TW201422654A - 硬化膜形成組成物 - Google Patents
硬化膜形成組成物 Download PDFInfo
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- TW201422654A TW201422654A TW102130809A TW102130809A TW201422654A TW 201422654 A TW201422654 A TW 201422654A TW 102130809 A TW102130809 A TW 102130809A TW 102130809 A TW102130809 A TW 102130809A TW 201422654 A TW201422654 A TW 201422654A
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- TW
- Taiwan
- Prior art keywords
- cured film
- forming composition
- film forming
- repeating unit
- ether
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 75
- -1 acrylate compound Chemical class 0.000 claims abstract description 55
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- 239000002904 solvent Substances 0.000 claims abstract description 24
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 10
- 239000007870 radical polymerization initiator Substances 0.000 claims abstract description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims abstract description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
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Abstract
本發明係提供一種硬化膜形成組成物,其係含有:(A)(A-1)具有以下述式(1)所示之重複單元的聚合物、(B)多官能丙烯酸酯化合物、(C)自由基聚合起始劑、及(D)溶劑。□(式中,R1係表示氫原子、甲基、氯基或苯基;R2係表示碳數1~5之烷基,L係表示碳數1~9之伸烷基)。
Description
本發明係關於一種硬化膜形成組成物。
目前,從搬運或保存上之要求,利用薄膜基板取代玻璃基板漸增加起來。薄膜基板係於保存時形成輥輪狀等而被保存,但其時,因基板彎曲,故塗佈於薄膜基板上之材料亦被要求與薄膜同樣的柔軟性。
又,在ITO薄膜等之薄膜上形成電極的基板中,於基板之貼合上使用黏著劑時,因黏著劑之水分而銀配線劣化,產生短路等之問題,故尋求一種保護電極與配線之被覆塗佈材料。
另外,以往之被覆塗佈材料係目的在於塗佈於玻璃基板上者,為提高硬度,含有無機微粒子(專利文獻1)。但,在含有無機微粒子等之習知方法中,硬度雖被改善,但無柔軟性,例如於彎折時產生出現龜裂等之不佳情形,故無法適用於對薄膜基板之塗佈乃為現狀。
[專利文獻1]特開2012-116975號公報
本發明係有鑑於上述問題者,目的在於提供一種可用來作為具有高的透過率、對ITO薄膜之高密著性、高硬度、高的柔軟性及長期信賴性的被覆塗佈材料之硬化膜形成組成物。
本發明人等係為解決上述課題,累積專心研究之結果,發現藉由含有具特定之重複單元的聚合物、多官能丙烯酸酯化合物、依需要之離子捕捉劑、與依需要之多官能硫醇化合物的組成物,俾可得到能解決上述課題之薄膜,終完成本發明。
亦即,本發明係提供
1.一種硬化膜形成組成物,其特徵係含有:(A)(A-1)具有以下述式(1)所示之重複單元的聚合物
(式中,R1係表示氫原子、甲基、氯基或苯基;R2係表示碳數1~5之烷基,L係表示碳數1~9之伸烷基)、(B)多官能丙烯酸酯化合物、(C)自由基聚合起始劑、及(D)溶劑。
2.如第1項之硬化膜形成組成物,其中進一步含有(A-2)具有以下述式(2)所示之重複單元的聚合物作為(A)成分;
(式中,R1係與上述相同)。
3.如第1或2項之硬化膜形成組成物,其中上述聚合物進一步具有以下述式(3)所示之重複單元;
(式中,R3及R3’係分別獨立表示氫原子或碳數1~3之烷基;R4、R4’及R5係分別獨立表示氫原子、鹵素原子或碳數1~5之烷基)。
4.如第1~3項中任一項之硬化膜形成組成物,其中進一步含有(E)離子捕捉劑。
5.如第1~4項中任一項之硬化膜形成組成物,其中進一步含有(F)多官能硫醇化合物。
