WO2014077019A1 - Sweetness and/or milk flavor enhancer - Google Patents
Sweetness and/or milk flavor enhancer Download PDFInfo
- Publication number
- WO2014077019A1 WO2014077019A1 PCT/JP2013/073476 JP2013073476W WO2014077019A1 WO 2014077019 A1 WO2014077019 A1 WO 2014077019A1 JP 2013073476 W JP2013073476 W JP 2013073476W WO 2014077019 A1 WO2014077019 A1 WO 2014077019A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sweetness
- oil
- partially hydrogenated
- milk flavor
- fat
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/007—Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0056—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/88—Taste or flavour enhancing agents
Definitions
- the present invention relates to a sweetness and / or milk flavor enhancer, and more specifically, reduces the amount of sweeteners, milk flavor flavors and the like used by strongly drawing out the taste of carbohydrates and milk fat that coexist in foods. It relates to the enhancement agent that is made possible.
- Patent Document 1 proposes a sweetness enhancer and a sweetness enhancing method for foods and drinks comprising long-chain highly unsaturated fatty acids and / or esters thereof. According to the invention of Patent Document 1, the sweetness of food and drink can be enhanced by adding it to food.
- Patent Document 2 proposes a milk flavor imparting or enhancing agent comprising 12-methyltridecanal.
- Patent Document 3 proposes a milk flavor enhancer or enhancer characterized by containing (Z) -6-octenal as an active ingredient. According to Patent Documents 2 and 3, a sweet creamy flavor unique to dairy products can be imparted by adding them to food.
- An object of the present invention is to provide a novel sweetness and / or milk flavor enhancer. Another object of the present invention is to provide a processed food containing the enhancer and a food cooked using the enhancer or the processed food.
- the present invention provides a sweetness and / or milk flavor enhancer containing an oxidized partially hydrogenated oil having a peroxide value of 25 to 300 as an active ingredient.
- sweetness enhancer means a substance or composition that acts to enhance the recognition of sweetness by a taste receptor when combined with a sweetening ingredient or sweetener in a foodstuff.
- Melk flavor means a milky taste or milky feeling peculiar to dairy products.
- the sweetness and / or milk flavor enhancer is referred to as “enhancement agent”, and the sweetness and / or milk flavor is abbreviated as “sweetness or the like”.
- the enhancer preferably has a trans fatty acid content of the oxidized partially hydrogenated oil of 5 to 75% by weight.
- the enhancer preferably has a C18: 2 trans isomer content of 5 to 60% by weight in the total constituent fatty acids of the oxidized partially hydrogenated oil.
- the enhancer preferably has an iodine value of 35 to 135 in the oxidized partially hydrogenated fat.
- the enhancer contains 0.003 to 10% by weight of the oxidized partially hydrogenated fat.
- the enhancer is made of, for example, powdered fats and oils.
- the above-mentioned powdered fats and oils can be obtained by further powder-drying an emulsion obtained by stirring a mixture containing oxidized partially hydrogenated fats and oils having a peroxide value of 25 to 300, edible fats and oils, emulsifier, powdered base material and water. .
- the fat sphere diameter (median diameter) of the powder is preferably 0.2 to 2.0 ⁇ m.
- the present invention also provides an oil and fat composition containing the enhancer.
- the present invention also provides a food product containing the enhancer or cooked using the enhancer.
- the present invention also provides a method for producing a sweetness and / or milk flavor enhancer, characterized in that an oxidized partially hydrogenated fat having a peroxide value of 25 to 300 is added as an active ingredient. provide.
- the present invention also provides sweetness of cooked food and / or cooking comprising adding a sweetness and / or milk flavor enhancer containing an oxidized partially hydrogenated fat or oil having a peroxide value of 25 to 300 as an active ingredient to a food material.
- a method for enhancing milk flavor is provided.
- the sweetness-enhancing agent is preferably added 0.00002 to 200 times as much as a partly oxidized hydrogenated fat and oil per sugar content. Therefore, the present invention provides a sweetness enhancer containing, as an active ingredient, oxidized partially hydrogenated fats and oils having a peroxide value of 25 to 300, so that the oxidized partially hydrogenated fats and oils are 0.00002 to 200 times the sugar content of the ingredients.
- a method for enhancing the sweetness of a cooked food comprising adding and cooking.
- the food or processed food to which the enhancer of the present invention is added can enhance the sweetness and / or milk flavor of additives such as ingredients and sweeteners. Therefore, if the enhancer of the present invention is used during the production, processing or cooking of food, the amount of additives such as sweeteners added to the food can be reduced while maintaining the sweetness of the food. In addition, it is possible to effectively use ingredients with low sweetness and the like.
- the enhancer of the present invention is expected to be used as an additive to, for example, low-calorie foods and dairy products.
- the enhancer of the present invention contains an oxidized partially hydrogenated oil (hereinafter referred to as “oxidized partially hydrogenated fat”) having a peroxide value (POV) within a certain range as an active ingredient.
- oxidized partially hydrogenated fat having a peroxide value (POV) within a certain range as an active ingredient.
- POV peroxide value
- the lower limit of the POV of the oxidized partially hydrogenated fat is 25 meq / kg, preferably 28 meq / kg, more preferably 30 meq / kg, still more preferably 80 meq / kg.
- the upper limit of POV is 300 meq / kg, preferably 280 meq / kg, more preferably 200 meq / kg. If the POV is higher than 300 meq / kg, an unpleasant odor due to the enhancer (hereinafter referred to as “deteriorated odor”) may occur.
- the partially hydrogenated fat that is the basis for the oxidized partially hydrogenated fat usually contains several to several tens of weight% of cis-trans isomers and positional isomers of linoleic acid and oleic acid.
- the unsaturated fatty acid double bond is isomerized from the cis form to the trans form, resulting in by-trans fatty acid as a by-product and a positional isomer from which the double bond has moved. is there.
- the trans fatty acid content of the oxidized partially hydrogenated fat is usually 5 to 75% by weight, preferably 7 to 70% by weight, more preferably 45 to 70% by weight.
- the trans fatty acid content of the enhancer to which this oxidized partially hydrogenated fat is added in the following range is usually from 0.00015 to 7.5% by weight, preferably from 0.005 to 3.3% by weight.
- the trans fatty acid content means the sum of C18: 1, C18: 2 and C18: 3 trans isomers when analyzing partially hydrogenated fat using a gas chromatography method.
- the trans fatty acid content of fats and oils can be measured by gas chromatography according to the American Oil Chemistry Society official method (Ce1h-05).
- the content of the C18: 2 trans isomer in the total fatty acids of the above oxidized partially hydrogenated fat is preferably 5 to 60% by weight, more preferably 8 to 50% by weight, still more preferably 15 to 45% by weight. %, Most preferably 30 to 45% by weight.
- the C18: 1 trans isomer corresponds to all peaks that appear between the C18: 0 peak and the C18: 1 cis isomer peak when the sample is analyzed using gas chromatography. It is a general term for fatty acids.
- the C18: 2 trans isomer is all that appears between the peak of the C18: 1 cis isomer and the peak of the C18: 2 cis isomer when the sample is analyzed using gas chromatography.
- the weight ratio of the C18: 2 trans isomer content to the C18: 1 trans isomer content in all the constituent fatty acids of the above partially oxidized hydrogenated fat is preferably in the range of 0.2 to 1.8. If it is out of this range, the enhancer may emit a heat deterioration odor.
- the iodine value (IV) of the oxidized partially hydrogenated fat is preferably 35 to 135, more preferably 70 to 130. If the IV is lower than 35, sufficient effects may not be exhibited. Conversely, if the IV is higher than 135, when a certain amount is added to the food, the sweetness of the food or additive is extracted and strengthened. It can be difficult. IV is calculated by the Wiis method at the Japan Oil Chemists' Society. IV can also be determined by simple near infrared analysis. Am. Oil Chem. Soc. A very high correlation is obtained in 76 (6) 693-9 (1999). In the present Example, it computed by the near-infrared analysis method.
- Oxidized partially hydrogenated fat is a step of partially hydrogenating fats and oils until the C18: 2 trans isomer content in the total constituent fatty acids is preferably 5 to 60% by weight, and the fats and fats have a peroxide value of 25 to 300 meq / It can be obtained by a production method including a step of oxidizing until kg.
- the order of the partial hydrogenation treatment and oxidation treatment of fats and oils is not particularly limited.
- the fat or oil is partially hydrogenated until the C18: 2 trans isomer content in the total constituent fatty acid is preferably 5 to 60% by weight, and then the resulting partially hydrogenated fat is subjected to a peroxide value of 25 to 300 meq. Oxidize until / kg.
- the oxidized partially hydrogenated fat is preferably obtained by partially hydrogenating oil and fat and oxidizing the obtained partially hydrogenated fat.
- the partially hydrogenated fat may be subjected to an oxidation treatment after being subjected to a purification step such as decolorization treatment or deodorization treatment according to a conventional method.
- the oxidized partially hydrogenated fat and the raw fat / oil for the partially hydrogenated fat are not particularly limited as long as they are used as food, but are preferably edible vegetable oils.
- edible vegetable oils include linseed oil, soybean oil, palm oil, walnut oil, egoma oil (seed oil), rapeseed oil, corn oil and the like.
- the ⁇ -linolenic acid content in the constituent fatty acids of the raw oil and fat is preferably 6% by weight or more, more preferably 30% by weight or more, and more preferably 45% by weight or more. While the effect of the enhancer containing oxidized partially hydrogenated fat is strengthened, the deterioration odor of the cooked product can be kept low. There is no particular upper limit for the ⁇ -linolenic acid content in the total constituent fatty acids of the raw fats and oils, but it does not exceed 70% by weight with normal edible fats and oils.
- Oils with high ⁇ -linolenic acid content are linseed oil, sesame oil (seed oil) and walnut oil.
- linseed oil and sesame oil contain 50% by weight or more of ⁇ -linolenic acid, and therefore it is desirable to include one or two of these in the raw oil.
- Raw material fats and oils may be combined with one or more of the above fats and oils. Oils and fats obtained by transesterification, fractionation, etc., and mixtures thereof may be used.
- Partially hydrogenated fat can be produced by a conventional hydrogenation reaction.
- a nickel catalyst or the like is added to edible vegetable fats and oils of raw material fats and oils, and a hydrogenation reaction is performed under conditions of a temperature of 120 to 220 ° C. and a hydrogen pressure of 0.01 to 0.3 MPa.
- the above-described raw material fat with a high ⁇ -linolenic acid content is used, for example, the following selective conditions: nickel catalyst (catalyst addition amount 0.05 to 0.3% by weight) ),
- the hydrogenation reaction is preferably performed at a reaction temperature of 170 to 210 ° C. and a hydrogen pressure of 0.01 to 0.2 MPa.
- the catalyst is a low-activity nickel catalyst (for example, a catalyst that has been used once or more in the hydrogenation reaction, or a product name SO650 (manufactured by Sakai Chemical Industry Co., Ltd.)), and a catalyst addition amount of 0.1 It is carried out at a reaction temperature of 190 to 210 ° C. and a hydrogen pressure of 0.01 to 0.1 MPa.
- fats and oils are usually heated at a temperature of 50 to 200 ° C., preferably 100 to 200 ° C., more preferably 100 to 180 ° C. It is not always necessary to blow air at the time of heating, but by blowing a constant amount (for example, 0.2 to 1.0 L / min) while stirring at a constant speed (for example, 50 to 350 rpm). Thus, it can be efficiently oxidized in a short time to a predetermined peroxide value. Oxidation for a short time can also prevent the generation of deteriorated odor.
- the peroxide value of partially hydrogenated fat (purified) before oxidation treatment is usually 0.
