28】<柑橘醬> [Example 28] <citrus sauce>

於一般市面上所販賣之柑橘醬(品名:Ponzu Vinegar、日本MIZKAN股份有限公司製、糖度25.9%)20g,添加0.2g之油脂(每糖度添加0.0004倍)或0.2g之菜籽油,其中0.2g油脂係於菜籽油中溶解1重量%之部份氫化亞麻籽油(POV為170),再評價柑橘醬之甜味。結果如表11所示。 20g of citrus sauce (name: Ponzu Vinegar, manufactured by MIZKAN Co., Ltd., Japan, 25.9%) sold in the market, adding 0.2g of oil (0.0004 times per sugar) or 0.2g of rapeseed oil, of which 0.2 g oil is dissolved in rapeseed oil to dissolve 1% by weight of partially hydrogenated linseed oil (POV is 170), and then the sweet taste of citrus sauce is evaluated. The results are shown in Table 11.

由上述表11可知,添加有本發明增強劑的柑橘醬之甜味,相較於對照之菜籽油可獲得顯著的增強效果。另外,於添加增強劑之柑橘醬,沒有銳利的酸味並有圓潤的口感。 As apparent from the above Table 11, the sweetness of the citrus sauce to which the enhancer of the present invention was added was able to obtain a remarkable reinforcing effect as compared with the rapeseed oil of the control. In addition, the citrus sauce to which the enhancer is added has no sharp acidity and a rounded mouthfeel.

【實施例29】<咖哩醬汁> [Example 29] <Curry Sauce>

於一般市面上所販賣之咖哩醬汁(品名:Golden Curry、日本S&B食品股份有限公司製)14g,添加2.2g之油脂或2.2g之菜籽油,其中2.2g油脂係於菜籽油中溶解1重量%之部份氫化亞麻籽油(POV為170),再以200g熱開水溶化得之咖哩(糖度(%):9.0%)且評價此咖哩的甜味(每糖度添加0.001倍)。結果如表12所示。 14g of curry sauce (product name: Golden Curry, made by Japan S&B Food Co., Ltd.) sold in the market, 2.2 g of oil or 2.2 g of rapeseed oil, 2.2 g of oil is dissolved in rapeseed oil 1% by weight of partially hydrogenated linseed oil (POV of 170), which was then melted with 200 g of hot water to obtain a curry (sugar degree (%): 9.0%) and the sweetness of the curry (0.001 times per sugar added) was evaluated. The results are shown in Table 12.

由上述表12可知,添加有本發明增強劑的咖哩醬汁之甜味,相較於對照之菜籽油可獲得顯著的增強效果。 As apparent from the above Table 12, the sweetness of the curry sauce to which the enhancer of the present invention was added was able to obtain a remarkable reinforcing effect as compared with the rapeseed oil of the control.

【實施例30】<甜甜圈> [Example 30] <Donuts>

調製出表13所示之甜甜圈麵團(添加糖分:17重量%)。於此甜甜圈麵團940g中添加混合0.7g(每糖度添加0.0004倍)之部份氫化亞麻籽油(POV為170)或0.7g之菜籽油。 The dough dough shown in Table 13 (added sugar: 17% by weight) was prepared. To this 940 g of donut dough, 0.7 g (0.0004 times per sugar) of partially hydrogenated linseed oil (POV of 170) or 0.7 g of rapeseed oil was added.

評價出利用180℃之棕櫚油且將上述甜甜圈麵團油炸1分40秒之蛋糕甜甜圈(cake doughnut)。結果如表14所示。 A cake doughnut using a palm oil of 180 ° C and frying the above dough dough for 1 minute and 40 seconds was evaluated. The results are shown in Table 14.

由上述表14可知,添加有本發明增強劑的甜甜圈之甜味及乳香味,相較於對照之菜籽油可獲得顯著的增強效果。 As apparent from the above Table 14, the sweetness and milky aroma of the doughnut to which the reinforcing agent of the present invention was added were able to obtain a remarkable reinforcing effect as compared with the rapeseed oil of the control.

再者,於油炸過之部分甜甜圈中,對舖有巧克力的甜恬圈進行評價。結果如表15所示。巧克力風味之基準如下。 In addition, in the fried doughnuts, the chocolate-coated sweet doughnuts were evaluated. The results are shown in Table 15. The basis of the chocolate flavor is as follows.