6.一種硬化膜之製造方法,其特徵係於基板上塗佈如第1~5項中任一項之硬化膜形成組成物,照射紫外線後,以80℃~120℃進行燒成。
7.一種硬化膜,其係以如第6項之製造方法來製造。
8.一種薄膜,其係具有如第7項之硬化膜。
本發明之組成物係因含有具三烷氧基矽烷構造的聚合物,故從此所得到之硬化膜係硬度高,密著性優異。進一步,藉多官能丙烯酸酯化合物,可進一步改善硬度。又,藉由含有多價硫醇化合物,柔軟性優,且亦可改善密著性。藉由此等,即使過剩地含有多官能丙烯酸酯,亦不會產生剝離及龜裂。
以下,更詳細地說明本發明。
本發明之硬化膜形成組成物係含有下述(A)~(D),依需要而含有下述(E)~(G)成分或其他之添加劑之中的1種以上。
本發明之組成物中的(A)成分係(A-1)具有以下述式(1)所示之重複單元的聚合物,依需要亦可含有(A-2)具有以下述式(2)所示之重複單元的聚合物。此等之聚合物係依需要進一步亦可具有以下述式(3)所示之重複單元。
(式中,R1分別獨立地表示氫原子、甲基、氯基或苯基,R2係表示碳數1~5之烷基,L表示碳數1~9之伸烷基,R3及R3’係分別獨立表示氫原子或碳數1~3之烷基,R4、R4’及R5係分別獨立表示氫原子、鹵原子或碳數1~5之烷基)。
上述聚合物具有以式(3)所示之重複單元時,可對本發明之硬化膜形成組成物進一步賦予密著性與疏水性(低
吸水性)之特性,故佳。
又,以式(1)所示之重複單元、以式(2)所示之重複單元、以式(3)所示之重複單元係亦可於一個聚合物中同時地含有。
在本發明之組成物所使用的聚合物中,以式(1)所示之重複單元的含有率係全重複單元100莫耳%中宜為1~60莫耳%。以式(1)所示之重複單元的含有率小於上述數值範圍時,有時本發明之聚合物的特性、硬化膜特性例如硬度等之特性降低。以式(1)所示之重複單元之含有率大於上述數值範圍時,有時清漆之保存安定性、密著性等之特性降低。
在本發明之組成物所使用的聚合物中,以式(2)所示之重複單元的含有率係全重複單元100莫耳%中宜為1~60莫耳%。以式(2)所示之重複單元的含有率小於上述數值範圍時,有時本發明之聚合物的特性、硬化膜特性之高溫高濕試驗的吸水性提高,長期信賴性之密著性等的特性降低。以式(2)所示之重複單元之含有率大於上述數值範圍時,有時密著性等之特性降低。
在本發明之組成物所使用的聚合物中,以式(3)所示之重複單元的含有率係全重複單元100莫耳%中宜為1~60莫耳%。以式(3)所示之重複單元的含有率小於上述數值範圍時,有時本發明之聚合物的特性、硬化膜特性之硬度、密著性等之特性降低。以式(3)所示之重複單元之含有率大於上述數值範圍時,有時密著性等之特性降低。
(A-1)成分之聚合物係藉由使得到以式(1)所示之重複單元之單體及依需要之以式(3)所示之重複單元的單體等聚合來製造。
(A-2)成分之聚合物係藉由使得到以式(2)所示之重複單元之單體及依需要之以式(3)所示之重複單元的單體等聚合來製造。
於一個聚合物同時地含有以式(1)~(3)所示之重複單元時,係藉由使得到以上述式(1)所示之重複單元之單體、得到以式(2)所示之重複單元之單體、得到依需要之以式(3)所示之重複單元的單體等共聚合來製造。
聚合方法係可採用自由基聚合、陰離子聚合、陽離子聚合等。此等之中,尤宜為自由基聚合,具體上係只要在溶劑中,在聚合起始劑之存在下加熱、聚合上述聚合性化合物即可。
得到以式(1)所示之重複單元之單體係可舉例如3-三甲氧基矽烷基丙基丙烯酸酯、3-三乙氧基矽烷基丙基丙烯酸酯、3-三甲氧基矽烷基丙基甲基丙烯酸酯、3-三乙氧基矽烷基丙基甲基丙烯酸酯等。其中,從汎用性、流通性之觀點,宜為3-三甲氧基矽烷基丙基甲基丙烯酸酯。
得到以式(2)所示之重複單元之單體係可舉例如丙烯酸、甲基丙烯酸等。
得到以式(3)所示之重複單元之單體係可舉例如苯乙烯、甲基苯乙烯、氯苯乙烯、溴苯乙烯、4-第三丁基苯乙烯等之苯乙烯化合物。
(A-1)及(A-2)成分之聚合物係亦可含有上述以外之其他的重複單元。可得到其他之重複單元的單體係可舉例如丙烯酸酯化合物、甲基丙烯酸酯化合物、馬來醯亞胺化合物、丙烯腈、馬來酸酐、乙烯基化合物等。以下,可舉例如其具體例,但不限定於此等。
丙烯酸酯化合物係可舉例如甲基丙烯酸酯、乙基丙烯酸酯、異丙基丙烯酸酯、苯甲基丙烯酸酯、萘基丙烯酸酯、蒽基丙烯酸酯、蒽基甲基丙烯酸酯、苯基丙烯酸酯、2,2,2-三氟乙基丙烯酸酯、第三丁基丙烯酸酯、環己基丙烯酸酯、異降莰基丙烯酸酯、2-甲氧基乙基丙烯酸酯、甲氧基三乙二醇丙烯酸酯、2-乙氧基乙基丙烯酸酯、四氫呋喃基丙烯酸酯、3-甲氧基丁基丙烯酸酯、2-甲基-2-金剛烷基丙烯酸酯、2-丙基-2-金剛烷基丙烯酸酯、8-甲基-8-三環癸基丙烯酸酯、2-羥乙基丙烯酸酯、2-羥丙基丙烯酸酯、2,3-二羥丙基丙烯酸酯、二乙二醇單丙烯酸酯、4-羥丁基丙烯酸酯、己內酯2-(丙烯醯氧)乙基酯、聚(乙二醇)乙基醚丙烯酸酯、5-丙烯醯氧-6-羥基降莰烯-2-羥酸基-6-內酯、8-乙基-8-三環癸基丙烯酸酯等。
甲基丙烯酸酯化合物係可舉例如甲基甲基丙烯酸酯、乙基甲基丙烯酸酯、異丙基甲基丙烯酸酯、苯甲基甲基丙烯酸酯、萘基甲基丙烯酸酯、蒽基甲基丙烯酸酯、蒽基甲基甲基丙烯酸酯、苯基甲基丙烯酸酯、2,2,2-三氟乙基甲基丙烯酸酯、第三丁基甲基丙烯酸酯、環己基甲基丙烯酸酯、異降莰基甲基丙烯酸酯、2-甲氧基乙基甲基丙烯酸