- the base oil for diluting the oxidized partially hydrogenated fat may be added to the enhancer of the present invention.
- Base oil will not be specifically limited if it is an edible oil and fat.
- base oils include palm oil, palm kernel oil, palm oil, palm oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, sunflower oil, safflower oil, cacao butter and other vegetable oils, lard, etc. Animal oils and the like.
- processed oils and fats such as these fractionated oils (mid melting point of palm oil, fractionated soft oil of palm oil, fractionated hard oil of palm oil, etc.) and transesterified oil can be used.
- these edible fats and oils can use 1 type (s) or 2 or more types.
- Additives commonly used in edible fats and oils can be added to the enhancer of the present invention.
- the additive include emulsifiers such as lecithin, diglyceride, glycerin fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, sucrose fatty acid ester and polyglycerol fatty acid ester; powdered base materials such as sugar, protein and peptide; Stabilizers such as casein, sodium caseinate, acid casein; pH adjusters such as sodium hydroxide; corn syrup, partially hydrogenated starch, glucose, fructose, maltose, sucrose, oligosaccharides, ribose, trehalose, isomaltose, erythritol , Maltitol, xylitol, sorbitol, aspartame, sucralose, etc .; milk flavor, butter flavor, cheese flavor, yogurt flavor, coffee flavor, tea flavor, cinnamon flavor Flavors such
- the content of oxidized partially hydrogenated fat in the enhancer of the present invention is usually 0.003 to 10% by weight, preferably 0.01 to 10% by weight, more preferably 0.05 to 5% by weight. %.
- the oil content in the enhancer of the present invention (total of oxidized partially hydrogenated fat and base oil) is usually 5 to 100% by weight, preferably 20 to 100% by weight.
- the form of the enhancer of the present invention can be liquid, emulsion (water-in-oil (W / O) type or oil-in-water (O / W) type), solid (powder, granules, flakes, blocks, etc.).
- the enhancer of the present invention preferably consists of powdered fats and oils.
- the particle size of the powder or granule is usually 0.3 to 3 mm, preferably 0.5 to 2 mm.
- the thickness of the flakes is usually 0.2 to 3 mm, preferably 0.5 to 2 mm.
- the fat sphere diameter (median diameter) of the powdered oil / fat is usually 0.2 to 2.0 ⁇ m, preferably 0.3 to 1.8 ⁇ m.
- the enhancer of the present invention can be prepared by an appropriate method depending on the form.
- an enhancer composed of a liquid or solid oil is obtained by mixing oxidized partially hydrogenated fat together with an appropriate base oil and additives. Depending on the choice of base oil, it can be adjusted to liquid or solid.
- An enhancer comprising an emulsion can be obtained by stirring and mixing a mixture containing oxidized partially hydrogenated fat, edible fat (base oil), emulsifier, other additives and water with an emulsifier.
- the oil content of the emulsion is usually 10 to 90% by weight.
- the enhancer consisting of powder and granulated fats and oils is a dry powdered emulsion obtained by stirring and mixing an oxidized partially hydrogenated fat, a mixture containing edible fats and oils (base oil), emulsifier, powdered base material and water. Is obtained.
- dry pulverization include spray drying of emulsion and freeze pulverization.
- the present invention also provides a food containing an enhancer (hereinafter referred to as processed food) or a food cooked using the enhancer (hereinafter referred to as cooked food).
- processed food an enhancer
- cooked food a food cooked using the enhancer
- the processed food include adjusted powder (tempura powder, deep-fried chicken powder, okonomiyaki powder, chijimi powder, cake mix, hot cake mix, donut mix, adjusted powdered milk, whey powder, etc.), roux (curry, stew, hayashi) Etc.), Instant cooked foods and drinks (instant noodles, instant soup, instant miso soup, instant coffee, instant cocoa, etc.), retort foods (curry, stew, pasta sauce, soup, etc.), refrigerated / frozen foods (doughnuts, french fries, tangs) Fried, croquette, pork cutlet, tonkatsu, fried fish, squid rings, onion rings, gratin, pizza, fried rice, pilaf, udon, ramen, meat bun, dumplings, etc., processed meat products (ham, bacon, sausage, hamburger, grilled pork, seasoned Meat, roast beef, steak, etc.), processed fishery products (fish meat soup) Sage, kamaboko, mentaiko, green onion
- the processed food can be produced by a conventional method according to the food used and its form, except that the enhancer of the present invention is added.
- Enhancer is added to, for example, the inside or surface of food, batter liquid, blender liquid, pickle liquid, tumbling liquid, or the like. Further, the enhancer is added to stir-fried oil, cooked rice oil or the like.
- the amount of the enhancer added to the processed food is usually 0.003 to 10% by weight, preferably 0.008 to 5% by weight, more preferably 0.005% by weight as the content of the oxidized partially hydrogenated fat. 008 to 3% by weight, particularly preferably 0.008 to 1% by weight.
- the processed food does not require the materials to be used or special conditions, and can be produced by a conventional method.
- cooked food examples include sugar beet, fried food, non-fried food-like food, dairy products, soft drinks, confectionery and the like obtained by cooking the processed food.
- the above-mentioned cooked food can be cooked or manufactured by a conventional method without requiring the materials to be used or special conditions other than cooking or manufacturing using the enhancer of the present invention.
- Oxidized partially hydrogenated fats used in the examples, and partially hydrogenated fats and oxidized fats and oils used in the comparative examples were prepared. 1. Preparation of raw oil and fat The following three raw oils and fats were prepared.
- Linseed oil manufactured by J-Oil Mills Co., Ltd., iodine value of 186.7, and ⁇ -linolenic acid content of 55.3%
- Soybean oil manufactured by J-Oil Mills Co., Ltd., iodine value 130, ⁇ -linolenic acid content 7.2%
- Palm oil manufactured by J-Oil Mills Co., Ltd., iodine value of 52.9, and ⁇ -linolenic acid content of 0%
- Oxidized soybean oil and extremely hardened hydrogenated palm oil were also prepared.
- the obtained GC chromatogram was obtained by analyzing the fatty acids represented by peak numbers 1 to 7, 13 to 27, and 30 to 33 in FIG. 5 of “Journal of oleo science Vol. 50, No. 5 (2001), 339-352”.
- the trans fatty acid content, the C18: 1 trans isomer (t18: 1) content, and the C18: 2 trans isomer (t18: 2) content are calculated from the peak areas corresponding to the following peak numbers. did.
- the results are shown in Table 1.
- Trans fatty acids fatty acids represented by peak numbers 1 to 7, 13 to 27 and 30 to 33 in FIG.
- Examples 1 and 2 ⁇ Corn cream soup (1)> Commercially available corn cream soup (product name: cup soup corn cream, manufactured by Ajinomoto Co., Inc., sugar content (%) when prepared according to the cooking method of the product is 9.1%), And 0.01% by weight of oil and fat having different POV) (0.0011 times per sugar content).
- the cooked product was sampled, and the sweetness, milk flavor and deteriorated odor of the corn cream soup were evaluated according to the following criteria.
- the sensory evaluation results of the cooked product are shown in Table 2.
- the sugar content (%) was a value measured as a BRIX value by “Pocket Sugar Content Meter PAL-J” manufactured by Atago Co., Ltd., and was measured under the same conditions.
- the value of the added sugar when blended with white sucrose is substantially the same as the sugar content.
- the addition amount (times) of the oxidized partially hydrogenated oil / fat per sugar content of the food material is a value obtained by dividing the added amount (% by weight) of the oxidized partially hydrogenated oil / fat with respect to the food material by the sugar content (%).
- Example 3 (Change of POV)
- Example 2 a cooked product was prepared and evaluated in the same procedure as in Example 2, except that oxidized partially hydrogenated linseed oil having different POV values shown in Table 3 was used. The results are shown in Table 3.
- the enhancer of the present invention has an effect when the POV of oxidized partially hydrogenated fat is in the range of 30 to 280.
- the POV is 120 or more, sweetness and milk flavor appear strongly in the food.
- the POV is 280 or more, a slightly deteriorated odor is generated in the food.
- Example 6 ⁇ Corn cream soup (2)>
- Example 4 a cooked product was prepared and evaluated in the same procedure as in Example 4 except that the amount of oxidized partially hydrogenated linseed oil was changed to the amount shown in Table 4. The results are shown in Table 4.
- the enhancement effect appeared when the content of the enhancer (oxidized partially hydrogenated fat) of the present invention was 0.005% by weight or more.
- the oxidized partially hydrogenated fat was added 0.0005 to 0.11 times the oxidized partially hydrogenated fat per sugar content of the food, a sweetness enhancing effect was obtained, and the effect was significant at 0.001 times or more.
- Example 12 to 15 ⁇ Corn cream soup (3)>
- the cooked food was prepared and evaluated in the same procedure as in Example 1 except that the fats and oils to be added were changed to fats and oils having different amounts of IV and trans fatty acids as shown in Table 5. The results are shown in Table 5.
- the enhancer of the present invention has an effect when the amount of trans fatty acid in the oxidized partially hydrogenated fat is 7.3% by weight or more.
- the effect of the enhancer was high when the amount of trans fatty acid was 57% by weight or more, and the effect was particularly high when the t18: 2 content was 37.2% by weight or more.
- Table 7 shows that the whipped cream using vegetable fat added with 0.01% by weight or more of the enhancer of the present invention consisting of oxidized partially hydrogenated fat can obtain a significant enhancement effect as compared with the control soybean oil.
- the enhancer added sweetened enhancing effect by adding at least 0.001 to 0.1 times oxidized partially hydrogenated linseed oil per saccharide.
- whipped cream added with 0.01% by weight or more of the enhancer of the present invention consisting of oxidized partially hydrogenated fat can obtain a significant enhancement effect as compared with the control soybean oil.
- the enhancer had a sweetness enhancing effect by adding at least 0.0005 to 0.05 times the oxidized partially hydrogenated fat per sugar.
- the enhancer of the present invention can obtain a good enhancing effect regardless of whether the whipped raw material is a vegetable fat or a dairy product and the amount of added sugar.
- Example 26 ⁇ Miso> 0.2 g of fat and oil obtained by dissolving 1% by weight of oxidized partially hydrogenated linseed oil (POV 170) in rapeseed oil in 20 g of commercially available miso (product name: Marcome-kun with miso soup stock, manufactured by Marcome Co., Ltd., sugar content 41.9%) (Addition of 0.0002 times per sugar content) or rapeseed oil 0.2 g was sampled to evaluate sweetness and salty taste. The results are shown in Table 9. The evaluation criteria for saltiness are as follows. ⁇ Salt taste> 4: Feels very strong compared to control 3: Feels stronger than control 2: Feels slightly stronger than control 1: Feels the same as or weaker than control
- Example 28 ⁇ Ponzu> 0.2 g of fats and oils in which 1% by weight of oxidized partially hydrogenated linseed oil (POV 170) is dissolved in rapeseed oil in 20 g of commercially available ponzu (product name: Ajipon, manufactured by Mitsukan Co., Ltd., sugar content 25.9%) 0.0004 times addition) or rapeseed oil 0.2g was added, and the sweetness of the ponzu was evaluated. The results are shown in Table 11.
- Examples 30 to 31 A donut dough (added sugar content: 17% by weight) shown in Table 13 was prepared. To 940 g of this donut dough, 0.7 g of oxidized partially hydrogenated linseed oil (POV 170) (0.004 times added per sugar content) or 0.7 g of rapeseed oil was added and mixed.
- POV 170 oxidized partially hydrogenated linseed oil
- Table 14 shows that the sweetness and milk flavor of the donut to which the enhancer of the present invention is added are significantly enhanced compared to the control rapeseed oil.