<巧克力風味> <Chocolate flavor>

4‧相較於對照下感覺非常強烈 4‧It feels very strong compared to the control

3‧相較於對照下有強烈感覺 3‧ has a strong feeling compared to the control

2‧相較於對照下稍微有強烈感覺 2‧ slightly stronger than the control

1‧相等於對照或相較於對照下感覺較弱 1‧ is equivalent to the control or feels weaker than the control

由上述表15可知,添加本發明增強劑且舖有巧克力的甜甜圈,除了甜味及乳香味外,巧克力風味也係顯著的增強效果。 As apparent from the above Table 15, the chocolate-coated doughnut to which the reinforcing agent of the present invention is added has a remarkable reinforcing effect in addition to the sweetness and the milky flavor.

【實施例32】<香料油> [Example 32] <flavor oil>

於一般市面上所販賣之香料油(品名:SavorUP奶油風味油、日本J-OIL-MILLS股份有限公司製)100g中,將添加0.3g之部份氫化亞麻籽油(POV為170)或0.3g之菜籽油,即各可獲得香料油。於混合有全蛋100g、牛奶15g及食鹽0.5g的蛋液中,各添加3重量%之上述香料油且均勻混合,即可獲得炒蛋麵團(糖度3.8.%)。以5g之菜籽油作為底油且藉由一般的方法各製作出炒蛋(scrambled egg)而試吃。所得之香料油之評價結果如表16所示。 0.3g of partially hydrogenated linseed oil (POV of 170) or 0.3g will be added to 100g of the fragrance oil (product name: SavorUP cream flavor oil, manufactured by J-OIL-MILLS Co., Ltd.) sold in the market. Rapeseed oil, that is, each can obtain a fragrance oil. In the egg mixture in which 100 g of whole eggs, 15 g of milk, and 0.5 g of salt were mixed, 3 wt% of the above-mentioned fragrance oil was added and uniformly mixed to obtain a scrambled egg dough (sugar degree: 3.8%). A 5 g of rapeseed oil was used as a base oil, and a scrambled egg was prepared by a general method to try it. The evaluation results of the obtained fragrance oil are shown in Table 16.

由上述表16可知,已添加本發明增強劑的香料油,其甜味及乳香味相較於對照之菜籽油可獲得顯著的增強效果。另外,乳香味之增強 效果相對也可獲得香料。 As apparent from the above Table 16, the fragrance oil to which the enhancer of the present invention has been added, the sweetness and the milky flavor can obtain a remarkable reinforcing effect as compared with the rapeseed oil of the control. In addition, the enhancement of milk aroma The effect is also relatively good.

【實施例33~36】<奶油> [Examples 33 to 36] <Cream>

利用表17所示之比例而搭配50℃之菜籽油、市面上販賣之奶油(品名:日本雪印北海道奶油、雪印MEGMILK股份有限公司製、糖度0.2%)及部份氫化亞麻籽油(POV為170)來加以溶解。表17為表示冷卻到室溫後之油脂的評價結果。 Use the ratio shown in Table 17 with 50°C rapeseed oil, commercially available cream (name: Japanese snow-printed Hokkaido cream, snow-printed MEGMILK Co., Ltd., sugar content 0.2%) and partially hydrogenated linseed oil (POV is 170) to dissolve. Table 17 shows the evaluation results of the fats and oils after cooling to room temperature.

由上述表17可知,已添加本發明增強劑的油脂,其甜味及乳香味相較於對照可獲得顯著的增強效果。再者,若加上部份氧化氫化亞麻籽油,即使減少1/4的奶油量也可獲得相同之風味(甜味、乳風味及鹹味)。另外,從實施例33與對照之對比來看,每糖度之部份氧化氫化脂添加量,即使為100倍也可獲得效果。 As apparent from the above Table 17, the fats and oils to which the reinforcing agent of the present invention has been added have a remarkable reinforcing effect as compared with the control. Furthermore, if a part of the oxidized linseed oil is added, the same flavor (sweet, milky and salty) can be obtained even if the amount of cream is reduced by 1/4. Further, from the comparison of Example 33 with the control, the amount of partial oxidation of hydrogenated fat per degree of sugar was obtained even if it was 100 times.

再者,將市面上販賣之麵包(品名:超熟切8片、敷島製麵包股份有限公司製)切成1/4且各塗布1ml表17所述之油脂,然後同樣評價其風味後,即可獲得與表17所述之相同結果。因此,已添加本發明增強劑的油脂,即使塗布於麵包上,其甜味、乳風味相較於對照可獲得顯著的增強效果。再者,若加上部份氧化氫化亞麻籽油,即使減少1/4的奶油量也可獲 得相同之風味(甜味、乳風味及鹹味)。 In addition, the commercially available bread (product name: 8 pieces of super cooked, made by Kojima Bread Co., Ltd.) was cut into 1/4, and 1 ml of the oil and fat described in Table 17 was applied, and then the flavor was evaluated in the same manner. The same results as described in Table 17 were obtained. Therefore, the fat or oil to which the reinforcing agent of the present invention has been added, even if it is applied to bread, its sweetness and milk flavor can obtain a remarkable reinforcing effect as compared with the control. Furthermore, if a part of the oxidized linseed oil is added, even a 1/4 amount of cream can be obtained. Get the same flavor (sweet, creamy and salty).