酯、甲氧基三乙二醇甲基丙烯酸酯、2-乙氧基乙基甲基丙烯酸酯、四氫呋喃基甲基丙烯酸酯、3-甲氧基丁基甲基丙烯酸酯、2-甲基-2-金剛烷基甲基丙烯酸酯、γ-丁內酯甲基丙烯酸酯、2-丙基-2-金剛烷基甲基丙烯酸酯、8-甲基-8-三環癸基甲基丙烯酸酯、8-乙基-8-三環癸基甲基丙烯酸酯、2-羥乙基甲基丙烯酸酯、2-羥丙基甲基丙烯酸酯、4-羥丁基甲基丙烯酸酯、2,3-二羥丙基甲基丙烯酸酯、二乙二醇單甲基丙烯酸酯、己內酯2-(甲基丙烯醯氧)乙基酯、聚(乙二醇)乙基醚甲基丙烯酸酯、5-甲基丙烯醯氧-6-羥基降莰烯-2-羥酸基-6-內酯等。
乙烯基化合物係可舉例如甲基乙烯基醚、苯甲基乙烯基醚、乙烯基萘、乙烯基蔥、乙烯基聯苯基、乙烯基咔唑、2-羥乙基乙烯基醚、苯基乙烯基醚、丙基乙烯基醚等。
馬來醯亞胺化合物係可舉例如馬來醯亞胺、N-甲基馬來醯亞胺、N-苯基馬來醯亞胺、N-環己基馬來醯亞胺等。
與可得到以式(1)所示之重複單元的單體共聚合之單體,上述化合物之中,宜為丙烯酸酯化合物、甲基丙烯酸酯化合物,尤宜為甲基丙烯酸酯。
上述聚合起始劑係可從以往公知者適當選擇而使用。可舉例如過氧化甲醯基、氫過氧化枯烯、氫過氧化第三丁基等之過氧化物;過硫酸鈉、過硫酸鉀、過硫酸銨等之過硫酸鹽;偶氮雙異丁腈、偶氮雙甲基丁腈、偶氮雙異戊腈、2,2’-偶氮雙(異酪酸)二甲基等之偶氮系化合物等。此
等係可1種單獨或組合2種以上而使用。
上述聚合起始劑之使用量係相對於單體1莫耳,宜為0.005~0.05莫耳左右。聚合時之反應溫度係只要以0℃至使用之溶劑的沸點適當設定即可,但宜為20~100℃左右。反應時間宜為0.1~30小時左右。
可使用於聚合反應之溶劑係無特別限定,從上述聚合反應一般所使用之各種溶劑適當選擇即可。具體上係可舉例如水;甲醇、乙醇、1-丙醇、2-丙醇、1-丁醇、2-丁醇、異丁醇、第三丁醇、1-戊醇、2-戊醇、3-戊醇、異戊醇、第三戊醇、1-己醇、1-庚醇、2-庚醇、3-庚醇、2-辛醇、2-乙基-1-己醇、苯甲基醇、環己醇等之醇類;二乙基醚、二異丙基醚、二丁基醚、環戊基甲基醚、四氫呋喃、1,4-二噁烷等之醚類;氯仿、二氯甲烷、二氯乙烷、四氯化碳等之鹵化烴類;甲基溶纖劑、乙基溶纖劑、異丙基溶纖劑、丁基溶纖劑、二乙二醇單丁基醚等之醚醇類;丙酮、甲乙酮、甲基異丁基酮、環己酮等之酮類;醋酸乙酯、醋酸丁酯、丙酸乙酯、溶纖劑乙酸酯等之酯類;正戊烷、正己烷、正庚烷、正辛烷、正壬烷、正癸烷、環戊烷、甲基環戊烷、環己烷、甲基環己烷、苯、甲苯、二甲苯、乙基苯、茴香醚等之脂肪族或芳香族烴類;二甲氧基甲烷(methylal)、二乙基縮醛等之縮醛類;蟻酸、醋酸、丙酸等之脂肪酸類;硝基丙烷、硝基苯、二甲基胺、單乙醇胺、吡啶、N-甲基-2-吡啶烷酮、N,N-二甲基甲醯胺、二甲基亞碸、乙腈等。此等係可1種單獨或組合2種以上
而使用。
可使用於本發明之聚合物係宜重量平均分子量為1,000~80,000,更宜為2,000~60,000,最宜為3,000~50,000。若重量平均分子量超過80,000,有時對於溶劑之溶解性降低,操作性降低,若重量平均分子量未達1,000,有時熱硬化時變成硬化不足,耐溶劑性及耐熱性降低。
又,重量平均分子量係以凝膠滲透色層分析(GPC)所得到之聚苯乙烯換算測定值。
又,可使用於本發明之聚合物係亦可為隨機共聚物、交互共聚物、嵌段共聚物的任一者。
本發明之組成物中的(B)成分係多官能丙烯酸酯化合物。如此之化合物的具體例可舉例如二季戊四醇六丙烯酸酯、二季戊四醇六甲基丙烯酸酯、二季戊四醇五丙烯酸酯、二季戊四醇五甲基丙烯酸酯、季戊四醇四丙烯酸酯、季戊四醇四甲基丙烯酸酯、季戊四醇三丙烯酸酯、季戊四醇三甲基丙烯酸酯、季戊四醇二丙烯酸酯、季戊四醇二甲基丙烯酸酯、四羥甲基丙烷四丙烯酸酯、四羥甲基丙烷四甲基丙烯酸酯、四羥甲基甲烷四丙烯酸酯、四羥甲基甲烷四甲基丙烯酸酯、三羥甲基丙烷三丙烯酸酯、三羥甲基丙烷三甲基丙烯酸酯、1,3,5-三丙烯醯基六氫-S-三嗪、1,3,5-三甲基丙烯醯基六氫-S-三嗪、參(羥乙基丙烯醯基)三聚異氰酸酯、參(羥乙基甲基丙烯醯基)三聚異氰酸酯等
之多官能丙烯酸酯化合物。
上述之多官能丙烯酸酯化合物係可自市售品容易取得,其具體例可舉例如KAYARAD T-1420、同DPHA、同DPHA-2C、同D-310、同D-330、同DPCA-20、同DPCA-30、同DPCA-60、同DPCA-120、同DN-0075、同DN-2475、同R-526、同NPGDA、同PEG400DA、同MANDA、同R-167、同HX-220、同HX 620、同R-551、同R-712、同R-604、同R-684、同GPO-303、同TMPTA、同THE-330、同TPA-320、同TPA-330、同PET-30、同RP-1040(以上,日本化藥(股)製)、ARONIX M-210、同M-240、同M-6200、同M-309、同M-400、同M-402、同M-405、同M-450、同M-7100、同M-8030、同M-8060、同M-1310、同M-1600、同M-1960、同M-8100、同M-8530、同M-8560、同M-9050(以上,東亞合成(股)製)、Biscoat 295、同300、同360、同GPT、同3PA、同400、同260、同312、同335HP(以上,大阪有機化學工業(股)製)等。又,此等係可1種單獨或組合2種以上而使用。