- the chocolate donut with the enhancer of the present invention significantly enhances the chocolate flavor in addition to the sweetness and milk flavor.
- Example 32 ⁇ Flavor oil> To 100 g of commercially available flavor oil (product name: SavorUp butter flavor oil, manufactured by J-Oil Mills Co., Ltd.), 0.3 g of oxidized partially hydrogenated linseed oil (POV 170) or 0.3 g of rapeseed oil was added, Each obtained flavor oil. 3% by weight of each of the above flavor oils was added to the egg liquid in which 100 g of whole egg, 15 g of milk and 0.5 g of salt were mixed, and mixed well to obtain a scrambled egg dough (sugar content of 3.8%). Using 5 g of rapeseed oil as the bedding oil, scrambled eggs were prepared and sampled by conventional methods. The evaluation results of the obtained flavor oil are shown in Table 16.
- Table 16 shows that the sweetness and milk flavor of the flavor oil to which the enhancer of the present invention is added are significantly enhanced compared to the control rapeseed oil. Moreover, it turned out that the milk flavor enhancement effect is acquired also with respect to flavor.
- rapeseed oil commercially available butter (product name: Snow Brand Hokkaido Butter, Snow Brand Megmilk Co., Ltd., sugar content 0.2%), and oxidized partially hydrogenated linseed oil (POV 170) are blended in the proportions shown in Table 17. Dissolved. Table 17 shows the evaluation results of the oil after cooling to room temperature.
- Example 37 ⁇ Fried vegetable batter batter> A tempura batter obtained by dissolving 100 g of commercially available tempura powder (product name: Nisshin Tempura Flour, Nisshin Flour Milling Co., Ltd.) in 150 g of cold water was obtained.
- commercially available tempura powder product name: Nisshin Tempura Flour, Nisshin Flour Milling Co., Ltd.
- the sweetness and milk flavor of bread are enhanced by adding 0.042% by weight or more of the enhancer of the present invention as oxidized partially hydrogenated fat to the dough material of bread.
- the sweetness and milk flavor of the cookies are enhanced by adding 0.06% by weight or more of the enhancer of the present invention as an oxidized partially hydrogenated fat to the cookie dough material.
- Examples 47 to 49 ⁇ Chocolate> A part of the cocoa butter (product name: cocoa butter 201, manufactured by Meiji Co., Ltd.) was added so that the amount of oxidized partially hydrogenated fat in the chocolate was as shown in Table 26.
- the chocolate dough was prepared by blending the amounts shown in Table 25.
- the dough was made into caledo-type chocolate (milk chocolate) by the slab tempering method (production method: oil / fat dissolution / mixing / refining / conching / tempering / molding) and aged at 17 ° C. for 10 days. The chocolate after aging was evaluated. The results are shown in Table 26.
- the sweetness and milk flavor of chocolate are enhanced by adding the enhancer of the present invention to the dough of chocolate at 0.05% by weight or more as oxidized partial hydrogenated fat.
- Example 50 ⁇ Stew> 1.
- Preparation of powdered oil and fat A composition for powdered oil and fat was obtained by blending oxidized partially hydrogenated linseed oil (POV 120) in the proportion shown in Preparation Example 13 of Table 27. The oil content of this composition was 45% by weight. 50 parts by weight of water was added to 50 parts by weight of this composition and stirred to obtain an O / W type emulsion. The obtained emulsion was further dried and powdered using a spray dryer (product name: B-290, manufactured by Nihon Büch) to obtain a powdered fat. The prepared powdered oil and fat had an oil content of 45% and a particle size of 1 ⁇ m.
- a spray dryer product name: B-290, manufactured by Nihon Büch
- Preparation Example 14 powdered fats and oils to which no oxidized partially hydrogenated linseed oil (POV 120) was added were prepared in the same procedure as Preparation Example 13 (oil content 45%, particle size 1 ⁇ m).
- the sweetness and milk flavor of stew are enhanced by adding 0.01% by weight of the enhancer of the present invention consisting of powdered fats and oils to the stew as oxidized partial hydrogenated fat.
- Examples 55 to 56 ⁇ Cocoa> 83.3 g of hot water was added to 16.7 g of commercially available instant cocoa (product name: milk cocoa, manufactured by Morinaga Seika Co., Ltd., sugar content 14.6%), and the mixture was stirred well. Further, Table 31 shows the evaluation results of cocoa well added with the amount of powdered fats and oils shown in Table 31 and well stirred.
- the sweetness and milk flavor of the hot cake are enhanced by adding 0.05% by weight or more of the enhancer of the present invention as oxidized partially hydrogenated fat to the hot cake dough.
- Examples 59 to 60 ⁇ Doughnut> Add 21.7 g of whole egg, 4.4 g of sugar, 8.7 g of melted butter, 65.2 g of commercially available hot cake mix (manufactured by Morinaga Seika Co., Ltd.), and the amount of powdered fats and oils shown in Table 33 to the bowl. Stir and prepare dough dough. The donut dough was stretched to a thickness of 10 mm with a rolling pin. Table 33 shows the evaluation results of the donuts that were cut from the dough and fried in 180 ° C oil.
- the sweetness and milk flavor of the donut are enhanced by adding 0.05% by weight or more of the enhancer of the present invention as an oxidized partially hydrogenated fat to the donut dough.
- Example 61 to 63 ⁇ pudding> 11.1 g of pudding (product name: Puriner, manufactured by House Foods Co., Ltd., sugar content 24.2%), 88.9 g of milk, and powdered fats and oils in the amounts shown in Table 34 were added to the pan. While stirring, heat on medium heat, boil to low heat and boil for about 1 minute. Poured into a container and cooled in a refrigerator to make pudding. Table 34 shows the evaluation results of pudding.
- the sweetness and milk flavor of the purine are enhanced by adding 0.003% by weight or more of the enhancer of the present invention as oxidized partial hydrogenated fat to the purine.
- Examples 64 to 66 ⁇ Whipped cream> 15.1 g of commercially available whipped cream base (product name: simple whipped, manufactured by Snow Brand Megmilk Co., Ltd., sugar content: 38.2%), 28.3 g of hot water, and predetermined amounts of powdered fats and oils shown in Table 35 were added to the bowl. Furthermore, 56.6 g of milk was added to the mixture and stirred for 1 minute and 30 seconds to prepare whipped cream. Table 35 shows the evaluation results of the whipped cream.
- the sweetness and milk flavor of the whipped cream are enhanced by adding 0.003% by weight or more of the enhancer of the present invention to the whipped cream as an oxidized partially hydrogenated fat. After refrigerated storage for 24 hours, the sweetness enhancing effect and milk flavor enhancing effect were maintained, although somewhat inferior.
- Example 67 to 68 ⁇ Apricot Tofu> A predetermined amount of 15.1 g of apricot tofu base (product name: Kenichi Chen Apricot Tofu, manufactured by Kyoritsu Foods Co., Ltd., sugar content 18.3%), 28.3 g of boiling water, and powdered fats and oils shown in Table 36 are added to the pan. Stir for 30 minutes. 56.6 g of milk was added to the mixture and stirred. Table 36 shows the evaluation results of annin tofu obtained by pouring into a container and cooling in a refrigerator.
- apricot tofu base product name: Kenichi Chen Apricot Tofu, manufactured by Kyoritsu Foods Co., Ltd., sugar content 18.3%
- Table 36 shows the evaluation results of annin tofu obtained by pouring into a container and cooling in a refrigerator.
- the sweetener and milk flavor of apricot tofu are enhanced by adding 0.01% by weight or more of the enhancer of the present invention as an oxidized partially hydrogenated fat to apricot tofu.
- the sweetness and milk flavor of coffee are enhanced by adding 0.005% by weight or more of the enhancer of the present invention as an oxidized partially hydrogenated fat to instant coffee.
- the sweetness and milk flavor of coffee are enhanced by adding 0.005% by weight or more of the enhancer of the present invention as an oxidized partially hydrogenated fat to instant coffee.
- Preparation of Creaming Powder (ICP) A composition for creaming powder was obtained, in which oxidized partially hydrogenated linseed oil (POV 120) was blended in the proportion shown in Preparation Example 15 in Table 39. The oil content of this composition was 45% by weight. 50 parts by weight of water was added to 50 parts by weight of this composition and stirred to obtain an O / W type emulsion. The obtained emulsion was further powdered into a dry powder using a spray dryer (B-290, manufactured by Nihon Büch) to obtain an ICP. The prepared ICP had an oil content of 20% and a particle size of 0.5 ⁇ m. Further, as shown in Preparation Example 15, an ICP to which no oxidized partially hydrogenated linseed oil (POV 120) was added was prepared in the same procedure as Preparation Example 16 (oil content 20%, particle size 0.5 ⁇ m).
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Edible Oils And Fats (AREA)
- Seasonings (AREA)
- Confectionery (AREA)
Abstract
Description
実施例に使用する酸化部分水添脂、並びに比較例に使用する部分水添脂及び酸化油脂を調製した。
1.原料油脂の準備
以下の三種類の原料油脂を用意した。
アマニ油:株式会社J-オイルミルズ製、ヨウ素価186.7、及びα-リノレン酸含量55.3%、
大豆油:株式会社J-オイルミルズ製、ヨウ素価130、及びα-リノレン酸含量7.2%、
パーム油:株式会社J-オイルミルズ製、ヨウ素価52.9、及びα-リノレン酸含量0% [Preparation Examples 1 to 12]
Oxidized partially hydrogenated fats used in the examples, and partially hydrogenated fats and oxidized fats and oils used in the comparative examples were prepared.
1. Preparation of raw oil and fat The following three raw oils and fats were prepared.
Linseed oil: manufactured by J-Oil Mills Co., Ltd., iodine value of 186.7, and α-linolenic acid content of 55.3%,
Soybean oil: manufactured by J-Oil Mills Co., Ltd., iodine value 130, α-linolenic acid content 7.2%,
Palm oil: manufactured by J-Oil Mills Co., Ltd., iodine value of 52.9, and α-linolenic acid content of 0%
上記の原料油脂を、以下の条件で、所望のヨウ素価となるよう部分水素添加処理した。
触媒 製品名SO-650(ニッケル含量14重量%、堺化学工業株式会社製)
触媒添加量 0.13%
反応温度 200℃
水素圧 0.05MPa
撹拌速度 700回転/分 2. Partial hydrogenation treatment The above-mentioned raw material fat was subjected to partial hydrogenation treatment under the following conditions so as to obtain a desired iodine value.
Catalyst Product name SO-650 (Nickel content 14% by weight, manufactured by Sakai Chemical Industry Co., Ltd.)
Addition amount of catalyst 0.13%
Reaction temperature 200 ℃
Hydrogen pressure 0.05MPa
Agitation speed 700 rpm
2.で得た部分水添脂を以下の手順で酸化処理した。まず、部分水添脂250gを、500mL容ステンレスビーカーに入れて、それを油温110℃のオイルバスに浸し、空気を吹き込みながら加熱撹拌し、表1に示す所望の過酸化物価になるまで強制酸化した。 3. 1. Partial oxidation hydrogenation treatment The partially hydrogenated fat obtained in (1) was oxidized according to the following procedure. First, 250 g of partially hydrogenated fat is put into a 500 mL stainless beaker, immersed in an oil bath with an oil temperature of 110 ° C., heated and stirred while blowing air, and forced until the desired peroxide value shown in Table 1 is reached. Oxidized.
各油脂の分析を以下の手順で行った。
4.1 ヨウ素価
1~3で得た油脂のヨウ素価を、近赤外分析計(製品名 近赤外分析計、型番 Model5000、株式会社ニレコ製)を用いて測定した。結果を表1に示す。 4). Composition analysis Each fats and oils were analyzed in the following procedures.