【實施例37】<油炸蔬菜奶油> [Example 37] <Fried Vegetable Cream>

將市面上販賣之天婦羅粉(品名:油炸酥脆的日清天婦羅粉、日清製粉股份有限公司製)100g溶解於冷水150g,即可獲得天婦羅奶油。各將洋蔥112g、胡蘿蔔32g、婉豆16g切成長度5公分寬度為3公分且撒了麵粉,然後於灑上90g上述之天婦羅粉之油炸蔬菜子250g,各添加2.5g油脂或2.5g之菜籽油,其中2.5g油脂係於菜籽油中溶解1重量%之部份氫化亞麻籽油(POV為170),藉由普通方法且以天婦羅油來油炸,作成油炸蔬菜(蔬菜之糖度7.8%)且加以試吃。結果為表18所示。 The tempura cream was obtained by dissolving 100 g of tempura powder (product name: fried crispy Nissin tempura powder, Nisshin Milluquan Co., Ltd.), which was sold in the market, in 150 g of cold water. Each of 112 g of onion, 32 g of carrot, and 16 g of cowpea were cut into a length of 5 cm and a width of 3 cm and sprinkled with flour, and then sprinkled with 90 g of the above-mentioned tempura flour fried vegetable 250 g, each adding 2.5 g of fat or 2.5 g of rapeseed oil, wherein 2.5 g of oil is dissolved in rapeseed oil to dissolve 1% by weight of partially hydrogenated linseed oil (POV is 170), which is fried by ordinary methods and with tempura oil to make fried Vegetables (sweetness of vegetables 7.8%) and try to eat. The results are shown in Table 18.

由上述表18可知,於天婦羅奶油中添加本發明增強劑的油炸蔬菜,其甜味相較於對照組可獲得顯著的增強效果。 As apparent from the above Table 18, the fried vegetables to which the reinforcing agent of the present invention was added to the tempura cream had a remarkable reinforcing effect compared with the control group.

【實施例38~40】<人造奶油> [Examples 38 to 40] <Margarine>

於表19所示之組成分中且於保溫約60℃之油相(oil phase)內,一邊攪拌水相且一邊放入而進行預乳化後,透過刮板式熱交換器(votator)且混煉冷卻,即可調製出表式人造奶油。於99g之表格式人造奶油中,添加將部份之1g菜籽油或表20所示之油而置換成部分氫化亞麻籽 油。有關各風味(甜味、乳香味、惡臭味),其評價結果如表20所示。 In the oil phase of the composition shown in Table 19 and in the oil phase of about 60 ° C, the aqueous phase was stirred and pre-emulsified, and then passed through a scraper type heat exchanger and kneaded. Cool down to prepare a table of margarine. In a 99g table format margarine, add 1g of rapeseed oil or the oil shown in Table 20 to replace partially hydrogenated flaxseed. oil. The evaluation results of each flavor (sweetness, milky flavor, and malodor) are shown in Table 20.

由上述表20可知,已添加本發明增強劑0.025%以上的人造奶油之甜味及乳風味,相較於對照之菜籽油可獲得顯著的增強效果。尤其利用添加0.05重量%以上之增強劑,可提高甜味及乳風味之增強效果。 As apparent from the above Table 20, the sweetness and milk flavor of the margarine having 0.025% or more of the reinforcing agent of the present invention were added, and a remarkable reinforcing effect was obtained as compared with the rapeseed oil of the control. In particular, by adding 0.05% by weight or more of the reinforcing agent, the sweetness and the flavor enhancement of the milk flavor can be improved.

【實施例41~43】<麵包> [Examples 41 to 43] <Bread>

於油脂(棕櫚油:棕櫚油酸(IV67)=7:3)內添加如表22所示之油脂並調製出實驗用油脂。利用普通方法並且將實驗用油脂搭配表21所示之組成份後與麵包材料混合製造出吐司麵包。評價烘烤一日後之風味(甜味、乳風味、惡臭味)。評價結果如表22所示。 The oil and fat shown in Table 22 was added to fats and oils (palm oil: palmitoleic acid (IV67) = 7:3), and the test fats and oils were prepared. Toast bread was prepared by mixing the experimental grease with the components shown in Table 21 and mixing with the bread material by an ordinary method. The flavor (sweet, milky, malodorous) after one day of baking was evaluated. The evaluation results are shown in Table 22.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於麵包之麵團材料搭中配0.042重量%以上,即可讓麵包之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the bread can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and blending the dough of the bread with 0.042% by weight or more.