(B)成分之含量係相對於(A)成分100質量份宜為10~300質量份,更宜為20~250質量份,尤宜為30~200質量份。此含量太小時,硬化膜之硬度特性降低,此比率太大時,密著性與柔軟性的特性降低,易產生龜裂。
(C)成分係自由基聚合起始劑,有助於(B)成分之聚合
的開始或促進者。
自由基聚合起始劑係只要可藉光照射及/或加熱釋出起始自由基聚合之物質即可。例如,光自由基聚合起始劑可舉例如二苯甲酮衍生物、咪唑衍生物、雙咪唑衍生物、N-芳基甘氨酸衍生物、有機疊氮化合物、二茂鈦類、氧化鋁鹽錯合物、有機過氧化物、N-烷氧基吡啶鎓鹽、硫雜蔥酮衍生物等,更具體地,可舉例如二苯甲酮、1,3-二(第三丁基二氧羰基)二苯甲酮、3,3’,4,4’-肆(第三丁基二氧羰基)二苯甲酮、3-苯基-5-異噁嗪酮、2-氫硫基苯並咪唑、雙(2,4,5-三苯基)咪唑、2,2-二甲氧基-1,2-二苯基乙烷-1-酮(商品名Irgacure651、BASF公司製)、1-羥基環己基苯基酮(商品名Irgacure184、BASF公司製)、2-苯甲基-2-二甲基胺基-1-(4-嗎啉基苯基)-丁烷-1-酮(商品名Irgacure369、BASF公司製)、雙(η5-2,4-環戊二烯-1-基)-雙(2,6-二氟-3-(1H-吡咯-1-基)-苯基)鈦鎓(商品名Irgacure784、BASF公司製)等,但不限定於此等。
上述以外,亦可使用市售品,具體上可舉例如BASF公司製之Irgacure907、Irgacure379、Irgacure819、Irgacure127、Irgacure500、Irgacure754、Irgacure250、Irgacure1800、Irgacure1870、IrgacureOXE01、DAROCURTPO、DAROCUR1173、Lambson公司製之SpeedcureMBB、SpeedcurePBZ、SpeedcureITX、SpeedcureCTX、SpeedcureEDB、EsacureONE、Esacure KIP150、Esacure KTO46、日本化藥(股)製之KAYACURE
DETX-S、KAYACURECTX、KAYACURE BMS、KAYACURE DMBI等。
此等之中,從密著性提昇之理由,尤宜為1-羥基環己基苯基酮與二苯甲酮之混合物(商品名Irgacure500,BASF公司製)。
(C)成分之自由基聚合起始劑的含量係相對於(A)成分100質量份,一般為1~20質量份,宜為1~15質量份。
本發明之硬化膜形成組成物係主要以溶解於溶解之溶液狀態使用。其時使用之溶劑係只要可溶解(A)成分、(B)成分、(C)成分、以及依需要之後述的(E)成分、(F)成分、(G)成分及其他之添加劑即可,並無特別限定。
溶劑之具體例可舉例如甲苯、二甲苯、乙二醇單甲基醚、乙二醇單甲基醚乙酸酯、乙二醇單乙基醚、乙二醇二乙基醚、乙二醇單乙基醚乙酸酯、乙二醇異丙基醚、乙二醇單乙酸酯、二乙二醇甲基乙基醚、丙二醇單甲基醚、丙二醇單乙基醚、1,1,2-三氯乙烷、1,1,1,2-四氯乙烷、1,1,2,2-四氯乙烷、甲基苯基醚、1,4-二噁烷、二乙基縮醛、丁醇、2-丁醇、異戊醇、甲基丙基酮、甲基丁基酮、甲基異丁基酮、二乙基酮、乙基-正丁基酮、二正丙基酮、醋酸異丁酯、丙酸正丁酯、癸烷、十二碳烷、對薄荷烷、二戊烯、乙二醇、乙二醇單丁基醚、乙二醇二丁基醚、乙二醇單丁基醚乙酸酯、乙二醇單苯基醚、乙二醇單己基醚、甲氧基甲氧基乙醇、乙二醇二乙酸酯、二乙二
醇、二乙二醇單甲基醚、二乙二醇單乙基醚、二乙二醇單乙基醚乙酸酯、二乙二醇單丁基醚、二乙二醇單丁基醚乙酸酯、二乙二醇二甲基醚、二乙二醇二乙基醚、二乙二醇二丁基醚、二乙二醇乙酸酯、三乙二醇單甲基醚、二氯化三甘醇、丙二醇、丙二醇單丁基醚、1-丁氧基乙氧基丙醇、二丙二醇、二丙二醇單甲基醚、二丙二醇單乙基醚、三丙二醇單甲基醚、二丙二醇單丁基醚、三亞甲基甘醇、1,3-丁烷二醇、2,3-丁烷二醇、1,5-戊烷二醇、己二醇、辛二醇、甘油、六氯乙烷、鄰-二氯苯、間-二氯苯、對-二氯苯、1,2,4-三氯苯、鄰二溴苯、二氯乙基醚、二異戊基醚、正己基醚、乙基苯基醚、乙基苯甲基醚、桉油醇(Cineole)、1-辛醇、2-辛醇、2-乙基己醇、3,5,5-三甲基己醇、壬醇、正癸醇、三甲基壬基醇、2-甲基環己醇、苯甲基醇、呋喃甲基醇、四氫呋喃甲基醇、α-萜烯醇、松脂醇、己二酮(acetonylacetone)、佛爾酮、異佛爾酮、乙醯苯、醋酸甲氧基丁酯、醋酸-2-乙基己基醋酸環己酯、醋酸甲基環己酯、醋酸苯甲酯、醋酸異戊酯、硬脂酸丁酯、乙醯酪酸乙酯、異吉草酸異戊酯、乳酸(正-、異-)丁酯、乳酸正戊酯、乳酸異戊酯、安息香酸甲酯、安息香酸乙酯、安息香酸丙酯、水楊酸甲酯、草酸二丁酯、丙二酸二乙酯、酪酸酐、吉草酸、異吉草酸、己酸、2-乙基酸、辛酸、2-乙基己烷酸、三氯醋酸、乳酸、硝基苯、苯腈、α-三腈、N-甲基甲醯胺、N-甲基乙醯胺、2-吡咯烷酮等。