4.1 Iodine Value The iodine value of the fats and oils obtained in 1 to 3 was measured using a near-infrared analyzer (product name: near-infrared analyzer, model number Model 5000, manufactured by Nireco Corporation). The results are shown in Table 1.
上記過酸化物価を、「社団法人 日本油化学会 基準油脂分析法2.5.2.1-1996」に記載の方法に従って測定した。結果を表1に示す。 4.2 Peroxide Value The peroxide value was measured according to the method described in “Japan Oil Chemists' Society, Standard Oil Analysis Method 2.5.2.1-1996”. The results are shown in Table 1.
上記油脂を三フッ化ホウ素メタノール法にて脂肪酸メチルエステルとした後、ガスクロマトグラフィー(GC)法で脂肪酸組成を分析した。GC測定条件を以下に示す。
GC装置 製品名GC2010((株)島津製作所製)
カラム SP-2560(100m×0.25mm×0.2μm)(スペルコ社製)
注入口温度 250℃
キャリアガス ヘリウム(29.1ml/min)
スプリット比 25:1
カラム温度 180℃55min→(8℃/min)→220℃5min
検出器 水素炎イオン検出器(260℃) 4.3 Trans-fatty acid content After making the said fats and oils fatty acid methyl ester by the boron trifluoride methanol method, the fatty acid composition was analyzed by the gas chromatography (GC) method. The GC measurement conditions are shown below.
GC device Product name GC2010 (manufactured by Shimadzu Corporation)
Column SP-2560 (100 m × 0.25 mm × 0.2 μm) (manufactured by Spelco)
Inlet temperature 250 ℃
Carrier gas Helium (29.1 ml / min)
Split ratio 25: 1
Column temperature 180 ° C. 55 min → (8 ° C./min)→220° C. 5 min
Detector Hydrogen flame ion detector (260 ° C)
トランス脂肪酸:図5中のピーク番号1~7、13~27及び30~33で示される脂肪酸、
C18:1トランス型異性体(t18:1):図5中のピーク番号1~7で示される脂肪酸、
C18:2トランス型異性体(t18:2):図5中のピーク番号13~27で示される脂肪酸 The obtained GC chromatogram was obtained by analyzing the fatty acids represented by peak numbers 1 to 7, 13 to 27, and 30 to 33 in FIG. 5 of “Journal of oleo science Vol. 50, No. 5 (2001), 339-352”. Next, the trans fatty acid content, the C18: 1 trans isomer (t18: 1) content, and the C18: 2 trans isomer (t18: 2) content are calculated from the peak areas corresponding to the following peak numbers. did. The results are shown in Table 1.
Trans fatty acids: fatty acids represented by peak numbers 1 to 7, 13 to 27 and 30 to 33 in FIG.
C18: 1 trans isomer (t18: 1): fatty acids represented by peak numbers 1 to 7 in FIG.
C18: 2 trans isomer (t18: 2): fatty acids represented by peak numbers 13 to 27 in FIG.
市販のコーンクリームスープ(製品名:カップスープ・コーンクリーム、味の素株式会社製、製品の調理方法に従って調製したときの糖度(%)は9.1%)に、表2に記載する原料油脂(IV及びPOVの異なる油脂)を0.01重量%添加した(糖分あたり0.0011倍)。調理品の試食をおこない、コーンクリームスープの甘味、乳風味及び劣化臭を以下の基準で評価した。調理品の官能評価結果を表2に示す。なお、糖度(%)は、アタゴ社製「ポケット糖度計PAL-J」にてBRIX値として測定した値とし、以下同様の条件で測定した。また、上白糖等を配合したときの添加糖分の値は、前記糖度とほぼ同一の値となる。また、食材の糖度あたり酸化部分水素添加油脂の添加量(倍)は、食材に対する酸化部分水素添加油脂の添加量(重量%)を糖度(%)で除した値である。 [Examples 1 and 2] <Corn cream soup (1)>
Commercially available corn cream soup (product name: cup soup corn cream, manufactured by Ajinomoto Co., Inc., sugar content (%) when prepared according to the cooking method of the product is 9.1%), And 0.01% by weight of oil and fat having different POV) (0.0011 times per sugar content). The cooked product was sampled, and the sweetness, milk flavor and deteriorated odor of the corn cream soup were evaluated according to the following criteria. The sensory evaluation results of the cooked product are shown in Table 2. The sugar content (%) was a value measured as a BRIX value by “Pocket Sugar Content Meter PAL-J” manufactured by Atago Co., Ltd., and was measured under the same conditions. Moreover, the value of the added sugar when blended with white sucrose is substantially the same as the sugar content. Moreover, the addition amount (times) of the oxidized partially hydrogenated oil / fat per sugar content of the food material is a value obtained by dividing the added amount (% by weight) of the oxidized partially hydrogenated oil / fat with respect to the food material by the sugar content (%).
<甘味>
4: 対照に比べ非常に強く感じる
3: 対照に比べ強く感じる
2: 対照に比べやや強く感じる
1: 対照と同じ、又は、弱く感じる
<乳風味>
4: 対照に比べ非常に強く感じる
3: 対照に比べ強く感じる
2: 対照に比べやや強く感じる
1: 対照と同じ、又は、弱く感じる
<劣化臭>
4: まったく感じない
3: わずかに感じる
2: 少し感じる
1: 強く感じる The evaluation criteria for various tastes are as follows.
<Sweetness>
4: Feels very strong compared to control 3: Feels stronger than control 2: Feels slightly stronger than control 1: Feels the same as or weaker than control <milk flavor>
4: Feels very strong compared to the control 3: Feels stronger than the control 2: Feels slightly stronger than the control 1: Feels the same as or weaker than the control <Deteriorated odor>
4: I do not feel at all 3: Slightly feel 2: Feel a little 1: Feel strong
実施例2において、表3に記載のPOVの値の異なる酸化部分水添アマニ油を使用した以外は、実施例2と同様の手順で調理品を調製して評価した。結果を表3に示す。 [Examples 3 to 5] (Change of POV)
In Example 2, a cooked product was prepared and evaluated in the same procedure as in Example 2, except that oxidized partially hydrogenated linseed oil having different POV values shown in Table 3 was used. The results are shown in Table 3.
実施例4において、酸化部分水素添加アマニ油の添加量を表4に示す量に変えた以外は、実施例4と同じ手順で調理品を調製して評価した。結果を表4に示す。 [Examples 6 to 11] <Corn cream soup (2)>
In Example 4, a cooked product was prepared and evaluated in the same procedure as in Example 4 except that the amount of oxidized partially hydrogenated linseed oil was changed to the amount shown in Table 4. The results are shown in Table 4.
実施例1において、添加する油脂を、表5に示すIV及びトランス脂肪酸量の異なる油脂に変えた以外は、実施例1と同様の手順で調理品を調製して評価した。結果を表5に示す。 [Examples 12 to 15] <Corn cream soup (3)>
In Example 1, the cooked food was prepared and evaluated in the same procedure as in Example 1 except that the fats and oils to be added were changed to fats and oils having different amounts of IV and trans fatty acids as shown in Table 5. The results are shown in Table 5.
砂糖を10重量%になるよう溶解した水(砂糖水)に、表6に記載の油脂を0.005重量%(糖分あたり0.0005倍)になるよう添加して評価した。結果を表6に示す。 [Examples 16 to 17] <Sugar water>
The water and fats shown in Table 6 were added to water in which sugar was dissolved to 10% by weight (sugar water), and evaluated by adding 0.005% by weight (0.0005 times per sugar content). The results are shown in Table 6.
市販のホイップクリーム(製品名:スジャータホイップ(植物性脂肪使用)、株式会社東京めいらく製)に上白糖を添加し、常法により調製したホイップクリーム(添加糖分:10重量%、比重:3.9g/ml、品温:9.3℃)に、表7に記載の油脂を添加して評価した。結果を表7に示す。 [Examples 18 to 21] <Whipped cream using vegetable fat>
Super white sugar was added to a commercially available whipped cream (product name: Sujata whipped (using vegetable fat), manufactured by Tokyo Meiraku Co., Ltd.), and whipped cream (added sugar content: 10% by weight, specific gravity: 3.9 g) / Ml, product temperature: 9.3 ° C.) and the fats and oils listed in Table 7 were added for evaluation. The results are shown in Table 7.
市販のクリーム(製品名:特選北海道純生クリーム35(乳製品)、高梨乳業株式会社製)に上白糖を添加し、常法により調製したホイップクリーム(添加糖分:20重量%、比重:4.7g/ml、品温:6.4℃)に、表8に記載の油脂を添加して評価した。結果を表8に示す。 [Examples 22 to 25] <Daily product whipped cream>
Whipped cream (added sugar content: 20% by weight, specific gravity: 4.7 g) prepared by adding ordinary white sugar to commercially available cream (Product name: Special Hokkaido Pure Cream 35 (dairy product), manufactured by Takanashi Dairy Co., Ltd.) / Ml, product temperature: 6.4 ° C.) and the fats and oils listed in Table 8 were added for evaluation. The results are shown in Table 8.
市販の味噌(製品名:マルコメ君合わせ味噌だし入り、マルコメ株式会社製、糖度41.9%)20gに、酸化部分水添アマニ油(POV 170)を菜種油に1重量%溶解した油脂0.2g(糖度あたり0.0002倍添加)、又は菜種油0.2gを添加したものを試食して、甘味及び塩味を評価した。結果を表9に示す。塩味の評価基準は以下のとおりである。
<塩味>
4: 対照に比べ非常に強く感じる
3: 対照に比べ強く感じる
2: 対照に比べやや強く感じる
1: 対照と同じ、又は、弱く感じる [Example 26] <Miso>
0.2 g of fat and oil obtained by dissolving 1% by weight of oxidized partially hydrogenated linseed oil (POV 170) in rapeseed oil in 20 g of commercially available miso (product name: Marcome-kun with miso soup stock, manufactured by Marcome Co., Ltd., sugar content 41.9%) (Addition of 0.0002 times per sugar content) or rapeseed oil 0.2 g was sampled to evaluate sweetness and salty taste. The results are shown in Table 9. The evaluation criteria for saltiness are as follows.
<Salt taste>
4: Feels very strong compared to control 3: Feels stronger than control 2: Feels slightly stronger than control 1: Feels the same as or weaker than control
市販のトマトソース(製品名:完熟トマトのピザソース、カゴメ株式会社製、糖度17.2%)20gに、酸化部分水添アマニ油(POV 170)を菜種油に1重量%溶解した油脂0.2g(糖度あたり0.0006倍添加)、又は菜種油0.2gを添加して得られたトマトソースの甘味を評価した。結果を表10に示す。 [Example 27] <Tomato sauce>
0.2 g of fat and oil obtained by dissolving 1% by weight of oxidized partially hydrogenated linseed oil (POV 170) in rapeseed oil in 20 g of commercial tomato sauce (product name: pizza sauce of ripe tomato, manufactured by Kagome Co., Ltd., sugar content 17.2%) The sweetness of tomato sauce obtained by adding 0.0006 times the sugar content) or 0.2 g of rapeseed oil was evaluated. The results are shown in Table 10.
市販のポン酢(製品名:味ぽん、株式会社ミツカン社製、糖度25.9%)20gに、酸化部分水添アマニ油(POV 170)を菜種油に1重量%溶解した油脂0.2g(糖度あたり0.0004倍添加)又は菜種油0.2gを添加し、ポン酢の甘味を評価した。結果を表11に示す。 [Example 28] <Ponzu>
0.2 g of fats and oils in which 1% by weight of oxidized partially hydrogenated linseed oil (POV 170) is dissolved in rapeseed oil in 20 g of commercially available ponzu (product name: Ajipon, manufactured by Mitsukan Co., Ltd., sugar content 25.9%) 0.0004 times addition) or rapeseed oil 0.2g was added, and the sweetness of the ponzu was evaluated. The results are shown in Table 11.