【實施例44~46】<餅乾> [Examples 44 to 46] <cookies>

於油脂(棕櫚油:棕櫚油酸(IV67)=7:3)內添加如表24所示之油脂且調製出實驗用油脂。依據表23而搭配實驗用油脂製作出餅乾麵團材料。製冰盒成型後,再以普通方法來評價烘烤一日後之風味(甜味、乳風味、惡臭味)。評價結果如表24所示。 The oil and fat shown in Table 24 was added to fats and oils (palm oil: palmitoleic acid (IV67) = 7:3), and the test fats and oils were prepared. According to Table 23, the biscuit dough material was prepared by using the experimental grease. After the ice making box is molded, the flavor (sweet, milky, malodorous) after one day of baking is evaluated by an ordinary method. The evaluation results are shown in Table 24.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於餅乾麵團材料搭配0.06重量%以上,即可讓餅乾之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the biscuit can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and the biscuit dough material in an amount of 0.06% by weight or more.

【實施例47~49】<巧克力> [Examples 47 to 49] <Chocolate>

可可亞奶油(品名:可可亞奶油201、日本明治股份有限公司)係將部份之可可亞奶油添加表26所示之巧克力中之部分氧化氫化脂的量。巧克力麵團搭配有表25所示之量而製作出。利用平板回火法(slabtempering)(製法:油脂溶解‧混合~細研磨~精煉~調溫~成型)將麵團材料製作出方型之板狀巧克力(牛奶巧克力),以17℃燒成10天。最後評價熟後之巧克力。評價結果如表26所示。 Cocoa butter (product name: Cocoa Butter 201, Japan Meiji Co., Ltd.) is a portion of cocoa butter that is added to the amount of partial oxidation of hydrogenated fat in the chocolate shown in Table 26. The chocolate dough was prepared in the same amount as shown in Table 25. Using a slabtempering method (preparation method: fat dissolving, mixing, fine grinding, refining, tempering, molding), the dough material is made into a square-shaped chocolate (milk chocolate), which is fired at 17 ° C for 10 days. Finally, the cooked chocolate is evaluated. The evaluation results are shown in Table 26.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於巧克力麵團內搭配0.05重量%以上,即可讓巧克力之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and the milk flavor of the chocolate can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and blending 0.05% by weight or more in the chocolate dough.

【實施例50】<燉煮調料> [Example 50] <Stew seasoning>

1.粉末油脂之調製 1. Modulation of powdered fat

利用表27所示之調製例13之比例來搭配部份氫化亞麻籽油(POV為120),而得之粉末油脂用組成物。此組成物之油份為45重量%。於此組成物之油份為45重量%添加50重量部之水且再藉由攪拌來獲得O/W型乳膠。進一步將所得之乳膠利用噴霧乾燥(品名:B-290、日本BUCHI公司製)且藉由乾 燥粉末而得之粉末油脂。調製之粉末油脂,油份為45%,粒子直徑為1μm。另外,如調製例14所示,利用相同於調製例13之步驟而調製出(油份為45%,粒子直徑為1μm)未添加部份氫化亞麻籽油(POV為120)之粉末油脂。 The composition of the powdered fat and oil was obtained by using a ratio of the preparation example 13 shown in Table 27 to a portion of the hydrogenated linseed oil (POV of 120). The oil content of this composition was 45% by weight. The oil of this composition was added in an amount of 50% by weight to 50 parts by weight of water and further stirred to obtain an O/W type latex. Further, the obtained latex was spray-dried (product name: B-290, manufactured by BUCHI, Japan) and dried. A powdered fat obtained by drying a powder. The prepared powdery fat and oil had an oil content of 45% and a particle diameter of 1 μm. Further, as shown in Preparation Example 14, a powdery fat or oil having a partial hydrogenated linseed oil (POV of 120) was prepared by the same procedure as in Preparation Example 13 (45% oil component, particle diameter: 1 μm).

2.粉末油脂之評價 2. Evaluation of powdered oil

將442.5g之水倒入自家用的鍋子,加火使其沸騰。關掉火之後,添加市面上販賣之燉煮調料(顆粒狀)(品名:燉煮調料〈奶油〉、House食品股份有限公司製)57.5g且均勻混合。用小火加熱2分鐘就可調製出燉煮調料。預先於容器秤出表28所示之粉末油脂量再添加燉煮料100g、糖分5.6%)。攪拌到溶解為止。所得之燉煮料之評價結果如表28所示。 Pour 442.5g of water into the pot from home and add to the fire to boil. After the fire was turned off, 57.5 g of a stewed seasoning (granular) (product name: stew seasoning <cream>, manufactured by House Food Co., Ltd.) sold in the market was added and uniformly mixed. Stew and seasoning can be prepared by heating on low heat for 2 minutes. The amount of the powdered fat shown in Table 28 was weighed in advance in the container, and 100 g of the stew and 5.6% of the sugar were added. Stir until dissolved. The evaluation results of the obtained stews are shown in Table 28.