上述溶劑係從印刷性之觀點,尤宜為二乙二醇單甲基
醚、二乙二醇單乙基醚、二乙二醇單乙基醚乙酸酯、二乙二醇單丁基醚、二乙二醇單丁基醚乙酸酯、二乙二醇二甲基醚、二乙二醇二乙基醚、二乙二醇二丁基醚、丙二醇單丁基醚、二丙二醇、二丙二醇單甲基醚、二丙二醇單乙基醚等。
此等之溶劑係可1種單獨或混合2種以上而使用。又,亦可直接使用用於(A)成分之聚合的溶劑。
(E)成分係離子捕捉劑,形成於基板上之金屬配線與水接觸,可防止造成遷移者。如此之離子捕捉劑係宜為在構造中具有不對稱電子之螯合形成能的化合物,可舉例如N,N’-雙[3-(3,5-二第三丁基-4-羥基苯基)丙醯基]聯胺(IrganoxMD1024,BASF公司製)、草酸雙(苄基聯胺)(EastmanInhibitorOABH、Eastman chemical製)、1,2,3-苯並三唑、5-甲基-1,2,3-苯並三唑、其他ADK STAB CDA-1(旭電化(股)製)、ADK STAB CDA-6(旭電化(股)製)、Qunox(三井東壓Fine(股)製)、NaugardXL-1(Uniroyal(股)製)等。尤其,宜使用5-甲基-1,2,3-苯並三唑。
上述離子捕捉劑的含量係相對於(A)成分之聚合物100質量份,宜為0.0001~20質量份,尤宜為0.001~10質量份。若未達0.0001質量份,有時無法得到金屬配線保護之效果,若超過20質量份,有時降低作為硬化膜之硬度、密著性等之特性。又,有時成本上不利。
於本發明之硬化膜形成組成物中係依需要而可添加(F)成分之多官能硫醇化合物。上述多官能硫醇化合物係宜為3官能以上之硫醇化合物。多官能硫醇化合物係可形成多元醇與單官能及/或多官能硫醇化合物之加成反應物而得到。具體之化合物可舉例如1,3,5-參(3-氫硫基丙醯基氧乙基)-三聚異氰酸酯、1,3,5-參(3-氫硫基丁醯基氧乙基)-三聚異氰酸酯(昭和電工(股)製、Karenz MT(註冊商標)NR1)、三羥甲基丙烷參(3-氫硫基丙酸酯)等之3官能硫醇化合物;季戊四醇肆(3-氫硫基丙酸酯)、季戊四醇肆(3-氫硫基丁酸酯)(昭和電工(股)製、Karenz MT(註冊商標)PEI)等之4官能硫醇化合物;二季戊四醇六(3-丙酸酯)等之6官能硫醇化合物等。
本發明之組成物中的多官能硫醇化合物之含有率宜為固形分中0.1~8質量%,更宜為0.8~5質量%。若含有率超出上述範圍,組成物之安定性、臭氣、感度、解析性、顯像性、密著性等變惡化。又,固形分謂從硬化膜形成組成物之全成分除去(D)溶劑者。
本發明之硬化膜形成組成物中係依需要而可添加(G)成分之聚合抑制劑。上述聚合抑制劑可舉例如2,6-二異丁基酚、3,5-二-第三丁基酚、3,5-二-第三丁基甲酚、氫醌、氫醌單甲基醚、沒食子酸、第三丁基兒茶酚、4-甲氧基-1-萘酚等。
本發明之組成物中的(G)成分之聚合抑制劑的含有率宜為固形分中1質量%以下,更宜為0.5質量%以下。若含有率超出上述範圍,引起硬化不良,有時反應變成不充分。
進一步,本發明之硬化膜形成組成物係只要無損本發明之效果,可依需要而含有界面活性劑、流變調整劑、矽烷偶合劑等之黏著補助劑、顏料、染料、保存安定劑、消泡劑、多價酚或多價羧酸等之溶劑促進劑等。
界面活性劑係無特別限定,但可舉例如氟系界面活性劑、聚矽氧系界面活性劑、非離子系界面活性劑等。此種之界面活性劑係可使用例如住友3M(股)製、大日本油墨化學工業(股)製或旭硝子(股)製等之市售品。此等市售品係可容易取得,故佳。其具體例可舉例如EFTOP EF301、EF303、EF352((股)JEMCO製)、Megafac F171、F173(大日本油墨化學工業(股)製)、Fluorad FC430、FC431(住友3M(股)製)、Asahiguard AG710、Surflone S-382、SC101、SC102、SC103、SC104、SC105、SC106(旭硝子(股)製)等之氟系界面活性劑。
本發明之硬化膜形成組成物的較佳例係如以下般。
[1]相對於(A)成分100質量份,含有0.5~200質量份之(B)成分、1~20質量份之(C)成分、依需要之0.0001~20質量份的(E)成分,此等溶解於(D)溶劑之硬化膜形成組成
物。
[2]在上述[1]之組成物中,進一步以固形分中0.1~8質量%之範圍含有(F)成分之硬化膜形成組成物。
[3]在上述[1]或[2]之組成物中,進一步以固形分中1質量%以下含有(G)成分之硬化膜形成組成物。
本發明之硬化膜形成組成物中的固形分之比率係只要各成分均一地溶解於溶劑即可,無特別限定,但宜為1~80質量%,更宜為5~60質量%,最宜為10~50質量%。
本發明之硬化膜形成組成物的調製方法係無特別限定。其一例係可舉例如使(A)成分溶解於(D)溶劑,在此溶液中以特定之比率混合(B)成分、(C)成分、更依需要之(E)成分等,形成均一的溶液之方法。又,在此調製方法之適當階段中,進一步添加(F)成分、(G)成分及其他之成分而混合的調製方法。