市販のカレールー(製品名:ゴールデンカレーハーフ、エスビー食品株式会社製)14gに、酸化部分水添アマニ油(POV 170)を菜種油に1重量%溶解した油脂2.2g又は菜種油2.2gを添加し、それを熱湯200gで溶いて得られたカレー(糖度(%):9.0%)の甘味を評価した(糖度あたり0.001倍添加)。結果を表12に示す。 [Example 29] <Carreru>
To 14 g of commercially available curry roux (product name: Golden Curry Half, manufactured by SB Foods Co., Ltd.), add 2.2 g of fat or oil or 2.2 g of rapeseed oil in which 1% by weight of oxidized partially hydrogenated linseed oil (POV 170) is dissolved in rapeseed oil. The sweetness of curry (sugar content (%): 9.0%) obtained by dissolving it in 200 g of hot water was evaluated (added 0.001 times per sugar content). The results are shown in Table 12.
表13に示すドーナツ生地(添加糖分:17重量%)を調製した。このドーナツ生地940gに、酸化部分水添アマニ油(POV 170)を0.7g(糖分あたり0.004倍添加)、又は菜種油0.7gを添加し混合した。 [Examples 30 to 31] <Doughnut>
A donut dough (added sugar content: 17% by weight) shown in Table 13 was prepared. To 940 g of this donut dough, 0.7 g of oxidized partially hydrogenated linseed oil (POV 170) (0.004 times added per sugar content) or 0.7 g of rapeseed oil was added and mixed.
<チョコレート風味>
4: 対照に比べ非常に強く感じる
3: 対照に比べ強く感じる
2: 対照に比べやや強く感じる
1: 対照と同じ、又は、弱く感じる
Furthermore, the donut which hung chocolate on some fried donuts was evaluated. The results are shown in Table 15. The standard of chocolate flavor is as follows.
<Chocolate flavor>
4: Feels very strong compared to control 3: Feels stronger than control 2: Feels slightly stronger than control 1: Feels the same as or weaker than control
市販の風味油(製品名:SavorUpバターフレーバーオイル、株式会社J-オイルミルズ社製)100gに、酸化部分水添アマニ油(POV 170)を0.3g、又は菜種油を0.3g添加して、それぞれ風味油を得た。全卵100g、牛乳15g、食塩0.5gを混合した卵液に、上記風味油をそれぞれ3重量%加えてよく混ぜ、スクランブルエッグ生地(糖度3.8%)とした。5gの菜種油を敷き油とし、常法によりそれぞれスクランブルエッグを作成して試食した。得られた風味油の評価結果を表16に示す。 [Example 32] <Flavor oil>
To 100 g of commercially available flavor oil (product name: SavorUp butter flavor oil, manufactured by J-Oil Mills Co., Ltd.), 0.3 g of oxidized partially hydrogenated linseed oil (POV 170) or 0.3 g of rapeseed oil was added, Each obtained flavor oil. 3% by weight of each of the above flavor oils was added to the egg liquid in which 100 g of whole egg, 15 g of milk and 0.5 g of salt were mixed, and mixed well to obtain a scrambled egg dough (sugar content of 3.8%). Using 5 g of rapeseed oil as the bedding oil, scrambled eggs were prepared and sampled by conventional methods. The evaluation results of the obtained flavor oil are shown in Table 16.
50℃の菜種油、市販のバター(製品名:雪印北海道バター、雪印メグミルク株式会社製、糖度0.2%)、及び酸化部分水添アマニ油(POV 170)を表17に示す割合で配合し、溶解した。室温まで冷却後の油脂の評価結果を表17に示す。 [Examples 33 to 36] <Butter>
50 ° C. rapeseed oil, commercially available butter (product name: Snow Brand Hokkaido Butter, Snow Brand Megmilk Co., Ltd., sugar content 0.2%), and oxidized partially hydrogenated linseed oil (POV 170) are blended in the proportions shown in Table 17. Dissolved. Table 17 shows the evaluation results of the oil after cooling to room temperature.
市販の天ぷら粉(製品名:さくっと揚がる日清天ぷら粉、日清製粉株式会社製)100gを冷水150gに溶いた天ぷらバッターを得た。玉ねぎ112g、にんじん32g、三度豆16gをそれぞれ5mm幅3cm長さに切って打ち粉をし、上記の天ぷらバッター90gをまぶした野菜かき揚げだね250gに、酸化部分水添アマニ油(POV 170)を菜種油に1重量%溶解した油脂2.5g又は菜種油2.5gをそれぞれ添加し、常法により天ぷら油で揚げ、野菜かき揚げ(野菜の糖度7.8%)を作成して試食した。結果を表18に示す。 [Example 37] <Fried vegetable batter batter>
A tempura batter obtained by dissolving 100 g of commercially available tempura powder (product name: Nisshin Tempura Flour, Nisshin Flour Milling Co., Ltd.) in 150 g of cold water was obtained. 112g of onion, 32g of carrot and 16g of 3rd beans were cut into 5mm width and 3cm length, dusted, and 250g of vegetable kneaded rice sprinkled with 90g of tempura batter was added to oxidized partially hydrogenated linseed oil (POV 170) 2 g of oil and fat dissolved in 1% by weight of rapeseed oil or 2.5 g of rapeseed oil were added, respectively, and fried in tempura oil by a conventional method to prepare fried vegetables (sugar content of vegetables 7.8%). The results are shown in Table 18.
From Table 18, it can be seen that the sweetness of the fried vegetables with the enhancer of the present invention added to the tempura batter is significantly enhanced compared to the control rapeseed oil.
表19に示す組成にて、約60℃に保温した油相に水相を攪拌しながら投入して予備乳化を行った後、ボテーターに通して冷却練りあわせを行い、テーブルタイプマーガリンを調製した。テーブルタイプマーガリン99gに、菜種油1g、もしくは、表20に記載のようにその一部を酸化部分水添アマニ油に置き換えたものを添加した。それぞれの風味(甘味、乳風味、劣化臭)について評価した結果を表20に示す。 [Examples 38 to 40] <Margarine>
In the composition shown in Table 19, the water phase was added to the oil phase kept at about 60 ° C. while stirring to pre-emulsify, and then cooled and kneaded through a bottor to prepare a table type margarine. To 99 g of table type margarine, 1 g of rapeseed oil or a part of which was replaced with oxidized partially hydrogenated linseed oil as shown in Table 20 was added. Table 20 shows the results of evaluation for each flavor (sweetness, milk flavor, deteriorated odor).
油脂(パーム油:パームオレイン(IV67)=7:3)に、表22に記載の油脂を添加し、試験用油脂を調製した。通常の方法で、試験用油脂を表21に示す配合でパン材料と混合してプルマン型食パンを製造した。焼成1日後の風味(甘味、乳風味、劣化臭)を評価した。結果を表22に示す。 [Examples 41 to 43] <Bread>
The fats and oils shown in Table 22 were added to the fats and oils (palm oil: palm olein (IV67) = 7: 3) to prepare test fats and oils. The pull fat type bread was manufactured by mixing the test fats and oils with the bread ingredients by the method shown in Table 21 in the usual manner. The flavor (sweetness, milk flavor, deteriorated odor) after 1 day of baking was evaluated. The results are shown in Table 22.
油脂(パーム油:パームオレイン(IV67)=7:3)に表24に記載の油脂を添加し、試験用油脂を作製した。試験用油脂を表23に従って配合し、クッキー生地を作製した。アイスボックス型に成形後、通常の方法で、クッキーを焼成した。焼成1日後の風味(甘味、乳風味、劣化臭)の評価結果を表24に示す。 [Examples 44 to 46] <Cookie>
The fats and oils shown in Table 24 were added to the fats and oils (palm oil: palm olein (IV67) = 7: 3) to prepare test fats and oils. Test fats and oils were blended according to Table 23 to prepare a cookie dough. After forming into an ice box mold, the cookies were baked by a normal method. Table 24 shows the evaluation results of the flavor (sweet taste, milk flavor, deteriorated odor) one day after baking.
ココアバター(製品名:ココアバター201、明治株式会社製)に対して、その一部をチョコレート中の酸化部分水添脂の量が表26となるように添加した。チョコレート生地は、表25に示す量を配合し、作製した。生地をスラブテンパリング法(製法:油脂溶解・ミキシング~リファイニング~コンチング~テンパリング~成型)にてカレドタイプの板チョコレート(ミルクチョコレート)を作り、10日間17℃にて熟成させた。熟成後のチョコレートを評価した。結果を表26に示す。 [Examples 47 to 49] <Chocolate>
A part of the cocoa butter (product name: cocoa butter 201, manufactured by Meiji Co., Ltd.) was added so that the amount of oxidized partially hydrogenated fat in the chocolate was as shown in Table 26. The chocolate dough was prepared by blending the amounts shown in Table 25. The dough was made into caledo-type chocolate (milk chocolate) by the slab tempering method (production method: oil / fat dissolution / mixing / refining / conching / tempering / molding) and aged at 17 ° C. for 10 days. The chocolate after aging was evaluated. The results are shown in Table 26.
1.粉末油脂の調製
酸化部分水添アマニ油(POV 120)を表27の調製例13に示す割合で配合した粉末油脂用組成物を得た。この組成物の油分は45重量%であった。この組成物50重量部に水を50重量部添加し、攪拌することによりO/W型エマルジョンを得た。得られたエマルジョンをさらに、スプレードライヤー(製品名:B-290、日本ビュッヒ社製)を用いて乾燥粉末化することにより粉末油脂を得た。調製した粉末油脂は、油分45%、粒子径は1μmであった。また、調製例14に示すように、酸化部分水添アマニ油(POV 120)を添加しない粉末油脂を、調製例13と同様の手順で調製した(油分45%、粒子径1μm)。 [Example 50] <Stew>
1. Preparation of powdered oil and fat A composition for powdered oil and fat was obtained by blending oxidized partially hydrogenated linseed oil (POV 120) in the proportion shown in Preparation Example 13 of Table 27. The oil content of this composition was 45% by weight. 50 parts by weight of water was added to 50 parts by weight of this composition and stirred to obtain an O / W type emulsion. The obtained emulsion was further dried and powdered using a spray dryer (product name: B-290, manufactured by Nihon Büch) to obtain a powdered fat. The prepared powdered oil and fat had an oil content of 45% and a particle size of 1 μm. Moreover, as shown in Preparation Example 14, powdered fats and oils to which no oxidized partially hydrogenated linseed oil (POV 120) was added were prepared in the same procedure as Preparation Example 13 (oil content 45%, particle size 1 μm).
手鍋に水442.5gを量り取り、火にかけ沸騰させた。火を止めた後、市販のシチューミックス(顆粒タイプ)(製品名:シチューミクス<クリーム>、ハウス食品株式会社製)57.5gを加えよく混ぜた。2分間弱火で加熱し、シチューを調製した。予め容器に粉末油脂を表28に示す量になるよう秤量し、シチュー100gを加えた(糖分5.6%)。溶解するまでよく撹拌した。得られたシチューの評価結果を表28に示す。 2. Evaluation of powdered fats and oils 442.5 g of water was weighed in a hand pan and boiled over a fire. After stopping the fire, 57.5 g of a commercially available stew mix (granule type) (product name: stew mix <cream>, manufactured by House Foods Co., Ltd.) was added and mixed well. The stew was prepared by heating on low heat for 2 minutes. Powdered fats and oils were previously weighed in a container to the amount shown in Table 28, and 100 g of stew was added (sugar content 5.6%). Stir well until dissolved. The evaluation results of the obtained stew are shown in Table 28.