由以上結果可知,利用將由粉末油脂所構成之本發明增強劑作為部分氧化氫化脂且於燉煮調料搭配0.01重量,即可讓燉煮調料之甜味及 乳風味獲得增強。 From the above results, it is understood that the sweetener of the present invention comprising the powdered fat and oil can be used as a partial oxidized hydrogenated fat and the stewing seasoning can be combined with 0.01 weight to make the sweetness of the stew seasoning and The milk flavor is enhanced.

【實施例51~52】<湯料(1)> [Examples 51 to 52] <Soup (1)>

於市面上販賣之湯料(品名:Knorr(註冊商標)杯湯、玉米濃湯、日本knorr食品股份有限公司製、糖分7.8%)11.3g上,放入熱水88.7g且均勻攪拌。再者,添加粉末油脂,其添加量如表29所示且均勻攪拌。溶解之湯料的評價結果如表29所示。 On the market, the soup (name: Knorr (registered trademark) cup soup, corn soup, made by Japan Knorr Food Co., Ltd., sugar 7.8%) was placed on 11.3 g of hot water, and 88.7 g of hot water was placed and uniformly stirred. Further, powdered fats and oils were added, and the amounts thereof were as shown in Table 29 and uniformly stirred. The evaluation results of the dissolved soup are shown in Table 29.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於湯料添加0.005重量%以上,即可讓湯料之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the soup can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.005% by weight or more to the soup.

於市面上販賣之湯料(品名:knorr(註冊商標)杯湯cold、玉米濃湯、日本knorr食品股份有限公司製)13g上,添加牛乳87g且均勻攪拌。再者,添加粉末油脂,其添加量如表30所示且均勻攪拌。溶解之湯料的評價結果如表30所示。 To 13 g of soup stock (product name: knorr (registered trademark) cup soup cold, corn soup, manufactured by Knorr Foods Co., Ltd.), 87 g of milk was added and uniformly stirred. Further, powdered fats and oils were added, and the amounts thereof were as shown in Table 30 and uniformly stirred. The evaluation results of the dissolved soup are shown in Table 30.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於湯料添加0.005重量%以上,即可讓湯料之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the soup can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.005% by weight or more to the soup.

【實施例55~56】<可可亞> [Examples 55 to 56] <Cocoa>

於市面上販賣之即溶可可粉(品名:MILKCOCOA、日本森永製果股份有限公司製、糖分14.6%)16.7g上,放入熱水83.3g且均勻攪拌。再者,添加粉末油脂,其添加量如表31所示。均勻攪拌之可可亞之評價結果如表31所示。 On the market, 16.7 g of instant cocoa powder (name: MILKCOCOA, manufactured by Morinaga Kogyo Co., Ltd., sugar, 14.6%) was placed in the market, and 83.3 g of hot water was placed and uniformly stirred. Further, powdered fats and oils were added, and the amounts thereof were as shown in Table 31. The evaluation results of cocoa with uniform stirring are shown in Table 31.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於可可亞粉添加0.005重量%以上,即可讓可可亞粉之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the cocoa powder can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.005 wt% or more to the cocoa powder.

【實施例57~58】<煎餅> [Examples 57 to 58] <pancake>

於碗內添加全蛋16.7g及牛奶33.3g且均勻混合攪拌。添加市面上販賣之煎餅混合料(品名:hotcake mix、日本森永製果股份有限公司製、糖分34..2%)50.0g,再者,添加如表32所示既定量之粉末油脂且均勻攪拌,調製出煎餅麵團。以加熱160℃之熱鐵板燒考煎餅麵團而得之煎餅。評價結果如表32所示。 In the bowl, 16.7 g of whole eggs and 33.3 g of milk were added and uniformly mixed and stirred. Add 50.0g of pancake mix (name: hotcake mix, made by Japan Morinaga Fruit Co., Ltd., sugar 34..2%), and add the same amount of powdered fat as shown in Table 32 and stir evenly. , prepare the pancake dough. Pancakes obtained by burning pancake dough with a hot iron plate heated at 160 °C. The evaluation results are shown in Table 32.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於煎餅麵團添加0.05重量%以上,即可讓煎餅麵團之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the pancake dough can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.05% by weight or more to the pancake dough.