當本發明之硬化膜形成組成物的調製時,係可直接使用藉由溶劑中之聚合反應所得到的(A)成分之溶液,此時,於此(A)成分之溶液中與上述同樣地置入(B)成分、(C)成分、進一步依需要之(E)成分等而形成均一的溶液時,以濃度調整為目的而進一步追加投入(D)溶劑。此時,在(A)成分之合成過程所使用的溶劑與硬化膜形成組成物之調製時用以調整濃度所使用之(D)溶劑係可為相同,亦可為相異者。
此做法所調製之溶液狀態的硬化膜形成組成物係宜使用孔徑為0.2μm左右的過濾器等而過濾後使用。
使本發明之硬化膜形成組成物在基板(例如矽/二氧化矽被覆基板、氮化矽基板、以金屬例如鋁、鉬、鉻等被覆之基板、玻璃基板、石英基板、ITO基板等)或薄膜(例如三乙醯基纖維素薄膜、聚酯薄膜、丙烯酸薄膜等之樹脂薄膜)等之上,藉由旋轉塗佈、垂流塗佈、輥輪塗佈、狹縫塗佈、繼狹縫之旋轉塗佈、噴墨塗佈、印刷塗佈等而進行塗佈,其後,以加熱板或烘箱等進行預備乾燥(預烘烤),俾可形成塗膜。
藉由對上述所得到之膜照射紫外線等之光,進行光硬化。上述光之波長宜為200~500nm,其曝光量宜為100~5000mJ/cm2。
然後,進行熱硬化用之後烘烤。具體上係使用加熱板或烘箱等而加熱。後烘烤一般可採用以溫度60℃~150℃,更佳係80℃~120℃的範圍中選出之加熱溫度,加熱板上之時係處理5~30分鐘,在烘箱中之時係處理30~90分鐘之方法。
依據如上述之條件,藉由使本發明之硬化膜形成組成物硬化,俾可充分使基板之段差平坦化,可形成具有高透明性之硬化膜。
又,本發明之硬化膜形成組成物係因具有至少必需之水準的平坦化性、硬度及密著性,故亦可用來作為形成薄膜電晶體(TFT)型液晶顯示元件、有機EL元件等之各種顯
示器的保護膜、平坦化膜、絕緣膜等之硬化膜的材料,尤其,適宜作為ITO薄膜用之被覆材。
使用本發明之硬化膜形成組成物所得到的硬化膜係因含有具有三烷氧基矽烷構造之聚合物,故硬度高且密著性優異。進一步,藉多官能丙烯酸酯,可進一步改善硬度。又,藉由含有多價硫醇化合物,俾柔軟性優,亦可進一步改善密著性。藉由此等,即使過多地含有多官能丙烯酸酯,亦不產生剝離及龜裂。而且,此薄膜係因透明性良好,故亦適宜利用於可撓性顯示器或觸控面板。
以下,舉出合成例,實施例及比較例,更詳細地說明本發明,但本發明係不限定於此等實施例。
又,在合成例中所得到的聚合物之重量平均分子量(Mw)係使用昭和電工(股)製GPC裝置(Shodex GPC-101)(管柱:Shodex(註冊商標)KF803L及KF804L(昭和電工(股)製)),使溶出溶劑四氫呋喃以流量1mL/分流入管柱中(管柱溫度40℃)而溶離之條件測定。Mw係以聚苯乙烯換算值表示。
又,在下述合成例、實施例、比較例使用之試藥及裝置係如下。
‧DEGMEA(二乙二醇單乙基醚乙酸酯)、MMA(甲基丙烯酸酯)、MAA(甲基丙烯酸)、ST(苯乙烯)、tBuST(4-第三丁基苯乙烯):東京化成工業(股)製。
‧KBM-503:3-甲基丙烯醯氧丙基三甲氧基矽烷、信越化學工業(股)製。
‧MAIB:2,2’-偶氮雙(異酪酸)二甲酯、東京化成工業(股)製。
‧PET-30:季戊四醇(三/四)丙烯酸酯、日本化藥(股)製。
‧DPHA:二季戊四醇(六/五)丙烯酸酯(Kayarad
DPHA、日本化藥(股)製。
‧IRG500:光聚合起始劑、BASF公司製Irgacure 500。
‧IRG651:光聚合起始劑、BASF公司製Irgacure 651。
‧PE1:鏈移動劑、昭和電工(股)製、Karez MT-PE1。
‧MBTA:5-甲基-1,2,3-苯並三唑、東京化成工業(股)製。
‧4-MNP:4-甲氧基-1-萘酚、東京化成工業(股)製。
‧AGITAN771:消泡劑、MUNZING公司製。
‧攪拌裝置:(股)Thinky製AWATORI鍊太郎ARE-310。
‧Z320:Daicel.Cytec(股)製Cyclomer-P。
於1000ml之四口燒瓶中置入DEGMEA 375.8g,氮氣
環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 300g及MAIB 7.5g之混合液。滴入後反應20小時,得到樹脂溶液P1。Mw=約3萬。
於1000ml之四口燒瓶中置入DEGMEA 436.1g,氮氣環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 270g、KBM-503 78.1g及MAIB 8.7g之混合液。滴入後反應20小時,得到樹脂溶液P2。Mw=約2萬5千。
於1000ml之四口燒瓶中置入DEGMEA 476.3g,氮氣環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 280g、MAA 29.8g及MAIB 7.7g之混合液。滴入後反應20小時,得到樹脂溶液P3。Mw=約3萬。
於1000ml之四口燒瓶中置入DEGMEA 424.5g,氮氣環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 190g、KBM-503 63.5g、tBuST 86.9g及MAIB 6.9g之混合液。滴入後反應20小時,得到樹脂溶液P4。Mw=約2萬。