市販のスープ(製品名:クノール(登録商標)カップスープ コーンクリーム、クノール食品株式会社製、糖分7.8%)11.3gに熱湯88.7gを加え、よく撹拌した。さらに、表29に示す量の粉末油脂を添加し、よく撹拌し溶解したスープの評価結果を表29に示す。 [Examples 51 to 52] <Soup (1)>
88.7 g of hot water was added to 11.3 g of commercially available soup (product name: Knorr (registered trademark) cup soup corn cream, manufactured by Knorr Foods Co., Ltd., 7.8% sugar content), and stirred well. Furthermore, the evaluation result of the soup which added the amount of powdered fats and oils shown in Table 29 and stirred well and melt | dissolved is shown in Table 29.
市販のスープ(製品名:クノール(登録商標)カップスープcold コーンポタージュ、クノール食品株式会社製)13gに、牛乳87gを加え、よく撹拌した。さらに、表30に示す量の粉末油脂を添加し、よく撹拌し、溶解したスープの評価結果を表30に示す。 [Examples 53 to 54] <Soup (2)>
To 13 g of commercially available soup (product name: Knorr (registered trademark) cup soup cold corn potage, manufactured by Knorr Foods Co., Ltd.), 87 g of milk was added and stirred well. Furthermore, the amount of powdered fats and oils shown in Table 30 is added, stirred well, and the evaluation results of the dissolved soup are shown in Table 30.
市販のインスタントココア(製品名:ミルクココア、森永製菓株式会社製、糖分14.6%)16.7gに、熱湯83.3gを加え、よく撹拌した。さらに表31に示す量の粉末油脂を加え、よく撹拌したココアの評価結果を表31に示す。 [Examples 55 to 56] <Cocoa>
83.3 g of hot water was added to 16.7 g of commercially available instant cocoa (product name: milk cocoa, manufactured by Morinaga Seika Co., Ltd., sugar content 14.6%), and the mixture was stirred well. Further, Table 31 shows the evaluation results of cocoa well added with the amount of powdered fats and oils shown in Table 31 and well stirred.
ボウルに全卵16.7g、及び牛乳33.3gを入れ、よく混ぜ合わせた。市販のホットケーキミックス(製品名:ホットケーキミックス、森永製菓株式会社製、糖分34.2%)50.0gを加え、さらに表32に示す粉末油脂を所定量添加し、撹拌し、ホットケーキの生地を調製した。ホットケーキの生地を、160℃に熱したホットプレートで焼いて得たホットケーキの評価結果を表32に示す。 [Examples 57 to 58] <Hot cake>
16.7 g of whole eggs and 33.3 g of milk were put in a bowl and mixed well. 50.0 g of a commercially available hot cake mix (product name: hot cake mix, manufactured by Morinaga Seika Co., Ltd., sugar content: 34.2%) is added, and a predetermined amount of powdered fats and oils shown in Table 32 are added and stirred, A dough was prepared. Table 32 shows the evaluation results of the hot cake obtained by baking the dough of the hot cake on a hot plate heated to 160 ° C.
ボウルに、全卵21.7g、砂糖4.4g、溶かしたバター8.7g、及び市販のホットケーキミックス(森永製菓株式会社製)65.2g、表33に示す量の粉末油脂を加え、よく撹拌し、ドーナツの生地を調製した。ドーナツ生地を麺棒で厚さ10mmに伸ばした。生地を型抜きし、180℃の油で揚げたドーナツの評価結果を表33に示す。 [Examples 59 to 60] <Doughnut>
Add 21.7 g of whole egg, 4.4 g of sugar, 8.7 g of melted butter, 65.2 g of commercially available hot cake mix (manufactured by Morinaga Seika Co., Ltd.), and the amount of powdered fats and oils shown in Table 33 to the bowl. Stir and prepare dough dough. The donut dough was stretched to a thickness of 10 mm with a rolling pin. Table 33 shows the evaluation results of the donuts that were cut from the dough and fried in 180 ° C oil.
鍋にプリンの素(製品名:プリンエル、ハウス食品株式会社製、糖分24.2%)11.1g、牛乳88.9g、及び表34に示す量の粉末油脂を加えた。かき混ぜながら、中火で加熱し、沸騰したら弱火にして、約1分煮た。容器に流し込み、冷蔵庫で冷やして、プリンを作った。プリンの評価結果を表34に示す。 [Examples 61 to 63] <pudding>
11.1 g of pudding (product name: Puriner, manufactured by House Foods Co., Ltd., sugar content 24.2%), 88.9 g of milk, and powdered fats and oils in the amounts shown in Table 34 were added to the pan. While stirring, heat on medium heat, boil to low heat and boil for about 1 minute. Poured into a container and cooled in a refrigerator to make pudding. Table 34 shows the evaluation results of pudding.
ボウルに、市販のホイップクリームの素(製品名:かんたんホイップ、雪印メグミルク株式会社製、糖分38.2%)15.1g、熱湯28.3g、及び表35に示す粉末油脂を所定量加えた。さらに、混合物に、牛乳56.6gを加え、1分30秒間撹拌し、ホイップクリームを調製した。ホイップクリームの評価結果を表35に示す。 [Examples 64 to 66] <Whipped cream>
15.1 g of commercially available whipped cream base (product name: simple whipped, manufactured by Snow Brand Megmilk Co., Ltd., sugar content: 38.2%), 28.3 g of hot water, and predetermined amounts of powdered fats and oils shown in Table 35 were added to the bowl. Furthermore, 56.6 g of milk was added to the mixture and stirred for 1 minute and 30 seconds to prepare whipped cream. Table 35 shows the evaluation results of the whipped cream.
鍋に、杏仁豆腐の素(製品名:陳健一 杏仁豆腐、共立食品株式会社製、糖分18.3%)15.1g、熱湯28.3g、及び表36に示す粉末油脂を所定量加え、1分30秒かき混ぜた。混合物に牛乳56.6gを入れ撹拌した。容器に流し込み、冷蔵庫で冷やして得た杏仁豆腐の評価結果を表36に示す。 [Examples 67 to 68] <Apricot Tofu>
A predetermined amount of 15.1 g of apricot tofu base (product name: Kenichi Chen Apricot Tofu, manufactured by Kyoritsu Foods Co., Ltd., sugar content 18.3%), 28.3 g of boiling water, and powdered fats and oils shown in Table 36 are added to the pan. Stir for 30 minutes. 56.6 g of milk was added to the mixture and stirred. Table 36 shows the evaluation results of annin tofu obtained by pouring into a container and cooling in a refrigerator.
市販のインスタントコーヒー(製品名:Blendy、味の素ゼネラルフーヅ株式会社製、糖分1.5%)1.38g及び表37に示す粉末油脂の所定量を、熱湯98.62gを注ぎよく撹拌してコーヒーを作った。コーヒーの評価結果を表37に示す。 [Examples 69 to 70] <Coffee (1)>
Instant coffee (product name: Blendy, manufactured by Ajinomoto General Foods Co., Ltd., sugar content 1.5%) 1.38 g and a predetermined amount of powdered fats and oils shown in Table 37 were poured into hot water 98.62 g and stirred to make coffee. It was. Table 37 shows the evaluation results of the coffee.
市販のインスタントコーヒー(製品名:Blendy、味の素ゼネラルフーヅ株式会社製、糖分1.5%)1.35g、市販のクリーミングパウダー(製品名:MARIM ハーフ、味の素ゼネラルフーヅ株式会社製、糖分2.4%)2.03g、及び表38に示す粉末油脂の所定量を、熱湯96.62gを注ぎよく撹拌してコーヒーを作った。コーヒーの評価結果を表38に示す。 [Examples 71 to 72] <Coffee (2)>
Commercial instant coffee (Product name: Blendy, Ajinomoto General Foods Co., Ltd., sugar content 1.5%) 1.35 g, Commercial creaming powder (Product name: MARIM Half, Ajinomoto General Foods Co., Ltd., sugar content 2.4%) 2 0.03 g and a predetermined amount of powdered fats and oils shown in Table 38 were poured into hot water 96.62 g and stirred well to make coffee. Table 38 shows the evaluation results of the coffee.
1.クリーミングパウダー(ICP)の調製
酸化部分水添アマニ油(POV 120)を表39の調製例15に示す割合で配合したクリーミングパウダー用組成物を得た。この組成物の油分は45重量%であった。この組成物50重量部に水50重量部を添加し、攪拌することによりO/W型エマルジョンを得た。得られたエマルジョンをさらに、スプレードライヤー(B-290、日本ビュッヒ社製)を用いて乾燥粉末化することによりICPを得た。調製したICPは、油分20%、粒子径は0.5μmであった。また、調製例15に示すように、酸化部分水添アマニ油(POV 120)を添加しないICPを、調製例16と同様の手順で調製した(油分20%、粒子径0.5μm)。 [Example 73] <Creaming Powder (ICP)>
1. Preparation of Creaming Powder (ICP) A composition for creaming powder was obtained, in which oxidized partially hydrogenated linseed oil (POV 120) was blended in the proportion shown in Preparation Example 15 in Table 39. The oil content of this composition was 45% by weight. 50 parts by weight of water was added to 50 parts by weight of this composition and stirred to obtain an O / W type emulsion. The obtained emulsion was further powdered into a dry powder using a spray dryer (B-290, manufactured by Nihon Büch) to obtain an ICP. The prepared ICP had an oil content of 20% and a particle size of 0.5 μm. Further, as shown in Preparation Example 15, an ICP to which no oxidized partially hydrogenated linseed oil (POV 120) was added was prepared in the same procedure as Preparation Example 16 (oil content 20%, particle size 0.5 μm).
調製例15又は16のICPをそのまま、食したところ、表40に示すように、調製例15のICPは、調製例16のICPよりも甘味及び乳風味が増強されていた。 2. Evaluation of ICP When the ICP of Preparation Example 15 or 16 was eaten as it was, as shown in Table 40, the ICP of Preparation Example 15 had enhanced sweetness and milk flavor than the ICP of Preparation Example 16.
Claims (13)
- 過酸化物価が25~300の酸化部分水素添加油脂を有効成分として含む甘味及び/又は乳風味増強剤。 Sweetness and / or milk flavor enhancer containing an oxidized partially hydrogenated oil having a peroxide value of 25 to 300 as an active ingredient.
- 前記酸化部分水素添加油脂のトランス脂肪酸含量が、5~75重量%であることを特徴とする、請求項1に記載の甘味及び/又は乳風味増強剤。 The sweetness and / or milk flavor enhancer according to claim 1, wherein the trans fatty acid content of the oxidized partially hydrogenated oil is 5 to 75% by weight.
- 前記酸化部分水素添加油脂の全構成脂肪酸中におけるC18:2トランス型異性体含量が、5~60重量%であることを特徴とする、請求項1に記載の甘味及び/又は乳風味増強剤。 2. The sweetness and / or milk flavor enhancer according to claim 1, wherein the content of C18: 2 trans isomer in the total constituent fatty acids of the oxidized partially hydrogenated fat is 5 to 60% by weight.
- 前記酸化部分水素添加油脂のヨウ素価が35~135である、請求項1に記載の甘味及び/又は乳風味増強剤。 The sweet taste and / or milk flavor enhancer according to claim 1, wherein the iodine value of the oxidized partially hydrogenated fat is 35 to 135.
- 前記酸化部分水素添加油脂を0.003~10重量%含有する、請求項1に記載の甘味及び/又は乳風味増強剤。 The sweetness and / or milk flavor enhancer according to claim 1, comprising 0.003 to 10% by weight of the oxidized partially hydrogenated oil.