【實施例59~60】<甜甜圈> [Examples 59 to 60] <Doughnuts>

於碗內放入全蛋21.7g、砂糖4.4g、溶解之奶油8.7g及市面上販賣之煎餅混合料(日本森永製果股份有限公司製)65.2g且添加如表33所示量之粉末油脂且均勻攪拌,調製出甜甜圈麵團。利用麵桿將甜甜圈麵團延展厚度為10mm。將麵團作成模型再以180℃油油炸,所得之甜甜圈評價結果如表33所示。 In a bowl, 21.7 g of whole egg, 4.4 g of sugar, 8.7 g of dissolved cream, and 65.2 g of a pancake mixture (made by Nippon Morinaga Co., Ltd.) sold in the market were added, and powder of the amount shown in Table 33 was added. Stir well and prepare the dough dough. The donut dough was stretched to a thickness of 10 mm using a face rod. The dough was modeled and fried in oil at 180 ° C, and the obtained doughnut evaluation results are shown in Table 33.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於甜甜圈麵團添加0.05重量%以上,即可讓甜甜圈麵團之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the dough dough can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.05% by weight or more to the dough dough.

【實施例61~63】<布丁> [Examples 61 to 63] <Pudding>

於鍋子放入布丁之混合料(品名:布丁L、House食品股份有限公司、糖分24.2%)11.1g,牛奶88.9g及表34所示之粉末油脂量。一邊攪動而一邊以中火加熱,若沸騰的話再關小火煮約1分鐘。倒入容器且放進冰箱冷藏而完成布丁製作。布丁之評價結果如表34所示。 In the pot, the mixture of pudding (product name: pudding L, House Food Co., Ltd., sugar 24.2%) 11.1 g, milk 88.9 g and the amount of powder grease shown in Table 34 were placed. While stirring, heat it on medium heat. If it is boiling, turn off the heat for about 1 minute. Pour into the container and put it in the refrigerator to complete the pudding. The evaluation results of the pudding are shown in Table 34.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於布丁添加0.003重量%以上,即可讓步丁之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetener and the milk flavor of the step can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.003% by weight or more to the pudding.

【實施例64~66】<發泡鮮奶油> [Examples 64 to 66] <foamed fresh cream>

於鍋子放入市面上販賣之發泡鮮奶油混合料(品名:簡單Whip、日本雪印MEGMILK股份有限公司製,糖度0.2%)15.1g、熱水28.3g及表35所示既定量之粉末油脂。再者,於混合物添加牛奶56.6g,攪拌約1分30秒而調製出發泡鮮奶油。發泡鮮奶油之評價結果如表35所示。 The pot was placed in a commercially available foamed fresh butter mix (product name: Simple Whip, Japan Snow Print MEGMILK Co., Ltd., sugar content 0.2%), 15.1 g, hot water 28.3 g, and the powdered fat shown in Table 35. Further, 56.6 g of milk was added to the mixture, and the mixture was stirred for about 1 minute and 30 seconds to prepare a foamed fresh cream. The evaluation results of the foamed fresh cream are shown in Table 35.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於發泡鮮奶油添加0.003重量%以上,即可讓發泡鮮奶油之甜味及乳風味獲得增強。冷藏保存24小時後,依然可維持稍有劣化之甜味增強效果及乳風味增強效果。 From the above results, it is understood that the sweetness and milk flavor of the foamed fresh cream can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.003 wt% or more to the foamed fresh cream. After being stored for 24 hours in a refrigerated state, the slightly enhanced sweetness enhancing effect and the milk flavor enhancing effect can be maintained.

【實施例67~68】<杏仁豆腐> [Examples 67 to 68] <Almond Tofu>

於鍋子放入杏仁豆腐混合料(品名:陳進一 杏仁豆腐、日本共立食品股份有限公司製、糖分18.3%)15.1g、熱水28.3g及表36所示既定量之粉末油脂且攪動1分30秒。於混合物中放入牛奶56.6g及加以攪拌。倒入容器內以冰箱加以冷藏即可得之杏仁豆腐。其評價結果如表36所示。 In the pot, add the almond tofu mixture (product name: Chen Jinyi almond tofu, made by Japan Kyori Food Co., Ltd., sugar 18.3%), 15.1g, hot water 28.3g, and the amount of powdered fat shown in Table 36 and stirred for 1 minute 30 second. 56.6 g of milk was placed in the mixture and stirred. Pour the tofu into the container and refrigerate it in the refrigerator. The evaluation results are shown in Table 36.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於杏仁豆腐添加0.01重量%以上,即可讓否仁豆腐之甜味及乳香味獲得增強。 From the above results, it is understood that the sweetener and the milky flavor of the glutinous tofu can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and adding 0.01% by weight or more to the almond tofu.