於1000ml之四口燒瓶中置入DEGMEA 460.7g,氮氣環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 230g、MAA 24.7g、tBuST 46g及MAIB 6.4g之混合液。滴入後反應20小時,得到樹脂溶液P5。Mw=約2萬。
於1000ml之四口燒瓶中置入DEGMEA 424.5g,氮氣環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 190g、KBM-503 63.5g、ST 56.5g及MAIB 6.9g之混合液。滴入後反應20小時,得到樹脂溶液P6。Mw=約2萬。
於1000ml之四口燒瓶中置入DEGMEA 460.7g,氮氣環境下在80℃(內溫)下攪拌。再花2小時徐緩地滴入MMA 230g、MAA 24.7g、ST 30g及MAIB 6.4g之混合液。滴入後反應20小時,得到樹脂溶液P7。Mw=約2萬。
於200ml之塑膠容器中置入於合成例2所得到之樹脂
溶液P2 20g、DHPA 5.4g、PE1 0.54g、IRG 500 0.54g,再置入於攪拌裝置,以10分鐘、2000rpm攪拌,製作清漆(實施例1)。
同樣地,以表1所示之組成,製作清漆(實施例2-8、比較例1)。
使上述之樹脂組成物桿塗佈機塗佈於三容真空(股)製之ITO薄膜(阻抗膜(高透過)ITO薄膜、阻抗值:400±100Ω/sq、全光透過率:>90%)上,以使厚度成為約3~10μm,首先,以110℃進行預烘烤5分鐘。然後,進行UV照射(400mJ/cm2),其後,以110℃進行後烘烤55分
鐘,製作硬化膜。
對於所得到之硬化膜,藉由下述方法而進行密著性之評估。
藉由交叉切割試驗方法進行評估。首先,使用切割刀導引,於塗佈膜製作100個棋盤眼。然後,於該棋盤眼上黏著Nichiban(股)製之賽路玢膠帶(註冊商標),從上面以橡皮擦強力擦拭,充分密著。繼而,其次,剝離賽路玢膠帶(註冊商標),其時,100個棋盤眼之中,以有幾個剝離開來進行評估。
OB:66個以上剝離
1B:36個~65個剝離
2B:16個~35個剝離
3B:6個~15個剝離
4B:1個~5個剝離
5B:無剝離
將以上之評估結果表示於表2中。
從表2所示之結果可知,從實施例1~8之硬化膜形成組成物所得到的硬化膜係密著性比比較例還高。
於1000ml之四口燒瓶中,置入DEGMEA 454.9g,在氮氣環境下,以80℃(內溫)攪拌,同時再花2小時徐緩地滴入MMA 250.0g、tBuST 91.5g、KBM-503 70.9g及MAIB 9.9g之混合液。滴入後,進一步以80℃反應20小時,得到樹脂溶液P8。Mw=約3萬。
於1000ml之四口燒瓶中,置入DEGMEA 506.5g,在氮氣環境下,以80℃(內溫)攪拌,同時再花2小時徐緩地滴入MMA 250.0g、tBuST 50.0g、MAA 26.9g及MAIB 10.8g之混合液。滴入後,進一步以80℃反應20小時,
得到樹脂溶液P9。Mw=約3萬。
於1000ml之四口燒瓶中,置入DEGMEA 520.0g,在氮氣環境下,以80℃(內溫)攪拌,同時再花2小時徐緩地滴入MMA 250.0g、ST 74.6g、KBM-503 88.6g及MAIB 12.3g之混合液。滴入後,進一步以80℃反應20小時,得到樹脂溶液P10。Mw=約3萬。
於1000ml之四口燒瓶中,置入DEGMEA 480.4g,在氮氣環境下,以80℃(內溫)攪拌,同時再花2小時徐緩地滴入MMA 250.0g、ST 32.6g、MAA 26.9g及MAIB 10.8g之混合液。滴入後,進一步以80℃反應20小時,得到樹脂溶液P11。Mw=約3萬。
於200ml之塑膠容器中置入於合成例8所得到之樹脂溶液P8 11.3g、於合成例9所得到之樹脂溶液P9 50.9g、PET-30 17.8g、IRG 500 3.1g、PE1 3.1g、MBTA 0.02g、AGITAN771 0.03g、DEGMEA 14.7g,再置入於攪拌裝置中,以10分鐘、2000rpm攪拌,製作清漆(實施例9)
同樣地,以表3所示之組成,製作清漆(實施例10-
14、比較例2-4)。
使上述之清漆桿塗佈機塗佈於三容真空(股)製之ITO薄膜(阻抗膜(高透過)ITO薄膜、阻抗值:400±100Ω/sq、全光透過率:>90%)上,以使厚度成為約3~10μm,首先,以110℃進行預烘烤10分鐘。然後,進行UV照射(400mJ/cm2),其後,以110℃進行後烘烤50分鐘,製作硬化膜。
對於所得到之硬化膜,藉由下述方法而進行鉛筆硬度、密著性、柔軟性之評估。
依據JIS K 5400,以1000g荷重測定。結果表示於表4。
藉由交叉切割試驗方法進行評估。首先,使用切割刀導引,於塗佈膜製作100個棋盤眼。然後,於該棋盤眼上黏著Nichiban(股)製之賽路玢膠帶(註冊商標),從上面以橡皮擦強力擦拭,充分密著。繼而,其次,剝離賽路玢膠帶(註冊商標),其時,100個棋盤眼之中,以有幾個剝離開來進行評估。
OB:66個以上剝離
1B:36個~65個剝離
2B:16個~35個剝離
3B:6個~15個剝離
4B:1個~5個剝離
5B:無剝離