- 粉末油脂からなる、請求項1に記載の甘味及び/又は乳風味増強剤。 The sweetness and / or milk flavor enhancer according to claim 1, comprising powdered fats and oils.
- 過酸化物価が25~300の酸化部分水素添加油脂、食用油脂、乳化剤、粉末化基材及び水を含む混合物を撹拌して得られるエマルジョンをさらに粉末乾燥化することにより得られる、請求項6に記載の甘味及び/又は乳風味増強剤。 7. The emulsion obtained by further stirring the emulsion obtained by stirring a mixture containing an oxidized partially hydrogenated oil / fat having a peroxide value of 25 to 300, an edible oil / fat, an emulsifier, a powdered base material, and water. The sweetness and / or milk flavor enhancer described.
- 前記粉末の脂肪球径(メディアン径)が0.2~2.0μmである、請求項7記載の甘味及び/又は乳風味増強剤。 The sweetness and / or milk flavor enhancer according to claim 7, wherein the powder has a fat globule diameter (median diameter) of 0.2 to 2.0 µm.
- 請求項1に記載の甘味及び/又は乳風味増強剤を含有する油脂組成物。 An oil / fat composition containing the sweetness and / or milk flavor enhancer according to claim 1.
- 請求項1に記載の甘味及び/又は乳風味増強剤を含有するか又は該増強剤を用いて調理された食品。 A food containing the sweetness and / or milk flavor enhancer according to claim 1 or cooked using the enhancer.
- 甘味及び/又は乳風味増強剤の製造方法であって、過酸化物価が25~300の酸化部分水素添加油脂を有効成分として添加することを特徴とする、前記製造方法。 A method for producing a sweetness and / or milk flavor enhancer, characterized in that an oxidized partially hydrogenated oil having a peroxide value of 25 to 300 is added as an active ingredient.
- 過酸化物価が25~300の酸化部分水素添加油脂を有効成分として含む甘味及び/又は乳風味増強剤を食材へ添加して調理することからなる、調理食品の甘味及び/又は乳風味の増強方法。 A method for enhancing sweetness and / or milk flavor of cooked food, comprising adding a sweetness and / or milk flavor enhancer containing an oxidized partially hydrogenated oil having a peroxide value of 25 to 300 as an active ingredient to cooking ingredients .
- 過酸化物価が25~300の酸化部分水素添加油脂を有効成分として含む甘味増強剤を食材へ酸化部分水素添加油脂が食材の糖度あたり0.00002~200倍になるように添加して調理することからなる、調理食品の甘味の増強方法。 Cooking by adding a sweetness enhancer containing an oxidized partially hydrogenated oil with a peroxide value of 25 to 300 as an active ingredient to the ingredients so that the oxidized partially hydrogenated oil is 0.00002 to 200 times the sugar content of the ingredients. A method for enhancing the sweetness of a cooked food comprising:
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014502918A JP5612234B1 (en) | 2012-11-14 | 2013-09-02 | Sweetness and / or milk flavor enhancer |
CN201380059329.9A CN104780779B (en) | 2012-11-14 | 2013-09-02 | Sweet taste and/or breast flavour enhancer |
SG11201502724PA SG11201502724PA (en) | 2012-11-14 | 2013-09-02 | Sweetness and/or milk flavor enhancer |
KR1020157010137A KR102098155B1 (en) | 2012-11-14 | 2013-09-02 | Sweetness and/or milk flavor enhancer |
PH12015500777A PH12015500777A1 (en) | 2012-11-14 | 2015-04-08 | Sweetness and/or milk flavor enhancer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012250613 | 2012-11-14 | ||
JP2012-250613 | 2012-11-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014077019A1 true WO2014077019A1 (en) | 2014-05-22 |
Family
ID=50730942
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2013/073476 WO2014077019A1 (en) | 2012-11-14 | 2013-09-02 | Sweetness and/or milk flavor enhancer |
Country Status (8)
Country | Link |
---|---|
JP (1) | JP5612234B1 (en) |
KR (1) | KR102098155B1 (en) |
CN (1) | CN104780779B (en) |
MY (1) | MY171340A (en) |
PH (1) | PH12015500777A1 (en) |
SG (1) | SG11201502724PA (en) |
TW (1) | TWI620510B (en) |
WO (1) | WO2014077019A1 (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018020812A1 (en) * | 2016-07-27 | 2018-02-01 | 株式会社J-オイルミルズ | Powder oil/fat composition and method for producing same |
WO2018037926A1 (en) * | 2016-08-22 | 2018-03-01 | 株式会社J-オイルミルズ | Sweetness and/or saltiness enhancing agent |
WO2018037927A1 (en) * | 2016-08-22 | 2018-03-01 | 株式会社J-オイルミルズ | Composition that suppresses unpleasant odor from food products |
WO2018123594A1 (en) * | 2016-12-27 | 2018-07-05 | 株式会社J-オイルミルズ | Sourness enhancing agent |
WO2018123595A1 (en) * | 2016-12-27 | 2018-07-05 | 株式会社J-オイルミルズ | Umami taste enhancing agent |
JP2018130052A (en) * | 2017-02-14 | 2018-08-23 | 株式会社Adeka | Method for producing flavor-enhancing oil/fat |
WO2018186328A1 (en) * | 2017-04-04 | 2018-10-11 | 株式会社J-オイルミルズ | Taste improver |
WO2019073811A1 (en) * | 2017-10-13 | 2019-04-18 | 株式会社J-オイルミルズ | Fat feeling enhancer for foods, and food containing same |
CN110072400A (en) * | 2016-12-27 | 2019-07-30 | J-制油株式会社 | Bad smell inhibitor |
WO2020090609A1 (en) * | 2018-10-31 | 2020-05-07 | 株式会社J-オイルミルズ | Oxidized product of palm-based fat/oil, production method for oxidized product, food sweetness-enhancing method, and food sweetness-enhancing composition |
WO2020090608A1 (en) * | 2018-10-31 | 2020-05-07 | 株式会社J-オイルミルズ | Production method for oil/fat composition, production method for edible oil/fat composition, food production method, food sweetness-enhancing method, and food sweetness-enhancing composition |
JP2020074708A (en) * | 2018-11-07 | 2020-05-21 | 株式会社Adeka | Oil and fat composition for bakery |
WO2020209158A1 (en) * | 2019-04-11 | 2020-10-15 | 株式会社J-オイルミルズ | Oil/fat feel enhancer for food and method for enhancing oil/fat feel of food |
WO2021065441A1 (en) * | 2019-09-30 | 2021-04-08 | 株式会社J-オイルミルズ | Umami enhancing composition, flavoring or extract, production method for umami enhancing composition, production method for flavoring or extract, and umami enhancing method for food |
WO2021065442A1 (en) * | 2019-09-30 | 2021-04-08 | 株式会社J-オイルミルズ | Umami-enhancing composition and method for manufacturing same, flavoring or extract and method for manufacturing same, fat/oil composition for cooking and method for manufacturing same, and method for enhancing umami in food |
JP2021078450A (en) * | 2019-11-20 | 2021-05-27 | 花王株式会社 | Sweetness enhancer |
WO2022102382A1 (en) * | 2020-11-10 | 2022-05-19 | 不二製油グループ本社株式会社 | Sweetness enhancement method for oil-based food product |
EP3884783A4 (en) * | 2018-11-20 | 2022-08-17 | Kao Corporation | Oil and fat composition |
WO2023038008A1 (en) * | 2021-09-13 | 2023-03-16 | 株式会社J-オイルミルズ | Rich flavor enhancer and rich flavor enhancing method |
WO2023054274A1 (en) | 2021-09-29 | 2023-04-06 | 株式会社Adeka | Oil-in-water type emulsion |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5976968B1 (en) * | 2015-10-02 | 2016-08-24 | 株式会社J−オイルミルズ | Oil and fat composition and method for producing the same |
TWI732020B (en) * | 2016-08-22 | 2021-07-01 | 日商J 制油股份有限公司 | Composition for enhanced imparting cheese flavor, manufacturing method of the composition for enhanced imparting cheese flavor, enhanced imparting method of cheese flavor for food, and manufacturing method of food with an enhanced imparting cheese flavor |
US20190166867A1 (en) * | 2016-08-22 | 2019-06-06 | J-Oil Mills, Inc. | Oil or fat composition for fried foods, method for producing oil or fat composition for fried foods, method for producing fried foods, and method for imparting cheese flavor to fried foods |
CN109984204A (en) * | 2017-12-29 | 2019-07-09 | 丰益(上海)生物技术研发中心有限公司 | The fat or oil composition of the powder of crushed rices containing rice |
CN112715911A (en) * | 2020-12-28 | 2021-04-30 | 上海华宝孔雀香精有限公司 | Natural milk flavor essence and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000511230A (en) * | 1996-05-21 | 2000-08-29 | カーギル,インコーポレーテッド | Very stable canola oil |
JP2003049189A (en) * | 2001-08-02 | 2003-02-21 | Ezaki Glico Co Ltd | Powdered fat containing new highly-branched cyclic dextrin, method for producing the same, and food and drink given by utilizing the same |
JP2009089684A (en) * | 2007-10-11 | 2009-04-30 | Nisshin Oillio Group Ltd | Low trans-fatty acid oil and fat composition |
JP2011254777A (en) * | 2010-06-11 | 2011-12-22 | Ueda Oils & Fats Mfg Co Ltd | Oil and fat for emulsified food, and emulsified food |
WO2013027439A1 (en) * | 2011-08-24 | 2013-02-28 | 株式会社J-オイルミルズ | Oxidized partially hydrogenated oil |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4319361B2 (en) | 2001-06-25 | 2009-08-26 | 長谷川香料株式会社 | Milk flavor enhancer or enhancer |
TW200526131A (en) * | 2003-11-12 | 2005-08-16 | J Oil Mills Inc | Method of application of body taste enhancer comprising long-chain highly unsaturated fatty acid and/or its ester |
JP2009284859A (en) | 2008-05-30 | 2009-12-10 | J-Oil Mills Inc | Sweetness-reinforcing agent for food and drink, and method for reinforcing sweetness |
JP5399083B2 (en) | 2009-01-09 | 2014-01-29 | 長谷川香料株式会社 | Milk flavor imparting or enhancing agent and its use in food and drink |
CA2774033A1 (en) * | 2009-09-14 | 2011-03-17 | J-Oil Mills, Inc. | Taste enhancing agent |
JP4675428B1 (en) * | 2010-02-15 | 2011-04-20 | 植田製油株式会社 | Method for producing hydrogenated fats and oils |
-
2013
- 2013-09-02 WO PCT/JP2013/073476 patent/WO2014077019A1/en active Application Filing
- 2013-09-02 CN CN201380059329.9A patent/CN104780779B/en active Active
- 2013-09-02 SG SG11201502724PA patent/SG11201502724PA/en unknown
- 2013-09-02 JP JP2014502918A patent/JP5612234B1/en active Active
- 2013-09-02 MY MYPI2015701529A patent/MY171340A/en unknown
- 2013-09-02 KR KR1020157010137A patent/KR102098155B1/en active IP Right Grant
- 2013-11-05 TW TW102140080A patent/TWI620510B/en not_active IP Right Cessation
-
2015
- 2015-04-08 PH PH12015500777A patent/PH12015500777A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000511230A (en) * | 1996-05-21 | 2000-08-29 | カーギル,インコーポレーテッド | Very stable canola oil |
JP2003049189A (en) * | 2001-08-02 | 2003-02-21 | Ezaki Glico Co Ltd | Powdered fat containing new highly-branched cyclic dextrin, method for producing the same, and food and drink given by utilizing the same |
JP2009089684A (en) * | 2007-10-11 | 2009-04-30 | Nisshin Oillio Group Ltd | Low trans-fatty acid oil and fat composition |