【實施例69~70】<咖啡(1)> [Examples 69 to 70] <Coffee (1)>

注入熱水98.62且均勻攪拌市面上販賣之即溶咖啡(品名:Blendy、AJINOMOTO GENERAL FOODS.INC、糖分1.5%)1.38g及表37所示既定量之粉末油脂而完成咖啡。咖啡評價結果如表36所示。 Coffee was injected by injecting hot water 98.62 and uniformly stirring the instant coffee (name: Blendy, AJINOMOTO GENERAL FOODS. INC, sugar 1.5%), 1.38 g, and the powdered fat shown in Table 37. The coffee evaluation results are shown in Table 36.

由以上結果可知,利用將本發明增強劑作為部分氧化氫化脂且於即溶咖啡搭配0.005重量%以上,即可讓咖啡之甜味及乳風味獲得增強。 From the above results, it is understood that the sweetness and milk flavor of the coffee can be enhanced by using the reinforcing agent of the present invention as a partial oxidized hydrogenated fat and 0.005% by weight or more of the instant coffee.

【實施例71~72】<咖啡(2)> [Examples 71 to 72] <Coffee (2)>

注入熱水98.62且均勻攪拌市面上販賣之即溶咖啡(品名:Blendy、AJINOMOTO GENERAL FOODS.INC製、糖分1.5%)1.35g、市面上販賣之乳化粉(Creaming Powder)(品名:MARIM、HALF、AJINOMOTO GENERAL FOODS.INC製、糖分2.4%)2.03g及表38所示既定量之粉末油脂而完成咖啡。咖啡評價結果如表38所示。 Inject hot water 98.62 and evenly mix the instant coffee (name: Blendy, AJINOMOTO GENERAL FOODS. INC, sugar 1.5%) 1.35g, commercially available emulsified powder (Creaming Powder) (product name: MARIM, HALF, Coffee was prepared from AJINOMOTO GENERAL FOODS. INC, with a sugar content of 2.4%) of 2.03 g and a quantitative amount of powdered fat shown in Table 38. The coffee evaluation results are shown in Table 38.

由以上結果可知,利用將本發明之部分氧化氫化脂作為增強劑且以0.005重量%以上於即溶咖啡搭配,即可讓咖啡之甜味及乳香味獲得增強。 From the above results, it is understood that the sweetness and the milky flavor of the coffee can be enhanced by using the partial hydrogenated hydrogenated fat of the present invention as a reinforcing agent and blending 0.005 wt% or more with instant coffee.

【實施例73】<乳化粉(Creaming Powder(ICP))> [Example 73] <Creaming Powder (ICP)>

1.乳化粉(ICP)的調製利用表39之調製例15所示之比例即可獲得配合部份氫化亞麻籽油(POV為120)之乳化粉用組合物。此種組合物之油份為45重量%。於此種組合物50重量%添加水50重量%且藉由攪拌即可獲得O/W型乳膠。再者,將所得之乳膠利用噴霧乾燥(品名:B-290、日本BUCHI公司製)且藉由乾燥粉末而得之。調製之ICP,油份為20%,粒子直徑為0.5μm。另外,如調製例15所示,利用相同於調製例16之步驟而調製出(油份為20%,粒子直徑為0.5μm)不添加有部份氫化亞麻籽油(POV為120)之ICP。 1. Preparation of emulsified powder (ICP) A composition for emulsifying powder containing a part of hydrogenated linseed oil (POV: 120) was obtained by using the ratio shown in Preparation Example 15 of Table 39. The oil content of this composition was 45% by weight. An O/W type latex was obtained by adding 50% by weight of water to 50% by weight of such a composition and stirring. Further, the obtained latex was obtained by spray drying (product name: B-290, manufactured by BUCHI, Japan) and dried by powder. The prepared ICP had an oil content of 20% and a particle diameter of 0.5 μm. Further, as shown in Preparation Example 15, an ICP having a partial hydrogenated linseed oil (POV of 120) was prepared by the same procedure as in Preparation Example 16 (oil content: 20%, particle diameter: 0.5 μm).

2. ICP的評價 2. Evaluation of ICP

吃完調製例15或16之ICP後,如表40所示,相較於調製例15之ICP或調製例16之ICP來說,可增加甜味及乳香味。 After the ICP of Preparation Example 15 or 16 was eaten, as shown in Table 40, the sweetness and the milky flavor were increased as compared with the ICP of Preparation Example 15 or the ICP of Preparation Example 16.