使薄膜以塗佈側作為外側而沿著直徑4cm之圓柱,固定15秒。觀察塗膜之外觀的變化,以無變化者作為○,產生龜裂者作為×。結果表示於表4。
從表4所示之結果可知,從實施例9~14之硬化膜形成組成物所得到的硬化膜係任一者均鉛筆硬度高達F以上,密著性亦高達4B以上,柔軟性亦良好。
另外,有關比較例2~4係密著性低至2B以下,無法滿足鉛筆硬度、密著性、柔軟性之全部。
Claims (8)
- 一種硬化膜形成組成物,其特徵係含有:(A)(A-1)具有以下述式(1)所示之重複單元的聚合物
- 如申請專利範圍第1項之硬化膜形成組成物,其中進一步含有(A-2)具有以下述式(2)所示之重複單元的聚合物作為(A)成分
- 如申請專利範圍第1或2項之硬化膜形成組成物,其中上述聚合物進一步具有以下述式(3)所示之重複單元
- 如申請專利範圍第1~3項中任一項之硬化膜形成組成物,其中進一步含有(E)離子捕捉劑。
- 如申請專利範圍第1~4項中任一項之硬化膜形成組成物,其中進一步含有(F)多官能硫醇化合物。
- 一種硬化膜之製造方法,其特徵係於基板上塗佈如申請專利範圍第1~5項中任一項之硬化膜形成組成物,照射紫外線後,以80℃~120℃進行燒成。
- 一種硬化膜,其係以如申請專利範圍第6項之製造方法來製造。
- 一種薄膜,其係具有如申請專利範圍第7項之硬化膜。
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KR (1) | KR20150052080A (zh) |
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TWI667274B (zh) * | 2014-07-23 | 2019-08-01 | 日商日產化學工業股份有限公司 | Resin composition for forming cured film, cured film, conductive member, and method for suppressing transfer |
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JP6561062B2 (ja) * | 2014-09-01 | 2019-08-14 | 株式会社カネカ | 硬化性組成物 |
TW201625730A (zh) * | 2014-11-25 | 2016-07-16 | Nissan Chemical Ind Ltd | 硬化膜形成用樹脂組成物、硬化膜、導電性構件、以及抑制金屬之電極及/或金屬之配線的腐蝕的方法 |
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JPH06287470A (ja) * | 1993-04-05 | 1994-10-11 | Mitsubishi Petrochem Co Ltd | 耐摩耗性被覆組成物 |
JPH08245903A (ja) * | 1995-03-10 | 1996-09-24 | Dainippon Ink & Chem Inc | 銀被覆用活性エネルギー線硬化型樹脂組成物 |
JP4814412B2 (ja) * | 2000-03-16 | 2011-11-16 | 関西ペイント株式会社 | 硬化組成物およびその被膜形成方法 |
JP2008255180A (ja) * | 2007-04-03 | 2008-10-23 | Toyo Ink Mfg Co Ltd | 活性エネルギー線硬化性樹脂組成物およびその積層体 |
JP2009215364A (ja) * | 2008-03-07 | 2009-09-24 | Fujifilm Corp | 光硬化性組成物、それを用いる接着方法、液晶パネルの製造方法 |
KR101151063B1 (ko) * | 2009-03-31 | 2012-06-01 | 히다치 가세고교 가부시끼가이샤 | 전자 부품용 액상 수지 조성물 및 전자 부품 장치 |
JP2012008262A (ja) * | 2010-06-23 | 2012-01-12 | Fujifilm Corp | 着色感光性樹脂組成物、パターン形成方法、カラーフィルタの製造方法、カラーフィルタ、およびそれを備えた表示装置 |
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TWI667274B (zh) * | 2014-07-23 | 2019-08-01 | 日商日產化學工業股份有限公司 | Resin composition for forming cured film, cured film, conductive member, and method for suppressing transfer |
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JPWO2014034516A1 (ja) | 2016-08-08 |
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