JP2011254777A (en) * | 2010-06-11 | 2011-12-22 | Ueda Oils & Fats Mfg Co Ltd | Oil and fat for emulsified food, and emulsified food |
WO2013027439A1 (en) * | 2011-08-24 | 2013-02-28 | 株式会社J-オイルミルズ | Oxidized partially hydrogenated oil |
Non-Patent Citations (5)
Title |
---|
"Shokuhin no Oishisa Tsuikyu, Tokyo Kaiyodai, Abura ni 'Aji' Chunyu, Enbun Hikaeme ni, Aji no Zofuku Machanism Kaimei e", NIKKAN KOGYO SHINBUN, 14 September 2009 (2009-09-14), pages 23 * |
"Urenai Jidai no 'Shokuhin' Zukuri, Kaihatsu Tantosha ga Kataru 8, Fry Abura 'Bimi Tokutoku', Kokyaku no Koe Han'ei 'Koku' Tsuikyu", NIKKAN KOGYO SHINBUN, 30 July 2009 (2009-07-30), pages 15 * |
KIYOHARA, R. ET AL.: "Effect of adding arachidonic acid to cooked foods", JOURNAL OF COOKERY SCIENCE OF JAPAN, vol. 42, no. 5, 2009, pages 294 - 299 * |
SUSUMU YAMAGUCHI: "Arachidonic Acid' ni yoru Shokuhin no Oishisa Kojo Koka, Yushi to sono Kanetsu Seisei Seibun ga Mikaku ni Oyobosu Eikyo", KAGAKU TO SEIBUTSU, vol. 49, no. 5, 2011, pages 297 - 299 * |
WATANABE, K.: "The technology to enhance palatability of the prepared foods by the new type of functional edible oil", FOOD CHEMICALS, vol. 3, 2010, pages 19 - 28 * |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018020812A1 (en) * | 2016-07-27 | 2018-02-01 | 株式会社J-オイルミルズ | Powder oil/fat composition and method for producing same |
WO2018037926A1 (en) * | 2016-08-22 | 2018-03-01 | 株式会社J-オイルミルズ | Sweetness and/or saltiness enhancing agent |
WO2018037927A1 (en) * | 2016-08-22 | 2018-03-01 | 株式会社J-オイルミルズ | Composition that suppresses unpleasant odor from food products |
JPWO2018037926A1 (en) * | 2016-08-22 | 2019-06-20 | 株式会社J−オイルミルズ | Sweetener and / or salt enhancer |
JPWO2018123594A1 (en) * | 2016-12-27 | 2019-10-31 | 株式会社J−オイルミルズ | Acidity enhancer |
WO2018123594A1 (en) * | 2016-12-27 | 2018-07-05 | 株式会社J-オイルミルズ | Sourness enhancing agent |
WO2018123595A1 (en) * | 2016-12-27 | 2018-07-05 | 株式会社J-オイルミルズ | Umami taste enhancing agent |
JPWO2018123595A1 (en) * | 2016-12-27 | 2019-10-31 | 株式会社J−オイルミルズ | Umami enhancer |
CN110072400A (en) * | 2016-12-27 | 2019-07-30 | J-制油株式会社 | Bad smell inhibitor |
CN110087494A (en) * | 2016-12-27 | 2019-08-02 | J-制油株式会社 | Flavour enhancer |
JP2018130052A (en) * | 2017-02-14 | 2018-08-23 | 株式会社Adeka | Method for producing flavor-enhancing oil/fat |
WO2018186328A1 (en) * | 2017-04-04 | 2018-10-11 | 株式会社J-オイルミルズ | Taste improver |
CN110536608A (en) * | 2017-04-04 | 2019-12-03 | J-制油株式会社 | Flavor improver |
JPWO2018186328A1 (en) * | 2017-04-04 | 2020-02-20 | 株式会社J−オイルミルズ | Taste improver |
JP7201584B2 (en) | 2017-04-04 | 2023-01-10 | 株式会社J-オイルミルズ | taste improver |
WO2019073811A1 (en) * | 2017-10-13 | 2019-04-18 | 株式会社J-オイルミルズ | Fat feeling enhancer for foods, and food containing same |
JP7166268B2 (en) | 2017-10-13 | 2022-11-07 | 株式会社J-オイルミルズ | FOOD GREASE ENHANCEMENT AGENT AND FOOD CONTAINING THE SAME |
JPWO2019073811A1 (en) * | 2017-10-13 | 2020-10-22 | 株式会社J−オイルミルズ | Food oil and fat sensation enhancer and foods containing it |
JP7454501B2 (en) | 2018-10-31 | 2024-03-22 | 株式会社J-オイルミルズ | Oxidized product of palm oil and fat, method for producing oxidized product, method for enhancing sweetness of food, and composition for enhancing sweetness of food |
JP7414728B2 (en) | 2018-10-31 | 2024-01-16 | 株式会社J-オイルミルズ | Method for producing an oil and fat composition, method for producing an edible oil and fat composition, method for producing a food, method for enhancing the sweetness of a food, and composition for enhancing the sweetness of a food |
WO2020090608A1 (en) * | 2018-10-31 | 2020-05-07 | 株式会社J-オイルミルズ | Production method for oil/fat composition, production method for edible oil/fat composition, food production method, food sweetness-enhancing method, and food sweetness-enhancing composition |
WO2020090609A1 (en) * | 2018-10-31 | 2020-05-07 | 株式会社J-オイルミルズ | Oxidized product of palm-based fat/oil, production method for oxidized product, food sweetness-enhancing method, and food sweetness-enhancing composition |
JPWO2020090609A1 (en) * | 2018-10-31 | 2021-09-24 | 株式会社J−オイルミルズ | Oxidized products of palm-based fats and oils, methods for producing oxidized products, methods for enhancing the sweetness of foods, and compositions for enhancing the sweetness of foods. |
JP2020074708A (en) * | 2018-11-07 | 2020-05-21 | 株式会社Adeka | Oil and fat composition for bakery |
JP7203574B2 (en) | 2018-11-07 | 2023-01-13 | 株式会社Adeka | Fat and oil composition for bakery |
EP3884783A4 (en) * | 2018-11-20 | 2022-08-17 | Kao Corporation | Oil and fat composition |
WO2020209158A1 (en) * | 2019-04-11 | 2020-10-15 | 株式会社J-オイルミルズ | Oil/fat feel enhancer for food and method for enhancing oil/fat feel of food |
JP6937958B1 (en) * | 2019-09-30 | 2021-09-22 | 株式会社J−オイルミルズ | Umami-enhancing composition, seasoning or extract, method for producing umami-enhancing composition, method for producing seasoning or extract, and method for producing umami-enhancing food. |
WO2021065442A1 (en) * | 2019-09-30 | 2021-04-08 | 株式会社J-オイルミルズ | Umami-enhancing composition and method for manufacturing same, flavoring or extract and method for manufacturing same, fat/oil composition for cooking and method for manufacturing same, and method for enhancing umami in food |
WO2021065441A1 (en) * | 2019-09-30 | 2021-04-08 | 株式会社J-オイルミルズ | Umami enhancing composition, flavoring or extract, production method for umami enhancing composition, production method for flavoring or extract, and umami enhancing method for food |
JP2021078450A (en) * | 2019-11-20 | 2021-05-27 | 花王株式会社 | Sweetness enhancer |
JP7406355B2 (en) | 2019-11-20 | 2023-12-27 | 花王株式会社 | sweetness enhancer |
JPWO2022102382A1 (en) * | 2020-11-10 | 2022-05-19 | ||
WO2022102382A1 (en) * | 2020-11-10 | 2022-05-19 | 不二製油グループ本社株式会社 | Sweetness enhancement method for oil-based food product |
JP7168119B2 (en) | 2020-11-10 | 2022-11-09 | 不二製油株式会社 | Method for enhancing sweetness of oily food |
WO2023038008A1 (en) * | 2021-09-13 | 2023-03-16 | 株式会社J-オイルミルズ | Rich flavor enhancer and rich flavor enhancing method |
WO2023054274A1 (en) | 2021-09-29 | 2023-04-06 | 株式会社Adeka | Oil-in-water type emulsion |
KR20240064631A (en) | 2021-09-29 | 2024-05-13 | 가부시키가이샤 아데카 | Oil-in-water emulsion |
Also Published As
Publication number | Publication date |
---|---|
MY171340A (en) | 2019-10-09 |
TWI620510B (en) | 2018-04-11 |
SG11201502724PA (en) | 2015-05-28 |
PH12015500777A1 (en) | 2015-06-15 |
JP5612234B1 (en) | 2014-10-22 |
TW201440666A (en) | 2014-11-01 |
JPWO2014077019A1 (en) | 2017-01-05 |
KR102098155B1 (en) | 2020-04-07 |
CN104780779B (en) | 2016-10-26 |
CN104780779A (en) | 2015-07-15 |
KR20150083995A (en) | 2015-07-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5612234B1 (en) | Sweetness and / or milk flavor enhancer | |
CN100448359C (en) | Ubiquinone-enriched foods | |
JP6585346B2 (en) | Plastic fat composition and method for producing the same | |
JP2011083264A (en) | Oil and fat feel enhancer | |
JP6956090B2 (en) | Sweetness and / or saltiness enhancer | |
JP2007129985A (en) | Soybean fermented material-containing food product, and food oil absorption suppressing composition, food peelability improving composition, food emulsification stabilizing composition, saccharide crystallization inhibiting composition, oil and fat crystallization inhibiting composition, maillard reaction promoting composition, food offensive smell/taste suppressing composition, and starch food product aging delaying composition | |
JP6841680B2 (en) | Manufacturing method of flavor-enhancing fats and oils | |
JPWO2018186328A1 (en) | Taste improver | |
TW202100027A (en) | Oil and fat texture enhancer for food and method for enhancing oil and fat texture of food | |
JP2002186424A (en) | Food/drink containing conjugated trienoic acid-based oil and fat | |
JP6210741B2 (en) | Taste improving agent and perfume composition containing the taste improving agent | |
WO2021256394A1 (en) | Method for improving persistence of flavor of food/beverage product | |
JP4801026B2 (en) | Roast food manufacturing method, roast food obtained by this manufacturing method, and food containing the same | |
JP2010227125A (en) | Emulsion stabilizing composition and fermented soybean-containing food containing the same | |
JP4800132B2 (en) | Fragrance composition for adzuki food addition, azuki food and method for improving flavor of azuki food | |
JP4906147B1 (en) | Taste improver for high-intensity sweeteners | |
JP2018068173A (en) | Fat composition for choux, choux dough using the same, and method for producing choux pastry | |
JP7090408B2 (en) | Edible fats and oils and foods containing the edible fats and oils | |
JPH06189711A (en) | Palm oil carotene-containing food | |
JP5927123B2 (en) | Food taste improver | |
JP6836320B2 (en) | Oil and fat composition for cooking and oil and fat composition for butter cream | |
JP4868640B2 (en) | Oil composition | |
TW202345703A (en) | Oil or fat composition for rich flavor enhancement | |
WO2013004743A1 (en) | Flavour delivery |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ENP | Entry into the national phase |
Ref document number: 2014502918 Country of ref document: JP Kind code of ref document: A |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 13855457 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12015500777 Country of ref document: PH |
|
ENP | Entry into the national phase |
Ref document number: 20157010137 Country of ref document: KR Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: IDP00201503472 Country of ref document: ID |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 13855457 Country of ref document: EP Kind code of ref document: A1 |