按,以上所述,僅係本發明之較佳實施例,惟本發明所主張之權利範圍,並不侷限於此,按凡熟悉該項技藝人士,依據本發明所揭露之技術內容,可輕易思及之等效變化,均應屬不脫離本發明之保護範疇。 The above is only the preferred embodiment of the present invention, but the scope of the claimed invention is not limited thereto, and the technical content disclosed in the present invention can be easily obtained by those skilled in the art. Equivalent changes in thought should be made without departing from the scope of protection of the present invention.

Claims (13)

一種甜味及/或乳香味增強劑,係包含過氧化價為25~300之部分氧化氫化油脂為有效成分。 A sweet and/or milk flavor enhancer comprising a partially oxidized hydrogenated fat having a peroxidation price of 25 to 300 as an active ingredient. 如請求項1所述之甜味及/或乳香味增強劑,其中該部分氧化氫化油脂之反式脂肪酸(Trans-fatty acid)含量為5~75重量%。 The sweetness and/or milk flavor enhancer according to claim 1, wherein the partially oxidized hydrogenated fat has a trans-fatty acid content of 5 to 75% by weight. 如請求項1所述之甜味及/或乳香味增強劑,其中於該部分氧化氫化油脂之所有構成脂肪酸中的C18:2反式型異構體含量為5~60重量%。 The sweetness and/or milk flavor enhancer according to claim 1, wherein the C18:2 trans isomer content in all of the constituent fatty acids of the partially hydrogenated hydrogenated fat is from 5 to 60% by weight. 如請求項1所述之甜味及/或乳香味增強劑,其中該部分氧化氫化油脂之碘價(iodine value)為35~135。 The sweetness and/or milk flavor enhancer according to claim 1, wherein the partially oxidized hydrogenated fat has an iodine value of 35 to 135. 如請求項1之甜味及/或乳香味增強劑,其中該部分氧化氫化油脂之含量為0.003~10重量%。 The sweetness and/or milk flavor enhancer of claim 1, wherein the partially hydrogenated hydrogenated fat is contained in an amount of 0.003 to 10% by weight. 如請求項1之甜味及/或乳香味增強劑,其由粉末油脂所構成。 A sweetness and/or milk flavor enhancer according to claim 1, which consists of a powdered fat. 如請求項6之甜味及/或乳香味增強劑,其中進一步將含有過氧化價為25~300之部分氧化氫化油脂、食用油脂、乳化劑、粉末化基材以及水的混合物攪拌所得之乳膠粉末乾燥化而取得。 The sweetness and/or milk flavor enhancer according to claim 6, wherein the latex obtained by stirring a mixture of a partially oxidized hydrogenated fat, a food fat, an emulsifier, a powdered substrate and water having a peroxide price of 25 to 300 is further provided. The powder is obtained by drying. 如請求項7之甜味及/或乳香味增強劑,其中該粉末之脂肪球直徑(中數粒徑)為0.2~2.0μm。 The sweetness and/or milk flavor enhancer of claim 7, wherein the powder has a fat globule diameter (median diameter) of 0.2 to 2.0 μm. 一種油脂組合物係含有請求項1所述之甜味及/或乳香味增強劑。 A fat or oil composition comprising the sweetness and/or milk flavor enhancer of claim 1. 一種食品,係含有請求項1所述之甜味及/或乳香味增強劑或使用上述的增強劑所調理過。 A food product comprising the sweetness and/or milk flavor enhancer of claim 1 or conditioned with the above-described enhancer. 一種甜味及/或乳香味增強劑之製造方法,係添加過氧化價為25~300之部分氧化氫化油脂作為有效成分。 A method for producing a sweetness and/or milk flavor enhancer is to add a partial oxidation hydrogenated fat or oil having a peroxidation price of 25 to 300 as an active ingredient. 一種調理食品之甜味及/或乳香味的增強方法,係將包含有過氧化價為25~300之部分氧化氫化油脂作為有效成份的甜味及/或乳香味增強劑添加於食材中調理而成。 The invention relates to a method for enhancing the sweetness and/or milk flavor of a food, which comprises adding a sweetener and/or a milk flavor enhancer containing a partial oxidation hydrogenated fat and oil having a peroxidation price of 25 to 300 as an active ingredient to the foodstuff. to make. 一種調理食品之甜味增強方法,係將包含過氧化價為25~300之部分氧化氫化油脂作為有效成分的甜味增強劑添加於食材中,調理部分氧化氫化油脂成為食材每糖度之0.00002~200倍而成。 The method for enhancing sweetness of a food for food is characterized in that a sweetness enhancer containing a part of oxidized hydrogenated fat having a peroxidation price of 25 to 300 as an active ingredient is added to the food, and a portion of the oxidized hydrogenated fat is adjusted to be 0.00002-200 per sugar content of the food. Doubled.
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